JP2010527770A5 - - Google Patents
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- Publication number
- JP2010527770A5 JP2010527770A5 JP2010509397A JP2010509397A JP2010527770A5 JP 2010527770 A5 JP2010527770 A5 JP 2010527770A5 JP 2010509397 A JP2010509397 A JP 2010509397A JP 2010509397 A JP2010509397 A JP 2010509397A JP 2010527770 A5 JP2010527770 A5 JP 2010527770A5
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- group
- metal
- germanium
- framework
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910021536 Zeolite Inorganic materials 0.000 claims description 20
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 20
- 239000010457 zeolite Substances 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 3
- 229910052796 boron Inorganic materials 0.000 claims 3
- 238000000151 deposition Methods 0.000 claims 3
- 229930195733 hydrocarbon Natural products 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 229910052718 tin Inorganic materials 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 4
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 3
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 229940119177 germanium dioxide Drugs 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US93161007P | 2007-05-24 | 2007-05-24 | |
| US60/931,610 | 2007-05-24 | ||
| US12/125,796 | 2008-05-22 | ||
| US12/125,796 US9221723B2 (en) | 2007-05-24 | 2008-05-22 | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1 |
| PCT/US2008/006631 WO2008147543A1 (en) | 2007-05-24 | 2008-05-23 | Catalyst for conversion of hydrocarbons, process of making and process of using thereof - incorporation-1 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010527770A JP2010527770A (ja) | 2010-08-19 |
| JP2010527770A5 true JP2010527770A5 (OSRAM) | 2013-07-11 |
| JP5323819B2 JP5323819B2 (ja) | 2013-10-23 |
Family
ID=41042110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010509397A Expired - Fee Related JP5323819B2 (ja) | 2007-05-24 | 2008-05-23 | 炭化水素の転化のための触媒、並びにその製造プロセスおよび使用プロセス |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9221723B2 (OSRAM) |
| EP (1) | EP2170509B1 (OSRAM) |
| JP (1) | JP5323819B2 (OSRAM) |
| KR (1) | KR20100024957A (OSRAM) |
| CN (1) | CN101687184A (OSRAM) |
| WO (1) | WO2008147543A1 (OSRAM) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8969232B2 (en) * | 2007-05-24 | 2015-03-03 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2 |
| WO2008153759A2 (en) | 2007-05-24 | 2008-12-18 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition |
| US8993468B2 (en) * | 2007-05-24 | 2015-03-31 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites |
| SG178307A1 (en) * | 2009-08-12 | 2012-03-29 | Mitsui Chemicals Inc | Method for manufacturing an aromatic hydrocarbon, and transition-metal-containing crystalline metallosilicate catalyst used in said manufacturing method |
| US20110132804A1 (en) * | 2009-12-04 | 2011-06-09 | Saudi Basic Industries Corporation | Increasing octane number of light naphtha using a germanium-zeolite catalyst |
| US9339802B2 (en) | 2011-01-26 | 2016-05-17 | Shell Oil Company | Zinc containing methane aromatization catalyst, method of making a method of using the catalyst |
| US8754280B2 (en) | 2011-09-07 | 2014-06-17 | Shell Oil Company | Method for start-up of an oxygenate-to-olefin process |
| US9242233B2 (en) | 2012-05-02 | 2016-01-26 | Saudi Basic Industries Corporation | Catalyst for light naphtha aromatization |
| US8772192B2 (en) | 2012-06-29 | 2014-07-08 | Saudi Basic Industries Corporation | Germanium silicalite catalyst and method of preparation and use |
| US9180441B2 (en) | 2012-09-20 | 2015-11-10 | Saudi Basic Industries Corporation | Method of forming zeolite shaped body with silica binder |
| AU2013342997B2 (en) * | 2012-11-09 | 2017-04-27 | Council Of Scientific & Industrial Research | A single step catalytic process for the conversion of n-paraffins and naphtha to diesel range hydrocarbons |
| US9861967B2 (en) | 2012-12-19 | 2018-01-09 | Shell Oil Company | Dehydroaromatization catalyst, method of making and use thereof |
| KR20140122117A (ko) * | 2013-04-09 | 2014-10-17 | 삼성전자주식회사 | 탄화수소의 이산화탄소 개질용 촉매 |
| US9782758B2 (en) * | 2013-04-23 | 2017-10-10 | Saudi Basic Industries Corporation | Method of preparing hydrocarbon aromatization catalyst, the catalyst, and the use of the catalyst |
| EP3071326B1 (en) | 2013-11-22 | 2022-08-24 | Saudi Basic Industries Corporation | Catalyst with improved activity/selectivity for light naphtha aromatization |
| US9764313B2 (en) | 2014-06-18 | 2017-09-19 | Basf Corporation | Molecular sieve catalyst compositions, catalyst composites, systems, and methods |
| US9889437B2 (en) | 2015-04-15 | 2018-02-13 | Basf Corporation | Isomorphously substituted catalyst |
| US10850265B2 (en) | 2014-06-18 | 2020-12-01 | Basf Corporation | Molecular sieve catalyst compositions, catalytic composites, systems, and methods |
| CA2966629C (en) | 2014-11-06 | 2023-01-03 | Shell Internationale Research Maatschappij B.V. | A self-activating hydroprocessing catalyst having enhanced activity and self-activation characteristics and its use for treating resid feedstocks |
| JP6866894B2 (ja) * | 2016-09-14 | 2021-04-28 | 住友化学株式会社 | ε−カプロラクタムの製造方法 |
| US10118167B2 (en) * | 2016-12-20 | 2018-11-06 | Chevron Phillips Chemical Company Lp | Methods for regenerating sulfur-contaminated aromatization catalysts |
| US10226761B2 (en) * | 2016-12-20 | 2019-03-12 | Chevron Phillips Chemical Company, Lp | Aromatization catalyst preparation with alkali metal present during a washing step |
| US11260376B2 (en) | 2016-12-21 | 2022-03-01 | Chevron Phillips Chemical Company Lp | Methods of preparing an aromatization catalyst |
| US10487025B2 (en) * | 2016-12-21 | 2019-11-26 | Chevron Phillips Chemical Company Lp | Methods of preparing an aromatization catalyst |
| JP7104298B2 (ja) * | 2018-02-06 | 2022-07-21 | 東ソー株式会社 | 新規ゼオライト及びこれを含む炭化水素吸着剤 |
| WO2020044309A1 (en) * | 2018-08-30 | 2020-03-05 | Sabic Global Technologies B.V. | Aromatization catalyst with improved isomerization, process of making and using thereof |
| US20220016611A1 (en) * | 2019-01-16 | 2022-01-20 | Lichen LIU | Sinter Resistant Metal Species In Zeolites |
| EP3858478A1 (en) * | 2020-01-31 | 2021-08-04 | SCG Chemicals Co., Ltd. | Stable, high selectivity catalysts and catalyst systems, and processes for their use |
| US12240792B2 (en) * | 2020-08-24 | 2025-03-04 | Univeristy Of Kansas | Processes for the preparation of alkylbenzenes |
| US11884615B2 (en) * | 2021-01-27 | 2024-01-30 | Saudi Arabian Oil Company | Modified beta zeolitic (*BEA) catalyst for isomerization of alkylated aromatics, and method for isomerization of alkylated aromatics |
| CN114558612B (zh) * | 2022-03-10 | 2022-11-18 | 河南大学 | 多级孔ZSM-5分子筛封装Pt-Ni双金属催化剂及其制备方法和用途 |
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| US7449168B2 (en) * | 2004-12-27 | 2008-11-11 | Saudi Basic Industries Corporation | Process for making a germanium-zeolite |
| US7223898B2 (en) * | 2005-03-11 | 2007-05-29 | Uop Llc | Isomerization process |
| US7745675B2 (en) * | 2006-12-20 | 2010-06-29 | Saudi Basic Industries Corporation | Regeneration of platinum-germanium zeolite catalyst |
| US7902413B2 (en) * | 2007-04-12 | 2011-03-08 | Saudi Basic Industries Corporation | Aromatization of alkanes using a germanium-zeolite catalyst |
| US8969232B2 (en) * | 2007-05-24 | 2015-03-03 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2 |
| US8993468B2 (en) * | 2007-05-24 | 2015-03-31 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites |
| WO2008153759A2 (en) * | 2007-05-24 | 2008-12-18 | Saudi Basic Industries Corporation | Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition |
-
2008
- 2008-05-22 US US12/125,796 patent/US9221723B2/en not_active Expired - Fee Related
- 2008-05-23 WO PCT/US2008/006631 patent/WO2008147543A1/en not_active Ceased
- 2008-05-23 EP EP08754707.1A patent/EP2170509B1/en not_active Not-in-force
- 2008-05-23 JP JP2010509397A patent/JP5323819B2/ja not_active Expired - Fee Related
- 2008-05-23 CN CN200880021428A patent/CN101687184A/zh active Pending
- 2008-05-23 KR KR1020097026909A patent/KR20100024957A/ko not_active Abandoned
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