JP2011522987A - 熱回収蒸気発生装置と併用する放出物低減装置 - Google Patents
熱回収蒸気発生装置と併用する放出物低減装置 Download PDFInfo
- Publication number
- JP2011522987A JP2011522987A JP2011509479A JP2011509479A JP2011522987A JP 2011522987 A JP2011522987 A JP 2011522987A JP 2011509479 A JP2011509479 A JP 2011509479A JP 2011509479 A JP2011509479 A JP 2011509479A JP 2011522987 A JP2011522987 A JP 2011522987A
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- Prior art keywords
- catalyst
- scr
- reducing agent
- catalysts
- exhaust stream
- Prior art date
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- Pending
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- 238000011084 recovery Methods 0.000 title claims abstract description 7
- 230000009467 reduction Effects 0.000 title abstract description 13
- 239000003054 catalyst Substances 0.000 claims abstract description 238
- 238000000034 method Methods 0.000 claims abstract description 52
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 94
- 229910021529 ammonia Inorganic materials 0.000 claims description 43
- 239000003638 chemical reducing agent Substances 0.000 claims description 38
- 239000003426 co-catalyst Substances 0.000 claims description 29
- 238000002347 injection Methods 0.000 claims description 29
- 239000007924 injection Substances 0.000 claims description 29
- 229930195733 hydrocarbon Natural products 0.000 claims description 18
- 150000002430 hydrocarbons Chemical class 0.000 claims description 18
- 238000011144 upstream manufacturing Methods 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 229910002089 NOx Inorganic materials 0.000 description 42
- 239000007789 gas Substances 0.000 description 38
- 238000002485 combustion reaction Methods 0.000 description 27
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 22
- 229910002091 carbon monoxide Inorganic materials 0.000 description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 14
- 238000006722 reduction reaction Methods 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000012530 fluid Substances 0.000 description 7
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- 239000002918 waste heat Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000004401 flow injection analysis Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
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- MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical compound C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
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- 230000000116 mitigating effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
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- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/003—Arrangements of devices for treating smoke or fumes for supplying chemicals to fumes, e.g. using injection devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/343—Heat recovery
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
- B01D53/8646—Simultaneous elimination of the components
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
- F22B1/1807—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines using the exhaust gases of combustion engines
- F22B1/1815—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines using the exhaust gases of combustion engines using the exhaust gases of gas-turbines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
- F22B1/1861—Waste heat boilers with supplementary firing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B37/00—Component parts or details of steam boilers
- F22B37/008—Adaptations for flue-gas purification in steam generators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/06—Arrangements of devices for treating smoke or fumes of coolers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/40—Carbon monoxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/10—Catalytic reduction devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/30—Technologies for a more efficient combustion or heat usage
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Sustainable Energy (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Sustainable Development (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12770808P | 2008-05-15 | 2008-05-15 | |
| US61/127,708 | 2008-05-15 | ||
| US12/214,541 US8220274B2 (en) | 2008-05-15 | 2008-06-19 | Emission reduction method for use with a heat recovery steam generation system |
| US12/214,541 | 2008-06-19 | ||
| PCT/US2009/002951 WO2009139860A1 (en) | 2008-05-15 | 2009-05-13 | Emission reduction system for use with a heat recovery steam generation system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011522987A true JP2011522987A (ja) | 2011-08-04 |
| JP2011522987A5 JP2011522987A5 (https=) | 2012-06-28 |
Family
ID=41314825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011509479A Pending JP2011522987A (ja) | 2008-05-15 | 2009-05-13 | 熱回収蒸気発生装置と併用する放出物低減装置 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8220274B2 (https=) |
| EP (1) | EP2318682A4 (https=) |
| JP (1) | JP2011522987A (https=) |
| CN (1) | CN102187078A (https=) |
| WO (1) | WO2009139860A1 (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015064193A1 (ja) * | 2013-10-29 | 2015-05-07 | 株式会社エコ・サポート | ガスタービン・コンバインドサイクル発電システム |
| JP2016513229A (ja) * | 2013-01-23 | 2016-05-12 | シーメンス アクティエンゲゼルシャフト | アンモニアスリップ削減のためのガスタービンの作動方法 |
| JP2023512906A (ja) * | 2020-01-08 | 2023-03-30 | 株式会社イーエムコ | 火力発電所の排ガス処理方法 |
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| US20100175366A1 (en) * | 2009-01-09 | 2010-07-15 | General Electric Company | Ammonia injection system for peaker cycle |
| EP2378096B1 (en) * | 2009-01-14 | 2017-08-23 | Toyota Jidosha Kabushiki Kaisha | Engine |
| US9435534B2 (en) * | 2009-08-31 | 2016-09-06 | Holistic Engineering Inc | Energy-recovery system for a production plant |
| GB201008806D0 (en) * | 2010-05-26 | 2010-07-14 | Heat Recovery Solutions Ltd | Heat exchange unit |
| US9019108B2 (en) | 2010-08-05 | 2015-04-28 | General Electric Company | Thermal measurement system for fault detection within a power generation system |
| US9097182B2 (en) | 2010-08-05 | 2015-08-04 | General Electric Company | Thermal control system for fault detection and mitigation within a power generation system |
| US8627643B2 (en) * | 2010-08-05 | 2014-01-14 | General Electric Company | System and method for measuring temperature within a turbine system |
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| US20120102951A1 (en) * | 2010-10-29 | 2012-05-03 | Gilbert Otto Kraemer | Apparatus for reducing emissions and method of assembly |
| US8734745B2 (en) * | 2012-08-10 | 2014-05-27 | Nooter/Eriksen, Inc. | Ammonia injection system for an HRSG |
| US9593609B2 (en) | 2012-10-05 | 2017-03-14 | Peerless Mfg. Co. | System and method for urea decomposition to ammonia in a side stream for selective catalytic reduction |
| US9746177B2 (en) | 2012-11-12 | 2017-08-29 | Peerless Mfg. Co. | Urea decomposition and improved SCR NOx reduction on industrial and small utility boilers |
| US9388978B1 (en) | 2012-12-21 | 2016-07-12 | Mitsubishi Hitachi Power Systems Americas, Inc. | Methods and systems for controlling gas temperatures |
| US9097418B2 (en) * | 2013-02-05 | 2015-08-04 | General Electric Company | System and method for heat recovery steam generators |
| US9739478B2 (en) | 2013-02-05 | 2017-08-22 | General Electric Company | System and method for heat recovery steam generators |
| US9511350B2 (en) | 2013-05-10 | 2016-12-06 | Clean Diesel Technologies, Inc. (Cdti) | ZPGM Diesel Oxidation Catalysts and methods of making and using same |
| US9511355B2 (en) | 2013-11-26 | 2016-12-06 | Clean Diesel Technologies, Inc. (Cdti) | System and methods for using synergized PGM as a three-way catalyst |
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| JPS60159501A (ja) * | 1984-01-30 | 1985-08-21 | 株式会社日立製作所 | 排熱回収ボイラ装置 |
| JPS6287701A (ja) * | 1985-10-14 | 1987-04-22 | バブコツク日立株式会社 | Co除去装置を内蔵した排熱回収ボイラ |
| JPS63290301A (ja) * | 1987-05-21 | 1988-11-28 | 株式会社タクマ | 排熱回収ボイラ |
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- 2009-05-13 WO PCT/US2009/002951 patent/WO2009139860A1/en not_active Ceased
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016513229A (ja) * | 2013-01-23 | 2016-05-12 | シーメンス アクティエンゲゼルシャフト | アンモニアスリップ削減のためのガスタービンの作動方法 |
| JP2019023557A (ja) * | 2013-01-23 | 2019-02-14 | シーメンス アクティエンゲゼルシャフト | アンモニアスリップ削減のためのガスタービンの作動方法 |
| WO2015064193A1 (ja) * | 2013-10-29 | 2015-05-07 | 株式会社エコ・サポート | ガスタービン・コンバインドサイクル発電システム |
| JP2023512906A (ja) * | 2020-01-08 | 2023-03-30 | 株式会社イーエムコ | 火力発電所の排ガス処理方法 |
| JP7417013B2 (ja) | 2020-01-08 | 2024-01-18 | 株式会社イーエムコ | 火力発電所の排ガス処理方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20090282803A1 (en) | 2009-11-19 |
| EP2318682A1 (en) | 2011-05-11 |
| CN102187078A (zh) | 2011-09-14 |
| EP2318682A4 (en) | 2014-07-30 |
| WO2009139860A1 (en) | 2009-11-19 |
| US8220274B2 (en) | 2012-07-17 |
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