JP2011508037A - オレフィン類の重合用触媒成分 - Google Patents
オレフィン類の重合用触媒成分 Download PDFInfo
- Publication number
- JP2011508037A JP2011508037A JP2010540113A JP2010540113A JP2011508037A JP 2011508037 A JP2011508037 A JP 2011508037A JP 2010540113 A JP2010540113 A JP 2010540113A JP 2010540113 A JP2010540113 A JP 2010540113A JP 2011508037 A JP2011508037 A JP 2011508037A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst component
- hydrogen
- groups
- polymerization
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 59
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 26
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 54
- -1 magnesium halide Chemical class 0.000 claims abstract description 34
- 239000011949 solid catalyst Substances 0.000 claims abstract description 33
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 19
- 239000001257 hydrogen Substances 0.000 claims abstract description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 14
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 12
- 239000011777 magnesium Substances 0.000 claims abstract description 11
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 8
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920000098 polyolefin Polymers 0.000 claims abstract description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 22
- 239000007789 gas Substances 0.000 claims description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 125000005842 heteroatom Chemical group 0.000 claims description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 8
- 150000003377 silicon compounds Chemical class 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 125000005498 phthalate group Chemical class 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 15
- 239000010936 titanium Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 10
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000012265 solid product Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 238000005243 fluidization Methods 0.000 description 4
- 238000012685 gas phase polymerization Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000012018 catalyst precursor Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- IPKKHRVROFYTEK-UHFFFAOYSA-N dipentyl phthalate Chemical compound CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCC IPKKHRVROFYTEK-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- UUAMLBIYJDPGFU-UHFFFAOYSA-N 1,3-dimethoxypropane Chemical compound COCCCOC UUAMLBIYJDPGFU-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- MQHNKCZKNAJROC-UHFFFAOYSA-N dipropyl phthalate Chemical compound CCCOC(=O)C1=CC=CC=C1C(=O)OCCC MQHNKCZKNAJROC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- NOAIBMQZUGBONL-UHFFFAOYSA-N (1,3-dimethoxy-2-methylpropan-2-yl)benzene Chemical compound COCC(C)(COC)C1=CC=CC=C1 NOAIBMQZUGBONL-UHFFFAOYSA-N 0.000 description 1
- HPOWOWTVWZELDK-UHFFFAOYSA-N (1,3-dimethoxy-2-methylpropan-2-yl)cyclohexane Chemical compound COCC(C)(COC)C1CCCCC1 HPOWOWTVWZELDK-UHFFFAOYSA-N 0.000 description 1
- NXDUWPUPBXRKTJ-UHFFFAOYSA-N (2-benzyl-1,3-dimethoxypropan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(COC)(COC)CC1=CC=CC=C1 NXDUWPUPBXRKTJ-UHFFFAOYSA-N 0.000 description 1
- BEDHCUAJOBASSZ-UHFFFAOYSA-N (2-cyclopentyl-1,3-dimethoxypropan-2-yl)cyclopentane Chemical compound C1CCCC1C(COC)(COC)C1CCCC1 BEDHCUAJOBASSZ-UHFFFAOYSA-N 0.000 description 1
- PJSFQEVODHCOOF-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(3,3,3-trifluoropropyl)silane Chemical compound CCC1CCCCN1[Si](CCC(F)(F)F)(OC)OC PJSFQEVODHCOOF-UHFFFAOYSA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- OTIJMHPVYPMCPU-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2,3-dimethylindene Chemical compound C1=CC=C2C(COC)(COC)C(C)=C(C)C2=C1 OTIJMHPVYPMCPU-UHFFFAOYSA-N 0.000 description 1
- HHGPZISECHQRLO-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-methyl-4-phenylindene Chemical compound COCC1(COC)C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 HHGPZISECHQRLO-UHFFFAOYSA-N 0.000 description 1
- FXWFWIIEIAUQHQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-2-phenylindene Chemical compound C=1C2=CC=CC=C2C(COC)(COC)C=1C1=CC=CC=C1 FXWFWIIEIAUQHQ-UHFFFAOYSA-N 0.000 description 1
- OSTKQRYZSROERR-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-3,6-dimethylindene Chemical compound C1=C(C)C=C2C(COC)(COC)C=C(C)C2=C1 OSTKQRYZSROERR-UHFFFAOYSA-N 0.000 description 1
- ZKXOLTKRGCQGJN-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4,5,6,7-tetrahydroindene Chemical compound C1CCCC2=C1C(COC)(COC)C=C2 ZKXOLTKRGCQGJN-UHFFFAOYSA-N 0.000 description 1
- REYOVQKLCXXZTD-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-4-phenylindene Chemical compound COCC1(COC)C=CC2=C1C=CC=C2C1=CC=CC=C1 REYOVQKLCXXZTD-UHFFFAOYSA-N 0.000 description 1
- JEENAIJBWUBGSW-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(3,3,3-trifluoropropyl)indene Chemical compound C1=CC(CCC(F)(F)F)=C2C(COC)(COC)C=CC2=C1 JEENAIJBWUBGSW-UHFFFAOYSA-N 0.000 description 1
- RMXREGKBZYAVSC-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-(trifluoromethyl)indene Chemical compound C1=CC(C(F)(F)F)=C2C(COC)(COC)C=CC2=C1 RMXREGKBZYAVSC-UHFFFAOYSA-N 0.000 description 1
- UQGOQZUZKNXSTQ-UHFFFAOYSA-N 1,1-bis(methoxymethyl)-7-phenylindene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1=CC=CC=C1 UQGOQZUZKNXSTQ-UHFFFAOYSA-N 0.000 description 1
- CCLDGIOSEOHYTP-UHFFFAOYSA-N 1,1-bis(methoxymethyl)cyclopenta[a]naphthalene Chemical compound C1=CC=CC2=C3C(COC)(COC)C=CC3=CC=C21 CCLDGIOSEOHYTP-UHFFFAOYSA-N 0.000 description 1
- KWXZYQJINBQUCF-UHFFFAOYSA-N 1,2,3,4-tetrafluoro-5,5-bis(methoxymethyl)cyclopenta-1,3-diene Chemical compound COCC1(COC)C(F)=C(F)C(F)=C1F KWXZYQJINBQUCF-UHFFFAOYSA-N 0.000 description 1
- CELOJHLXFPSJPH-UHFFFAOYSA-N 1,3-dimethoxypropan-2-ylbenzene Chemical compound COCC(COC)C1=CC=CC=C1 CELOJHLXFPSJPH-UHFFFAOYSA-N 0.000 description 1
- NOWCPSTWMDNKTI-UHFFFAOYSA-N 1,3-dimethoxypropan-2-ylcyclohexane Chemical compound COCC(COC)C1CCCCC1 NOWCPSTWMDNKTI-UHFFFAOYSA-N 0.000 description 1
- SCTKUNIIBPPKNV-UHFFFAOYSA-N 1,8-dichloro-9,9-bis(methoxymethyl)fluorene Chemical compound C12=CC=CC(Cl)=C2C(COC)(COC)C2=C1C=CC=C2Cl SCTKUNIIBPPKNV-UHFFFAOYSA-N 0.000 description 1
- DCYAOZBIBQDJCQ-UHFFFAOYSA-N 1-(1,3-dimethoxypropyl)-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene Chemical compound C1CCCC2C(C(OC)CCOC)CCCC21 DCYAOZBIBQDJCQ-UHFFFAOYSA-N 0.000 description 1
- JPYFOVDNCBIHAV-UHFFFAOYSA-N 1-(1,3-dimethoxypropyl)-4-fluorobenzene Chemical compound COCCC(OC)C1=CC=C(F)C=C1 JPYFOVDNCBIHAV-UHFFFAOYSA-N 0.000 description 1
- HPFWUWXYBFOJAD-UHFFFAOYSA-N 1-chloro-4-(1,3-dimethoxypropan-2-yl)benzene Chemical compound COCC(COC)C1=CC=C(Cl)C=C1 HPFWUWXYBFOJAD-UHFFFAOYSA-N 0.000 description 1
- PUBYKMSPAJMOGX-UHFFFAOYSA-N 1-chloro-4-[2-(4-chlorophenyl)-1,3-dimethoxypropan-2-yl]benzene Chemical compound C=1C=C(Cl)C=CC=1C(COC)(COC)C1=CC=C(Cl)C=C1 PUBYKMSPAJMOGX-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- ROSQVPGTZCDBOC-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,4-dimethylpentane Chemical compound COCC(C)(COC)CC(C)C ROSQVPGTZCDBOC-UHFFFAOYSA-N 0.000 description 1
- XAGXJWYEHBCLPN-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2-methylbutane Chemical compound COCC(C)(CC)COC XAGXJWYEHBCLPN-UHFFFAOYSA-N 0.000 description 1
- WZGYJLJMTYSGCS-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-3,3-dimethylbutane Chemical compound COCC(C(C)(C)C)COC WZGYJLJMTYSGCS-UHFFFAOYSA-N 0.000 description 1
- NGMVWDKVVMVTTM-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-3-methylbutane Chemical compound COCC(C(C)C)COC NGMVWDKVVMVTTM-UHFFFAOYSA-N 0.000 description 1
- FDLMLTYTOFIPCK-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-3-methylpentane Chemical compound CCC(C)C(COC)COC FDLMLTYTOFIPCK-UHFFFAOYSA-N 0.000 description 1
- PPHMKLXXVBJEHR-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)hexane Chemical compound CCCCC(COC)COC PPHMKLXXVBJEHR-UHFFFAOYSA-N 0.000 description 1
- POXXQVSKWJPZNO-UHFFFAOYSA-N 1-o-ethyl 2-o-(2-methylpropyl) benzene-1,2-dicarboxylate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC(C)C POXXQVSKWJPZNO-UHFFFAOYSA-N 0.000 description 1
- OONQZFJQVHEJFR-UHFFFAOYSA-N 2,3,6,7-tetrafluoro-1,1-bis(methoxymethyl)indene Chemical compound C1=C(F)C(F)=C2C(COC)(COC)C(F)=C(F)C2=C1 OONQZFJQVHEJFR-UHFFFAOYSA-N 0.000 description 1
- LDAYPNRUDRHPCA-UHFFFAOYSA-N 2,7-dicyclopentyl-9,9-bis(methoxymethyl)fluorene Chemical compound C1=C2C(COC)(COC)C3=CC(C4CCCC4)=CC=C3C2=CC=C1C1CCCC1 LDAYPNRUDRHPCA-UHFFFAOYSA-N 0.000 description 1
- YIBYCVPCWUSPQY-UHFFFAOYSA-N 2-(1,3-dimethoxypropyl)-1,1-dimethylcyclohexane Chemical compound COCCC(OC)C1CCCCC1(C)C YIBYCVPCWUSPQY-UHFFFAOYSA-N 0.000 description 1
- DUAYDERMVQWIJD-UHFFFAOYSA-N 2-n,2-n,6-trimethyl-1,3,5-triazine-2,4-diamine Chemical compound CN(C)C1=NC(C)=NC(N)=N1 DUAYDERMVQWIJD-UHFFFAOYSA-N 0.000 description 1
- JEABIFHLYSDNRJ-UHFFFAOYSA-N 2-o-butyl 1-o-ethyl benzene-1,2-dicarboxylate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC JEABIFHLYSDNRJ-UHFFFAOYSA-N 0.000 description 1
- LZZZFFYXZLMKDR-UHFFFAOYSA-N 3,3-bis(ethoxymethyl)pentane Chemical compound CCOCC(CC)(CC)COCC LZZZFFYXZLMKDR-UHFFFAOYSA-N 0.000 description 1
- SBWACGDKPKXCRS-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,2,4,4-tetramethylpentane Chemical compound COCC(C(C)(C)C)(C(C)(C)C)COC SBWACGDKPKXCRS-UHFFFAOYSA-N 0.000 description 1
- RGHIYOCUMCUWAQ-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,5-dimethylhexane Chemical compound COCC(COC)(CC(C)C)C(C)C RGHIYOCUMCUWAQ-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- SKWKIEFIPVHTHJ-UHFFFAOYSA-N 3,3-bis(methoxymethyl)pentane Chemical compound COCC(CC)(CC)COC SKWKIEFIPVHTHJ-UHFFFAOYSA-N 0.000 description 1
- PYHOSWIHPZRHDU-UHFFFAOYSA-N 4,4-bis(butoxymethyl)-2,6-dimethylheptane Chemical compound CCCCOCC(CC(C)C)(CC(C)C)COCCCC PYHOSWIHPZRHDU-UHFFFAOYSA-N 0.000 description 1
- VVEYETJZOMJKNK-UHFFFAOYSA-N 4,4-bis(ethoxymethyl)-2,6-dimethylheptane Chemical compound CCOCC(CC(C)C)(CC(C)C)COCC VVEYETJZOMJKNK-UHFFFAOYSA-N 0.000 description 1
- DDONJMJAIMKSOS-UHFFFAOYSA-N 4,4-bis(ethoxymethyl)heptane Chemical compound CCOCC(CCC)(CCC)COCC DDONJMJAIMKSOS-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- LOGBQWSMOBPZEA-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-3,5-dimethylheptane Chemical compound CCC(C)C(COC)(COC)C(C)CC LOGBQWSMOBPZEA-UHFFFAOYSA-N 0.000 description 1
- WOLQDDKBJWHVQK-UHFFFAOYSA-N 4,4-bis(methoxymethyl)heptane Chemical compound CCCC(CCC)(COC)COC WOLQDDKBJWHVQK-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- LHBLDRAQSNFIEY-UHFFFAOYSA-N 4-cyclohexyl-1,1-bis(methoxymethyl)indene Chemical compound COCC1(COC)C=CC2=C1C=CC=C2C1CCCCC1 LHBLDRAQSNFIEY-UHFFFAOYSA-N 0.000 description 1
- CWVKCYDPJZCDMC-UHFFFAOYSA-N 4-ethyl-1-methoxy-2-(methoxymethyl)-2-methyloctane Chemical compound CCCCC(CC)CC(C)(COC)COC CWVKCYDPJZCDMC-UHFFFAOYSA-N 0.000 description 1
- VIJVFTUOJNTXCA-UHFFFAOYSA-N 4-ethyl-1-methoxy-2-(methoxymethyl)octane Chemical compound CCCCC(CC)CC(COC)COC VIJVFTUOJNTXCA-UHFFFAOYSA-N 0.000 description 1
- XWJMQJGSSGDJSY-UHFFFAOYSA-N 4-methyloct-1-ene Chemical compound CCCCC(C)CC=C XWJMQJGSSGDJSY-UHFFFAOYSA-N 0.000 description 1
- UURZCHPNAPLYER-UHFFFAOYSA-N 4-tert-butyl-9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C(C(C)(C)C)C2=C1C(COC)(COC)C1=CC=CC=C12 UURZCHPNAPLYER-UHFFFAOYSA-N 0.000 description 1
- NDTLNHGFAUSCAE-UHFFFAOYSA-N 5,5-bis(ethoxymethyl)nonane Chemical compound CCCCC(CCCC)(COCC)COCC NDTLNHGFAUSCAE-UHFFFAOYSA-N 0.000 description 1
- NUPABKVXQKZAHY-UHFFFAOYSA-N 5,5-bis(methoxymethyl)-1,2,3,4-tetramethylcyclopenta-1,3-diene Chemical compound COCC1(COC)C(C)=C(C)C(C)=C1C NUPABKVXQKZAHY-UHFFFAOYSA-N 0.000 description 1
- DNQBFNSYXQGWEA-UHFFFAOYSA-N 5,5-bis(methoxymethyl)cyclopenta-1,3-diene Chemical compound COCC1(COC)C=CC=C1 DNQBFNSYXQGWEA-UHFFFAOYSA-N 0.000 description 1
- UAVYNJZKEVSSFO-UHFFFAOYSA-N 5,5-bis(methoxymethyl)nonane Chemical compound CCCCC(COC)(COC)CCCC UAVYNJZKEVSSFO-UHFFFAOYSA-N 0.000 description 1
- IRVLICZNRLVVKJ-UHFFFAOYSA-N 5,9-diethyl-7,7-bis(methoxymethyl)tridecane Chemical compound CCCCC(CC)CC(COC)(COC)CC(CC)CCCC IRVLICZNRLVVKJ-UHFFFAOYSA-N 0.000 description 1
- TYYSEGNSDSKJDW-UHFFFAOYSA-N 7-cyclohexyl-1,1-bis(methoxymethyl)indene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1CCCCC1 TYYSEGNSDSKJDW-UHFFFAOYSA-N 0.000 description 1
- OEGBIJMAWUHNFV-UHFFFAOYSA-N 7-cyclopentyl-1,1-bis(methoxymethyl)indene Chemical compound C=12C(COC)(COC)C=CC2=CC=CC=1C1CCCC1 OEGBIJMAWUHNFV-UHFFFAOYSA-N 0.000 description 1
- OQYGKBOREGNKLC-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)-2-methylindene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C(C)=CC2=C1 OQYGKBOREGNKLC-UHFFFAOYSA-N 0.000 description 1
- XBHBMIOEDQWGPY-UHFFFAOYSA-N 7-tert-butyl-1,1-bis(methoxymethyl)indene Chemical compound C1=CC(C(C)(C)C)=C2C(COC)(COC)C=CC2=C1 XBHBMIOEDQWGPY-UHFFFAOYSA-N 0.000 description 1
- UMMOCVFWWKDPNL-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-1,2,3,4,5,6,7,8-octahydrofluorene Chemical compound C1CCCC2=C1C(COC)(COC)C1=C2CCCC1 UMMOCVFWWKDPNL-UHFFFAOYSA-N 0.000 description 1
- MGQOPBZMDMTUQK-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-1,2,3,4-tetrahydrofluorene Chemical compound C12=CC=CC=C2C(COC)(COC)C2=C1CCCC2 MGQOPBZMDMTUQK-UHFFFAOYSA-N 0.000 description 1
- BJBJQWLYAGUTIO-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,3,6,7-tetramethylfluorene Chemical compound CC1=C(C)C=C2C(COC)(COC)C3=CC(C)=C(C)C=C3C2=C1 BJBJQWLYAGUTIO-UHFFFAOYSA-N 0.000 description 1
- PQRUIZPAUUOIPY-UHFFFAOYSA-N 9,9-bis(methoxymethyl)-2,7-di(propan-2-yl)fluorene Chemical compound C1=C(C(C)C)C=C2C(COC)(COC)C3=CC(C(C)C)=CC=C3C2=C1 PQRUIZPAUUOIPY-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- MGFZRAOWZZERMS-UHFFFAOYSA-N C(C1=CC=CC=C1)C(COC)(COC)CC1=CC=CC=C1.C1(=CC=CC=C1)C(COC)(COC)C1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)C(COC)(COC)CC1=CC=CC=C1.C1(=CC=CC=C1)C(COC)(COC)C1=CC=CC=C1 MGFZRAOWZZERMS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- ZVGIBQMBZHWERX-UHFFFAOYSA-N [2-(cyclohexylmethyl)-3-methoxy-2-(methoxymethyl)propyl]cyclohexane Chemical compound C1CCCCC1CC(COC)(COC)CC1CCCCC1 ZVGIBQMBZHWERX-UHFFFAOYSA-N 0.000 description 1
- RORSEGNGPOMSSV-UHFFFAOYSA-N [3,3-bis(methoxymethyl)-5-phenylpentyl]benzene Chemical compound C=1C=CC=CC=1CCC(COC)(COC)CCC1=CC=CC=C1 RORSEGNGPOMSSV-UHFFFAOYSA-N 0.000 description 1
- WVEZHRZEAFZJOI-UHFFFAOYSA-N [3-methoxy-2-(methoxymethyl)-1-phenylpropyl]benzene Chemical compound C=1C=CC=CC=1C(C(COC)COC)C1=CC=CC=C1 WVEZHRZEAFZJOI-UHFFFAOYSA-N 0.000 description 1
- UKEUPAFEWAEVGQ-UHFFFAOYSA-N [3-methoxy-2-(methoxymethyl)-2-methylpropyl]benzene Chemical compound COCC(C)(COC)CC1=CC=CC=C1 UKEUPAFEWAEVGQ-UHFFFAOYSA-N 0.000 description 1
- ZOUNQYODSPCWEH-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)-2-methylbutan-2-yl]benzene Chemical compound COCC(COC)C(C)(C)C1=CC=CC=C1 ZOUNQYODSPCWEH-UHFFFAOYSA-N 0.000 description 1
- JXQCBJLNEGKSCN-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)butyl]benzene Chemical compound COCC(COC)CCC1=CC=CC=C1 JXQCBJLNEGKSCN-UHFFFAOYSA-N 0.000 description 1
- AWLBWJXVYGYRNY-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)butyl]cyclohexane Chemical compound COCC(COC)CCC1CCCCC1 AWLBWJXVYGYRNY-UHFFFAOYSA-N 0.000 description 1
- IFKPQKNFYPMKNL-UHFFFAOYSA-N [5-cyclohexyl-3,3-bis(methoxymethyl)pentyl]cyclohexane Chemical compound C1CCCCC1CCC(COC)(COC)CCC1CCCCC1 IFKPQKNFYPMKNL-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- KYZHGEFMXZOSJN-UHFFFAOYSA-N benzoic acid isobutyl ester Natural products CC(C)COC(=O)C1=CC=CC=C1 KYZHGEFMXZOSJN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- GPTXWRGISTZRIO-UHFFFAOYSA-N chlorquinaldol Chemical compound ClC1=CC(Cl)=C(O)C2=NC(C)=CC=C21 GPTXWRGISTZRIO-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- DIJRHOZMLZRNLM-UHFFFAOYSA-N dimethoxy-methyl-(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](C)(OC)CCC(F)(F)F DIJRHOZMLZRNLM-UHFFFAOYSA-N 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229940052296 esters of benzoic acid for local anesthesia Drugs 0.000 description 1
- NWPWRAWAUYIELB-UHFFFAOYSA-N ethyl 4-methylbenzoate Chemical compound CCOC(=O)C1=CC=C(C)C=C1 NWPWRAWAUYIELB-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000012886 linear function Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- TXLMBPWQZULYHP-UHFFFAOYSA-N tert-butyl(dimethoxy)silane Chemical compound CO[SiH](OC)C(C)(C)C TXLMBPWQZULYHP-UHFFFAOYSA-N 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07150461 | 2007-12-28 | ||
| US1053508P | 2008-01-09 | 2008-01-09 | |
| PCT/EP2008/068132 WO2009083522A1 (en) | 2007-12-28 | 2008-12-22 | Catalyst components for the polymerization of olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011508037A true JP2011508037A (ja) | 2011-03-10 |
| JP2011508037A5 JP2011508037A5 (OSRAM) | 2012-01-19 |
Family
ID=40485865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010540113A Pending JP2011508037A (ja) | 2007-12-28 | 2008-12-22 | オレフィン類の重合用触媒成分 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9453088B2 (OSRAM) |
| EP (1) | EP2225287B1 (OSRAM) |
| JP (1) | JP2011508037A (OSRAM) |
| CN (1) | CN101910208B (OSRAM) |
| AT (1) | ATE522552T1 (OSRAM) |
| BR (1) | BRPI0821817A2 (OSRAM) |
| WO (1) | WO2009083522A1 (OSRAM) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013014725A (ja) * | 2011-07-06 | 2013-01-24 | Sunallomer Ltd | α−オレフィン重合方法 |
| JP2018522128A (ja) * | 2015-08-04 | 2018-08-09 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用予備重合触媒成分 |
| JP2022531958A (ja) * | 2019-05-10 | 2022-07-12 | ダブリュー・アール・グレース・アンド・カンパニー－コーン | オレフィン重合用活性化触媒成分 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2264075B1 (en) * | 2008-04-08 | 2016-05-25 | Mitsui Chemicals, Inc. | Solid titanium catalyst component for ethylene polymerization, ethylene polymerization catalyst and ethylene polymerization method |
| EP2452975A1 (en) * | 2010-11-12 | 2012-05-16 | Borealis AG | Soft heterophasic propylene copolymers |
| BR112017017446B1 (pt) * | 2015-03-10 | 2022-04-12 | Basell Poliolefine Italia S.R.L. | Componente catalisador sólido, catalisador e processo para a (co)polimerização de olefinas |
| EP3416990B1 (en) * | 2016-02-15 | 2020-06-17 | Basell Polyolefine GmbH | Preactivated catalyst component for the polymerization of olefins |
| CN111072815A (zh) * | 2018-10-19 | 2020-04-28 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分和催化剂及其应用与烯烃聚合方法 |
| WO2021052733A1 (en) | 2019-09-17 | 2021-03-25 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| CN114539448B (zh) * | 2022-01-18 | 2024-02-27 | 北京吉海川科技发展有限公司 | 一种用于烯烃聚合的催化剂及其制备方法和应用 |
| EP4596588A1 (en) | 2022-10-26 | 2025-08-06 | China Petroleum & Chemical Corporation | Solid catalyst component for olefin polymerization, and preparation method therefor and use thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06503123A (ja) * | 1991-06-03 | 1994-04-07 | モンテル テクノロジー カンパニー ビーブイ | オレフィンの気相重合方法 |
| JPH06100623A (ja) * | 1992-06-18 | 1994-04-12 | Spherilene Srl | オレフィン類の気相重合法と装置 |
| JPH09104709A (ja) * | 1995-10-11 | 1997-04-22 | Mitsui Petrochem Ind Ltd | 固体状チタン触媒成分の製造方法、固体状チタン触媒成分およびこれを含むオレフィン重合用触媒、オレフィンの重合方法 |
| JP2001233878A (ja) * | 1999-12-15 | 2001-08-28 | Idemitsu Petrochem Co Ltd | マグネシウム化合物、オレフィン重合触媒及びオレフィン重合体の製造方法 |
| JP2001342211A (ja) * | 2000-03-30 | 2001-12-11 | Sumitomo Chem Co Ltd | オレフィン気相重合用予備重合触媒及びその製造方法 |
| JP2002509578A (ja) * | 1998-05-06 | 2002-03-26 | モンテル テクノロジー カンパニー ビーブイ | オレフィン類重合用触媒成分 |
| JP2002522571A (ja) * | 1998-08-03 | 2002-07-23 | モンテル テクノロジー カンパニー ビーブイ | オレフィンを重合するための予備重合触媒成分 |
| JP2005146197A (ja) * | 2003-11-19 | 2005-06-09 | Mitsui Chemicals Inc | １−ブテンの重合方法 |
| JP2005187550A (ja) * | 2003-12-25 | 2005-07-14 | Mitsui Chemicals Inc | オレフィン重合用固体状チタン触媒成分の製造方法、オレフィン重合用触媒、およびオレフィンの重合方法 |
| JP2006016607A (ja) * | 2004-05-31 | 2006-01-19 | Sumitomo Chemical Co Ltd | α−オレフィン重合用固体触媒成分、α−オレフィン重合用触媒、α−オレフィン重合体の製造方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL162661B (nl) * | 1968-11-21 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
| YU35844B (en) * | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| FR2669915B1 (fr) * | 1990-11-29 | 1993-01-29 | Atochem | Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique. |
| US5589539A (en) | 1994-11-23 | 1996-12-31 | Union Carbide Chemicals & Plastics Technology Corporation | Process for preparing an in situ polyethylene blend |
| KR100845167B1 (ko) | 2000-12-22 | 2008-07-09 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 마그네슘 이할라이드를 함유하는 구형 지지체의 제조방법 |
| US7942572B2 (en) | 2003-10-16 | 2011-05-17 | Basell Poliolefine Italia S.R.L. | Process for the continuous production of emulsions |
-
2008
- 2008-12-22 BR BRPI0821817-0A patent/BRPI0821817A2/pt not_active Application Discontinuation
- 2008-12-22 WO PCT/EP2008/068132 patent/WO2009083522A1/en not_active Ceased
- 2008-12-22 AT AT08867168T patent/ATE522552T1/de not_active IP Right Cessation
- 2008-12-22 US US12/735,278 patent/US9453088B2/en not_active Expired - Fee Related
- 2008-12-22 CN CN2008801233054A patent/CN101910208B/zh not_active Expired - Fee Related
- 2008-12-22 JP JP2010540113A patent/JP2011508037A/ja active Pending
- 2008-12-22 EP EP08867168A patent/EP2225287B1/en not_active Not-in-force
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06503123A (ja) * | 1991-06-03 | 1994-04-07 | モンテル テクノロジー カンパニー ビーブイ | オレフィンの気相重合方法 |
| JPH06100623A (ja) * | 1992-06-18 | 1994-04-12 | Spherilene Srl | オレフィン類の気相重合法と装置 |
| JPH09104709A (ja) * | 1995-10-11 | 1997-04-22 | Mitsui Petrochem Ind Ltd | 固体状チタン触媒成分の製造方法、固体状チタン触媒成分およびこれを含むオレフィン重合用触媒、オレフィンの重合方法 |
| JP2002509578A (ja) * | 1998-05-06 | 2002-03-26 | モンテル テクノロジー カンパニー ビーブイ | オレフィン類重合用触媒成分 |
| JP2002522571A (ja) * | 1998-08-03 | 2002-07-23 | モンテル テクノロジー カンパニー ビーブイ | オレフィンを重合するための予備重合触媒成分 |
| JP2001233878A (ja) * | 1999-12-15 | 2001-08-28 | Idemitsu Petrochem Co Ltd | マグネシウム化合物、オレフィン重合触媒及びオレフィン重合体の製造方法 |
| JP2001342211A (ja) * | 2000-03-30 | 2001-12-11 | Sumitomo Chem Co Ltd | オレフィン気相重合用予備重合触媒及びその製造方法 |
| JP2005146197A (ja) * | 2003-11-19 | 2005-06-09 | Mitsui Chemicals Inc | １−ブテンの重合方法 |
| JP2005187550A (ja) * | 2003-12-25 | 2005-07-14 | Mitsui Chemicals Inc | オレフィン重合用固体状チタン触媒成分の製造方法、オレフィン重合用触媒、およびオレフィンの重合方法 |
| JP2006016607A (ja) * | 2004-05-31 | 2006-01-19 | Sumitomo Chemical Co Ltd | α−オレフィン重合用固体触媒成分、α−オレフィン重合用触媒、α−オレフィン重合体の製造方法 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013014725A (ja) * | 2011-07-06 | 2013-01-24 | Sunallomer Ltd | α−オレフィン重合方法 |
| JP2018522128A (ja) * | 2015-08-04 | 2018-08-09 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用予備重合触媒成分 |
| JP2018526494A (ja) * | 2015-08-04 | 2018-09-13 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | プロピレンの気相重合方法 |
| KR20190116578A (ko) * | 2015-08-04 | 2019-10-14 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌의 기상 중합 방법 |
| US10730974B2 (en) | 2015-08-04 | 2020-08-04 | Basell Poliolefine Italia S.R.L. | Gas-phase process for the polymerization of propylene |
| KR102378917B1 (ko) * | 2015-08-04 | 2022-03-24 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌의 기상 중합 방법 |
| JP7102075B2 (ja) | 2015-08-04 | 2022-07-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | プロピレンの気相重合方法 |
| JP2022531958A (ja) * | 2019-05-10 | 2022-07-12 | ダブリュー・アール・グレース・アンド・カンパニー－コーン | オレフィン重合用活性化触媒成分 |
| JP7704688B2 (ja) | 2019-05-10 | 2025-07-08 | ダブリュー・アール・グレース・アンド・カンパニー－コーン | オレフィン重合用活性化触媒成分 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101910208B (zh) | 2012-09-19 |
| EP2225287A1 (en) | 2010-09-08 |
| WO2009083522A1 (en) | 2009-07-09 |
| ATE522552T1 (de) | 2011-09-15 |
| US20100292419A1 (en) | 2010-11-18 |
| US9453088B2 (en) | 2016-09-27 |
| EP2225287B1 (en) | 2011-08-31 |
| CN101910208A (zh) | 2010-12-08 |
| BRPI0821817A2 (pt) | 2015-06-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2225287B1 (en) | Catalyst components for the polymerization of olefins | |
| EP2585499B1 (en) | Catalyst system for the polymerization of olefins | |
| US8062989B2 (en) | Magnesium chloroakolate-based catalyst precursors | |
| EP1458767B1 (en) | Process for the preparation of catalyst components for the polymeriztion of olefins | |
| US20140046010A1 (en) | Catalyst components for the polymerization of olefins | |
| JP6841814B2 (ja) | オレフィン重合用予備重合触媒成分 | |
| CN102164969B (zh) | 烯烃聚合的催化剂组分 | |
| US20100261859A1 (en) | Catalyst components for the polymerization of olefins | |
| AU2003293783A1 (en) | Magnesium dichloride-based adducts and catalyst components obtained therefrom | |
| ES2372351T3 (es) | Componentes de catalizadores para la polimerización de olefinas. | |
| US20240209125A1 (en) | Prepolymerized catalyst components for the polymerization of olefins | |
| KR20250073335A (ko) | 올레핀 중합용 촉매 성분 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111128 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20111128 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130821 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130823 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140709 |