JP2008071804A - Process for fabricating high temperature superconducting bonding element utilizing phase separation of liquid phase diffusion method - Google Patents
Process for fabricating high temperature superconducting bonding element utilizing phase separation of liquid phase diffusion method Download PDFInfo
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Abstract
Description
本発明は、高温超伝導体において、液相拡散法の相分離を利用した超伝導接合素子及びその製造方法に関するものである。 The present invention relates to a superconducting junction element using phase separation of a liquid phase diffusion method in a high-temperature superconductor and a method for manufacturing the same.
近年、高感度の磁束計や高速・低消費電力の集積回路を目指し、様々な超伝導接合が作製されている。
しかし超伝導接合の製作には高度の加工技術が要求され、これが普及遅延の原因になっている。
However, the manufacture of superconducting junctions requires a high level of processing technology, which causes a delay in popularization.
本発明は上記目的を解決するため、超伝導接合の製造方法において、高温超伝導薄膜を、希土類常伝導相を含む三層構造薄膜にする。そして、三層構造薄膜を部分溶融することより相分離させ、超伝導薄膜に常伝導層を形成し接合を作製する。 In order to solve the above-mentioned object, the present invention changes a high-temperature superconducting thin film to a three-layered thin film containing a rare earth normal conducting phase in a method for producing a superconducting junction. Then, the three-layer structure thin film is partially melted to cause phase separation, and a normal conduction layer is formed on the superconducting thin film to produce a bond.
常伝導/超伝導/常伝導の三層構造薄膜を堆積する。エッチング等により傾斜を持つようにパターニングする。超伝導薄膜を部分溶融し、常伝導層を形成する。エッチングにより常伝導層の厚さを制御する。超伝導薄膜を堆積し上部電極とする。 Deposit normal / superconducting / normal conducting three-layered thin films. Patterning so as to have an inclination by etching or the like. A superconducting thin film is partially melted to form a normal conducting layer. The thickness of the normal layer is controlled by etching. A superconducting thin film is deposited to form the upper electrode.
脳から発生している微小磁束などを、本センサーで検出することや、高速・低消費電力の集積回路用素子となる。 The sensor detects small magnetic flux generated from the brain, and it becomes a high-speed, low-power-consumption device for integrated circuits.
次いで、本実施形態による超伝導接合素子の製造方法について図1から図4を用いて説明する。 Next, the method for manufacturing the superconducting junction element according to the present embodiment will be explained with reference to FIGS.
まず、図1のように、MgO基板上(1)に、例えばスパッタ法により、膜厚約100nmのGd211(2)膜、膜厚約200nmのY123膜(3)、膜厚約100nmのGd211(2)膜を連続堆積する。 First, as shown in FIG. 1, on a MgO substrate (1), a Gd211 (2) film having a film thickness of about 100 nm, a Y123 film (3) having a film thickness of about 200 nm, and a Gd211 (film having a film thickness of about 100 nm are formed by sputtering. 2) Deposit films continuously.
次いで、Gd211(2)膜上に、通常のリソグラフィー技術によりレジストパターンを形成する。 Next, a resist pattern is formed on the Gd211 (2) film by a normal lithography technique.
次いで、レジストパターンをマスクとして、例えば燐酸水溶液かArイオンミリングにより、Gd211(2)膜、Y123膜(3)及びGd211(2)膜を傾斜45°でエッチングする。 Next, using the resist pattern as a mask, the Gd211 (2) film, the Y123 film (3), and the Gd211 (2) film are etched at an inclination of 45 ° by, for example, phosphoric acid aqueous solution or Ar ion milling.
次いで、レジストパターンを除去した後、部分溶融温度まで基板加熱し、Y123膜(3)表面にY211(4)と液相を相分離させる。 Next, after removing the resist pattern, the substrate is heated to the partial melting temperature, and Y211 (4) and the liquid phase are phase-separated on the surface of the Y123 film (3).
このとき、Y123より相分離した液相は包昌反応により、図2のように、Gd211(2)とY211(4)に接している面にGd123(5)が形成される。 At this time, the liquid phase phase-separated from Y123 forms Gd123 (5) on the surface in contact with Gd211 (2) and Y211 (4) as shown in FIG.
次いで、図3のように上部Y123(3)膜を堆積する前処理として、例えばECRプラズマによるクリーニングを行い、Y123膜表面のY211膜厚(4)を制御する。 Next, as a pretreatment for depositing the upper Y123 (3) film as shown in FIG. 3, for example, cleaning with ECR plasma is performed to control the Y211 film thickness (4) on the surface of the Y123 film.
このクリーニング処理により、YBCO膜のエッジには、Y211膜厚(4)が制御できる。 By this cleaning process, the Y211 film thickness (4) can be controlled at the edge of the YBCO film.
なお、本実施形態による超伝導接合素子の製造方法では、Y123膜のエッジに形成されるバリア層の膜厚は、Y211膜の膜厚に依存する。したがって、Y211膜の膜厚を予め部分溶融時間で制御しておくことで、所望の厚さのバリア層を形成することができる(図3)。 In the superconducting junction element manufacturing method according to the present embodiment, the thickness of the barrier layer formed at the edge of the Y123 film depends on the thickness of the Y211 film. Therefore, a barrier layer having a desired thickness can be formed by previously controlling the film thickness of the Y211 film with the partial melting time (FIG. 3).
次いで、例えばレーザーアブレーション法により、図3のように膜厚200nmのY123(3)膜を堆積してパターニングし、Y123(3)よりなる超伝導層を形成する(図4)。 Next, a Y123 (3) film having a thickness of 200 nm is deposited and patterned by laser ablation, for example, as shown in FIG. 3 to form a superconducting layer made of Y123 (3) (FIG. 4).
このようにして、超伝導層Y123より延在するバリア層Y211を介して超伝導層Y123(3)が接合された平面型ジョセフソン接合を有する超伝導接合素子を形成する。 In this manner, a superconducting junction element having a planar Josephson junction in which the superconducting layer Y123 (3) is joined via the barrier layer Y211 extending from the superconducting layer Y123 is formed.
このように、本実施形態によれば、超伝導層と超伝導層との間に形成されるバリア層の膜厚を、Y211膜の膜厚により制御するので、バリア層の厚さが均一な接合を形成することができる。これにより、素子のばらつきを抑えることができる。 As described above, according to this embodiment, the thickness of the barrier layer formed between the superconducting layer is controlled by the thickness of the Y211 film, so that the thickness of the barrier layer is uniform. A bond can be formed. Thereby, the dispersion | variation in an element can be suppressed.
なお、上記実施形態では、接合部の傾斜角度を45°とした平面型ジョセフソン接合を有する超伝導接合素子を示したが、接合部の傾斜角度を例えば60°としたランプエッジ型ジョセフソン接合を有する超伝導接合素子においても同様に適用することができる。 In the above-described embodiment, a superconducting junction element having a planar Josephson junction in which the inclination angle of the junction is 45 ° is shown. However, a ramp edge type Josephson junction in which the inclination angle of the junction is 60 °, for example. The present invention can be similarly applied to a superconducting junction element having the following.
さらに、従来のNb系超伝導接合作製技術を用いて、超伝導層Y123上部に相分離したY211をバリア層とする超伝導接合素子も作製可能である。 Furthermore, a superconducting junction element using Y211 phase-separated on the superconducting layer Y123 as a barrier layer can also be fabricated using a conventional Nb-based superconducting junction fabrication technique.
1 MgO基板
2 Gd2BaCuO膜
3 YBa2Cu3O膜
4 Y2BaCuO膜
5 GdBa2Cu3O膜
1
5 GdBa2Cu3O film
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0945970A (en) * | 1995-08-03 | 1997-02-14 | Matsushita Electric Ind Co Ltd | Superconducting element |
JPH0945976A (en) * | 1995-08-03 | 1997-02-14 | Matsushita Electric Ind Co Ltd | Nonlinear element |
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Publication number | Priority date | Publication date | Assignee | Title |
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JPH0945970A (en) * | 1995-08-03 | 1997-02-14 | Matsushita Electric Ind Co Ltd | Superconducting element |
JPH0945976A (en) * | 1995-08-03 | 1997-02-14 | Matsushita Electric Ind Co Ltd | Nonlinear element |
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