JP2007297286A - 3,7−ジメチル−5−オクテン酸とその誘導体、およびそれらを含有する香料組成物。 - Google Patents
3,7−ジメチル−5−オクテン酸とその誘導体、およびそれらを含有する香料組成物。 Download PDFInfo
- Publication number
- JP2007297286A JP2007297286A JP2006123818A JP2006123818A JP2007297286A JP 2007297286 A JP2007297286 A JP 2007297286A JP 2006123818 A JP2006123818 A JP 2006123818A JP 2006123818 A JP2006123818 A JP 2006123818A JP 2007297286 A JP2007297286 A JP 2007297286A
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- Prior art keywords
- dimethyl
- octenoic acid
- group
- acid
- fragrance
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 35
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- 239000002304 perfume Substances 0.000 title abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 24
- 235000013305 food Nutrition 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 239000002537 cosmetic Substances 0.000 claims abstract description 9
- 239000003205 fragrance Substances 0.000 claims description 32
- 239000000126 substance Substances 0.000 claims description 20
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- BVPJGXAHSVNERV-UHFFFAOYSA-N 7,7-dimethyloct-5-enoic acid Chemical compound CC(C=CCCCC(=O)O)(C)C BVPJGXAHSVNERV-UHFFFAOYSA-N 0.000 claims description 2
- -1 alkynyl ester compounds Chemical class 0.000 abstract description 10
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- 239000000463 material Substances 0.000 abstract description 2
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- 230000015572 biosynthetic process Effects 0.000 description 4
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- 239000012044 organic layer Substances 0.000 description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 3
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- 239000000606 toothpaste Substances 0.000 description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 2
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- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- IFYYFLINQYPWGJ-VIFPVBQESA-N gamma-Decalactone Natural products CCCCCC[C@H]1CCC(=O)O1 IFYYFLINQYPWGJ-VIFPVBQESA-N 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 235000015243 ice cream Nutrition 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 235000008446 instant noodles Nutrition 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229940043353 maltol Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- DILOFCBIBDMHAY-UHFFFAOYSA-N methyl 2-(3,4-dimethoxyphenyl)acetate Chemical compound COC(=O)CC1=CC=C(OC)C(OC)=C1 DILOFCBIBDMHAY-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- JPTOCTSNXXKSSN-UHFFFAOYSA-N methylheptenone Chemical compound CCCC=CC(=O)CC JPTOCTSNXXKSSN-UHFFFAOYSA-N 0.000 description 1
- 235000020124 milk-based beverage Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000002324 mouth wash Substances 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000013606 potato chips Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000001844 prenyl group Chemical group [H]C([*])([H])C([H])=C(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 235000011962 puddings Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000004366 reverse phase liquid chromatography Methods 0.000 description 1
- 238000004007 reversed phase HPLC Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 235000015961 tonic Nutrition 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 229960000716 tonics Drugs 0.000 description 1
- MBDOYVRWFFCFHM-UHFFFAOYSA-N trans-2-hexenal Natural products CCCC=CC=O MBDOYVRWFFCFHM-UHFFFAOYSA-N 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Seasonings (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Abstract
飲食品や香粧品に要求される嗜好性が多様化してきていることから、各種各様の特徴ある香気特性を有する香料組成物が求められており、特に従来にない香気特性を有する香料組成物が求められている。
【解決手段】
3,7−ジメチル−5E−オクテン酸、3,7−ジメチル−5Z−オクテン酸、ならびにこれらの低級アルキルまたはアルキニルエステル化合物が、従来にない香調を持つ特徴的な香気特性を有し、またこれらの化合物を含有する香料組成物は有用な調合素材となる。
【選択図】 なし
Description
Bulletin de l‘Academie Polonaise des Sciences, Serie des Sciences Chimiques, 第25巻, 529−40頁(1977年) Synthesis, 767−768頁(1976年)
1H−NMR(400MHz,CDCl3,δppm):0.91(3H,d),0.96(3H,d),1.24(3H,d),1.90−2.10(4H,m),2.25(1H,m),2.30(1H,dd),5.01(1H,m),5.20−5.45(2H,m)
13C−NMR(100MHz,CDCl3,δppm):19.6,21.8,21.9,22.6,22.7,30.5,30.9,39.6,40.8,67.4,124.3,140.1,172.9
EI−MS(m/z,相対強度)212(M+,2),169(12),153(38),152(52),110(100),109(49),95(82),81(17),69(75),55(34),43(34),41(40)
1H−NMR(400MHz,CDCl3,δppm):0.94(6H,d),0.95(3H,d),1.23(3H,d),1.94−2.10(4H,m),2.29(1H,dd),2.56(1H,m),5.01(1H,m),5.15−5.30(2H,m)
13C−NMR(100MHz,CDCl3,δppm):19.5,21.8,21.9,23.1,23.1,26.4,30.9,34.1,41.6,67.3,124.7,139.1,172.8
EI−MS(m/z,相対強度)184(M+,1),153(15),152(38),110(66),95(100),69(31),55(29),41(25)
1H−NMR(400MHz,CDCl3,δppm):0.93(6H,d),0.95(3H,d),1.90−2.15(4H,m),2.34(1H,dd),2.55(1H,m),5.15−5.30(2H,m)
13C−NMR(100MHz,CDCl3,δppm):19.7,23.0,23.1,26.4,30.8,34.2,41.0,51.4,124.6,139.2,173.7
EI−MS(m/z,相対強度)170(M+,3),152(20),110(63),95(100),69(46),55(52),41(38)
1H−NMR(400MHz,CDCl3,δppm):0.93(6H,d),0.98(3H,d),1.96−2.18(4H,m),2.40(1H,dd),2.56(1H,m),5.17−5.32(2H,m)
13C−NMR(100MHz,CDCl3,δppm):19.6,23.1,23.1,26.5,30.6,34.1,41.7,124.5,139.4,178.5
上記画分のなかで、酢酸エチル3%、ヘキサン97%の混合溶媒を用いて溶出した画分55gを、ジエチルエーテルに溶かし、10%炭酸ナトリウム水溶液で酸性成分を抽出した。水層を希塩酸でpHを3に調整し、酢酸エチルで抽出した。洗浄、乾燥後、減圧濃縮したところ、強い酸臭を有する0.6gの油状物質を得た。
EI−MS(m/z,相対強度)184(M+,1),153(15),152(38),110(66),95(100),69(31),55(29),41(25)
1H−NMR(400MHz,CDCl3,δppm):0.92(3H,d),0.96(6H,d),1.89−2.15(4H,m),2.25(1H,m),2.33(1H,dd),5.25−5.45(2H,m)
13C−NMR(100MHz,CDCl3,δppm):19.6,22.6,22.6,30.6,31.1,39.7,40.9,51.4,124.4,140.1,173.8
GC−MS(RI,DB−WAX):2128
EI−MS(m/z,相対強度)170(M+,3),152(20),110(63),95(100),69(46),55(52),41(38)
GC−MS(RI,DB−WAX):2147
EI−MS(m/z,相対強度)170(M+,3),152(20),110(63),95(100),69(46),55(52),41(38)
成分名 実施例 比較例
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ペパーミントオイル 61.9 62.0
メントール 30.0 30.0
ユーカリ オイル 5.0 5.0
シトラス オイル 3.0 3.0
実施例3で合成した化合物 0.1 添加せず
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 100.0 100.0
成分名 実施例 比較例
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
エタノール 526.7 527.7
精製水 400.0 400.0
イソアミル アセテート 15.0 15.0
エチル ブチレート 12.0 12.0
エチル アセテート 8.0 8.0
ヘキサノール 6.0 6.0
イソアミル イソバレレート 6.0 6.0
トランス−2−ヘキサナール 5.0 5.0
ヘキサナール 5.0 5.0
2−メチル酪酸 4.0 4.0
アセトアルデヒドジエチルアセタール 4.0 4.0
プロピオン酸 3.0 3.0
ブチル ホーメイト 2.0 2.0
エチル イソバレレート 2.0 2.0
ヘキサナール 0.2 0.2
ダマセノン 0.1 0.1
実施例1で合成した幾何異性体混合物 0.1 添加せず
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 100.0 100.0
成分名 実施例 比較例
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
エタノール 557.5 560.0
精製水 400.0 400.0
ヘキシル アセテート 15.0 15.0
エチル アセテート 10.0 10.0
シス−3−ヘキセノール 6.0 6.0
イソアミル アセテート 5.0 5.0
ヘキシル ブチレート 2.0 2.0
2−メチル酪酸 1.0 1.0
シス−3−ヘキセニル アセテート 0.7 0.7
α−ダマスコン 0.2 0.2
1−ヘキサナール 0.1 0.1
実施例2で合成した幾何異性体混合物 2.5 添加せず
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
合計 100.0 100.0
Claims (5)
- 請求項1記載の化合物または請求項2に記載の香料組成物を含有する飲食品。
- 請求項1記載の化合物または請求項2に記載の香料組成物を含有する香粧品。
- 請求項1記載の化合物の香料としての使用。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2017110403A1 (ja) * | 2015-12-22 | 2018-08-02 | アース製薬株式会社 | 蚊取り線香 |
WO2023213386A1 (en) | 2022-05-04 | 2023-11-09 | Symrise Ag | A fragrance mixture (v) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08502522A (ja) * | 1993-08-09 | 1996-03-19 | フイルメニツヒ ソシエテ アノニム | 繊維の芳香付け法 |
JPH08245508A (ja) * | 1995-03-16 | 1996-09-24 | Nippon Zeon Co Ltd | 不飽和カルボン酸エステルおよび不飽和カルボン酸エステルの製造方法 |
-
2006
- 2006-04-27 JP JP2006123818A patent/JP5158463B2/ja active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH08502522A (ja) * | 1993-08-09 | 1996-03-19 | フイルメニツヒ ソシエテ アノニム | 繊維の芳香付け法 |
JPH08245508A (ja) * | 1995-03-16 | 1996-09-24 | Nippon Zeon Co Ltd | 不飽和カルボン酸エステルおよび不飽和カルボン酸エステルの製造方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2017110403A1 (ja) * | 2015-12-22 | 2018-08-02 | アース製薬株式会社 | 蚊取り線香 |
WO2023213386A1 (en) | 2022-05-04 | 2023-11-09 | Symrise Ag | A fragrance mixture (v) |
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