JP2006518698A - 破断ラインを備えるガラス - Google Patents
破断ラインを備えるガラス Download PDFInfo
- Publication number
- JP2006518698A JP2006518698A JP2006502140A JP2006502140A JP2006518698A JP 2006518698 A JP2006518698 A JP 2006518698A JP 2006502140 A JP2006502140 A JP 2006502140A JP 2006502140 A JP2006502140 A JP 2006502140A JP 2006518698 A JP2006518698 A JP 2006518698A
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- Prior art keywords
- window
- glass
- weakened
- zone
- break
- Prior art date
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Links
- 239000011521 glass Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 claims abstract description 30
- 230000009471 action Effects 0.000 claims abstract description 8
- 238000013021 overheating Methods 0.000 claims abstract description 6
- 230000035515 penetration Effects 0.000 claims abstract description 6
- 230000005855 radiation Effects 0.000 claims description 18
- 230000000694 effects Effects 0.000 claims description 8
- 239000005340 laminated glass Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 230000007547 defect Effects 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- 230000000593 degrading effect Effects 0.000 claims 1
- 230000002349 favourable effect Effects 0.000 claims 1
- 230000005865 ionizing radiation Effects 0.000 claims 1
- 230000002093 peripheral effect Effects 0.000 claims 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 239000005357 flat glass Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000003313 weakening effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/352—Working by laser beam, e.g. welding, cutting or boring for surface treatment
- B23K26/356—Working by laser beam, e.g. welding, cutting or boring for surface treatment by shock processing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/02—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
- C03B33/0222—Scoring using a focussed radiation beam, e.g. laser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/352—Working by laser beam, e.g. welding, cutting or boring for surface treatment
- B23K26/359—Working by laser beam, e.g. welding, cutting or boring for surface treatment by providing a line or line pattern, e.g. a dotted break initiation line
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B33/00—Severing cooled glass
- C03B33/07—Cutting armoured, multi-layered, coated or laminated, glass products
- C03B33/076—Laminated glass comprising interlayers
- C03B33/078—Polymeric interlayers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/006—Vehicles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/50—Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
- B23K2103/54—Glass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/15—Sheet, web, or layer weakened to permit separation through thickness
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Joining Of Glass To Other Materials (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Surface Treatment Of Glass (AREA)
- Securing Of Glass Panes Or The Like (AREA)
- Laser Beam Processing (AREA)
- Window Of Vehicle (AREA)
Abstract
Description
Claims (17)
- 窓に意図的な破断ゾーンを作り出すための方法であり、ガラスの構造が、ガラスに浸透する高エネルギービームを用いる局所過熱にさらされ、沿って破断させるための窓(1)のための好ましい経路に沿って所定の経路(ライン3)に高エネルギービームを連続的に案内し、かつ前記所定の経路(ライン3)に沿っておよび窓(1)の表面に対して種々の深さでの両方にて高エネルギービームを連続的に集束させることによって、意図的な破断ゾーン(5)が作り出される方法であって、種々の浸透深さにおける連続的な集束が、ガラスの表面に対する法線に対して傾斜されおよび/または湾曲されたラインをたどり、破断に導く影響が作用する方向によって異なる窓(1)の破断動作を得るために、弱められた構造が窓に生起されることを特徴とする、方法。
- 弱められた構造が、円錐状またはくさび状に形成されることを特徴とする、請求項1に記載の方法。
- 意図的な破断ゾーン(5)が、少なくとも2つのラインに作り出され、一方のラインが他方のラインに対して向かい合って配置されており、且つライン間に窓(1)の表面のある領域を境界付けることを特徴とする、請求項1に記載の方法。
- 周囲の弱められたゾーン(3)が、意図的な破断ゾーン(5)によって全体に形成されることを特徴とする、請求項1または2に記載の方法。
- 意図的な破断ゾーン(5)が、経路(ライン3)に沿って、連続的にまたは断続的に配置されることを特徴とする、請求項1または2または3に記載の方法。
- 合わせガラスからなる窓ガラスに組み込まれた、または合わせガラスからなる窓ガラスに組み込まれるべき1つ以上の窓に、意図的な破断ゾーンが設けられることを特徴とする、請求項1から5のいずれか一項に記載の方法。
- 意図的な破断ゾーンを形成するマイクロクラックが、ガラスのいずれか一方または両方の表面を劣化させることなく、ガラスの塊内に生起されることを特徴とする、請求項1から6のいずれか一項に記載の方法。
- ガラスの少なくとも1つの表面に開口するマイクロクラックが、作り出されることを特徴とする、請求項1から5のいずれか一項に記載の方法。
- ガラスの意図的な破断ゾーンまたは弱められたゾーンが、視界から隠されることを特徴とする、請求項1から8のいずれか一項に記載の方法。
- 1064nmまたは532nmの波長を有するレーザが使用されることを特徴とする、請求項1から9のいずれか一項に記載の方法。
- 高エネルギー放射が、次の特性を有し、すなわち、(肉眼にて)視認し得る損傷を作り出すのに充分なほど高くはないが、ガラス内またはガラス上に初期損傷を作り出す、エネルギーまたは出力を有し、初期損傷が、高エネルギー放射に対するさらなる露出、または熱的、化学的、または機械的応力に対するさらなる露出のもとで、クラックに、またはガラス内における視認可能な損傷にも発展し得ることを特徴とする、請求項1から10のいずれか一項に記載の方法。
- 意図的な破断ゾーン、弱められたゾーン、または欠陥を生起するように、高エネルギーまたはイオン化タイプの放射に対して少なくとも部分的に透過する物質内または物質上への高エネルギーまたはイオン化放射が、処理されるべきエリアの局所環境の目標とされた物理的または化学的構成の結果として、収束された放射、誘導放出、または超放射を導き、且つそれゆえ処理されるべき領域内に増大される局所放射濃度に導くことを特徴とする、請求項1から11のいずれか一項に記載の方法。
- 少なくとも1つの弱められたゾーン(3)を有する窓(1)であって、該弱められたゾーン(3)が、もしも窓が過負荷であれば、所定の破断経路に沿った破断を促進し、破断が、高エネルギー放射を用いる、特に請求項1から12のいずれか一項の方法を用いる、マイクロクラックの生起によって作り出され、窓において、窓(1)の厚みを通る断面内であるとみなされる前記弱められたゾーン(3)が、ガラスの表面の法線に対して傾斜された経路および/または湾曲された経路を有する、窓。
- 弱められたゾーン(3)が、少なくとも2つのラインから形成され、該ラインが、ラインの間に窓の表面の領域の境界を定め、且つ特に窓の縁部まで続く、請求項13に記載の窓。
- 弱められたゾーン(3)が、外側縁部からいくらかの距離の周囲ラインを描き、結果として破断輪郭がおおむね円錐形状またはくさび形状である破断の破片を生じる、請求項13または14に記載の窓。
- 弱められたゾーン(3)が、好ましい破断反応を作り出す目的で、少なくとも一面に開口するマイクロクラック(5)を有する、請求項13から15のいずれか一項に記載の窓。
- 互いに向かい合って配置された弱められたゾーン(5)が、反対方向に向けられ、且つ最外側から達するボディへの衝撃が続く破断の際に、窓(1)が比較的柔軟となるように、窓(1)の凸状面から凹状面へ放射状に広がる、原動機付き乗り物における湾曲されたフロントガラスとしての請求項13から16のいずれか一項に記載の窓の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10305733A DE10305733B4 (de) | 2003-02-12 | 2003-02-12 | Verfahren zum Erzeugen von Sollbruchstellen in Glasscheiben, Glasscheibe mit Schwächungszone und Verwendung derselben |
DE10305733.1 | 2003-02-12 | ||
PCT/FR2004/000304 WO2004074193A2 (fr) | 2003-02-12 | 2004-02-11 | Vitrage comprenant des lignes de rupture |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006518698A true JP2006518698A (ja) | 2006-08-17 |
JP4786526B2 JP4786526B2 (ja) | 2011-10-05 |
Family
ID=32797352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006502140A Expired - Fee Related JP4786526B2 (ja) | 2003-02-12 | 2004-02-11 | 破断ラインを備えるガラス |
Country Status (9)
Country | Link |
---|---|
US (1) | US7508406B2 (ja) |
EP (1) | EP1613561B1 (ja) |
JP (1) | JP4786526B2 (ja) |
KR (1) | KR101122651B1 (ja) |
CN (1) | CN100471808C (ja) |
AT (1) | ATE348082T1 (ja) |
DE (2) | DE10305733B4 (ja) |
ES (1) | ES2278302T3 (ja) |
WO (1) | WO2004074193A2 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013534509A (ja) * | 2010-06-29 | 2013-09-05 | ヴェトロテック サン−ゴバン(インターナチオナル)アクチエンゲゼルシャフト | 防火合わせガラス |
WO2024181075A1 (ja) * | 2023-03-02 | 2024-09-06 | Agc株式会社 | 自動車窓用合わせガラス及び自動車 |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8327666B2 (en) * | 2009-02-19 | 2012-12-11 | Corning Incorporated | Method of separating strengthened glass |
WO2011025908A1 (en) | 2009-08-28 | 2011-03-03 | Corning Incorporated | Methods for laser cutting articles from chemically strengthened glass substrates |
US8322771B2 (en) * | 2009-10-05 | 2012-12-04 | Honda Motor Co., Ltd. | Connection between roof panel and side panel |
CN102284936A (zh) * | 2011-06-01 | 2011-12-21 | 王顺桥 | 有弱点的车窗玻璃与穿撬玻璃工具的制作使用方法 |
US10035331B2 (en) | 2011-06-24 | 2018-07-31 | Corning Incorporated | Light-weight hybrid glass laminates |
US9616641B2 (en) | 2011-06-24 | 2017-04-11 | Corning Incorporated | Light-weight hybrid glass laminates |
DE102011080426A1 (de) * | 2011-08-04 | 2013-02-07 | Bayerische Motoren Werke Aktiengesellschaft | Kraftfahrzeugscheibe |
EP2581243B1 (en) * | 2011-10-12 | 2019-10-09 | Volvo Car Corporation | Controlled collapse of car windshield |
WO2013181505A1 (en) * | 2012-06-01 | 2013-12-05 | Corning Incorporated | Glass laminate construction for optimized breakage performance |
US9387651B2 (en) | 2012-09-26 | 2016-07-12 | Corning Incorporated | Methods for producing ion exchanged glass and resulting apparatus |
CN105705467B (zh) | 2013-08-26 | 2019-09-27 | 康宁股份有限公司 | 用于化学强化的玻璃的局部退火的方法 |
US9154138B2 (en) | 2013-10-11 | 2015-10-06 | Palo Alto Research Center Incorporated | Stressed substrates for transient electronic systems |
US9780044B2 (en) | 2015-04-23 | 2017-10-03 | Palo Alto Research Center Incorporated | Transient electronic device with ion-exchanged glass treated interposer |
US10012250B2 (en) * | 2016-04-06 | 2018-07-03 | Palo Alto Research Center Incorporated | Stress-engineered frangible structures |
US9993999B2 (en) | 2016-07-22 | 2018-06-12 | Ford Global Technologies, Llc | Laminated windshield with defined break path |
US10026579B2 (en) | 2016-07-26 | 2018-07-17 | Palo Alto Research Center Incorporated | Self-limiting electrical triggering for initiating fracture of frangible glass |
US10224297B2 (en) | 2016-07-26 | 2019-03-05 | Palo Alto Research Center Incorporated | Sensor and heater for stimulus-initiated fracture of a substrate |
US10903173B2 (en) | 2016-10-20 | 2021-01-26 | Palo Alto Research Center Incorporated | Pre-conditioned substrate |
US11021126B1 (en) * | 2017-06-30 | 2021-06-01 | Apple Inc. | Windshield area intrusion control |
DE102017124579A1 (de) * | 2017-10-20 | 2019-04-25 | Dalphi Metal Espana, S.A. | Fahrzeuginsassen-rückhaltesystem mit einem gassack |
US10626048B2 (en) | 2017-12-18 | 2020-04-21 | Palo Alto Research Center Incorporated | Dissolvable sealant for masking glass in high temperature ion exchange baths |
DE102018107143A1 (de) * | 2018-03-26 | 2019-09-26 | Volkswagen Ag | Fahrzeugfenster und Verfahren zu dessen Herstellung |
US10717669B2 (en) | 2018-05-16 | 2020-07-21 | Palo Alto Research Center Incorporated | Apparatus and method for creating crack initiation sites in a self-fracturing frangible member |
US11107645B2 (en) | 2018-11-29 | 2021-08-31 | Palo Alto Research Center Incorporated | Functionality change based on stress-engineered components |
US10947150B2 (en) | 2018-12-03 | 2021-03-16 | Palo Alto Research Center Incorporated | Decoy security based on stress-engineered substrates |
US10969205B2 (en) | 2019-05-03 | 2021-04-06 | Palo Alto Research Center Incorporated | Electrically-activated pressure vessels for fracturing frangible structures |
DE102019217611A1 (de) * | 2019-11-14 | 2021-05-20 | Volkswagen Aktiengesellschaft | Verfahren und Vorrichtung zur Herstellung einer Glasscheibe, Glasscheibe |
GB202009887D0 (en) | 2020-06-29 | 2020-08-12 | Pilkington Group Ltd | Laminated glazing |
GB202009886D0 (en) | 2020-06-29 | 2020-08-12 | Pilkington Group Ltd | Laminated glazing |
US12013043B2 (en) | 2020-12-21 | 2024-06-18 | Xerox Corporation | Triggerable mechanisms and fragment containment arrangements for self-destructing frangible structures and sealed vessels |
US11904986B2 (en) | 2020-12-21 | 2024-02-20 | Xerox Corporation | Mechanical triggers and triggering methods for self-destructing frangible structures and sealed vessels |
GB202100636D0 (en) * | 2021-01-18 | 2021-03-03 | Pilkington Group Ltd | Glazing |
GB202113179D0 (en) * | 2021-09-15 | 2021-10-27 | Pilkington Group Ltd | Laminated glazing |
DE202021106914U1 (de) | 2021-12-20 | 2022-01-05 | Saint-Gobain SEKURIT Deutschland GmbH | Windschutzscheibe mit verbessertem Aufprallschutz |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2005535545A (ja) * | 2002-06-10 | 2005-11-24 | サン−ゴバン グラス フランス | 脆くされた領域を有する合せガラス |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6392683B1 (en) | 1997-09-26 | 2002-05-21 | Sumitomo Heavy Industries, Ltd. | Method for making marks in a transparent material by using a laser |
DE19957317C2 (de) * | 1999-11-29 | 2002-01-31 | Vitro Laser Gmbh | Verfahren zur Anbringung von Sollbruchkanten an einem Werkstück |
-
2003
- 2003-02-12 DE DE10305733A patent/DE10305733B4/de not_active Withdrawn - After Issue
-
2004
- 2004-02-11 EP EP04710055A patent/EP1613561B1/fr not_active Expired - Lifetime
- 2004-02-11 DE DE602004003688T patent/DE602004003688T2/de not_active Expired - Lifetime
- 2004-02-11 AT AT04710055T patent/ATE348082T1/de not_active IP Right Cessation
- 2004-02-11 WO PCT/FR2004/000304 patent/WO2004074193A2/fr active IP Right Grant
- 2004-02-11 ES ES04710055T patent/ES2278302T3/es not_active Expired - Lifetime
- 2004-02-11 US US10/544,481 patent/US7508406B2/en not_active Expired - Fee Related
- 2004-02-11 CN CN200480003964.6A patent/CN100471808C/zh not_active Expired - Fee Related
- 2004-02-11 JP JP2006502140A patent/JP4786526B2/ja not_active Expired - Fee Related
- 2004-02-11 KR KR1020057014811A patent/KR101122651B1/ko active IP Right Grant
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005535545A (ja) * | 2002-06-10 | 2005-11-24 | サン−ゴバン グラス フランス | 脆くされた領域を有する合せガラス |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013534509A (ja) * | 2010-06-29 | 2013-09-05 | ヴェトロテック サン−ゴバン(インターナチオナル)アクチエンゲゼルシャフト | 防火合わせガラス |
WO2024181075A1 (ja) * | 2023-03-02 | 2024-09-06 | Agc株式会社 | 自動車窓用合わせガラス及び自動車 |
Also Published As
Publication number | Publication date |
---|---|
ATE348082T1 (de) | 2007-01-15 |
WO2004074193A8 (fr) | 2005-09-15 |
KR20050100674A (ko) | 2005-10-19 |
JP4786526B2 (ja) | 2011-10-05 |
EP1613561B1 (fr) | 2006-12-13 |
DE10305733A1 (de) | 2004-09-02 |
DE602004003688T2 (de) | 2007-10-25 |
KR101122651B1 (ko) | 2012-03-09 |
CN100471808C (zh) | 2009-03-25 |
DE10305733B4 (de) | 2005-10-20 |
US20060138798A1 (en) | 2006-06-29 |
WO2004074193A3 (fr) | 2004-09-30 |
DE602004003688D1 (de) | 2007-01-25 |
US7508406B2 (en) | 2009-03-24 |
EP1613561A2 (fr) | 2006-01-11 |
ES2278302T3 (es) | 2007-08-01 |
WO2004074193A2 (fr) | 2004-09-02 |
CN1798706A (zh) | 2006-07-05 |
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