JP2006506791A - 有機デバイス構造体およびその製造方法 - Google Patents
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- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 4
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- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 5
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- 230000008021 deposition Effects 0.000 description 4
- UEEXRMUCXBPYOV-UHFFFAOYSA-N iridium;2-phenylpyridine Chemical compound [Ir].C1=CC=CC=C1C1=CC=CC=N1.C1=CC=CC=C1C1=CC=CC=N1.C1=CC=CC=C1C1=CC=CC=N1 UEEXRMUCXBPYOV-UHFFFAOYSA-N 0.000 description 4
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- SCZWJXTUYYSKGF-UHFFFAOYSA-N 5,12-dimethylquinolino[2,3-b]acridine-7,14-dione Chemical compound CN1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3N(C)C1=C2 SCZWJXTUYYSKGF-UHFFFAOYSA-N 0.000 description 3
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- DHDHJYNTEFLIHY-UHFFFAOYSA-N 4,7-diphenyl-1,10-phenanthroline Chemical compound C1=CC=CC=C1C1=CC=NC2=C1C=CC1=C(C=3C=CC=CC=3)C=CN=C21 DHDHJYNTEFLIHY-UHFFFAOYSA-N 0.000 description 2
- DIVZFUBWFAOMCW-UHFFFAOYSA-N 4-n-(3-methylphenyl)-1-n,1-n-bis[4-(n-(3-methylphenyl)anilino)phenyl]-4-n-phenylbenzene-1,4-diamine Chemical compound CC1=CC=CC(N(C=2C=CC=CC=2)C=2C=CC(=CC=2)N(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=C(C)C=CC=2)C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C=C(C)C=CC=2)=C1 DIVZFUBWFAOMCW-UHFFFAOYSA-N 0.000 description 2
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- 125000004429 atom Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 2
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- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 2
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- STTGYIUESPWXOW-UHFFFAOYSA-N 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline Chemical compound C=12C=CC3=C(C=4C=CC=CC=4)C=C(C)N=C3C2=NC(C)=CC=1C1=CC=CC=C1 STTGYIUESPWXOW-UHFFFAOYSA-N 0.000 description 1
- IXHWGNYCZPISET-UHFFFAOYSA-N 2-[4-(dicyanomethylidene)-2,3,5,6-tetrafluorocyclohexa-2,5-dien-1-ylidene]propanedinitrile Chemical compound FC1=C(F)C(=C(C#N)C#N)C(F)=C(F)C1=C(C#N)C#N IXHWGNYCZPISET-UHFFFAOYSA-N 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-M 4-phenylphenolate Chemical compound C1=CC([O-])=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-M 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
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- 125000003118 aryl group Chemical group 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- UFVXQDWNSAGPHN-UHFFFAOYSA-K bis[(2-methylquinolin-8-yl)oxy]-(4-phenylphenoxy)alumane Chemical compound [Al+3].C1=CC=C([O-])C2=NC(C)=CC=C21.C1=CC=C([O-])C2=NC(C)=CC=C21.C1=CC([O-])=CC=C1C1=CC=CC=C1 UFVXQDWNSAGPHN-UHFFFAOYSA-K 0.000 description 1
- KYPOHTVBFVELTG-UHFFFAOYSA-N but-2-enedinitrile Chemical group N#CC=CC#N KYPOHTVBFVELTG-UHFFFAOYSA-N 0.000 description 1
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- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- MILUBEOXRNEUHS-UHFFFAOYSA-N iridium(3+) Chemical compound [Ir+3] MILUBEOXRNEUHS-UHFFFAOYSA-N 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- IBHBKWKFFTZAHE-UHFFFAOYSA-N n-[4-[4-(n-naphthalen-1-ylanilino)phenyl]phenyl]-n-phenylnaphthalen-1-amine Chemical compound C1=CC=CC=C1N(C=1C2=CC=CC=C2C=CC=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C3=CC=CC=C3C=CC=2)C=C1 IBHBKWKFFTZAHE-UHFFFAOYSA-N 0.000 description 1
- 238000013086 organic photovoltaic Methods 0.000 description 1
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- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
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- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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- H10K85/324—Metal complexes comprising a group IIIA element, e.g. Tris (8-hydroxyquinoline) gallium [Gaq3] comprising aluminium, e.g. Alq3
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Abstract
Description
本明細書で用いる略語は以下の材料を意味する。
CBP: 4,4'-N,N-ジカルバゾール-ビフェニル
m-MTDATA: 4,4',4"-トリス(3-メチルフェニルフェニルアミノ)トリフェニルアミン
Alq3: 8-トリス-ヒドロキシキノリンアルミニウム
Bphen: 4,7-ジフェニル-l,l0-フェナントロリン
n-BPhen: n-ドープBPhen (リチウムをドーピング)
F4-TCNQ: テトラフルオロ-テトラシアノ-キノジメタン
p-MTDATA: p-ドープm-MTDATA (F4-TCNQをドーピング)
Ir(ppy)3: トリス(2-フェニルピリジン)-イリジウム
Ir(ppz)3: トリス(1-フェニルピラゾロト,N,C(2')イリジウム(III)
BCP: 2,9-ジメチル-4,7-ジフェニル-1,10-フェナントロリン
TAZ: 3-フェニル-4-(1'-ナフチル)-5-フェニル-1,2,4-トリアゾール
CuPc: 銅フタロシアニン
ITO: インジウムスズ酸化物
NPD: ナフチル-フェニル-ジアミン
TPD: N,N=-ビス(3-メチルフェニル)-N,N =-ビス-(フェニル)-ベンジジン
BAlq: アルミニウム(III)ビス(2-メチル-8-キノリナト)4-フェニルフェノラート
mCP: 1,3-N,N-ジカルバゾール-ベンゼン
DCM: 4-(ジシアノエチレン)-6-(4-ジメチルアミノスチリル-2-メチル)-4H-ピラン
DMQA: N,N'-ジメチルキナクリドン
PEDOT:PSS : ポリ(3,4-エチレンジオキシチオフェン)とポリスチレンスルホネート(PSS)の水性分散液
110, 210, 310 基板
120 正孔注入層
125, 225, 330 正孔輸送層
130 電子阻止層
135, 220, 360 発光層
Claims (21)
- 下部電極と、
前記下部電極の上に配置されており、第1の光スペクトルを発光することができる第1の領域を含むパターン化された第1の有機層と、
前記下部電極の上に配置されており、第2の光スペクトルを発光することができ、前記第1の有機層の上にこれと物理的に接触して配置された第2の有機層と、
前記第2の有機層の上に配置された上部電極とを含む有機発光デバイス。 - 前記パターン化された第1の有機層が、第3の光スペクトルを発光することができる第2の領域をさらに含む請求項1に記載の有機発光デバイス。
- 前記第1、第2、および第3の光スペクトルが、それぞれ異なるものである請求項2に記載の有機発光デバイス。
- 前記第1の光スペクトルが、赤色である請求項2に記載の有機発光デバイス。
- 前記第2の光スペクトルが、青色である請求項2に記載の有機発光デバイス。
- 前記第3の光スペクトルが、緑色である請求項2に記載の有機発光デバイス。
- 前記第1の有機層が、溶液処理で堆積されたものである請求項1に記載の有機発光デバイス。
- 前記溶液処理が、インクジェットによるものである請求項7に記載の有機発光デバイス。
- 前記第2の有機層が、熱気相堆積で堆積されたものである請求項1に記載の有機発光デバイス。
- 前記上部電極が、インジウムスズ酸化物を含む請求項1に記載の有機発光デバイス。
- 前記上部電極および下部電極が、前記有機層に電気的に接続されている請求項1に記載の有機発光デバイス。
- 前記第1の有機層が正孔輸送層であり、前記第2の有機層が発光層である請求項1に記載の有機発光デバイス。
- 前記第2の有機層が、発光材料の純物質層を含む発光層である請求項1に記載の有機発光デバイス。
- 前記下部電極と前記第1の有機層の間に配置された第3の有機層をさらに含む請求項1に記載の有機発光デバイス。
- 前記第3の有機層が正孔輸送層であり、前記第1の有機層が発光層である請求項14に記載の有機発光デバイス。
- 前記第3の有機層が正孔注入層であり、前記第1の有機層が発光層である請求項14に記載の有機発光デバイス。
- 前記第3の有機層が電子阻止層であり、前記第1の有機層が発光層である請求項14に記載の有機発光デバイス。
- 前記下部電極と前記第3の有機層の間に配置された第4の有機層をさらに含む請求項14に記載の有機発光デバイス。
- 前記第4の有機層が正孔輸送層であり、前記第3の有機層が電子阻止層である請求項18に記載の有機発光デバイス。
- 下部電極を基板の上に堆積させる工程と、
第1の光スペクトルを発光することができるパターン化された第1の有機層を、前記下部電極の上に堆積させる工程と、
前記下部電極の上に配置されて、第2の光スペクトルを発光することができる第2の有機層を、前記第1の有機層の上にこれと物理的に接触させて堆積させる工程と、
上部電極を前記第2の有機層の上に堆積させる工程とを含む有機発光デバイスの製造方法。 - 下部電極を基板の上に堆積させる工程と、
第1の領域が第1の光スペクトルを発光することができ、第2の領域が第3の光スペクトルを発光することができる2つの領域を含むパターン化された第1の有機層を、前記下部電極の上に堆積させる工程と、
第2の光スペクトルを発光することができる第2の有機層を、前記第1の有機層および前記下部電極の上に堆積させる工程と、
上部電極を前記第2の有機層の上に堆積させる工程とを含む有機発光デバイスの製造方法。
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US10/295,322 | 2002-11-15 | ||
US10/295,322 US6891326B2 (en) | 2002-11-15 | 2002-11-15 | Structure and method of fabricating organic devices |
PCT/US2003/036170 WO2004047196A2 (en) | 2002-11-15 | 2003-11-12 | Structure and method of fabricating organic devices |
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JP2006506791A true JP2006506791A (ja) | 2006-02-23 |
JP4896402B2 JP4896402B2 (ja) | 2012-03-14 |
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US (1) | US6891326B2 (ja) |
EP (1) | EP1561250A2 (ja) |
JP (1) | JP4896402B2 (ja) |
KR (1) | KR101166924B1 (ja) |
CN (2) | CN1711653A (ja) |
AU (1) | AU2003299558A1 (ja) |
WO (1) | WO2004047196A2 (ja) |
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EP1561250A2 (en) | 2005-08-10 |
WO2004047196A3 (en) | 2004-12-29 |
US6891326B2 (en) | 2005-05-10 |
JP4896402B2 (ja) | 2012-03-14 |
CN1711653A (zh) | 2005-12-21 |
KR101166924B1 (ko) | 2012-07-19 |
CN103474577A (zh) | 2013-12-25 |
AU2003299558A1 (en) | 2004-06-15 |
KR20050074591A (ko) | 2005-07-18 |
WO2004047196A2 (en) | 2004-06-03 |
US20040095064A1 (en) | 2004-05-20 |
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