JP2007514200A - 増感されたハロゲン化銀を含有するフォトサーモグラフィ材料 - Google Patents

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Publication number

JP2007514200A

JP2007514200A JP2006543863A JP2006543863A JP2007514200A JP 2007514200 A JP2007514200 A JP 2007514200A JP 2006543863 A JP2006543863 A JP 2006543863A JP 2006543863 A JP2006543863 A JP 2006543863A JP 2007514200 A JP2007514200 A JP 2007514200A

Authority

JP

Japan

Prior art keywords

silver

photothermographic

photosensitive

gold

silver halide

Prior art date

2003-12-09

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Withdrawn

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• -1 silver halide Chemical class 0.000 title claims abstract description 324
• 229910052709 silver Inorganic materials 0.000 title claims abstract description 298
• 239000004332 silver Substances 0.000 title claims abstract description 297
• 239000000463 material Substances 0.000 title claims description 378
• 150000001875 compounds Chemical class 0.000 claims abstract description 284
• 239000000839 emulsion Substances 0.000 claims abstract description 117
• 239000000126 substance Substances 0.000 claims abstract description 67
• 229910052717 sulfur Inorganic materials 0.000 claims abstract description 45
• CBMIPXHVOVTTTL-UHFFFAOYSA-N gold(3+) Chemical group [Au+3] CBMIPXHVOVTTTL-UHFFFAOYSA-N 0.000 claims abstract description 44
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 42
• 239000011593 sulfur Substances 0.000 claims abstract description 42
• 230000001235 sensitizing effect Effects 0.000 claims abstract description 36
• CHYUXCABJMXHJN-UHFFFAOYSA-N diphenyl(sulfanylidene)phosphanium Chemical group C=1C=CC=CC=1[P+](=S)C1=CC=CC=C1 CHYUXCABJMXHJN-UHFFFAOYSA-N 0.000 claims abstract description 19
• 239000010410 layer Substances 0.000 claims description 166
• 239000000203 mixture Substances 0.000 claims description 126
• 238000000034 method Methods 0.000 claims description 93
• 238000003384 imaging method Methods 0.000 claims description 74
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 72
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 60
• 238000009472 formulation Methods 0.000 claims description 58
• 239000011230 binding agent Substances 0.000 claims description 43
• 239000003638 chemical reducing agent Substances 0.000 claims description 42
• 150000003378 silver Chemical class 0.000 claims description 41
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 37
• 230000003595 spectral effect Effects 0.000 claims description 37
• 230000005855 radiation Effects 0.000 claims description 33
• 239000010931 gold Substances 0.000 claims description 32
• 239000011248 coating agent Substances 0.000 claims description 31
• 238000000576 coating method Methods 0.000 claims description 31
• FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 28
• PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 28
• 229910052737 gold Inorganic materials 0.000 claims description 26
• GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 26
• 206010070834 Sensitisation Diseases 0.000 claims description 25
• 230000008313 sensitization Effects 0.000 claims description 25
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 23
• 230000008569 process Effects 0.000 claims description 20
• 239000003446 ligand Substances 0.000 claims description 19
• 150000004820 halides Chemical class 0.000 claims description 18
• RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 18
• 229960005070 ascorbic acid Drugs 0.000 claims description 17
• 125000005647 linker group Chemical group 0.000 claims description 17
• 229910052761 rare earth metal Inorganic materials 0.000 claims description 17
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
• 235000010323 ascorbic acid Nutrition 0.000 claims description 16
• 239000011668 ascorbic acid Substances 0.000 claims description 16
• VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 claims description 16
• 125000000217 alkyl group Chemical group 0.000 claims description 15
• 125000004432 carbon atom Chemical group C* 0.000 claims description 15
• 150000003839 salts Chemical class 0.000 claims description 15
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 14
• 238000007792 addition Methods 0.000 claims description 14
• 229910052736 halogen Inorganic materials 0.000 claims description 14
• 150000002367 halogens Chemical class 0.000 claims description 14
• 238000004519 manufacturing process Methods 0.000 claims description 14
• 150000002910 rare earth metals Chemical class 0.000 claims description 14
• 238000010438 heat treatment Methods 0.000 claims description 13
• 239000007800 oxidant agent Substances 0.000 claims description 13
• 229920000642 polymer Polymers 0.000 claims description 13
• JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 12
• 229910052771 Terbium Inorganic materials 0.000 claims description 12
• 239000011575 calcium Substances 0.000 claims description 12
• 239000006185 dispersion Substances 0.000 claims description 12
• 229910052751 metal Inorganic materials 0.000 claims description 12
• 239000002184 metal Substances 0.000 claims description 12
• 229910052693 Europium Inorganic materials 0.000 claims description 11
• 229910052739 hydrogen Inorganic materials 0.000 claims description 11
• 239000001257 hydrogen Substances 0.000 claims description 11
• 230000001590 oxidative effect Effects 0.000 claims description 11
• ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 11
• CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 10
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 10
• XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 10
• 230000002209 hydrophobic effect Effects 0.000 claims description 10
• AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 10
• 239000011777 magnesium Substances 0.000 claims description 10
• 229910052757 nitrogen Inorganic materials 0.000 claims description 10
• GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 10
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
• 229910052798 chalcogen Inorganic materials 0.000 claims description 9
• 150000001787 chalcogens Chemical class 0.000 claims description 9
• KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 8
• 229910052772 Samarium Inorganic materials 0.000 claims description 8
• 125000001931 aliphatic group Chemical group 0.000 claims description 8
• 150000001450 anions Chemical class 0.000 claims description 8
• 125000003118 aryl group Chemical group 0.000 claims description 8
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
• 229910052799 carbon Inorganic materials 0.000 claims description 8
• OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 8
• 239000010955 niobium Substances 0.000 claims description 8
• 229910052760 oxygen Inorganic materials 0.000 claims description 8
• 239000001301 oxygen Substances 0.000 claims description 8
• 239000011241 protective layer Substances 0.000 claims description 8
• 239000011734 sodium Substances 0.000 claims description 8
• 229940102001 zinc bromide Drugs 0.000 claims description 8
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
• 229910052765 Lutetium Inorganic materials 0.000 claims description 7
• 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
• BULYQPQVGJVSJD-UHFFFAOYSA-N diphenyl(sulfanylidene)-lambda5-phosphane Chemical class C=1C=CC=CC=1P(=S)C1=CC=CC=C1 BULYQPQVGJVSJD-UHFFFAOYSA-N 0.000 claims description 7
• 230000005670 electromagnetic radiation Effects 0.000 claims description 7
• OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 7
• 229910052711 selenium Inorganic materials 0.000 claims description 7
• ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 claims description 7
• 125000004434 sulfur atom Chemical group 0.000 claims description 7
• 229910052714 tellurium Inorganic materials 0.000 claims description 7
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
• 229910052684 Cerium Inorganic materials 0.000 claims description 6
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
• 150000001342 alkaline earth metals Chemical class 0.000 claims description 6
• 229910052791 calcium Inorganic materials 0.000 claims description 6
• 229910001502 inorganic halide Inorganic materials 0.000 claims description 6
• KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 6
• 239000011669 selenium Substances 0.000 claims description 6
• AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 claims description 6
• 229910052727 yttrium Inorganic materials 0.000 claims description 6
• UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 claims description 6
• 229910052688 Gadolinium Inorganic materials 0.000 claims description 5
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
• XXWDKWAUNILFEM-UHFFFAOYSA-N S.[Au+3] Chemical compound S.[Au+3] XXWDKWAUNILFEM-UHFFFAOYSA-N 0.000 claims description 5
• 229910001622 calcium bromide Inorganic materials 0.000 claims description 5
• WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 5
• GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 5
• UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 5
• 125000005842 heteroatom Chemical group 0.000 claims description 5
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
• 229910052758 niobium Inorganic materials 0.000 claims description 5
• 230000002165 photosensitisation Effects 0.000 claims description 5
• 239000003504 photosensitizing agent Substances 0.000 claims description 5
• 229910052700 potassium Inorganic materials 0.000 claims description 5
• 239000011591 potassium Substances 0.000 claims description 5
• UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 5
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
• BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 4
• 229910052788 barium Inorganic materials 0.000 claims description 4
• DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 4
• 125000001246 bromo group Chemical group Br* 0.000 claims description 4
• 229910052792 caesium Inorganic materials 0.000 claims description 4
• TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 4
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
• 239000011651 chromium Substances 0.000 claims description 4
• 238000001035 drying Methods 0.000 claims description 4
• 229910052746 lanthanum Inorganic materials 0.000 claims description 4
• FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 4
• 239000004816 latex Substances 0.000 claims description 4
• 229920000126 latex Polymers 0.000 claims description 4
• 229910052749 magnesium Inorganic materials 0.000 claims description 4
• 239000011572 manganese Substances 0.000 claims description 4
• 229910052701 rubidium Inorganic materials 0.000 claims description 4
• IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 4
• 229910052708 sodium Inorganic materials 0.000 claims description 4
• 229910052712 strontium Inorganic materials 0.000 claims description 4
• CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 4
• 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 4
• PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 4
• 150000003852 triazoles Chemical class 0.000 claims description 4
• JFJNVIPVOCESGZ-UHFFFAOYSA-N 2,3-dipyridin-2-ylpyridine Chemical compound N1=CC=CC=C1C1=CC=CN=C1C1=CC=CC=N1 JFJNVIPVOCESGZ-UHFFFAOYSA-N 0.000 claims description 3
• CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims description 3
• 229910052775 Thulium Inorganic materials 0.000 claims description 3
• 150000007942 carboxylates Chemical class 0.000 claims description 3
• 239000007858 starting material Substances 0.000 claims description 3
• 229910052715 tantalum Inorganic materials 0.000 claims description 3
• GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
• VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical group [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
• VMKYTRPNOVFCGZ-UHFFFAOYSA-N 2-sulfanylphenol Chemical compound OC1=CC=CC=C1S VMKYTRPNOVFCGZ-UHFFFAOYSA-N 0.000 claims description 2
• 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
• ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 2
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
• 229910052692 Dysprosium Inorganic materials 0.000 claims description 2
• 229910052691 Erbium Inorganic materials 0.000 claims description 2
• 229910005793 GeO 2 Inorganic materials 0.000 claims description 2
• 229910052689 Holmium Inorganic materials 0.000 claims description 2
• 229910021193 La 2 O 3 Inorganic materials 0.000 claims description 2
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
• 229910052779 Neodymium Inorganic materials 0.000 claims description 2
• 229910052777 Praseodymium Inorganic materials 0.000 claims description 2
• 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
• 229910006404 SnO 2 Inorganic materials 0.000 claims description 2
• 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
• 229910052769 Ytterbium Inorganic materials 0.000 claims description 2
• GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims description 2
• 229910052804 chromium Inorganic materials 0.000 claims description 2
• 229910017052 cobalt Inorganic materials 0.000 claims description 2
• 239000010941 cobalt Substances 0.000 claims description 2
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
• OAEGRYMCJYIXQT-UHFFFAOYSA-N dithiooxamide Chemical compound NC(=S)C(N)=S OAEGRYMCJYIXQT-UHFFFAOYSA-N 0.000 claims description 2
• KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 2
• UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 2
• 229930195729 fatty acid Natural products 0.000 claims description 2
• 239000000194 fatty acid Substances 0.000 claims description 2
• 150000004665 fatty acids Chemical class 0.000 claims description 2
• KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 2
• 150000002431 hydrogen Chemical class 0.000 claims description 2
• 150000002466 imines Chemical class 0.000 claims description 2
• 229910052748 manganese Inorganic materials 0.000 claims description 2
• QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 2
• 229910052759 nickel Inorganic materials 0.000 claims description 2
• GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
• 125000004437 phosphorous atom Chemical group 0.000 claims description 2
• PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 2
• 229940071182 stannate Drugs 0.000 claims description 2
• FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 claims description 2
• PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims description 2
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• NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 2
• 125000004663 dialkyl amino group Chemical group 0.000 claims 1
• 150000002344 gold compounds Chemical class 0.000 claims 1
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• 230000001965 increasing effect Effects 0.000 abstract description 16
• 239000000975 dye Substances 0.000 description 93
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 46
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 30
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• NSBNSZAXNUGWDJ-UHFFFAOYSA-O monopyridin-1-ium tribromide Chemical compound Br[Br-]Br.C1=CC=[NH+]C=C1 NSBNSZAXNUGWDJ-UHFFFAOYSA-O 0.000 description 18
• 239000002245 particle Substances 0.000 description 17
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• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
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• 125000001424 substituent group Chemical group 0.000 description 10
• 108010010803 Gelatin Proteins 0.000 description 9
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 9
• 239000008199 coating composition Substances 0.000 description 9
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• 229920000159 gelatin Polymers 0.000 description 9
• 239000008273 gelatin Substances 0.000 description 9
• 235000019322 gelatine Nutrition 0.000 description 9
• 235000011852 gelatine desserts Nutrition 0.000 description 9
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• IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 8
• 239000002243 precursor Substances 0.000 description 8
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• 229910052782 aluminium Inorganic materials 0.000 description 7
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
• 239000011258 core-shell material Substances 0.000 description 7
• LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical group C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 7
• UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 7
• 238000002835 absorbance Methods 0.000 description 6
• 125000004429 atom Chemical group 0.000 description 6
• XSCHRSMBECNVNS-UHFFFAOYSA-N benzopyrazine Natural products N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 6
• 229920006217 cellulose acetate butyrate Polymers 0.000 description 6
• 230000000052 comparative effect Effects 0.000 description 6
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