JP2008505883A - 水殺菌用新規固体組成物 - Google Patents
水殺菌用新規固体組成物 Download PDFInfo
- Publication number
- JP2008505883A JP2008505883A JP2007519980A JP2007519980A JP2008505883A JP 2008505883 A JP2008505883 A JP 2008505883A JP 2007519980 A JP2007519980 A JP 2007519980A JP 2007519980 A JP2007519980 A JP 2007519980A JP 2008505883 A JP2008505883 A JP 2008505883A
- Authority
- JP
- Japan
- Prior art keywords
- solid
- dimethylhydantoin
- weight
- molded body
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 17
- 239000008247 solid mixture Substances 0.000 title claims abstract description 15
- 230000001954 sterilising effect Effects 0.000 title claims description 8
- 239000000203 mixture Substances 0.000 claims abstract description 66
- 239000007787 solid Substances 0.000 claims abstract description 51
- 238000000034 method Methods 0.000 claims abstract description 34
- 150000001875 compounds Chemical class 0.000 claims abstract description 24
- 230000003115 biocidal effect Effects 0.000 claims abstract description 22
- -1 halogenated 5,5-dimethylhydantoin compound Chemical class 0.000 claims abstract description 16
- 238000000465 moulding Methods 0.000 claims abstract description 15
- 239000008187 granular material Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000000748 compression moulding Methods 0.000 claims abstract description 4
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 claims description 58
- PQRDTUFVDILINV-UHFFFAOYSA-N bcdmh Chemical compound CC1(C)N(Cl)C(=O)N(Br)C1=O PQRDTUFVDILINV-UHFFFAOYSA-N 0.000 claims description 57
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 47
- 229950009390 symclosene Drugs 0.000 claims description 31
- VRLDVERQJMEPIF-UHFFFAOYSA-N dbdmh Chemical compound CC1(C)N(Br)C(=O)N(Br)C1=O VRLDVERQJMEPIF-UHFFFAOYSA-N 0.000 claims description 23
- 230000006835 compression Effects 0.000 claims description 18
- 238000007906 compression Methods 0.000 claims description 18
- YIROYDNZEPTFOL-UHFFFAOYSA-N 5,5-Dimethylhydantoin Chemical compound CC1(C)NC(=O)NC1=O YIROYDNZEPTFOL-UHFFFAOYSA-N 0.000 claims description 15
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 15
- 229910052801 chlorine Inorganic materials 0.000 claims description 15
- 239000000460 chlorine Substances 0.000 claims description 15
- PIEXCQIOSMOEOU-UHFFFAOYSA-N 1-bromo-3-chloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Br)C(=O)N(Cl)C1=O PIEXCQIOSMOEOU-UHFFFAOYSA-N 0.000 claims description 12
- 230000001590 oxidative effect Effects 0.000 claims description 8
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 6
- 239000012736 aqueous medium Substances 0.000 claims description 5
- 230000000249 desinfective effect Effects 0.000 claims description 5
- 230000026030 halogenation Effects 0.000 claims description 5
- 238000005658 halogenation reaction Methods 0.000 claims description 5
- 229940091173 hydantoin Drugs 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 claims description 4
- 239000008235 industrial water Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 235000012431 wafers Nutrition 0.000 claims description 2
- 239000002351 wastewater Substances 0.000 claims 1
- 239000003826 tablet Substances 0.000 description 37
- 239000000047 product Substances 0.000 description 20
- 229910052736 halogen Inorganic materials 0.000 description 14
- 150000002367 halogens Chemical class 0.000 description 14
- 239000000654 additive Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000003139 biocide Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 150000001469 hydantoins Chemical class 0.000 description 2
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- OFTZZDZZNXTWFO-UHFFFAOYSA-N 1,3-dichloro-5-ethyl-5-methylimidazolidine-2,4-dione Chemical compound CCC1(C)N(Cl)C(=O)N(Cl)C1=O OFTZZDZZNXTWFO-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- RHYBFKMFHLPQPH-UHFFFAOYSA-N N-methylhydantoin Chemical compound CN1CC(=O)NC1=O RHYBFKMFHLPQPH-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 239000007891 compressed tablet Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- 125000000950 dibromo group Chemical group Br* 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical compound BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GMHKMTDVRCWUDX-UHFFFAOYSA-N mephenytoin Chemical compound C=1C=CC=CC=1C1(CC)NC(=O)N(C)C1=O GMHKMTDVRCWUDX-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000007932 molded tablet Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000007916 tablet composition Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL16293404A IL162934A0 (en) | 2004-07-08 | 2004-07-08 | Novel solid compositions for disinfecting water |
| PCT/IL2005/000723 WO2006006155A2 (en) | 2004-07-08 | 2005-07-07 | Novel solid compositions for disinfecting water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008505883A true JP2008505883A (ja) | 2008-02-28 |
| JP2008505883A5 JP2008505883A5 (https=) | 2008-06-05 |
Family
ID=35784249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007519980A Pending JP2008505883A (ja) | 2004-07-08 | 2005-07-07 | 水殺菌用新規固体組成物 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20080038303A1 (https=) |
| EP (1) | EP1778008A4 (https=) |
| JP (1) | JP2008505883A (https=) |
| CN (1) | CN101014241B (https=) |
| AU (1) | AU2005261344B2 (https=) |
| CA (1) | CA2572414A1 (https=) |
| IL (1) | IL162934A0 (https=) |
| MX (1) | MX2007000261A (https=) |
| WO (1) | WO2006006155A2 (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013536816A (ja) * | 2010-08-31 | 2013-09-26 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 新規な殺生物組成物 |
| JP2018030063A (ja) * | 2016-08-23 | 2018-03-01 | 栗田工業株式会社 | 複合型固形水処理製品 |
| WO2018038090A1 (ja) * | 2016-08-23 | 2018-03-01 | 栗田工業株式会社 | 固形水処理剤用容器及び容器セット並びに水処理方法 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030194454A1 (en) * | 1998-07-28 | 2003-10-16 | Bessette Steven M. | Pesticidal compositions containing rosemary oil and wintergreen oil |
| US6863830B1 (en) * | 2003-08-21 | 2005-03-08 | Biolab Services, Inc. | Dual layer tablet, method of making and use thereof |
| EP1830421A3 (en) | 2006-03-03 | 2012-03-14 | Semiconductor Energy Laboratory Co., Ltd. | Light emitting device, manufacturing method of light emitting device, and sheet-like sealing material |
| WO2008110165A1 (en) * | 2007-03-09 | 2008-09-18 | Vestergaard Sa | Microporous filter with a halogen source |
| CN103875709A (zh) * | 2014-04-01 | 2014-06-25 | 青岛市中心医院 | 一种游泳池灭菌剂及其制备方法 |
| CN106417301A (zh) * | 2016-09-12 | 2017-02-22 | 广东海洋大学 | 一种水环境固体消毒片及其制备方法和应用 |
| CN110927155A (zh) * | 2019-12-25 | 2020-03-27 | 上海三爱思试剂有限公司 | 二溴海因消毒剂检测试纸及其制备方法与应用 |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4560766A (en) * | 1983-02-02 | 1985-12-24 | Glyco Chemicals, Inc. | Shaped halogenated hydantoins |
| JPH03221194A (ja) * | 1989-11-06 | 1991-09-30 | Bio Lab Inc | 青色顔料入り乾燥酸化剤組成物 |
| JPH0827119A (ja) * | 1994-07-07 | 1996-01-30 | Nippon Soda Co Ltd | ハロゲン化ジメチルヒダントイン成形物 |
| US5603941A (en) * | 1994-05-03 | 1997-02-18 | Lonza, Inc. | Multifunctional biodispersant/biocidal compositions |
| US5610126A (en) * | 1985-06-14 | 1997-03-11 | Jeyes Group Limited | Lavatory cleansing compositions |
| JP2003520257A (ja) * | 2000-01-18 | 2003-07-02 | アルベマール・コーポレーシヨン | 固めることができない粒子状殺生物剤から固めることができる殺生物剤への結合剤を用いない製造 |
| JP2003520213A (ja) * | 2000-01-18 | 2003-07-02 | アルベマール・コーポレーシヨン | 高められた性質の1,3−ジブロモ−5,5−ジメチルヒダントイン |
| JP2003520256A (ja) * | 2000-01-18 | 2003-07-02 | アルベマール・コーポレーシヨン | 1,3−ジハロ−5,5−ジメチルヒダントインの結合剤を含まない圧縮された形態 |
| US20030228341A1 (en) * | 2000-01-18 | 2003-12-11 | Howarth Jonathan N. | Microbiological control in aqueous systems |
| JP2005508733A (ja) * | 2001-10-09 | 2005-04-07 | アルベマール・コーポレーシヨン | 水系の微生物学的管理 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3873685A (en) * | 1973-09-10 | 1975-03-25 | Fmc Corp | Contiguous shaped chlorine releasing structure |
| US4532330A (en) | 1982-09-30 | 1985-07-30 | Great Lakes Chemical Corporation | Process for producing densified halogenated dimethylhydantoins |
| US4654424A (en) | 1983-02-02 | 1987-03-31 | Glyco Inc. | Method for preparing halogenated hydantoins |
| US4677130A (en) | 1985-10-07 | 1987-06-30 | Great Lakes Chemical Corporation | Process of densification of N-halohydantoin compositions and products thereof |
| US4745189A (en) | 1986-06-23 | 1988-05-17 | Ethyl Corporation | Method of preparing N-halogenated organic heterocyclic compounds |
| US5565576A (en) | 1994-10-27 | 1996-10-15 | Lonza Inc. | Halohydantoin and fatty amide composition for compaction, process of compacting and product produced thereby |
-
2004
- 2004-07-08 IL IL16293404A patent/IL162934A0/xx unknown
-
2005
- 2005-07-07 CN CN2005800230002A patent/CN101014241B/zh not_active Expired - Fee Related
- 2005-07-07 EP EP05758911A patent/EP1778008A4/en not_active Withdrawn
- 2005-07-07 WO PCT/IL2005/000723 patent/WO2006006155A2/en not_active Ceased
- 2005-07-07 MX MX2007000261A patent/MX2007000261A/es active IP Right Grant
- 2005-07-07 AU AU2005261344A patent/AU2005261344B2/en not_active Ceased
- 2005-07-07 CA CA002572414A patent/CA2572414A1/en not_active Abandoned
- 2005-07-07 JP JP2007519980A patent/JP2008505883A/ja active Pending
-
2007
- 2007-03-21 US US11/631,922 patent/US20080038303A1/en not_active Abandoned
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4560766A (en) * | 1983-02-02 | 1985-12-24 | Glyco Chemicals, Inc. | Shaped halogenated hydantoins |
| US5610126A (en) * | 1985-06-14 | 1997-03-11 | Jeyes Group Limited | Lavatory cleansing compositions |
| JPH03221194A (ja) * | 1989-11-06 | 1991-09-30 | Bio Lab Inc | 青色顔料入り乾燥酸化剤組成物 |
| US5603941A (en) * | 1994-05-03 | 1997-02-18 | Lonza, Inc. | Multifunctional biodispersant/biocidal compositions |
| JPH0827119A (ja) * | 1994-07-07 | 1996-01-30 | Nippon Soda Co Ltd | ハロゲン化ジメチルヒダントイン成形物 |
| JP2003520257A (ja) * | 2000-01-18 | 2003-07-02 | アルベマール・コーポレーシヨン | 固めることができない粒子状殺生物剤から固めることができる殺生物剤への結合剤を用いない製造 |
| JP2003520213A (ja) * | 2000-01-18 | 2003-07-02 | アルベマール・コーポレーシヨン | 高められた性質の1,3−ジブロモ−5,5−ジメチルヒダントイン |
| JP2003520256A (ja) * | 2000-01-18 | 2003-07-02 | アルベマール・コーポレーシヨン | 1,3−ジハロ−5,5−ジメチルヒダントインの結合剤を含まない圧縮された形態 |
| US20030228341A1 (en) * | 2000-01-18 | 2003-12-11 | Howarth Jonathan N. | Microbiological control in aqueous systems |
| JP2005508733A (ja) * | 2001-10-09 | 2005-04-07 | アルベマール・コーポレーシヨン | 水系の微生物学的管理 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013536816A (ja) * | 2010-08-31 | 2013-09-26 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 新規な殺生物組成物 |
| JP2018030063A (ja) * | 2016-08-23 | 2018-03-01 | 栗田工業株式会社 | 複合型固形水処理製品 |
| WO2018038091A1 (ja) * | 2016-08-23 | 2018-03-01 | 栗田工業株式会社 | 複合型固形水処理製品 |
| WO2018038090A1 (ja) * | 2016-08-23 | 2018-03-01 | 栗田工業株式会社 | 固形水処理剤用容器及び容器セット並びに水処理方法 |
| JPWO2018038090A1 (ja) * | 2016-08-23 | 2019-06-24 | 栗田工業株式会社 | 固形水処理剤用容器及び容器セット並びに水処理方法 |
| JP7044065B2 (ja) | 2016-08-23 | 2022-03-30 | 栗田工業株式会社 | 固形水処理剤用容器及び容器セット並びに水処理方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| IL162934A0 (en) | 2005-11-20 |
| AU2005261344A1 (en) | 2006-01-19 |
| WO2006006155A2 (en) | 2006-01-19 |
| EP1778008A2 (en) | 2007-05-02 |
| AU2005261344A2 (en) | 2006-01-19 |
| WO2006006155A3 (en) | 2006-04-06 |
| CN101014241B (zh) | 2011-11-23 |
| CA2572414A1 (en) | 2006-01-19 |
| CN101014241A (zh) | 2007-08-08 |
| US20080038303A1 (en) | 2008-02-14 |
| EP1778008A4 (en) | 2009-08-26 |
| AU2005261344B2 (en) | 2010-07-01 |
| MX2007000261A (es) | 2007-04-02 |
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