JP2007016356A - Knitted and woven fabric of hollow spun yarn and method for producing the same - Google Patents

Knitted and woven fabric of hollow spun yarn and method for producing the same Download PDF

Info

Publication number
JP2007016356A
JP2007016356A JP2005200428A JP2005200428A JP2007016356A JP 2007016356 A JP2007016356 A JP 2007016356A JP 2005200428 A JP2005200428 A JP 2005200428A JP 2005200428 A JP2005200428 A JP 2005200428A JP 2007016356 A JP2007016356 A JP 2007016356A
Authority
JP
Japan
Prior art keywords
spun yarn
hollow
fiber
knitted fabric
polylactic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005200428A
Other languages
Japanese (ja)
Inventor
Terushige Nakanishi
輝薫 中西
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unitika Textiles Ltd
Original Assignee
Unitika Textiles Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unitika Textiles Ltd filed Critical Unitika Textiles Ltd
Priority to JP2005200428A priority Critical patent/JP2007016356A/en
Publication of JP2007016356A publication Critical patent/JP2007016356A/en
Pending legal-status Critical Current

Links

Landscapes

  • Knitting Of Fabric (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide knitted and woven fabric made of hollow spun yarns excellent in light weight, bulkiness, warmth-keeping properties and quick drying properties and having little hollow crushing and a method for producing the same with suppressing environmental pollution. <P>SOLUTION: The knitted and woven fabric mainly comprises hollow spun yarns. The spun yarn is produced by preparing a double layered spun yarn in which a polylactic acid-based fiber is arranged as a core component and dissolving and removing the polylactic acid-based fiber. The method for producing the knitted and woven fabric of hollow spun yarn is to knit and weave the double layered spun yarn in which the polylactic acid-based fiber are arranged as the core component, subsequently treat the same with alkali. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、中空紡績糸織編物及びその製造方法に関するものである。   The present invention relates to a hollow spun yarn knitted fabric and a method for producing the same.

従来から、芯成分として溶解性繊維を配した複重層紡績糸が提案され、この複重層紡績糸を用いて織編物を作製した後、該溶解性繊維を溶解除去することで複重層紡績糸の横断面中央部に中空部を形成させた織編物が提案されている。この織編物は、軽量性、嵩高性に優れるため、主としてインナー用途に用いられている。   Conventionally, a multi-layer spun yarn in which a soluble fiber is arranged as a core component has been proposed. After producing a woven or knitted fabric using this multi-layer spun yarn, the soluble fiber is dissolved and removed to remove the multi-layer spun yarn. A woven or knitted fabric in which a hollow portion is formed at the center of the cross section has been proposed. Since this woven or knitted fabric is excellent in lightness and bulkiness, it is mainly used for inner use.

例えば、特許文献1には、ポリエステル系長繊維のPOY(POY:未延伸糸)の周囲を綿の繊維束で被覆してなる複合糸を使用した織物を、アルカリ処理することによりポリエステル系長繊維のPOYを除去し、綿の繊維束より構成される糸状が中空形状となった綿織物が開示されている。   For example, Patent Document 1 discloses that polyester-based long fibers are obtained by alkali treatment of a fabric using a composite yarn in which a POY (POY: undrawn yarn) of polyester-based long fibers is covered with a fiber bundle of cotton. A cotton fabric is disclosed in which the POY is removed, and the filament formed from a bundle of cotton fibers has a hollow shape.

また、特許文献2には、芯成分として水溶性ポリビニルアルコール系繊維を、鞘成分としてポリエステル系繊維を配してなる芯鞘型複合紡績糸を用いて製織した後、熱水処理を施して該芯成分を溶解除去する嵩高性織編物が提案されている。
特公平8−1026号公報(請求項1) 特開平9−302543号公報(実施例2)
In Patent Document 2, water-soluble polyvinyl alcohol fiber is woven using a core-sheath type composite spun yarn in which a polyester fiber is arranged as a sheath component, and then subjected to hot water treatment. A bulky woven or knitted fabric that dissolves and removes the core component has been proposed.
Japanese Patent Publication No. 8-1026 (Claim 1) JP-A-9-302543 (Example 2)

上記従来技術では溶解除去するものにまで石油系ポリマーが使用されていて石油原料を消費する。また、これらの織編物の製造において、複合紡績糸の芯成分を溶解除去した後の廃液には芯成分の繊維を構成するポリマーが含まれており、このポリマーが分解せずに長期に渡って地中に残るため、環境汚染を引き起こすという問題もある。   In the above-mentioned conventional technology, petroleum-based polymers are used up to what is dissolved and removed, and petroleum raw materials are consumed. Further, in the production of these woven and knitted fabrics, the waste liquid after dissolving and removing the core component of the composite spun yarn contains the polymer that constitutes the fiber of the core component, and this polymer does not decompose for a long period of time. There is also a problem of causing environmental pollution because it remains underground.

本発明は、上記のような従来技術の欠点を解消するものであり、軽量性、嵩高性、保温性及び速乾性に優れ、かつ中空つぶれの少ない中空紡績糸織編物、及びこの中空紡績糸織編物を効率よく、かつ環境汚染を抑制しつつ製造する方法を提供することを技術的課題とするものである。   The present invention eliminates the drawbacks of the prior art as described above, and is a hollow spun yarn knitted fabric that is excellent in lightness, bulkiness, heat retention and quick drying properties, and has little hollow crushing, and this hollow spun yarn knitted fabric. An object of the present invention is to provide a method for manufacturing efficiently and while suppressing environmental pollution.

本発明者は、上記課題を解決するために鋭意研究の結果、複合紡績糸の芯成分としてポリ乳酸系繊維を用いたところ、従来法と比較して効率よく芯成分を溶解除去できること、並びに芯成分を溶解除去した後の廃液が環境汚染を引き起こし難くなることを見出し、本発明に到達した。   As a result of intensive studies to solve the above problems, the present inventor has used polylactic acid fibers as the core component of the composite spun yarn, and can efficiently dissolve and remove the core component as compared with the conventional method. The present inventors have found that the waste liquid after dissolving and removing the components hardly causes environmental pollution, and reached the present invention.

すなわち、本発明の要旨は以下の通りである。
(1) 主として中空紡績糸からなる織編物であって、該中空紡績糸が、芯成分としてポリ乳酸系繊維を配してなる複重層紡績糸から該ポリ乳酸系繊維を溶解除去することにより得られたものであることを特徴とする中空紡績糸織編物。
(2)前記複重層紡績糸が、前記ポリ乳酸系繊維を多芯的に配してなることを特徴とする上記(1)記載の中空紡績糸織編物。
(3)前記複重層紡績糸が、鞘成分としてセルロース系繊維を配してなることを特徴とする上記(1)又は(2)記載の中空紡績糸織編物。
(4)前記複重層紡績糸が、鞘成分としてポリエステル短繊維を配してなることを特徴とする上記(1)〜(3)のいずれかに記載の中空紡績糸織編物。
(5)前記ポリエステル短繊維が中空繊維であることを特徴とする上記(4)記載の中空紡績糸織編物。
(6)前記複重層紡績糸が、鞘成分として外側部分にセルロース系繊維を配し、内側部分にポリエステル短繊維を配してなることを特徴とする上記(4)又は(5)記載の中空紡績糸織編物。
(7)芯成分としてポリ乳酸系繊維を配してなる複重層紡績糸を用いて製織編した後、アルカリ処理することを特徴とする上記(1)〜(6)のいずれかに記載の中空紡績糸織編物の製造方法。
That is, the gist of the present invention is as follows.
(1) A woven or knitted fabric mainly composed of hollow spun yarn, which is obtained by dissolving and removing the polylactic acid fiber from a multi-layer spun yarn in which the polylactic acid fiber is arranged as a core component. Hollow spun yarn knitted or knitted fabric characterized by being made.
(2) The hollow spun yarn knitted or knitted fabric according to (1), wherein the multi-layer spun yarn is formed by arranging the polylactic acid fibers in a multi-core manner.
(3) The hollow spun yarn knitted or knitted fabric according to (1) or (2) above, wherein the multi-layer spun yarn is formed by arranging a cellulosic fiber as a sheath component.
(4) The hollow spun yarn knitted fabric according to any one of (1) to (3) above, wherein the multi-layer spun yarn comprises polyester short fibers as a sheath component.
(5) The hollow spun yarn knitted fabric according to the above (4), wherein the polyester short fiber is a hollow fiber.
(6) The hollow according to (4) or (5), wherein the multi-layer spun yarn is formed by disposing a cellulosic fiber in an outer portion as a sheath component and a polyester short fiber in an inner portion. Spun yarn knitted fabric.
(7) The hollow according to any one of (1) to (6) above, wherein weaving and knitting using a multi-layer spun yarn having a polylactic acid fiber as a core component, followed by alkali treatment Manufacturing method of spun yarn knitted fabric.

本発明の中空紡績糸織編物は、軽量性、嵩高性、保温性及び速乾性に優れる。したがって、本発明の中空紡績糸織編物は、広く衣料用途に使用することができ、特に直接肌に触れるインナー用途に好適に用いることができる。   The hollow spun yarn knitted fabric of the present invention is excellent in lightness, bulkiness, heat retention and quick drying. Therefore, the hollow spun yarn knitted fabric of the present invention can be widely used for apparel, and can be suitably used for inner use that directly touches the skin.

また、本発明の中空紡績糸織編物の製造方法によれば、上記複重層紡績糸を含む織編物としてからアルカリ処理するので、製織編により中空部がつぶれるという心配がなく、効率よく芯成分のポリ乳酸系繊維を溶解除去することができる。そして、アルカリ処理後の廃液は、通常の中和処理によって環境を汚染することなく処分することができる。   Further, according to the method for producing a hollow spun yarn woven or knitted fabric of the present invention, since the woven or knitted fabric containing the above-mentioned multi-layer spun yarn is subjected to alkali treatment, there is no concern that the hollow portion will be crushed by the weaving and knitting, and the core component polycrystal is efficiently produced. The lactic acid fiber can be dissolved and removed. And the waste liquid after an alkali treatment can be disposed of without contaminating the environment by a normal neutralization treatment.

以下、本発明を詳細に説明する。   Hereinafter, the present invention will be described in detail.

本発明の中空紡績糸織編物は、中空紡績糸を用いてなる織編物である。中空紡績糸とは、紡績糸の横断面において繊維の存在しない中空部を有する紡績糸をいう。中空紡績糸の横断面形状としては、例えば、図1、5、6に示す単穴型の他、図2に示す2穴型に代表される複数の中空部を有する多穴型などがあげられる。   The hollow spun yarn knitted fabric of the present invention is a woven or knitted fabric using hollow spun yarn. The hollow spun yarn refers to a spun yarn having a hollow portion where no fiber exists in the cross section of the spun yarn. Examples of the cross-sectional shape of the hollow spun yarn include a single-hole type shown in FIGS. 1, 5, and 6, and a multi-hole type having a plurality of hollow parts represented by a two-hole type shown in FIG. .

中空紡績糸の中空率としては、10〜25%が好ましい。中空紡績糸の中空率とは、紡績糸横断面において中空部を含む全断面積に対する該中空部の断面積比率を指す。紡績糸の中空率が10%未満であると、中空部を有することによる保温性が低下する傾向にあるため好ましくない。一方、25%を超えると、外力によって中空部がつぶされやすい傾向にあるため好ましくない。   The hollow rate of the hollow spun yarn is preferably 10 to 25%. The hollow ratio of the hollow spun yarn refers to the ratio of the cross-sectional area of the hollow portion to the total cross-sectional area including the hollow portion in the cross-section of the spun yarn. If the hollow ratio of the spun yarn is less than 10%, the heat retention due to having the hollow portion tends to decrease, which is not preferable. On the other hand, if it exceeds 25%, the hollow portion tends to be crushed by an external force, which is not preferable.

本発明における中空紡績糸は、芯成分としてポリ乳酸系繊維を配してなる複重層紡績糸から該ポリ乳酸系繊維を溶解除去することにより得られる。ポリ乳酸系繊維の溶解除去は、製織編の前後いずれであってもよい。該複重層紡績糸の横断面形状の例を図3、4、7、8に示す。ポリ乳酸系繊維の配置としては、図3、7、8に示すような単芯型の他、図4に示す2芯型に代表される複数の芯成分を有する多芯型であってもよい。   The hollow spun yarn in the present invention can be obtained by dissolving and removing the polylactic acid fiber from a multi-layer spun yarn comprising polylactic acid fiber as a core component. The dissolution removal of the polylactic acid fiber may be performed before or after the weaving. Examples of the cross-sectional shape of the multi-layer spun yarn are shown in FIGS. The arrangement of the polylactic acid fibers may be a multi-core type having a plurality of core components represented by the 2-core type shown in FIG. 4 in addition to the single-core type as shown in FIGS. .

ポリ乳酸系繊維としては、乳酸の構造単位がL−乳酸であるポリL−乳酸、構造単位がD−乳酸であるポリD−乳酸、L−乳酸とD−乳酸との共重合体であるポリD,L−乳酸、もしくはポリD−乳酸とポリ−L乳酸とからなるポリ乳酸ステレオコンプレックス、さらにはD−乳酸とヒドロキシカルボン酸との共重合体、L−乳酸とヒドロキシカルボン酸との共重合体、D−乳酸とL−乳酸とヒドロキシカルボン酸との共重合体などのポリ乳酸系ポリマーで形成されたポリ乳酸系繊維を用いることができる。   Examples of the polylactic acid fiber include poly L-lactic acid in which the structural unit of lactic acid is L-lactic acid, poly D-lactic acid in which the structural unit is D-lactic acid, and poly which is a copolymer of L-lactic acid and D-lactic acid. D, L-lactic acid, or polylactic acid stereocomplex composed of poly-D-lactic acid and poly-L-lactic acid, a copolymer of D-lactic acid and hydroxycarboxylic acid, and a copolymer of L-lactic acid and hydroxycarboxylic acid A polylactic acid fiber formed of a polylactic acid polymer such as a coalescence, a copolymer of D-lactic acid, L-lactic acid, and hydroxycarboxylic acid can be used.

ここで、前記ヒドロキシカルボン酸としては、グリコール酸、ヒドロキシ酪酸、ヒドロキシ吉草酸、ヒドロキシペンタン酸、ヒドロキシカプロン酸、ヒドロキシヘプタン酸、ヒドロキシカプリル酸などがあげられる。   Here, examples of the hydroxycarboxylic acid include glycolic acid, hydroxybutyric acid, hydroxyvaleric acid, hydroxypentanoic acid, hydroxycaproic acid, hydroxyheptanoic acid, and hydroxycaprylic acid.

ポリ乳酸系ポリマーの数平均分子量としては、製糸性の点から、2万〜15万であることが好ましく、4万〜15万であることがより好ましい。ポリ乳酸系ポリマーの融点としては、サイジング工程での受熱による繊維の溶融を抑制する点から、120℃以上が好ましく、150℃以上がより好ましい。   The number average molecular weight of the polylactic acid-based polymer is preferably from 20,000 to 150,000, more preferably from 40,000 to 150,000, from the viewpoint of yarn production. The melting point of the polylactic acid-based polymer is preferably 120 ° C. or higher, more preferably 150 ° C. or higher, from the viewpoint of suppressing fiber melting due to heat reception in the sizing step.

上記ポリ乳酸系繊維の横断面形状としては、どのような形状であってもよいが、溶解除去に要する時間を短縮させたい場合は、中空繊維を採用することが好ましい。繊維の形態としては、長繊維、短繊維の何れであってもよい。   The cross-sectional shape of the polylactic acid fiber may be any shape, but it is preferable to employ a hollow fiber when it is desired to shorten the time required for dissolution and removal. The form of the fiber may be either a long fiber or a short fiber.

また、上記ポリ乳酸系繊維の結晶化度としては、繊維の機械的強度を向上させる点から10〜40%の範囲にあることが好ましい。上記範囲の結晶化度を達成するには、熱処理や延伸を施せばよい。特に、ポリ乳酸系ポリマーに対して、例えば、タルク、窒化ホウ素、炭酸カルシウム、炭酸マグネシウム、酸化チタンなどの結晶核剤を添加することにより結晶化度を向上させやすくなるので好ましい。結晶核剤を添加することは、繊維の機械的強度の向上だけでなく、耐熱性を向上させ、しかも溶融紡糸工程及び冷却工程における糸条間の融着(ブロッキング)をも防止しうる点で好ましい。結晶核剤の添加量としては、ポリ乳酸系ポリマーに対し、0.1〜3.0質量%が好ましく、0.2〜2.0質量%がより好ましい。   The crystallinity of the polylactic acid fiber is preferably in the range of 10 to 40% from the viewpoint of improving the mechanical strength of the fiber. In order to achieve the crystallinity in the above range, heat treatment or stretching may be performed. In particular, it is preferable to add a crystal nucleating agent such as talc, boron nitride, calcium carbonate, magnesium carbonate, and titanium oxide to the polylactic acid-based polymer because the crystallinity can be easily improved. The addition of the crystal nucleating agent not only improves the mechanical strength of the fiber, but also improves the heat resistance, and also prevents the fusion (blocking) between yarns in the melt spinning process and the cooling process. preferable. The addition amount of the crystal nucleating agent is preferably 0.1 to 3.0% by mass and more preferably 0.2 to 2.0% by mass with respect to the polylactic acid polymer.

一方、複重層紡績糸の鞘成分の繊維としては、特に限定されるものではないが、ポリエステル、ナイロン、アクリル、ポリウレタンなどの合成繊維、ジアセテート、トリアセテートなどの半合成繊維、ポリノジック、ビスコースレーヨン、銅アンモニアレーヨン、溶剤紡糸セルロース繊維などの再生繊維、綿、麻、竹、絹、羊毛などの天然繊維を用いることができる。中でも、中空紡績糸織編物の嵩高性向上の点からセルロース系繊維を用いることが好ましい。セルロース系繊維としては、ポリノジック、ビスコースレーヨン、銅アンモニアレーヨン、溶剤紡糸セルロース繊維、綿、麻、竹繊維などがあげられる。   On the other hand, the fiber of the sheath component of the multi-layer spun yarn is not particularly limited, but synthetic fibers such as polyester, nylon, acrylic and polyurethane, semi-synthetic fibers such as diacetate and triacetate, polynosic and viscose rayon Regenerated fibers such as copper ammonia rayon and solvent-spun cellulose fibers, and natural fibers such as cotton, hemp, bamboo, silk, and wool can be used. Among these, it is preferable to use cellulosic fibers from the viewpoint of improving the bulkiness of the hollow spun yarn knitted fabric. Examples of the cellulosic fiber include polynosic, viscose rayon, copper ammonia rayon, solvent-spun cellulose fiber, cotton, hemp, bamboo fiber and the like.

また、鞘成分においては、複数種の繊維が混合されて用いられていてもよい。混合形態としては、混紡あるいは多層構造の何れであってよいが、各繊維の特性を中空紡績糸織編物に効果的に反映できる点で多層構造を採用することが好ましい。多層構造とは、複数の繊維層が重なりあっている態様をいう。繊維層の数は、適宜設定することができるが、製造上の点から2層が好ましい。   In the sheath component, a plurality of types of fibers may be mixed and used. The mixing form may be either a mixed spinning or a multilayer structure, but it is preferable to adopt a multilayer structure in that the characteristics of each fiber can be effectively reflected in the hollow spun yarn knitted fabric. A multilayer structure refers to an embodiment in which a plurality of fiber layers are overlapped. The number of fiber layers can be appropriately set, but two layers are preferable from the viewpoint of production.

鞘成分の繊維の形態としては、長繊維、短繊維の何れであってもよいが、中空紡績糸織編物の風合いを向上させる点から短繊維が好ましい。特に、速乾性を向上させる点でポリエステル短繊維が好ましい。   The fiber form of the sheath component may be either a long fiber or a short fiber, but a short fiber is preferred from the viewpoint of improving the texture of the hollow spun yarn knitted fabric. In particular, polyester short fibers are preferable in terms of improving quick drying properties.

鞘成分の繊維の横断面形状としては、特に限定されるものではなく、通常の丸断面の他、楕円形、三角形、多角形、井型などの異形断面であってもよい。特に横断面形状として、マカロニ型、井型などの中空型(以下、横断面形状が中空型である繊維を中空繊維と記す)を採用すると、織編物の軽量性、保温性を高めることができる。これは、前記した中空紡績糸の中空部、すなわちマクロ的な中空部と、鞘成分を構成する繊維の内部に存在するミクロ的な中空部との相乗効果による。ただし、前記した中空紡績糸の中空率の算出にあたっては、中空繊維内部のミクロ的な中空部は中空部とは見ない。   The cross-sectional shape of the fiber of the sheath component is not particularly limited, and may be an elliptical shape, a triangular shape, a polygonal shape, a well-shaped cross-section shape such as a well shape in addition to a normal round cross section. In particular, when a hollow type such as a macaroni type or a well type (hereinafter, a fiber having a horizontal cross-sectional shape is referred to as a hollow fiber) is adopted as the cross-sectional shape, the lightness and heat retention of the woven or knitted fabric can be improved. . This is due to the synergistic effect of the hollow portion of the hollow spun yarn, that is, the macro hollow portion, and the micro hollow portion existing inside the fiber constituting the sheath component. However, in calculating the hollow ratio of the hollow spun yarn as described above, the microscopic hollow portion inside the hollow fiber is not regarded as a hollow portion.

なお、ミクロ的な中空部にかかる上記中空繊維の中空率(中空部を含む中空繊維全断面積に対する該中空部の占める面積比率)は、10〜50%が好ましい。中空率が10%未満では、中空繊維とする効果に乏しい。一方、中空率が50%を超えるものは、安定して製造し難いので好ましくない。   In addition, as for the hollow ratio (area ratio which the said hollow part occupies with respect to the hollow fiber whole cross-sectional area containing a hollow part) of the said hollow fiber concerning a micro hollow part, 10-50% is preferable. When the hollow ratio is less than 10%, the effect of forming hollow fibers is poor. On the other hand, those having a hollowness ratio exceeding 50% are not preferred because they are difficult to produce stably.

また、鞘成分の繊維の繊度としては、0.5〜3.3dtexが好ましい。短繊維の場合の繊維長としては、30〜60mmが好ましい。繊度及び繊維長を上記の範囲に設定することで、繊維同士の絡みが良くなり、中空紡績糸織編物が擦れなどの外力を受けても繊維層間のずれや剥離が生じ難くなる。   The fineness of the sheath component fiber is preferably 0.5 to 3.3 dtex. The fiber length in the case of short fibers is preferably 30 to 60 mm. By setting the fineness and the fiber length within the above ranges, the entanglement between the fibers is improved, and even when the hollow spun yarn knitted fabric is subjected to an external force such as rubbing, the fiber layer is less likely to be displaced or peeled off.

本発明の中空紡績糸織編物は、軽量性、嵩高性、保温性及び速乾性に優れているが、これらの特性をより向上させるには、中空紡績糸がセルロース系繊維からなる層とポリエステル短繊維からなる層との二層構造を有していることが好ましい。セルロース系繊維により中空紡績糸織編物の嵩高性を向上させることができ、ポリエステル短繊維により速乾性を向上させることができる。特に、セルロース系繊維を外側に配し、ポリエステル短繊維を内側に配することで中空紡績糸織編物の嵩高性を一層向上させることができるので好ましい。このような中空紡績糸の横断面形状を図5に例示する。   The hollow spun yarn knitted fabric of the present invention is excellent in lightness, bulkiness, heat retention and quick drying, but in order to further improve these characteristics, the hollow spun yarn is composed of a cellulose fiber layer and a polyester short fiber. It preferably has a two-layer structure with a layer composed of Cellulose fibers can improve the bulkiness of the hollow spun yarn knitted fabric, and polyester short fibers can improve the quick-drying property. In particular, it is preferable to dispose the cellulosic fibers on the outside and the polyester short fibers on the inside because the bulkiness of the hollow spun yarn knitted fabric can be further improved. The cross-sectional shape of such a hollow spun yarn is illustrated in FIG.

本発明においては、特に上記ポリエステル短繊維が中空繊維であると、軽量性及び保温性を一層向上させることができるので好ましい。そのような外側にセルロース系繊維を配し、内側に中空のポリエステル短繊維を配してなる中空紡績糸の横断面形状を図6に例示する。   In the present invention, it is particularly preferable that the polyester short fiber is a hollow fiber, since the lightness and heat retention can be further improved. FIG. 6 illustrates a cross-sectional shape of a hollow spun yarn in which cellulosic fibers are arranged on the outside and hollow polyester short fibers are arranged on the inside.

本発明においては、本発明の効果を損なわない範囲であれば、織編物中に上記した中空紡績糸以外の糸条(以下、他糸条と記す)が含まれていてもよい。ただし、本発明の効果を十分に発現するには織編物中に占める中空紡績糸の質量比率が60質量%以上であることが好ましい。   In the present invention, yarns other than the hollow spun yarn described above (hereinafter referred to as other yarns) may be included in the woven or knitted fabric as long as the effects of the present invention are not impaired. However, the mass ratio of the hollow spun yarn in the woven or knitted fabric is preferably 60% by mass or more in order to fully exhibit the effects of the present invention.

他糸条の種類としては、特に限定されるものでない。また、織編物中における他糸条の複合形態としては、特に限定されるものでなく、例えば、交編織、配列、混繊、合撚などがあげられる。   The type of other yarn is not particularly limited. In addition, the composite form of the other yarns in the woven or knitted fabric is not particularly limited, and examples thereof include union knitting, arrangement, mixed fiber, and twisting.

次に、本発明の中空紡績糸織編物の製造方法について説明する。   Next, a method for producing the hollow spun yarn knitted fabric of the present invention will be described.

本発明の中空紡績糸織編物を製造するには、まず、芯成分としてポリ乳酸系繊維を配してなる、例えば図3、4、7、8に示すような横断面形状を有する複重層紡績糸を予め作製する。   In order to produce the hollow spun yarn knitted fabric of the present invention, first, a multi-layer spun yarn having a cross-sectional shape as shown in FIGS. Is prepared in advance.

そのような複重層紡績糸は、通常の紡績手段により得ることができる。例えば、図3に示すような横断面形状を有する複重層紡績糸を得るには、まず、図9の如く、ポリ乳酸系繊維からなるスライバー(SA)と、鞘成分の繊維からなるスライバー(SB)とを粗紡機に並行に供給し、SAにSBを巻き付けながら粗糸を紡出する。次に、この粗糸を精紡することにより得ることができる。   Such a multi-layer spun yarn can be obtained by ordinary spinning means. For example, in order to obtain a multi-layer spun yarn having a cross-sectional shape as shown in FIG. 3, first, as shown in FIG. 9, a sliver (SA) made of polylactic acid fiber and a sliver (SB) made of sheath component fibers are used. ) To the roving machine in parallel, and the roving yarn is spun while SB is wound around the SA. Next, this roving can be obtained by spinning.

図4に示すような横断面形状を有する複重層紡績糸を得るには、芯成分としてポリ乳酸系繊維を配してなる粗糸を精紡交撚することにより得ることができる。   In order to obtain a multi-layer spun yarn having a cross-sectional shape as shown in FIG. 4, it can be obtained by finely spinning and twisting a roving yarn comprising a polylactic acid fiber as a core component.

図7、8に示すような横断面形状を有する複重層紡績糸を得るには、まず、図10の如く、鞘成分の内側部分の繊維からなるスライバー(SB1)と、鞘成分の外側部分の繊維からなるスライバー(SB2)とを重ねあわせた状態で粗紡機に供給し、SAにSB1及びSB2を巻き付けながら粗糸を紡出する。次に、この粗糸を精紡することにより得ることができる。また、SB1とSB2との位置関係に一定の間隔を設けつつ、SAと共に粗紡機へ並行に供給し、SAを芯とし、SB1、SB2を順次SAに巻き付けながら粗糸を紡出し、しかる後にこの粗糸を精紡することによっても得ることができる。あるいは、まず、SAと、SB1とを粗紡機に並行に供給し、SAにSB1を巻き付けながら粗糸(RA)を紡出する。次に、このRAと、通常の紡績手段により得られた、鞘成分の外側部分の繊維からなる粗糸(RB)とを精紡機に並行に供給し、RAにRBを巻き付けながら精紡することによっても得ることができる。   In order to obtain a multi-layer spun yarn having a cross-sectional shape as shown in FIGS. 7 and 8, first, as shown in FIG. 10, a sliver (SB1) made of fibers in the inner portion of the sheath component and an outer portion of the sheath component. The sliver (SB2) made of fibers is superposed on the roving machine, and the roving yarn is spun while SB1 and SB2 are wound around the SA. Next, this roving can be obtained by spinning. In addition, while providing a certain interval in the positional relationship between SB1 and SB2, the SA and the rough spinning machine are supplied in parallel to the SA, and the SA is used as a core, and the SB1 and SB2 are sequentially wound around the SA to spin the roving yarn. It can also be obtained by spinning a roving yarn. Alternatively, first, SA and SB1 are supplied to the roving machine in parallel, and the roving yarn (RA) is spun while SB1 is wound around the SA. Next, this RA and the roving yarn (RB) made of fibers of the outer portion of the sheath component obtained by ordinary spinning means are supplied in parallel to the spinning machine, and the spinning is performed while winding the RB around the RA. Can also be obtained.

次いで、上記の複重層紡績糸を用いて通常の製織編手段により製織編した後に、アルカリ処理を行う。複重層紡績糸にアルカリ処理を施した後に製織編する場合と比して、製織編の過程で中空つぶれが生じる恐れがないので有利である。アルカリ処理に用いる処理液としては、通常、濃度20〜30g/Lの水酸化ナトリウム水溶液が好ましい。処理条件としては、液流染色機などを用いて80〜100℃で30〜60分間処理することが好ましい。このようなアルカリ処理により、複重層紡績糸の芯成分であるポリ乳酸系繊維を溶解除去して中空紡績糸とすることができる。アルカリ処理した後の廃液に含まれるポリ乳酸系ポリマーは、生分解性を有するので、廃液に通常の中和処理を適切に行った後に廃棄すれば、環境汚染を引き起こすことがない。   Next, after weaving and knitting by the usual weaving and knitting means using the above multi-layer spun yarn, alkali treatment is performed. Compared with the case of weaving and knitting after subjecting the multi-layer spun yarn to alkali treatment, there is no possibility of hollow crushing during the weaving and knitting process, which is advantageous. As the treatment liquid used for the alkali treatment, a sodium hydroxide aqueous solution having a concentration of 20 to 30 g / L is usually preferable. As processing conditions, it is preferable to process at 80-100 degreeC for 30 to 60 minutes using a liquid dyeing machine. By such alkali treatment, it is possible to dissolve and remove the polylactic acid fiber, which is the core component of the multilayer spun yarn, to obtain a hollow spun yarn. Since the polylactic acid polymer contained in the waste liquid after the alkali treatment has biodegradability, if the waste liquid is appropriately subjected to normal neutralization treatment and then discarded, it does not cause environmental pollution.

また、本発明の製造方法においては、必要に応じてプレセット、染色、ファイナルセットなどを行ってもよい。特に、複重層紡績糸の鞘成分として合成繊維が配されている場合、アルカリ処理の前にプレセットを施すことにより、中空紡績糸織編物の形態安定性を向上させることができる。これは、鞘成分の合成繊維が熱固定されるためであり、衣服となった後の洗濯又はアイロン掛けなどによる中空つぶれが生じ難くなるので好ましい。   Moreover, in the manufacturing method of this invention, you may perform a preset, dyeing | staining, final setting, etc. as needed. In particular, when a synthetic fiber is arranged as a sheath component of a multi-layer spun yarn, the shape stability of the hollow spun yarn knitted fabric can be improved by performing a preset before the alkali treatment. This is because the synthetic fiber of the sheath component is heat-set, and it is difficult to cause hollow crushing due to washing or ironing after becoming a garment.

プレセットの条件としては、合成繊維の種類を考慮して適宜設定すればよいが、例えばポリエステル繊維の場合は、160〜180℃で1〜5分間とすることが好ましい。温度が低すぎたり処理時間が短すぎたりすると、鞘成分の合成繊維が十分に熱固定されない場合があり、好ましくない。一方、温度が高すぎたり処理時間が長すぎたりすると、鞘成分の合成繊維が黄変して織編物の風合いを硬化させる場合があり、好ましくない。   The conditions for the presetting may be set as appropriate in consideration of the type of synthetic fiber. If the temperature is too low or the treatment time is too short, the synthetic fiber of the sheath component may not be sufficiently heat-set, which is not preferable. On the other hand, if the temperature is too high or the treatment time is too long, the synthetic fiber of the sheath component may turn yellow and the texture of the woven or knitted fabric may be cured, which is not preferable.

次に、本発明を実施例により具体的に説明する。なお、実施例における中空紡績糸及び中空ポリエステル短繊維の各中空率は、下記の方法で算出した。   Next, the present invention will be specifically described with reference to examples. In addition, each hollow rate of the hollow spun yarn and hollow polyester short fiber in an Example was computed with the following method.

(1)中空紡績糸の中空率
まず、最終的に得られた中空紡績糸織編物より中空紡績糸をサンプリングし、該紡績糸の横断面形状を電子顕微鏡(倍率500倍)で撮影し、写真をトレースして中空部を含む紡績糸全体に相当する部分を切り取り、その質量(A)を測定する。測定後さらに中空部に相当する部分を切り取ってその質量(B)を測定する。この作業を10本のサンプルについて行い、A、Bの平均値を算出し、それらの値を下記式に代入し、中空紡績糸の中空率とする。
(1) Hollow ratio of hollow spun yarn First, hollow spun yarn is sampled from the finally obtained hollow spun yarn knitted fabric, and the cross-sectional shape of the spun yarn is photographed with an electron microscope (500 times magnification). The part corresponding to the whole spun yarn including the hollow part is cut out and the mass (A) is measured. After the measurement, a portion corresponding to the hollow portion is cut out and its mass (B) is measured. This operation is performed for 10 samples, the average values of A and B are calculated, and those values are substituted into the following formula to obtain the hollow ratio of the hollow spun yarn.

(2)中空ポリエステル短繊維の中空率
中空ポリエステル短繊維の横断面形状を電子顕微鏡(倍率7500倍)で撮影し、写真をトレースして中空部を含む中空ポリエステル短繊維全体に相当する部分を切り取り、その質量(C)を測定する。測定後さらに中空部に相当する部分を切り取ってその質量(D)を測定する。この作業を10本のサンプルについて行い、C、Dの平均値を算出し、それらの値を下記式に代入し、中空ポリエステル短繊維の中空率とする。
(2) Hollow ratio of hollow polyester short fiber Take a cross-sectional shape of the hollow polyester short fiber with an electron microscope (magnification: 7500 times), trace the photo and cut out the part corresponding to the whole hollow polyester short fiber including the hollow part The mass (C) is measured. After the measurement, a portion corresponding to the hollow portion is cut out and its mass (D) is measured. This operation is performed for 10 samples, the average values of C and D are calculated, and those values are substituted into the following formula to obtain the hollow ratio of the hollow polyester short fiber.

(実施例1)
ポリ乳酸系繊維(ユニチカ(株)製「テラマック(商品名)」、1.7dtex×38mm)及び綿(エジプト超長綿、1.3dtex×38mm)の各原綿をそれぞれ別々に紡績工程に投入し、ポリ乳酸系繊維からなるスライバーSA、綿からなるスライバーSBを得た。これら2種のスライバーの単位長さ当り質量比率は、SA:SB=2:8であった。
Example 1
Polylactic acid fibers ("Terramac (trade name)" manufactured by Unitika Ltd., 1.7 dtex x 38 mm) and cotton (Egypt ultra-long cotton, 1.3 dtex x 38 mm) are introduced separately into the spinning process. A sliver SA made of polylactic acid fiber and a sliver SB made of cotton were obtained. The mass ratio per unit length of these two slivers was SA: SB = 2: 8.

次に、図9に示す粗紡機へ上記2種のスライバーを供給するにあたり、スライバーSBをフライヤーヘッド11の位置からみてドラフト域の内側に供給し、スライバーSAを外側に供給した。各スライバーはバックローラー6を通過後、エプロン7及びセカンドローラー8を通過する過程でドラフトされ、フロントローラー9を通過後、スライバーSAにスライバーSBを巻付けて繊維束10とした後、回転するフライヤーにより加撚し、太さ240gr/30yd(1gr=0.065g、1yd=0.9144m)、撚数1.0T/2.54cmの粗糸として巻取った。次いで、この粗糸を2本用いて精紡交撚し、40番手双糸(英式綿番手)の複重層紡績糸を得た。   Next, when supplying the above-mentioned two types of sliver to the roving machine shown in FIG. 9, the sliver SB was supplied to the inside of the draft area as viewed from the position of the fryer head 11, and the sliver SA was supplied to the outside. Each sliver is drafted in the process of passing through the apron 7 and the second roller 8 after passing through the back roller 6, passing through the front roller 9, winding the sliver SB around the sliver SA to form a fiber bundle 10, and then a rotating flyer Was twisted and wound up as a roving yarn having a thickness of 240 gr / 30 yd (1 gr = 0.065 g, 1 yd = 0.9144 m) and a twist number of 1.0 T / 2.54 cm. Subsequently, the two spun yarns were used for fine spinning and twisting to obtain a double-layer spun yarn of 40 count double yarn (English cotton count).

得られた複重層紡績糸は、図4に示すような横断面形状を有する、2芯型の複重層紡績糸であった。   The obtained multi-layer spun yarn was a two-core multi-layer spun yarn having a cross-sectional shape as shown in FIG.

次に、この複重層紡績糸を用いて釜径76cm、針密度22本/2.54cmのシングル丸編機で天竺編を編成した。その後、得られた生機を濃度20g/Lの水酸化ナトリウム水溶液中で浴比1:20、97℃×30分間アルカリ処理した。その後、反応染料を用いて80℃×60分間染色を行い、柔軟処理を行った後、ピンテンターにて160℃×2分のファイナルセットを行い、本発明の中空紡績糸織編物を得た。
この中空紡績糸織編物に含まれる中空紡績糸は、図2に示すような横断面形状を有し、中空紡績糸の中空率は20%であった。
Next, using this multi-layer spun yarn, a tentacle knitting was knitted with a single circular knitting machine having a hook diameter of 76 cm and a needle density of 22 / 2.54 cm. Then, the obtained raw machine was alkali-treated in an aqueous solution of sodium hydroxide having a concentration of 20 g / L at a bath ratio of 1:20 at 97 ° C. for 30 minutes. Thereafter, dyeing was performed using a reactive dye at 80 ° C. for 60 minutes, and after softening, final setting was performed at 160 ° C. for 2 minutes using a pin tenter to obtain a hollow spun yarn knitted fabric of the present invention.
The hollow spun yarn contained in the hollow spun yarn knitted fabric had a cross-sectional shape as shown in FIG. 2, and the hollow ratio of the hollow spun yarn was 20%.

(実施例2)
ポリ乳酸系繊維(ユニチカ(株)製「テラマック(商品名)」、1.7dtex×38mm)、中空ポリエステル短繊維(1.4dtex×38mm)、及び綿(エジプト超長綿、1.3 dtex×38mm)の各原綿をそれぞれ別々に紡績工程に投入し、ポリ乳酸系繊維からなるスライバーSA、中空ポリエステル短繊維(中空率12%)からなるスライバーSB1、及び綿からなるスライバーSB2を得た。これら3種のスライバーの単位長さ当り質量比率は、SA:SB1:SB2=3:5:12であった。
(Example 2)
Polylactic acid fiber ("Terramac (trade name)" manufactured by Unitika Ltd., 1.7 dtex x 38 mm), hollow polyester short fiber (1.4 dtex x 38 mm), and cotton (Egypt ultra-long cotton, 1.3 dtex x 38 mm) were separately fed into the spinning process to obtain a sliver SA made of polylactic acid fibers, a sliver SB1 made of hollow polyester short fibers (hollow rate 12%), and a sliver SB2 made of cotton. The mass ratio per unit length of these three slivers was SA: SB1: SB2 = 3: 5: 12.

次に、図10に示す粗紡機へ上記3種のスライバーを供給するにあたり、スライバーSB1とSB2とを、SB1がSA側に配されるように重ねあわせつつ、フライヤーヘッド11の位置からみてドラフト域の内側に供給した。スライバーSAは、ドラフト域の外側に供給した。各スライバーはバックローラー6を通過後、エプロン7及びセカンドローラー8を通過する過程でドラフトされ、フロントローラー9を通過後、スライバーSAにスライバーSB1、SB2を巻付けて繊維束10とした後、回転するフライヤーにより加撚し、太さ280gr/30yd(1gr=0.065g、1yd=0.9144m)、撚数0.8T/2.54cmの粗糸として巻取った。次いで、この粗糸を精紡し、26番手(英式綿番手)の複重層紡績糸を得た。   Next, when supplying the above three types of sliver to the roving machine shown in FIG. 10, the sliver SB1 and SB2 are overlapped so that SB1 is arranged on the SA side, and the draft area as seen from the position of the flyer head 11 Supplied inside. Sliver SA was supplied to the outside of the draft area. Each sliver passes through the back roller 6 and is drafted in the process of passing through the apron 7 and the second roller 8. After passing through the front roller 9, the sliver SB 1 and SB 2 are wound around the sliver SA to form a fiber bundle 10, and then rotated. And twisted with a fryer, and wound up as a roving yarn having a thickness of 280 gr / 30 yd (1 gr = 0.065 g, 1 yd = 0.9144 m) and a twist number of 0.8 T / 2.54 cm. Next, this roving was finely spun to obtain a double-layer spun yarn of 26th (English cotton count).

得られた複重層紡績糸は、図8の如く、芯成分としてポリ乳酸系繊維を配し、鞘成分として内側部分に中空ポリエステル短繊維を、外側部分に綿を配する複重層紡績糸であった。   As shown in FIG. 8, the obtained multi-layer spun yarn is a multi-layer spun yarn in which polylactic acid fibers are arranged as a core component, hollow polyester short fibers are arranged as an inner portion, and cotton is arranged as an outer portion. It was.

次に、この複重層紡績糸を用いて釜径76cm、針密度24本/2.54cmの両面丸編機で袋編みを編成した。その後、ピンテンターを用いて、170℃×2分間プレセットし、濃度20g/Lの水酸化ナトリウム水溶液中で浴比1:20、97℃×30分間アルカリ処理した。その後、分散染料を用いて130℃×60分間染色した後、反応染料を用いて80℃×60分間染色した。さらに、柔軟処理を行った後、ピンテンターにて160℃×2分のファイナルセットを行い、本発明の中空紡績糸織編物を得た。
この中空紡績糸織編物に含まれる中空紡績糸は、図6に示すような横断面形状を有し、中空紡績糸の中空率は15%であった。
Next, bag knitting was knitted using this double-layer spun yarn with a double-sided circular knitting machine having a hook diameter of 76 cm and a needle density of 24 / 2.54 cm. Then, using a pin tenter, it was preset at 170 ° C. for 2 minutes, and alkali-treated in a sodium hydroxide aqueous solution having a concentration of 20 g / L at a bath ratio of 1:20 at 97 ° C. for 30 minutes. Then, after dyeing | staining for 130 degreeC x 60 minutes using a disperse dye, it dye | stained for 80 degreeC x 60 minutes using the reactive dye. Further, after performing the softening treatment, final setting was performed at 160 ° C. for 2 minutes using a pin tenter to obtain the hollow spun yarn knitted fabric of the present invention.
The hollow spun yarn contained in this hollow spun yarn knitted fabric had a cross-sectional shape as shown in FIG. 6, and the hollow ratio of the hollow spun yarn was 15%.

(比較例1)
ポリ乳酸系繊維に代えて通常のポリエステル繊維(中実糸、1.4dtex×38mm)を用いたこと以外は、実施例1と同様にして、比較用の織編物を得た。
(Comparative Example 1)
A comparative woven or knitted fabric was obtained in the same manner as in Example 1 except that ordinary polyester fiber (solid yarn, 1.4 dtex × 38 mm) was used instead of the polylactic acid fiber.

上記、本発明の中空紡績糸織編物(実施例1、2)は、軽量性、嵩高性、保温性及び速乾性に優れたものであった。   The hollow spun yarn knitted fabric of the present invention (Examples 1 and 2) was excellent in lightness, bulkiness, heat retention and quick drying.

これに対し、比較例1については、中空部を有しない複重層紡績糸が用いられているため、軽量性、保温性に劣るものとなった。   On the other hand, about the comparative example 1, since the multi-layer spun yarn which does not have a hollow part is used, it became inferior to lightness and heat retention.

本発明に使用できる単穴型の中空紡績糸の横断面形状を示す図である。It is a figure which shows the cross-sectional shape of the single hole type | formula hollow spun yarn which can be used for this invention. 本発明に使用できる2穴型の中空紡績糸の横断面形状を示す図である。It is a figure which shows the cross-sectional shape of the 2-hole type hollow spun yarn which can be used for this invention. 本発明に使用できる、ポリ乳酸系繊維が単芯的に配された該複重層紡績糸の横断面形状を示す図である。It is a figure which shows the cross-sectional shape of this multilayered spun yarn in which the polylactic acid type fiber which can be used for this invention was arranged by single core. 本発明に使用できる、ポリ乳酸系繊維が2芯的に配された複重層紡績糸の横断面形状を示す図である。It is a figure which shows the cross-sectional shape of the multilayered spun yarn in which the polylactic acid type fiber which can be used for this invention was distribute | arranged to 2 cores. 本発明に好ましく使用できる、外側にセルロース系繊維を配し内側にポリエステル短繊維を配してなる単穴型の中空紡績糸の横断面形状を示す図である。It is a figure which shows the cross-sectional shape of the single hole type hollow spun yarn which arrange | positions a cellulosic fiber on the outer side and arrange | positions the polyester short fiber on the inner side which can be preferably used for this invention. 本発明に好ましく使用できる、外側にセルロース系繊維を配し内側に中空ポリエステル短繊維を配してなる単穴型の中空紡績糸の横断面形状を示す図である。It is a figure which shows the cross-sectional shape of the single hole type hollow spun yarn which arrange | positions a cellulosic fiber outside and can arrange | position a hollow polyester short fiber inside, which can be preferably used for this invention. 本発明に好ましく使用できる、芯成分としてポリ乳酸系繊維を単芯的に配してなり、鞘成分として内側部分にセルロース系繊維を配し外側部分にポリエステル短繊維を配してなる複重層紡績糸の横断面形状を示す図である。A multi-layer spinning which can be preferably used in the present invention, comprising a polylactic acid fiber as a core component in a single core, a cellulose fiber as an inner portion and a polyester short fiber as an outer portion as a sheath component It is a figure which shows the cross-sectional shape of a thread | yarn. 本発明に好ましく使用できる、芯成分としてポリ乳酸系繊維を単芯的に配してなり、鞘成分として内側部分にセルロース系繊維を配し外側部分に中空ポリエステル短繊維を配してなる複重層紡績糸の横断面形状を示す図である。A multi-layer comprising polylactic acid fibers as a core component, which can be preferably used in the present invention, a cellulosic fiber as an inner portion and a hollow polyester short fiber as an outer portion as a sheath component It is a figure which shows the cross-sectional shape of a spun yarn. 本発明に使用できる複重層紡績糸の粗糸を作製する粗紡機の一例を示す概略平面図である。1 is a schematic plan view showing an example of a roving machine for producing a roving of a multi-layer spun yarn that can be used in the present invention. 本発明に使用できる複重層紡績糸の粗糸を作製する粗紡機の一例を示す概略平面図である。1 is a schematic plan view showing an example of a roving machine for producing a roving of a multi-layer spun yarn that can be used in the present invention.

符号の説明Explanation of symbols

1 鞘成分の繊維
2 ポリ乳酸系繊維
3 セルロース系繊維
4 ポリエステル短繊維
5 中空ポリエステル短繊維
6 バックローラー
7 エプロン
8 セカンドローラー
9 フロントローラー
10 繊維束
11 フライヤーヘッド
SA ポリ乳酸系繊維からなるスライバー
SB 鞘成分の繊維からなるスライバー
SB1 鞘成分の内側部分の繊維からなるスライバー
SB2 鞘成分の外側部分の繊維からなるスライバー
DESCRIPTION OF SYMBOLS 1 Fiber of sheath component 2 Polylactic acid fiber 3 Cellulose fiber 4 Polyester short fiber 5 Hollow polyester short fiber 6 Back roller 7 Apron 8 Second roller 9 Front roller 10 Fiber bundle 11 Flyer head SA Sliver made of polylactic acid fiber SB sheath Sliver consisting of the fibers of the component SB1 Sliver consisting of the fibers of the inner portion of the sheath component SB2 Sliver consisting of the fibers of the outer portion of the sheath component

Claims (7)

主として中空紡績糸からなる織編物であって、該中空紡績糸が、芯成分としてポリ乳酸系繊維を配してなる複重層紡績糸から該ポリ乳酸系繊維を溶解除去することにより得られたものであることを特徴とする中空紡績糸織編物。   Woven knitted fabric mainly composed of hollow spun yarn, the hollow spun yarn obtained by dissolving and removing the polylactic acid fiber from a multi-layer spun yarn comprising polylactic acid fiber as a core component A hollow spun yarn knitted fabric characterized by 前記複重層紡績糸が、前記ポリ乳酸系繊維を多芯的に配してなることを特徴とする請求項1記載の中空紡績糸織編物。   2. The hollow spun yarn knitted fabric according to claim 1, wherein the multi-layer spun yarn is formed by arranging the polylactic acid fibers in a multi-core manner. 前記複重層紡績糸が、鞘成分としてセルロース系繊維を配してなることを特徴とする請求項1又は2記載の中空紡績糸織編物。   The hollow spun yarn knitted or knitted fabric according to claim 1 or 2, wherein the multi-layer spun yarn comprises cellulose fibers as a sheath component. 前記複重層紡績糸が、鞘成分としてポリエステル短繊維を配してなることを特徴とする請求項1〜3のいずれかに記載の中空紡績糸織編物。   The hollow spun yarn knitted fabric according to any one of claims 1 to 3, wherein the multi-layer spun yarn includes polyester short fibers as a sheath component. 前記ポリエステル短繊維が中空繊維であることを特徴とする請求項4記載の中空紡績糸織編物。   The hollow spun yarn knitted fabric according to claim 4, wherein the polyester short fibers are hollow fibers. 前記複重層紡績糸が、鞘成分として外側部分にセルロース系繊維を配し、内側部分にポリエステル短繊維を配してなることを特徴とする請求項4又は5記載の中空紡績糸織編物。   The hollow spun yarn knitted or knitted fabric according to claim 4 or 5, wherein the multi-layer spun yarn is formed by disposing a cellulosic fiber in an outer portion as a sheath component and a polyester short fiber in an inner portion. 芯成分としてポリ乳酸系繊維を配してなる複重層紡績糸を用いて製織編した後、アルカリ処理することを特徴とする請求項1〜6のいずれかに記載の中空紡績糸織編物の製造方法。
The method for producing a hollow spun yarn knitted fabric according to any one of claims 1 to 6, wherein the yarn is woven and knitted using a multi-layer spun yarn having a polylactic acid fiber as a core component, and then subjected to alkali treatment. .
JP2005200428A 2005-07-08 2005-07-08 Knitted and woven fabric of hollow spun yarn and method for producing the same Pending JP2007016356A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005200428A JP2007016356A (en) 2005-07-08 2005-07-08 Knitted and woven fabric of hollow spun yarn and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005200428A JP2007016356A (en) 2005-07-08 2005-07-08 Knitted and woven fabric of hollow spun yarn and method for producing the same

Publications (1)

Publication Number Publication Date
JP2007016356A true JP2007016356A (en) 2007-01-25

Family

ID=37753760

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005200428A Pending JP2007016356A (en) 2005-07-08 2005-07-08 Knitted and woven fabric of hollow spun yarn and method for producing the same

Country Status (1)

Country Link
JP (1) JP2007016356A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112008001927T5 (en) 2007-07-31 2010-06-24 Stella Chemifa Corp. Method for producing a body with a hollow structure
JP2016069755A (en) * 2014-09-30 2016-05-09 ユニチカトレーディング株式会社 Composite multi-layered yarn and method for producing bulky woven or knitted fabric
EP3412809A1 (en) * 2017-06-06 2018-12-12 Welspun India Limited Hygro textile structures and related processes
EP3412811A1 (en) * 2017-06-06 2018-12-12 Welspun India Limited Hygro terry structures, articles, and related processes
WO2024043274A1 (en) * 2022-08-26 2024-02-29 ユニチカトレーディング株式会社 Two-layer-structure spun yarn and woven or knitted fabric

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07278982A (en) * 1994-04-06 1995-10-24 Unitika Ltd Combined spun yarn
JPH0931781A (en) * 1995-05-16 1997-02-04 Kuraray Co Ltd Hollow twisted yarn, its production and fabric
JPH0959839A (en) * 1995-06-12 1997-03-04 Kuraray Co Ltd Twisted yarn of multilayered structure and its production
JPH09302545A (en) * 1996-05-10 1997-11-25 Kuraray Co Ltd Spun yarn having multi-layered structure, hollow fiber obtained therefrom, production thereof and woven or knitted fabric
JP2722498B2 (en) * 1988-06-28 1998-03-04 東洋紡績株式会社 Heat retaining multilayer yarn
JPH10110341A (en) * 1996-10-03 1998-04-28 Unitika Ltd Production of deeply dyed woven or knitted fabric
JPH11302926A (en) * 1998-04-24 1999-11-02 Unitika Ltd Polyester-based conjugate fiber
JP2000054257A (en) * 1998-07-30 2000-02-22 Uesuke Senko Kk Production of spun textured hollow yarn and production of woven or knit fabric using the same
JP2002138336A (en) * 2000-10-30 2002-05-14 Gunze Ltd Two-layered structure twisted yarn which is partially dissolved off to form hollow and underwear using the same
JP2002173844A (en) * 2000-12-07 2002-06-21 Unitika Textiles Ltd Double-layer structural spun yarn having biodegradability
JP2002285442A (en) * 2001-03-28 2002-10-03 Maison:Kk Spun yarn having both of form-stability and hygroscopicity, and fiber structure using the same
JP2003082546A (en) * 2001-09-06 2003-03-19 Kanebo Ltd Spun yarn and textile structure using the same
JP2005068596A (en) * 2003-08-25 2005-03-17 Asahi Kasei Fibers Corp Spun yarn
JP2005344234A (en) * 2004-06-02 2005-12-15 Unitika Textiles Ltd Woven or knitted fabric with hollow double-structured spun yarn

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2722498B2 (en) * 1988-06-28 1998-03-04 東洋紡績株式会社 Heat retaining multilayer yarn
JPH07278982A (en) * 1994-04-06 1995-10-24 Unitika Ltd Combined spun yarn
JPH0931781A (en) * 1995-05-16 1997-02-04 Kuraray Co Ltd Hollow twisted yarn, its production and fabric
JPH0959839A (en) * 1995-06-12 1997-03-04 Kuraray Co Ltd Twisted yarn of multilayered structure and its production
JPH09302545A (en) * 1996-05-10 1997-11-25 Kuraray Co Ltd Spun yarn having multi-layered structure, hollow fiber obtained therefrom, production thereof and woven or knitted fabric
JPH10110341A (en) * 1996-10-03 1998-04-28 Unitika Ltd Production of deeply dyed woven or knitted fabric
JPH11302926A (en) * 1998-04-24 1999-11-02 Unitika Ltd Polyester-based conjugate fiber
JP2000054257A (en) * 1998-07-30 2000-02-22 Uesuke Senko Kk Production of spun textured hollow yarn and production of woven or knit fabric using the same
JP2002138336A (en) * 2000-10-30 2002-05-14 Gunze Ltd Two-layered structure twisted yarn which is partially dissolved off to form hollow and underwear using the same
JP2002173844A (en) * 2000-12-07 2002-06-21 Unitika Textiles Ltd Double-layer structural spun yarn having biodegradability
JP2002285442A (en) * 2001-03-28 2002-10-03 Maison:Kk Spun yarn having both of form-stability and hygroscopicity, and fiber structure using the same
JP2003082546A (en) * 2001-09-06 2003-03-19 Kanebo Ltd Spun yarn and textile structure using the same
JP2005068596A (en) * 2003-08-25 2005-03-17 Asahi Kasei Fibers Corp Spun yarn
JP2005344234A (en) * 2004-06-02 2005-12-15 Unitika Textiles Ltd Woven or knitted fabric with hollow double-structured spun yarn

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112008001927T5 (en) 2007-07-31 2010-06-24 Stella Chemifa Corp. Method for producing a body with a hollow structure
US8366980B2 (en) 2007-07-31 2013-02-05 Stella Chemifa Corporation Method for producing hollow structual body
US8668851B2 (en) 2007-07-31 2014-03-11 Stella Chemifa Corporation Method for producing hollow structural body
JP2016069755A (en) * 2014-09-30 2016-05-09 ユニチカトレーディング株式会社 Composite multi-layered yarn and method for producing bulky woven or knitted fabric
EP3412809A1 (en) * 2017-06-06 2018-12-12 Welspun India Limited Hygro textile structures and related processes
EP3412811A1 (en) * 2017-06-06 2018-12-12 Welspun India Limited Hygro terry structures, articles, and related processes
US20230066139A1 (en) * 2017-06-06 2023-03-02 Welspun India Limited Hygro Terry Structures, Articles, and Related Processes
WO2024043274A1 (en) * 2022-08-26 2024-02-29 ユニチカトレーディング株式会社 Two-layer-structure spun yarn and woven or knitted fabric

Similar Documents

Publication Publication Date Title
CN101429689B (en) Superfine fibre material and producing method thereof
Borbély Lyocell, the new generation of regenerated cellulose
EP3178980B1 (en) Fabric and method of manufacturing fabric
JP4916787B2 (en) Method for producing double layer yarn
JP2007016356A (en) Knitted and woven fabric of hollow spun yarn and method for producing the same
JP2010261127A (en) Composite spun yarn and fabric
CN101798726B (en) Non-woven fabric and preparation method thereof
JP4434544B2 (en) Method for producing fine spinning twisted yarn
US10968544B2 (en) Process for manufacturing air rich yarn and air rich fabric
CN107059205B (en) A kind of Yarn spinning method of the blended core-spun double-layer structure yarn of accumulation of heat heat generating fiber
CN101787581A (en) Ultrafine fiber based on recycled polyester and production method thereof
JPH09143836A (en) Fibrilated core-sheath composite spun yarn woven or knitted fabric
JP2007284846A (en) Polyester conjugate fiber
JPH0931781A (en) Hollow twisted yarn, its production and fabric
JP2005344234A (en) Woven or knitted fabric with hollow double-structured spun yarn
JP2008133584A (en) Polyester fiber-containing woven or knitted fabric and method for production thereof
JP2010057606A (en) Towel
JP5398972B2 (en) Cellulose ester-based composite yarn, method for producing the same, and woven / knitted fabric
JP3323165B2 (en) Biodegradable spun yarn with core-sheath structure and fabric comprising the same
JP2005029918A (en) Twisted union spun yarn, method for producing the same and woven or knitted fabric
JP4064188B2 (en) Biodegradable false twisted spun yarn and woven / knitted fabric
JP2009150008A (en) Long and short composite spun yarn and cloth
JP2009052175A (en) Method for producing extrafine spun yarn
JP4550242B2 (en) Filter media
JP2008190063A (en) Method for producing soft spun raw yarn having excellent feeling and textile product obtained from the same

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080519

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A712

Effective date: 20091102

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20100910

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100921

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20110426