JP2007204878A - Composite yarn composed of filament and staple fiber and cloth made thereof - Google Patents

Composite yarn composed of filament and staple fiber and cloth made thereof Download PDF

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JP2007204878A
JP2007204878A JP2006025408A JP2006025408A JP2007204878A JP 2007204878 A JP2007204878 A JP 2007204878A JP 2006025408 A JP2006025408 A JP 2006025408A JP 2006025408 A JP2006025408 A JP 2006025408A JP 2007204878 A JP2007204878 A JP 2007204878A
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hollow
filament
fiber
yarn
long
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JP5087841B2 (en
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Noriyoshi Shintaku
知徳 新宅
Nobuaki Tanaka
伸明 田中
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Toray Industries Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a hollow composite yarn composed of filaments and staple fibers and having excellent water-absorption/antipilling property and remarkably light weight. <P>SOLUTION: The yarn is an essentially non-twisted composite yarn composed of filaments and staple fibers and containing hollow filaments at the core part and staple fibers of synthetic fiber/semisynthetic fiber and/or natural fiber at the sheath part. The hollow filament of the core part accounts for 15-60 wt.% of the whole spun yarn, the staple fiber of the sheath part accounts for 40-85 wt.% of the whole spun yarn and the hollow retention ratio of the composite yarn composed of filaments and staple fibers defined by the following formula is ≥80%. Hollow retention ratio (%)=[(hollowness of hollow filament before spinning)-(hollowness of hollow filament after spinning)]/(hollowness of hollow filament before spinning)×100. A cloth having texture with excellent springiness and stiffness can be produced by using the composite yarn composed of filaments and staple fibers. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、芯部に中空型フィラメントを有し、鞘部に短繊維を有するとともに、実質的に無撚であることを特徴とする長短複合糸およびそれを用いてなる布帛に関する。   The present invention relates to a long / short composite yarn characterized by having a hollow filament in a core portion, short fibers in a sheath portion and being substantially untwisted, and a fabric using the same.

従来、フィラメントと短繊維からなる長短複合糸に関しては数々の研究・開発が行われており、その中で軽量化やハリ・コシの特徴を持った、衣料用長短複合糸は多数提案、生産、販売されている。   Conventionally, many researches and developments have been conducted on long and short composite yarns consisting of filaments and short fibers. Among them, a number of long and short composite yarns for clothing with the characteristics of weight reduction and elasticity are proposed, produced, Sold.

また、長短複合糸において吸水性や軽量感をもたせ快適な着用感を狙いうために、中空部を形成するために、一旦芯鞘複合繊維で布帛を製造し、布帛等の加工後に化学処理などで芯部を溶出して中空部を有する繊維からなる長短複合糸および布帛を得ようとするものが提案されている。これは、長短複合化する際に紡績工程での撚りやローラニップ等により中空部が破壊してしまうという問題を回避する手段である。   In addition, in order to form a hollow portion in order to give water-absorbing and lightweight feeling in long and short composite yarns, a fabric is once manufactured with a core-sheath composite fiber, and chemical processing is performed after processing the fabric etc. In order to obtain long and short composite yarns and fabrics made of fibers having a hollow part by eluting the core part, a proposal has been made. This is a means for avoiding the problem that the hollow portion is broken due to twisting, a roller nip, or the like in the spinning process when combining the lengths.

しかしながら、同時にこれらの機能をもった糸および布帛を得るには繊維自身の改質が必要であり、原料となる繊維製造おいて特別なポリマを用いたりする必要がある。すなわち、原糸原綿の生産においては、紡糸難易度があがり、生産性が低下したり、品種切り替え時の清掃等が念入り行うことが必要になったり、紡績等での次工程においても別品種に混入すること懸念せねばならなくなるといった問題がある。また、フィラメントと短繊維の長短複合糸では、芯成分と鞘成分との絡合性、拘束性に欠け、鞘成分と芯成分が分離したいわゆるヌードヤーンの発生、また後の織編物工程通過時の摩擦によるネップの発生等の品質低下するなどの問題があった。   However, at the same time, in order to obtain yarns and fabrics having these functions, it is necessary to modify the fiber itself, and it is necessary to use a special polymer in the production of the raw fiber. In other words, in the production of raw silk, the difficulty of spinning increases, the productivity decreases, it becomes necessary to carefully clean up when changing the type, etc., and in the next step in spinning etc. There is a problem that you have to worry about mixing. In addition, long and short composite yarns of filaments and short fibers lack the entanglement property and restraint property of the core component and the sheath component, so-called nude yarn is generated in which the sheath component and the core component are separated, and when passing through the subsequent knitting and knitting process There was a problem such as a decrease in quality such as generation of a nep due to friction.

そこで、従来の長短複合糸は上記のような問題を防ぐために、紡績糸の撚りを通常対比高めに設定して、芯成分のフィラメントと鞘成分の短繊維を強く拘束させている。しかし、このような方法によると短繊維成分の収束が強くなるために、ソフトな風合いが得られにくく、芯部に中空型形状のものを用いると、その中空部が潰れてしまうことがあった。   Therefore, in order to prevent the above-described problems, the conventional long and short composite yarns set the twist of the spun yarn to be higher than usual to strongly restrain the filaments of the core component and the short fibers of the sheath component. However, according to such a method, since the convergence of the short fiber component is strong, it is difficult to obtain a soft texture, and when the hollow part is used for the core part, the hollow part may be crushed. .

これらの問題を解決するために、特開平11−323688号公報(特許文献1)には、工程通過時に中糸の中空を保つために、芯糸を繊維断面形状を井型とし、その断面剛性により工程通過後にも中空を保つ長短複合糸が提案されている。しかしながら同時に、繊維自体の剛性高まってしまうことから、布帛としたときの風合いが粗硬化してしまう欠点があった。   In order to solve these problems, Japanese Patent Application Laid-Open No. 11-323688 (Patent Document 1) discloses that the core yarn has a cross-sectional shape of the fiber and a cross-sectional rigidity in order to keep the middle yarn hollow during the process. Thus, long and short composite yarns that maintain a hollow state after passing through the process have been proposed. However, at the same time, since the rigidity of the fiber itself is increased, there is a drawback that the texture of the fabric is roughly cured.

また、特開平7−278982号公報(特許文献2)には、中空フィラメントと短繊維よりなる長短複合糸において、中空繊維の亀裂や割れ、繰り返し摩耗によるフィブリル化してなる白化現象を解決するために、中空率10〜40%、沸水収縮率8%以上の中空フィラメント糸と短繊維束を用い、混合重量比が芯/鞘≦1.5とし、糸形成後沸水処理する内容が記載されている。   Japanese Patent Application Laid-Open No. 7-278982 (Patent Document 2) discloses a method for solving a whitening phenomenon in a long and short composite yarn composed of a hollow filament and a short fiber, which is caused by fibrillation due to cracks, cracks, and repeated wear of the hollow fiber. The hollow fiber yarn and the short fiber bundle having a hollow rate of 10 to 40% and a boiling water shrinkage rate of 8% or more are used, and the mixing weight ratio is set to core / sheath ≦ 1.5, and the content of boiling water treatment after yarn formation is described. .

しかしながら、加撚していることから、これらの問題が生じ、フィラメントの沸水収縮率やの規制や、さらにはヌードヤーン発生を抑えるために、必ず沸水処理(おそらく、通常紡績で行われているヨリ止めセットと推定される)が必要であることから製造に関しては、これらに随時注意を払らわなければならず、チェックも容易に行え難いものであった。   However, twisting causes these problems, and in order to control the boiling water shrinkage rate of the filament and to suppress the occurrence of nude yarn, be sure to use boiling water treatment (perhaps the twisting that is usually performed in spinning). Since it was necessary to pay attention to the manufacturing from time to time, it was difficult to perform the check easily.

また、特開平11−61558号公報(特許文献3)には、芯に中空率10〜40%のポリエステル糸条を用い、鞘に0.3デニール以下のポリエステル短繊維を用いて、軽量でハリ・コシ等の特徴を有し、衣料とした時に着用快適性を得ようとしたものが提案されている。しかしながら鞘の短繊維および長繊維は改質したポリマを用い、後加工により溶融させ芯成分を抜いて中空化するものであり、後加工を必要とし、使用される繊維も改質したポリマが必要であるため、製造においては手間がかかるものであった。同様に、特開平6−49730号公報(特許文献4)には、芯にC字状のヨコ断面形状を有した鞘部分と、融解・分解除去成分からなる芯成分からなるFY糸を用い、鞘に綿を用いたコアヤーンを織編物とし、この織編物を処理し、融解・分解除去成分を除去し、速乾性を有した布帛を得ようとしるものであり、これも後加工を必要とし、使用される繊維も改質したポリマが必要であるため、製造においては手間がかかるものであった
また、特開2003−55848号公報(特許文献5)には抗ピル性をもった長短複合糸を得ようと鞘成分に改質ポリマを使用した短繊維を用いたものが提案されているが、改質ポリマを有することや、中空繊維であるため、工程通過においてデリケートな面があり、生産性に欠けるものであった。
特開平11−323688号公報 特開平7−278982号公報 特開平11−61558号公報 特開平6−49730号公報 特開2003−55848号公報
Japanese Patent Application Laid-Open No. 11-61558 (Patent Document 3) uses a polyester yarn having a hollow ratio of 10 to 40% for the core and a polyester short fiber having a denier of 0.3 denier or less for the sheath and is lightweight and firm.・ Proposals have been proposed that have features such as stiffness and are intended to provide comfort when worn as clothing. However, the short fibers and long fibers of the sheath use a modified polymer, which is melted by post-processing to remove the core component and hollow, requiring post-processing, and the fibers used must also be modified Therefore, it takes time and effort in manufacturing. Similarly, in JP-A-6-49730 (Patent Document 4), a sheath part having a C-shaped horizontal cross-sectional shape in the core and an FY yarn made of a core component made of a melting / decomposing and removing component are used. The core yarn using cotton as the sheath is made into a woven or knitted fabric, and the woven or knitted fabric is processed to remove the melting / decomposing / removing component to obtain a fabric having quick drying properties, which also requires post-processing. In addition, since a modified polymer is also required for the fibers used, it takes time to manufacture. Also, Japanese Patent Application Laid-Open No. 2003-55848 (Patent Document 5) discloses a long and short composite having anti-pill properties. Although it has been proposed to use a short fiber using a modified polymer as a sheath component to obtain a yarn, because it has a modified polymer and is a hollow fiber, there is a delicate aspect in passing through the process, Productivity was lacking.
JP-A-11-323688 JP-A-7-278982 JP-A-11-61558 JP-A-6-49730 JP 2003-55848 A


そこで本発明は、上述のような従来技術では得られなかった、優れた吸水性・抗ピル性を有し軽量性に優れ、従来にないハリコシのすぐれた風合いを有する布帛を得ることができる中空型長短複合糸およびそれを用いた布帛を提供することを目的とする。

Therefore, the present invention provides a hollow fabric that has an excellent water absorption and anti-pill property, is excellent in light weight, and has an unprecedented sharpness that has not been obtained by the conventional technology as described above. It is an object of the present invention to provide a mold long / short composite yarn and a fabric using the same.

前記した課題を解決するため本発明は、次の構成を有する。すなわち、
(1)芯部に中空型フィラメントを有し鞘部に短繊維を有するとともに、実質的に無撚であることを特徴とする長短複合糸。
In order to solve the above-described problems, the present invention has the following configuration. That is,
(1) A long / short composite yarn characterized by having a hollow filament in a core portion and short fibers in a sheath portion and being substantially untwisted.

(2)芯部の中空型フィラメントが紡績糸全体の15〜60重量%を占め、鞘部の短繊維が紡績糸全体の40〜85重量%を占めることを特徴とする前記(1)に記載の長短複合糸。   (2) The hollow filament at the core occupies 15 to 60% by weight of the entire spun yarn, and the short fibers at the sheath occupy 40 to 85% by weight of the entire spun yarn. Long and short composite yarn.

(3)次式による中空保持率80%以上であることを特徴とする長短複合糸。   (3) A long / short composite yarn having a hollow retention rate of 80% or more according to the following formula.

(紡績前の中空フィラメントの中空率−紡績後の中空フィラメントの中空率)/紡績前の中空フィラメントの中空率×100=中空保持率(%)
(4)前記(1)〜(3)のいずれかに記載の長短複合糸を用い、かつ次式による中空保持率80%以上であることを特徴とする布帛。
(織製または編成前の中空フィラメントの中空率−織製または編成後の中空フィラメントの中空率)/織製または編成前の中空フィラメントの中空率×100=中空保持率(%)
(Hollow rate of hollow filament before spinning−hollow rate of hollow filament after spinning) / Hollow rate of hollow filament before spinning × 100 = Hollow retention rate (%)
(4) A fabric using the long and short composite yarn according to any one of (1) to (3), and having a hollow retention of 80% or more according to the following formula.
(Hollow rate of hollow filament before woven or knitted-hollow rate of hollow filament after woven or knitted) / Hollow rate of hollow filament before woven or knitted × 100 = Hollow retention rate (%)

本発明により、優れた吸水性・抗ピル性を有し軽量性に優れ、従来にないハリコシのすぐれた風合いを有する布帛を得ることができる長短複合糸およびそれを用いた布帛を提供することができる。   According to the present invention, it is possible to provide a long / short composite yarn capable of obtaining a fabric having excellent water absorption and anti-pilling properties, excellent lightness, and an unprecedented feel of elasticity, and a fabric using the same. it can.

以下、本発明につき詳細に説明する。   Hereinafter, the present invention will be described in detail.

まず、本発明の長短複合糸の糸構造について説明する。   First, the yarn structure of the long and short composite yarn of the present invention will be described.

本発明の長短複合糸においては、中空型繊維フィラメントを芯部に、短繊維を鞘部に有した長短複合糸であり、さらには優れたカバリング性と軽量性および、膨らみ感を得るために、紡績糸自体が実質的に無撚りであることが重要である。   In the long and short composite yarn of the present invention, it is a long and short composite yarn having a hollow fiber filament in the core portion and a short fiber in the sheath portion, and in addition, in order to obtain excellent covering properties and light weight, and a feeling of swelling, It is important that the spun yarn itself is substantially untwisted.

すなわち、実質的に無撚り構造糸であれば、実撚り糸のような短繊維成分による芯部のフィラメント成分への強い拘束力や、芯部のフィラメントに付与される実撚りによって、前述の中空型繊維フィラメントの中空形状を破壊することがなく、優れた軽量性や吸水性、および膨らみ感といった風合いを十分に発揮することができる。   That is, in the case of a substantially untwisted structure yarn, the above-described hollow type is obtained by a strong binding force to the filament component of the core portion by a short fiber component such as a real twist yarn or the actual twist imparted to the filament of the core portion. The hollow shape of the fiber filament is not destroyed, and excellent texture such as excellent lightness, water absorption, and swelling can be exhibited.

ここで、本発明における実質的に無撚り構造糸とは、撚りのトルクの作用による撚り戻りの発生がない、もしくはきわめて小さい状態のものであることをいい、短繊維成分の平均繊維長をLsとした場合、4.0T/Ls以下の実撚りがかかっているものまたは無撚状のものである。撚り数が4.0T/Ls以下の場合には、撚りのトルクの作用による撚り戻りの発生がないので、実質的に無撚り構造糸ということができる。   Here, the substantially untwisted structure yarn in the present invention means that there is no occurrence of untwisting due to the action of twisting torque, or a very small state, and the average fiber length of the short fiber component is Ls. In this case, a real twist of 4.0 T / Ls or less or a non-twisted one is used. When the number of twists is 4.0 T / Ls or less, there is no occurrence of untwisting due to the action of twisting torque, so that it can be said to be a substantially untwisted structure yarn.

撚り数の測定方法については、検撚機を用いて測定することができる。すなわち、糸の両端をつかみ初荷重をかけ解撚する方法を用いるものであるが、本発明の長短複合糸は、この方法では解撚できないか、撚り数が4.0T/Ls以下とするものである。
さらに、実撚り構造糸の場合には、芯部のフィラメントを鞘部の短繊維により十分に被覆し、また、しごきなどによる短繊維成分の脱落を防ぐために、撚り数を通常対比高めに設定する必要がある。しかし、この場合には芯部のフィラメントを拘束する力が高くなり過ぎて、中空繊維の中空部が失われてしまい、また、芯部のフィラメントにも実撚りが付与されるために捲縮発現性が低下し、十分な膨らみ感が得られなくなるので、本発明が目的とする優れた風合いを得る手段としてはふさわしくない。
About the measuring method of a twist number, it can measure using a tester. That is, a method of grasping both ends of the yarn and applying an initial load to untwist is used, but the long / short composite yarn of the present invention cannot be untwisted by this method, or the number of twists is 4.0 T / Ls or less. It is.
Furthermore, in the case of a real twist structure yarn, the number of twists is set to be higher than usual in order to sufficiently cover the filament in the core with the short fibers in the sheath and prevent the short fiber components from falling off due to ironing or the like. There is a need. However, in this case, the force that restrains the filament in the core part becomes too high, and the hollow part of the hollow fiber is lost. This is not suitable as a means for obtaining an excellent texture intended by the present invention because the properties are lowered and a sufficient swell feeling cannot be obtained.

また、本発明の長短複合糸においては、鞘部の短繊維成分が長短複合糸全体に占める混率が40〜85重量%の範囲にあることが好ましく、さらには50〜70重量%の範囲にあることがより好ましい。短繊維成分の混率が40重量%より小さい場合には、短繊維の繊維本数が少なくなるため、十分な被覆性が得られず、逆に85重量%よりも大きい場合には、短繊維成分の物性の影響が支配的となり、通常繊維との有意差が小さくなり、したがって、短繊維による被覆性と前述のような優れた性能を兼ね備えた長短複合糸を得るためには、短繊維成分の混率が50〜70重量%の範囲にあることがより好ましい。   In the long and short composite yarn of the present invention, the mixing ratio of the short fiber component in the sheath to the entire long and short composite yarn is preferably in the range of 40 to 85% by weight, and more preferably in the range of 50 to 70% by weight. It is more preferable. When the mixing ratio of the short fiber component is smaller than 40% by weight, the number of short fiber fibers is reduced, so that sufficient coverage cannot be obtained. The influence of physical properties becomes dominant, and a significant difference from ordinary fibers becomes small. Therefore, in order to obtain long and short composite yarns that have both excellent coverage as described above and excellent performance as described above, the mixing ratio of short fiber components Is more preferably in the range of 50 to 70% by weight.

次に、本発明の長短複合糸に用いる中空型繊維のフィラメントについて説明する。   Next, a hollow fiber filament used in the long and short composite yarn of the present invention will be described.

本発明の長短複合糸に用いる中空型フィラメントの断面形状は、丸断面、扁平断面、三角断面、マルチローバル断面、X型断面、その他の異形断面であってもよいが、中空型断面である必要がある。   The cross-sectional shape of the hollow filament used in the long and short composite yarn of the present invention may be a round cross-section, flat cross-section, triangular cross-section, multi-loval cross-section, X-type cross-section, or other irregular cross-section, but it must be a hollow cross-section. There is.

ここでいう中空型断面とは、図1に示すように繊維断面の中央部に空間を有する繊維のことを言い、その中空部が繊維の中心または図2のように繊維の中心点と中空部の中心点をずらしたものでも良い。その中空率は10容積%〜70容積%の範囲にすることが好ましい。10容積%以下にすると十分な軽量性が得られないし、70容積%を超えると繊維の肉厚が極端に薄くなり、十分な繊維強度が得られにくくなるため好ましくない。   As used herein, the hollow cross section refers to a fiber having a space at the center of the fiber cross section as shown in FIG. 1, and the hollow part is the center of the fiber or the center point and hollow part of the fiber as shown in FIG. What shifted the center point of may be used. The hollow ratio is preferably in the range of 10 volume% to 70 volume%. If it is 10% by volume or less, sufficient lightness cannot be obtained, and if it exceeds 70% by volume, the fiber thickness becomes extremely thin, and it becomes difficult to obtain sufficient fiber strength.

また、中空部の断面形状は、丸型の他、楕円型、三角型、四角型などの多角形型、星型など本来の機能を喪失しない限り適宜選択でき、中空部の数も1つに限らず、多数設けることも好適なことである。図3にその一例を示す。
これら中空型フィラメントは直接紡糸によっても製造できるが、芯鞘型複合繊維として製造した後に芯部を溶出させることにより、中空部の断面形状がシャープな中空型フィラメントを得ることができる。
Further, the cross-sectional shape of the hollow portion can be appropriately selected as long as the original function is not lost, such as a round shape, a polygonal shape such as an elliptical shape, a triangular shape or a square shape, or a star shape, and the number of hollow portions is also one. However, it is also preferable to provide a large number. An example is shown in FIG.
Although these hollow filaments can be produced by direct spinning, a hollow filament having a sharp cross-sectional shape of the hollow portion can be obtained by eluting the core portion after producing the core-sheath type composite fiber.

中空フィラメントの繊度は適宜選択しうるが、本発明の長短複合糸を得るには、単糸繊度を5dtex以下とするのが好ましい。フィラメントの構成本数についても、特に限定されるものでなく、モノフィラメントでも本来の機能を喪失しないかぎり用いてもよいが、長短複合糸の生産性や、フィラメントと短繊維の絡み合いを考慮すると、複数本とすることが好ましい。特に10本以上とすることが好ましいが、単糸繊度や、得ようとする長短複合糸の番手を考慮し、トータル繊度や単糸繊度を設定する必要がある。   The fineness of the hollow filament can be selected as appropriate, but in order to obtain the long and short composite yarn of the present invention, the single yarn fineness is preferably 5 dtex or less. The number of filaments is not particularly limited, and monofilaments may be used as long as they do not lose their original function. However, considering the productivity of long and short composite yarns and the entanglement between filaments and short fibers, multiple filaments may be used. It is preferable that In particular, the number is preferably 10 or more, but it is necessary to set the total fineness and the single yarn fineness in consideration of the single yarn fineness and the count of the long and short composite yarn to be obtained.

繊維の素材は、ポリエステル、アクリル、ポリアミド、ポリプロピレンなどの合成繊維を適宜選択しうる。中でもポリエステルは、安定性に優れた糸物性が得られやすいことから好ましい素材である。   As the fiber material, synthetic fibers such as polyester, acrylic, polyamide, and polypropylene can be appropriately selected. Among these, polyester is a preferable material because it is easy to obtain yarn properties excellent in stability.

次に、本発明の長短複合糸に用いる短繊維について説明する。   Next, the short fiber used for the long and short composite yarn of the present invention will be described.

上記の短繊維として用いる繊維素材は特に限定されず、綿、ウール、麻などの天然繊維、ポリエステル、アクリル、ポリアミド、ポリプロピレンなどの合成繊維であってもよいし、レーヨントリアセテート、などの半合成繊維であってもよく、これらを2種以上混ぜ合わせても良い。   The fiber material used as the above short fiber is not particularly limited, and may be a natural fiber such as cotton, wool or hemp, a synthetic fiber such as polyester, acrylic, polyamide or polypropylene, or a semi-synthetic fiber such as rayon triacetate. Or two or more of these may be mixed.

また上記の短繊維を合成繊維または半合成繊維を用いる場合、断面形状は特に限定されず、丸であっても、多角形、H型、中空などの異形断面であっても良い。また、短繊維の繊度についても特に限定されないが、紡積性を考慮すると0.6〜5デシテックスの範囲内にすることが好ましい。繊維長については各種紡績方法に応じた繊維長とするのがよいが、空気精紡を用いる場合は、その紡績原理を考慮すると25mm〜51mm程度が好適に使用でき、さらには30mm〜44mmの範囲内とするのがさらに好ましい。   In addition, when synthetic fibers or semi-synthetic fibers are used as the short fibers, the cross-sectional shape is not particularly limited, and may be a round shape, an irregular shape such as a polygonal shape, an H shape, or a hollow shape. Further, the fineness of the short fiber is not particularly limited, but is preferably in the range of 0.6 to 5 dtex in consideration of the spinnability. The fiber length is preferably a fiber length corresponding to various spinning methods. However, when air spinning is used, about 25 mm to 51 mm can be preferably used in consideration of the spinning principle, and further, the range is 30 mm to 44 mm. More preferably, it is inside.

以上のような構成により、本発明の長短複合糸は次式による中空保持率を80%以上とすることができる。   With the above configuration, the long and short composite yarn of the present invention can have a hollow retention rate of 80% or more according to the following formula.

(紡績前の中空フィラメントの中空率−紡績後の中空フィラメントの中空率)/紡績前の中空フィラメントの中空率×100=中空保持率(%)
従来の、中空繊維を芯糸にして撚りをかける長短複合糸の製造方法では、80%という中空保持率は達成し得ないものである。
(Hollow rate of hollow filament before spinning−hollow rate of hollow filament after spinning) / Hollow rate of hollow filament before spinning × 100 = Hollow retention rate (%)
With the conventional method for producing a long / short composite yarn in which a hollow fiber is used as a core yarn and twisted, a hollow retention of 80% cannot be achieved.

本発明の長短複合糸は、公知の方法で製織、編成等して布帛とすることができる。本発明の長短複合糸により、優れた吸水性・抗ピル性を有し軽量性に優れ、従来にないハリコシのすぐれた風合いを有する布帛を得ることができる。なお、本発明の効果を損なわない範囲で、他の糸と交織、交編することももちろん可能である。   The long and short composite yarn of the present invention can be made into a fabric by weaving, knitting or the like by a known method. With the long and short composite yarns of the present invention, it is possible to obtain a fabric that has excellent water absorption and anti-pill properties, is excellent in lightness, and has an unprecedented sharpness. Of course, weaving and knitting with other yarns are possible within a range not impairing the effects of the present invention.

なお、本発明の布帛は、本発明の長短複合糸を用いたことにより、次式による中空保持率を80%以上とすることができる。
(織製または編成前の中空フィラメントの中空率−織製または編成後の中空フィラメントの中空率)/織製または編成前の中空フィラメントの中空率×100=中空保持率(%)
ここで、織製または編成前の中空フィラメントの中空率とは、紡績糸の中空フィラメントの中空率と同義である。
次に、本発明の長短複合糸を製造する方法について説明する。
In addition, the fabric of this invention can make the hollow retention rate by following Formula 80% or more by using the long and short composite yarn of this invention.
(Hollow rate of hollow filament before woven or knitted-hollow rate of hollow filament after woven or knitted) / Hollow rate of hollow filament before woven or knitted × 100 = Hollow retention rate (%)
Here, the hollow ratio of the hollow filament before weaving or knitting is synonymous with the hollow ratio of the hollow filament of the spun yarn.
Next, a method for producing the long and short composite yarn of the present invention will be described.

まず、中空型フィラメントおよび短繊維をそれぞれ準備する。それぞれの繊維の製造方法は公知の方法によればよい。次にこれら繊維を紡績し、紡績糸とする。   First, a hollow filament and a short fiber are prepared. Each fiber may be produced by a known method. Next, these fibers are spun into a spun yarn.

紡績方法としては、できあがる長短複合糸が実質的に無撚りとなる方法であれば特に限定されないのであるが、空気流の作用により短繊維成分を結束させて紡績糸を形成する汎用の空気精紡機において、適当なフィードローラと糸道ガイドなどの長繊維用の設備を介して、フィラメントを糸形成部手前で短繊維束の中心部に供給することにより得る方法を好ましく用いることができる。特に好ましいのは、ムラタボルテックススピナー(村田機械社製:以下MVSと記す)を用いる方法があげられる。空気流の作用を利用する紡績方法は各種、提案、開発、利用されているが、本発明の長短複合糸を得るにはカバー率が良いことが好ましく、MVSを用いた紡績方法はこれを最も達成しうる紡績方法の一つである。   The spinning method is not particularly limited as long as the resulting long and short composite yarns are substantially untwisted, but a general-purpose air spinning machine that binds short fiber components by the action of airflow to form a spun yarn In the method, a method obtained by supplying the filament to the center portion of the short fiber bundle in front of the yarn forming portion through a suitable feed roller and a long fiber facility such as a yarn path guide can be preferably used. Particularly preferred is a method using a Murata vortex spinner (Murata Kikai Co., Ltd .: hereinafter referred to as MVS). Various spinning methods that utilize the action of airflow have been proposed, developed, and used. However, in order to obtain the long and short composite yarns of the present invention, it is preferable that the coverage is good, and this is the most suitable for the spinning method using MVS. This is one of the spinning methods that can be achieved.

また、その他の方法としては、次のような方法がある。まず、短繊維成分に好ましくは120℃以下の低い融点を有する低融点繊維をある一定比率混ぜて、リング精紡機を用いる長短複合糸の一般的な製造方法によって実撚り構造の長短複合糸を得る。次に、ホットローラー、または非接触式の熱板を有するリング撚糸機にこの長短複合糸を仕掛けて、精紡機とは逆方向の同じ撚り数の撚りを与えて、撚りを完全に戻しながら、ホットローラー、または熱板によって低融点繊維を周りの短繊維やフィラメントに融着させて無撚り長短複合糸を得ることもできる。この方法の場合、混ぜる低融点繊維の混率や与える撚り数、およびホットローラー、または熱板の温度設定値などは、得られる長短複合糸の風合いが損なわれないように適正な設計を行うことが重要である。   Other methods include the following methods. First, a low-melting fiber having a low melting point of preferably 120 ° C. or lower is mixed in a certain ratio with the short fiber component, and a long / short composite yarn having a real twist structure is obtained by a general production method of a long / short composite yarn using a ring spinning machine. . Next, we put this long and short composite yarn on a ring twisting yarn machine with a hot roller or a non-contact type hot plate, giving the same number of twists in the opposite direction to the spinning machine, while completely returning the twist, It is also possible to obtain a non-twisted long / short composite yarn by fusing the low melting point fibers to the surrounding short fibers and filaments with a hot roller or a hot plate. In this method, the mixing ratio of the low melting point fiber to be mixed, the number of twists to be given, and the temperature setting value of the hot roller or hot plate may be appropriately designed so that the texture of the obtained long and short composite yarn is not impaired. is important.

以下、本発明を実施例で詳細に説明する。   Hereinafter, the present invention will be described in detail with reference to examples.

(紡績糸評価測定方法)
(1)紡績糸の中空保持率
紡績前のフィラメント(n=5)の断面写真をSEM(倍率×500)で撮影し、繊維の断面積(中空部を含む全断面積)Aおよびその繊維の中空部の断面積Bを求め、次式よりフィラメント中空率Cをその平均で示した。
(A−B)/A×100=フィラメント中空率C(%)
同じく、紡績後の糸断面のSEM(倍率×500)で撮影し、紡績糸を構成している中空フィラメントの断面積Dおよびそのフィラメント中空部の断面積Eを5点分求め、次式より紡績後の中空率Fをその平均で示した。
(D−E)/D×100=紡績後のフィラメント中空率F(%)
紡績後の中空保持率を下記式で求めた。
(C−F)/C×100=紡績後の中空保持率(%)
(2)被覆性評価
評価は得られた紡績糸の側面を25倍の顕微鏡で観察し、糸長1m当たりに芯部のフィラメントが表層部から確認できる箇所の数により判断した。
判定基準は、×:10カ所以上またはヌードヤーンの発生、△:5〜9カ所、○:1〜5カ所、◎:0カ所の4段階評価で行った。
(Spun yarn evaluation measurement method)
(1) Hollow retention rate of spun yarn A cross-sectional photograph of the filament (n = 5) before spinning was taken with SEM (magnification × 500), and the cross-sectional area of the fiber (total cross-sectional area including the hollow part) A and the fiber The cross-sectional area B of the hollow portion was obtained, and the filament hollow ratio C was shown as an average from the following formula.
(A−B) / A × 100 = Filament hollow ratio C (%)
Similarly, a SEM (magnification × 500) of the cross section of the spun yarn was photographed, and the cross-sectional area D of the hollow filament constituting the spun yarn and the cross-sectional area E of the hollow portion of the filament were determined for five points. The latter hollowness F was shown by the average.
(DE) / D × 100 = Filament hollow ratio after spinning F (%)
The hollow retention after spinning was determined by the following formula.
(C−F) / C × 100 = Hollow retention after spinning (%)
(2) Coverability evaluation Evaluation was made by observing the side surface of the obtained spun yarn with a 25-fold microscope and judging the number of locations where the filament of the core portion can be confirmed from the surface layer portion per 1 m of yarn length.
Judgment criteria were as follows: x: 10 or more places or occurrence of nude yarn, Δ: 5-9 places, ◯: 1-5 places, ◎: 0 places.

(布帛評価測定方法)
(1)織製・編成後の中空保持率
織製または編成前の糸(n=5)の断面写真をSEM(倍率×500)で撮影し、構成している中空フィラメントの断面積(中空部を含む全断面積)イおよびその繊維の中空部の断面積ロを求め、次式よりフィラメント中空率ハをその平均で示した。
(イ−ロ)/イ×100=フィラメント中空率ハ(%)
同じく、織製または編成前後の糸断面のSEM(倍率×500)で撮影し、紡績糸を構成しているフィラメント1本の断面積ニおよびそのフィラメント中空部の断面積ホを5点分求め、次式より紡績後の中空率ヘをその平均で示した。
(ニ−ホ)/ニ×100=紡績後のフィラメント中空率ヘ(%)
紡績後の中空保持率を下記式で求めた。
(ハ−ヘ)/ハ×100=織製・編成後の中空保持率(%)
(2)防シワ性
試料:直径9.6cm円形を準備し、50mlのプラスチック製ビーカーを準備し、ビーカーの上部にサンプルを載せ、荷重500gのおもり(押圧面積43g/cm2)、にてビーカー内に押し込むように投入し、時間10分間荷重をかけ除重し、直後、1時間後、24時間後の状態を「外観判定横光線」を用いてシワの状態で判別した。
(Fabric evaluation measurement method)
(1) Hollow retention rate after weaving / knitting Cross-sectional area of hollow filaments (hollow part) taken by SEM (magnification × 500) by taking a cross-sectional photograph of yarn (n = 5) before weaving or knitting The cross-sectional area (b) of the hollow portion of the fiber and the fiber was obtained, and the average hollowness ratio of the filament was shown by the following formula.
(Iro) / I x 100 = Filament hollowness ratio (%)
Similarly, SEM (magnification × 500) of the yarn cross section before and after knitting or knitting was taken, and the cross-sectional area of one filament constituting the spun yarn and the cross-sectional area of the hollow portion of the filament were obtained for five points. From the following equation, the average hollowness after spinning is shown.
(Neho) / D x 100 = Filament hollow ratio after spinning (%)
The hollow retention after spinning was determined by the following formula.
(Ha ha) / ha x 100 = hollow retention after weaving and knitting (%)
(2) Wrinkle resistance Sample: Prepare a 9.6 cm diameter circle, prepare a 50 ml plastic beaker, place the sample on the top of the beaker, and place the sample in the beaker with a weight of 500 g (pressing area 43 g / cm2). Then, the load was applied for 10 minutes and de-weighted. Immediately after that, the state after 1 hour and 24 hours was discriminated by using the “appearance determination lateral ray” in the state of wrinkles.

(3)ピリング性
JIS L−1076(1992) ICI法を用い、処理時間 織物10時間 編物5時間で処理し級判別した。
(3) Pilling property JIS L-1076 (1992) Using the ICI method, the treatment time was 10 hours for the woven fabric and 5 hours for the knitted fabric, and the grade was determined.

(4)曲げ剛性
KES法により曲げ強さ・ヒステリシス幅をKES FB−2試験機で測定した。
(4) Bending rigidity Bending strength and hysteresis width were measured by the KES method with a KES FB-2 testing machine.

(5)寸法変化率
JIS L−1096(1999)に準じて測定した。
(5) Dimensional change rate It measured according to JIS L-1096 (1999).

(6)速乾性
サンプルサイズ40cm×40cmを準備し、水中へ5分沈めた後、家庭用洗濯機で30秒脱水をかけ、温度20℃ 湿度65%RH下の条件で5分ごとの重量を求め、下記式にてその含水率(%)を求め、含水率が2%以下になった時間を乾燥時間(分)を速乾性とした。
(6) Quick-drying Sample size 40cm x 40cm is prepared, submerged in water for 5 minutes, then dehydrated in a household washing machine for 30 seconds, and weight every 5 minutes under conditions of temperature 20 ° C and humidity 65% RH. The moisture content (%) was determined by the following formula, and the time when the moisture content became 2% or less was defined as the drying time (minutes).

(7)官能評価
長短複合糸を経糸と緯糸の両方に使用して平織り組織の織物を製織し、得られた生機をオープンソーパーで95℃でリラックス熱処理し、乾燥後、乾熱180℃で中間セットし、120℃で染色した。その後160℃の乾熱でピンテンター方式により仕上セットを行った。
(7) Sensory evaluation Weaving plain weave fabric using both long and short composite yarns for both warp and weft, and the resulting green machine is relaxed and heat treated at 95 ° C with an open soaper, dried and then dried at 180 ° C in the middle Set and stain at 120 ° C. Thereafter, finish setting was performed by a pin tenter method with a dry heat of 160 ° C.

得られた布帛について、ハリコシ感、軽量感、触感につき10人のモニターにより官能試験を実施し、その判定結果の平均を評価結果とした。   The obtained fabric was subjected to a sensory test with 10 monitors per touch, feel of lightness, and touch, and the average of the determination results was taken as the evaluation result.

なお、評価の判定基準は、×:全く感じない、△:ほとんど感じない、○:感じる、◎:強く感じるの4段階評価で行い、×=0点、△=1点、○=2点、◎=3点と点数に置き換え、その平均点をもとめ、0.0〜0.9点を×、1.0〜1.5点を△、1.6〜2.5点を○、2.5点以上を◎として最終的な評価結果とした。   The evaluation criteria are as follows: x: not felt at all, Δ: hardly felt, ◯: felt, ◎: felt strongly, x = 0 point, Δ = 1 point, ○ = 2 point, == Replaced with 3 points and averaged, 0.0 to 0.9 points for x, 1.0 to 1.5 points for Δ, 1.6 to 2.5 points for ○, Five or more points were rated as ◎ for final evaluation results.

(実施例1)
長短複合糸の短繊維としてポリエチレンテレフタレート短繊維(T403、1.45dtex×38mm、東レ製)を使用し、通常の紡績方式を経て1.0g/mの太さのスライバーを作成した。また、中空フィラメントとして“ボデイジョイ”(素材:ポリエチレンテレフタレート44dtex−12F、東レ製)を用いた。
Example 1
A polyethylene terephthalate short fiber (T403, 1.45 dtex × 38 mm, manufactured by Toray) was used as the short fiber of the long / short composite yarn, and a sliver having a thickness of 1.0 g / m was prepared through a normal spinning method. Further, “body joy” (material: polyethylene terephthalate 44 dtex-12F, manufactured by Toray Industries, Inc.) was used as a hollow filament.

スライバーをMVSに仕掛け、フィラメント用のフィードローラ装置と糸道ガイドを介して、前述の中空型フィラメントをフロントトップローラー〜セカンドトップローラ間から短繊維束の幅方向中心位置に供給し、綿方式の番手で30’sの長短複合糸を得た。被覆性に優れ、糸切れの発生も少なく、加工後の中空部破損もなく、紡績性は良好であった。
得られた長短複合糸をヨコ糸として、タテ糸をポリエチレンテレフタレートFYとし、通常の織機を用いて、織組織を3/1ツイルとし、織密度283g/mの織物を得た。得られた布帛について、各評価を行った結果、表1に示すように、加工後の中空部破損もなく、図6に示す通り、防しわ性に優れ、風合いも軽量感に優れたものであった。得られた布帛断面のSEM写真を、図4および糸の断面を図5に示す。
A sliver is mounted on the MVS, and the hollow filament is supplied from the front top roller to the second top roller to the center position in the width direction of the short fiber bundle via the filament feed roller device and the yarn path guide. A 30's long and short composite yarn was obtained with a count. The coating property was excellent, the occurrence of thread breakage was small, the hollow part was not damaged after processing, and the spinnability was good.
The obtained long / short composite yarn was used as a weft yarn, the warp yarn was used as polyethylene terephthalate FY, and using a normal loom, the woven structure was changed to 3/1 twill and a woven fabric having a woven density of 283 g / m was obtained. As a result of performing each evaluation on the obtained fabric, as shown in Table 1, there is no breakage of the hollow portion after processing, and as shown in FIG. 6, it is excellent in wrinkle resistance, and the texture is excellent in lightness. there were. An SEM photograph of the cross section of the obtained fabric is shown in FIG. 4 and a cross section of the yarn is shown in FIG.

(実施例2)
長短複合糸の短繊維として実施例1と同じスライバーを作成した。また、中空フィラメントとして“ファリーロ”(素材:ナイロン6、28dtex−12F、東レ製)を用いた。
(Example 2)
The same sliver as in Example 1 was prepared as a short fiber of a long / short composite yarn. Further, “Fariro” (material: nylon 6, 28 dtex-12F, manufactured by Toray Industries, Inc.) was used as a hollow filament.

スライバーをMVSに仕掛け、フィラメント用のフィードローラ装置と糸道ガイドを介して、前述の中空型フィラメントをフロントトップローラー〜セカンドトップローラ間から短繊維束の幅方向中心位置に供給し、綿方式の番手で30’sの長短複合糸を得た。被覆性に優れ、加工後の中空部破損もなく、糸切れの発生も少なく紡績性は良好であった。
得られた長短複合糸をについて、実施例と同じ方法を用いて、織密度279g/mの織物を得た。各評価を行った結果、図6に示す通り、防しわ性に優れ、表1に示すように、風合いも軽量感に優れ良好なものであった。
A sliver is mounted on the MVS, and the hollow filament is supplied from the front top roller to the second top roller to the center position in the width direction of the short fiber bundle via the filament feed roller device and the yarn path guide. A 30's long and short composite yarn was obtained with a count. The coating property was excellent, the hollow part was not damaged after processing, the occurrence of yarn breakage was small, and the spinnability was good.
About the obtained long-short composite yarn, the same method as the Example was used, and the textile fabric of woven density 279g / m was obtained. As a result of each evaluation, as shown in FIG. 6, it was excellent in wrinkle resistance, and as shown in Table 1, the texture was excellent in lightness and good.

(比較例1)
実施例1と同じポリエステル短繊維を用い、通常の紡績方式を経て0.35g/mの太さの粗糸を作成しリング精紡機に仕掛けた。一方、実施例1と同じ中空型フィラメントをフロントトップローラー〜セカンドトップローラー間から短繊維束の中心位置に、フィラメント用のフィードローラー装置と糸道ガイドを介して供給し、リング精紡機のドラフト率を40倍、撚り数を27.8T/2.54cmに設定して、綿方式の番手で30’sの長短複合糸を得た。
得られた長短複合糸は紡績性に優れたものであったが、被覆性が実施例1と対比すると劣り、実撚りによる中空型フィラメントへの拘束力が強いために、中空部が破損していた。実施例1と同様に、緯糸として、織密度296g/mの織物を得たが、充分な中空率を保持できないために、吸水性に劣り、官能評価でも良好な風合いを得ることができなかった。
(Comparative Example 1)
Using the same polyester short fiber as in Example 1, a roving yarn having a thickness of 0.35 g / m was prepared through a normal spinning method and mounted on a ring spinning machine. On the other hand, the same hollow filament as in Example 1 is supplied from the front top roller to the second top roller to the center position of the short fiber bundle through the feed roller device for filament and the yarn path guide, and the draft rate of the ring spinning machine Was set to 40 times and the number of twists was set to 27.8 T / 2.54 cm, and a 30 'long / short composite yarn was obtained with a cotton count.
The obtained long and short composite yarns were excellent in spinnability, but the coating properties were inferior to those in Example 1, and the hollow part was damaged because the binding force to the hollow filaments by actual twisting was strong. It was. Similar to Example 1, a woven fabric having a weave density of 296 g / m was obtained as a weft, but a sufficient hollow ratio could not be maintained, so that the water absorption was poor and good texture could not be obtained even in sensory evaluation. .

(比較例2)
実施例1と同じポリエステル短繊維を用い、通常の紡績方式を経て0.35g/mの太さの粗糸を作成しリング精紡機に仕掛けた。一方、実施例2と同じ中空型フィラメントをフロントトップローラー〜セカンドトップローラー間から短繊維束の中心位置に、フィラメント用のフィードローラー装置と糸道ガイドを介して供給し、リング精紡機のドラフト率を40倍、撚り数を27.8T/2.54cmに設定して、綿方式の番手で30’sの長短複合糸を得た。
得られた長短複合糸は紡績性に優れたものであったが、被覆性が実施例2と対比すると劣り、実撚りによる中空型フィラメントへの拘束力が強いために、中空部が破損していた。実施例1と同様に、緯糸として、織密度296g/mの織物を得たが、充分な中空率を保持できないために、吸水性に劣り、官能評価でも良好な風合いを得ることができなかった。
(Comparative Example 2)
Using the same polyester short fiber as in Example 1, a roving yarn having a thickness of 0.35 g / m was prepared through a normal spinning method and mounted on a ring spinning machine. On the other hand, the same hollow filament as in Example 2 is supplied from between the front top roller to the second top roller to the center position of the short fiber bundle via the filament feed roller device and the yarn path guide, and the draft rate of the ring spinning machine Was set to 40 times and the number of twists was set to 27.8 T / 2.54 cm, and a 30 'long / short composite yarn was obtained with a cotton count.
The obtained long and short composite yarns were excellent in spinnability, but the coating properties were inferior to those of Example 2, and the hollow part was damaged because the binding force to the hollow filaments by actual twisting was strong. It was. Similar to Example 1, a woven fabric having a weave density of 296 g / m was obtained as a weft, but a sufficient hollow ratio could not be maintained, so that the water absorption was poor and good texture could not be obtained even in sensory evaluation. .

(比較例3)
実施例1と同じスライバーを用い、フィラメントを供給せずにMVSに掛け30sの紡績糸を得た。実施例1と同じように、織密度287g/mの織物を得て、各評価を行ったが、中心部に中空フィラメントを用いてないために、充分な軽量性が得れず、図6のように防シワ性に欠け、風合いもハリコシには欠けるものであった。
(Comparative Example 3)
The same sliver as in Example 1 was used, and it was subjected to MVS without supplying a filament to obtain a spun yarn of 30 s. Similar to Example 1, a woven fabric having a weave density of 287 g / m was obtained and evaluated. However, since a hollow filament was not used at the center, sufficient lightness could not be obtained, as shown in FIG. In addition, it was not wrinkle-proof and the texture was lacking in sharpness.

同心部に中空部を有する繊維断面の一例の模式図である。It is a schematic diagram of an example of the fiber cross section which has a hollow part in a concentric part. 偏心部に中空部を有する繊維断面の一例の模式図である。It is a schematic diagram of an example of the fiber cross section which has a hollow part in an eccentric part. その他使用できる繊維断面の一例の模式図である。It is a schematic diagram of an example of the fiber cross section which can be used for others. 本発明で、得られた長短複合糸を使用した布帛の断面SEM写真である。It is a cross-sectional SEM photograph of the fabric using the obtained long and short composite yarn in this invention. 本発明で、得られた長短複合糸の断面のSEM写真である。It is a SEM photograph of the section of the long and short composite yarn obtained in the present invention. 防シワ試験での布帛状態を撮影した写真である。It is the photograph which image | photographed the fabric state in the wrinkle-proof test.

符号の説明Explanation of symbols

1:繊維中空部   1: Fiber hollow part

Claims (4)

芯部に中空型フィラメントを有し、鞘部に短繊維を有するとともに、実質的に無撚であることを特徴とする長短複合糸。 A long / short composite yarn characterized by having a hollow filament in a core portion, short fibers in a sheath portion and being substantially untwisted. 芯部の中空型フィラメントが全体の15〜60重量%を占め、鞘部の短繊維が全体の40〜85重量%を占めることを特徴とする請求項1に記載の長短複合糸。 2. The long / short composite yarn according to claim 1, wherein the hollow filaments in the core occupy 15 to 60% by weight of the whole, and the short fibers in the sheath occupy 40 to 85% by weight of the whole. 次式による中空保持率が80%以上であることを特徴とする請求項1または2に記載の長短複合糸。
(紡績前の中空フィラメントの中空率−紡績後の中空フィラメントの中空率)/紡績前の中空フィラメントの中空率×100=中空保持率(%)
3. The long / short composite yarn according to claim 1 or 2, wherein the hollow retention rate according to the following formula is 80% or more.
(Hollow rate of hollow filament before spinning−hollow rate of hollow filament after spinning) / Hollow rate of hollow filament before spinning × 100 = Hollow retention rate (%)
請求項1〜3のいずれかに記載の長短複合糸を用い、かつ次式による中空保持率が80%以上であることを特徴とする布帛。
(織製または編成前の中空フィラメントの中空率−織製または編成後の中空フィラメントの中空率)/織製または編成前の中空フィラメントの中空率×100=中空保持率(%)
A fabric comprising the long and short composite yarn according to any one of claims 1 to 3 and having a hollow retention rate of 80% or more according to the following formula.
(Hollow rate of hollow filament before woven or knitted-hollow rate of hollow filament after woven or knitted) / Hollow rate of hollow filament before woven or knitted × 100 = Hollow retention rate (%)
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106048813A (en) * 2016-08-11 2016-10-26 苏州维杰纺织有限公司 Shrink-proof wool core-spun yarn

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004084103A (en) * 2002-08-26 2004-03-18 Teijin Ltd Composite yarn
JP2004084102A (en) * 2002-08-26 2004-03-18 Teijin Ltd Polyester composite yarn
JP2005213708A (en) * 2004-02-02 2005-08-11 Teijin Techno Products Ltd Flame-retardant conjugated yarn

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004084103A (en) * 2002-08-26 2004-03-18 Teijin Ltd Composite yarn
JP2004084102A (en) * 2002-08-26 2004-03-18 Teijin Ltd Polyester composite yarn
JP2005213708A (en) * 2004-02-02 2005-08-11 Teijin Techno Products Ltd Flame-retardant conjugated yarn

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106048813A (en) * 2016-08-11 2016-10-26 苏州维杰纺织有限公司 Shrink-proof wool core-spun yarn

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