JP2008513326A - 液体炭化水素質燃料の触媒部分酸化方法 - Google Patents
液体炭化水素質燃料の触媒部分酸化方法 Download PDFInfo
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- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
- B01J4/002—Nozzle-type elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
- F02M27/02—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by catalysts
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M31/00—Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture
- F02M31/02—Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture for heating
- F02M31/12—Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture for heating electrically
- F02M31/135—Fuel-air mixture
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00716—Means for reactor start-up
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1288—Evaporation of one or more of the different feed components
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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Abstract
Description
CnH2n+2+n/2O2→nCO+(n+1)H2 (1)
により表される発熱反応である。
本発明の目的は、液体炭化水素質燃料の触媒部分酸化の改良方法を提供することである。この目的のため、炭化水素質燃料を第1の量の分子酸素と反応させて、燃料の触媒転化の前に燃料を蒸発させるのに十分な熱を発生させる。
a)液体炭化水素質燃料を第1の量の分子酸素と混合し、燃料と分子酸素とを含んだ第1の混合物を形成する工程と;
b)前記第1の混合物に点火することにより前記燃料を蒸発させる工程と;
c)蒸発した燃料を第2の量の分子酸素と混合し、燃料と分子酸素とを含んだ第2の混合物を形成する工程と;
d)少なくとも水素を含んだ生成物ガスに転化するために、前記第2の混合物を部分酸化触媒と接触させる工程と、
からなり、該方法において全酸素対炭素比が0.3〜0.8の範囲にあり、前記第1の混合物中の酸素対炭素比が0.01〜0.4の範囲にあることを特徴とする液体炭化水素質燃料の触媒部分酸化方法を提供する。
本発明による方法は、液体炭化水素質燃料の触媒部分酸化方法である。液体燃料を第1の量の分子酸素(O2)と混合して、燃料と分子酸素からなる第1の混合物を形成する(工程(a))。次に、第1の混合物に点火し、燃料を分子酸素と発熱反応させる(工程(b))。発熱反応により発生した熱により、混合物中の燃料を蒸発させる。
図1は本発明による方法に適した燃料処理装置を概略的に示す。燃料処理装置1は、それぞれフランジを介してボルト留めされた3つの部分3、4、5から成るハウジング2を備える。最も上流の部分3は本質的に混合器であり、エアアシスト式燃料ノズル6と半径方向に延びた入口7とを備える。混合器3はさらに、2つの同軸シリンダー8、9を含み、ボルト12及びバッフル13により混合器3内に取り付けられた環状ダクト11(シリンダー8とシリンダー9との間)だけでなく主流路10(最も内側のシリンダー内)も形成する。開口部14及び15がシリンダー8及びバッフル13にそれぞれ設けられる。スパークプラグ16が、ノズル6と内側シリンダー8の開口部14との間にて混合器3の壁中に取り付けられる。ハウジング2の下流部分4、5は、生成物ガス用の出口開口部17を備えると共に、上述した内側シリンダー8に整列したシリンダー18を含み、よって主流路10を延ばす。シリンダー18は燃料を転化するための触媒ゾーン19を含む。
2 ハウジング
3 混合器
6 燃料ノズル
8、9 シリンダー
10 主流路
11 環状ダクト
12 ボルト
13 バッフル
14、15 開口部
16 スパークプラグ
17 出口開口部
Claims (9)
- 液体炭化水素質燃料の触媒部分酸化方法であって、
a)液体炭化水素質燃料を第1の量の分子酸素と混合し、燃料と分子酸素とを含んだ第1の混合物を形成する工程と;
b)前記第1の混合物に点火することにより前記燃料を蒸発させる工程と;
c)蒸発した燃料を第2の量の分子酸素と混合し、燃料と分子酸素とを含んだ第2の混合物を形成する工程と;
d)少なくとも水素を含んだ生成物ガスに転化するために、前記第2の混合物を部分酸化触媒と接触させる工程と、
からなり、該方法において全酸素対炭素比が0.3〜0.8の範囲にあり、前記第1の混合物中の酸素対炭素比が0.01〜0.4の範囲にあることを特徴とする液体炭化水素質燃料の触媒部分酸化方法。 - 前記第1の混合物中の酸素対炭素比が0.01〜0.15、好ましくは0.02〜0.10の範囲にあることを特徴とする請求項1に記載の方法。
- 前記全酸素対炭素比が0.40〜0.75、好ましくは0.45〜0.65の範囲にあることを特徴とする請求項1又は2に記載の方法。
- 前記炭化水素質燃料の終点が400℃以下、好ましくは250〜400℃の範囲にあることを特徴とする請求項1〜3のいずれか一項に記載の方法。
- 前記炭化水素質燃料がディーゼル燃料であることを特徴とする請求項1〜4のいずれか一項に記載の方法。
- 工程(a)において燃料をノズル内で酸素と混合して第1の混合物の噴霧を形成することを特徴とする請求項1〜5のいずれか一項に記載の方法。
- 工程(a)及び(c)において燃料と混合する酸素が独立に空気、ディーゼル排気ガス又はそれらの混合物中に含まれることを特徴とする請求項1〜6のいずれか一項に記載の方法。
- 工程(c)において燃料と混合する酸素の温度が周囲温度〜400℃、好ましくは200〜400℃の範囲にあることを特徴とする請求項1〜7のいずれか一項に記載の方法。
- スパークプラグを用いて前記第1の混合物に点火することを特徴とする請求項1〜8のいずれか一項に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04022293 | 2004-09-20 | ||
PCT/EP2005/054659 WO2006032644A1 (en) | 2004-09-20 | 2005-09-19 | A process for the catalytic partial oxidation of a liquid hydrocarbonaceous fuel |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2008513326A true JP2008513326A (ja) | 2008-05-01 |
Family
ID=34926605
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007531760A Abandoned JP2008513326A (ja) | 2004-09-20 | 2005-09-19 | 液体炭化水素質燃料の触媒部分酸化方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20070261686A1 (ja) |
EP (1) | EP1791783A1 (ja) |
JP (1) | JP2008513326A (ja) |
KR (1) | KR20070061883A (ja) |
CN (1) | CN101023024A (ja) |
CA (1) | CA2580647A1 (ja) |
WO (1) | WO2006032644A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011181490A (ja) * | 2009-12-17 | 2011-09-15 | Topsoee Fuel Cell As | 燃料を低酸素ガスおよび/または高水素ガスに転化するためのガス発生器および方法 |
Families Citing this family (15)
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CN101802353B (zh) * | 2007-08-30 | 2013-04-17 | 酷焰技术有限公司 | 用于再生NOx捕集器和颗粒过滤器的废气设备和方法 |
GB2468159B (en) * | 2009-02-27 | 2011-11-09 | Energy Conversion Technology As | Exhaust gas cleaning apparatus and method for cleaning an exhaust gas |
US8439990B2 (en) * | 2009-07-21 | 2013-05-14 | Precision Combustion, Inc. | Reactor flow control apparatus |
US10035960B2 (en) | 2010-09-07 | 2018-07-31 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone management by gasification |
US9574142B2 (en) | 2010-09-07 | 2017-02-21 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone management by gasification |
US9234146B2 (en) | 2011-07-27 | 2016-01-12 | Saudi Arabian Oil Company | Process for the gasification of heavy residual oil with particulate coke from a delayed coking unit |
GB2510171B (en) | 2013-01-28 | 2015-01-28 | Cool Flame Technologies As | Method and cleaning apparatus for removal of SOx and NOx from exhaust gas |
DE102013008367A1 (de) * | 2013-05-16 | 2014-11-20 | Man Truck & Bus Ag | Antriebsvorrichtung sowie Verfahren zum Betreiben derselben unter Verwendung eines partiell oxidierten Dieselkraftstoffs |
CA2929546C (en) | 2013-11-06 | 2019-03-05 | Watt Fuel Cell Corp. | Gaseous fuel cpox reformers and methods of cpox reforming |
KR101865032B1 (ko) * | 2013-11-06 | 2018-06-07 | 와트 퓨얼 셀 코퍼레이션 | 액체 연료 cpox 개질장치-연료 전지 시스템, 및 전기 생산 방법 |
US9624104B2 (en) | 2013-11-06 | 2017-04-18 | Watt Fuel Cell Corp. | Liquid fuel CPOX reformers and methods of CPOX reforming |
KR101925826B1 (ko) | 2013-11-06 | 2018-12-06 | 와트 퓨얼 셀 코퍼레이션 | 구조적 구성요소로서 페로브스카이트를 가지는 개질장치 |
CN105706283B (zh) | 2013-11-06 | 2018-11-06 | 瓦特燃料电池公司 | 集成的气态燃料催化部分氧化重整器和燃料电池系统、以及产生电力的方法 |
CN105706281B (zh) | 2013-11-06 | 2019-07-26 | 瓦特燃料电池公司 | 化学反应器系统 |
DE102016105492A1 (de) | 2016-03-23 | 2017-09-28 | Karlsruher Institut für Technologie | Reaktor zur Herstellung von Synthesegas |
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US4522894A (en) * | 1982-09-30 | 1985-06-11 | Engelhard Corporation | Fuel cell electric power production |
DE3532413A1 (de) * | 1985-09-11 | 1987-03-12 | Uhde Gmbh | Vorrichtung zur erzeugung von synthesegas |
FR2679217B1 (fr) * | 1991-07-18 | 1994-04-01 | Institut Francais Petrole | Procede et dispositif pour la fabrication de gaz de synthese et application. |
US6244367B1 (en) * | 1997-06-02 | 2001-06-12 | The University Of Chicago | Methanol partial oxidation reformer |
DE19955929C2 (de) * | 1999-11-20 | 2002-04-18 | Daimler Chrysler Ag | Verfahren zur autothermen Reformierung eines Kohlenwasserstoffs |
JP2001270704A (ja) * | 2000-03-28 | 2001-10-02 | Matsushita Electric Ind Co Ltd | 水素発生装置 |
US6872379B2 (en) * | 2001-08-15 | 2005-03-29 | Sulzer Hexis Ag | Method for the reformation of fuels, in particular heating oil |
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US20040144030A1 (en) * | 2003-01-23 | 2004-07-29 | Smaling Rudolf M. | Torch ignited partial oxidation fuel reformer and method of operating the same |
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US7261751B2 (en) * | 2004-08-06 | 2007-08-28 | Conocophillips Company | Synthesis gas process comprising partial oxidation using controlled and optimized temperature profile |
-
2005
- 2005-09-19 EP EP05789379A patent/EP1791783A1/en not_active Withdrawn
- 2005-09-19 KR KR1020077008881A patent/KR20070061883A/ko not_active Application Discontinuation
- 2005-09-19 JP JP2007531760A patent/JP2008513326A/ja not_active Abandoned
- 2005-09-19 WO PCT/EP2005/054659 patent/WO2006032644A1/en active Application Filing
- 2005-09-19 CA CA002580647A patent/CA2580647A1/en not_active Abandoned
- 2005-09-19 CN CNA200580031661XA patent/CN101023024A/zh active Pending
- 2005-09-19 US US11/663,117 patent/US20070261686A1/en not_active Abandoned
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011181490A (ja) * | 2009-12-17 | 2011-09-15 | Topsoee Fuel Cell As | 燃料を低酸素ガスおよび/または高水素ガスに転化するためのガス発生器および方法 |
Also Published As
Publication number | Publication date |
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KR20070061883A (ko) | 2007-06-14 |
EP1791783A1 (en) | 2007-06-06 |
WO2006032644A1 (en) | 2006-03-30 |
CA2580647A1 (en) | 2006-03-30 |
US20070261686A1 (en) | 2007-11-15 |
CN101023024A (zh) | 2007-08-22 |
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