JP2006335975A - Insulation coating, electronic part by using the same and method for producing the electronic part - Google Patents

Insulation coating, electronic part by using the same and method for producing the electronic part Download PDF

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JP2006335975A
JP2006335975A JP2005165421A JP2005165421A JP2006335975A JP 2006335975 A JP2006335975 A JP 2006335975A JP 2005165421 A JP2005165421 A JP 2005165421A JP 2005165421 A JP2005165421 A JP 2005165421A JP 2006335975 A JP2006335975 A JP 2006335975A
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parts
weight
insulating paint
insulation coating
electronic component
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Satoshi Shiga
智 志賀
Katsuhiko Yasu
克彦 安
Takuya Sugishita
拓也 杉下
Masahiro Kimura
昌宏 木村
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Showa Denko Materials Co Ltd
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Hitachi Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an insulation coating having heat resistance and a good working property, and capable of performing the concealment of printed characters without using an azo-based coloring agent, also electronic parts by using the insulation coating and further the method for producing the electronic parts by using the insulation coating. <P>SOLUTION: This insulation coating contains (a) 10-40 pts.wt. A-B-A type styrene block copolymer, (b) 1-20 pts.wt. tackiness-imparting resin, (c) 50-90 pts.wt. solvent and (d) an azine-based coloring agent. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、アジン系着色剤を含有する絶縁塗料、及び、この絶縁塗料を塗布した電子部品、更に、この絶縁塗料を用いた電子部品の製造方法に関する。   The present invention relates to an insulating paint containing an azine-based colorant, an electronic component coated with the insulating paint, and a method for manufacturing an electronic component using the insulating paint.

電気機器は、年々小型軽量化及び多機能化の傾向にあり、これを制御する各種電気機器に搭載した実装回路板は、湿気、塵埃、ガス等から保護する目的で絶縁処理が行われる。この絶縁処理方法としては、アクリル系樹脂、シリコーン系樹脂等の塗料を塗布する保護コーティング処理が広く採用されている。そして、このような実装回路板は、過酷な環境下、特に高湿度下で使用されることがあり、例えば洗濯機、自動車、フラットパネルディスプレイ等の機器に搭載されて使用されている。
特開2004−99761号公報
Electrical devices tend to be smaller and lighter and more multifunctional year by year, and a mounting circuit board mounted on various electrical devices that control the electrical devices is subjected to insulation treatment for the purpose of protecting it from moisture, dust, gas, and the like. As this insulating treatment method, a protective coating treatment in which a paint such as an acrylic resin or a silicone resin is applied is widely employed. Such a mounted circuit board may be used under harsh environments, particularly under high humidity. For example, the mounted circuit board is mounted and used in devices such as washing machines, automobiles, and flat panel displays.
JP 2004-99761 A

しかしながら、背景技術にて述べたアクリル系樹脂の塗料は、耐熱性が80〜100℃という低温であり、加熱劣化後には可撓性が失われ、耐熱性が要求される電子部品での使用ができず、その用途が限定される。一方、シリコーン系樹脂の塗料は、耐熱性に優れ、加熱劣化後の可とう性が良いものの、材料価格が高く、塗料に皮張り、ゲル化等が発生し作業性に問題があった。   However, the acrylic resin paint described in the background art has a heat resistance of a low temperature of 80 to 100 ° C. and loses flexibility after heat deterioration, so that it can be used in an electronic component that requires heat resistance. It is not possible and its application is limited. On the other hand, the silicone resin paint has excellent heat resistance and good flexibility after heat deterioration, but the material price is high, and the paint has a problem of workability due to skinning and gelation.

また、実装回路板に絶縁塗料を塗布した場合、実装回路板に搭載される電子部品の部品番号等が印字隠ぺいされない問題があるが、特許文献1に開示されるアゾ系着色剤を用いることにより、隠蔽問題を解決することが出来た。但し、近年では、環境問題によりアゾ化合物の使用が問題視されている。   In addition, when insulating paint is applied to the mounting circuit board, there is a problem that the part number of the electronic component mounted on the mounting circuit board is not concealed by printing, but by using the azo colorant disclosed in Patent Document 1 We were able to solve the concealment problem. However, in recent years, the use of azo compounds has been regarded as a problem due to environmental problems.

本発明は、耐熱性を有し、作業性が良好で、アゾ系着色剤を用いることなく印字隠蔽を行える絶縁塗料、またこの絶縁塗料を用いた電子部品、更に、この絶縁塗料を用いた電子部品の製造方法を提供することを目的とする。   The present invention is an insulating paint having heat resistance, good workability, and capable of concealing printing without using an azo colorant, an electronic component using the insulating paint, and an electronic device using the insulating paint. It aims at providing the manufacturing method of components.

(1)本発明は、(a)A−B−A型スチレンブロック共重合体ゴム10〜40重量部、(b)粘着性付与樹脂1〜20重量部、(c)溶剤50〜90重量部、(d)アジン系着色剤を含有してなる絶縁塗料である。
(2)項(1)において、(d)アジン系着色剤の含有量が、絶縁塗料100重量部に対し0.01〜70重量部である絶縁塗料である。
(3)項(1)又は(2)において、さらに充填剤、改質剤、消泡剤および接着性付与剤からなる添加剤から選ばれる少なくとも1種を含む絶縁塗料である。
(4)項(1)乃至(3)の何れかの絶縁塗料を塗布した電子部品である。
(5)項(1)乃至(3)の何れかの絶縁塗料を電子部品に塗布し、その後乾燥させる電子部品の製造方法である。
(1) The present invention comprises (a) ABA type styrene block copolymer rubber 10-40 parts by weight, (b) tackifying resin 1-20 parts by weight, (c) solvent 50-90 parts by weight (D) An insulating paint comprising an azine colorant.
(2) In the item (1), the content of the (d) azine colorant is 0.01 to 70 parts by weight with respect to 100 parts by weight of the insulating paint.
(3) The insulating paint further comprising at least one selected from additives consisting of a filler, a modifier, an antifoaming agent, and an adhesiveness imparting agent in the item (1) or (2).
(4) An electronic component to which the insulating paint according to any one of (1) to (3) is applied.
(5) A method of manufacturing an electronic component in which the insulating paint according to any one of (1) to (3) is applied to the electronic component and then dried.

本発明の絶縁塗料は、アゾ系の着色剤を使用せず隠避性に優れ電子部品の品番等を隠ぺいすることができる。   The insulating paint of the present invention is excellent in concealment without using an azo colorant and can conceal the part number of the electronic component.

本発明にて述べる(a)A−B−A型スチレンブロック共重合体ゴムは、スチレン−ブタジエン−スチレンブロック共重合体ゴム(SBS)、スチレン−イソプレン−スチレンブロック共重合体ゴム(SIS)、スチレン−ビニル・イソプレン−スチレンブロック共重合体ゴム(SVIS)、スチレン−エチレン/ブチレン−スチレンブロック共重合体ゴム(SEBS)、スチレン−エチレン/プロピレン−スチレンブロック共重合体ゴム(SEPS)等を用いることができる。   The (A) ABA type styrene block copolymer rubber described in the present invention is a styrene-butadiene-styrene block copolymer rubber (SBS), a styrene-isoprene-styrene block copolymer rubber (SIS), Styrene-vinyl / isoprene-styrene block copolymer rubber (SVIS), styrene-ethylene / butylene-styrene block copolymer rubber (SEBS), styrene-ethylene / propylene-styrene block copolymer rubber (SEPS), etc. are used. be able to.

また、これらのA−B−A型スチレンブロック共重合体ゴムは、その二重結合の一部若しくは全部を水素化していても良い。これらのA−B−A型スチレンブロック共重合体ゴムの配合量は10〜40重量部であり、15〜30重量部が好ましく、20〜25重量部がより好ましい。A−B−A型スチレンブロック共重合体ゴムの配合量は、10重量部より少ないと組成物の防湿効果が徐々薄れ、40重量部より多いとガラスやプリント基板等の基材との接着性が徐々に低くなる。   In addition, these ABA type styrene block copolymer rubbers may be partially or fully hydrogenated. The compounding amount of these ABA type styrene block copolymer rubbers is 10 to 40 parts by weight, preferably 15 to 30 parts by weight, and more preferably 20 to 25 parts by weight. When the blending amount of the ABA type styrene block copolymer rubber is less than 10 parts by weight, the moisture-proof effect of the composition gradually fades. When the blending amount is more than 40 parts by weight, the adhesiveness to a substrate such as glass or a printed board is increased. Gradually decreases.

本発明にて述べる(b)粘着性付与樹脂は、基材に対する接着性を向上させるものであり、石油系樹脂、ロジン系樹脂、及び、テルペン系樹脂、或いはそれらの混合物等を用いることができ、溶剤に溶解しやすいものが好ましい。   The (b) tackifying resin described in the present invention improves the adhesion to the substrate, and petroleum-based resins, rosin-based resins, terpene-based resins, or mixtures thereof can be used. Those that are easily dissolved in a solvent are preferred.

石油系樹脂としては、脂肪族系石油樹脂、芳香族系石油樹脂、脂環式系石油樹脂、脂肪族/芳香族共重合系石油樹脂及びそれらの水添石油樹脂等を用いることができる。ロジン系樹脂としては、ロジン、ロジン変性樹脂及びその誘導体等を用いることができる。テルペン系樹脂としては、ポリテルペン、テルペンフェノール系樹脂等及びそれらの水添樹脂等を用いることができる。   Examples of the petroleum resin include aliphatic petroleum resins, aromatic petroleum resins, alicyclic petroleum resins, aliphatic / aromatic copolymer petroleum resins, and hydrogenated petroleum resins thereof. Examples of rosin resins that can be used include rosin, rosin-modified resins and derivatives thereof. As the terpene resin, polyterpene, terpene phenol resin and the like, hydrogenated resins thereof and the like can be used.

これら粘着性付与樹脂の配合量は、1〜20重量部であり、2〜15重量部が好ましく、3〜13重量部がより好ましい。粘着付与樹脂の配合量は、1重量部より少ないとガラスやプリント基板等の基材との接着性が徐々に低下し、20重量部より多いと組成物の防湿効果が徐々に薄れる。   The compounding amount of these tackifying resins is 1 to 20 parts by weight, preferably 2 to 15 parts by weight, and more preferably 3 to 13 parts by weight. If the blending amount of the tackifying resin is less than 1 part by weight, the adhesiveness with a base material such as glass or a printed circuit board gradually decreases, and if it exceeds 20 parts by weight, the moisture-proof effect of the composition gradually decreases.

本発明にて述べる(c)溶剤は、アセトン、メチルエチルケトン等のケトン系溶剤、トルエン、キシレン等の芳香族系溶剤、シクロヘキサン、メチルシクロヘキサン、エチルシクロヘキサン等の脂肪族系溶剤、酢酸ブチル、酢酸イソプロピル等のエステル系溶剤、エタノール、ブタノール等のアルコール系溶剤、パラフィン油、ナフテン油等のパラフィン系溶剤、ミネラルターペン、ナフサ等の石油系溶剤等を用いることができる。溶剤の配合は、作業性に関連する塗料の粘度に応じて決められるが、50〜90重量部、好ましくは60〜80重量部の割合である。   (C) Solvents described in the present invention include ketone solvents such as acetone and methyl ethyl ketone, aromatic solvents such as toluene and xylene, aliphatic solvents such as cyclohexane, methylcyclohexane, and ethylcyclohexane, butyl acetate, isopropyl acetate, and the like. Ester solvents, alcohol solvents such as ethanol and butanol, paraffin solvents such as paraffin oil and naphthenic oil, petroleum solvents such as mineral terpenes and naphtha, and the like can be used. The blending of the solvent is determined in accordance with the viscosity of the paint relating to workability, but is 50 to 90 parts by weight, preferably 60 to 80 parts by weight.

本発明にて述べる(d)アジン系着色剤は、C.I. Solvent Black 5、C.I. Solvent Black 7等が好適に用いられる。これらは、2種以上組み合わせて使用しても良い。また、公知の無機顔料、有機系顔料、及び有機系染料等と組み合わせて使用しても良い。市販品としては、OIL BLACK No.5、OIL OPLAS BLACK BS(オリエント化学工業(株)製商品名)などが挙げられる。   The (d) azine colorant described in the present invention is C.I. I. Solvent Black 5, C.I. I. Solvent Black 7 or the like is preferably used. You may use these in combination of 2 or more types. Further, it may be used in combination with known inorganic pigments, organic pigments, organic dyes and the like. As a commercial item, OIL BLACK No. 5, OIL OPLAS BLACK BS (trade name, manufactured by Orient Chemical Industry Co., Ltd.) and the like.

アジン系着色剤の添加量は、塗料100重量部に対し、0.01〜70重量部であり、0.1〜60重量部が好ましく、0.1〜50重量部がより好ましい。   The addition amount of the azine colorant is 0.01 to 70 parts by weight, preferably 0.1 to 60 parts by weight, and more preferably 0.1 to 50 parts by weight with respect to 100 parts by weight of the paint.

本発明にて述べる絶縁塗料には、必要に応じ充填剤、改質剤、消泡剤、及び接着性付与剤などを塗料に任意に添加することができる。   In the insulating paint described in the present invention, a filler, a modifier, an antifoaming agent, an adhesion-imparting agent, and the like can be optionally added to the paint as necessary.

充填剤としては、微粉末酸化けい素、酸化マグネシウム、水酸化アルミニウム、炭酸カルシウム等を用いることができる。   As the filler, fine powder silicon oxide, magnesium oxide, aluminum hydroxide, calcium carbonate, or the like can be used.

改質剤としては、乾燥性を向上させるためにナフテン酸マンガン、オクテン酸マンガン等の有機酸金属塩等を用いることができる。   As the modifier, organic acid metal salts such as manganese naphthenate and manganese octenoate can be used to improve the drying property.

シランカップリング剤としては、3−メタクリロキシプロピルメチルジメトキシシラン、3−メタクリロキシプロピルトリメトキシシラン、3−メタクリロキシプロピルメチルジエトキシシラン、3−メタクリロキシプロピルトリエトキシシラン等のメタクリロキシ系シランカップリング剤、3−アクリロキシプロピルトリメトキシシラン等のアクリロキシ系シランカップリング剤、3−メルカプトプロピルメチルジメトキシシラン、3−メルカプトプロピルトリメトキシシラン等のメルカプト系シランカップリング剤およびN−2(アミノエチル)3−アミノプロピルメチルジメトキシシラン、N−2(アミノエチル)3−アミノプロピルトリメトキシシラン、N−2(アミノエチル)3−アミノプロピルトリエトキシシラン、3−アミノプロピルトリメトキシシラン、3−アミノプロピルトリエトキシシラン、3−トリエトキシシリル−N−(1.3−ジメチル−ブチリデン)プロピルアミン、N−フェニル−3−アミノプロピルトリメトキシシラン、N−(ビニルベンジル)−2−アミノエチル−3−アミノプロピルトリメトキシシランの塩酸塩、特殊アミノシラン等のアミン系等を用いることができ、これらは2種以上組み合わせて使用しても良い。
市販品としては、KBM−502、KBE−502、KBM−503、KBE−503、KBM−5103、KBM−802、KBM−803、KBM−602、KBE−603(信越化学工業(株)製商品名)およびA−174、A−189、A−1122(日本ユニカ−(株)製商品名)等が挙げられる。
これらのシランカップリング剤の配合量は0.1〜5重量部であり、0.3〜3重量部が好ましく、0.5〜1重量部がより好ましい。シランカップリング剤の配合量が0.1重量部より少ないとガラスやプリント基板等の基材との接着性が劣り、5重量部より多いと製造方法によっては組成物の粘度が上昇し作業性が劣る。
Examples of silane coupling agents include methacryloxy silane couplings such as 3-methacryloxypropylmethyldimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropylmethyldiethoxysilane, and 3-methacryloxypropyltriethoxysilane. Agents, acryloxy silane coupling agents such as 3-acryloxypropyltrimethoxysilane, mercapto silane coupling agents such as 3-mercaptopropylmethyldimethoxysilane, 3-mercaptopropyltrimethoxysilane, and N-2 (aminoethyl) 3-aminopropylmethyldimethoxysilane, N-2 (aminoethyl) 3-aminopropyltrimethoxysilane, N-2 (aminoethyl) 3-aminopropyltriethoxysilane, 3-amino Propyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-triethoxysilyl-N- (1.3-dimethyl-butylidene) propylamine, N-phenyl-3-aminopropyltrimethoxysilane, N- (vinyl) Benzyl) -2-aminoethyl-3-aminopropyltrimethoxysilane hydrochloride, special aminosilane, and other amines can be used, and these may be used in combination of two or more.
Commercially available products include KBM-502, KBE-502, KBM-503, KBE-503, KBM-5103, KBM-802, KBM-803, KBM-602, KBE-603 (trade names, manufactured by Shin-Etsu Chemical Co., Ltd.) ) And A-174, A-189, A-1122 (trade name, manufactured by Nippon Unicar Co., Ltd.) and the like.
The compounding quantity of these silane coupling agents is 0.1-5 weight part, 0.3-3 weight part is preferable and 0.5-1 weight part is more preferable. When the amount of the silane coupling agent is less than 0.1 parts by weight, the adhesiveness to a substrate such as glass or a printed circuit board is inferior. Is inferior.

消泡剤としては、シリコーン系オイル、フッ素オイル、ポリカルボン酸系ポリマ−等公知の消泡剤を用いることができ、塗料100重量部に対し、0.001〜5重量部添加することができる。   As the antifoaming agent, known antifoaming agents such as silicone oil, fluorine oil, polycarboxylic acid polymer, etc. can be used, and 0.001 to 5 parts by weight can be added to 100 parts by weight of the coating material. .

本発明の絶縁塗料を塗布する電子部品は、特に制限されるものではないが、マイコン、トランジスタ、コンデンサ、抵抗、リレ−、トランス等及びこれらを搭載した実装回路板などが挙げられ、更にこれら電子部品に接合されるリ−ド線、ハーネス、フィルム基板等も含むことができる。   The electronic component to which the insulating paint of the present invention is applied is not particularly limited, and examples thereof include a microcomputer, a transistor, a capacitor, a resistor, a relay, a transformer, and a mounting circuit board on which these are mounted. It can also include lead wires, harnesses, film substrates, etc. that are joined to the components.

本発明になる絶縁塗料を用いて絶縁される電子部品の製造方法としては、一般に知られている浸漬法、ハケ塗り法、スプレ−法、線引き塗布法、ディスペンス法等を用いることができ、絶縁塗料を上記電子部品に塗布し、乾燥すればよい。   As a manufacturing method of an electronic component insulated using the insulating paint according to the present invention, a generally known dipping method, brush coating method, spray method, wire drawing method, dispensing method, etc. can be used. What is necessary is just to apply | coat a coating material to the said electronic component and to dry.

以下、本発明の実施例を説明するが、本発明はこれらに制限されるものではない。
また、本発明で、「部」として表したものは特に限定しない限り重量部を示す。
(実施例1)
1リットルの四つ口フラスコに、SIS樹脂(クレイトンポリマージャパン(株)製商品名、D−1107)20部、粘着性付与樹脂(出光石油化学(株)製商品名、P−100)10部、エチルシクロヘキサン70部を加え100℃で3時間攪拌溶解しワニスAを得た。
ワニスAを100部秤量し、アジン系の着色材(オリエント化学(株)製商品名、OIL BLACK No.5)5部を加えて、室温で攪拌溶解し絶縁塗料(ア)を得た。
(実施例2)
実施例1にて得たワニスA105部に、アジン系の着色材(オリエント化学(株)製商品名、OIL BLACK No.5)5部、及び、シランカップリング剤(信越化学工業(株)製商品名、KBM−5103)1部を加え室温で攪拌混合し絶縁塗料(イ)を得た。
(比較例1)
1リットルの四つ口フラスコに、SIS樹脂(クレイトンポリマージャパン(株)製商品名、D−1107)20部、粘着性付与樹脂(出光石油化学(株)製商品名、P−100)10部、エチルシクロヘキサン70部を加え100℃で3時間攪拌溶解し絶縁塗料(ウ)を得た。
(比較例2)
比較例1にて得た絶縁塗料(ウ)100部に、アゾ化合物クロム錯塩(オリエント化学(株)製商品名、VALIFAST BLACK 3804)5部を加えて、室温で攪拌溶解し絶縁塗料(エ)を得た。
Examples of the present invention will be described below, but the present invention is not limited thereto.
In the present invention, what is expressed as “parts” represents parts by weight unless otherwise specified.
Example 1
In a 1 liter four-necked flask, 20 parts of SIS resin (trade name, D-1107, manufactured by Kraton Polymer Japan Co., Ltd.), 10 parts of tackifier resin (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., P-100) Then, 70 parts of ethylcyclohexane was added and dissolved by stirring at 100 ° C. for 3 hours to obtain varnish A.
100 parts of varnish A was weighed, 5 parts of an azine-based coloring material (trade name, OIL BLACK No. 5 manufactured by Orient Chemical Co., Ltd.) was added, and the mixture was stirred and dissolved at room temperature to obtain an insulating paint (A).
(Example 2)
In 105 parts of varnish A obtained in Example 1, 5 parts of an azine-based coloring material (trade name, OIL BLACK No. 5 manufactured by Orient Chemical Co., Ltd.) and a silane coupling agent (manufactured by Shin-Etsu Chemical Co., Ltd.) 1 part of a trade name, KBM-5103) was added, and the mixture was stirred and mixed at room temperature to obtain an insulating paint (I).
(Comparative Example 1)
In a 1 liter four-necked flask, 20 parts of SIS resin (trade name, D-1107, manufactured by Kraton Polymer Japan Co., Ltd.), 10 parts of tackifier resin (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., P-100) Then, 70 parts of ethylcyclohexane was added and stirred and dissolved at 100 ° C. for 3 hours to obtain an insulating coating (C).
(Comparative Example 2)
To 100 parts of the insulating paint (C) obtained in Comparative Example 1, 5 parts of an azo compound chromium complex (trade name, VALIFAST BLACK 3804, manufactured by Orient Chemical Co., Ltd.) was added and dissolved by stirring at room temperature. Got.

絶縁塗料(ア)〜(エ)を基材との接着試験用として、ガラス板(縦750mm×横750mm×厚さ2mm)に塗布し、乾燥させて厚み100μmの塗膜を成形した。次いで、この塗膜をJIS K5400「碁盤目テープ法」に準じ試験を行った。その結果を表1に示す。   Insulating paints (a) to (d) were applied to a glass plate (length 750 mm × width 750 mm × thickness 2 mm) for adhesion test with a base material and dried to form a coating film having a thickness of 100 μm. Subsequently, this coating film was tested according to JIS K5400 “cross-cut tape method”. The results are shown in Table 1.

また、透湿度測定用としてフッ素加工板(縦150mm×横100mm×厚さ2mm)に塗布し、乾燥させて100μmの塗膜を成形した。次いで、この塗膜をJIS Z0208の「防湿包装材料の透湿度試験方法(カップ法)」に準じ試験を行った。その結果を表1に示す。   Moreover, it applied to the fluorine processing board (length 150mm x width 100mm x thickness 2mm) for moisture permeability measurement, it was made to dry and the 100 micrometers coating film was shape | molded. Next, this coating film was tested in accordance with JIS Z0208 “Moisture permeability test method for moisture-proof packaging material (cup method)”. The results are shown in Table 1.

更に、絶縁塗料(ア)〜(エ)の遮光性試験用として、ガラス板(縦200mm×横100mm×厚さ2mm)に塗布し、乾燥させて100μmの塗膜を成形した。次いで、この塗膜を分光光度計(日立製作所製 U−2000型 日立Double beam分光光度計)を用いて、400〜700nm領域での遮光性を測定した。その結果を表1に示す。

















Furthermore, for the light shielding test of the insulating paints (A) to (D), it was applied to a glass plate (length 200 mm × width 100 mm × thickness 2 mm) and dried to form a 100 μm coating film. Subsequently, the light shielding property in the 400-700 nm area | region was measured for this coating film using the spectrophotometer (Hitachi Ltd. U-2000 type Hitachi Double beam spectrophotometer). The results are shown in Table 1.

















Figure 2006335975
Figure 2006335975

表1に示すように、実施例1及び実施例2にて得られた絶縁塗料(ア)、(イ)は、比較例に比べ、遮光性が高く、アゾ系の着色剤を使用せず電子部品の品番等を隠ぺいすることができる




As shown in Table 1, the insulating paints (a) and (b) obtained in Example 1 and Example 2 have higher light-shielding properties than the comparative examples, and do not use azo colorants. It is possible to conceal part numbers etc.




Claims (5)

(a)A−B−A型スチレンブロック共重合体ゴム10〜40重量部、(b)粘着性付与樹脂1〜20重量部、(c)溶剤50〜90重量部、(d)アジン系着色剤を含有してなる絶縁塗料。   (A) ABA type styrene block copolymer rubber 10-40 parts by weight, (b) tackifying resin 1-20 parts by weight, (c) solvent 50-90 parts by weight, (d) azine-based coloring Insulating paint containing an agent. 請求項1において、(d)アジン系着色剤の含有量が、絶縁塗料100重量部に対し0.01〜70重量部である絶縁塗料。   2. The insulating paint according to claim 1, wherein the content of the (d) azine-based colorant is 0.01 to 70 parts by weight with respect to 100 parts by weight of the insulating paint. 請求項1又は2において、さらに充填剤、改質剤、消泡剤および接着性付与剤からなる添加剤から選ばれる少なくとも1種を含む絶縁塗料。   3. The insulating paint according to claim 1 or 2, further comprising at least one selected from an additive comprising a filler, a modifier, an antifoaming agent, and an adhesion promoter. 請求項1乃至3の何れかの絶縁塗料を塗布した電子部品。   An electronic component to which the insulating paint according to claim 1 is applied. 請求項1乃至3の何れかの絶縁塗料を電子部品に塗布し、その後乾燥させる電子部品の製造方法。



A method of manufacturing an electronic component, wherein the insulating paint according to any one of claims 1 to 3 is applied to the electronic component and then dried.



JP2005165421A 2005-06-06 2005-06-06 Insulation coating, electronic part by using the same and method for producing the electronic part Pending JP2006335975A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102568803A (en) * 2010-12-31 2012-07-11 东莞美信科技有限公司 Improved encapsulation process for surface mounted device (SMD) transformer
WO2012124737A1 (en) * 2011-03-15 2012-09-20 昭和電工株式会社 Moisture-proof insulative coating with visible light-blocking properties
JP2012229414A (en) * 2011-04-26 2012-11-22 Chi Mei Corp Moisture-proof insulation coating materal and use thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102568803A (en) * 2010-12-31 2012-07-11 东莞美信科技有限公司 Improved encapsulation process for surface mounted device (SMD) transformer
WO2012124737A1 (en) * 2011-03-15 2012-09-20 昭和電工株式会社 Moisture-proof insulative coating with visible light-blocking properties
JP2012229414A (en) * 2011-04-26 2012-11-22 Chi Mei Corp Moisture-proof insulation coating materal and use thereof
US9136038B2 (en) 2011-04-26 2015-09-15 Chi Mei Corporation Moisture-proof and insulating coating material and uses thereof

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