JP2010048844A - Filter for display - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a filter for display which is inexpensive and can suppress the deterioration in visibility of a display image caused by metallic glossiness of a conductive mesh. <P>SOLUTION: The filter for display has the conductive mesh on a substrate and has a surface layer on the conductive mesh, wherein the conductive mesh includes a metal layer (A) made of predetermined metal and a metal layer (B) made of a metal different from the predetermined metal or made of a metallic compound in the order from the substrate side, a thickness of the metal layer (A) is 0.5 to 4 μm, a thickness of the metal layer (B) is 0.005 to 0.1 μm, and the surface layer contains light-transmissive particles having an average particle size of 1 to 20 μm. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a display filter mounted on a screen of a display device such as a CRT, an organic EL display, a liquid crystal display, and a plasma display.

  In the display device, a display filter is usually arranged on the viewing side of the display for the purpose of preventing reflection of external light, shielding electromagnetic waves generated from the display, and protecting the display. In particular, PDP generates strong electromagnetic waves due to its structure and operating principle, so there are concerns about the effects on human bodies and other devices. In Japan, VCCI (Electromagnetic Interference Regulations for Information Processing Equipment, etc.) and FCC ( It is standardized to keep within the standard value of the Federal Communications Commission).

  On the other hand, with the price reduction of plasma displays, the price of display filters has been decreasing year by year, and the demand for cost reduction has become severe. A general display filter includes an optical functional film having functional layers such as a hard coat layer, an antireflection layer and an antiglare layer on a substrate such as a plastic film, and a conductive layer on the substrate such as a plastic film. It is manufactured by laminating an electromagnetic wave shielding film on which an (electromagnetic wave shielding layer) is formed via an adhesive layer, but only one base material is used for a display filter comprising these two base materials. By configuring, the price can be reduced.

  As one configuration of a display filter composed of only one substrate, functional layers such as a hard coat layer and an antireflection layer are arranged so as to cover a conductive layer composed of a conductive mesh formed on the substrate. An embodiment is mentioned. The conductive mesh is preferably used because a conductive layer having a low resistance can be obtained at a relatively low cost compared to a metal thin film formed by sputtering or vacuum deposition.

  A display filter is known in which a conductive layer made of a conductive mesh is covered with a functional layer. For example, Patent Document 1 discloses a transparent conductive hard coat film in which a hard layer such as a hard coat, an antiglare layer, or an antireflection layer is directly disposed on a conductive mesh. A display filter in which a hard coat layer or a hard coat layer and an antireflection layer are laminated is described in Patent Document 2, and a flattening layer for flattening irregularities of a metal pattern layer (conductive mesh) Patent Document 3 describes an optical filter in which an antireflection layer is laminated.

Since the conductive mesh constituting the display filter is usually made of metal, there is a problem that the metallic luster reduces the visibility of the display image on the display. That is, there is a problem that the reflected image of external light such as a fluorescent lamp becomes clear and the visibility of the display image decreases. Therefore, in order to suppress the metallic luster of the conductive mesh, it is generally performed to provide a blackened layer on the surface of the conductive mesh. As a method for forming the blackened layer, a method of blackening the surface of the metal layer constituting the conductive mesh by oxidation (for example, Patent Document 4), a black metal oxide layer on the surface of the metal layer constituting the conductive mesh (E.g., Patent Documents 5 and 6), or a method of blackening by plating a Ni-Sn alloy on a metal layer (e.g., a copper plating layer) constituting a conductive mesh ( For example, Patent Document 7) is known.
JP 2007-140282 A JP 2007-243158 A JP-A-11-337702 JP 2006-191010 A JP 2000-223886 A JP 2001-127485 A JP 2006-173189 A

  The above-described method of Patent Document 4 (method of oxidizing the surface of the metal layer constituting the conductive mesh) is effective in terms of suppressing the metallic luster of the conductive mesh. There is a problem that the adhesion between the base material and the conductive mesh is lowered due to its high alkalinity, and in particular, a metal formed by a vapor deposition method suitable as a method for producing a metal layer used in the display filter of the present invention. A conductive mesh using layers has a problem that it is easily affected. In addition, the blackened layer formed by oxidation treatment is fragile and easily detached, and a part of the blackened layer is applied in the process of coating the surface layer on the conductive mesh in the display filter manufacturing process. Detaches and remains on the display filter as a foreign substance, or contaminates a transport path such as a roll. Furthermore, in order to obtain sufficient performance as a blackened layer, a thickness of about 1 μm is required, and the thickness of the blackened layer is reduced by the thickness of the metal layer, resulting in a problem that electromagnetic wave shielding properties are reduced. .

  On the other hand, the methods of the above-mentioned patent documents 5 to 7 (method of forming a blackened layer by vapor deposition or plating) are sufficient to suppress the metallic gloss of the conductive mesh (actually black color is not exhibited). There is a problem that it is difficult to form. However, on the other hand, the method of forming a blackened layer by vapor deposition such as vapor deposition is preferable in terms of the working environment because it does not require a wet process such as the above-described oxidation process. This is advantageous in that a thin film having a thickness of 1 μm or less can be easily formed, and is useful for producing a conductive mesh having a small thickness.

  In the case of the above-described two-substrate display filter that has been generally used, the adhesive layer, the near-infrared shielding layer, the color on the viewing side (viewing side) with respect to the conductive mesh Since a correction layer, a base material made of a plastic film, or a surface layer such as an antireflection layer is disposed, the latter method (method of forming a blackened layer by a vapor deposition method or a plating method) is used. Even the blackened layer was not a problem from the viewpoint of suppressing the metallic luster of the conductive mesh.

  However, the display filter targeted by the present invention has no layer for reducing the metallic luster of the conductive mesh, such as a plastic film substrate or an adhesive layer, on the viewing side with respect to the conductive mesh. In the blackened layer formed by the latter method (method of forming the blackened layer by vapor deposition or plating), it is insufficient to suppress the metallic luster of the conductive mesh, and the visibility of the display image is poor. It has been newly found that there is a problem of causing a decrease.

  Moreover, also about patent documents 1-3 regarding the filter for a display which laminated | stacked the functional layer so that the conductive mesh mentioned above may be covered, in order to suppress the fall of the visibility of the display image resulting from the metallic luster of a conductive mesh It is not described that the functional layer (hard coat layer, antireflection layer, antiglare layer, etc.) contains particles.

  In view of the above-described problems, an object of the present invention is to provide a display filter that is low in cost and suppresses a decrease in visibility of a display image due to the metallic luster of a conductive mesh.

The above object of the present invention has been basically achieved by the following invention.
1) A display filter having a conductive mesh on a substrate and a surface layer on the conductive mesh,
The conductive mesh is composed of, in order from the base material side, a metal layer (A) made of a specific metal and a layer (B) made of a metal different from the specific metal or a metal compound,
And the thickness of the said metal layer (A) is 0.5-4 micrometers, The thickness of the said layer (B) is 0.005-0.1 micrometer,
The display filter, wherein the surface layer contains translucent particles having an average particle diameter of 1 to 20 μm.
2) The display filter according to 1), wherein the surface layer contains 2 to 20% by mass of the translucent particles with respect to 100% by mass of all components of the surface layer.
3) The display filter according to 1) or 2), wherein the surface layer further contains a colorant.
4) The display filter according to any one of 1) to 3), wherein a center line average roughness Ra of the surface layer is 300 to 1000 nm.
5) The display according to any one of 1) to 4), wherein the specific metal constituting the metal layer (A) is at least one selected from the group consisting of gold, silver, copper, aluminum, and nickel. Filter.
6) The metal compound constituting the layer (B) is at least one selected from the group consisting of metal oxides, metal sulfides, and metal nitrides, according to any one of 1) to 5) above. Display filter.
7) The surface layer includes at least a hard coat layer, and the hard coat layer contains translucent particles having an average particle diameter of 1 to 20 μm, according to any one of 1) to 6). Display filter.
8) The display filter according to 7), wherein the hard coat layer further contains a colorant.

  ADVANTAGE OF THE INVENTION According to this invention, the filter for a display by which the fall of the visibility of the display image resulting from metal gloss of a conductive mesh was suppressed at low cost can be provided.

  The display filter of the present invention has a conductive mesh on a substrate, and a surface layer on the conductive mesh. Here, the surface layer is formed on the conductive mesh so as to cover the conductive mesh. The surface layer is a layer that becomes the outermost surface on the viewing side (viewer side) when the display filter is mounted on the display. Details of the surface layer will be described later.

(Conductive mesh)
The conductive mesh according to the present invention includes a metal layer (A) made of a specific metal and a layer (B) made of a metal or a metal compound different from the specific metal in this order from the substrate side.

  Here, the specific metal constituting the metal layer (A) is preferably a highly conductive metal, for example, at least one metal selected from the group consisting of gold, silver, copper, aluminum, and nickel is preferable. Any one of silver, copper, and aluminum is preferable, and copper is particularly preferable.

  For the layer (B), a metal or metal compound different from the specific metal of the metal layer (A) is used. The dissimilar metal is at least one selected from the group consisting of gold, platinum, silver, mercury, copper, aluminum, nickel, chromium, iron, tin, zinc, indium, palladium, iridium, cobalt, tantalum, antimony, titanium and the like. A metal of a seed | species is mentioned and the metal different from the specific metal of a metal layer (A) is selected. Examples of the metal compound include at least one selected from the group consisting of oxides, nitrides, sulfides, carbides, and fluorides of the metals exemplified as the above-mentioned different metals. Among these, metal oxides, metal nitrides, and metal sulfides are preferably used. The specific metal of the metal layer (A) and the metal in the metal compound of the layer (B) may be the same metal. For example, when the metal layer (A) is made of copper, the layer A mode in which (B) is composed of copper oxide is included in the present invention.

  As the metal oxide, ITO, ATO, copper oxide, chromium oxide, tin oxide, zinc oxide, silver oxide, cobalt oxide, mercury oxide, gold oxide, iridium oxide and the like are preferably used.

  As the above metal nitride, aluminum nitride, titanium nitride or the like is preferably used.

  As the metal sulfide, chromium sulfide, copper sulfide, palladium sulfide, nickel sulfide, cobalt sulfide, iron sulfide, tantalum sulfide, titanium sulfide and the like are preferably used.

  The thickness of the metal layer (A) which comprises the electroconductive mesh concerning this invention is 0.5-4 micrometers. The metal layer (A) is a layer that exhibits the electromagnetic wave shielding performance of the conductive mesh. In order to ensure sufficient electromagnetic wave shielding performance, the thickness is required to be 0.5 μm or more, and the thickness is 1 μm or more. preferable. On the other hand, since the thickness of the conductive mesh greatly depends on the thickness of the metal layer (A), if the thickness of the metal layer (A) exceeds 4 μm, the total thickness of the conductive mesh increases, and the coating of the surface layer is performed. This is disadvantageous in terms of cost and workability of the conductive mesh.

The conductive mesh of the present invention does not need to be subjected to conventional general blackening treatment (oxidation treatment). That is, instead of this blackening treatment, the metallic luster of the metal layer (A) can be reduced by laminating the layer (B) on the metal layer (A). The layer (B) is preferably disposed on the outermost surface of the conductive mesh.
The conductive mesh of the present invention is not necessarily subjected to conventional general blackening treatment (oxidation treatment). That is, instead of this blackening treatment, the layer (B) is laminated on the metal layer (A), and a surface layer containing translucent particles having an average particle diameter of 1 to 20 μm is further provided. It is because the fall of visibility resulting from the metallic luster of a layer (A) can be suppressed. In the present invention, the layer (B) is preferably disposed on the outermost surface of the conductive mesh.

  The layer (B) constituting the conductive mesh is a layer for reducing the metallic luster of the metal layer (A) or changing the color of the metal layer (A). In the present invention, the layer (B) is an ultrathin film of 0.1 μm or less. When the thickness of the layer (B) is larger than 0.1 μm, it is disadvantageous in terms of cost and workability. Further, in order to change the color of the metal layer (A) by the difference in refractive index between the metal layer (A) and the layer (B), the layer (B) needs to have light transmittance, and the thickness of the layer (B). When the thickness exceeds 0.1 μm, the light transmittance is lowered and the above-mentioned purpose cannot be achieved.

  For example, when copper is used as the metal layer (A), the reddish hue can be changed to a desired color by laminating the layer (B) made of a different metal.

  In order to achieve the purpose of the layer (B) described above, the thickness of the layer (B) needs to be 0.005 μm or more, preferably 0.01 μm or more.

  The thickness of the conductive mesh (the total thickness of the conductive mesh including the metal layer (A) and the layer (B)) according to the present invention is preferably 4 μm, more preferably 3.5 μm or less, and particularly preferably 3 μm or less. On the other hand, the lower limit of the total thickness of the conductive mesh is preferably 0.6 μm or more, more preferably 0.8 μm or more, and particularly preferably 1 μm or more.

  The manufacturing method of the electroconductive mesh concerning this invention is demonstrated below.

  In producing the conductive mesh, a metal layer (A) made of a specific metal and a layer (B) made of a metal or a metal compound different from the specific metal are previously formed on the substrate from the metal layer ( A) and layer (B) are laminated in this order. As a lamination method of the metal layer (A) and the layer (B), it is preferable to use a vapor deposition method. The vapor deposition method is suitable for forming an ultrathin film such as the layer (B) uniformly and accurately, and the metal layer (A) and the layer (B) are vapor deposition methods. Films can be continuously formed, which is advantageous in terms of productivity. Further, the vapor deposition method is preferable in terms of working environment as compared with the wet plating method.

  Examples of the vapor deposition method include sputtering, ion plating, electron beam evaporation, vacuum evaporation, and chemical vapor deposition. Among these, sputtering and vacuum evaporation are preferable.

  Two preferable processing methods will be described for the pattern processing method of the metal layer (A) and the layer (B) laminated on the base material by the vapor deposition method. In the following description, a structure in which the metal layer (A) and the layer (B) are laminated is simply referred to as a metal-containing laminated film.

  One pattern processing method is a method of processing a metal-containing laminated film into a mesh pattern by an etching method. In another processing method, a pattern reverse to the pattern of the conductive mesh is formed on a base material in advance using a resin soluble in a solvent, and then a gas phase film forming method is applied to the pattern forming surface of the base material. This is a method of forming a metal-containing laminated film having a mesh pattern by laminating a metal-containing laminated film and removing the reverse-patterned resin and the metal-containing laminated film thereon with a solvent.

  The former pattern processing method will be described in detail. Such a processing method includes forming a resist pattern on a metal-containing laminate film laminated on a substrate by a vapor deposition method using a photolithography method or a screen printing method, and then forming the metal-containing laminate film. This is a method of etching. As a method for forming the resist pattern, a photolithography method is preferably used. In such a photolithography method, a photosensitive resist layer is laminated on a metal thin film, the resist layer is exposed to a mesh pattern, developed to form a resist pattern, and then the metal-containing laminated film is etched to form a mesh pattern. The resist layer on the mesh is peeled and removed.

  As the photosensitive resist layer, a negative resist in which the exposed portion is cured or a positive resist in which the exposed portion is dissolved by development can be used. The photosensitive resist layer may be directly coated and laminated on the metal-containing laminated film, or a film made of a photoresist may be bonded. As a method for exposing the photoresist layer, there can be used a method of exposing with an ultraviolet ray or the like through a photomask, or a method of directly scanning and exposing using a laser.

  Etching methods include chemical etching methods. Chemical etching is a method in which a metal other than a metal portion protected by a resist pattern is dissolved and removed with an etching solution. Examples of the etching solution include a ferric chloride aqueous solution, a cupric chloride aqueous solution, and an alkaline etching solution.

  The latter pattern processing method will be described in detail. This pattern processing method is generally called lift-off. A resin layer having a pattern opposite to that of the conductive mesh is formed on a substrate in advance using a resin that can be peeled, and a metal-containing laminated film is laminated thereon. Then, the resin layer having the reverse pattern is peeled off. When the resin layer having the reverse pattern is peeled off, the metal-containing laminated film on the resin layer is also peeled off at the same time, so that the pattern of the metal-containing laminated film is formed only in the portion where the resin layer is not formed. . Therefore, in this processing method, it is necessary to form the peelable resin layer in a pattern opposite to that of the conductive mesh.

  A resin that is soluble in a solvent is preferably used as the resin used for the peelable resin layer that is formed in advance on the substrate in a pattern opposite to the conductive mesh pattern. As such a resin, a water-soluble resin, a resin soluble in an organic solvent, and a resin soluble in an alkali can be used. Among these resins, a water-soluble resin is preferable from the viewpoint of work environment and the like, and a water-soluble polymer resin is particularly preferably used.

  Examples of water-soluble polymer resins include polyvinyl pyrrolidone, polyvinyl alcohol, partially saponified polyvinyl alcohol, soluble starch, carboxymethyl starch, vinyl acetate-maleic acid alternating copolymer, and hydroxypropyl cellulose. One or a mixture of two or more molecular resins can be used.

  Examples of resins that are soluble in organic solvents include polyimide ether resins, polyamide resins, polyamideimide resins, polybenzimidazole resins, polyhydantoin resins, polyparaban resins, and solvent-soluble polyimide resins. Silicone grease or oil-based ink can also be used.

  As the alkali-soluble resin, a general resist can be used. Examples of the binder polymer constituting the resist include the following. Natural rubber, polyisoprene, poly-1,2-butadiene, polyisobutene, polybutene, poly-2-heptyl-1,3-butadiene, poly-2-t-butyl-1,3-butadiene, poly-1,3- (Di) enes such as butadiene, polyoxyethylene, polyoxypropylene, polyvinyl ethyl ether, polyvinyl hexyl ether, polyethers such as polyvinyl butyl ether, polyesters such as polyvinyl acetate and polyvinyl propionate, polyurethane, ethyl cellulose, poly Vinyl chloride, polyacrylonitrile, polymethacrylonitrile, polysulfone, polysulfide, polyethyl acrylate, polybutyl acrylate, poly-2-ethylhexyl acrylate, poly-t-butyl acrylate, poly-3-eth Xylpropyl acrylate, polyoxycarbonyl tetramethacrylate, polymethyl acrylate, polyisopropyl methacrylate, polydodecyl methacrylate, polytetradecyl methacrylate, poly-n-propyl methacrylate, poly-3,3,5-trimethylcyclohexyl methacrylate, polyethyl methacrylate, Poly (meth) acrylic acid esters such as poly-2-nitro-2-methylpropyl methacrylate, poly-1,1-diethylpropyl methacrylate, and polymethyl methacrylate can be used. Furthermore, epoxy acrylate, urethane acrylate, polyether acrylate, polyester acrylate, or the like can be used as a copolymerizable monomer other than acrylic resin and acrylic.

  As a method for forming a resin layer having a pattern opposite to that of the conductive mesh on a substrate using a peelable resin, a printing method, a photolithography method, or the like can be used. As a printing method, for example, various methods such as screen printing, inkjet, intaglio printing, relief printing, offset printing, gravure printing, flexographic printing, and the like can be used.

  As the photolithography method, the photolithography method described in the pattern processing method using the above-described etching method can be used.

  In the electroconductive mesh concerning this invention, when using copper as a metal layer (A), in order to improve the adhesiveness of a metal layer (A) and a base material, a base material and a metal layer (A) are used. It is preferable to arrange a nickel layer having a thickness of 5 to 100 nm between them. This nickel layer is preferably formed by the vapor deposition method described above. This nickel layer is patterned in the same way when the metal layer is patterned, and constitutes a part of the conductive mesh.

  In the present invention, the line width of the conductive mesh is preferably in the range of 3 to 30 μm, more preferably in the range of 5 to 20 μm, and particularly preferably in the range of 5 to 12 μm. The pitch of the conductive mesh is preferably in the range of 50 to 500 μm, more preferably in the range of 80 to 400 μm, and particularly preferably in the range of 100 to 300 μm. Here, the pitch of the conductive mesh means the pitch of the openings of the conductive mesh. Specifically, the center of gravity of one opening and an adjacent opening sharing one side with this opening. Is the distance between. As the conductive mesh, a grid-like mesh pattern with square openings is generally used, but in the case of a grid-like conductive mesh with square openings, the pitch is the distance between adjacent fine lines. (Distance between two sides of a square facing each other).

The shape of the mesh pattern of the conductive mesh (the shape of the opening) is, for example, a lattice mesh pattern formed of a quadrangle such as a square, a rectangle, or a rhombus, a triangle, a pentagon, a hexagon, an octagon, or a dodecagon. Examples thereof include a mesh pattern made of a polygon, a mesh pattern made of a circle and an ellipse, a mesh pattern made of the composite shape, and a random mesh pattern. Among these, a lattice mesh pattern made of a tetragon and a mesh pattern made of a hexagon are preferable, and a regular mesh pattern is more preferably used.
(Surface layer)
Next, the surface layer laminated on the conductive mesh will be described. The surface layer according to the present invention is preferably a layer having an optical function and / or a surface protection function. Examples of the optical function include an antireflection function and an antiglare function, and examples of the surface protection function include a hard coat function and an antifouling function.

  Further, the surface layer of the present invention is a layer for suppressing a decrease in visibility of a display image due to the metallic gloss of the conductive mesh. As described above, the ultrathin layer (B) alone is not sufficient to prevent the metallic luster of the metal layer (A) constituting the conductive mesh and suppress the decrease in the visibility of the display image, In order to compensate for this, the surface layer of the present invention, that is, the surface layer containing translucent particles having an average particle diameter of 1 to 20 μm is disposed.

  The surface layer according to the present invention may be composed of a single layer or a plurality of layers. Moreover, you may be comprised by the layer which has a some function together.

  The surface layer according to the present invention preferably includes at least a hard coat layer. In this case, it may be constituted only by a hard coat layer, or may be a laminated constitution with other functional layers such as an antireflection layer, an antiglare layer, an antifouling layer and the like. When the surface layer has a plurality of laminated structures, the hard coat layer is preferably disposed at a position closest to the conductive mesh (that is, the hard coat layer is preferably formed so as to cover the conductive mesh). .)

  The surface layer according to the present invention contains translucent particles having an average particle diameter of 1 to 20 μm. Such translucent particles include inorganic and organic particles, but those formed of organic materials are preferred. Specific examples of the translucent particles include silica beads for inorganic systems and plastic beads for organic systems.

  Examples of plastic beads include acrylic, styrene, melamine, acrylic-styrene, polycarbonate, and polyethylene. In the present invention, it is preferable to use an acrylic system having excellent transparency.

  Further, the shape of the translucent particles is preferably spherical (true spherical, elliptical, etc.), more preferably true spherical.

  The average particle diameter of the translucent particles contained in the surface layer is preferably 1.5 to 15 μm, more preferably 2 to 12 μm. Here, the average particle diameter of the translucent particles is a volume-based volume average diameter, and is measured by taking an optical micrograph of the filter sample and analyzing the microphotograph.

  The content of the translucent particles in the surface layer is preferably in the range of 2 to 20% by mass, more preferably in the range of 3 to 15% by mass, and further 3 to 12% by mass with respect to 100% by mass of all components of the surface layer. The range of 3-10 mass% is especially preferable. In addition, also when a surface layer is comprised by multiple layers, the above-mentioned quantity range is preferable with respect to 100 mass% of all the components total of all the layers which comprise a surface layer. Further, even when the surface layer is composed of a plurality of layers, and the translucent particles are contained only in a part of the plurality of layers and the translucent particles are not contained in the other layers, the surface layer The above-mentioned amount range is preferable with respect to a total of 100% by mass of all components of all the layers constituting the layer.

  As described above, the surface layer preferably includes at least a hard coat layer, and the hard coat layer preferably includes the above-described translucent particles. When the hard coat layer contains the light transmissive particles, the content of the light transmissive particles is preferably in the range of 2 to 20% by weight with respect to 100% by weight of all the components of the hard coat layer, and 3 to 15% by weight. The range is more preferable, the range of 3 to 12% by mass is further preferable, and the range of 3 to 10% by mass is particularly preferable.

  In the present invention, the center line average roughness Ra of the surface layer is preferably in the range of 300 to 1000 nm, more preferably in the range of 400 to 900 nm, and particularly preferably in the range of 500 to 800 nm. The center line average roughness Ra of the surface layer is preferably controlled by adjusting the average particle diameter and the content of the above-described translucent particles within the above range.

  The surface layer according to the present invention preferably further contains a colorant. By including a colorant in the surface layer, it is possible to further improve the decrease in visibility due to the metallic luster of the conductive mesh. As such a colorant, it is preferable to use a pigment, a dye, a dye, or the like that can give a neutral color to the surface layer. The colorant is preferably a black one, and for example, carbon black, graphite, black chrome, titanium black and the like are preferably used. Also, two or more of the following red pigments, green pigments, and blue pigments can be mixed and used.

  As a red pigment, Color Index No. Pigment Red (hereinafter abbreviated as PR) 9, 97, 122, 123, 149, 168, 177, 180, 192, 215, 254, and the like, and Color Index No. Pigment Green (hereinafter abbreviated as PG) 7, 36, and the like, as a blue pigment, Color Index No. Pigment blue (hereinafter abbreviated as PB) 15: 3, 15: 4, 15: 6, 21, 22, 60, 64, and the like.

  As the particle diameter of the above-mentioned black, red, green, and blue pigments, the average primary particle diameter is preferably in the range of 5 to 400 nm, more preferably in the range of 10 to 200 nm, particularly 10 to 100 nm. A range is preferred. Here, the average primary particle diameter can be measured using a dynamic light scattering method. Specifically, it can be measured using “Nanotrack” manufactured by Nikkiso Co., Ltd.

  The content of the colorant is suitably in the range of 0.01 to 10% by weight, preferably in the range of 0.05 to 8% by weight, particularly 0.05 to 100% by weight of all components of the surface layer. A range of ˜5 mass% is preferred. In addition, also when a surface layer is comprised by multiple layers, the above-mentioned quantity range is preferable with respect to 100 mass% of all the components total of all the layers which comprise a surface layer. In addition, the surface layer is composed of a plurality of layers, and even if the colorant is contained only in some of the plurality of layers and the colorant is not contained in the other layers, all that constitute the surface layer The above-mentioned amount range is preferable with respect to a total of 100% by mass of all the components of the layer.

  In the present invention, the visible light transmittance of the entire display filter is preferably adjusted to a range of 25 to 65%, and more preferably adjusted to a range of 30 to 60%. Therefore, the amount of the colorant added to the surface layer is also preferably adjusted so that the luminous transmittance of the entire display filter is in the above range.

  The colorant can be contained in any one of the layers constituting the surface layer. When the surface layer has a plurality of structures, it can be contained in a plurality of layers. The colorant is preferably contained in the hard coat layer.

  When the colorant is contained in the hard coat layer, the content of the colorant is suitably in the range of 0.01 to 10% by mass with respect to 100% by mass of all components of the hard coat layer, and 0.05 to 8% by mass. % Is preferable, and a range of 0.05 to 5% by mass is particularly preferable.

  Since the conductive mesh of the present invention does not form a complete blackened layer (blackened layer by oxidation treatment or the like) on the surface of the conductive mesh as in the prior art, as a result of the metallic luster of the conductive mesh In some cases, external light may be reflected. This reflection of external light can be effectively suppressed by laminating the above-described surface layer of the present invention on a conductive mesh.

As described above, the thickness of the conductive mesh according to the present invention is preferably 4 μm or less, and this thickness is smaller than the thickness of a conventional general conductive mesh (about 10 μm). Therefore, the coating property of the surface layer formed on the conductive mesh is improved.
In the present invention, the thickness of the surface layer is preferably in the range of 1 to 15 μm, more preferably in the range of 2 to 12 μm, and particularly preferably in the range of 2.5 to 10 μm.

(Hard coat layer)
The surface layer according to the present invention preferably includes at least a hard coat layer. Hereinafter, the hard coat layer that can be used in the present invention will be described in detail.

  In the present invention, the hard coat layer preferably has a high hardness from the viewpoint of enhancing the scratch resistance of the display filter. As for the hardness of the hard coat layer, the pencil hardness defined by JIS K5600-5-4 (1999) is preferably H or more, and more preferably 2H or more. The upper limit is about 9H.

  The hard coat layer in the present invention can contain monomers, oligomers and polymers as the resin component. Examples of such resin components include thermosetting resins or photocurable resins such as acrylic resins, silicon resins, melamine resins, urethane resins, alkyd resins, and fluorine resins. In view of the balance of productivity and the like, an acrylate resin is preferably applied.

  As said acrylate-type curable resin, it is preferable that it is a hardening composition which has a polyfunctional acrylate as a main component. Examples of the polyfunctional acrylate include monomers or oligomers and prepolymers having 3 or more (preferably 4 or more, more preferably 5 or more) (meth) acryloyloxy groups per molecule. Here, the (meth) acryloyloxy group is an abbreviation of the acryloyloxy group and the (meth) acryloyloxy group. Hereinafter, “(meta)...” Has the same meaning as described above.

  Specific examples include pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol tri (meth) acrylate, dipentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, Dipentaerythritol hexa (meth) acrylate, trimethylolpropane tri (meth) acrylate, trimethylolpropane EO modified tri (meth) acrylate, pentaerythritol triacrylate hexamethylene diisocyanate urethane prepolymer, pentaerythritol triacrylate toluene diisocyanate urethane prepolymer, Pentaerythritol triacrylate isophorone diisocyanate urethane prepolymer Or the like can be used. These may be used alone or in combination of two or more.

  These monomers, oligomers and prepolymers having 3 or more (meth) acryloyloxy groups in one molecule are used in an amount of 50% by mass with respect to 100% by mass of all components (excluding organic solvents) of the hard coat layer. The range of -90 mass% is preferable, and the range of 50-80 mass% is more preferable.

  In addition to the above-mentioned compounds, it is preferable to use one or two functional acrylates together for the purpose of relaxing the rigidity of the hard coat layer or reducing shrinkage during curing. The monomer having 1 to 2 ethylenically unsaturated double bonds in one molecule can be used without particular limitation as long as it is a normal monomer having radical polymerizability.

  As the compound having two ethylenically unsaturated double bonds in the molecule, the following (a) to (f) (meth) acrylates and the like can be used.

  (A) C2-C12 alkylene glycol (meth) acrylic acid diesters: ethylene glycol di (meth) acrylate, propylene glycol di (meth) acrylate, 1,4-butanediol di (meth) acrylate, neopentyl Glycol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate.

  (B) (Meth) acrylate diesters of polyoxyalkylene glycol: diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, tetraethylene glycol di (meth) acrylate, dipropylene glycol di (meth) acrylate, Polyethylene glycol di (meth) acrylate, polypropylene glycol di (meth) acrylate.

  (C) Polyhydric alcohol (meth) acrylic acid diesters: pentaerythritol di (meth) acrylate.

  (D) (Meth) acrylic acid diesters of ethylene oxide and propylene oxide adducts of bisphenol A or bisphenol A hydride: 2,2′-bis (4-acryloxyethoxyphenyl) propane, 2,2′-bis ( 4-acryloxypropoxyphenyl) propane.

  (E) A terminal isocyanate group-containing compound obtained by reacting a diisocyanate compound and two alcoholic hydroxyl group-containing compounds in advance with a hydroxyl group-containing (meth) acrylate further reacted with two ( Urethane (meth) acrylates having a (meth) acryloyloxy group.

  (F) Epoxy (meth) acrylates having two (meth) acryloyloxy groups in a molecule obtained by reacting a compound having two epoxy groups in the molecule with acrylic acid or methacrylic acid.

  Compounds having one ethylenically unsaturated double bond in the molecule include methyl (meth) acrylate, ethyl (meth) acrylate, n- and i-propyl (meth) acrylate, n-, sec-, and t. -Butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate, methoxyethyl (meth) acrylate, ethoxyethyl (meth) acrylate, hydroxyethyl (meth) acrylate, polyethylene glycol Mono (meth) acrylate, polypropylene glycol mono (meth) acrylate, glycidyl (meth) acrylate, tetrahydrofurfuryl (meth) acrylate, N-hydroxyethyl (meth) acrylamide, N-vinylpyrrolidone, - vinyl-3-methylpyrrolidone, or the like can be used N- vinyl-5-methyl pyrrolidone. These monomers may be used alone or in combination of two or more.

  The use ratio of the monomer having 1 to 2 ethylenically unsaturated double bonds in one molecule is preferably in the range of 10 to 40% by mass with respect to 100% by mass of all components of the hard coat layer. The range of 20-40 mass% is more preferable.

  Further, as a modifier of the hard coat layer, an antifoaming agent, a thickening agent, an antistatic agent, an organic polymer compound, an ultraviolet absorber, a light stabilizer, a dye, a pigment or a stabilizer can be used. Can be contained in the hard coat layer within a range not impairing the reaction due to the active ray or heat.

  In the present invention, as a method of curing the hard coat layer, for example, a method of irradiating ultraviolet rays or the like as active rays, a high temperature heating method, or the like can be used. When these methods are used, the hard coat layer is used. It is desirable to add a photopolymerization initiator, a thermal polymerization initiator, or the like.

  Specific examples of the photopolymerization initiator include acetophenone, 2,2-diethoxyacetophenone, p-dimethylacetophenone, p-dimethylaminopropiophenone, benzophenone, 2-chlorobenzophenone, 4,4′-dichlorobenzophenone, 4,4′-bisdiethylaminobenzophenone, Michler's ketone, benzyl, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, methyl benzoyl formate, p-isopropyl-α-hydroxyisobutylphenone, α-hydroxyisobutylphenone, 2, Carbonyl compounds such as 2-dimethoxy-2-phenylacetophenone and 1-hydroxycyclohexyl phenyl ketone, tetramethylthiuram monosulfide, tetramethylthio Sulfur compounds such as uranium disulfide, thioxanthone, 2-chlorothioxanthone, and 2-methylthioxanthone can be used. These photopolymerization initiators may be used alone or in combination of two or more. Moreover, as a thermal polymerization initiator, a peroxide compound such as benzoyl peroxide or di-t-butyl peroxide can be used.

  The use amount of the photopolymerization initiator or thermal polymerization initiator is suitably in the range of 0.01 to 10% by mass with respect to 100% by mass of all components of the hard coat layer. When an electron beam or gamma ray is used as a curing means, it is not always necessary to add a polymerization initiator. Further, when thermosetting at a high temperature of 200 ° C. or higher, it is not always necessary to add a thermal polymerization initiator.

  A thermal polymerization inhibitor such as hydroquinone, hydroquinone monomethyl ether or 2,5-t-butyl hydroquinone can be added to the hard coat layer in order to prevent thermal polymerization during production and dark reaction during storage. The addition amount of the thermal polymerization inhibitor is preferably in the range of 0.005 to 0.05% by mass with respect to 100% by mass of all components of the hard coat layer.

  Examples of the active rays used as necessary in the present invention include electromagnetic waves that polymerize acrylic vinyl groups such as ultraviolet rays, electron beams and radiation (α rays, β rays, γ rays, etc.). Ultraviolet light is convenient and preferred. As the ultraviolet ray source, an ultraviolet fluorescent lamp, a low pressure mercury lamp, a high pressure mercury lamp, an ultra high pressure mercury lamp, a xenon lamp, a carbon arc lamp, or the like can be used. Moreover, when irradiating actinic radiation, if it irradiates under a low oxygen concentration, it can harden | cure efficiently. Furthermore, the electron beam system is advantageous in that the apparatus is expensive and needs to be operated under an inert gas, but it is not necessary to include a photopolymerization initiator or a photosensitizer in the coating layer. is there.

  As the heat necessary for the thermosetting used in the present invention, steam heater, electric heater, infrared heater or far-infrared heater is used. The heat given by spraying on the base material and the coating film using is used. Among them, heat by air heated to 200 ° C. or higher is preferable, more preferably heat by nitrogen heated to 200 ° C. or higher. It is preferable because the curing rate is high.

  As a method for curing the hard coat layer, from the viewpoint of imparting high hardness to the hard coat layer and from the viewpoint of productivity, a method of irradiating actinic rays is preferable, and a method of irradiating ultraviolet rays is particularly preferable. Therefore, the hard coat layer of the present invention is preferably an ultraviolet curable hard coat layer.

  The hard coat layer can also serve as a high refractive index layer described later by increasing the refractive index. As means for increasing the refractive index of the hard coat layer, the hard coat layer contains metal oxide fine particles having an average primary particle diameter of about 1 to 50 nm, or a resin containing molecules and atoms of a high refractive index component. The method of containing is mentioned. Examples of the metal oxide fine particles include tin-containing antimony oxide particles (ATO), zinc-containing antimony oxide particles, tin-containing indium oxide particles (ITO), zinc oxide / aluminum oxide particles, and antimony oxide particles.

The thickness of the hard coat layer is preferably in the range of 1 to 15 μm, more preferably in the range of 2 to 12 μm, and particularly preferably in the range of 2.5 to 10 μm.
(Other functional layers constituting the surface layer)
As described above, in the surface layer of the present invention, other functional layers such as an antireflection layer and an antifouling layer can be laminated on the hard coat layer. Further, an antireflection function and an antifouling function can be imparted to the hard coat layer.
(Antireflection layer)
Specifically, the antireflection layer is a thin film of fluorine-based transparent polymer resin, magnesium fluoride, silicone resin, or silicon oxide having a refractive index of 1.5 or less, preferably 1.4 or less in the visible region. Etc., for example, a single layer formed with an optical film thickness of ¼ wavelength, or inorganic compounds such as metal oxides, fluorides, silicides, nitrides, sulfides or silicone resins having different refractive indexes, Examples thereof include those obtained by laminating two or more thin films of organic compounds such as acrylic resin and fluorine resin.

  As a configuration in which the antireflection performance and the cost are balanced, a configuration in which a low refractive index layer and a high refractive index layer are laminated from the outermost layer is preferable, but in the present invention, even if the high refractive index layer is not laminated. In that case, only the low refractive index layer is used.

  The refractive index of the high refractive index layer is preferably in the range of 1.5 to 1.8, more preferably in the range of 1.55 to 1.7. The refractive index of the low refractive index layer is preferably in the range of 1.25 to 1.45, more preferably in the range of 1.3 to 1.4.

  The above refractive index is obtained by applying a coating of a layer to be measured on a silicon wafer, drying it, and curing it as necessary to form a coating film. It can obtain | require by measuring the refractive index in 633nm with a measuring apparatus (Nikon Co., Ltd. product: NPDM-1000).

(High refractive index layer)
The high refractive index layer uses a resin component such as an acrylic resin, urethane resin, melamine resin, organic silicate compound, silicone resin, phosphorus-containing resin, sulfide-containing resin, halogen-containing resin alone or in a mixed system. However, it is particularly preferable to use a silicone resin or an acrylic resin from the viewpoints of hardness and durability. Furthermore, from the viewpoint of curability, flexibility, and productivity, an active energy ray-curable acrylic resin or a thermosetting acrylic resin is preferable. In particular, a (meth) acrylate-based resin is preferable because radical polymerization easily occurs upon irradiation with active energy rays and the solvent resistance and hardness of the formed film are improved.

Examples of such (meth) acrylate resins include pentaerythritol tri (meth) acrylate, trimethylolpropane tri (meth) acrylate, glycerol tri (meth) acrylate, ethylene-modified trimethylolpropane tri (meth) acrylate, and tris- (2- Trifunctional (meth) acrylate such as hydroxyethyl) -isocyanuric acid ester tri (meth) acrylate, tetrafunctional such as pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate The above (meth) acrylate etc. are mentioned.
In the high refractive index layer, a (meth) acrylate compound (monomer) having an acidic functional group such as a carboxyl group, a phosphoric acid group, or a sulfonic acid group can be used. Specifically, as the acidic functional group-containing monomer, unsaturated carboxylic acid such as acrylic acid, methacrylic acid, crotonic acid, 2- (meth) acryloyloxyethyl succinic acid, 2- (meth) acryloyloxyethylphthalic acid, Examples thereof include phosphoric acid (meth) acrylic acid esters such as mono (2- (meth) acryloyloxyethyl) acid phosphate and diphenyl-2- (meth) acryloyloxyethyl phosphate, and 2-sulfoester (meth) acrylate. In addition, a (meth) acrylate compound having a polar bond such as an amide bond, a urethane bond, or an ether bond can be used.

  The high refractive index layer may contain an initiator in order to advance curing of the applied resin component. As the initiator, the applied resin component initiates or accelerates polymerization and / or crosslinking reaction by radical reaction, anion reaction, cation reaction, etc., and various conventionally known photopolymerization initiators can be used. is there.

  Specific examples of such photopolymerization initiators include sulfides such as sodium methyldithiocarbamate sulfide, diphenyl monosulfide, dibenzothiazoyl monosulfide and disulfide, thioxanthone, 2-ethylthioxanthone, 2-chlorothioxanthone, Thioxanthone derivatives such as 2,4-diethylthioxanthone, azo compounds such as hydrazone and azobisisobutyronitrile, diazo compounds such as benzenediazonium salt, benzoin, benzoin methyl ether, benzoin ethyl ether, benzophenone, dimethylaminobenzophenone Michler's ketone, benzylanthraquinone, t-butylanthraquinone, 2-methylanthraquinone, 2-ethylanthraquinone, 2-aminoanthraquinone, Aromatic carbonyl compounds such as -chloroanthraquinone, dialkylaminobenzoic acid esters such as methyl p-dimethylaminobenzoate, ethyl p-dimethylaminobenzoate, butyl D-dimethylaminobenzoate, isopropyl p-diethylaminobenzoate, Peroxides such as benzoyl peroxide, di-t-butyl peroxide, dicumyl peroxide, cumene hydroperoxide, 9-phenylacridine, 9-p-methoxyphenylacridine, 9-acetylaminoacridine, benzacridine, etc. Acridine derivatives, phenazine derivatives such as 9,10-dimethylbenzphenazine, 9-methylbenzphenazine, 10-methoxybenzphenazine, and 6,4 ′, 4 ″ -trimethoxy-2,3-diphenylquinoxaline Quinoxaline derivatives, 2,4,5-triphenylimidazolyl dimer, 2-nitrofluorene, 2,4,6-triphenylpyrylium tetrafluoride boron salt, 2,4,6-tris (trichloromethyl) ) -1,3,5-triazine, 3,3′-carbonylbiscoumarin, thiomichler ketone, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, oligo (2-hydroxy-2-methyl-1- ( 4- (1-methylvinyl) phenyl) propanone, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) -butanone, and the like.

  In the high refractive index layer, an amine compound may coexist in the photopolymerization initiator in order to prevent a decrease in sensitivity due to oxygen inhibition of the initiator. Such an amine compound is not particularly limited as long as it is a non-volatile compound such as an aliphatic amine compound or an aromatic amine compound. For example, triethanolamine, methyldiethanolamine and the like are preferable.

The high refractive index layer preferably contains metal oxide fine particles having a refractive index of 1.6 or more. As a result, a high refractive index can be achieved and an antistatic effect can be obtained.
As the metal oxide fine particles, tin-containing antimony oxide particles (ATO), zinc-containing antimony oxide particles, tin-containing indium oxide particles (ITO), zinc oxide / aluminum oxide particles, antimony oxide particles, etc. are preferable, and tin-containing oxidation is more preferable. Indium particles (ITO) and tin-containing antimony oxide particles (ATO).

  The content of the metal oxide fine particles in the high refractive index layer is preferably in the range of 0.1 to 20 parts by mass with respect to 100 parts by mass of the resin component.

  The average primary particle diameter of the metal oxide fine particles is preferably 1 to 50 nm. Here, the average primary particle diameter can be measured using a dynamic light scattering method. Specifically, it can be measured using “Nanotrack” manufactured by Nikkiso Co., Ltd.

  The thickness of the high refractive index layer is preferably 200 nm or less, and more preferably 150 nm or less. The lower limit of the thickness is about 20 nm.

(Low refractive index layer)
The low refractive index layer is composed of a fluorine-containing polymer, a part of (meth) acrylic acid or a fully fluorinated alkyl ester, an organic material such as fluorine-containing silicone, and an inorganic material such as MgF ₂ , CaF ₂ , and SiO _2. Can do. Hereinafter, preferred embodiments of the low refractive index layer will be exemplified.

As a preferred embodiment of the low refractive index layer, a method of forming a thin film such as MgF ₂ or SiO ₂ by a vapor deposition method such as vacuum deposition, sputtering, or plasma CVD, or a sol solution containing SiO ₂ sol from SiO ₂ Examples thereof include a method for forming a gel film.

  As another preferred embodiment of the low refractive index layer, a constitution mainly composed of a siloxane polymer bonded to silica-based fine particles can be employed. The term “bond” as used herein means a state in which the silica component of the silica-based fine particles and the siloxane polymer in the matrix are reacted and homogenized. A siloxane polymer formed by combining with silica-based fine particles once forms a silanol compound by a known hydrolysis reaction with a polyfunctional silane compound in a solvent and an acid catalyst in the presence of the silica-based fine particles. It can be obtained by utilizing the reaction.

  The polyfunctional silane compound preferably includes a polyfunctional fluorine-containing silane compound from the viewpoint of low refractive index and antifouling properties, and includes trifluoromethylmethoxysilane, trifluoromethylethoxysilane, and trifluoropropyltrimethoxy. Trifunctional fluorine-containing silane compounds such as silane, trifluoropropyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, tridecafluorooctyltrimethoxysilane, heptadecafluorodecyltriethoxysilane, tridecafluorooctyltriethoxysilane, Examples include bifunctional fluorine-containing silane compounds such as heptadecafluorodecylmethyldimethoxysilane, all of which are preferably used. From the viewpoint of surface hardness, trifluoromethylmethoxysilane, trifluoro Chill silane, trifluoropropyl trimethoxy silane, trifluoropropyl triethoxy silane, more preferably.

  A polyfunctional fluorine-free silane compound can be used as the polyfunctional silane compound. Examples of such polyfunctional fluorine-free silane compounds include vinyltrimethoxysilane, vinyltriethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropyltriethoxysilane, methyltrimethoxysilane, and methyltriethoxy. Silane, hexyltrimethoxysilane, octadecyltrimethoxysilane, octadecyltriethoxysilane, phenyltrimethoxysilane, phenyltriethoxysilane, 3-aminopropyltriethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethoxy Trifunctional silanes such as silane, 3-chloropropyltrimethoxysilane, 3- (N, N-diglycidyl) aminopropyltrimethoxysilane, 3-glycidoxysipropyltrimethoxysilane Compound, dimethyldimethoxysilane, dimethyldiethoxysilane, diphenyldimethoxysilane, diphenyldiethoxysilane, methylphenyldimethoxysilane, methylvinyldimethoxysilane, methylvinyldiethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 3-amino Propylmethyldimethoxysilane, N- (2-aminoethyl) -3-aminopropylmethyldimethoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropylmethyldiethoxysilane, cyclohexylmethyldimethoxysilane, 3-methacryloxypropyldimethoxy Bifunctional silane compounds such as silane and octadecylmethyldimethoxysilane, tetrafunctional silane compounds such as tetramethoxysilane and tetraethoxysilane, etc. All of these are preferably used. From the viewpoint of surface hardness, vinyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, methyltrimethoxysilane, methyltriethoxysilane, phenyltrimethoxysilane, and phenyltriethoxysilane are preferable. More preferable.

  The silica-based fine particles are preferably silica-based fine particles having an average particle diameter of 1 nm to 50 nm. Further, among these silica-based fine particles, those having a structure having a cavity inside are particularly preferably used in order to lower the refractive index.

  Examples of such silica-based fine particles having cavities therein include silica-based fine particles having a hollow portion surrounded by an outer shell, porous silica-based fine particles having a large number of hollow portions, and the like. As such an example, for example, it can be produced by the method disclosed in Japanese Patent No. 3272111, and the volume occupied by the cavities inside the fine particles, that is, the porosity of the fine particles is preferably 5% or more, more preferably 30% or more. preferable. The porosity can be measured using, for example, a mercury porosimeter (trade name: Bore Sizer 9320-PC2, manufactured by Shimadzu Corporation). Further, the refractive index of the fine particles themselves is preferably 1.20 to 1.40, more preferably 1.20 to 1.35. Examples of such silica-based fine particles include those disclosed in Japanese Patent Application Laid-Open No. 2001-233611, and those commercially available such as Japanese Patent No. 3272111.

  The thickness of the low refractive index layer is preferably 200 nm or less, and more preferably 150 nm or less. The lower limit of the thickness is about 20 nm.

(Anti-fouling layer)
The surface layer according to the present invention can be imparted with an antifouling function. The antifouling function may be imparted to the hard coat layer or the antireflection layer, or a new antifouling layer may be laminated.
The antifouling function prevents the oily substances from adhering to the display filter when touched with a finger, prevents dust and dirt in the atmosphere from adhering, or It is a layer for facilitating removal even if attached. As such an antifouling layer, for example, a fluorine coating agent, a silicone coating agent, a silicon / fluorine coating agent, or the like is used. When the antifouling layer is newly provided, the thickness of the antifouling layer is preferably in the range of 1 to 10 nm.

(Base material)
A base material is used for the display filter of the present invention, and the filter is preferably composed of only one base material. A plastic film is preferably used as the substrate according to the present invention.

  Examples of the resin constituting the plastic film include polyester resins such as polyethylene terephthalate and polyethylene naphthalate, cellulose resins such as triacetyl cellulose, polyolefin resins such as polyethylene, polypropylene, and polybutylene, acrylic resins, polycarbonate resins, arton resins, and epoxy resins. , Polyimide resin, polyetherimide resin, polyamide resin, polysulfone resin, polyphenylene sulfide resin, polyether sulfone resin, and the like. Among these, a polyester resin, a polyolefin resin, and a cellulose resin are preferable, and a polyester resin is particularly preferably used. The thickness of the plastic film is suitably in the range of 50 to 300 μm, but is particularly preferably in the range of 80 to 250 μm from the viewpoint of cost and ensuring the rigidity of the display filter. Moreover, as a plastic film, the laminated | multilayer film which laminated | stacked the several layer can also be used.

  The plastic film used in the present invention is provided with a primer layer (easy-adhesive layer, undercoat layer) for enhancing the adhesion (adhesive strength) to the conductive mesh, the surface layer or the near-infrared shielding layer described later. Is preferred.

(Display filter)
The display filter of the present invention is preferably further provided with a layer having at least one function selected from a near-infrared shielding function, a color tone adjustment function, or a visible light transmittance adjustment function.

  The near-infrared shielding function is preferably adjusted so that the maximum value of light transmittance in the wavelength range of 800 to 1100 nm is 15% or less. The near-infrared shielding function may be imparted by kneading and dispersing a near-infrared absorber in a plastic film, a functional layer, or an adhesive layer described later, or a near-infrared shielding layer may be newly provided. The near-infrared shielding function can be imparted by using a near-infrared absorbing agent or by providing a layer that reflects near-infrared rays by metal free electrons such as a conductive thin film.

  In the present invention, a near-infrared shielding layer formed by applying and drying a paint in which a near-infrared absorber is dispersed or dissolved in a resin binder is used, or the near-infrared absorber is applied to a hard coat layer or an adhesive layer described later. The mode of inclusion is preferably used.

  Near-infrared absorbers include organic near-infrared absorbers such as phthalocyanine compounds, anthraquinone compounds, dithiol compounds, diimonium compounds, or titanium oxide, zinc oxide, indium oxide, tin oxide, zinc sulfide, cesium-containing oxides An inorganic near infrared absorber such as tungsten can be used.

  When the above-described near-infrared shielding layer is newly provided, it can be provided by coating the base material between the base material and the conductive mesh or on the opposite surface of the base material from the conductive mesh. .

  In the case where the near infrared shielding function is imparted to the viewer side from the base material, it is preferable to use an inorganic near infrared absorber having excellent light resistance.

  The color tone adjustment function is a function for improving color purity and whiteness by absorbing light of a specific wavelength emitted from the display. In particular, it is preferable to shield orange light that reduces the color purity of red light emission, and it is preferable to include a dye having an absorption maximum in a wavelength range of 580 to 620 nm. Furthermore, it is preferable to contain a dye having an absorption maximum at a wavelength of 480 to 500 nm in order to improve whiteness. For the color tone adjustment function, a layer containing a dye that absorbs light having the above-described wavelength may be newly provided, or a dye may be contained in the above-described near-infrared shielding layer, hard coat layer, or adhesive layer described later. .

  The visible light transmittance adjusting function is a function for adjusting the visible light transmittance, and can be adjusted by containing a dye or a pigment. The visible light transmittance adjusting function may be imparted to the base material, the near-infrared shielding layer, the hard coat layer, or an adhesive layer described later, or a transmittance adjusting layer may be newly provided.

  When a layer having the above-described color tone adjusting function and a layer having a visible light transmittance adjusting function are newly provided, these layers are between the base material and the conductive mesh, or the conductive mesh with respect to the base material. It can be provided on the opposite side.

The display filter of the present invention can be attached to the display directly or via a known high-rigidity substrate such as a glass plate, an acrylic plate, or a polycarbonate plate. The display filter of the present invention is preferably provided with an adhesive layer for adhering to a display or a highly rigid substrate.
The high-rigidity substrate is usually a substrate having a thickness of 0.5 to 5 mm, and the high-rigidity substrate is not included in the base material constituting the display filter of the present invention.

  As described above, the adhesive layer can be provided with a near-infrared shielding function, a color tone adjusting function, or a visible light transmittance adjusting function. Moreover, it is a preferable aspect to provide the adhesive layer with an impact relaxation function for protecting the display from impact. In order to impart an impact relaxation function to the adhesive layer, the thickness of the adhesive layer is preferably 100 μm or more, and more preferably 300 μm or more. The upper limit thickness is preferably 3000 μm or less in consideration of the coating suitability of the adhesive layer.

  A well-known adhesive material or an adhesive material can be used for an adhesive layer. Examples of the adhesive material include acrylic, silicone, urethane, polyvinyl butyral, and ethylene-vinyl acetate. Adhesives include bisphenol A type epoxy resins, tetrahydroxyphenylmethane type epoxy resins, novolac type epoxy resins, resorcin type epoxy resins, polyolefin type epoxy resins and other epoxy resins, natural rubber, polyisoprene, poly-1, 2- (Di) enes such as butadiene, polyisobutene, polybutene, poly-2-heptyl-1,3-butadiene, poly-1,3-butadiene, polyoxyethylene, polyoxypropylene, polyvinyl ethyl ether, polyvinyl hexyl ether, etc. Polyesters such as polyethers, polyvinyl acetate, polyvinyl propionate, polyurethane, ethyl cellulose, polyvinyl chloride, polyacrylonitrile, polymethacrylonitrile, polysulfone, phenoxy resin Etc., and the like.

Hereinafter, some examples of the configuration of the display filter of the present invention will be exemplified, but the present invention is not limited thereto. In the following configuration, the adhesive layer is on the display side.
1) Adhesive layer / Near-infrared shielding layer / Substrate / conductive mesh / hard coat layer 2) Adhesive layer / Near-infrared shielding layer / Substrate / conductive mesh / hard coat layer / antireflection layer 3) Adhesive layer / base Material / conductive mesh / hard coat layer 4) Adhesive layer / base material / conductive mesh / hard coat layer / antireflection layer The near-infrared shielding layers of the above 1) and 2) also have a color tone adjusting function. The adhesive layers 3) and 4) have both a near-infrared shielding function and a color tone adjustment function. Further, the hard coat layers 1) and 3) can have an antiglare function.

EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited by these Examples. In addition, the evaluation method of each sample of the filter for a display produced in the present Example is shown below.
(1) Centerline average roughness Ra of the surface layer
The center line average roughness Ra of the surface layer was measured using a surface roughness measuring instrument SE-3400 (manufactured by Kosaka Laboratory Ltd.).

Measurements were made at any five or more locations from one 20 cm × 20 cm sample, and the average value was taken as the Ra value of the surface layer.
·Measurement condition:
Feeding speed: 0.5mm / S
Cut-off value λc;
When Ra is 20 nm or less, λc = 0.08 mm
When Ra is greater than 20 nm and less than or equal to 100 nm, λc = 0.25 mm
When Ra is greater than 100 nm and less than or equal to 2000 nm, λc = 0.8 mm
Evaluation length: 8mm
In the measurement under the above measurement conditions, first, the measurement is performed with the cut-off value λc = 0.8 mm. As a result, when Ra is larger than 100 nm, the Ra is adopted. On the other hand, if Ra is 100 nm or less as a result of the above measurement, the measurement is performed again at λc = 0.25 mm. If Ra is larger than 20 nm, Ra is adopted. On the other hand, if Ra is 20 nm or less as a result of the re-measurement, measurement is performed at λc = 0.08 mm, and the Ra is adopted.
Ra: A parameter defined as Ra by a surface roughness measuring instrument SE-3400 (manufactured by Kosaka Laboratory Ltd.). It measured based on the method of JISB0601-1982.

(2) Conductive mesh thickness A sample cross section is cut out with a microtome, and the cross section is observed with an electrolytic emission scanning electron microscope (Hitachi S-800, acceleration voltage 26 kV, observation magnification 3000 times). The thickness of the sex mesh was measured.

  Measurement was made at an arbitrary five locations from one 20 cm × 20 cm sample, and the average value was taken as the thickness of the conductive mesh.

(3) Line width and pitch of conductive mesh Surface observation was performed at a magnification of 450 times using a Keyence digital microscope (VHX-200). Using the length measurement function, the pitch of the grid-like conductive mesh was measured. Measurements were made at 25 arbitrary locations from one 20 cm × 20 cm sample, and the average values were taken as the line width and pitch of the conductive mesh. Note that the pitch of the conductive mesh is a distance between the centers of gravity of an opening having a mesh structure and an adjacent opening sharing one side with the opening.

(4) Thickness of surface layer (hard coat layer) A sample cross section was cut out with a microtome, and the cross section was cut with an electrolytic emission scanning electron microscope (S-800, Hitachi, Ltd., acceleration voltage 15 kV, observation magnification 2000 times). Observe and measure the thickness of the surface layer.

  For each of the examples and comparative examples, 10 arbitrary positions were selected from one sample of 20 cm × 20 cm size, and as shown in FIG. 1, the lowest point of the surface layer (surface layer) existing on the arbitrary two openings The average value ((Hr1 + Hr2) / 2) of the distance between the lowermost point of the surface on the viewing side) and the lower part of the surface layer (surface on the base material side of the surface layer) The thickness (Hr). Hr1 and Hr2 are normal to the substrate surface.

  Further, when the particle concentration in the surface layer is low and only one convex structure can be seen in the microscope field of view, the convex part is arranged in the center of the field of view as shown in FIG. Using the thicknesses (Hr1, Hr2), the surface layer thickness is calculated by the same method.

If it is difficult to confirm the boundary between the lower part of the surface layer and the layer below it, select a place where it is easy to confirm.
(5) Average particle diameter of translucent particles A display filter sample is observed with an optical microscope (inspection / research microscope DMLB HC / Leica Microsystems) and a photomicrograph is taken (imaging conditions: transmission mode, magnification; 500 times, capacitor unit; set to the lowest position). Photographs are taken at any 10 locations of the filter, and in any 100 μm square area of the 10 photographs obtained, all the particles whose entire shape is present in the above area are measured on a scale and individually measured. The particle size (dm) (unit: μm) of the particles is obtained, and a data distribution obtained by rounding dm is used to obtain a number distribution for each 1 μm (the value (d) obtained by rounding dm is the number distribution for each 1 μm). (Representative value for each channel). Using this number distribution data, the volume-based volume average diameter is calculated by the following formula. When the particle shape is not circular, the maximum particle diameter is defined as the particle diameter of the particle.

D = Σ (v _n × d _n ) / Σ v _n
(V _n = (N _n × d _n ³ ) / Σ (N _n × d _n ³ ))
D: Average particle diameter of translucent particles (μm)
v _n : volume-based% of each channel in the number distribution every 1 μm
N _n : number in each channel
d _n: After removing the genuine entire filter from the display panel evaluation Plasma TV visibility representative value (6) the display image of each channel (Matsushita Electric Industrial Co., Ltd. of TH-42PX500), the following exemplary The samples prepared in the examples and comparative examples were placed directly on the panel so that the surface layer was on the viewing side. Furthermore, a three-wavelength fluorescent lamp (Neoline Rapid Master manufactured by Toshiba Lighting & Technology Corp .; three-wavelength daylight white FLR40S N-EDL / M) is used as external light, and the vertical illuminance and horizontal illuminance of the panel are 100 lux and 70 lux, respectively. It installed so that it might become.

Next, the visibility of the display image was visually evaluated according to the following criteria at a position 1.3 m away from the panel in a panel lighting state.
◎: The outline of the reflected image of the fluorescent lamp in the display image is not visible (very good)
○: The outline of the reflected image of the fluorescent lamp in the display image is unclear (good)
Δ: The outline of the reflected image of the fluorescent lamp on the display image is slightly blurred (possible)
×: The outline of the reflected image of the fluorescent lamp on the display image looks clear (impossible)
(7) Luminous transmittance With respect to the filter sample for display, using a spectrophotometer (manufactured by Shimadzu Corporation, UV3150PC), the transmittance for incident light from the observer side (resin layer side) is in a wavelength range of 300 to 1300 nm. Measure and obtain the luminous transmittance in the visible light wavelength region (380 to 780 nm).
Example 1
A display filter was prepared as follows.
<Production of conductive mesh>
On one side of an optical polyester film (Lumirror (registered trademark) QT96 manufactured by Toray Industries, Inc., thickness 100 μm), a nickel layer (thickness 0.02 μm) by vacuum deposition under a vacuum of 3 × 10 ⁻³ Pa at room temperature. ) Was formed. Furthermore, a copper layer (thickness 3 μm) to be a metal layer (A) was formed thereon by a vacuum vapor deposition method at a room temperature and under a vacuum of 3 × 10 ⁻³ Pa. Further, a copper nitride layer (0.02 μm) to be a layer (B) was formed on the copper layer by a vacuum vapor deposition method at a room temperature and under a vacuum of 3 × 10 ⁻³ Pa.

Subsequently, a photoresist layer was applied and formed on the surface of the copper nitride, the photoresist layer was exposed and developed through a mask having a lattice mesh pattern, and then an etching process was performed to produce a conductive mesh. This conductive mesh had a line width of 10 μm and a pitch of 200 μm. Moreover, the thickness of the metal layer (A) made of copper constituting the conductive mesh is 3 μm, the thickness of the layer (B) made of copper nitride is 0.02 μm, the nickel layer, the metal layer (A), And the thickness of the electroconductive mesh which consists of a layer (B) was 3.04 micrometer.
<Coating of hard coat layer>
A coating liquid containing 35 parts by mass of dipentaerythritol hexaacrylate, 12 parts by mass of N-vinylpyrrolidone, 3 parts by mass of methyl methacrylate, and 50 parts by mass of methyl ethyl ketone was prepared (HC coating agent 1).
A coating material for a hard coat layer is prepared by adding 5% by mass of acrylic particles having an average particle diameter of 3.5 μm (Chemisen (registered trademark) MX series manufactured by Soken Chemical) as translucent particles to HC coating agent 1. did. In addition, the density | concentration of said acrylic particle is a density | concentration with respect to 100 mass% of the total solid (all components except an organic solvent) of a hard-coat layer, and the following Examples are also synonymous.

On the conductive mesh of the conductive layer obtained above, the above hard coat layer coating was applied with a micro gravure coater to a wet coating amount of 7 g / m ² , dried at 80 ° C. / Cm ² was irradiated and cured to form a hard coat layer.
<Preparation of display filter>
<Lamination of near-infrared shielding layer having Ne-cut function>
As a near-infrared absorbing dye, 14.5 parts by mass of KAYASORB (registered trademark) IRG-068 manufactured by Nippon Kayaku Co., Ltd., 8 parts by mass of eXcolor (registered trademark) IR-10A manufactured by Nippon Shokubai Co., Ltd. As an organic dye having a main absorption peak at 593 nm, TAP-2 manufactured by Yamada Chemical Industry Co., Ltd. was stirred and mixed in 2.9 parts by mass and 2000 parts by mass of methyl ethyl ketone and dissolved. This solution was stirred and mixed with 2000 parts by mass of Hals Hybrid (registered trademark) IR-G205 (solid content 29% solution) manufactured by Nippon Shokubai Co., Ltd. as a transparent polymer resin binder solution to prepare a paint.

The paint was applied to the optical polyester film side opposite to the side on which the hard coat layer was formed using a die coater, dried at 120 ° C., and a near-infrared shielding layer having a thickness of 10 μm was laminated.
<Lamination of adhesive layer>
A pressure-sensitive adhesive layer made of an acrylic transparent pressure-sensitive adhesive having a thickness of 25 μm was laminated on the near-infrared shielding layer. Note that carbon black was included in the pressure-sensitive adhesive layer so that the visible light transmittance of the entire display filter was 40%.

(Examples 2 to 4, Comparative Examples 1 and 2)
The average particle diameter and content of the translucent particles contained in the HC coating agent 1 of Example 1 were changed as shown in Table 1. The wet coating amount of the hard coat layer coating material was also changed as shown in Table 1. Otherwise, a display filter was produced in the same manner as in Example 1.
(Example 5)
A display filter was produced in the same manner as in Example 1 except that the following conductive mesh was used.
<Production of conductive mesh>
On one side of an optical polyester film (Lumirror (registered trademark) QT96 manufactured by Toray Industries, Inc., thickness 100 μm), a nickel layer (thickness 0.02 μm) by vacuum deposition under a vacuum of 3 × 10 ⁻³ Pa at room temperature. ) Was formed. Furthermore, a copper layer (thickness 3 μm) to be a metal layer (A) was formed thereon by a vacuum vapor deposition method at a room temperature and under a vacuum of 3 × 10 ⁻³ Pa. Further, a copper oxide layer (0.02 μm) to be a layer (B) was formed on the copper layer by a vacuum vapor deposition method at a room temperature and under a vacuum of 3 × 10 ⁻³ Pa.

  Subsequently, a photoresist layer was applied and formed on the surface of the copper oxide, the photoresist layer was exposed and developed through a mask having a lattice mesh pattern, and then an etching process was performed to produce a conductive mesh. This conductive mesh had a line width of 10 μm and a pitch of 200 μm. Further, the thickness of the copper metal layer (A) constituting the conductive mesh is 3 μm, the thickness of the copper oxide layer (B) is 0.02 μm, the nickel layer, the metal layer (A), And the thickness of the electroconductive mesh which consists of a layer (B) was 3.04 micrometer.

(Examples 6 to 9)
Carbon black (Oguni Dye Co., Ltd. # 201) as a colorant was further added to each of the hard coat layer paints of Examples 1 to 4, and the total solid content of HC Coating 1 (all components excluding organic solvents) was 100 masses. A filter for display was produced in the same manner as in Examples 1 to 4, except that the coating material added with 0.13% by mass with respect to% was used. In addition, Example 6 is based on Example 1, Example 7 is based on Example 2, Example 8 is based on Example 3, and Example 9 is based on Example 4.
(Evaluation)
About each sample produced above, centerline average roughness Ra of the surface layer and the visibility of the display image were evaluated. The results are shown in Table 1.

From the results in Table 1, it can be seen that the example of the present invention is excellent in the visibility of the display image. In particular, in Examples 6 to 9, the surface layer contains a colorant in addition to the translucent particles, and the visibility of the display image is further improved.
On the other hand, in Comparative Example 1 containing translucent particles having an average particle diameter of less than 1 μm and Comparative Example 2 not containing translucent particles, the visibility of the display image is not improved.

The schematic cross section which shows the thickness of the surface layer of the filter for displays of an example of this invention. The schematic cross section which shows the thickness of the surface layer of the filter for displays of the other example of this invention.

Explanation of symbols

1 Translucent particle 2 Surface layer (hard coat layer)
3 Substrate 4 Conductive mesh Hm: Conductive mesh thickness Hr1: Surface layer thickness Hr2: Surface layer thickness

Claims (8)

A display filter having a conductive mesh on a substrate and a surface layer on the conductive mesh,
The conductive mesh is composed of, in order from the base material side, a metal layer (A) made of a specific metal and a layer (B) made of a metal different from the specific metal or a metal compound,
And the thickness of the said metal layer (A) is 0.5-4 micrometers, The thickness of the said layer (B) is 0.005-0.1 micrometer,
The display filter, wherein the surface layer contains translucent particles having an average particle diameter of 1 to 20 μm.   The display filter according to claim 1, wherein the surface layer contains 2 to 20% by mass of the translucent particles with respect to 100% by mass of all components of the surface layer.   The display filter according to claim 1, wherein the surface layer further contains a colorant.   The display filter according to any one of claims 1 to 3, wherein a center line average roughness Ra of the surface layer is 300 to 1000 nm.   The display-use filter according to claim 1, wherein the specific metal constituting the metal layer (A) is at least one selected from the group consisting of gold, silver, copper, aluminum, and nickel.   The display-use filter according to claim 1, wherein the metal compound constituting the layer (B) is at least one selected from the group consisting of metal oxides, metal sulfides, and metal nitrides. .   The display filter according to claim 1, wherein the surface layer includes at least a hard coat layer, and the hard coat layer contains translucent particles having an average particle diameter of 1 to 20 μm. .   The display filter according to claim 7, wherein the hard coat layer further contains a colorant.

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