JP2007510003A - メタロセン触媒型線状低密度ポリエチレンポリマーのための加工助剤 - Google Patents
メタロセン触媒型線状低密度ポリエチレンポリマーのための加工助剤 Download PDFInfo
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- 229920000092 linear low density polyethylene Polymers 0.000 title claims abstract description 9
- 239000004707 linear low-density polyethylene Substances 0.000 title claims abstract description 9
- 229920000642 polymer Polymers 0.000 title claims description 19
- 239000006057 Non-nutritive feed additive Substances 0.000 title abstract description 24
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- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 13
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 8
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
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- 125000003118 aryl group Chemical group 0.000 claims description 3
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- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
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- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 229920013716 polyethylene resin Polymers 0.000 claims 1
- 229920005609 vinylidenefluoride/hexafluoropropylene copolymer Polymers 0.000 claims 1
- 238000001125 extrusion Methods 0.000 abstract description 9
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- 238000000034 method Methods 0.000 description 10
- 229920002313 fluoropolymer Polymers 0.000 description 9
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- 239000003054 catalyst Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
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- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 5
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
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- QAERDLQYXMEHEB-UHFFFAOYSA-N 1,1,3,3,3-pentafluoroprop-1-ene Chemical group FC(F)=CC(F)(F)F QAERDLQYXMEHEB-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
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- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
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- AXKZIDYFAMKWSA-UHFFFAOYSA-N 1,6-dioxacyclododecane-7,12-dione Chemical compound O=C1CCCCC(=O)OCCCCO1 AXKZIDYFAMKWSA-UHFFFAOYSA-N 0.000 description 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
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- 238000003379 elimination reaction Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- RSVIRMFSJVHWJV-UHFFFAOYSA-N n,n-dimethyloctan-1-amine oxide Chemical compound CCCCCCCC[N+](C)(C)[O-] RSVIRMFSJVHWJV-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229920006120 non-fluorinated polymer Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Description
A)樹脂ブレンドの全重量を基準にして1〜99重量%のメタロセン触媒型線状低密度ポリエチレン樹脂および樹脂ブレンドの全重量を基準にして99〜1重量%の低密度ポリエチレン樹脂を含む樹脂ブレンド、
B)押出し成形可能な組成物の全重量を基準にして25〜2000ppmの、121℃におけるムーニー粘度ML(1+10)が30〜60であるフルオロエラストマーおよび
C)フルオロエラストマーに対する界面剤の重量比が0.1〜0.9となる量の界面剤、
を含む押出し成形可能な組成物であって、0〜20ppmのイオノマーを含有する押出し成形可能な組成物である。
mLL−LDPE樹脂ブレンドは、「エクソンモービル(ExxonMobil)」1018C mLLと「ダウ(Dow)」640i LDPEの70/30(重量)ブレンドであった。各樹脂のメルトインデックス(190℃、2160g)はそれぞれ1および2であった。
PPA−1:a)75の121℃におけるML(1+10)を有する52重量%のフッ化ビニリデン/ヘキサフルオロプロピレン(60/40重量比)コポリマーフルオロエラストマー、b)42重量%のポリエチレングリコールおよびc)残りのミネラル分配剤を含むブレンド。
PPA−2:a)75の121℃におけるML(1+10)を有する32重量%のフッ化ビニリデン/ヘキサフルオロプロピレン(60/40重量比)コポリマーフルオロエラストマー、b)65重量%のポリカプロラクトンおよびc)残りのミネラル分配剤を含むブレンド。
PPA−3:a)40の121℃におけるML(1+10)を有する66重量%のフッ化ビニリデン/ヘキサフルオロプロピレン(60/40重量比)コポリマーフルオロエラストマー、b)27重量%のポリカプロラクトンおよびc)残りのミネラル分配剤を含むブレンド。
mLL−LDPE樹脂ブレンド中のそれぞれのポリマー加工助剤マスターバッチを押出機に落とすことにより、比較される押出し成形可能な組成物(サンプルA〜B)および本発明の押出し成形可能な組成物(サンプル1)を調製した。押出し成形可能な組成物中の全加工助剤濃度(フルオロエラストマー+界面剤)は500ppmであった。
Claims (9)
- A)樹脂ブレンドの全重量を基準にして1〜99重量%のメタロセン触媒型線状低密度ポリエチレン樹脂および樹脂ブレンドの全重量を基準にして99〜1重量%の低密度ポリエチレン樹脂を含む樹脂ブレンド、
B)押出し成形可能な組成物の全重量を基準にして25〜2000ppmの、121℃におけるムーニー粘度ML(1+10)が30〜60であるフルオロエラストマーおよび
C)フルオロエラストマーに対する界面剤の重量比が0.1〜0.9となる量の界面剤、
を含む押出し成形可能な組成物であって、該組成物が0〜20ppmのイオノマーを含有することを特徴とする押出し成形可能な組成物。 - 前記樹脂ブレンドが、前記樹脂ブレンドの全重量を基準にして、50〜90重量%のメタロセン触媒型線状低密度ポリエチレン樹脂および前記樹脂ブレンドの全重量を基準にして、50〜10重量%の低密度ポリエチレン樹脂を含むことを特徴とする請求項1に記載の押出し成形可能な組成物。
- 前記フルオロエラストマーが、i)フッ化ビニリデン/ヘキサフルオロプロピレン、
ii)フッ化ビニリデン/ヘキサフルオロプロピレン/テトラフルオロエチレン、iii)テトラフルオロエチレン/プロピレンおよびiv)テトラフルオロエチレン/プロピレン/フッ化ビニリデンからなる群から選択された共重合単位を含むことを特徴とする請求項1に記載の押出し成形可能な組成物。 - 前記フルオロエラストマーがフッ化ビニリデン/ヘキサフルオロプロピレンの共重合単位を含むことを特徴とする請求項3に記載の押出し成形可能な組成物。
- 前記界面剤がi)シリコーン−ポリエーテルコポリマー、ii)脂肪族ポリエステル、iii)芳香族ポリエステル、iv)ポリエーテルポリオール、v)アミンオキシド、vi)カルボン酸、vii)脂肪酸エステルおよびvii)ポリ(オキシアルキレン)ポリマーからなる群から選択されることを特徴とする請求項1に記載の押出し成形可能な組成物。
- 前記界面剤が脂肪族ポリエステルであることを特徴とする請求項5に記載の押出し成形可能な組成物。
- 前記脂肪族ポリエステルが1000〜32000の数平均分子量を有するポリカプロラクトンであることを特徴とする請求項6に記載の押出し成形可能な組成物。
- 前記界面剤がポリ(オキシアルキレン)ポリマーであることを特徴とする請求項5に記載の押出し成形可能な組成物。
- 前記ポリ(オキシアルキレン)ポリマーがポリエチレングリコールであることを特徴とする請求項8に記載の押出し成形可能な組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US49644703P | 2003-08-20 | 2003-08-20 | |
US10/911,037 US7238748B2 (en) | 2003-08-20 | 2004-08-04 | Process aid for metallocene catalyzed linear low density polyethylene polymers |
PCT/US2004/026795 WO2005019334A1 (en) | 2003-08-20 | 2004-08-18 | Process aid for metallocene catalyzed linear low density polyethylene polymers |
Publications (2)
Publication Number | Publication Date |
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JP2007510003A true JP2007510003A (ja) | 2007-04-19 |
JP2007510003A5 JP2007510003A5 (ja) | 2007-09-06 |
Family
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JP2006524002A Pending JP2007510003A (ja) | 2003-08-20 | 2004-08-18 | メタロセン触媒型線状低密度ポリエチレンポリマーのための加工助剤 |
Country Status (5)
Country | Link |
---|---|
US (1) | US7238748B2 (ja) |
JP (1) | JP2007510003A (ja) |
BR (1) | BRPI0412622A (ja) |
CA (1) | CA2534229A1 (ja) |
WO (1) | WO2005019334A1 (ja) |
Cited By (5)
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WO2011025052A1 (en) * | 2009-08-27 | 2011-03-03 | Daikin Industries, Ltd. | Processing additive, molding composition, masterbatch of processing additive and molding article |
WO2014203727A1 (ja) | 2013-06-21 | 2014-12-24 | ダイキン工業株式会社 | 加工助剤、及び組成物 |
WO2015098867A1 (ja) | 2013-12-26 | 2015-07-02 | ダイキン工業株式会社 | ポリオレフィン用加工助剤、及び、ポリオレフィン組成物 |
US10308800B2 (en) | 2014-08-21 | 2019-06-04 | Daikin Industries, Ltd. | Processing aid |
US11274172B2 (en) | 2009-08-27 | 2022-03-15 | Daikin Industries, Ltd. | Processing additive, molding composition masterbatch of processing additive and molding article |
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US10662324B2 (en) | 2014-08-21 | 2020-05-26 | Daikin Industries, Ltd. | Processing aid |
Also Published As
Publication number | Publication date |
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CA2534229A1 (en) | 2005-03-03 |
US20050043456A1 (en) | 2005-02-24 |
US7238748B2 (en) | 2007-07-03 |
BRPI0412622A (pt) | 2006-09-26 |
WO2005019334A1 (en) | 2005-03-03 |
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