ES2078688T3 - Procedimiento y dispositivo de deshidrogenacion de hidrocarburos alifaticos en hidrocarburos olefinicos. - Google Patents

Procedimiento y dispositivo de deshidrogenacion de hidrocarburos alifaticos en hidrocarburos olefinicos.

Info

Publication number
ES2078688T3
ES2078688T3 ES92401253T ES92401253T ES2078688T3 ES 2078688 T3 ES2078688 T3 ES 2078688T3 ES 92401253 T ES92401253 T ES 92401253T ES 92401253 T ES92401253 T ES 92401253T ES 2078688 T3 ES2078688 T3 ES 2078688T3
Authority
ES
Spain
Prior art keywords
tubes
hydrocarbons
enclosure
catalyst
sensitively
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92401253T
Other languages
English (en)
Inventor
Didier Duee
Larry Mank
Pierre Renard
Jean-Pierre Burzynski
Gerard Leger
Philippe Vacher
Ari Minkkinen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR919105673A external-priority patent/FR2676181B1/fr
Priority claimed from FR919105671A external-priority patent/FR2676222B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2078688T3 publication Critical patent/ES2078688T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/909—Heat considerations
    • Y10S585/911—Heat considerations introducing, maintaining, or removing heat by atypical procedure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/919—Apparatus considerations
    • Y10S585/921—Apparatus considerations using recited apparatus structure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/919—Apparatus considerations
    • Y10S585/921—Apparatus considerations using recited apparatus structure
    • Y10S585/924—Reactor shape or disposition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCESO Y UN DISPOSITIVO EN LECHO FIJO DE PRODUCCION DE HIDROCARBUROS OLEFINICOS A PARTIR DE UNA CARGA DE HIDROCARBUROS ALIFATICOS SATURADOS DE 2 A 20 ATOMOS DE CARBONO Y DE HIDROGENO EN UN RECINTO 1 QUE COMPRENDE UNA PLURALIDAD DE TUBOS 3 LLENOS DE UN CATALIZADOR, PARALELOS, DISPUESTOS EN HILERAS. SE EFECTUA UNA FASE LLAMADA DE REACCION Y UNA FASE DE REGENERACION DEL CATALIZADOR EN LOS TUBOS DEL RECINTO. EL CALENTAMIENTO DE LOS TUBOS SE REALIZA POR MEDIOS DE CALENTAMIENTO 6 RADIANTES APROPIADOS, DISPUESTOS EN CAPAS SENSIBLEMENTE PERPENDICULARES A LOS TUBOS. ESTAS CAPAS CALIENTAN UNA PRIMERA PARTE DE LOS TUBOS (DEL LADO DE LA ALIMENTACION) CON UN FLUJO TERMICO SUPERIOR AL FLUJO TERMICO MEDIO DEL RECINTO Y UNA SEGUNDA PARTE SUBSIGUIENTE CON UN FLUJO MEDIO A LO SUMO IGUAL AL FLUJO TERMICO MEDIO, DE TAL MANERA QUE LA ISOTERMICIDAD DEL CATALIZADOR SE MANTIENE SENSIBLEMENTE, GRACIAS A MEDIOS DE CONTROL ADECUADOS. APLICACION EN LA PRODUCCION DE ISOBUTENO.
ES92401253T 1991-05-06 1992-05-04 Procedimiento y dispositivo de deshidrogenacion de hidrocarburos alifaticos en hidrocarburos olefinicos. Expired - Lifetime ES2078688T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR919105673A FR2676181B1 (fr) 1991-05-06 1991-05-06 Dispositif de conversion d'hydrocarbures dans une enceinte chauffee par des moyens de chauffage radiants a flux thermique variable et son utilisation.
FR919105671A FR2676222B1 (fr) 1991-05-06 1991-05-06 Procede de deshydrogenation d'hydrocarbures aliphatiques en hydrocarbures olefiniques.

Publications (1)

Publication Number Publication Date
ES2078688T3 true ES2078688T3 (es) 1995-12-16

Family

ID=26228685

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92401253T Expired - Lifetime ES2078688T3 (es) 1991-05-06 1992-05-04 Procedimiento y dispositivo de deshidrogenacion de hidrocarburos alifaticos en hidrocarburos olefinicos.

Country Status (5)

Country Link
US (1) US6191332B1 (es)
EP (1) EP0512911B1 (es)
JP (1) JP3118671B2 (es)
DE (1) DE69203938T2 (es)
ES (1) ES2078688T3 (es)

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TW527218B (en) * 1999-03-16 2003-04-11 Basf Ag Multitube reactor, especially for catalytic gas-phase reactions
DE102004055890A1 (de) * 2004-11-19 2006-05-24 Basf Ag Verfahren und Vorrichtung zur Vorwärmung von Einsatzstoffströmen in Anlagen zur Alkandehydrierung
JP2006282458A (ja) * 2005-03-31 2006-10-19 Toyota Motor Corp 水素生成装置及び燃料電池システム
JP4549216B2 (ja) * 2005-03-31 2010-09-22 株式会社豊田中央研究所 水素燃料供給システム
JP4559900B2 (ja) * 2005-03-31 2010-10-13 株式会社豊田中央研究所 水素燃料供給システム
JP2006282457A (ja) * 2005-03-31 2006-10-19 Toyota Motor Corp 水素生成装置及び燃料電池システム
JP4564392B2 (ja) * 2005-04-01 2010-10-20 株式会社豊田中央研究所 水素燃料供給システム
JP4505367B2 (ja) * 2005-04-01 2010-07-21 株式会社豊田中央研究所 水素燃料供給システム
DE102006017908A1 (de) * 2006-04-18 2007-10-25 Basf Ag Verfahren und Vorrichtung zur kontrollierten Regeneration eines Katalysators und Reaktors
WO2009003647A1 (en) * 2007-07-05 2009-01-08 Saudi Basic Industries Corporation Process for performing an endothermic reaction
US20100160702A1 (en) * 2008-12-23 2010-06-24 Chevron Phillips Chemical Company Lp Methods of Preparing an Aromatization Catalyst
DE102009012663B3 (de) * 2009-03-13 2010-09-16 Uhde Gmbh Verfahren und Vorrichtung zur gleichmäßigen Dampferzeugung aus der Abwärme einer Alkandehydrierung
US8895797B2 (en) * 2010-03-30 2014-11-25 Uop Llc Process for dehydrogenation of hydrocarbons in a multi-stage fluidized bed reactor
US8716161B2 (en) 2012-03-05 2014-05-06 Chevron Phillips Chemical Company Methods of regenerating aromatization catalysts
US8912108B2 (en) 2012-03-05 2014-12-16 Chevron Phillips Chemical Company Lp Methods of regenerating aromatization catalysts
US9387467B2 (en) 2012-09-26 2016-07-12 Chevron Phillips Chemical Company Lp Aromatization catalysts with high surface area and pore volume
CN104250195B (zh) * 2013-06-28 2016-01-13 中国石油化工股份有限公司 一种异丁烯的制备方法
CN104250194B (zh) * 2013-06-28 2016-01-13 中国石油化工股份有限公司 一种异丁烯的制备方法
US10246386B2 (en) * 2014-09-12 2019-04-02 Sabic Global Technologies B.V. Embedded alkane dehydrogenation systems and processes
CN104483998B (zh) * 2014-11-19 2017-02-22 四川辉腾科技有限公司 一种纺浆温度控制系统
CA3004298C (en) * 2015-11-04 2020-04-28 Exxonmobil Chemical Patents Inc. Fired tube conversion system and process
JP2018531970A (ja) * 2015-11-04 2018-11-01 エクソンモービル ケミカル パテンツ インコーポレイテッド 統合されたガスタービン及び変換システムプロセス
EP3371135B1 (en) * 2015-11-04 2020-07-01 ExxonMobil Chemical Patents Inc. Integrated gas turbine and conversion system process
ES2881297T3 (es) * 2017-02-10 2021-11-29 Technobell D O O Koper Reactor tubular de doble zona mejorado y método para llevar a cabo la producción de anhídrido maleico mediante la oxidación de n-butano
EP3995475B1 (en) 2019-07-05 2024-02-28 Sekisui Chemical Co., Ltd. Method for producing 1,3-butadiene
IT201900015683A1 (it) * 2019-09-05 2021-03-05 Nippon Gases Ind S R L Sistema modulabile per la generazione di endogas a contenuto di monossido di carbonio impostabile
WO2021102351A1 (en) * 2019-11-20 2021-05-27 Lummus Technology Llc Heat storage in chemical reactors
CN117202985A (zh) * 2021-04-07 2023-12-08 林德有限公司 用于执行化学反应的方法和反应器装置

Family Cites Families (4)

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FR1549226A (es) * 1967-06-22 1968-12-13
FR2511671A1 (fr) * 1981-08-18 1983-02-25 Davy Mckee Ag Procede de deshydrogenation
DE3416672A1 (de) * 1984-05-05 1985-11-07 Veba Oel AG, 4650 Gelsenkirchen Verfahren zum dehydrieren von kohlenwasserstoffen
US4996387A (en) * 1989-07-20 1991-02-26 Phillips Petroleum Company Dehydrogenation process

Also Published As

Publication number Publication date
EP0512911B1 (fr) 1995-08-09
JP3118671B2 (ja) 2000-12-18
JPH05246902A (ja) 1993-09-24
DE69203938D1 (de) 1995-09-14
US6191332B1 (en) 2001-02-20
EP0512911A1 (fr) 1992-11-11
DE69203938T2 (de) 1996-02-08

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