JP2009256320A - 低融解性殺生物配合物 - Google Patents
低融解性殺生物配合物 Download PDFInfo
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- JP2009256320A JP2009256320A JP2009051828A JP2009051828A JP2009256320A JP 2009256320 A JP2009256320 A JP 2009256320A JP 2009051828 A JP2009051828 A JP 2009051828A JP 2009051828 A JP2009051828 A JP 2009051828A JP 2009256320 A JP2009256320 A JP 2009256320A
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- JP
- Japan
- Prior art keywords
- hydroxybenzoate
- composition
- methyl
- dcoit
- surfactant
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing carboxylic groups or thio analogues thereof, directly attached by the carbon atom to a cycloaliphatic ring; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
【解決手段】4,5−ジクロロ−2−オクチル−3(2H)−イソチアゾロン、3−ヨードプロパルギル−N−ブチルカルバマート、および少なくとも1種のC1−C4アルキル4−ヒドロキシベンゾアートを含む低融解性殺生物組成物。この組成物は室温での凝集および結晶化に関して安定である。
【選択図】なし
Description
本発明のある実施形態においては、組成物は10%〜18%の4,5−ジクロロ−2−オクチル−3(2H)−イソチアゾロン、4.5%〜9%の3−ヨードプロパルギル−N−ブチルカルバマート、2%〜8%の少なくとも1種のC1−C4アルキル4−ヒドロキシベンゾアート、50%〜72%の水、および10%〜20%の界面活性剤、充填剤および増粘剤の組み合わせ;を含む。
DCOIT:IPBC、2:1の混合物が第3成分と混合され、第3成分が融点に与える影響を評価した。DCOIT/IPBC混合物は31〜36℃の融点を有していた。結果は、アルキル4−ヒドロキシベンゾアートについて最も良好であった。そのパーセンテージ変更についてのデータは下記の表1にまとめられる。試験された他の好適な固体化合物であって、不溶性であるか、または融点をアルキル4−ヒドロキシベンゾアートより低く下げることが見いだされたものは、ベンゾイソチアゾロン(BIT)、n−ブチルBIT、カルベンダジム、クロロタロニル、ジウロン、ホルペット、イルガロール、OIT、ペルメトリン、プロピコナゾール、テブコナゾール、テルブトリン、テルブチラジン、チアベンダゾールおよび亜鉛オマジンを含んでいた。87%の(2:1)DCOIT:IPBC、および2種の界面活性剤:6.5%のC11分岐アルコール・7単位のエチレンオキシドおよび6.5%のC9−C11分岐アルコール・2.5単位のエチレンオキシドの組み合わせは32℃で融解した。
2.DSCは約−25℃で結晶化を示した。
下記の表2に示される成分が下記の手順に従って一緒にされた。得られた分散物のDSC分析は、−30℃の冷却の際に結晶化点を示した。
実施例2に記載される組成物のサンプルが、0〜5%のメチル4−ヒドロキシベンゾアート(HMB)を用いて製造された。サンプルの一部分が40℃に2時間加熱され、次いで室温(r.t.)に冷却され、一方で別の一部分はその間中室温に保たれた。様々な時点でのサンプルの観察が下記の表3に示される。
Claims (10)
- (a)50%〜70%の4,5−ジクロロ−2−オクチル−3(2H)−イソチアゾロン;
(b)20%〜30%の3−ヨードプロパルギル−N−ブチルカルバマート;および
(c)5%〜30%の少なくとも1種のC1−C4アルキル4−ヒドロキシベンゾアート;
の混合物を含む殺生物組成物。 - 少なくとも1種のC1−C4アルキル4−ヒドロキシベンゾアートが、メチル4−ヒドロキシベンゾアート、エチル4−ヒドロキシベンゾアートおよびプロピル4−ヒドロキシベンゾアートの少なくとも1種である、請求項1に記載の組成物。
- 52%〜68%の4,5−ジクロロ−2−オクチル−3(2H)−イソチアゾロン、20%〜28%の3−ヨードプロパルギル−N−ブチルカルバマート並びに10%〜25%のメチル4−ヒドロキシベンゾアート、エチル4−ヒドロキシベンゾアートおよびプロピル4−ヒドロキシベンゾアートの少なくとも1種を含む、請求項2に記載の組成物。
- 少なくとも1種の界面活性剤をさらに含む、請求項3に記載の組成物。
- 4,5−ジクロロ−2−オクチル−3(2H)−イソチアゾロンと、3−ヨードプロパルギル−N−ブチルカルバマートと、メチル4−ヒドロキシベンゾアート、エチル4−ヒドロキシベンゾアートおよびプロピル4−ヒドロキシベンゾアートの少なくとも1種との混合物が組成物の15%〜35%を構成し;水が組成物の50%〜75%を構成し;並びに界面活性剤、無機充填剤および増粘剤を含む組み合わせが、組成物の10%〜20%を構成する、請求項4に記載の組成物。
- 界面活性剤が、2〜10モルのエチレンオキシドでエトキシ化されたC9−C11分岐アルコールの少なくとも1種を含み、無機充填剤がカオリンを含む請求項5に記載の組成物。
- (a)10%〜18%の4,5−ジクロロ−2−オクチル−3(2H)−イソチアゾロン;
(b)4.5%〜9%の3−ヨードプロパルギル−N−ブチルカルバマート;
(c)2%〜8%の少なくとも1種のC1−C4アルキル4−ヒドロキシベンゾアート;
(d)50%〜72%の水;並びに
(e)10%〜20%の界面活性剤、無機充填剤および増粘剤の組み合わせ;
を含む殺生物組成物。 - 少なくとも1種のC1−C4アルキル4−ヒドロキシベンゾアートが、メチル4−ヒドロキシベンゾアート、エチル4−ヒドロキシベンゾアートおよびプロピル4−ヒドロキシベンゾアートの少なくとも1種である、請求項7に記載の殺生物組成物。
- 界面活性剤が、2〜10モルのエチレンオキシドでエトキシ化されたC9−C11分岐アルコールの少なくとも1種を含み、無機充填剤がカオリンを含む請求項8に記載の殺生物組成物。
- 10%〜18%の4,5−ジクロロ−2−オクチル−3(2H)−イソチアゾロン;4.5%〜9%の3−ヨードプロパルギル−N−ブチルカルバマート;2%〜8%のメチル4−ヒドロキシベンゾアート、エチル4−ヒドロキシベンゾアートおよびプロピル4−ヒドロキシベンゾアートの少なくとも1種;50%〜72%の水;6.5%〜13.5%の少なくとも1種の無機充填剤;0.4%〜1.2%の少なくとも1種の増粘剤;0.3%〜1.8%の少なくとも1種の銅塩;並びに1%〜5%の少なくとも1種の界面活性剤;を含む請求項9に記載の殺生物組成物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12397308P | 2008-04-11 | 2008-04-11 | |
US61/123,973 | 2008-04-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009256320A true JP2009256320A (ja) | 2009-11-05 |
JP4845225B2 JP4845225B2 (ja) | 2011-12-28 |
Family
ID=40750999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009051828A Active JP4845225B2 (ja) | 2008-04-11 | 2009-03-05 | 低融解性殺生物配合物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US8252819B2 (ja) |
EP (1) | EP2108259B1 (ja) |
JP (1) | JP4845225B2 (ja) |
KR (1) | KR101099050B1 (ja) |
CN (1) | CN101554172B (ja) |
AT (1) | ATE492159T1 (ja) |
AU (1) | AU2009200981B2 (ja) |
BR (1) | BRPI0900949B1 (ja) |
CA (1) | CA2657524C (ja) |
DE (1) | DE602009000451D1 (ja) |
MX (1) | MX2009003574A (ja) |
PL (1) | PL2108259T3 (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130195947A1 (en) | 2010-03-17 | 2013-08-01 | Willem Anker | Biocide powder formulation |
US8648027B2 (en) | 2012-07-06 | 2014-02-11 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a cationic biocide |
CN102934635B (zh) * | 2012-11-16 | 2014-07-30 | 中国热带农业科学院橡胶研究所 | 一种环保型橡胶木防霉防变色保护剂 |
US10779538B2 (en) * | 2014-05-21 | 2020-09-22 | Boss Holdings Inc. | Antimicrobial composition for protecting wood |
CA2852530A1 (en) * | 2014-05-21 | 2015-11-21 | The Sansin Corporation | Antimicrobial composition for protecting wood |
US9096821B1 (en) | 2014-07-31 | 2015-08-04 | The Clorox Company | Preloaded dual purpose cleaning and sanitizing wipe |
US10982177B2 (en) | 2017-09-18 | 2021-04-20 | The Clorox Company | Cleaning wipes with particular lotion retention and efficacy characteristics |
US10973385B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular pore volume distribution characteristics |
US10973386B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes system having particular performance characteristics |
US10975341B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular MABDF characteristics |
WO2019133480A1 (en) * | 2017-12-28 | 2019-07-04 | Dow Global Technologies Llc | Stabilization of dcoit in aqueous systems |
US11364711B2 (en) | 2018-12-21 | 2022-06-21 | The Clorox Company | Multi-layer substrates comprising sandwich layers and polyethylene |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03184904A (ja) * | 1989-11-02 | 1991-08-12 | Rohm & Haas Co | 4,5―ジクロロ―2―オクチル―3―イソチアゾロンと特定の市販の殺生物剤を含有する相乗的殺微生物性組成物 |
JP2004051635A (ja) * | 2002-07-18 | 2004-02-19 | Rohm & Haas Co | 安定化されたハロアルキニル殺菌剤組成物 |
Family Cites Families (11)
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US3097131A (en) * | 1959-04-09 | 1963-07-09 | Ueno | Eutectic liquid preservatives |
US4496576A (en) | 1980-10-23 | 1985-01-29 | Mallinckrodt, Inc. | Compositions of p-hydroxybenzoic acid esters and methods of preparation and use |
US4357258A (en) | 1980-10-23 | 1982-11-02 | Mallinckrodt, Inc. | Stable emulsions of p-hydroxybenzoic acid esters and method of preparation |
US4309564A (en) | 1980-10-23 | 1982-01-05 | Mallinckrodt, Inc. | Methods for preparing eutectic mixtures of p-hydroxybenzoic acid esters |
US5468759A (en) * | 1991-12-19 | 1995-11-21 | Rohm And Haas Company | Synergistic microbicidal combinations containing 4,5-dichloro-2-octyl-3-isothiazolone and certain commercial biocides |
KR20010013377A (ko) * | 1997-06-04 | 2001-02-26 | 데이비드 엠 모이어 | 마일드한 잔류성 항균 조성물 |
US6310013B1 (en) * | 1999-10-27 | 2001-10-30 | Ecolab Inc. | Lubricant compositions having antimicrobial properties and methods for manufacturing and using lubricant compositions having antimicrobial properties |
DE60305844T2 (de) * | 2002-11-22 | 2007-05-16 | Rohm And Haas Co. | Wässrige Dispersion von organischen Feststoffen mit niedrigem Schmelzpunkt |
JP2004315507A (ja) * | 2003-04-07 | 2004-11-11 | Rohm & Haas Co | 殺微生物組成物 |
US9034390B2 (en) * | 2006-05-02 | 2015-05-19 | Bioneutral Laboratories Corporation | Anti-microbial composition and method for making and using same |
US20070292465A1 (en) | 2006-06-16 | 2007-12-20 | Clariant International, Ltd. | Eutectic biocide compositions and formulations |
-
2009
- 2009-03-05 JP JP2009051828A patent/JP4845225B2/ja active Active
- 2009-03-09 EP EP09154679A patent/EP2108259B1/en active Active
- 2009-03-09 AT AT09154679T patent/ATE492159T1/de not_active IP Right Cessation
- 2009-03-09 CA CA2657524A patent/CA2657524C/en active Active
- 2009-03-09 DE DE602009000451T patent/DE602009000451D1/de active Active
- 2009-03-09 PL PL09154679T patent/PL2108259T3/pl unknown
- 2009-03-10 AU AU2009200981A patent/AU2009200981B2/en not_active Ceased
- 2009-03-20 KR KR1020090023894A patent/KR101099050B1/ko active IP Right Grant
- 2009-03-26 BR BRPI0900949A patent/BRPI0900949B1/pt active IP Right Grant
- 2009-04-02 MX MX2009003574A patent/MX2009003574A/es active IP Right Grant
- 2009-04-08 US US12/384,872 patent/US8252819B2/en active Active
- 2009-04-10 CN CN2009101341553A patent/CN101554172B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03184904A (ja) * | 1989-11-02 | 1991-08-12 | Rohm & Haas Co | 4,5―ジクロロ―2―オクチル―3―イソチアゾロンと特定の市販の殺生物剤を含有する相乗的殺微生物性組成物 |
JP2004051635A (ja) * | 2002-07-18 | 2004-02-19 | Rohm & Haas Co | 安定化されたハロアルキニル殺菌剤組成物 |
Also Published As
Publication number | Publication date |
---|---|
DE602009000451D1 (de) | 2011-02-03 |
CA2657524A1 (en) | 2009-10-11 |
BRPI0900949B1 (pt) | 2016-05-10 |
MX2009003574A (es) | 2009-10-19 |
CN101554172A (zh) | 2009-10-14 |
ATE492159T1 (de) | 2011-01-15 |
KR101099050B1 (ko) | 2011-12-26 |
AU2009200981A1 (en) | 2009-10-29 |
EP2108259A1 (en) | 2009-10-14 |
CN101554172B (zh) | 2013-02-13 |
US20090258916A1 (en) | 2009-10-15 |
BRPI0900949A2 (pt) | 2009-12-01 |
PL2108259T3 (pl) | 2011-05-31 |
AU2009200981B2 (en) | 2014-02-27 |
US8252819B2 (en) | 2012-08-28 |
EP2108259B1 (en) | 2010-12-22 |
JP4845225B2 (ja) | 2011-12-28 |
CA2657524C (en) | 2012-01-24 |
KR20090108531A (ko) | 2009-10-15 |
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