JP2010058068A - 複層塗膜形成方法 - Google Patents
複層塗膜形成方法 Download PDFInfo
- Publication number
- JP2010058068A JP2010058068A JP2008227252A JP2008227252A JP2010058068A JP 2010058068 A JP2010058068 A JP 2010058068A JP 2008227252 A JP2008227252 A JP 2008227252A JP 2008227252 A JP2008227252 A JP 2008227252A JP 2010058068 A JP2010058068 A JP 2010058068A
- Authority
- JP
- Japan
- Prior art keywords
- coating film
- acid
- coat paint
- hydroxyl group
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000576 coating method Methods 0.000 title claims abstract description 146
- 239000011248 coating agent Substances 0.000 title claims abstract description 140
- 238000000034 method Methods 0.000 title claims abstract description 46
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- 239000005056 polyisocyanate Substances 0.000 claims abstract description 80
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 80
- 229920005989 resin Polymers 0.000 claims abstract description 77
- 239000011347 resin Substances 0.000 claims abstract description 77
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002981 blocking agent Substances 0.000 claims abstract description 23
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 142
- 239000003973 paint Substances 0.000 claims description 134
- 239000000049 pigment Substances 0.000 claims description 71
- -1 oxime compound Chemical class 0.000 claims description 65
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- 239000004640 Melamine resin Substances 0.000 claims description 12
- 230000009477 glass transition Effects 0.000 claims description 9
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 7
- 239000002932 luster Substances 0.000 claims description 4
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 2
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- 238000010438 heat treatment Methods 0.000 abstract description 9
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- 239000002585 base Substances 0.000 description 83
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 73
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 18
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- 239000003054 catalyst Substances 0.000 description 9
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- 238000012360 testing method Methods 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
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- 239000004611 light stabiliser Substances 0.000 description 8
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- 239000003960 organic solvent Substances 0.000 description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 7
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 7
- 239000012948 isocyanate Substances 0.000 description 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 6
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 6
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
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Abstract
【解決手段】被塗物に、ベースコート塗料を塗装してベースコート塗膜を形成し、該未硬化のベースコート塗膜上に、水酸基含有樹脂及びポリイソシアネート化合物を含有する2液型クリヤコート塗料を塗装してクリヤコート塗膜を形成し、ベースコート塗膜及びクリヤコート塗膜を同時に加熱硬化する複層塗膜形成方法において、該ベースコート塗料が、(A)水酸基含有樹脂、(B)架橋剤及び(C)アルコールを除くポリイソシアネート化合物のブロック剤を含有するベースコート塗料であって、(C)成分の含有量が、(A)成分及び(B)成分の総量を基準にして、1〜10質量%であることを特徴とする複層塗膜形成方法。
【選択図】なし
Description
本方法において被塗物に、最初に塗装されるベースコート塗料は、(A)水酸基含有樹脂、(B)架橋剤及び(C)アルコールを除くポリイソシアネート化合物のブロック剤を特定量含有するベースコート塗料である。
水酸基含有樹脂(A)
水酸基含有樹脂(A)は、水酸基を含有する樹脂であれば、特に限定されるものではなく、樹脂の種類としては、具体的には、例えば、アクリル樹脂、ポリエステル樹脂、ポリエーテル樹脂、ポリカーボネート樹脂、ポリウレタン樹脂などをあげることができる。特に、水酸基含有樹脂(A)として、アクリル樹脂、ポリエステル樹脂、及びポリウレタン樹脂を好適に使用することができる。
水酸基含有アクリル樹脂
水酸基含有アクリル樹脂は、水酸基含有不飽和モノマー(M−1)及びその他の共重合可能な不飽和モノマー(M−2)を常法により共重合せしめることによって合成することができる。
水酸基含有ポリエステル樹脂
水酸基含有ポリエステル樹脂は、既知の方法で、常法に従い、多塩基酸と多価アルコールとをエステル化反応させることによって合成することができる。
水酸基含有ポリウレタン樹脂
水酸基含有ポリウレタン樹脂は、常法により、例えば、ポリオールとジイソシアネートとを反応させることにより得ることができる。
架橋剤(B)
架橋剤(B)は、水酸基含有樹脂(A)の水酸基と反応性を有するものであれば特に制限なく使用することができる。特に、メラミン樹脂及びブロックポリイソシアネート化合物を好適に使用することができる。
上記ブロック剤のうち、硬化性、塗膜黄変性の観点から、オキシム系、ピラゾール系の化合物を好適に使用することができる。
アルコールを除くポリイソシアネート化合物のブロック剤(C)
本方法のベースコート塗料に含有されるアルコールを除くポリイソシアネート化合物のブロック剤(C)は、遊離のイソシアネート基を封鎖する化合物である。
2液型クリヤコート塗料
本方法に用いられる2液型クリヤコート塗料は、水酸基含有樹脂及びポリイソシアネート化合物を含有する2液型クリヤコート塗料である。
水酸基含有樹脂
本発明の2液型クリヤコート塗料の水酸基含有樹脂は、水酸基を含有するものであれば特に限定されるものではなく、具体的には、例えば、アクリル樹脂、ポリエステル樹脂、ポリエーテル樹脂、ポリウレタン樹脂などをあげることができ、好ましいものとして、水酸基含有アクリル樹脂、水酸基含有ポリエステル樹脂及び水酸基含有ポリウレタン樹脂をあげることができる。
としては、具体的には上記したもののうち、4−ヒドロキシブチル(メタ)アクリレートをあげることができる。
芳香族系不飽和モノマーを構成成分とすることにより、得られる樹脂のTgが上昇し、また、高屈折率で疎水性の塗膜を得ることができることから、塗膜の光沢向上による仕上り性の向上、耐水性および耐酸性の向上という効果を得ることができる。
また、水酸基含有樹脂には、いわゆるウレタン変性アクリル樹脂及びウレタン変性ポリエステル樹脂も包含される。
ポリイソシアネート化合物
本発明にかかる2液型クリヤコート塗料のポリイソシアネート化合物は、1分子中に遊離のイソシアネート基を2個以上有する化合物であり、従来からポリウレタンの製造に使用されているものを使用することができる。例えば、脂肪族ポリイソシアネート、脂環族ポリイソシアネート、芳香脂肪族ポリイソシアネート、芳香族ポリイソシアネート及びこれらポリイソシアネートの誘導体などをあげることができる。
本発明の2液型クリヤコート塗料において、塗膜の硬化性及び耐擦り傷性等の観点から、水酸基含有樹脂の水酸基とポリイソシアネート化合物のイソシアネート基の当量比(NCO/OH)は好ましくは0.5〜2.0、さらに好ましくは0.8〜1.5の範囲内である。
その他の成分
本発明にかかる2液型クリヤコート塗料には、得られる塗膜の透明性を阻害しない程度の範囲で、必要に応じて、着色顔料、体質顔料、光輝性顔料、防錆顔料等の公知の顔料を配合できる。
2液型クリヤコート塗料の調製方法
本発明にかかる2液型クリヤコート塗料は、水酸基含有樹脂、ポリイソシアネート化合物及び必要に応じて使用される硬化触媒、顔料、各種樹脂、紫外線吸収剤、光安定剤、有機溶剤等を、公知の方法により、混合することによって、調製することができる。
ベースコート塗料を塗装してベースコート塗膜を形成した後、該未硬化のベースコート塗膜上に、前述の2液型クリヤコート塗料の塗装が行なわれる。2液型クリヤコート塗料の塗装は、特に限定されずベースコート塗料と同様の方法で行うことができ、例えば、エアスプレー、エアレススプレー、回転霧化塗装、カーテンコート塗装などの塗装方法により行なうことができる。これらの塗装方法は、必要に応じて、静電印加してもよい。これらのうち静電印加による回転霧化塗装が好ましい。2液型クリヤコート塗料の塗布量は、通常、硬化膜厚として、10〜50μm程度となる量とするのが好ましい。
複層塗膜の加熱硬化
2液型クリヤコート塗料を塗装し、クリヤコート塗膜を形成させた後(必要に応じてさらにクリヤコート塗膜の形成後、揮発成分の揮散を促進するために、プレヒートを行なうこともできる(例えば、50〜80℃程度の温度で3〜10分間程度))、ベースコート塗膜及びクリヤコート塗膜が同時に加熱硬化される。加熱は公知の手段により行うことができ、例えば、熱風炉、電気炉、赤外線誘導加熱炉等の乾燥炉を適用できる。加熱温度は、80〜180℃、好ましくは100〜160℃の範囲内にあることが適している。加熱時間は、特に制限されるものではないが、10〜40分間の範囲内であるのが好適である。
製造例1
攪拌機、温度調整器及び冷却器を備えた反応容器にプロピレングリコールモノプロピルエーテル120部を入れ、110℃に加熱し、同温度に保持してから、2−メタクリロイルオキシエチルアシッドフォスフェート12部、n−ブチルアクリレート30部、スチレン30部、2−エチルヘキシルアクリレート18部、2−ヒドロキシエチルアクリレート10部及びt−ブチルパーオキシ−2−エチルヘキサノエート3部からなる混合物103部を4時間かけて滴下し、滴下終了後、さらに1時間攪拌して熟成をおこなった。その後、t−ブチルパーオキシ−2−エチルヘキサノエート1部とプロピレングリコールモノメチルエーテル30部とからなる開始剤溶液を1時間かけて滴下し、滴下終了後さらに1時間攪拌して熟成することにより固形分含有率40%の顔料分散樹脂(AC−1)を得た。
水酸基含有樹脂(アクリルエマルション) (EM−1)の製造
製造例2
温度計、サーモスタット、攪拌器、還流冷却器及び滴下装置を備えた反応容器に脱イオン水32.1部、「NEWCOL707SF」(日本乳化剤社製、商品名、乳化剤)0.24部を加え、80℃に加温してから、脱イオン水1.11部に溶解した過硫酸アンモニウム0.033部及び下記のプレエマルション1の全量の1%量を投入し、同温度で20分間熟成した。その後、残りのプレエマルション1を2時間かけて反応容器に滴下し、その後1時間熟成した。次いで下記プレエマルション2を、過硫酸アンモニウム0.003部を脱イオン水1.11部に溶解したものと同時に、2時間かけて滴下した。その後、1時間熟成して、脱イオン水19.53部に2−(ジメチルアミノ)エタノール0.294部を溶解したものを投入し、固形分含有率25%、pH8.5、粒子径120nmのアクリルエマルション(EM−1)を得た。
ポリエステル水溶液 (PE−1)の製造
製造例3
攪拌機、還流冷却器、水分離器及び温度計を備えた反応容器に、1,6−ヘキサンジオール142部(1.2モル)、トリメチロールプロパン109部(0.8モル)、アジピン酸123部(0.84モル)及びヘキサヒドロ無水フタル酸129部(0.84モル)を仕込み、3時間を要して150℃から230℃に昇温し、同温度で1.5時間保持して縮合水を系外に流出させながら縮合反応を行った。その後、トルエン3部を加えて還流させながら、攪拌と脱水を継続して行い、カルボキシル基による酸価が5mgKOH/gになるまで反応せしめ、生成する水をトルエンと共沸させて除去した。その後、温度を170℃とし、無水トリメリット酸38.4部(0.2モル)を投入し、同温度で30分間反応させてからジプロピレングリコールモノメチルエーテル20部を加え、温度を80℃として、酸価が45mgKOH/g、水酸基価が150mgKOH/g、数平均分子量が1400のポリエステルを得た。これに2−(ジメチルアミノ)エタノール9部を加えて中和し、脱イオン水を加えることにより固形分含有濃度35%のポリエステル水溶液(PE−1)を得た。
光輝性顔料濃厚液(P−1)の製造
製造例4
アルミニウム顔料ペースト「GX−180」(旭化成メタルズ社製、商品名、アルミニウム顔料含有率73%)19部、2−エチルヘキサノール35部、製造例1で得た顔料分散用樹脂(AC−1)10部及びジメチルエタノールアミン0.2部を均一に混合して光輝性顔料濃厚液(P−1)を得た。
水性ベースコート塗料の製造
製造例5
製造例2で得たアクリルエマルション(EM−1)160部、製造例3で得たポリエステル水溶液(PE−1)85.7部、サイメル327(メラミン樹脂、商品名、日本サイテックインダストリー社製、固形分90%)33部、製造例4で得た光輝性顔料濃厚液(P−1)64.2部及びメチルエチルケトオキシム5部を均一に混合し、更に脱イオン水及びジメチルエタノールアミンを添加することにより、800mPa・s(B型粘度計により、20℃、60rpmの測定条件で測定)、pHが7.8、固形分濃度25%の水性ベースコート塗料1を得た。
表1に示す配合にて製造例5と同様にして製造することにより、各水性ベースコート塗料2〜8を得た。なお、表1に示す配合は固形分配合である。
また、光輝性顔料濃厚液(P−1)の固形分18部の内訳は、アルミ顔料固形分が14部と顔料分散樹脂(AC−1)が4部である。
製造例14
攪拌機、温度調整器及び冷却器を備えた反応容器にキシレン50部及びn−ブタノール20部を入れ、110℃に加熱し、同温度に保持してから、2−メタクリロイルオキシエチルアシッドフォスフェート6部、メチルメタクリレート24部、n−ブチルアクリレート30部、スチレン20部、2−ヒドロキシエチルアクリレート20部及びt−ブチルパーオキシ−2−エチルヘキサノエート3部からなる混合物103部を4時間かけて滴下し、滴下終了後、さらに1時間攪拌して熟成をおこなった。その後、t−ブチルパーオキシ−2−エチルヘキサノエート1部とプロピレングリコールモノプロピルエーテル30部とからなる開始剤溶液を1時間かけて滴下し、滴下終了後さらに1時間攪拌して熟成することにより固形分含有率50%の顔料分散樹脂(AC−2)を得た。
ポリエステル溶液 (PE−2)の製造
製造例15
攪拌機、還流冷却器、水分離器及び温度計を備えた反応容器に、ネオペンチルグリコール52.5部(0.50モル)、トリメチロールプロパン40.95部(0.30モル)、1,6−ヘキサンジオール23.6部(0.20モル)、アジピン酸58.4部(0.40モル)及びイソフタル酸83.0部(0.50モル)を仕込み、3時間を要して150℃から230℃に昇温し、同温度で1.5時間保持して縮合水を系外に流出させながら縮合反応を行った。その後、トルエン3部を加えて還流させながら、攪拌と脱水を継続して行い、カルボキシル基による酸価が5mgKOH/gになるまで反応せしめ、生成する水をトルエンと共沸させて除去した。その後、冷却し、キシレン100部、n−ブタノール49部で希釈して、酸価が5mgKOH/g、水酸基価が130mgKOH/g、数平均分子量が1880の固形分含有濃度60%のポリエステル溶液(PE−2)を得た。
溶剤型ベースコート塗料の製造
製造例16
製造例14で得た顔料分散樹脂(AC−2)60部(固形分30部)、製造例15で得たポリエステル溶液(PE−2)66.7部(固形分40部)、ユーバン28−60(ブチル化メラミン樹脂、商品名、三井化学株式会社製、固形分60%)50部(固形分30部)、アルミペースト1830L(アルミペースト、商品名、東洋アルミ社製、固形分濃度60%)25部(固形分15部)及びメチルエチルケトオキシム5部を均一に混合し、更にキシレンと酢酸ブチルを等量配合したシンナーにより希釈し、固形分含有濃度が30%となるように調整することにより、フォードカップ粘度が18秒(フォードカップNo.4、20℃)、固形分濃度30%の溶剤型ベースコート塗料1を得た。
製造例16でメチルエチルケトオキシムを添加しない以外は同様にして製造することにより、溶剤型ベースコート塗料2を得た。
アクリル樹脂溶液(AC−3)の製造
製造例18
攪拌機、温度調整器及び冷却器を備えた反応容器にエチル−3−エトキシプロピオネート60部を入れ、145℃に加熱し、同温度に保持してから、スチレン10部、n−ブチルメタクリレート25部、2−エチルヘキシルアクリレート10部、イソボルニルアクリレート10部、n−ブチルアクリレート10部、ヒドロキシプロピルアクリレート34部、アクリル酸1部及びジ−t−ブチルパーオキサイド5部から成る混合物105部を4時間かけて滴下し、滴下終了後、さらに1時間攪拌して熟成をおこなった。その後、ジ−t−ブチルパーオキサイド1部とエチル−3−エトキシプロピオネート21.9部とからなる開始剤溶液を1時間かけて滴下し、滴下終了後さらに1時間攪拌して熟成することにより固形分濃度55%のアクリル樹脂溶液(AC−3)を得た。得られたアクリル樹脂の重量平均分子量は6000、水酸基価は147mgKOH/g、酸価は7.8mgKOH/g、ガラス転移温度は−16℃であった。
2液型クリヤコート塗料の製造
製造例19
アクリル樹脂溶液(AC−3)181.8部に、スミジュールN−3300(HDIの三量体、イソシアヌレート変性HDI、住化バイエルウレタン社製)45部をエチル−3−エトキシプロピオネート30部に溶解させたものを加え、更に、ディスパロンLC−951(表面調整剤、楠本化成品、有効成分10%)2部を添加して混合した。これを固形分濃度50%となるようにエチル−3−エトキシプロピオネート/酢酸ブチル=1/1(質量比)で希釈し、2液型クリヤコート塗料として塗装に供した。その時のフォードカップ粘度は20秒(フォードカップNo.4、20℃)であった。
複層塗膜形成方法
被塗物
リン酸亜鉛化成処理を施した厚さ0.8mmのダル鋼板上に、エレクロン9600(関西ペイント社製、商品名、熱硬化性エポキシ樹脂系カチオン電着塗料)を膜厚が20μmになるように電着塗装し、170℃で30分間加熱し硬化させ、その上にアミラックTP−65−2(関西ペイント社製、商品名、ポリエステル樹脂・メラミン樹脂系自動車中塗塗料)を膜厚35μmとなるようにエアスプレー塗装し、140℃で30分間加熱硬化させたものを被塗物とした。
試験板の作成
被塗物の中塗塗膜面に、製造例5〜13で得られた各水性ベースコート塗料1〜9及び製造例16〜17で得られた各溶剤型ベースコート塗料1〜2を、回転式霧化静電塗装機を用いて、ブース温湿度25℃/75%で、膜厚15μmとなるように塗装し、2分間放置した(水性ベースコート塗料1〜9を塗装したものについては、さらに80℃で5分間プレヒートを行なった)。次いでその未硬化塗面に、製造例19で得られた2液型クリヤコート塗料を、ミニベル型回転式霧化静電塗装機を用い、ブース温湿度25℃/75%で、膜厚40μmとなるように塗装し、7分間経過後、140℃で30分間加熱して、ベースコート塗膜及びクリヤコート塗膜を同時に硬化させることにより、各試験板を作製した。得られた各試験板につき、以下の項目につき評価を行なった。
○:塗面のツヤに変化が認められない
△:ツヤビケがわずかに認められる
×:ツヤビケが著しく認められる
耐水性:試験板を40℃の温水に240時間浸漬後引き上げ、20℃で12時間乾燥した後、試験板上の複層塗膜を素地に達するようにカッターで格子状に切り込み、大きさ2mm×2mmのゴバン目を100個作る。続いて、その表面に粘着セロハンテープを貼着し、20℃においてそのテープを急激に剥離した後のゴバン目塗膜の残存状態を調べた。
◎:ゴバン目塗膜が100個残存し、かつフチカケが生じていない。
○:ゴバン目塗膜が100個残存しているが、フチカケが生じている。
△:ゴバン目塗膜が90〜99個残存している。
×:ゴバン目塗膜の残存数が89個以下である。
試験結果を表2に示す。
Claims (7)
- 被塗物に、ベースコート塗料を塗装してベースコート塗膜を形成し、該未硬化のベースコート塗膜上に、水酸基含有樹脂及びポリイソシアネート化合物を含有する2液型クリヤコート塗料を塗装してクリヤコート塗膜を形成し、ベースコート塗膜及びクリヤコート塗膜を同時に加熱硬化する複層塗膜形成方法において、
該ベースコート塗料が、(A)水酸基含有樹脂、(B)架橋剤及び(C)アルコールを除くポリイソシアネート化合物のブロック剤を含有するベースコート塗料であって、(C)成分の含有量が、(A)成分及び(B)成分の総量を基準にして、1〜10質量%であることを特徴とする複層塗膜形成方法。 - (C)ポリイソシアネート化合物のブロック剤が、オキシム化合物、アゾール化合物及びラクタム化合物から選ばれる少なくとも1種である請求項1に記載の複層塗膜形成方法。
- 架橋剤(B)がメラミン樹脂である請求項1又は2に記載の複層塗膜形成方法。
- ベースコート塗料が更に光輝性顔料を含有するものである請求項1〜3のいずれかに記載の複層塗膜形成方法。
- ベースコート塗料が水性ベースコート塗料である請求項1〜4のいずれかに記載の複層塗膜形成方法。
- 2液型クリヤコート塗料におけるポリイソシアネート化合物が、ヘキサメチレンジイソシアネート系化合物である請求項1〜5のいずれかに記載の複層塗膜形成方法。
- 2液型クリヤコート塗料における水酸基含有樹脂が、水酸基価が80〜200mgKOH/g、ガラス転移温度が−40℃〜20℃の水酸基含有アクリル樹脂である請求項1〜6のいずれかに記載の複層塗膜形成方法。
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013017940A (ja) * | 2011-07-09 | 2013-01-31 | Kansai Paint Co Ltd | 複層塗膜形成方法 |
WO2013047209A1 (ja) * | 2011-09-30 | 2013-04-04 | 関西ペイント株式会社 | 塗膜形成方法及び塗装物品 |
WO2014045657A1 (ja) * | 2012-09-20 | 2014-03-27 | 関西ペイント株式会社 | 複層塗膜形成方法 |
JPWO2013047208A1 (ja) * | 2011-09-30 | 2015-03-26 | 関西ペイント株式会社 | 塗料組成物及び塗装物品 |
JP2019529157A (ja) * | 2016-07-26 | 2019-10-17 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 二重層硬化機構により形成される1成分の低温硬化コーティング |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005220285A (ja) * | 2004-02-09 | 2005-08-18 | Nippon Paint Co Ltd | メタリックベース塗料組成物および積層塗膜の形成方法 |
JP2006131696A (ja) * | 2004-11-04 | 2006-05-25 | Kansai Paint Co Ltd | 熱硬化性水性塗料及び塗膜形成方法 |
JP2007283271A (ja) * | 2006-04-20 | 2007-11-01 | Kansai Paint Co Ltd | 複層塗膜形成方法 |
-
2008
- 2008-09-04 JP JP2008227252A patent/JP5015884B2/ja active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005220285A (ja) * | 2004-02-09 | 2005-08-18 | Nippon Paint Co Ltd | メタリックベース塗料組成物および積層塗膜の形成方法 |
JP2006131696A (ja) * | 2004-11-04 | 2006-05-25 | Kansai Paint Co Ltd | 熱硬化性水性塗料及び塗膜形成方法 |
JP2007283271A (ja) * | 2006-04-20 | 2007-11-01 | Kansai Paint Co Ltd | 複層塗膜形成方法 |
Cited By (10)
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JP2013017940A (ja) * | 2011-07-09 | 2013-01-31 | Kansai Paint Co Ltd | 複層塗膜形成方法 |
WO2013047209A1 (ja) * | 2011-09-30 | 2013-04-04 | 関西ペイント株式会社 | 塗膜形成方法及び塗装物品 |
JPWO2013047208A1 (ja) * | 2011-09-30 | 2015-03-26 | 関西ペイント株式会社 | 塗料組成物及び塗装物品 |
JPWO2013047209A1 (ja) * | 2011-09-30 | 2015-03-26 | 関西ペイント株式会社 | 塗膜形成方法及び塗装物品 |
US9636703B2 (en) | 2011-09-30 | 2017-05-02 | Kansai Paint Co., Ltd. | Method for forming coating film and coated article |
WO2014045657A1 (ja) * | 2012-09-20 | 2014-03-27 | 関西ペイント株式会社 | 複層塗膜形成方法 |
US9404010B2 (en) | 2012-09-20 | 2016-08-02 | Kansai Paint Co., Ltd. | Method for forming multilayer coating film |
JPWO2014045657A1 (ja) * | 2012-09-20 | 2016-08-18 | 関西ペイント株式会社 | 複層塗膜形成方法 |
JP2019529157A (ja) * | 2016-07-26 | 2019-10-17 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 二重層硬化機構により形成される1成分の低温硬化コーティング |
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