JP2006247595A - Apparatus for adsorption and concentration - Google Patents

Apparatus for adsorption and concentration Download PDF

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JP2006247595A
JP2006247595A JP2005070683A JP2005070683A JP2006247595A JP 2006247595 A JP2006247595 A JP 2006247595A JP 2005070683 A JP2005070683 A JP 2005070683A JP 2005070683 A JP2005070683 A JP 2005070683A JP 2006247595 A JP2006247595 A JP 2006247595A
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adsorption
concentration
desorption
gas
adsorbing
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Masashi Nishiguchi
昌志 西口
Kazuhiro Niwa
和裕 丹羽
Masato Suzuki
正人 鈴木
Takuya Oka
卓也 岡
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an apparatus for adsorption and concentration, which is used for an exhaust gas treatment apparatus containing an organic solvent, which can remove gases without changing treatment air flow and faults even when gas concentrations fluctuate, and which can supply stable concentrated gases. <P>SOLUTION: An adsorption means 1 is provided with an adsorption part 1a and a desorption part 1b, which can be switched at cycles determined by an adsorption/desorption cycle-adjusting means 3. An inlet-concentration measurement means 2 is provided at the inlet of the adsorption part 1a. The signal of a measured concentration is sent to the adsorption/desorption cycle-adjusting means 3. Air for desorption is sent by a fan 5 to the desorption part 1b. Gases are desorbed from the desorption part 1b and then the concentrated gases are supplied to a secondary treatment means. With the above configuration, the amount of gases to be adsorbed to the adsorption means 1 can be stabilized even when the concentration of exhaust gases fluctuate. As a result, this makes it possible to positively remove gases and to obtain stable concentrated gases. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、排ガス中に含まれる有機溶剤などの有害物質を除去する排ガス浄化装置に使用される吸着濃縮装置に関する。   The present invention relates to an adsorption concentration apparatus used in an exhaust gas purification apparatus that removes harmful substances such as organic solvents contained in exhaust gas.

従来、この種の吸着濃縮装置は、低濃度の有機溶剤ガスを処理する場合、低濃度有機溶剤ガスを吸着材に通気吸着させ、吸着された有機溶剤を少量の加熱気体にて吸着材から脱着し、脱着された小風量、高濃度の有機溶剤ガスを2次処理装置で処理する濃縮処理方法が用いられ、2次処理装置としては触媒燃焼装置などの酸化分解装置や、冷却し液化する回収装置などが一般的に使用される。そして、2次処理装置を効率的に、安全に動作させるため2次処理装置の運転状況より、吸着濃縮装置の動作を制御したものが知られている(例えば、特許文献1、2参照)。   Conventionally, this type of adsorption concentrating device, when processing low-concentration organic solvent gas, allows low-concentration organic solvent gas to be adsorbed by adsorption to the adsorbent, and the adsorbed organic solvent is desorbed from the adsorbent with a small amount of heated gas. In addition, a concentration treatment method is used in which the desorbed small air volume and high-concentration organic solvent gas are treated in a secondary treatment device. As the secondary treatment device, an oxidative decomposition device such as a catalytic combustion device, or a cooling and liquefying recovery is used. A device or the like is generally used. And what controlled operation | movement of the adsorption concentration apparatus from the operating condition of a secondary processing apparatus in order to operate a secondary processing apparatus efficiently and safely is known (for example, refer patent documents 1, 2).

以下、その吸着濃縮について図9乃至図11を参照しながら説明する。   Hereinafter, the adsorption concentration will be described with reference to FIGS.

図9に示すように、ファン103を介して吸着体101の吸着部101aに通気された有機溶剤ガスは、吸着浄化され放出される。一方、溶剤を吸着した吸着材は、吸着部101aから101bへ移動され、ファン102を介して加熱部5にて加熱された少量の空気で脱着再生される。脱着部101bから少量の加熱空気で脱着された有機溶剤は、濃縮ガスとしてファン105を介して触媒燃焼装置106に付設された加熱器106aによって加熱され触媒106bに通気される。触媒入口のガス温度は温度検出部108と温度調節器109が加熱器106aを制御することによって調整される。濃縮ガスは、触媒106bによって有機溶剤が酸化分解されることによって浄化され、排出される。   As shown in FIG. 9, the organic solvent gas ventilated through the fan 103 to the adsorbing portion 101a of the adsorbent 101 is adsorbed and purified and released. On the other hand, the adsorbent adsorbing the solvent is moved from the adsorbing unit 101 a to 101 b and is desorbed and regenerated with a small amount of air heated by the heating unit 5 via the fan 102. The organic solvent desorbed from the desorption unit 101b with a small amount of heated air is heated as a concentrated gas by the heater 106a attached to the catalytic combustion device 106 via the fan 105 and is passed through the catalyst 106b. The gas temperature at the catalyst inlet is adjusted by the temperature detector 108 and the temperature controller 109 controlling the heater 106a. The concentrated gas is purified and discharged by oxidizing and decomposing the organic solvent by the catalyst 106b.

温度検出器107によって検出された触媒燃焼装置106の出口温度を温度指示器110が吸脱着周期調整器111に伝達し、該吸脱着周期調整器111により、吸着体101の吸脱着周期を調整する。   The temperature indicator 110 transmits the outlet temperature of the catalytic combustion apparatus 106 detected by the temperature detector 107 to the adsorption / desorption cycle adjuster 111, and the adsorption / desorption cycle adjuster 111 adjusts the adsorption / desorption cycle of the adsorbent 101. .

また、図10に示すように、温度検出器107によって検出された触媒燃焼装置106の出口温度を温度指示器110がファン102およびファン105に伝達し、吸着体101の脱着部101bに供給する脱着再生用の加熱空気の風量および触媒燃焼装置106への供給風量を調整する。   Further, as shown in FIG. 10, the temperature indicator 110 transmits the outlet temperature of the catalytic combustion apparatus 106 detected by the temperature detector 107 to the fan 102 and the fan 105, and the desorption supplied to the desorption part 101 b of the adsorbent 101. The air volume of the heated air for regeneration and the air volume supplied to the catalytic combustion apparatus 106 are adjusted.

また、この種の吸着濃縮装置には、吸気側のガス濃度を測定し、吸気風量を調整しているものもある(例えば、特許文献3参照)。   Some of these types of adsorption concentrators measure the intake-side gas concentration and adjust the intake air volume (see, for example, Patent Document 3).

以下、その吸着濃縮装置について図11を参照しながら説明する。吸着部101aと脱着部101bを有する吸着体101とアンモニア、硫化水素および揮発性有機化合物などの周期成分に感度を有する脱臭制御用ガスセンサ112を備える。上記吸着体101の吸着部101aにガスを供給するファン103を設ける。そして、上記脱臭制御用ガスセンサ112により検出されたガス濃度が濃くなるほど吸着用ファン103の風量が多くなり、脱臭制御用ガスセンサ112により検出されたガス濃度が薄くなるほど吸着用ファン103の風量が少なくなるように、制御部113により吸着用ファン103を制御している。
特開平10−330号公報 特開平10−128048号公報 特開2002−126438号公報
Hereinafter, the adsorption concentration apparatus will be described with reference to FIG. An adsorbent body 101 having an adsorbing part 101a and a desorbing part 101b and a deodorizing control gas sensor 112 having sensitivity to periodic components such as ammonia, hydrogen sulfide and volatile organic compounds are provided. A fan 103 for supplying gas to the adsorption unit 101a of the adsorbent 101 is provided. As the gas concentration detected by the deodorizing control gas sensor 112 increases, the air volume of the adsorption fan 103 increases. As the gas concentration detected by the deodorizing control gas sensor 112 decreases, the air volume of the adsorption fan 103 decreases. As described above, the suction fan 103 is controlled by the control unit 113.
JP-A-10-330 Japanese Patent Laid-Open No. 10-128048 JP 2002-126438 A

このような従来の吸着濃縮装置では、排気ガスの濃度が変動しても吸着材で確実に除去するとともに、2次処理装置に導入する濃縮ガスの濃度を2次処理が効率的に行える濃度で提供することが要求されている。   In such a conventional adsorption concentration apparatus, even if the exhaust gas concentration fluctuates, it is reliably removed by the adsorbent, and the concentration of the concentrated gas introduced into the secondary treatment apparatus is such that the secondary treatment can be performed efficiently. It is required to provide.

しかしながら、2次処理装置である触媒燃焼装置の温度を測定する方法では、他の方式の2次処理装置に用いることができなかった。   However, the method for measuring the temperature of the catalytic combustion apparatus, which is a secondary processing apparatus, cannot be used for other types of secondary processing apparatuses.

また、吸気ガス濃度を測定し、吸気風量を調整する吸着濃縮装置では、工場の排気において、一定量の排気風量を保つ必要や、製造設備からの排気においては、排気風量を定常に保つ必要があり、このような用途では用いることができなかった。   In addition, in an adsorption concentrator that measures the intake gas concentration and adjusts the intake air volume, it is necessary to maintain a constant amount of exhaust air at the factory exhaust, and to maintain a constant exhaust air volume when exhausting from manufacturing equipment. Yes, it could not be used in such applications.

本発明は、このような従来の課題を解決するものであり、排気ガス濃度が変動した場合においても吸着材への吸着量を調整する事ができ、また、安定した濃度の濃縮ガスを2次処理装置に供給することができる吸着濃縮装置を提供することを目的としている。   The present invention solves such a conventional problem, and even when the exhaust gas concentration fluctuates, the amount of adsorption to the adsorbent can be adjusted, and the concentrated gas having a stable concentration can be converted into the secondary gas. It aims at providing the adsorption concentration apparatus which can be supplied to a processing apparatus.

また、処理風量を変動させずに安定して排気ガスを吸着濃縮することのできる吸着濃縮装置を提供することを目的としている。   It is another object of the present invention to provide an adsorption concentrator capable of adsorbing and concentrating exhaust gas stably without changing the processing air volume.

本発明の吸着濃縮装置は上記目的を達成するために、吸着体の入口ガス濃度を測定し、ガス濃度に応じて吸着体の吸脱着周期を調整するとしたものである。   In order to achieve the above object, the adsorption concentration apparatus of the present invention measures the inlet gas concentration of the adsorbent and adjusts the adsorption / desorption cycle of the adsorbent according to the gas concentration.

この手段によりガス濃度が変動しても吸着体へのガス吸着量を安定化することができ、また、装置への供給風量を変えることなくガスを確実に除去でき、2次処理装置に安定した濃縮ガスを供給できる吸着濃縮装置が得られる。   By this means, the gas adsorption amount to the adsorbent can be stabilized even if the gas concentration fluctuates, and the gas can be reliably removed without changing the supply air amount to the apparatus, which is stable in the secondary processing apparatus. An adsorption concentrator capable of supplying a concentrated gas is obtained.

また、他の手段は、吸着体の出口ガス濃度を測定し、ガス濃度に応じて吸着体の吸脱着周期を調整するとしたものである。   Another means is that the outlet gas concentration of the adsorbent is measured and the adsorption / desorption cycle of the adsorbent is adjusted according to the gas concentration.

これにより吸着体に吸着したガスが増加し除去性能が低下していく度合いを知ることができ、ガス濃度が変動しても風量を変えることなく除去性能を維持するとともに、吸着体へのガス吸着量を安定化でき、2次処理装置に安定した濃縮ガスを供給できる吸着濃縮装置が得られる。   This makes it possible to know the extent to which the gas adsorbed on the adsorber increases and the removal performance decreases, and even if the gas concentration changes, the removal performance is maintained without changing the air volume, and the gas adsorption to the adsorbent The adsorption concentration apparatus which can stabilize the quantity and can supply a stable concentrated gas to the secondary processing apparatus is obtained.

また、他の手段は、吸着体の入口ガス濃度と出口ガス濃度を測定し、そのガス濃度に応じて吸脱着周期を調整するとしたものである。   The other means measures the inlet gas concentration and outlet gas concentration of the adsorbent and adjusts the adsorption / desorption cycle according to the gas concentration.

これにより、吸着体に供給されるガスの濃度変動、除去後のガス濃度、除去性能を知ることができるため、最適な吸脱着周期で運転することができ、ガス濃度が変動しても風量を変えることなく除去性能を維持するとともに、吸着体へのガス吸着量を安定化でき、2次処理装置に安定した濃縮ガスを供給できる吸着濃縮装置が得られる。   As a result, it is possible to know the concentration fluctuation of the gas supplied to the adsorbent, the concentration of the gas after removal, and the removal performance. It is possible to obtain an adsorption concentrator capable of maintaining the removal performance without change, stabilizing the amount of gas adsorbed to the adsorbent, and supplying a stable concentrated gas to the secondary treatment apparatus.

また、他の手段は、吸着体の入口濃度と出口濃度を1つの濃度測定手段で測定し、そのガス濃度に応じて吸脱着周期を調整するとしたものである。   Another means is that the inlet concentration and outlet concentration of the adsorbent are measured by one concentration measuring means, and the adsorption / desorption period is adjusted according to the gas concentration.

これにより、1台の濃度測定手段で吸着体に供給されるガスの濃度変動、除去後のガス濃度、除去性能を知ることができるため、最適な吸脱着周期で運転することができ、ガス濃度が変動しても風量を変えることなく除去性能を維持するとともに、吸着体へのガス吸着量を安定化でき、2次処理装置に安定した濃縮ガスを供給できる吸着濃縮装置が得られる。   As a result, it is possible to know the concentration fluctuation of the gas supplied to the adsorbent, the concentration of the gas after removal, and the removal performance with one concentration measuring means, so that the operation can be performed with the optimum adsorption / desorption cycle. As a result, the adsorption performance can be maintained without changing the air volume, the gas adsorption amount to the adsorbent can be stabilized, and a stable concentrated gas can be supplied to the secondary processing apparatus.

また、他の手段は、吸着体の入口ガス濃度と出口ガス濃度を測定し、吸着体のメンテナンス時期を知らせるものである。   Another means measures the inlet gas concentration and the outlet gas concentration of the adsorbent and informs the adsorbent maintenance time.

これにより、吸着体の除去性能の低下から最適なメンテナンス時期を知ることができるため、長期にわたり除去性能を維持できる吸着濃縮装置が得られる。   Thereby, since the optimal maintenance time can be known from the decline in the removal performance of the adsorbent, an adsorption concentrator capable of maintaining the removal performance over a long period of time can be obtained.

また、他の手段は、吸脱着周期によって脱着用気体の風量を調整し、周期が短い場合は風量を多く、周期が長い場合は風量を少なくすることによって、脱着した濃縮ガスの濃度を安定化することが出来る吸着濃縮装置が得られる。   In addition, other means adjust the flow rate of the desorption gas according to the adsorption / desorption cycle, and stabilize the concentration of the desorbed concentrated gas by increasing the flow rate when the cycle is short and decreasing the flow rate when the cycle is long. An adsorption concentrator that can be obtained is obtained.

また、他の手段は、脱着した脱着ガスの濃度を測定し、脱着ガスの濃度が安定するように脱着用気体の風量を調整することによって、安定した濃縮ガスを得ることが出来る吸着濃縮装置が得られる。   Another means is to measure the concentration of the desorbed desorbed gas and adjust the air flow of the desorbed gas so that the concentration of the desorbed gas is stable. can get.

また、他の手段は、吸着手段の入口濃度と出口濃度と脱着ガス濃度を測定し、その濃度より吸脱着周期と脱着用気体の風量を調整するものである。   The other means measures the inlet concentration, outlet concentration and desorption gas concentration of the adsorption means, and adjusts the adsorption / desorption period and the flow rate of the desorption gas based on the concentrations.

これにより、最適な吸脱着周期と脱着用気体の風量を設定できるため、確実にガスを除去できるとともに安定した濃縮ガスを得ることが出来る吸着濃縮装置を得ることが出来る。   Thereby, since the optimal adsorption / desorption period and the air volume of the desorption gas can be set, it is possible to obtain an adsorption / concentration apparatus capable of reliably removing the gas and obtaining a stable concentrated gas.

また、他の手段は、吸着手段が1つもしくは複数の吸着塔に吸着体を充填したものである。   Another means is that the adsorbing means is one or a plurality of adsorption towers packed with an adsorbent.

これにより、確実な除去性能と安定な濃縮ガスを得ることが出来る吸着濃縮装置が得られる。   Thereby, the adsorption concentration apparatus which can obtain reliable removal performance and a stable concentrated gas is obtained.

また、他の手段は、吸着手段が吸着ロータとしたものである。   Another means is that the suction means is a suction rotor.

これにより、簡易な構成で確実な除去性能と安定な濃縮ガスを得ることが出来る吸着濃縮装置が得られる。   Thereby, the adsorption concentration apparatus which can obtain reliable removal performance and a stable concentrated gas with a simple configuration is obtained.

また、他の手段は、ガス濃度を測定する濃度測定手段を半導体式ガスセンサとしたものである。   As another means, the concentration measuring means for measuring the gas concentration is a semiconductor gas sensor.

これにより、簡易にガス濃度が測定できるため、簡易な構成で確実な除去性能と安定な濃縮ガスを得ることが出来る吸着濃縮装置が得られる。   Thereby, since the gas concentration can be easily measured, an adsorption concentrating device capable of obtaining a reliable removal performance and a stable concentrated gas with a simple configuration can be obtained.

本発明によれば排気ガスの濃度が変動しても、風量を変えることなく確実に除去できるという効果のある吸着濃縮装置を提供できる。   ADVANTAGE OF THE INVENTION According to this invention, even if the density | concentration of exhaust gas fluctuates, the adsorption | suction concentration apparatus with the effect that it can remove reliably, without changing an air volume can be provided.

また、安定した濃度の濃縮ガスを得ることができる。   Further, a concentrated gas having a stable concentration can be obtained.

本発明請求項1記載の発明は、低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、吸着手段の入口濃度を測定する入口濃度測定手段と前記入口濃度測定手段の信号を受け、吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置としたものであり、入口濃度が低い場合は吸着時間を長く、入口濃度が高い場合は吸着時間を短く吸脱着周期を調整する作用を有する。   The invention according to claim 1 of the present invention is an adsorption means provided with an adsorbent for adsorbing exhaust gas containing a low concentration organic solvent, an adsorption part for adsorbing gas to the adsorption means, and desorbing the adsorbed gas And a desorption gas supply means for supplying a desorption gas for desorbing the organic solvent adsorbed by the desorption portion, and periodically switching between the adsorption portion and the desorption portion. In the adsorption concentration apparatus, an adsorption concentration apparatus having an inlet concentration measuring means for measuring the inlet concentration of the adsorption means and an adsorption / desorption cycle adjusting means for adjusting the adsorption / desorption cycle in response to a signal from the inlet concentration measuring means. When the inlet concentration is low, the adsorption time is lengthened, and when the inlet concentration is high, the adsorption time is shortened to adjust the adsorption / desorption cycle.

また、請求項2記載の発明は、低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、吸着手段の出口濃度を測定する出口濃度測定手段と前記出口濃度測定手段の信号を受け、吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置としたものであり、出口濃度が高くなってくると吸着から脱着に切替えるよう吸脱着周期を調整する作用を有する。   According to a second aspect of the present invention, there is provided an adsorption means provided with an adsorbent for adsorbing exhaust gas containing a low concentration organic solvent, an adsorption portion for adsorbing the gas to the adsorption means, and desorbing the adsorbed gas. And a desorption gas supply means for supplying a desorption gas for desorbing the organic solvent adsorbed by the desorption portion, and periodically switching between the adsorption portion and the desorption portion. In the adsorption concentration apparatus, an adsorption concentration apparatus is provided with an outlet concentration measuring means for measuring the outlet concentration of the adsorption means and an adsorption / desorption cycle adjusting means for adjusting the adsorption / desorption cycle in response to a signal from the outlet concentration measuring means. When the outlet concentration becomes higher, the adsorption / desorption cycle is adjusted so as to switch from adsorption to desorption.

また、請求項3記載の発明は、低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、前記吸着部の入口濃度を測定する入口濃度測定手段と出口濃度を測定する出口濃度測定手段と前記入口濃度測定手段と出口濃度測定手段の信号を受け吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置としたものであり、入口濃度と出口濃度、さらに入口濃度と出口濃度の差から、吸脱着周期を最適に設定する作用を有する。   According to a third aspect of the present invention, there is provided an adsorption means provided with an adsorbent for adsorbing an exhaust gas containing a low concentration organic solvent, an adsorption portion for adsorbing the gas to the adsorption means, and desorbing the adsorbed gas. And a desorption gas supply means for supplying a desorption gas for desorbing the organic solvent adsorbed by the desorption portion, and periodically switching between the adsorption portion and the desorption portion. In the adsorption concentrator, an inlet concentration measuring means for measuring the inlet concentration of the adsorption section, an outlet concentration measuring means for measuring the outlet concentration, and an adsorption / desorption cycle for adjusting the adsorption / desorption period by receiving signals from the inlet concentration measuring means and the outlet concentration measuring means. The adsorption / concentration apparatus is provided with a desorption cycle adjusting means, and has an action of setting the adsorption / desorption cycle optimally based on the difference between the inlet concentration and the outlet concentration, and the difference between the inlet concentration and the outlet concentration.

また、請求項4記載の発明は、低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、前記吸着部の入口と出口から交互に切替えて気体をサンプリングするサンプリング手段と前記サンプリング手段でサンプリングした気体のガス濃度を測定する濃度測定手段と前記濃度測定手段の信号を受け吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置としたものであり、1つの濃度測定手段で入口濃度と出口濃度を測定し、吸脱着周期を最適に調整する作用を有する。   According to a fourth aspect of the present invention, there is provided an adsorption means provided with an adsorbent for adsorbing an exhaust gas containing a low concentration organic solvent, an adsorption portion for adsorbing the gas to the adsorption means, and desorbing the adsorbed gas. And a desorption gas supply means for supplying a desorption gas for desorbing the organic solvent adsorbed by the desorption portion, and periodically switching between the adsorption portion and the desorption portion. In the adsorption concentration apparatus, sampling means for alternately sampling from the inlet and the outlet of the adsorption section, sampling the gas, concentration measuring means for measuring the gas concentration of the gas sampled by the sampling means, and signals from the concentration measuring means are received and absorbed. It is an adsorption concentrator equipped with an adsorption / desorption cycle adjusting means for adjusting the desorption cycle, and the inlet concentration and the outlet concentration are measured by one concentration measuring means to optimally adjust the adsorption / desorption cycle. It has the effect that.

また、請求項5記載の発明は、出口濃度測定手段の信号もしくは、入口濃度測定手段と出口濃度測定手段の信号より、吸着体のメンテナンス時期を知らせるメンテナンス信号を出力するメンテナンス信号出力手段を備えたものであり、出口濃度もしくは入口濃度と出口濃度を比較することにより、吸着手段の除去能力の低下を判断しメンテナンス時期を知ることができる作用を有する。   Further, the invention according to claim 5 includes a maintenance signal output means for outputting a maintenance signal notifying the maintenance timing of the adsorbent from the signal of the outlet concentration measuring means or the signals of the inlet concentration measuring means and the outlet concentration measuring means. By comparing the outlet concentration or the inlet concentration with the outlet concentration, it has an effect of determining a decrease in the removal capability of the adsorption means and knowing the maintenance time.

また、請求項6記載の発明は、吸脱着周期調整手段で調整された吸脱着周期に応じて、脱着用気体風量調整手段により脱着用気体の風量を調整する構成としたものであり、脱着周期が短い場合は風量を多く、周期が長い場合は風量を少なくし脱着される濃縮ガスの濃度を安定化する作用を有する。   The invention described in claim 6 is configured to adjust the air volume of the desorption gas by the desorption gas air volume adjusting means according to the adsorption / desorption period adjusted by the adsorption / desorption period adjusting means. When the period is short, the air volume is increased. When the period is long, the air volume is decreased to stabilize the concentration of the desorbed concentrated gas.

また、請求項7記載の発明は、脱着手段によって脱着した脱着ガスの濃度を測定する脱着ガス濃度測定手段を備え、前記脱着ガス濃度測定手段の信号を受け、脱着ガスの濃度が定常になるように脱着用気体風量調整手段により脱着用気体の風量を調整する構成としたものであり、脱着ガス濃度が低くなると風量を少なくし、ガス濃度が高くなると風量を多くする作用を有する。   Further, the invention described in claim 7 is provided with a desorption gas concentration measuring means for measuring the concentration of the desorbed gas desorbed by the desorbing means, and receives the signal of the desorbed gas concentration measuring means so that the concentration of the desorbed gas becomes steady. The desorption gas flow rate adjusting means adjusts the flow rate of the desorption gas, and has a function of decreasing the flow rate when the desorption gas concentration is lowered and increasing the flow rate when the gas concentration is increased.

また、請求項8記載の発明は、吸着手段の入口濃度測定手段と出口濃度測定手段と脱着ガス濃度測定手段の信号より、吸脱着周期と脱着用気体の風量を演算し、それぞれ吸脱着周期調整手段、脱着用気体風量調整手段に出力する信号処理手段を備えたものであり、最適な吸脱着周期および脱着用気体の風量を設定する作用を有する。   The invention according to claim 8 calculates the adsorption / desorption period and the air volume of the desorption gas from the signals of the inlet concentration measuring means, the outlet concentration measuring means and the desorption gas concentration measuring means of the adsorption means, and adjusts the adsorption / desorption period respectively. Means, and a signal processing means for outputting to the desorption gas air volume adjustment means, and has an effect of setting an optimum adsorption / desorption cycle and an air volume of the desorption gas.

また、請求項9記載の発明は、吸着手段が1つもしくは複数の吸着塔に充填された吸着体で構成したものであり、吸着塔を切り替えることにより吸脱着を行う作用を有するものである。   In the invention according to claim 9, the adsorbing means is constituted by an adsorbent packed in one or a plurality of adsorption towers, and has an action of performing adsorption / desorption by switching the adsorption towers.

また、請求項10記載の発明は、吸着手段が吸着ローターで構成したものであり、吸着ローターの回転速度で吸脱着周期を調整する作用を有する。   In the invention according to claim 10, the adsorption means is constituted by an adsorption rotor, and has an action of adjusting the adsorption / desorption period by the rotation speed of the adsorption rotor.

また、請求項11記載の発明は、ガス濃度を測定する濃度測定手段を半導体式ガスセンサで構成したものであり、半導体式ガスセンサの信号よりガス濃度を測定する作用を有する。   Further, the invention according to claim 11 is that the concentration measuring means for measuring the gas concentration is constituted by a semiconductor type gas sensor, and has an action of measuring the gas concentration from the signal of the semiconductor type gas sensor.

以下、本発明の実施の形態について図面を参照しながら説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

(実施の形態1)
図1に示すように、吸着手段1は、吸着体として、活性炭やゼオライトなどの有機溶剤を吸着する材料で構成され、吸着部1aと脱着部1bを備え、吸脱着周期調整手段3によって設定した周期でそれぞれ切り替えられる。また、吸着手段1の構成としては、吸着体を充填した吸着塔で構成し、吸着と脱着を切替えて吸着部1aには、ファン4により排気ガスが導入される。また、吸着部1aの入口には入口濃度測定手段2を備え、測定した濃度信号を吸脱着周期調整手段3に送る。
(Embodiment 1)
As shown in FIG. 1, the adsorbing means 1 is made of a material that adsorbs an organic solvent such as activated carbon or zeolite as an adsorbent, and includes an adsorbing part 1 a and a desorbing part 1 b, and is set by the adsorption / desorption period adjusting means 3. Each can be switched in a cycle. Further, the adsorption means 1 is constituted by an adsorption tower filled with an adsorbent, and the adsorption and desorption are switched, and exhaust gas is introduced into the adsorption section 1a by a fan 4. In addition, an inlet concentration measuring means 2 is provided at the inlet of the adsorption unit 1a, and the measured concentration signal is sent to the adsorption / desorption period adjusting means 3.

また、脱着部1bには、ファン5により脱着用の気体が送られる。脱着部1bよりガスを脱着し濃縮ガスを2次処理手段に供給する。ここで、脱着用の気体としては、加熱空気や水蒸気、加熱窒素ガスなどが用いられ熱源としては、ヒーター、ボイラーなどが用いられる。   Moreover, the desorption gas is sent to the desorption part 1b by the fan 5. A gas is desorbed from the desorption section 1b and a concentrated gas is supplied to the secondary processing means. Here, heated air, water vapor, heated nitrogen gas, or the like is used as the desorption gas, and a heater, a boiler, or the like is used as the heat source.

また、入口濃度測定手段2は、FID方式やPID方式の検知器や半導体方式のガスセンサなどを用いることができる。   The inlet concentration measuring means 2 may be an FID type or PID type detector, a semiconductor type gas sensor, or the like.

特に、半導体式のガスセンサを用いると、コストが安く、構成も簡単になる。   In particular, when a semiconductor gas sensor is used, the cost is low and the configuration is simple.

上記構成において、入口濃度測定手段2吸着手段1に供給される排気ガスの濃度を測定し、マイコンである吸脱着周期調整手段3に信号を送る、吸脱着周期調整手段3は信号を受け、ガスの濃度が低い場合は吸着時間を長くし、逆にガス濃度が高い場合は、吸着時間を短くするように周期を調整する。そのため、排ガスの濃度が変動した場合においても、吸着手段1に吸着するガス量を安定化することができる。そのため、確実にガスを除去できるとともに、安定した濃縮ガスを得ることが可能となる。   In the above configuration, the concentration of the exhaust gas supplied to the inlet concentration measuring means 2 adsorbing means 1 is measured, and a signal is sent to the adsorption / desorption period adjusting means 3 which is a microcomputer. If the concentration is low, the adsorption time is lengthened. Conversely, if the gas concentration is high, the period is adjusted to shorten the adsorption time. Therefore, even when the concentration of the exhaust gas varies, the amount of gas adsorbed on the adsorption means 1 can be stabilized. Therefore, it is possible to reliably remove the gas and obtain a stable concentrated gas.

ここで、吸着手段1の構成としては、吸着体を充填した吸着塔で構成し、吸着と脱着を切替えて動作する。   Here, the adsorption means 1 is constituted by an adsorption tower filled with an adsorbent, and operates by switching between adsorption and desorption.

また、吸着塔を複数設置し、順番に吸着と脱着を切替えて動作しても良い。   Alternatively, a plurality of adsorption towers may be installed and operated by switching between adsorption and desorption in order.

さらに、吸着材を円筒形のハニカム状のローターとし、回転させることによりその一部を吸着と脱着に切り替えても良い。   Further, the adsorbent may be a cylindrical honeycomb rotor, and a part thereof may be switched between adsorption and desorption by rotating.

(実施の形態2)
実施の形態1と同じ部分は同一番号を附し、詳細な説明は省略する。図2は、本発明の吸着濃縮装置の構成を示すブロック図である。
(Embodiment 2)
The same parts as those in the first embodiment are denoted by the same reference numerals, and detailed description thereof is omitted. FIG. 2 is a block diagram showing the configuration of the adsorption concentration apparatus of the present invention.

図において、出口濃度測定手段6は、ファン4により吸着手段1の吸着部1aに供給された排ガスの吸着部1aを通過後の出口におけるガス濃度を測定する。出口濃度測定手段6で測定したガス濃度は、吸脱着周期調整手段3に送られ吸着手段1の吸脱着切換周期を調整する。   In the figure, the outlet concentration measuring means 6 measures the gas concentration at the outlet after passing through the adsorption part 1a of the exhaust gas supplied to the adsorption part 1a of the adsorption means 1 by the fan 4. The gas concentration measured by the outlet concentration measuring means 6 is sent to the adsorption / desorption period adjusting means 3 to adjust the adsorption / desorption switching period of the adsorption means 1.

上記構成において、出口濃度測定手段6で測定するガス濃度は、吸着手段1の吸着部1aでガス成分を除去した後のガス濃度である。ここで、吸着部1aへのガスの吸着量が増加し飽和に近くなると徐々にガスの除去量が低下し始め、出口ガス濃度が増加する。この出口ガス濃度の増加を検知し吸着から脱着に切りかえることにより、除去性能を維持しつつ吸着手段1への吸着量を安定化できることになり、得られる濃縮ガスの濃度を安定化することができる。   In the above configuration, the gas concentration measured by the outlet concentration measuring means 6 is the gas concentration after the gas component is removed by the adsorption portion 1a of the adsorption means 1. Here, when the amount of gas adsorbed to the adsorbing portion 1a increases and approaches saturation, the gas removal amount gradually begins to decrease, and the outlet gas concentration increases. By detecting the increase in the outlet gas concentration and switching from adsorption to desorption, the adsorption amount to the adsorption means 1 can be stabilized while maintaining the removal performance, and the concentration of the concentrated gas obtained can be stabilized. .

(実施の形態3)
実施の形態1または2と同じ部分は同一番号を附し、詳細な説明は省略する。図3は、本発明の吸着濃縮装置の構成を示すブロック図である。
(Embodiment 3)
The same parts as those in the first or second embodiment are denoted by the same reference numerals, and detailed description thereof is omitted. FIG. 3 is a block diagram showing the configuration of the adsorption concentration apparatus of the present invention.

図において、入口濃度測定手段2と出口濃度測定手段6は、それぞれ吸着部1aの入口と出口のガス濃度を吸脱着周期調整手段3に伝える。吸脱着周期調整手段3は、入口濃度測定手段2と出口濃度測定手段6の信号を受けて、吸脱着周期を調整し、吸着部1aおよび脱着部1bを切りかえる。   In the figure, an inlet concentration measuring means 2 and an outlet concentration measuring means 6 transmit the gas concentrations at the inlet and outlet of the adsorption part 1a to the adsorption / desorption cycle adjusting means 3, respectively. The adsorption / desorption cycle adjusting unit 3 receives signals from the inlet concentration measuring unit 2 and the outlet concentration measuring unit 6 to adjust the adsorption / desorption cycle, and switches the adsorption unit 1a and the desorption unit 1b.

上記構成において、吸脱着周期調整手段3は、吸着部1aの入口濃度と出口濃度の比較を行い吸着手段1の吸着部1aにおけるガスの除去率を演算する。演算結果である、除去率が低下することを検知して吸着から脱着に切りかえることにより、除去性能を維持しつつ吸着手段1への吸着量を安定化できることになり、得られる濃縮ガスの濃度を安定化することができる。   In the above configuration, the adsorption / desorption cycle adjusting unit 3 compares the inlet concentration and the outlet concentration of the adsorption unit 1a, and calculates the gas removal rate in the adsorption unit 1a of the adsorption unit 1. By switching from adsorption to desorption by detecting that the removal rate is reduced, which is the calculation result, the adsorption amount to the adsorption means 1 can be stabilized while maintaining the removal performance, and the concentration of the concentrated gas obtained can be reduced. Can be stabilized.

(実施の形態4)
実施の形態1乃至3のいずれかと同じ部分は同一番号を附し、詳細な説明は省略する。図4は、本発明の吸着濃縮装置の構成を示すブロック図である。
(Embodiment 4)
The same parts as those in any of Embodiments 1 to 3 are denoted by the same reference numerals, and detailed description thereof is omitted. FIG. 4 is a block diagram showing the configuration of the adsorption concentration apparatus of the present invention.

図において、濃度測定手段7は吸着手段1の吸着部1aの入口と出口のガスを切替えて交互にサンプリングできるように配管及びバルブ、ポンプで構成したサンプリング手段12で接続されている。濃度測定手段7で測定したガス濃度は、吸脱着周期調整手段3に送られる。濃度測定手段7は、FID方式やPID方式の検知器や半導体方式のガスセンサなどを用いることができる。   In the figure, the concentration measuring means 7 is connected by a sampling means 12 composed of pipes, valves and pumps so that the gas at the inlet and outlet of the adsorption part 1a of the adsorption means 1 can be switched and sampled alternately. The gas concentration measured by the concentration measuring means 7 is sent to the adsorption / desorption period adjusting means 3. As the concentration measuring means 7, an FID type or PID type detector, a semiconductor type gas sensor, or the like can be used.

上記構成において、濃度測定手段7で測定した吸着部1aの入口および出口のガス濃度は、吸脱着周期調整手段3に伝えられ、吸着部1aの入口濃度と出口濃度の比較を行い吸着手段1の吸着部1aにおけるガスの除去率を演算する。演算結果である、除去率が低下することを検知して吸着から脱着に切りかえることにより、除去性能を維持しつつ吸着手段1への吸着量を安定化できることになり、得られる濃縮ガスの濃度を安定化することができる。   In the above configuration, the gas concentrations at the inlet and outlet of the adsorption unit 1a measured by the concentration measuring unit 7 are transmitted to the adsorption / desorption cycle adjusting unit 3, and the inlet concentration and the outlet concentration of the adsorption unit 1a are compared with each other. The gas removal rate in the adsorption part 1a is calculated. By switching from adsorption to desorption by detecting that the removal rate is reduced, which is the calculation result, the adsorption amount to the adsorption means 1 can be stabilized while maintaining the removal performance, and the concentration of the concentrated gas obtained can be reduced. Can be stabilized.

(実施の形態5)
実施の形態1乃至4のいずれかと同じ部分は同一番号を附し、詳細な説明は省略する。図5は、本発明の吸着濃縮装置の構成を示すブロック図である。
(Embodiment 5)
The same parts as those in any of Embodiments 1 to 4 are denoted by the same reference numerals, and detailed description thereof is omitted. FIG. 5 is a block diagram showing the configuration of the adsorption concentration apparatus of the present invention.

図において、メンテナンス信号出力手段8は、吸脱着周期調整手段3から吸着手段1の吸着部1aの除去率の信号を受け、吸着体の除去性能低下を判断し、メンテナンス信号を出力する。   In the figure, a maintenance signal output means 8 receives a signal of the removal rate of the adsorption part 1a of the adsorption means 1 from the adsorption / desorption period adjusting means 3, determines a decrease in the removal performance of the adsorbent, and outputs a maintenance signal.

上記構成において、メンテナンス信号出力手段8は、吸着部1aの除去率が低下していることを知ることができるため、吸着部1aもしくは吸着手段1の吸着体の劣化を検知することができるため、適切に吸着体の交換やクリーニングなどの処置を行うことができる。メンテナンス信号出力手段8としては、マイコンとLED等の表示との組合せ等がある。   In the above configuration, since the maintenance signal output means 8 can know that the removal rate of the suction part 1a is reduced, it can detect the deterioration of the suction part 1a or the suction body of the suction means 1, It is possible to appropriately perform treatment such as replacement of the adsorbent and cleaning. The maintenance signal output means 8 includes a combination of a microcomputer and a display such as an LED.

(実施の形態6)
実施の形態1乃至5のいずれかと同じ部分は同一番号を附し、詳細な説明は省略する。図6は、本発明の吸着濃縮装置の構成を示すブロック図である。
(Embodiment 6)
The same parts as those in any of Embodiments 1 to 5 are denoted by the same reference numerals, and detailed description thereof is omitted. FIG. 6 is a block diagram showing the configuration of the adsorption concentration apparatus of the present invention.

図において、脱着用気体風量調整手段9は、吸脱着周期調整手段3から吸脱着周期の信号を受け、脱着用気体の風量を計算しファン5に信号を送る。ファンは、脱着用気体風量調整手段9の信号を受け、風量を調整し吸着手段1の脱着部1bに脱着用気体を送風する。   In the figure, the desorption gas air volume adjusting means 9 receives the signal of the adsorption / desorption period from the adsorption / desorption period adjusting means 3, calculates the air volume of the desorption gas, and sends a signal to the fan 5. The fan receives the signal from the desorption gas air volume adjusting means 9, adjusts the air volume, and blows the desorption gas to the desorption part 1 b of the adsorption means 1.

上記構成において、脱着用気体風量調整手段9は、脱着周期が短い場合は風量を少なく、逆に周期が長い場合は、風量を多く調整しファン5を制御する。そのため、脱着部1bから脱着されるガス濃度は、吸脱着周期が変動する場合においても安定したガス濃度を得ることが可能となる。   In the above configuration, the desorption gas air volume adjusting means 9 controls the fan 5 by adjusting the air volume to a large value when the desorption cycle is short and conversely when the cycle is long. Therefore, the gas concentration desorbed from the desorption part 1b can obtain a stable gas concentration even when the adsorption / desorption cycle varies.

(実施の形態7)
実施の形態1乃至6のいずれかと同じ部分は同一番号を附し、詳細な説明は省略する。図7は、本発明の吸着濃縮装置の構成を示すブロック図である。
(Embodiment 7)
The same parts as those in any of Embodiments 1 to 6 are denoted by the same reference numerals, and detailed description thereof is omitted. FIG. 7 is a block diagram showing the configuration of the adsorption concentration apparatus of the present invention.

図において、脱着ガス濃度測定手段10は吸着手段1の脱着部1bの出口に設置され、脱着ガスの濃度を測定する。脱着ガス濃度測定手段10で測定した脱着ガスの濃度は、脱着用気体風量調整手段9に送られる。脱着用気体風量調整手段9は、脱着ガスの濃度を受け、風量を演算しファン5に出力する。   In the figure, the desorption gas concentration measuring means 10 is installed at the outlet of the desorption portion 1b of the adsorption means 1 and measures the concentration of the desorption gas. The concentration of the desorption gas measured by the desorption gas concentration measuring means 10 is sent to the desorption gas air volume adjusting means 9. The desorption gas air volume adjusting means 9 receives the concentration of the desorption gas, calculates the air volume and outputs it to the fan 5.

上記構成において、脱着用気体風量調整手段9は脱着ガスの濃度が設定値より高い場合は、風量を増やし、逆に、設定値より脱着ガスの濃度が低い場合は、風量を減らすように調整し、ファン5を制御する。そのため、脱着ガスの濃度を安定化することができ、2次処理装置に安定した濃縮ガスを供給することが可能となる。   In the above configuration, the desorption gas air volume adjusting means 9 increases the air volume when the concentration of the desorption gas is higher than the set value, and conversely adjusts the air volume to decrease when the concentration of the desorption gas is lower than the set value. The fan 5 is controlled. Therefore, the concentration of the desorption gas can be stabilized, and a stable concentrated gas can be supplied to the secondary processing apparatus.

ここで、設定するガス濃度は、2次処理装置の性能に依存し、2次処理装置が効率的に動作できる濃度に設定することが望ましい。   Here, the gas concentration to be set depends on the performance of the secondary processing apparatus, and is desirably set to a concentration at which the secondary processing apparatus can operate efficiently.

(実施の形態8)
実施の形態1乃至7のいずれかと同じ部分は同一番号を附し、詳細な説明は省略する。図8は、本発明の吸着濃縮装置の構成を示すブロック図である。
(Embodiment 8)
The same parts as those in any of Embodiments 1 to 7 are denoted by the same reference numerals, and detailed description thereof is omitted. FIG. 8 is a block diagram showing the configuration of the adsorption concentration apparatus of the present invention.

図において、信号処理手段11は、吸着手段1の吸着部1aの入口濃度を測定する入口濃度測定手段2と出口濃度を測定する出口濃度測定手段6と脱着部1bの出口濃度を測定する脱着ガス濃度測定手段10の信号を受け、吸脱着周期と脱着用気体の風量を演算し、それぞれ吸脱着周期調整手段3と脱着用気体風量調整手段9に出力する。   In the figure, the signal processing means 11 includes an inlet concentration measuring means 2 for measuring the inlet concentration of the adsorption section 1a of the adsorption means 1, an outlet concentration measuring means 6 for measuring the outlet concentration, and a desorption gas for measuring the outlet concentration of the desorption section 1b. In response to the signal from the concentration measuring means 10, the adsorption / desorption period and the air volume of the desorption gas are calculated and output to the adsorption / desorption period adjusting means 3 and the desorption gas air volume adjusting means 9, respectively.

上記構成において、信号処理手段11は、吸着部1aの入口ガス濃度および出口ガス濃度より、処理すべきガス量と除去率、さらに脱着ガスの濃度を入力するため、総合的に最適な吸脱着周期と脱着用気体の風量を演算することができる。そのため、吸着部1aにおける除去性能の安定化と脱着ガスの濃度の安定化を確実に行うことが可能となる。   In the above configuration, the signal processing means 11 inputs the gas amount to be processed, the removal rate, and the concentration of the desorption gas from the inlet gas concentration and the outlet gas concentration of the adsorbing portion 1a. And the air volume of the desorption gas can be calculated. Therefore, it is possible to surely stabilize the removal performance and the concentration of the desorption gas in the adsorption unit 1a.

印刷や塗装、接着、化学製品製造、工業用洗浄などの揮発性有機溶剤を排出する施設に取り付けた排出ガス処理装置を効率的に運転するための排出ガス濃縮装置として有用である。また、悪臭ガスの処理装置の用途にも適用することができる。   It is useful as an exhaust gas concentration device for efficiently operating an exhaust gas treatment device attached to a facility that discharges volatile organic solvents such as printing, painting, adhesion, chemical product manufacturing, and industrial cleaning. Further, the present invention can be applied to the use of a malodor gas treatment apparatus.

本発明の実施の形態1の構成を示すブロック図The block diagram which shows the structure of Embodiment 1 of this invention. 本発明の実施の形態2の構成を示すブロック図The block diagram which shows the structure of Embodiment 2 of this invention. 本発明の実施の形態3の構成を示すブロック図The block diagram which shows the structure of Embodiment 3 of this invention. 本発明の実施の形態4の構成を示すブロック図The block diagram which shows the structure of Embodiment 4 of this invention. 本発明の実施の形態5の構成を示すブロック図The block diagram which shows the structure of Embodiment 5 of this invention. 本発明の実施の形態6の構成を示すブロック図The block diagram which shows the structure of Embodiment 6 of this invention. 本発明の実施の形態7の構成を示すブロック図The block diagram which shows the structure of Embodiment 7 of this invention 本発明の実施の形態8の構成を示すブロック図The block diagram which shows the structure of Embodiment 8 of this invention. 従来の吸着濃縮装置の構成を示すブロック図Block diagram showing the configuration of a conventional adsorption concentrator 従来の吸着濃縮装置の構成を示すブロック図Block diagram showing the configuration of a conventional adsorption concentrator 従来の吸着濃縮装置の構成を示すブロック図Block diagram showing the configuration of a conventional adsorption concentrator

符号の説明Explanation of symbols

1 吸着手段
1a 吸着部
1b 脱着部
2 入口濃度測定手段
3 吸脱着周期調整手段
5 ファン
6 出口濃度測定手段
7 濃度測定手段
8 メンテナンス信号出力手段
9 脱着用気体風量調整手段
10 脱着ガス濃度測定手段
11 信号処理手段
12 サンプリング手段
DESCRIPTION OF SYMBOLS 1 Adsorption means 1a Adsorption part 1b Desorption part 2 Inlet concentration measurement means 3 Adsorption / desorption period adjustment means 5 Fan 6 Outlet concentration measurement means 7 Concentration measurement means 8 Maintenance signal output means 9 Desorption gas air volume adjustment means 10 Desorption gas concentration measurement means 11 Signal processing means 12 Sampling means

Claims (11)

低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、吸着手段の入口濃度を測定する入口濃度測定手段と前記入口濃度測定手段の信号を受け、吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置。 The adsorbing means in which an adsorbent for adsorbing exhaust gas containing a low concentration organic solvent is disposed, and the adsorbing means comprises an adsorbing portion for adsorbing gas and a desorbing portion for desorbing the adsorbed gas, and the desorption In an adsorption concentration apparatus comprising a desorption gas supply means for supplying a desorption gas for desorbing an organic solvent adsorbed at the section, and periodically switching between the adsorption section and the desorption section, the inlet concentration of the adsorption means An adsorption concentration apparatus provided with an inlet concentration measuring means for measuring the concentration and an adsorption / desorption period adjusting means for adjusting the adsorption / desorption period upon receiving a signal from the inlet concentration measuring means. 低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、吸着手段の出口濃度を測定する出口濃度測定手段と前記出口濃度測定手段の信号を受け、吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置。 The adsorbing means in which an adsorbent for adsorbing exhaust gas containing a low concentration organic solvent is disposed, and the adsorbing means comprises an adsorbing portion for adsorbing gas and a desorbing portion for desorbing the adsorbed gas, and the desorption In an adsorption concentrating apparatus comprising a desorption gas supply means for supplying a desorption gas for desorbing an organic solvent adsorbed by the section, and periodically switching between the adsorption section and the desorption section, the outlet concentration of the adsorption means An adsorbing and concentrating apparatus comprising an outlet concentration measuring means for measuring the concentration and an adsorption / desorption period adjusting means for adjusting the adsorption / desorption period in response to a signal from the outlet concentration measuring means. 低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、前記吸着部の入口濃度を測定する入口濃度測定手段と出口濃度を測定する出口濃度測定手段と前記入口濃度測定手段と出口濃度測定手段の信号を受け吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置。 The adsorbing means in which an adsorbent for adsorbing exhaust gas containing a low concentration organic solvent is disposed, and the adsorbing means comprises an adsorbing portion for adsorbing gas and a desorbing portion for desorbing the adsorbed gas, A desorption gas supply means for supplying a desorption gas for desorbing the organic solvent adsorbed by the unit, wherein the adsorption unit is configured to periodically switch between the adsorption unit and the desorption unit, and the inlet of the adsorption unit An adsorption concentration apparatus comprising an inlet concentration measuring means for measuring concentration, an outlet concentration measuring means for measuring outlet concentration, and an adsorption / desorption cycle adjusting means for adjusting the adsorption / desorption cycle by receiving signals from the inlet concentration measuring means and the outlet concentration measuring means. . 低濃度の有機溶剤を含有する排ガスを吸着する吸着体が配設された吸着手段と前記吸着手段をガスを吸着するための吸着部と吸着したガスを脱着する脱着部とで構成し、前記脱着部で吸着された有機溶剤を脱着するための脱着用気体を供給する脱着用気体供給手段とで構成し、吸着部と脱着部を周期的に切替え動作する吸着濃縮装置において、前記吸着部の入口と出口から交互に切替えて気体をサンプリングするサンプリング手段と前記サンプリング手段でサンプリングした気体のガス濃度を測定する濃度測定手段と前記濃度測定手段の信号を受け吸脱着周期を調整する吸脱着周期調整手段を備えた吸着濃縮装置。 The adsorbing means in which an adsorbent for adsorbing exhaust gas containing a low concentration organic solvent is disposed, and the adsorbing means comprises an adsorbing portion for adsorbing gas and a desorbing portion for desorbing the adsorbed gas, and the desorption A desorption gas supply means for supplying a desorption gas for desorbing the organic solvent adsorbed by the unit, wherein the adsorption unit is configured to periodically switch between the adsorption unit and the desorption unit, and the inlet of the adsorption unit Sampling means for alternately switching from the outlet and sampling the gas, concentration measuring means for measuring the gas concentration of the gas sampled by the sampling means, and an adsorption / desorption cycle adjusting means for receiving the signal of the concentration measuring means and adjusting the adsorption / desorption period Adsorption concentrator equipped with. 出口濃度測定手段の信号もしくは、入口濃度測定手段と出口濃度測定手段の信号より、吸着体のメンテナンス時期を知らせるメンテナンス信号を出力するメンテナンス信号出力手段を備えた請求項1,2,3または4記載の吸着濃縮装置。 5. A maintenance signal output means for outputting a maintenance signal for notifying the maintenance timing of the adsorbent from the signal of the outlet concentration measuring means or the signals of the inlet concentration measuring means and the outlet concentration measuring means. Adsorption concentration equipment. 吸脱着周期調整手段で調整された吸脱着周期に応じて、脱着用気体風量調整手段により脱着用気体の風量を調整する構成とした請求項1,2,3,4、または5記載の吸着濃縮装置。 The adsorption concentration according to claim 1, 2, 3, 4, or 5, wherein the air volume of the desorption gas is adjusted by the desorption gas air volume adjustment means according to the adsorption / desorption period adjusted by the adsorption / desorption period adjustment means. apparatus. 脱着手段によって脱着した脱着ガスの濃度を測定する脱着ガス濃度測定手段を備え、前記脱着ガス濃度測定手段の信号を受け、脱着ガスの濃度が定常になるように脱着用気体風量調整手段により脱着用気体の風量を調整する構成とした請求項1,2,3,4、または5記載の吸着濃縮装置。 Desorption gas concentration measuring means for measuring the concentration of the desorbed gas desorbed by the desorbing means is received, and is desorbed by the desorbing gas air volume adjusting means so as to receive a signal from the desorbing gas concentration measuring means so that the concentration of the desorbing gas becomes steady The adsorption concentrator according to claim 1, 2, 3, 4, or 5, wherein the gas flow rate is adjusted. 吸着手段の入口濃度測定手段と出口濃度測定手段と脱着ガス濃度測定手段の信号より、吸脱着周期と脱着用気体の風量を演算し、それぞれ吸脱着周期調整手段、脱着用気体風量調整手段に出力する信号処理手段を備えた請求項1,2,3,4、または5記載の吸着濃縮装置。 Calculates the adsorption / desorption cycle and desorption gas air volume from the signals of the inlet concentration measurement means, outlet concentration measurement means, and desorption gas concentration measurement means of the adsorption means, and outputs them to the adsorption / desorption period adjustment means and desorption gas air volume adjustment means, respectively. 6. The adsorption concentrating device according to claim 1, further comprising a signal processing means. 吸着手段が1つもしくは複数の吸着塔に充填された吸着体で構成された請求項1,2,3,4,5,6,7または8記載の吸着濃縮装置。 The adsorption concentrating apparatus according to claim 1, 2, 3, 4, 5, 6, 7 or 8, wherein the adsorption means comprises an adsorbent packed in one or a plurality of adsorption towers. 吸着手段が吸着ローターで構成した請求項1,2,3,4,5,6,7または8記載の吸着濃縮装置。   The adsorption concentrator according to claim 1, 2, 3, 4, 5, 6, 7 or 8, wherein the adsorption means comprises an adsorption rotor. ガス濃度を測定する濃度測定手段を半導体式ガスセンサで構成した請求項1,2,3,4,5,6,7、8,9または10記載の吸着濃縮装置。   The adsorption concentration apparatus according to claim 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10, wherein the concentration measuring means for measuring the gas concentration is constituted by a semiconductor type gas sensor.
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CN115364614A (en) * 2022-07-29 2022-11-22 国能(山东)能源环境有限公司 Adsorption-desorption control system and method for emission reduction of VOCs
WO2024100740A1 (en) * 2022-11-07 2024-05-16 日本碍子株式会社 Management device, management method, and acidic gas adsorption system
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