JP2006231423A - Surface coated cermet cutting tool with hard coating layer exerting excellent chipping resistance in high-speed intermittent cutting - Google Patents

Surface coated cermet cutting tool with hard coating layer exerting excellent chipping resistance in high-speed intermittent cutting Download PDF

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JP2006231423A
JP2006231423A JP2005045352A JP2005045352A JP2006231423A JP 2006231423 A JP2006231423 A JP 2006231423A JP 2005045352 A JP2005045352 A JP 2005045352A JP 2005045352 A JP2005045352 A JP 2005045352A JP 2006231423 A JP2006231423 A JP 2006231423A
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inclination angle
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JP4474647B2 (en
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Akira Osada
晃 長田
Keiji Nakamura
惠滋 中村
Arata Tsuchiya
新 土屋
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Mitsubishi Materials Corp
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<P>PROBLEM TO BE SOLVED: To provide a surface coated cermet cutting tool with a hard coating layer exerting excellent chipping resistance in high-speed intermittent cutting. <P>SOLUTION: This cutting tool has the hard coating layer formed on a surface of a tool base body. The hard coating layer is constituted of the following (a) to (d) layers: (a) a TiN layer having an average layer thickness of 0.1 to 2 μm as a base adhesive layer, (b) a TiCN layer having an average layer thickness of 3 to 20 μm as a lower layer, (c) a Ti compound layer composed of one or more layers of a TiC layer, a TiN layer, a TiCO layer and a TiCNO layer and having a total average layer thickness of 0.1 to 3 μm as an intermediate layer, and (d) a Al<SB>2</SB>O<SB>3</SB>layer having an average layer thickness of 1 to 15 μm as an upper layer. A modified TiCN layer showing a specific inclination angle frequency distribution graph as the lower layer of the (b) is constituted by interposing a modified WC layer having an average layer thickness of 0.1 to 2 μm and having vertical direction feathery growing structures by an observation by a transmission type electron microscope between the base adhesive layer of the (a) and the lower layer of the (b). <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

この発明は、特に鋼や鋳鉄などの高速断続切削加工で、硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具(以下、被覆サーメット工具という)に関するものである。   The present invention relates to a surface-coated cermet cutting tool (hereinafter referred to as a coated cermet tool) that exhibits excellent chipping resistance with a hard coating layer, particularly in high-speed intermittent cutting of steel or cast iron.

従来、一般に、炭化タングステン(以下、WCで示す)基超硬合金または炭窒化チタン(以下、TiCNで示す)基サーメットで構成された基体(以下、これらを総称して工具基体という)の表面に、
(a)下地密着層として、0.1〜2μmの平均層厚を有する化学蒸着形成された窒化チタン(以下、TiNで示す)層、
(b)下部層として、3〜20μmの平均層厚を有する化学蒸着形成された炭窒化チタン(以下、TiCNで示す)層、
(c)中間層として、いずれも化学蒸着形成されたTiの炭化物(以下、TiCで示す)層、窒化物(以下、同じくTiNで示す)層、炭酸化物(以下、TiCOで示す)層、および炭窒酸化物(以下、TiCNOで示す)のうちの1層以上からなり、かつ0.1〜3μmの合計平均層厚を有するTi化合物層、
(d)上部層として、1〜15μmの平均層厚を有する化学蒸着形成された酸化アルミニウム(以下、Al23で示す)層、
以上(a)〜(d)で構成された硬質被覆層を形成してなる被覆サーメット工具が知られており、この被覆サーメット工具が、例えば各種の鋼や鋳鉄などの連続切削や断続切削に用いられていることも知られている。
特開平6−31503号公報
Conventionally, generally on the surface of a substrate (hereinafter collectively referred to as a tool substrate) composed of a tungsten carbide (hereinafter referred to as WC) -based cemented carbide or titanium carbonitride (hereinafter referred to as TiCN) -based cermet. ,
(A) a titanium nitride (hereinafter referred to as TiN) layer formed by chemical vapor deposition having an average layer thickness of 0.1 to 2 μm as a base adhesion layer;
(B) As a lower layer, a chemical vapor deposited titanium carbonitride (hereinafter referred to as TiCN) layer having an average layer thickness of 3 to 20 μm,
(C) Ti carbide (hereinafter referred to as TiC) layer, nitride (hereinafter also referred to as TiN) layer, carbonate (hereinafter referred to as TiCO) layer formed by chemical vapor deposition, all as an intermediate layer, and Ti compound layer composed of one or more layers of carbonitride oxide (hereinafter referred to as TiCNO) and having a total average layer thickness of 0.1 to 3 μm,
(D) As an upper layer, a chemical vapor deposited aluminum oxide (hereinafter referred to as Al 2 O 3 ) layer having an average layer thickness of 1 to 15 μm,
A coated cermet tool formed by forming a hard coating layer composed of (a) to (d) above is known, and this coated cermet tool is used for continuous cutting and intermittent cutting of various steels and cast irons, for example. It is also known that
Japanese Unexamined Patent Publication No. 6-31503

近年の切削装置の高性能化はめざましく、一方で切削加工に対する省力化および省エネ化、さらに低コスト化の要求は強く、これに伴い、切削加工は一段と高速化の傾向にあるが、上記の従来被覆サーメット工具においては、これを鋼や鋳鉄などの通常の条件での連続切削や断続切削に用いた場合には問題はないが、特にこれを切削条件の最も厳しい高速断続切削、すなわち切刃部にきわめて短いピッチで繰り返し機械的衝撃の加わる高速断続切削に用いた場合、これを構成する硬質被覆層は下部層のTiCN層による高温強度、同上部層のAl23層による高温硬さおよび耐熱性を具備するものの、前記TiCN層による高温強度が不十分であるために、機械的衝撃に対して満足に対応することができず、この結果硬質被覆層にはチッピング(微小欠け)が発生し易くなることから、比較的短時間で使用寿命に至るのが現状である。 In recent years, the performance of cutting machines has been remarkable. On the other hand, there is a strong demand for labor saving, energy saving, and cost reduction for cutting work, and along with this, cutting work tends to be further accelerated. For coated cermet tools, there is no problem when this is used for continuous cutting and interrupted cutting under normal conditions such as steel and cast iron. When it is used for high-speed interrupted cutting that is repeatedly subjected to mechanical impact at a very short pitch, the hard coating layer constituting this has high temperature strength due to the TiCN layer of the lower layer, high temperature hardness due to the Al 2 O 3 layer of the upper layer, and Although it has heat resistance, the TiCN layer has insufficient high-temperature strength, so it cannot respond satisfactorily to mechanical impacts. As a result, the hard coating layer has no chipping. Since the grayed (minute chipping) tends to occur, at present, leading to a relatively short time service life.

そこで、本発明者等は、上述のような観点から、上記の被覆サーメット工具の硬質被覆層の耐チッピング性向上をはかるべく、これの下部層であるTiCN層に着目し、研究を行った結果、
(a)上記の被覆サーメット工具の硬質被覆層を通常の化学蒸着装置で形成するに際して、構成層である下地密着層のTiN層を通常の条件で形成した後で、これに、同じく通常の化学蒸着装置で、
反応ガス組成−体積%で、WF:0.04〜0.4%、CHCN:0.04〜0.4%:、H:40〜80%、Ar:残り、
反応雰囲気温度:920〜1050℃、
反応雰囲気圧力:5〜30kPa、
の条件で、炭化タングステン(以下、WCで示す)層を0.1〜2μmの平均層厚で形成すると、この結果のWC層(以下、「改質WC層」という)は、透過型電子顕微鏡による縦断面組織観察で、図1に例示される通り[なお、図1は、実施例における本発明被覆サーメット工具4の硬質被覆層を構成する改質WC層の透過型電子顕微鏡(倍率:5万倍)による縦断面組織を示すものであり、図1の上方が表面側、下方が工具基体側となる]、縦方向羽毛状成長組織を有するものとなること。
In view of the above, the inventors of the present invention focused on the TiCN layer, which is the lower layer, in order to improve the chipping resistance of the hard coating layer of the above coated cermet tool. ,
(A) When forming the hard coating layer of the above coated cermet tool with a normal chemical vapor deposition apparatus, after forming the TiN layer of the base adhesion layer as a constituent layer under normal conditions, With a vapor deposition device,
Reaction gas composition - by volume%, WF 6: 0.04~0.4%, CH 3 CN: 0.04~0.4% :, H 2: 40~80%, Ar: the remaining,
Reaction atmosphere temperature: 920-1050 ° C.
Reaction atmosphere pressure: 5 to 30 kPa,
When a tungsten carbide (hereinafter referred to as WC) layer is formed with an average layer thickness of 0.1 to 2 μm under the above conditions, the resulting WC layer (hereinafter referred to as “modified WC layer”) is a transmission electron microscope. As shown in FIG. 1, the transmission electron microscope (magnification: 5) shows the modified WC layer constituting the hard coating layer of the coated cermet tool 4 of the present invention in the example. 1), the upper side of FIG. 1 is the surface side and the lower side is the tool base side], and has a vertical feather-like growth structure.

(b)上記の縦方向羽毛状成長組織を有する改質WC層の上に、通常の条件で下部層としてTiCN層を化学蒸着形成すると、この結果形成されたTiCN層(以下、「改質TiCN層」という)は、改質層として介在させた前記改質WC層の履歴作用で、上記の従来硬質被覆層で下地密着層であるTiN層の上に同じく通常の条件で下部層として化学蒸着形成されたTiCN層(以下、「従来TiCN層」という)に比して、一段とすぐれた高温強度を有し、すぐれた耐機械的衝撃性を具備するようになることから、硬質被覆層の上部層が前記Al23層、下部層が前記改質TiCN層からなる被覆サーメット工具は、特に激しい機械的衝撃を伴なう高速断続切削加工でも、前記硬質被覆層がすぐれた耐チッピング性を発揮し、長期に亘ってすぐれた耐摩耗性を示すようになること。 (B) When a TiCN layer is formed by chemical vapor deposition as a lower layer under a normal condition on the modified WC layer having the vertical feather-like growth structure, the resulting TiCN layer (hereinafter, “modified TiCN”) is formed. Layer ”) is a history action of the modified WC layer interposed as a modified layer, and is a chemical vapor deposition as a lower layer under the same normal conditions on the TiN layer which is a base adhesion layer in the conventional hard coating layer. Compared to the formed TiCN layer (hereinafter referred to as “conventional TiCN layer”), it has a higher high-temperature strength and superior mechanical impact resistance. The coated cermet tool comprising the Al 2 O 3 layer as the layer and the modified TiCN layer as the lower layer has excellent chipping resistance even in high-speed intermittent cutting with a severe mechanical impact. Demonstrate and long-term It exhibits a superior wear resistance Te.

(c)上記の従来TiCN層と改質TiCN層について、電界放出型走査電子顕微鏡を用い、図2(a),(b)に概略説明図で示される通り、表面研磨面の測定範囲内に存在する立方晶結晶格子を有する結晶粒個々に電子線を照射して、前記表面研磨面の法線に対して、前記結晶粒の結晶面である{112}面の法線がなす傾斜角を測定し、前記測定傾斜角のうち、0〜45度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計してなる傾斜角度数分布グラフを作成した場合、前記従来TiCN層は、図4に例示される通り、{112}面の測定傾斜角の分布が0〜45度の範囲内で不偏的な傾斜角度数分布グラフを示すのに対して、前記改質TiCN層は、図3に例示される通り、0〜10度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記0〜10度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の50%以上の割合を占める傾斜角度数分布グラフを示すこと。 (C) Using the field emission scanning electron microscope, the conventional TiCN layer and the modified TiCN layer are within the measurement range of the surface polished surface as shown in the schematic explanatory diagrams of FIGS. 2 (a) and 2 (b). An electron beam is irradiated to each of the crystal grains having a cubic crystal lattice, and an inclination angle formed by a normal of the {112} plane that is a crystal plane of the crystal grain is set with respect to a normal of the surface polished surface. Measured and divided the measured inclination angle within the range of 0 to 45 degrees among the measured inclination angles for each pitch of 0.25 degrees, and the number of inclination angles obtained by totalizing the frequencies existing in each section When a distribution graph is created, the conventional TiCN layer shows an unbiased inclination angle number distribution graph within the range of the measured inclination angle of the {112} plane within the range of 0 to 45 degrees as illustrated in FIG. On the other hand, the modified TiCN layer has 0 to 0 as illustrated in FIG. The highest peak exists in the inclination angle section within the range of 0 degrees, and the total of the frequencies existing in the range of 0 to 10 degrees accounts for 50% or more of the total degrees in the inclination angle frequency distribution graph. Show the angle distribution graph.

(c)上記の下部層としての改質TiCN層は、上記の通り、改質層として形成した縦方向羽毛状成長組織を有する改質WC層の上に化学蒸着することにより形成されるが、前記改質WC層の形成条件のうち、いずれかの条件が上記の条件範囲から外れても縦方向羽毛状成長組織を有する改質WC層の形成はできなくなり、この場合0〜10度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記0〜10度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の50%以上の割合を占める傾斜角度数分布グラフを示す、すなわちすぐれた高温強度を有する改質TiCN層の形成は不可能となること。
以上(a)〜(c)に示される研究結果を得たのである。
(C) The modified TiCN layer as the lower layer is formed by chemical vapor deposition on the modified WC layer having the vertical feather-like growth structure formed as the modified layer as described above. Even if any of the conditions for forming the modified WC layer deviates from the above condition range, the modified WC layer having a vertical feather-like growth structure cannot be formed, and in this case, the range of 0 to 10 degrees. An inclination angle number distribution graph in which the highest peak exists in the inclination angle section and the total of the frequencies existing in the range of 0 to 10 degrees occupies 50% or more of the entire frequency in the inclination angle distribution graph. That is, it is impossible to form a modified TiCN layer having excellent high-temperature strength.
The research results shown in (a) to (c) above were obtained.

この発明は、上記の研究結果に基づいてなされたものであって、WC基超硬合金またはTiCN基サーメットで構成された工具基体の表面に、
(a)下地密着層として、0.1〜2μmの平均層厚を有する化学蒸着形成されたTiN層、
(b)下部層として、3〜20μmの平均層厚を有する化学蒸着形成されたTiCN層、
(c)中間層として、いずれも化学蒸着形成された、TiC層、TiN層、TiCO層、およびTiCNO層のうちの1層以上からなり、かつ0.1〜3μmの合計平均層厚を有するTi化合物層、
(d)上部層として、1〜15μmの平均層厚を有する化学蒸着形成されたAl層、
以上(a)〜(d)で構成された硬質被覆層を形成してなる表面被覆サーメット製切削工具において、
上記(a)の下地密着層と上記(b)の下部層との間に、0.1〜2μmの平均層厚を有し、かつ透過型電子顕微鏡による縦断面組織観察で、縦方向羽毛状成長組織を有する化学蒸着形成された改質WC層、
を改質層として介在させて、上記(b)の下部層としてのTiCN層を、
電界放出型走査電子顕微鏡を用い、表面研磨面の測定範囲内に存在する立方晶結晶格子を有する結晶粒個々に電子線を照射して、前記表面研磨面の法線に対して、前記結晶粒の結晶面である{112}面の法線がなす傾斜角を測定し、前記測定傾斜角のうち、0〜45度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計してなる傾斜角度数分布グラフにおいて、0〜10度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記0〜10度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の50%以上の割合を占める傾斜角度数分布グラフを示す改質TiCN層、
としてなる、高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する被覆サーメット工具に特徴を有するものである。
The present invention has been made based on the above research results, and on the surface of a tool base composed of a WC-based cemented carbide or TiCN-based cermet,
(A) TiN layer formed by chemical vapor deposition having an average layer thickness of 0.1 to 2 μm as a base adhesion layer,
(B) TiCN layer formed by chemical vapor deposition having an average layer thickness of 3 to 20 μm as a lower layer;
(C) Ti having a total average layer thickness of 0.1 to 3 μm, which is formed of one or more of a TiC layer, a TiN layer, a TiCO layer, and a TiCNO layer, all formed by chemical vapor deposition as an intermediate layer Compound layer,
(D) Al 2 O 3 layer formed by chemical vapor deposition having an average layer thickness of 1 to 15 μm as an upper layer,
In the surface-coated cermet cutting tool formed by forming the hard coating layer composed of (a) to (d) above,
Between the base adhesion layer of the above (a) and the lower layer of the above (b), it has an average layer thickness of 0.1 to 2 [mu] m, and has a longitudinal feather shape by observing the longitudinal sectional structure with a transmission electron microscope. A modified WC layer formed by chemical vapor deposition having a growth structure;
And a TiCN layer as a lower layer of (b) above,
Using a field emission scanning electron microscope, each crystal grain having a cubic crystal lattice existing within the measurement range of the surface polished surface is irradiated with an electron beam, and the crystal grain is normal to the surface polished surface. The tilt angle formed by the normal of the {112} plane, which is the crystal plane, is measured, and, among the measured tilt angles, the measured tilt angles within the range of 0 to 45 degrees are classified for each pitch of 0.25 degrees. In addition, in the inclination angle number distribution graph obtained by summing up the frequencies existing in each section, the highest peak exists in the inclination angle section within the range of 0 to 10 degrees and also exists within the range of 0 to 10 degrees. A modified TiCN layer showing a tilt angle frequency distribution graph in which the total frequency to be accounted for 50% or more of the total frequency in the tilt angle frequency distribution graph,
It is characterized by a coated cermet tool that exhibits excellent chipping resistance with a hard coating layer in high-speed intermittent cutting.

つぎに、この発明の被覆サーメット工具の硬質被覆層の構成層について、その平均層厚を上記の通りに限定した理由を以下に説明する。
(a)TiN層(下地密着層)
TiN層には、下地密着層として、工具基体および上記改質WC層のいずれにも強固に密着し、硬質被覆層の工具基体表面に対する密着性を向上させる作用を有するが、その平均層厚が0.1μm未満では所望の密着性向上効果が得られず、一方、密着性向上効果は平均層厚で2μmまでで充分であることから、その平均層厚を0.1〜2μmと定めた。
Next, the reason why the average layer thickness of the hard coating layer of the coated cermet tool of the present invention is limited as described above will be described below.
(A) TiN layer (base adhesion layer)
The TiN layer has a function of improving the adhesion of the hard coating layer to the surface of the tool substrate, as an underlying adhesion layer, firmly adhering to both the tool substrate and the modified WC layer. If the thickness is less than 0.1 μm, the desired adhesion improving effect cannot be obtained. On the other hand, the average layer thickness is determined to be 0.1 to 2 μm because an average layer thickness of 2 μm is sufficient.

(b)改質WC層(改質層)
上記改質WC層には、下地密着層であるTiN層および下部層の改質TiCN層のいずれにも強固に密着し、硬質被覆層の工具基体表面に対する密着性を向上させると共に、上記の通り自身の有する縦方向羽毛状成長組織が、これに通常の条件で蒸着形成される下部層としてのTiCN層の性質に著しい履歴効果を及ぼし、この結果蒸着形成された前記TiCN層は改質されて一段とすぐれた高温強度を具備する、すなわち、0〜10度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記0〜10度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の50%以上の割合を占める傾斜角度数分布グラフを示すようになる作用を有するが、その平均層厚が0.1μm未満では前記作用に所望の効果が得られず、一方、その平均層厚が2μmを越えると、この部分が脆化層として作用する場合が生じるようになり、チッピング発生の原因となることから、その平均層厚を0.1〜2μmと定めた。
(B) Modified WC layer (modified layer)
The modified WC layer is firmly adhered to both the TiN layer as the underlying adhesion layer and the modified TiCN layer of the lower layer, improving the adhesion of the hard coating layer to the tool substrate surface, as described above. The longitudinal feather-like growth structure that it has has a significant history effect on the properties of the TiCN layer as a lower layer deposited under normal conditions. As a result, the deposited TiCN layer is modified. It has excellent high-temperature strength, that is, the highest peak exists in the inclination angle section within the range of 0 to 10 degrees, and the sum of the frequencies existing in the range of 0 to 10 degrees is the inclination angle number distribution. In the graph, it has an action to show an inclination angle frequency distribution graph occupying a ratio of 50% or more of the entire frequency, but if the average layer thickness is less than 0.1 μm, a desired effect cannot be obtained in the action, On the other hand, if the average layer thickness exceeds 2 μm, this part may act as an embrittlement layer, which causes chipping. Therefore, the average layer thickness is set to 0.1 to 2 μm. .

(c)改質TiCN層(下部層)
上記の通り、改質WC層を上記の蒸着条件で形成することにより縦方向羽毛状成長組織を具備せしめ、前記改質WC層のもつ縦方向羽毛状成長組織による履歴作用で、これに蒸着形成されるTiCN層は改質されて、0〜10度の傾斜角区分範囲内に測定傾斜角の最高ピークが現れ、かつ前記0〜10度の傾斜角区分内に存在する度数の合計割合が、傾斜角度数分布グラフにおける度数全体の50%以上となる傾斜角度数分布グラフを示すようになり、この結果として一段とすぐれた高温強度を具備するようになるが、その平均層厚が3μm未満では所望のすぐれた高温強度を硬質被覆層に具備せしめることができず、一方その平均層厚が20μmを越えると、偏摩耗の原因となる熱塑性変形が発生し易くなり、摩耗が加速するようになることから、その平均層厚を3〜20μmと定めた。
(C) Modified TiCN layer (lower layer)
As described above, by forming the modified WC layer under the above-described deposition conditions, a vertical feather-like growth structure is provided, and by the hysteresis action by the vertical feather-like growth structure of the modified WC layer, vapor deposition is formed on this. The TiCN layer is modified so that the highest peak of the measured tilt angle appears in the tilt angle section range of 0 to 10 degrees, and the total ratio of the frequencies existing in the tilt angle section of 0 to 10 degrees is An inclination angle number distribution graph showing 50% or more of the entire frequency in the inclination angle number distribution graph is shown, and as a result, the high temperature strength is further improved. However, if the average layer thickness is less than 3 μm, it is desirable. The hard coating layer cannot be provided with excellent high-temperature strength. On the other hand, when the average layer thickness exceeds 20 μm, thermoplastic deformation that causes uneven wear tends to occur, and wear is accelerated. Therefore, the average layer thickness was determined to be 3 to 20 μm.

(d)Ti化合物層(中間層)
Ti化合物層は、主に下部層の改質TiCN層と上部層であるAl23層のいずれにも強固に密着し、よって硬質被覆層の工具基体に対する密着性向上に寄与する作用をもつが、その合計平均層厚が0.1μm未満では所望の密着性向上効果が得られず、一方、密着性向上効果は合計平均層厚で3μmまでで充分であることから、その合計平均層厚を0.1〜3μmと定めた。
(D) Ti compound layer (intermediate layer)
The Ti compound layer mainly adheres firmly to both the modified TiCN layer as the lower layer and the Al 2 O 3 layer as the upper layer, and thus has an effect of contributing to improved adhesion of the hard coating layer to the tool substrate. However, if the total average layer thickness is less than 0.1 μm, the desired effect of improving the adhesion cannot be obtained. On the other hand, the total average layer thickness is sufficient because the total average layer thickness is 3 μm. Was determined to be 0.1 to 3 μm.

(e)Al23層(上部層)
Al23層は、すぐれた高温硬さと耐熱性を有し、硬質被覆層の耐摩耗性向上に寄与するが、その平均層厚が1μm未満では、硬質被覆層に十分な耐摩耗性を発揮せしめることができず、一方その平均層厚が15μmを越えて厚くなりすぎると、チッピングが発生し易くなることから、その平均層厚を1〜15μmと定めた。
(E) Al 2 O 3 layer (upper layer)
The Al 2 O 3 layer has excellent high-temperature hardness and heat resistance, and contributes to improving the wear resistance of the hard coating layer. However, if the average layer thickness is less than 1 μm, the hard coating layer has sufficient wear resistance. On the other hand, if the average layer thickness exceeds 15 μm and becomes too thick, chipping tends to occur. Therefore, the average layer thickness is set to 1 to 15 μm.

なお、切削工具の使用前後の識別を目的として、硬質被覆層の最表面層として黄金色の色調を有するTiN層を、必要に応じて蒸着形成してもよいが、この場合の平均層厚は0.1〜1μmでよく、これは0.1μm未満では、十分な識別効果が得られず、一方前記TiN層による前記識別効果は1μmまでの平均層厚で十分であるという理由からである。   In addition, for the purpose of identification before and after the use of the cutting tool, a TiN layer having a golden color tone may be vapor-deposited as necessary as the outermost surface layer of the hard coating layer, but the average layer thickness in this case is It may be 0.1 to 1 μm, and if the thickness is less than 0.1 μm, a sufficient discrimination effect cannot be obtained, while the discrimination effect by the TiN layer is sufficient for an average layer thickness of up to 1 μm.

この発明被覆サーメット工具は、機械的熱的衝撃がきわめて高い鋼や鋳鉄などの高速断続切削でも、硬質被覆層の下部層を構成する改質TiCN層が一段とすぐれた高温強度を有し、すぐれた耐チッピング性を発揮することから、硬質被覆層にチッピングの発生なく、すぐれた耐摩耗性を示すものである。   The coated cermet tool according to the present invention has excellent high-temperature strength with the modified TiCN layer constituting the lower layer of the hard coating layer even in high-speed intermittent cutting such as steel and cast iron with extremely high mechanical and thermal shock. Since it exhibits chipping resistance, the hard coating layer exhibits excellent wear resistance without occurrence of chipping.

つぎに、この発明の被覆サーメット工具を実施例により具体的に説明する。   Next, the coated cermet tool of the present invention will be specifically described with reference to examples.

原料粉末として、いずれも1〜3μmの平均粒径を有するWC粉末、TiC粉末、ZrC粉末、VC粉末、TaC粉末、NbC粉末、Cr32粉末、TiN粉末、TaN粉末、およびCo粉末を用意し、これら原料粉末を、表1に示される配合組成に配合し、さらにワックスを加えてアセトン中で24時間ボールミル混合し、減圧乾燥した後、98MPaの圧力で所定形状の圧粉体にプレス成形し、この圧粉体を5Paの真空中、1370〜1470℃の範囲内の所定の温度に1時間保持の条件で真空焼結し、焼結後、切刃部にR:0.07mmのホーニング加工を施すことによりISO・CNMG120408に規定するスローアウエイチップ形状をもったWC基超硬合金製の工具基体A〜Fをそれぞれ製造した。 WC powder, TiC powder, ZrC powder, VC powder, TaC powder, NbC powder, Cr 3 C 2 powder, TiN powder, TaN powder, and Co powder all having an average particle diameter of 1 to 3 μm are prepared as raw material powders. These raw material powders were blended into the composition shown in Table 1, added with wax, ball milled in acetone for 24 hours, dried under reduced pressure, and pressed into a green compact with a predetermined shape at a pressure of 98 MPa. The green compact was vacuum sintered at a predetermined temperature in the range of 1370 to 1470 ° C. for 1 hour in a vacuum of 5 Pa. After sintering, the cutting edge portion was R: 0.07 mm honing By performing the processing, tool bases A to F made of a WC-base cemented carbide having a throwaway tip shape specified in ISO · CNMG120408 were manufactured.

また、原料粉末として、いずれも0.5〜2μmの平均粒径を有するTiCN(質量比で、TiC/TiN=50/50)粉末、Mo2C粉末、ZrC粉末、NbC粉末、TaC粉末、WC粉末、Co粉末、およびNi粉末を用意し、これら原料粉末を、表2に示される配合組成に配合し、ボールミルで24時間湿式混合し、乾燥した後、98MPaの圧力で圧粉体にプレス成形し、この圧粉体を1.3kPaの窒素雰囲気中、温度:1540℃に1時間保持の条件で焼結し、焼結後、切刃部分にR:0.07mmのホーニング加工を施すことによりISO規格・CNMG120412のチップ形状をもったTiCN基サーメット製の工具基体a〜fを形成した。 Further, as raw material powders, TiCN (mass ratio, TiC / TiN = 50/50) powder, Mo 2 C powder, ZrC powder, NbC powder, TaC powder, WC, all having an average particle diameter of 0.5 to 2 μm. Prepare powder, Co powder, and Ni powder, blend these raw material powders into the composition shown in Table 2, wet mix with a ball mill for 24 hours, dry, and press-mold into a green compact at 98 MPa pressure The green compact is sintered in a nitrogen atmosphere of 1.3 kPa at a temperature of 1540 ° C. for 1 hour, and after sintering, the cutting edge portion is subjected to a honing process of R: 0.07 mm. Tool bases a to f made of TiCN-based cermet having a chip shape conforming to ISO standards / CNMG 120212 were formed.

つぎに、これらの工具基体A〜Fおよび工具基体a〜fの表面に、通常の化学蒸着装置を用い、表3に示される条件で、かつ表5に示される目標層厚で下地密着層としてのTiN層を蒸着形成し、さらに表3,4に示される条件で、かつ表5に示される組み合わせ並びに目標層厚で、改質層である改質WC層(a)〜(m)、および下部層としてのTiCN層を蒸着形成して、これを改質TiCN層とし、ついで同じく表3に示される条件にて、中間層としてのTi化合物と上部層のAl23層を同じく表5に示される組み合わせで、かつ目標層厚で蒸着形成することにより本発明被覆サーメット工具1〜13をそれぞれ製造した。 Next, on the surface of these tool bases A to F and tool bases a to f, using a normal chemical vapor deposition apparatus, the conditions shown in Table 3 and the target layer thickness shown in Table 5 are used as the base adhesion layer. The modified WC layers (a) to (m), which are modified layers, under the conditions shown in Tables 3 and 4 and the combinations and target layer thicknesses shown in Table 5; A TiCN layer as a lower layer is formed by vapor deposition, and this is used as a modified TiCN layer. Then, under the conditions shown in Table 3, the Ti compound as the intermediate layer and the Al 2 O 3 layer as the upper layer are also shown in Table 5. The coated cermet tools 1 to 13 of the present invention were produced by vapor deposition with the combination shown in FIG.

また、比較の目的で、表6に示される通りの組み合わせ並びに目標層厚で、硬質被覆層の下地密着層であるTiN層および下部層であるTiCN層(従来TiCN層)を表3に示される条件で蒸着形成し、さらに同じく表3に示される条件で、中間層としてのTi化合物と上部層のAl23層を同じく表6に示される組み合わせで、かつ目標層厚で蒸着形成することにより従来被覆サーメット工具1〜13をそれぞれ製造した。 For comparison purposes, Table 3 shows the TiN layer that is the base adhesion layer of the hard coating layer and the TiCN layer that is the lower layer (conventional TiCN layer) with the combinations and target layer thicknesses shown in Table 6. Vapor deposition is performed under the conditions shown in Table 3, and the Ti compound as the intermediate layer and the Al 2 O 3 layer as the upper layer are also vapor-deposited with the combination shown in Table 6 and with the target layer thickness. Thus, conventionally coated cermet tools 1 to 13 were produced.

ついで、上記の本発明被覆サーメット工具と従来被覆サーメット工具の硬質被覆層を構成する改質TiCN層および従来TiCN層について、電界放出型走査電子顕微鏡を用いて、傾斜角度数分布グラフをそれぞれ作成した。
すなわち、上記傾斜角度数分布グラフは、上記の改質TiCN層および従来TiCN層の表面を研磨面とした状態で、電界放出型走査電子顕微鏡の鏡筒内にセットし、前記研磨面に70度の入射角度で15kVの加速電圧の電子線を1nAの照射電流で、前記表面研磨面の測定範囲内に存在する立方晶結晶格子を有する結晶粒個々に照射して、電子後方散乱回折像装置を用い、30×50μmの領域を0.1μm/stepの間隔で、前記表面研磨面の法線に対して、前記結晶粒の結晶面である{112}面の法線がなす傾斜角を測定し、この測定結果に基づいて、前記測定傾斜角のうち、0〜45度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計することにより作成した。
Next, an inclination angle number distribution graph was prepared for each of the modified TiCN layer and the conventional TiCN layer constituting the hard coating layer of the above-described coated cermet tool of the present invention and the conventional coated cermet tool using a field emission scanning electron microscope. .
That is, the tilt angle number distribution graph is set in a lens barrel of a field emission scanning electron microscope with the surfaces of the modified TiCN layer and the conventional TiCN layer being polished surfaces, and 70 ° on the polished surface. An electron backscatter diffraction imaging apparatus is irradiated by irradiating an electron beam with an acceleration voltage of 15 kV at an incident angle of 1 nA with an irradiation current of 1 nA on each crystal grain having a cubic crystal lattice existing within the measurement range of the polished surface. Using a 30 × 50 μm region at an interval of 0.1 μm / step, the inclination angle formed by the normal of the {112} plane, which is the crystal plane of the crystal grain, is measured with respect to the normal of the polished surface. Based on this measurement result, among the measured tilt angles, the measured tilt angles within the range of 0 to 45 degrees are divided for each pitch of 0.25 degrees, and the frequencies existing in each section are tabulated. Created by.

この結果得られた各種の改質TiCN層および従来TiCN層の傾斜角度数分布グラフにおいて、{112}面が最高ピークを示す傾斜角区分、並びに0〜10度の範囲内の傾斜角区分内に存在する傾斜角度数の傾斜角度数分布グラフ全体の傾斜角度数に占める割合をそれぞれ表5,6にそれぞれ示した。   In the gradient angle distribution graphs of the various modified TiCN layers and the conventional TiCN layers obtained as a result, the {112} plane has the highest peak, and the tilt angle within the range of 0 to 10 degrees. Tables 5 and 6 show the ratios of the existing inclination angle numbers to the inclination angle number distribution graph as a whole.

上記の各種の傾斜角度数分布グラフにおいて、表5,6にそれぞれ示される通り、本発明被覆サーメット工具の改質TiCN層は、いずれも{112}面の測定傾斜角の分布が0〜10度の範囲内の傾斜角区分に最高ピークが現れ、かつ0〜10度の範囲内の傾斜角区分内に存在する傾斜角度数の割合が50%以上である傾斜角度数分布グラフを示すのに対して、従来被覆サーメット工具の従来TiCN層は、いずれも{112}面の測定傾斜角の分布が0〜45度の範囲内で不偏的で、最高ピークが存在せず、0〜10度の範囲内の傾斜角区分内に存在する傾斜角度数の割合も30%以下である傾斜角度数分布グラフを示すものであった。
なお、図3は、本発明被覆サーメット工具4の改質TiCN層の傾斜角度数分布グラフ、図4は、従来被覆サーメット工具2の従来TiCN層の傾斜角度数分布グラフをそれぞれ示すものである。
In each of the above-mentioned various inclination angle number distribution graphs, as shown in Tables 5 and 6, each of the modified TiCN layers of the coated cermet tool of the present invention has a measured inclination angle distribution on the {112} plane of 0 to 10 degrees. In contrast to the slope angle distribution graph, the highest peak appears in the slope angle section within the range of 0 and the ratio of the slope angle numbers existing in the slope angle section within the range of 0 to 10 degrees is 50% or more. In the conventional TiCN layer of the conventional coated cermet tool, the distribution of the measured inclination angle of the {112} plane is unbiased within the range of 0 to 45 degrees, the highest peak does not exist, and the range of 0 to 10 degrees. The inclination angle number distribution graph in which the ratio of the inclination angle numbers existing in the inclination angle section is 30% or less was also shown.
FIG. 3 is a graph showing the distribution of inclination angle numbers of the modified TiCN layer of the coated cermet tool 4 of the present invention, and FIG. 4 is a graph showing the distribution of inclination angle numbers of the conventional TiCN layer of the conventional coated cermet tool 2.

さらに、上記の本発明被覆サーメット工具1〜13について、これの硬質被覆層の構成層である改質WC層の縦断面を透過型電子顕微鏡を用いて測定したところ、前記改質WC層はいずれも縦方向羽毛状成長組織を示した。
また、上記の本発明被覆サーメット工具1〜13および従来被覆サーメット工具1〜13について、これらの硬質被覆層の構成層をそれぞれを電子線マイクロアナライザー(EPMA)およびオージェ分光分析装置を用いて観察(層の縦断面を観察)したところ、いずれの構成層もそれぞれ目標組成と実質的に同じ組成を有することが確認された。さらに、これらの被覆サーメット工具の硬質被覆層の構成層の厚さを、走査型電子顕微鏡を用いて測定(同じく縦断面測定)したところ、いずれも目標層厚と実質的に同じ平均層厚(5点測定の平均値)を示した。
Further, with respect to the above-described coated cermet tools 1 to 13 of the present invention, when the longitudinal section of the modified WC layer, which is a constituent layer of the hard coating layer, was measured using a transmission electron microscope, the modified WC layer was Also showed longitudinal feather-like growth tissue.
Further, regarding the above-described coated cermet tools 1 to 13 and the conventional coated cermet tools 1 to 13, the constituent layers of these hard coating layers are observed using an electron beam microanalyzer (EPMA) and an Auger spectroscopic analyzer ( As a result of observing the longitudinal section of the layer, it was confirmed that each constituent layer had substantially the same composition as the target composition. Furthermore, when the thickness of the constituent layer of the hard coating layer of these coated cermet tools was measured using a scanning electron microscope (similarly longitudinal section measurement), the average layer thickness was substantially the same as the target layer thickness ( Average value of 5-point measurement) was shown.

つぎに、上記の各種の被覆サーメット工具をいずれも工具鋼製バイトの先端部に固定治具にてネジ止めした状態で、本発明被覆サーメット工具1〜13および従来被覆サーメット工具1〜13について、
被削材:JIS・SCr420Hの長さ方向等間隔4本縦溝入り丸棒、
切削速度:420m/min、
切り込み:1.2mm、
送り:0.23mm/rev、
切削時間:10分、
の条件(切削条件A)での合金鋼の乾式高速断続切削試験(通常の切削速度は200m/min)、
被削材:JIS・S45Cの長さ方向等間隔4本縦溝入り丸棒、
切削速度:380m/min、
切り込み:1.2mm、
送り:0.22mm/rev、
切削時間:10分、
の条件(切削条件B)での炭素鋼の乾式高速断続切削試験(通常の切削速度は200m/min)、
被削材:JIS・FCD450の長さ方向等間隔4本縦溝入り丸棒、
切削速度:420m/min、
切り込み:1.5mm、
送り:0.32mm/rev、
切削時間:10分、
の条件(切削条件C)でのダクタイル鋳鉄の乾式高速断続切削試験(通常の切削速度は200m/min)を行い、いずれの切削試験でも切刃の逃げ面摩耗幅を測定した。この測定結果を表7に示した。
Next, in the state where each of the various coated cermet tools is screwed to the tip of the tool steel tool with a fixing jig, the present coated cermet tools 1 to 13 and the conventional coated cermet tools 1 to 13 are as follows.
Work material: JIS · SCr420H lengthwise equidistant 4 round bars with vertical grooves,
Cutting speed: 420 m / min,
Cutting depth: 1.2mm,
Feed: 0.23mm / rev,
Cutting time: 10 minutes,
Dry high-speed intermittent cutting test (normal cutting speed is 200 m / min) of alloy steel under the above conditions (cutting condition A),
Work material: JIS · S45C lengthwise equal 4 round grooved round bars,
Cutting speed: 380 m / min,
Cutting depth: 1.2mm,
Feed: 0.22mm / rev,
Cutting time: 10 minutes,
Dry high-speed intermittent cutting test of carbon steel under the conditions (cutting condition B) (normal cutting speed is 200 m / min),
Work material: JIS / FCD450 lengthwise equidistant round bars with 4 vertical grooves,
Cutting speed: 420 m / min,
Incision: 1.5mm,
Feed: 0.32mm / rev,
Cutting time: 10 minutes,
The dry high-speed intermittent cutting test (normal cutting speed is 200 m / min) of ductile cast iron under the above conditions (cutting condition C), and the flank wear width of the cutting edge was measured in any cutting test. The measurement results are shown in Table 7.

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Figure 2006231423
Figure 2006231423

表5〜7に示される結果から、本発明被覆サーメット工具1〜13は、いずれも硬質被覆層の下部層が、改質層である改質WC層の履歴作用で、{112}面の傾斜角が0〜10度の範囲内の傾斜角区分で最高ピークを示すと共に、前記0〜10度の傾斜角区分範囲内に存在する度数の合計割合が50%以上を占める傾斜角度数分布グラフを示す改質TiCN層で構成され、機械的衝撃がきわめて高い鋼や鋳鉄の高速断続切削でも、前記改質TiCN層がすぐれた高温強度を有し、すぐれた耐チッピング性を発揮することから、切刃部のチッピング発生が著しく抑制され、すぐれた耐摩耗性を示すのに対して、硬質被覆層の下部層が、{112}面の測定傾斜角の分布が0〜45度の範囲内で不偏的で、最高ピークが存在しない傾斜角度数分布グラフを示す従来TiCN層で構成された従来被覆サーメット工具1〜13においては、いずれも高速断続切削では硬質被覆層の耐機械的衝撃性が不十分であるために、切刃部にチッピングが発生し、比較的短時間で使用寿命に至ることが明らかである。   From the results shown in Tables 5 to 7, in the coated cermet tools 1 to 13 of the present invention, the lower layer of the hard coating layer is the history action of the modified WC layer that is the modified layer, and the inclination of the {112} plane An inclination angle distribution graph showing the highest peak in the inclination angle section within the angle range of 0 to 10 degrees, and the total ratio of the frequencies existing in the inclination angle section range of 0 to 10 degrees occupying 50% or more. Since the modified TiCN layer has excellent high-temperature strength and excellent chipping resistance even in high-speed intermittent cutting of steel or cast iron, which is composed of the modified TiCN layer shown in FIG. While the occurrence of chipping at the blade is remarkably suppressed and excellent wear resistance is exhibited, the lower layer of the hard coating layer is unbiased when the distribution of measured inclination angles on the {112} plane is within the range of 0 to 45 degrees. A few minutes of tilt angle without the highest peak In the conventional coated cermet tools 1 to 13 composed of the conventional TiCN layer shown in the graph, the mechanical impact resistance of the hard coating layer is insufficient in high-speed intermittent cutting, so chipping occurs at the cutting edge. It is clear that the service life is reached in a relatively short time.

上述のように、この発明の被覆サーメット工具は、各種鋼や鋳鉄などの通常の条件での連続切削や断続切削は勿論のこと、特に高温強度が要求される高速断続切削でもすぐれた耐チッピング性を示し、長期に亘ってすぐれた切削性能を発揮するものであるから、切削装置の高性能化並びに切削加工の省力化および省エネ化、さらに低コスト化に十分満足に対応できるものである。   As described above, the coated cermet tool of the present invention has excellent chipping resistance not only for continuous cutting and interrupted cutting under normal conditions such as various steels and cast iron, but also for high-speed interrupted cutting particularly requiring high-temperature strength. Since it exhibits excellent cutting performance over a long period of time, it can sufficiently satisfy the high performance of the cutting device, the labor saving and energy saving of the cutting work, and the cost reduction.

本発明被覆サーメット工具4の硬質被覆層を構成する改質WC層の透過型電子顕微鏡(倍率:5万倍)による縦断面組織写真(縦方向羽毛状成長組織写真)である。It is a longitudinal cross-section structure | tissue photograph (longitudinal feather-like growth structure | tissue photograph) by the transmission electron microscope (magnification: 50,000 times) of the modified WC layer which comprises the hard coating layer of this invention coated cermet tool 4. FIG. 硬質被覆層を構成する各種TiCN層における結晶粒の{112}面の傾斜角の測定範囲を示す概略説明図である。It is a schematic explanatory drawing which shows the measurement range of the inclination angle of the {112} plane of the crystal grain in the various TiCN layers which comprise a hard coating layer. 本発明被覆サーメット工具4の硬質被覆層の下部層を構成する改質TiCN層の{112}面の傾斜角度数分布グラフである。It is an inclination angle number distribution graph of the {112} plane of the modified TiCN layer constituting the lower layer of the hard coating layer of the coated cermet tool 4 of the present invention. 従来被覆サーメット工具2の硬質被覆層の下部層を構成する従来TiCNの{112}面の傾斜角度数分布グラフである。It is the inclination angle number distribution graph of the {112} plane of the conventional TiCN which comprises the lower layer of the hard coating layer of the conventional coating cermet tool 2. FIG.

Claims (1)

炭化タングステン基超硬合金または炭窒化チタン基サーメットで構成された工具基体の表面に、
(a)下地密着層として、0.1〜2μmの平均層厚を有する化学蒸着形成された窒化チタン層、
(b)下部層として、3〜20μmの平均層厚を有する化学蒸着形成された炭窒化チタン層、
(c)中間層として、いずれも化学蒸着形成されたTiの炭化物層、窒化物層、炭酸化物層、および炭窒酸化物層のうちの1層以上からなり、かつ0.1〜3μmの合計平均層厚を有するTi化合物層、
(d)上部層として、1〜15μmの平均層厚を有する化学蒸着形成された酸化アルミニウム層、
以上(a)〜(d)で構成された硬質被覆層を形成してなる表面被覆サーメット製切削工具において、
上記(a)の下地密着層と上記(b)の下部層との間に、0.1〜2μmの平均層厚を有し、かつ透過型電子顕微鏡による縦断面組織観察で、縦方向羽毛状成長組織を有する化学蒸着形成された改質炭化タングステン層、
を改質層として介在させて、前記(b)の下部層としての炭窒化チタン層を、
電界放出型走査電子顕微鏡を用い、表面研磨面の測定範囲内に存在する立方晶結晶格子を有する結晶粒個々に電子線を照射して、前記表面研磨面の法線に対して、前記結晶粒の結晶面である{112}面の法線がなす傾斜角を測定し、前記測定傾斜角のうち、0〜45度の範囲内にある測定傾斜角を0.25度のピッチ毎に区分すると共に、各区分内に存在する度数を集計してなる傾斜角度数分布グラフにおいて、0〜10度の範囲内の傾斜角区分に最高ピークが存在すると共に、前記0〜10度の範囲内に存在する度数の合計が、傾斜角度数分布グラフにおける度数全体の50%以上の割合を占める傾斜角度数分布グラフを示す改質炭窒化チタン層、
としたことを特徴とする高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具。
On the surface of the tool base composed of tungsten carbide based cemented carbide or titanium carbonitride based cermet,
(A) a titanium nitride layer formed by chemical vapor deposition having an average layer thickness of 0.1 to 2 μm as a base adhesion layer;
(B) a titanium carbonitride layer formed by chemical vapor deposition having an average layer thickness of 3 to 20 μm as a lower layer;
(C) As an intermediate layer, all consist of one or more of Ti carbide layer, nitride layer, carbonate layer, and carbonitride layer formed by chemical vapor deposition, and a total of 0.1 to 3 μm A Ti compound layer having an average layer thickness;
(D) As an upper layer, an aluminum oxide layer formed by chemical vapor deposition having an average layer thickness of 1 to 15 μm,
In the surface-coated cermet cutting tool formed by forming the hard coating layer composed of (a) to (d) above,
Between the base adhesion layer of the above (a) and the lower layer of the above (b), it has an average layer thickness of 0.1 to 2 [mu] m, and has a longitudinal feather shape by observing the longitudinal sectional structure with a transmission electron microscope. Modified tungsten carbide layer formed by chemical vapor deposition having a growth structure,
Is interposed as a modified layer, the titanium carbonitride layer as the lower layer of (b),
Using a field emission scanning electron microscope, each crystal grain having a cubic crystal lattice existing within the measurement range of the surface polished surface is irradiated with an electron beam, and the crystal grain is normal to the surface polished surface. The tilt angle formed by the normal of the {112} plane, which is the crystal plane, is measured, and, among the measured tilt angles, the measured tilt angles within the range of 0 to 45 degrees are classified for each pitch of 0.25 degrees. In addition, in the inclination angle number distribution graph obtained by summing up the frequencies existing in each section, the highest peak exists in the inclination angle section within the range of 0 to 10 degrees and also exists within the range of 0 to 10 degrees. A modified titanium carbonitride layer showing an inclination angle distribution graph in which the total frequency to be accounted for 50% or more of the entire frequency in the inclination angle distribution graph,
A surface-coated cermet cutting tool that exhibits excellent chipping resistance with a hard coating layer in high-speed intermittent cutting.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009107028A (en) * 2007-10-26 2009-05-21 Mitsubishi Materials Corp Surface-coated cutting tool having hard coating layer exhibiting excellent chipping resistance
JP2009113125A (en) * 2007-11-02 2009-05-28 Mitsubishi Materials Corp Surface-coated cutting tool having hard coating layer exhibiting excellent chipping resistance

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009107028A (en) * 2007-10-26 2009-05-21 Mitsubishi Materials Corp Surface-coated cutting tool having hard coating layer exhibiting excellent chipping resistance
JP2009113125A (en) * 2007-11-02 2009-05-28 Mitsubishi Materials Corp Surface-coated cutting tool having hard coating layer exhibiting excellent chipping resistance

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