JP2008507472A - アルカリ金属過塩素酸塩含有ガス発生剤 - Google Patents
アルカリ金属過塩素酸塩含有ガス発生剤 Download PDFInfo
- Publication number
- JP2008507472A JP2008507472A JP2007523660A JP2007523660A JP2008507472A JP 2008507472 A JP2008507472 A JP 2008507472A JP 2007523660 A JP2007523660 A JP 2007523660A JP 2007523660 A JP2007523660 A JP 2007523660A JP 2008507472 A JP2008507472 A JP 2008507472A
- Authority
- JP
- Japan
- Prior art keywords
- weight percent
- gas generant
- composition
- alkali metal
- nitrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910001485 alkali metal perchlorate Inorganic materials 0.000 title claims abstract description 61
- 239000000203 mixture Substances 0.000 claims abstract description 204
- 239000007789 gas Substances 0.000 claims abstract description 137
- 239000002245 particle Substances 0.000 claims abstract description 44
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000002485 combustion reaction Methods 0.000 claims abstract description 30
- 229910052802 copper Inorganic materials 0.000 claims abstract description 24
- 239000010949 copper Substances 0.000 claims abstract description 24
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000000446 fuel Substances 0.000 claims abstract description 17
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 12
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- YTNLBRCAVHCUPD-UHFFFAOYSA-N 5-(1$l^{2},2,3,4-tetrazol-5-yl)-1$l^{2},2,3,4-tetrazole Chemical compound [N]1N=NN=C1C1=NN=N[N]1 YTNLBRCAVHCUPD-UHFFFAOYSA-N 0.000 claims abstract description 9
- UDPYNCXWXQWOTC-UHFFFAOYSA-O azanium copper trinitrate Chemical compound [NH4+].[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O UDPYNCXWXQWOTC-UHFFFAOYSA-O 0.000 claims abstract description 8
- 229960004643 cupric oxide Drugs 0.000 claims abstract description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 38
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 36
- 229910044991 metal oxide Inorganic materials 0.000 claims description 23
- 239000000654 additive Substances 0.000 claims description 22
- 150000004706 metal oxides Chemical class 0.000 claims description 22
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 21
- 230000000996 additive effect Effects 0.000 claims description 20
- 229910021529 ammonia Inorganic materials 0.000 claims description 19
- 239000002893 slag Substances 0.000 claims description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 18
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 18
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims description 17
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 claims description 17
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- -1 amine nitrates Chemical class 0.000 claims description 9
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical group [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 8
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 231100000419 toxicity Toxicity 0.000 claims description 4
- 230000001988 toxicity Effects 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical group [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 claims description 3
- 229910001488 sodium perchlorate Inorganic materials 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- SFDJOSRHYKHMOK-UHFFFAOYSA-N nitramide Chemical class N[N+]([O-])=O SFDJOSRHYKHMOK-UHFFFAOYSA-N 0.000 claims description 2
- FGHAZDVJHATENE-UHFFFAOYSA-N [N-]=[N+]=[N-].[N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH6+3] Chemical compound [N-]=[N+]=[N-].[N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH6+3] FGHAZDVJHATENE-UHFFFAOYSA-N 0.000 claims 1
- OMEUAIRDZHFIHD-UHFFFAOYSA-O azanium copper(1+) dinitrate Chemical compound [N+](=O)([O-])[O-].[NH4+].[N+](=O)([O-])[O-].[Cu+] OMEUAIRDZHFIHD-UHFFFAOYSA-O 0.000 claims 1
- 150000003536 tetrazoles Chemical class 0.000 claims 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract description 2
- 150000001540 azides Chemical class 0.000 abstract 1
- 125000001477 organic nitrogen group Chemical group 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- WKDKOOITVYKILI-UHFFFAOYSA-M caesium perchlorate Chemical class [Cs+].[O-]Cl(=O)(=O)=O WKDKOOITVYKILI-UHFFFAOYSA-M 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- UUZZMWZGAZGXSF-UHFFFAOYSA-N peroxynitric acid Chemical compound OON(=O)=O UUZZMWZGAZGXSF-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- UGWHPQNZVGJHMU-UHFFFAOYSA-Q triazanium trinitrate Chemical compound [NH4+].[NH4+].[NH4+].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O UGWHPQNZVGJHMU-UHFFFAOYSA-Q 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/02—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Air Bags (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Emergency Lowering Means (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/899,452 US8101033B2 (en) | 2004-07-26 | 2004-07-26 | Alkali metal perchlorate-containing gas generants |
| PCT/US2005/026053 WO2006014801A2 (en) | 2004-07-26 | 2005-07-22 | Alkali metal perchlorate-containing gas generants |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013037443A Division JP2013126947A (ja) | 2004-07-26 | 2013-02-27 | アルカリ金属過塩素酸塩含有ガス発生剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008507472A true JP2008507472A (ja) | 2008-03-13 |
| JP2008507472A5 JP2008507472A5 (enExample) | 2008-07-10 |
Family
ID=35655877
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007523660A Withdrawn JP2008507472A (ja) | 2004-07-26 | 2005-07-22 | アルカリ金属過塩素酸塩含有ガス発生剤 |
| JP2013037443A Pending JP2013126947A (ja) | 2004-07-26 | 2013-02-27 | アルカリ金属過塩素酸塩含有ガス発生剤 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013037443A Pending JP2013126947A (ja) | 2004-07-26 | 2013-02-27 | アルカリ金属過塩素酸塩含有ガス発生剤 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8101033B2 (enExample) |
| EP (1) | EP1789371B1 (enExample) |
| JP (2) | JP2008507472A (enExample) |
| KR (1) | KR101154214B1 (enExample) |
| CN (1) | CN100462342C (enExample) |
| AT (1) | ATE551311T1 (enExample) |
| WO (1) | WO2006014801A2 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012509235A (ja) * | 2008-11-12 | 2012-04-19 | オートリブ エーエスピー,インコーポレイティド | ガラス繊維を有するガス発生組成物 |
| JP2013504507A (ja) * | 2009-09-10 | 2013-02-07 | エスエムウー | 火工ガス発生物 |
| JP2016514084A (ja) * | 2013-03-13 | 2016-05-19 | オートリブ エーエスピー,インコーポレイティド | 銅含有ガス発生剤のための改善されたスラグ生成 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8101033B2 (en) | 2004-07-26 | 2012-01-24 | Autoliv Asp, Inc. | Alkali metal perchlorate-containing gas generants |
| US20060289096A1 (en) * | 2003-07-25 | 2006-12-28 | Mendenhall Ivan V | Extrudable gas generant |
| JP2009536146A (ja) | 2006-05-05 | 2009-10-08 | ティー ケー ホールディングス インク | ガス生成組成物 |
| US7692024B2 (en) | 2006-05-05 | 2010-04-06 | Tk Holdings, Inc. | Gas generant compositions |
| US7758709B2 (en) * | 2006-06-21 | 2010-07-20 | Autoliv Asp, Inc. | Monolithic gas generant grains |
| DE112007002257T5 (de) * | 2006-09-30 | 2009-07-30 | TK Holdings, Inc., Armada | Gaserzeugungsmittelzusammensetzungen |
| US9193639B2 (en) | 2007-03-27 | 2015-11-24 | Autoliv Asp, Inc. | Methods of manufacturing monolithic generant grains |
| US8057611B2 (en) * | 2007-08-13 | 2011-11-15 | Autoliv Asp, Inc. | Multi-composition pyrotechnic grain |
| US8815029B2 (en) * | 2008-04-10 | 2014-08-26 | Autoliv Asp, Inc. | High performance gas generating compositions |
| FR2964656B1 (fr) * | 2010-09-15 | 2012-10-12 | Snpe Materiaux Energetiques | Composes pyrotechniques generateurs de gaz |
| US9051223B2 (en) | 2013-03-15 | 2015-06-09 | Autoliv Asp, Inc. | Generant grain assembly formed of multiple symmetric pieces |
| US10874152B2 (en) | 2014-05-01 | 2020-12-29 | Legionarius, Llc | Wearable device for reducing fluid loss |
| CN105777458B (zh) * | 2014-12-26 | 2018-05-29 | 比亚迪股份有限公司 | 一种用于汽车安全气囊气体发生器的自动点火药及其制备方法 |
| CN105061123A (zh) * | 2015-08-17 | 2015-11-18 | 陕西庆华汽车安全系统有限公司 | 一种用于汽车安全带预紧器的产气药及其制备方法 |
| US11173992B2 (en) | 2017-12-28 | 2021-11-16 | Legionarus, Llc | Buoyancy garment |
| US11471112B2 (en) | 2018-11-21 | 2022-10-18 | Legionarius, Llc | Mobile application for wearable device |
| USD905935S1 (en) | 2019-02-20 | 2020-12-29 | Legionarius, Llc | Shirt with back pocket |
| US12478324B2 (en) | 2019-02-20 | 2025-11-25 | Legionarius, Llc | Sensors for wearable devices |
| CN110317120B (zh) * | 2019-05-30 | 2020-10-20 | 湖北航鹏化学动力科技有限责任公司 | 点火药及其制备方法与应用以及安全气囊气体发生器 |
| US12264115B2 (en) | 2019-08-02 | 2025-04-01 | Autoliv Asp, Inc. | Ignition booster compositions and methods of making the same |
| JP7444493B2 (ja) * | 2020-01-22 | 2024-03-06 | シーアン クリステン マテリアルズ テクノロジー コーポレーション リミテッド | 化合物、その調製方法及びエネルギー物質としての使用 |
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| US6004411A (en) * | 1997-12-29 | 1999-12-21 | Trw Airbag Systems Gmbh & Co. Kg | Azide-free gas-producing composition |
| JP2003128489A (ja) * | 2001-10-23 | 2003-05-08 | Nof Corp | ガス発生剤組成物及びガス発生器 |
| WO2003106378A1 (en) * | 2002-06-14 | 2003-12-24 | Autoliv Asp, Inc. | Micro-gas generation |
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- 2005-07-22 KR KR1020077001901A patent/KR101154214B1/ko not_active Expired - Fee Related
- 2005-07-22 CN CNB2005800253108A patent/CN100462342C/zh not_active Expired - Fee Related
- 2005-07-22 EP EP05773588A patent/EP1789371B1/en not_active Expired - Lifetime
- 2005-07-22 AT AT05773588T patent/ATE551311T1/de active
- 2005-07-22 JP JP2007523660A patent/JP2008507472A/ja not_active Withdrawn
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2012
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2013
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012509235A (ja) * | 2008-11-12 | 2012-04-19 | オートリブ エーエスピー,インコーポレイティド | ガラス繊維を有するガス発生組成物 |
| JP2013504507A (ja) * | 2009-09-10 | 2013-02-07 | エスエムウー | 火工ガス発生物 |
| JP2016514084A (ja) * | 2013-03-13 | 2016-05-19 | オートリブ エーエスピー,インコーポレイティド | 銅含有ガス発生剤のための改善されたスラグ生成 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1789371A2 (en) | 2007-05-30 |
| WO2006014801A2 (en) | 2006-02-09 |
| CN101065340A (zh) | 2007-10-31 |
| KR20070040377A (ko) | 2007-04-16 |
| US8388777B2 (en) | 2013-03-05 |
| JP2013126947A (ja) | 2013-06-27 |
| EP1789371A4 (en) | 2010-12-15 |
| US20060016529A1 (en) | 2006-01-26 |
| WO2006014801A3 (en) | 2007-06-28 |
| KR101154214B1 (ko) | 2012-06-18 |
| US8101033B2 (en) | 2012-01-24 |
| CN100462342C (zh) | 2009-02-18 |
| US20120118449A1 (en) | 2012-05-17 |
| ATE551311T1 (de) | 2012-04-15 |
| EP1789371B1 (en) | 2012-03-28 |
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