JP2010532707A5 - - Google Patents
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- Publication number
- JP2010532707A5 JP2010532707A5 JP2010513759A JP2010513759A JP2010532707A5 JP 2010532707 A5 JP2010532707 A5 JP 2010532707A5 JP 2010513759 A JP2010513759 A JP 2010513759A JP 2010513759 A JP2010513759 A JP 2010513759A JP 2010532707 A5 JP2010532707 A5 JP 2010532707A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- passage
- heating medium
- reaction
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims description 127
- 238000010438 heat treatment Methods 0.000 claims description 115
- 238000006243 chemical reaction Methods 0.000 claims description 106
- 238000000034 method Methods 0.000 claims description 41
- 230000020169 heat generation Effects 0.000 claims description 18
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 12
- 238000002485 combustion reaction Methods 0.000 claims description 8
- 230000005855 radiation Effects 0.000 claims description 7
- 238000004891 communication Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000002609 medium Substances 0.000 description 68
- 239000000047 product Substances 0.000 description 37
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 18
- 238000009826 distribution Methods 0.000 description 13
- 239000001294 propane Substances 0.000 description 9
- 238000007086 side reaction Methods 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 239000003546 flue gas Substances 0.000 description 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000000571 coke Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000012913 medium supplement Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- -1 ethylene, propylene Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07013192 | 2007-07-05 | ||
| EP07013192.5 | 2007-07-05 | ||
| EP07022847.3 | 2007-11-26 | ||
| EP07022847 | 2007-11-26 | ||
| PCT/EP2008/005265 WO2009003647A1 (en) | 2007-07-05 | 2008-06-25 | Process for performing an endothermic reaction |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014198977A Division JP2015061726A (ja) | 2007-07-05 | 2014-09-29 | 吸熱反応を行うプロセス |
| JP2016018705A Division JP2016155120A (ja) | 2007-07-05 | 2016-02-03 | 吸熱反応を行うプロセス |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010532707A JP2010532707A (ja) | 2010-10-14 |
| JP2010532707A5 true JP2010532707A5 (cg-RX-API-DMAC7.html) | 2016-03-24 |
| JP6009732B2 JP6009732B2 (ja) | 2016-10-19 |
Family
ID=39717824
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010513759A Expired - Fee Related JP6009732B2 (ja) | 2007-07-05 | 2008-06-25 | 吸熱反応を行うプロセス |
| JP2014198977A Pending JP2015061726A (ja) | 2007-07-05 | 2014-09-29 | 吸熱反応を行うプロセス |
| JP2016018705A Abandoned JP2016155120A (ja) | 2007-07-05 | 2016-02-03 | 吸熱反応を行うプロセス |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014198977A Pending JP2015061726A (ja) | 2007-07-05 | 2014-09-29 | 吸熱反応を行うプロセス |
| JP2016018705A Abandoned JP2016155120A (ja) | 2007-07-05 | 2016-02-03 | 吸熱反応を行うプロセス |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US8916737B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2173469B1 (cg-RX-API-DMAC7.html) |
| JP (3) | JP6009732B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN101687162B (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0814196A2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2691566C (cg-RX-API-DMAC7.html) |
| EA (1) | EA017645B1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2496171T3 (cg-RX-API-DMAC7.html) |
| IL (1) | IL202831A (cg-RX-API-DMAC7.html) |
| MX (1) | MX2009014078A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2009003647A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8608696B1 (en) | 2009-02-24 | 2013-12-17 | North Carolina State University | Rapid fluid cooling devices and methods for cooling fluids |
| DE102009012663B3 (de) * | 2009-03-13 | 2010-09-16 | Uhde Gmbh | Verfahren und Vorrichtung zur gleichmäßigen Dampferzeugung aus der Abwärme einer Alkandehydrierung |
| EP2671634B1 (en) * | 2012-06-08 | 2017-08-09 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method to homogenize the tube temperatures between tubes during processes involving heating of gas flowing in the tubes |
| US10246386B2 (en) * | 2014-09-12 | 2019-04-02 | Sabic Global Technologies B.V. | Embedded alkane dehydrogenation systems and processes |
| CA2987457C (en) | 2015-06-08 | 2020-04-07 | Ihi Corporation | Multilayer reactor utilizing heat exchange |
| WO2017072057A1 (en) * | 2015-10-28 | 2017-05-04 | Haldor Topsøe A/S | Dehydrogenation of alkanes |
| CN108778988B (zh) * | 2016-02-04 | 2022-08-19 | 法国德西尼布 | 降低重整器中温度扩散的方法 |
| WO2017212341A1 (en) | 2016-06-09 | 2017-12-14 | Sabic Global Technologies B.V. | Systems for heating multi-tubular reactors |
| JP2018084308A (ja) | 2016-11-25 | 2018-05-31 | 株式会社Ihi | 圧力容器 |
| US10544371B2 (en) * | 2018-05-11 | 2020-01-28 | Intramicron, Inc. | Channel reactors |
| CN114728251B (zh) * | 2019-11-20 | 2025-03-21 | 鲁姆斯科技有限责任公司 | 化学反应器中的热存储 |
| JP7467192B2 (ja) * | 2020-03-25 | 2024-04-15 | 三菱重工業株式会社 | ガス状生成物を得るための装置およびガス状生成物を得るための方法 |
| FR3114590B1 (fr) * | 2020-09-25 | 2022-09-09 | Ifp Energies Now | Procédé de deshydrogenation de l’éthanol en reacteur multitubulaire |
| US20240101418A1 (en) * | 2022-09-23 | 2024-03-28 | Tushar P. Vispute | Method for carbon formation free operation of reformers |
| CN119771278A (zh) * | 2023-10-07 | 2025-04-08 | 北京化工大学 | 一种管壳式换热反应装置及反应方法 |
| KR20250134948A (ko) * | 2024-03-05 | 2025-09-12 | 주식회사 엘지화학 | 전기 가열 반응기 |
| CN119951422B (zh) * | 2025-04-09 | 2025-06-20 | 苏州大学 | 一种多级流化循环反应系统的加热控制方法 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2945077A (en) * | 1955-12-01 | 1960-07-12 | Phillips Petroleum Co | Process and apparatus for pressure and temperature control system |
| US3453087A (en) * | 1964-06-25 | 1969-07-01 | Girdler Corp | Modular reformer furnace |
| GB1367453A (en) | 1970-09-25 | 1974-09-18 | Topsoe H F A | Furnace design |
| US3958951A (en) * | 1974-04-09 | 1976-05-25 | Stone & Webster Engineering Corporation | Convective power reformer equipment and system |
| NL187622C (nl) | 1975-04-14 | 1991-12-02 | Stone & Webster Eng Corp | Reformeeroven met convectieverhitting van de procesbuizen. |
| JPS5863783A (ja) | 1981-10-13 | 1983-04-15 | Babcock Hitachi Kk | 改質装置 |
| JPS5930705A (ja) * | 1982-08-12 | 1984-02-18 | Mitsubishi Heavy Ind Ltd | 燃料改質装置 |
| NL8401064A (nl) * | 1984-04-04 | 1985-11-01 | Dow Chemical Nederland | Werkwijze voor de dehydrogenering van een koolwaterstof, een apparaat voor het uitvoeren van chemische reacties en een methode voor het daarin uitvoeren van die reacties. |
| US4769506A (en) | 1985-03-21 | 1988-09-06 | The Dow Chemical Company | Method for dehydrogenating a hydrocarbon, an apparatus and method for conducting chemical reactions therein |
| JPS6339629A (ja) | 1986-08-01 | 1988-02-20 | Yamaha Motor Co Ltd | 燃料電池用改質装置 |
| GB2201903B (en) * | 1987-03-03 | 1990-11-28 | Shell Int Research | Apparatus and process suitable for producing hydrogen |
| FR2634396B1 (fr) | 1988-07-22 | 1990-09-14 | Inst Francais Du Petrole | Procede et appareillage de reformage basse pression des essences avec chauffage par des gaz de fumees |
| JPH07483B2 (ja) * | 1988-10-27 | 1995-01-11 | 株式会社富士電機総合研究所 | 熱媒加熱式改質装置 |
| JP3096302B2 (ja) | 1989-12-11 | 2000-10-10 | ゲブリユーダー ズルツアー アクチエンゲゼルシヤフト | 不均一反応型の反応器及び反応器用触媒 |
| FR2657273B1 (fr) | 1990-01-19 | 1992-05-15 | Inst Francais Du Petrole | Enceinte reactionnelle comprenant un reacteur calandre et des moyens de stratification du courant d'un fluide caloporteur. |
| JPH04190843A (ja) | 1990-11-22 | 1992-07-09 | Toshiba Corp | ガス反応装置 |
| ES2078688T3 (es) * | 1991-05-06 | 1995-12-16 | Inst Francais Du Petrole | Procedimiento y dispositivo de deshidrogenacion de hidrocarburos alifaticos en hidrocarburos olefinicos. |
| US5247907A (en) | 1992-05-05 | 1993-09-28 | The M. W. Kellogg Company | Process furnace with a split flue convection section |
| JP3202441B2 (ja) * | 1993-10-08 | 2001-08-27 | 東京瓦斯株式会社 | 水素製造装置 |
| JP3283958B2 (ja) | 1993-04-13 | 2002-05-20 | 株式会社日立製作所 | 反応器およびその製造方法 |
| US5935531A (en) | 1993-10-29 | 1999-08-10 | Mannesmann Aktiengesellschaft | Catalytic reactor for endothermic reactions |
| JP4041567B2 (ja) | 1997-12-25 | 2008-01-30 | 千代田化工建設株式会社 | 触媒改質型反応炉 |
| GB2359764A (en) * | 2000-03-01 | 2001-09-05 | Geoffrey Gerald Weedon | An endothermic tube reactor |
| DE10042746A1 (de) | 2000-08-31 | 2002-03-28 | Degussa | Verfahren und Vorrichtung zum Durchführen von Reaktionen in einem Reaktor mit spaltförmigen Reaktionsräumen |
| US6781024B2 (en) * | 2000-11-22 | 2004-08-24 | Fina Technology, Inc. | Dehydrogenation process |
| DE10229661A1 (de) | 2001-10-09 | 2003-04-10 | Linde Ag | Verfahren zur Dehydrierung von Alkanen |
| JP3993023B2 (ja) * | 2002-05-22 | 2007-10-17 | 東邦瓦斯株式会社 | 熱風循環装置 |
| JP4401644B2 (ja) | 2002-11-22 | 2010-01-20 | 三菱化学エンジニアリング株式会社 | プレート型触媒反応装置及び（メタ）アクリル酸等の製造方法 |
| JP2006097526A (ja) | 2004-09-29 | 2006-04-13 | Mitsubishi Heavy Ind Ltd | 車両積載型水素製造システムのための昇温装置 |
-
2008
- 2008-06-25 EP EP08759353.9A patent/EP2173469B1/en active Active
- 2008-06-25 CA CA2691566A patent/CA2691566C/en active Active
- 2008-06-25 ES ES08759353.9T patent/ES2496171T3/es active Active
- 2008-06-25 US US12/452,362 patent/US8916737B2/en active Active
- 2008-06-25 MX MX2009014078A patent/MX2009014078A/es active IP Right Grant
- 2008-06-25 WO PCT/EP2008/005265 patent/WO2009003647A1/en not_active Ceased
- 2008-06-25 EA EA201000156A patent/EA017645B1/ru active IP Right Revival
- 2008-06-25 BR BRPI0814196-7A2A patent/BRPI0814196A2/pt not_active IP Right Cessation
- 2008-06-25 CN CN2008800235175A patent/CN101687162B/zh not_active Expired - Fee Related
- 2008-06-25 JP JP2010513759A patent/JP6009732B2/ja not_active Expired - Fee Related
-
2009
- 2009-12-20 IL IL202831A patent/IL202831A/en active IP Right Grant
-
2014
- 2014-09-29 JP JP2014198977A patent/JP2015061726A/ja active Pending
- 2014-11-07 US US14/536,093 patent/US9492803B2/en not_active Expired - Fee Related
-
2016
- 2016-02-03 JP JP2016018705A patent/JP2016155120A/ja not_active Abandoned
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