JP2012046787A - Forged alloy for steam turbine and steam turbine rotor using the same - Google Patents

Forged alloy for steam turbine and steam turbine rotor using the same Download PDF

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JP2012046787A
JP2012046787A JP2010188982A JP2010188982A JP2012046787A JP 2012046787 A JP2012046787 A JP 2012046787A JP 2010188982 A JP2010188982 A JP 2010188982A JP 2010188982 A JP2010188982 A JP 2010188982A JP 2012046787 A JP2012046787 A JP 2012046787A
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steam turbine
heat treatment
grain size
forged alloy
crystal grain
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JP5633883B2 (en
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Hiroki Kamoshida
宏紀 鴨志田
Shinya Konno
晋也 今野
Jun Sato
順 佐藤
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Hitachi Ltd
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/056—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12—Blades
    • F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2220/00—Application
    • F05D2220/30—Application in turbines
    • F05D2220/31—Application in turbines in steam turbines

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a forged alloy for a steam turbine of good creep property and fatigue property, and to provide a rotor for a steam turbine using the forged alloy.SOLUTION: The forged alloy for the steam turbine includes, by weight, 15-45% Fe; 14-18% Cr; 1.0-1.8% Ti; 1.0-2.0% Al; 1.25-3.0% Nb; 0.05% or less of C+N and the balance of Ni. The crystal grain size number after heat treatment of the forged alloy is 0 to 2, and the heat treatment includes a plurality of solution heat treatments in different temperature ranges.

Description

本発明は、主蒸気温度が６７５℃以上の蒸気タービン部品（例えばロータ）に用いるＮｉＦｅ基鍛造合金に関する。   The present invention relates to a NiFe-based forged alloy used for a steam turbine component (for example, a rotor) having a main steam temperature of 675 ° C. or higher.

石炭火力発電プラントの高効率化を目指して、蒸気温度が７００℃以上の火力プラントの開発が進められている。これまでの蒸気タービン部品（例えば、ロータ，ボルト，ブレード）には、鉄系の材料である１２Ｃｒ系フェライト鋼が用いられているが、使用環境として蒸気温度で６５０℃が限界であると言われている。それに代わって、７００℃級の蒸気タービン部品には、析出強化型合金であるＮｉ基系の材料が検討されている。   Development of a thermal power plant having a steam temperature of 700 ° C. or higher is being promoted with the aim of increasing the efficiency of a coal thermal power plant. Conventional steam turbine parts (for example, rotors, bolts, blades) are made of 12Cr ferritic steel, which is an iron-based material, but it is said that 650 ° C is the limit as the operating environment. ing. Instead, Ni-based materials, which are precipitation-strengthened alloys, are being studied for 700 ° C-class steam turbine components.

蒸気タービン部品は、大型のものが多いため、求められる特性として、大型鋼塊製造性や熱間鍛造性、また熱膨張係数の比較的小さいフェライト鋼と組み合わせての適用が考えられるため、低熱膨張性も求められる。   Since steam turbine parts are often large-sized, low thermal expansion is possible because the properties required are large steel ingot manufacturability, hot forgeability, and ferritic steel with a relatively low thermal expansion coefficient. Sex is also required.

例えば、特許文献１に示すＮｉ基合金（ＵＳＣ１４１）は、Ｎｉ基の中でも線膨張係数が小さく、クリープ強度も７００℃級の蒸気タービンに使用されようとしている候補材の中でも、優れた強度を有している。   For example, the Ni-based alloy (USC141) shown in Patent Document 1 has excellent strength even among candidate materials that have a low coefficient of linear expansion among Ni-based alloys and have a creep strength of 700 ° C class steam turbines. is doing.

また、特許文献２に示すＦｅ−Ｎｉ基合金では、偏析元素であるＮｂを低減させ、γ′相生成元素であるＡｌを増やすことで、大型鋼塊製造性とクリープ強度を両立した材料であり、蒸気タービンの大型部材、例えばロータへの適用が期待される。   In addition, the Fe—Ni base alloy shown in Patent Document 2 is a material that achieves both large steel ingot manufacturability and creep strength by reducing the segregation element Nb and increasing the γ ′ phase generation element Al. Application to a large member of a steam turbine such as a rotor is expected.

材料の特性は、材料組成が同じでも、材料組織によって大きく異なる。結晶粒径が大きくなると、クリープ強度は高くなるが、疲労特性が低下するという問題があった。   Even if the material composition is the same, the characteristics of the material vary greatly depending on the material structure. When the crystal grain size is increased, the creep strength is increased, but there is a problem that the fatigue characteristics are lowered.

特開平９−１５７７７９号公報JP-A-9-157779 特開２００５−２９２９号公報JP 2005-2929 A

本発明の目的は、クリープ特性と疲労特性に優れた蒸気タービン用鍛造合金、それを用いた蒸気タービンロータを提供することにある。   An object of the present invention is to provide a forged alloy for a steam turbine excellent in creep characteristics and fatigue characteristics, and a steam turbine rotor using the forged alloy.

すなわち、本発明の蒸気タービン用鍛造合金は、重量で、Ｆｅ１５〜４５％，Ｃｒ１４〜１８％，Ｔｉ１.０〜１.８％，Ａｌ１.０〜２.０％，Ｎｂ１.２５〜３.０％，Ｃ＋Ｎ０.０５％以下、残部Ｎｉからなる蒸気タービン用鍛造合金を、熱処理した後の結晶粒度番号が０〜２であって、前記熱処理が、異なる温度範囲での複数の溶体化熱処理を含むことを特徴とする。   That is, the forged alloy for steam turbines of the present invention is Fe 15-45%, Cr 14-18%, Ti 1.0-1.8%, Al 1.0-2.0%, Nb 1.25-3.0 by weight. %, C + N 0.05% or less, forged alloy for steam turbine made of balance Ni, grain size number after heat treatment is 0-2, and the heat treatment includes a plurality of solution heat treatments in different temperature ranges It is characterized by that.

本発明によれば、クリープ特性と疲労特性に優れた蒸気タービン用鍛造合金、それを用いた蒸気タービンロータを提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the forge alloy for steam turbines excellent in creep characteristics and fatigue characteristics, and a steam turbine rotor using the same can be provided.

結晶粒度番号とクリープ破断時間との関係を示す図（クリープ条件；７００℃，３３３ＭＰａ）。The figure which shows the relationship between a crystal grain size number and creep rupture time (creep conditions; 700 degreeC, 333 MPa). 結晶粒度番号と低サイクル疲労破断回数との関係を示す図（ひずみ範囲；０.８％，７００℃）。The figure which shows the relationship between a grain size number and the low cycle fatigue fracture number (strain range; 0.8%, 700 degreeC).

本発明者らは、材料の結晶粒度（結晶粒径）が、クリープ強度と疲労特性に及ぼす影響を検討した。γ′相の溶体化温度を通常よりも高くすることで、結晶粒径（結晶粒度）を粗大化させた。   The inventors examined the influence of the crystal grain size (crystal grain size) of the material on creep strength and fatigue characteristics. The crystal grain size (crystal grain size) was coarsened by raising the solution temperature of the γ ′ phase higher than usual.

結晶粒度番号が０〜２のＮｉＦｅ鍛造合金を用いて、クリープ強度と疲労特性を調査した結果、同じクリープ条件でクリープ破断時間が、通常よりも約６倍長くなることがわかった。さらに、疲労特性は、同じ低サイクル疲労試験条件下において、大きな低下が見られなかった。   As a result of investigating creep strength and fatigue characteristics using a NiFe forged alloy having a grain size number of 0 to 2, it was found that the creep rupture time was about 6 times longer than usual under the same creep conditions. Furthermore, the fatigue characteristics did not show a significant decrease under the same low cycle fatigue test conditions.

以下、本発明のＮｉＦｅ基鍛造合金を説明する。   Hereinafter, the NiFe-based forged alloy of the present invention will be described.

（ＮｉＦｅ基鍛造合金）
Ａｌは、Ｎｂ低減による強度低下を補い、組織安定性を向上させるため、１.０重量％以上含有させることが必要である。しかし、過度の含有は、γ′相の過度な増加による鍛造性の悪化を生じるため、２.０重量％以下とする。 (NiFe-based forged alloy)
Al is required to be contained in an amount of 1.0% by weight or more in order to compensate for a decrease in strength due to Nb reduction and improve the structural stability. However, excessive content causes deterioration of forgeability due to excessive increase of the γ ′ phase, so it is made 2.0% by weight or less.

Ｔｉは、γ′相を析出させる元素であり、また、高温でＮｉ3Ｔｉを安定にする元素であるため、過大な含有は好ましくなく、１.０〜１.８重量％とする。 Ti is an element for precipitating the γ 'phase, and is an element that stabilizes Ni 3 Ti at a high temperature. Therefore, excessive content is not preferable, and the content is 1.0 to 1.8% by weight.

ＣとＮは、前述のように、ＮｂＣの増加に伴う結晶粒の微細化を抑えるため、ＣとＮとの総和で０.０５重量％以下とする。   As described above, C and N are 0.05% by weight or less in total of C and N in order to suppress the refinement of crystal grains accompanying the increase in NbC.

Ｆｅは、有害析出相であるσ相およびδ相の析出を抑制するため、１５〜４５重量％とする。   Fe is 15 to 45% by weight in order to suppress precipitation of σ phase and δ phase, which are harmful precipitation phases.

Ｎｂは、γ′相の安定化元素であり、含有量が少なすぎると、有効な強度が得られないため、また過度の含有は偏析特性の悪化を招くため、１.２５〜３.０重量％とする。   Nb is a stabilizing element of the γ 'phase, and if the content is too small, an effective strength cannot be obtained, and excessive content causes deterioration of segregation characteristics. %.

Ｃｒは、過度の含有は有害析出相であるσ相の析出を促すが、耐酸化性を得るため、１４〜１８重量％とする。   When Cr is excessively contained, the precipitation of the σ phase, which is a harmful precipitation phase, is promoted.

本発明のＮｉ−Ｆｅ基超合金は、以上述べた成分と、残部のＮｉから構成される。これらの成分以外に、原料中、もしくは製造過程で混入する元素が不純物として含まれることがある。若干の不純物の混入は避けることができないことから、ここでは、不可避不純物と称している。   The Ni—Fe-based superalloy of the present invention is composed of the above-described components and the remaining Ni. In addition to these components, elements mixed in the raw material or in the manufacturing process may be included as impurities. Since some impurities cannot be avoided, they are referred to as inevitable impurities here.

次に、ＮｉＦｅ基鍛造合金の製造方法を説明する。   Next, a method for producing a NiFe-based forged alloy will be described.

（ＮｉＦｅ基鍛造合金の製造方法）
まず、上記組成からなるＮｉＦｅ基鍛造合金について、２段階の溶体化熱処理を行う。 (Method for producing NiFe-based forged alloy)
First, a two-step solution heat treatment is performed on the NiFe-based forged alloy having the above composition.

１段目の溶体化熱処理は、１０２０℃〜１１００℃で１〜１０時間行う。１０２０℃未満であると、結晶粒の粗大化が進まない、もしくは長時間の熱処理が必要となり実用的ではない。一方、１１００℃を超えると、結晶粒の粗大化速度が速くなるため、結晶粒径の制御が難しい。   The first solution heat treatment is performed at 1020 ° C. to 1100 ° C. for 1 to 10 hours. If it is less than 1020 ° C., the crystal grains do not become coarse, or a long-time heat treatment is required, which is not practical. On the other hand, when the temperature exceeds 1100 ° C., the coarsening rate of the crystal grains increases, so that it is difficult to control the crystal grain size.

２段目の溶体化熱処理は、９６５℃〜９９５℃で１〜４時間行う。この温度範囲は、一般的にこの種のＮｉ基合金で溶体化熱処理として行われる温度でよい。この温度範囲にすることで、γ′相を析出させずに炭化物のみを析出させ、時効熱処理時に、炭化物が結晶粒界に連続的に析出させることを防ぐことを目的とする。   The second solution heat treatment is performed at 965 ° C. to 995 ° C. for 1 to 4 hours. This temperature range may be a temperature generally used as a solution heat treatment with this type of Ni-based alloy. The purpose of this temperature range is to precipitate only the carbide without precipitating the γ 'phase and prevent the carbide from continuously precipitating at the grain boundaries during the aging heat treatment.

次に、時効熱処理を行う。時効熱処理の温度は、この種のＮｉＦｅ基鍛造合金で時効熱処理で一般的に行われる温度でよい。好ましくは２回にわたる時効処理がよく，１回目は８２５〜８５５℃で１０時間以内，２回目はそれ以下の温度で７１０〜７４０℃で１０〜４８時間である。   Next, an aging heat treatment is performed. The temperature of the aging heat treatment may be a temperature generally used in aging heat treatment with this type of NiFe-based forged alloy. The aging treatment is preferably carried out twice, the first time being within 850 hours at 825 to 855 ° C., and the second time being 10 to 48 hours at 710 to 740 ° C. at a lower temperature.

次に、熱処理後の結晶粒度を説明する。   Next, the crystal grain size after the heat treatment will be described.

（熱処理後の結晶粒度）
熱処理後の結晶粒度（結晶粒径）は、日本工業規格（ＪＩＳ）における結晶粒度番号で０〜２、好ましくは１〜２の範囲である。結晶粒度番号は、その値が小さいほど、結晶粒度が大きいことを意味する。 (Grain size after heat treatment)
The crystal grain size (crystal grain size) after the heat treatment is 0 to 2, preferably 1 to 2 in terms of crystal grain size number in Japanese Industrial Standards (JIS). The crystal grain size number means that the smaller the value, the larger the crystal grain size.

０より小さい結晶粒度番号、つまり結晶粒径が大きくなると、疲労特性が低下する傾向にあり、超音波透過性が悪くなるために欠陥検出性が低くなりやすい。   When the crystal grain size number smaller than 0, that is, the crystal grain size is increased, the fatigue characteristics tend to be lowered, and the ultrasonic wave permeability is deteriorated, so that the defect detectability tends to be lowered.

一方、２より大きい結晶粒度番号、つまり結晶粒径が小さくなると、疲労特性やクリープ破断延性は維持、もしくは改善されるが、クリープ強度は従来と大きく変わらず、改善が見られない。   On the other hand, when the crystal grain size number larger than 2, that is, the crystal grain size becomes small, the fatigue characteristics and creep rupture ductility are maintained or improved, but the creep strength is not greatly changed from the conventional one and no improvement is observed.

以下、実施例を示して本発明を具体的に説明する。   Hereinafter, the present invention will be specifically described with reference to examples.

真空誘導溶解（ＶＩＭ）とエレクトロスラグ再溶解（ＥＳＲ）のダブルメルトプロセスによって得られた素材を熱間鍛造し、供試材を作成した。   A material obtained by a double melt process of vacuum induction melting (VIM) and electroslag remelting (ESR) was hot forged to prepare a specimen.

表１に、供試材の組成を示す。   Table 1 shows the composition of the test material.

Figure 2012046787
Figure 2012046787

（供試材の熱処理）
得られた供試材について、表２に示す温度条件で溶体化熱処理を２回行い、時効熱処理した後、結晶粒度番号を測定した。結晶粒度番号の測定は、ＪＩＳ Ｇ０５５１に準拠した。 (Heat treatment of test material)
The obtained specimen was subjected to solution heat treatment twice under the temperature conditions shown in Table 2, and after aging heat treatment, the crystal grain size number was measured. The measurement of the crystal grain size number was based on JIS G0551.

１回目の溶体化熱処理の温度範囲が１０２０〜１１００℃のものを本発明材Ａ，Ｂ，Ｃとし、それ以外のものを比較材Ａ，Ｂ，Ｃとした。   The material having the temperature range of the first solution heat treatment at 1020 to 1100 ° C. was designated as the present invention materials A, B, and C, and the other materials were designated as comparative materials A, B, and C.

Figure 2012046787
Figure 2012046787

本発明材Ａ，本発明材Ｂ，本発明材Ｃは、１回目の溶体化熱処理をそれぞれ１０２０℃×３時間，１０６０℃×３時間，１１００℃×３時間で行った後、２回目の溶体化熱処理を９８０℃×２時間で行った。その後、時効熱処理を８４０℃×８時間，７４０℃×２４時間行った。   Invention Material A, Invention Material B, and Invention Material C were subjected to the first solution heat treatment at 1020 ° C. × 3 hours, 1060 ° C. × 3 hours, and 1100 ° C. × 3 hours, respectively, The heat treatment was performed at 980 ° C. for 2 hours. Thereafter, aging heat treatment was performed at 840 ° C. × 8 hours and 740 ° C. × 24 hours.

比較材Ａ，比較材Ｂは、１回目の溶体化熱処理をそれぞれ１１４０℃×３時間，１１４０℃×１時間で行った後、２回目の溶体化熱処理を９８０℃×２時間で行った。その後、時効熱処理を８４０℃×８時間，７４０℃×２４時間行った。   Comparative material A and comparative material B were subjected to a first solution heat treatment at 1140 ° C. × 3 hours and 1140 ° C. × 1 hour, respectively, and then a second solution heat treatment at 980 ° C. × 2 hours. Thereafter, aging heat treatment was performed at 840 ° C. × 8 hours and 740 ° C. × 24 hours.

比較材Ｃは、１段目の溶体化熱処理を行わず、２段目の熱処理のみ行った。その後、時効熱処理を８４０℃×８時間，７４０℃×２４時間行った。   Comparative material C was not subjected to the first stage solution heat treatment, but only the second stage heat treatment. Thereafter, aging heat treatment was performed at 840 ° C. × 8 hours and 740 ° C. × 24 hours.

表２に示すとおり、溶体化熱処理を２回行い、１回目の温度を１０２０〜１１００℃とした本発明材Ａ，Ｂ，Ｃは、結晶粒度番号が２，１，０であった。比較材Ａ，Ｂ，Ｃは−１，−０.７，３であった。   As shown in Table 2, the material A, B and C of the present invention in which the solution heat treatment was performed twice and the first temperature was 1020 to 1100 ° C. had crystal grain size numbers of 2, 1, 0. Comparative materials A, B, and C were −1, −0.7, and 3, respectively.

溶体化熱処理の温度範囲を調整することで、熱処理後の結晶粒度番号を０〜２にすることができる。   By adjusting the temperature range of the solution heat treatment, the grain size number after the heat treatment can be set to 0-2.

（クリープ試験）
本発明材Ａ，Ｂ，Ｃと、比較材Ａ，Ｂ，Ｃについて、７００℃，３３３ＭＰａの条件でクリープ試験を行った。 (Creep test)
A creep test was performed on the inventive materials A, B, and C and the comparative materials A, B, and C at 700 ° C. and 333 MPa.

結果を図１に示す。   The results are shown in FIG.

図１は、結晶粒度番号とクリープ破断時間との関係を示す図である。クリープ条件は７００℃，３３３ＭＰａである。従来、本材料においては、結晶粒度番号で３以下として粒度調整をした際の破断時間は２００時間である。図１に示すように、結晶粒度番号が小さくなるにつれて破断時間が長くなる傾向にある。   FIG. 1 is a diagram showing the relationship between the grain size number and the creep rupture time. The creep conditions are 700 ° C. and 333 MPa. Conventionally, in this material, the fracture time when the grain size is adjusted with a grain size number of 3 or less is 200 hours. As shown in FIG. 1, the fracture time tends to increase as the grain size number decreases.

（低サイクル疲労試験）
次に、図２に試験片における低サイクル疲労試験の結果を示す。図２は、結晶粒度番号と低サイクル疲労破断回数との関係を示す図である。 (Low cycle fatigue test)
Next, the result of the low cycle fatigue test in a test piece is shown in FIG. FIG. 2 is a diagram showing the relationship between the grain size number and the number of low cycle fatigue fractures.

ひずみ範囲は、０.８％，７００℃である。結晶粒度番号が１以上の場合、ほぼ横ばいであるが、０の場合、若干の低下傾向が見られ、０より小さい場合、破断回数が大きく低下している。   The strain range is 0.8%, 700 ° C. When the grain size number is 1 or more, it is almost flat.

したがって、図１，図２に示すとおり、クリープ強度については、結晶粒度番号で２以下であることが好ましく、疲労特性については、０以上、好ましくは１以上であることが好ましい。   Accordingly, as shown in FIGS. 1 and 2, the creep strength is preferably 2 or less in terms of the crystal grain size number, and the fatigue properties are preferably 0 or more, preferably 1 or more.

熱処理により、結晶粒度番号を０〜２、好ましくは１〜２に調整したＮｉＦｅ基鍛造合金を用いることで、クリープ強度を低下させることなく疲労特性を改善することができる。   By using a NiFe-based forged alloy having a grain size number adjusted to 0-2, preferably 1-2, by heat treatment, the fatigue characteristics can be improved without reducing the creep strength.

本発明材は、上記特性を備えるため、主蒸気温度が６７５℃を超えるような蒸気タービン発電プラントの蒸気タービン部品（例えば、ロータ）に好適である。   Since this invention material is provided with the said characteristic, it is suitable for the steam turbine components (for example, rotor) of a steam turbine power plant in which the main steam temperature exceeds 675 degreeC.

蒸気タービンは、大きく高圧タービン（中圧タービン），低圧タービンから構成される。例えば、蒸気温度７００℃級の蒸気タービンでも、温度の低くなる低圧タービンでは、６００℃以下となるため、鉄系の材料が用いられる一方、高圧タービン、一部の蒸気タービンの中圧タービンでは、蒸気温度が７００℃を超えるため、Ｎｉ基、もしくはＮｉ−Ｆｅ基合金がロータ，動翼，ケーシングボルトなどに用いられる。   The steam turbine is mainly composed of a high pressure turbine (medium pressure turbine) and a low pressure turbine. For example, even in a steam turbine with a steam temperature of 700 ° C., a low-pressure turbine with a low temperature has a temperature of 600 ° C. or less, and therefore, an iron-based material is used. Since the steam temperature exceeds 700 ° C., Ni-based or Ni—Fe-based alloys are used for rotors, blades, casing bolts and the like.

Claims (3)

重量で、Ｆｅ１５〜４５％，Ｃｒ１４〜１８％，Ｔｉ１.０〜１.８％，Ａｌ１.０〜２.０％，Ｎｂ１.２５〜３.０％，Ｃ＋Ｎ０.０５％以下、残部Ｎｉからなる蒸気タービン用鍛造合金を、熱処理した後の結晶粒度番号が０〜２であって、
前記熱処理が、異なる温度範囲での複数の溶体化熱処理を含むことを特徴とする蒸気タービン用鍛造合金。 Fe 15-45%, Cr 14-18%, Ti 1.0-1.8%, Al 1.0-2.0%, Nb 1.25-3.0%, C + N 0.05% or less, and the balance Ni The grain size number after heat treating the steam turbine forged alloy is 0-2,
The forged alloy for steam turbines, wherein the heat treatment includes a plurality of solution heat treatments in different temperature ranges. 請求項１において、前記異なる温度範囲が１０２０〜１１００℃と、９６５〜９９５℃であることを特徴とする蒸気タービン用鍛造合金。   The forged alloy for a steam turbine according to claim 1, wherein the different temperature ranges are 1020 to 1100 ° C and 965 to 995 ° C. 請求項１または２に記載の蒸気タービン用鍛造合金からなることを特徴とする蒸気タービンロータ。   A steam turbine rotor comprising the forged alloy for a steam turbine according to claim 1.
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