JP2006183431A - Soil block with both water retainability and water permeability - Google Patents

Soil block with both water retainability and water permeability Download PDF

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JP2006183431A
JP2006183431A JP2004381105A JP2004381105A JP2006183431A JP 2006183431 A JP2006183431 A JP 2006183431A JP 2004381105 A JP2004381105 A JP 2004381105A JP 2004381105 A JP2004381105 A JP 2004381105A JP 2006183431 A JP2006183431 A JP 2006183431A
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water
block
water permeability
soil block
soil
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JP4662336B2 (en
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Shozo Furusawa
昭三 古沢
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NIPPON GLASS KOGYO KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a block which is composed of an inorganic material mixture which is superior both in water retainability and water permeability, has relatively small specific gravity and proper toughness, can be collapsed relatively easily after being used up, does not cause a waste disposal problem, is returned to the soil easily, and suppresses an increase in manufacturing cost. <P>SOLUTION: The soil block is a mixture of pit sand of 15 to 60 wt%, molten slug of 10 to 35 wt%, Portland cement of 5 to 15%, recycled expanded glass of 20 to 30%, and an additive such as a nonionic surface active agent and pigment. The soil block has both water retainability and water permeability. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、保水性と透水性に優れ、軽量で、且つ使用後には比較的簡単に崩壊させ、土壌に戻すことのできるブロック体に関する。 The present invention relates to a block body that is excellent in water retention and water permeability, is lightweight, can be disintegrated relatively easily after use, and can be returned to soil.

一般的に舗道等に使用されるブロックは、一定の強度を必要とされる為、堅牢ではあるが、重量物となり、又、使用後には反って廃棄物としての処理に困難を伴うことが多い。
そこで、本発明は、軽量で且つ廃棄物としての処理においてリサイクルを可能とするブロックに関するもので、その成分として山砂等により土ブロックを形成するものである。
ところで、この山砂等を使用した例としては、従来鋪装構造に関する特許文献1が存在し、その概要は、土系鋪装材と、フライアッシュとセメントを混合させて表面層とするものである。
しかし、該鋪装材においても、セメントによる強い結合力で、重量物となり、且つ、使用後には廃棄処理に困ることは従来と同様である。
特開2002−275814
In general, blocks used for pavements and the like are robust because they require a certain level of strength, but they are heavy, and often become difficult to process as waste after being warped. .
Therefore, the present invention relates to a block that is lightweight and can be recycled in the treatment as waste, and forms a soil block from mountain sand or the like as its component.
By the way, as an example using this mountain sand or the like, there is Patent Document 1 relating to a conventional outfitting structure, and the outline thereof is to make a surface layer by mixing earth-based outfitting material, fly ash and cement.
However, as in the conventional case, the outfitting material also becomes heavy due to the strong binding force of cement and is difficult to dispose of after use.
JP 2002-275814 A

本発明は上記実情に鑑みてなされたもので、組成混合物は(1)保水性と透水性に優れ、(2)比較的比重が小さく、適度な強靱性を備える無機質材料で、 (3)使用後には比較的簡単に崩壊させることができ、且つ廃棄物の問題が生じることなく、土壌に戻し易い無機質材料であると共に、製造コストを抑制しうるブロック体を提供するものである。 The present invention has been made in view of the above circumstances. The composition mixture is (1) excellent in water retention and water permeability, (2) is an inorganic material having a relatively small specific gravity and suitable toughness. The present invention provides a block body that can be easily disintegrated later and that is easy to return to the soil without causing a problem of waste and that can suppress the manufacturing cost.

上記目的を達成するために、請求項1記載の土ブロックは、重量比で山砂50〜70%、ポルトランドセメント5〜15%とリサイクル発泡ガラス20〜30%及びノニオン系界面活性剤及び顔料等の添加剤を混合させて保水性と透水性を兼備することを特徴とする。 In order to achieve the above-mentioned object, the soil block according to claim 1 is composed of mountain sand 50 to 70% by weight ratio, Portland cement 5 to 15%, recycled foamed glass 20 to 30%, nonionic surfactant and pigment, etc. It is characterized by having both water retention and water permeability by mixing these additives.

請求項2記載の土ブロックは、重量比で山砂15〜60%、溶融スラグ10〜35、ポルトランドセメント5〜15%とリサイクル発泡ガラス20〜30%及びノニオン系界面活性剤及び顔料等の添加剤を混合させて保水性と透水性を兼備することを特徴とする。   The soil block according to claim 2 is 15-60% pile sand by weight ratio, 10-35 molten slag, 5-15% Portland cement, 20-30% recycled foamed glass, nonionic surfactants, pigments, etc. It is characterized by mixing the agent and having both water retention and water permeability.

本発明の土ブロックは、山砂にポルトランドセメント、リサイクル発泡ガラス及びノニオン系界面活性剤混合させてあるので、透水性と保水性に優れ、ブロック体の軽量化と保水性を高めることができる。更に、溶融スラグを加えると、表面硬度を高めることができる。
又、土ブロックの比重が1.1〜1.3g/cm、曲げ強度が3〜4MPa程度となるので、軽量で且つ、容易に粉砕することができ、且つ、土ブロックを構成する組成物は無機質および界面活性剤であるので、廃棄物の問題を生じない。
Since the soil block of the present invention is mixed with portland cement, recycled foamed glass and nonionic surfactant in mountain sand, it is excellent in water permeability and water retention, and can reduce the weight and water retention of the block body. Furthermore, the surface hardness can be increased by adding molten slag.
Further, since the specific gravity of the soil block is 1.1 to 1.3 g / cm 3 and the bending strength is about 3 to 4 MPa, it is lightweight and can be easily pulverized and constitutes the soil block. Is a mineral and surfactant, so it does not cause waste problems.

そこで、この発明の実施の形態を、図1、図2、図3および表1に基づいて説明する。
本発明は、保水性と透水性を兼備した無機質組成物として一体化するが、その構成は、山砂、溶融スラグ、リサイクル発泡ガラス、ポルトランドセメントに、ノニオン系界面活性剤及び顔料等の添加剤から成る。
以下、該材料の特徴について記述した後、該材料で構成されるブロック1を説明する。
An embodiment of the present invention will be described with reference to FIGS. 1, 2, 3 and Table 1. FIG.
The present invention is integrated as an inorganic composition that has both water retention and water permeability. The composition of the composition is mountain sand, molten slag, recycled foam glass, Portland cement, additives such as nonionic surfactants and pigments. Consists of.
Hereinafter, after describing the characteristics of the material, the block 1 made of the material will be described.

山砂は、主として花崗岩などが風化してできた土で、火山灰などの粘土質を除いた骨材である。その粒度は、通常2mmのふるい目下のものが用いられ、図1に粒度分布状態の一例を拡大して模式的に示す。この図は、粗い粒径(2〜0.5mm)のものaと、細かい粒径(0.5〜0.075mm)のものbと、微粒径(0.075mm未満)のものcとが満遍なく分布し、各粒子間にランダムに僅かな空隙dが形成されていることを示し、ポーラス状で空気や水が保存できることを表している。透水性を高めるためには、均等係数が小さく、均一で粗い粒径の骨材を多くすることが必要であるが、コスト高となるため粒度分布を持たせて透水性の確保を図った。 Mountain sand is an aggregate made of weathered granite, excluding volcanic ash and other clays. The particle size is usually 2 mm or less, and FIG. 1 schematically shows an enlarged example of the particle size distribution state. This figure shows that a having a coarse particle size (2 to 0.5 mm), b having a fine particle size (0.5 to 0.075 mm), and c having a fine particle size (less than 0.075 mm). It is evenly distributed, and it is shown that slight voids d are randomly formed between the particles, indicating that air and water can be stored in a porous shape. In order to increase the water permeability, it is necessary to increase the aggregate having a small uniformity coefficient and a uniform and coarse particle diameter. However, since the cost is high, the water permeability is secured by providing a particle size distribution.

ポルトランドセメントは、山砂の表面を実質的に囲繞し、山砂の各粒子を結合して、多数の空隙を形成する。ポルトランドセメントは山砂その他も一体に固化し、ブロック1をポーラス状に保持する役割を担っている。しかしながら、ポルトランドセメントは骨材間の接合力を大きく保持できるが、それ自体が団子状、塊状になり易く、空隙を埋め易いので、使用量は少量が望ましい。 Portland cement substantially surrounds the surface of mountain sand and binds the particles of mountain sand to form a number of voids. Portland cement also solidifies sand and sand and plays a role of holding the block 1 in a porous shape. However, although Portland cement can maintain a large bonding force between aggregates, it is easy to form a dumpling or a lump and easily fills voids, so a small amount is desirable.

ノニオン系界面活性剤は、山砂の濡れ性を高め、山砂の表面にポルトランドセメントを均一に分散させ、水の表面張力を抑えて均一な保水と透水を可能とする性状を保有する。ポルトランドセメントが山砂の表面において均一に分散されると、ブロック体として適度な強度が現れる。一方、ポルトランドセメントが山砂の表面において不均一であると、団子状、塊状となり、強度が強くなり過ぎて破砕が困難となり、不適である。
配合剤の濡れ性や分散性を高めることを担うノニオン系界面活性剤は、例えばオーストラリアのデプコ・プティ・リミテッド社(DEBCO.PTY.LIMITED)製のサチュライドなどノニルフェニルエーテル系重合体で炭素数6〜7のものを利用することができる。
Nonionic surfactants have the property of increasing the wettability of mountain sand, uniformly dispersing Portland cement on the surface of mountain sand, and suppressing the surface tension of water to enable uniform water retention and water permeability. When Portland cement is uniformly dispersed on the surface of mountain sand, moderate strength appears as a block body. On the other hand, if the Portland cement is uneven on the surface of mountain sand, it becomes unsuitable because it becomes dumplings or lumps, and the strength becomes too strong, making it difficult to crush.
Nonionic surfactants responsible for improving the wettability and dispersibility of the compounding agent are nonylphenyl ether polymers such as saturides manufactured by DEBCO.PTY.LIMITED, Australia. ~ 7 can be used.

リサイクル発泡ガラスは、廃ガラスを粉砕して添加剤を加えて混合し、該混合物を焼成炉に入れてガラス軟化点以上に加熱発泡させたもので、ブロック体の軽量化と保水性を高める材料である。すなわち、リサイクル発泡ガラスはそれ自体が軽量な保水性セラミックスで、るつぼ状の気孔を大量に含み、急速且つ強力な吸水性と適度な蒸発性を備えているので、これを配合したブロック体は軽量となり、保水を高めるものとなる。 Recycled foam glass is a material that pulverizes waste glass, adds additives, mixes them, puts the mixture in a firing furnace and heats it to a temperature above the glass softening point, and increases the weight and water retention of the block body. It is. In other words, recycled foam glass is a lightweight water-holding ceramic itself, contains a large amount of crucible-like pores, has rapid and strong water absorption, and moderate evaporation. And increase water retention.

溶融スラグは、溶鉱炉で1400℃の高温で焼却灰を溶融して生成されるガラス質の固化物で、比重は山砂と同程度であるが、硬度が高く、山砂に換えて一定割合を混合すると、硬化後のブロック体の表面硬度を高めると共に耐摩耗性を向上させることができる。 Molten slag is a vitreous solidified product produced by melting incineration ash at a high temperature of 1400 ° C in a blast furnace, and the specific gravity is the same as mountain sand, but the hardness is high, and instead of mountain sand, a certain ratio is obtained. When mixed, the surface hardness of the block body after curing can be increased and the wear resistance can be improved.

以上に記述した各材料の特徴を踏まえ、本発明である保水性と透水性を兼備したブロック1の配合と成形方法について説明する。   Based on the characteristics of each material described above, the composition and molding method of the block 1 having both water retention and water permeability according to the present invention will be described.

表1に前記材料を含有した配合表を示す。山砂50〜70%、リサイクル発泡ガラス20〜30%、ポルトランドセメント5〜15%、ノニオン系界面活性剤及び顔料等の添加剤を含む組成混合物に水を滴下して混練し、ブロック1を形成する。 Table 1 shows a blending table containing the above materials. Block 1 is formed by dripping and kneading water into a composition mixture containing mountain sand 50 to 70%, recycled foam glass 20 to 30%, Portland cement 5 to 15%, additives such as nonionic surfactants and pigments. To do.

Figure 2006183431
Figure 2006183431

前記配合に基づき、無機質組成物のブロック体として一体化する製造方法を以下に説明する。
図2に示す通り、該組成混合物に水を加えながら撹拌機で撹拌し、ブロック1に調整し、加圧成形し、2日間養生すると、該ブロック1は自然固化し、次第に硬度を増す。図3は固化後のブロック1である。
配合剤のリサイクル発泡ガラスはそれ自体が軽量で吸水性を保持しているが、適度な蒸発性を備えているので、自然乾燥し易い。
一方、本発明ブロック体の曲げ強度は、ポルトランドセメントと山砂、発泡ガラス、ノニオン系界面活性剤の量や成形マシーンによる加圧力等で決められ、ブロック体の廃棄時にクラッシャーなどで容易に破砕できる量は、それぞれ5〜15、20〜30gが良い。この範囲であれば、本発明ブロック体の曲げ強度は、3〜4MPaに確保できる。
また、本発明の配合は、廃棄時には自然土に還元できる材料を使用し、そのままでも自然土に還元できるブロック体となっている。
上記配合に基づくブロック体の物性は、曲げ強度が3〜4MPaであり、比重は1.1〜1.3g/cmである。透水係数は1×10一4cm/sec前後を示した。
Based on the said mixing | blending, the manufacturing method integrated as a block body of an inorganic composition is demonstrated below.
As shown in FIG. 2, when water is added to the composition mixture, the mixture is stirred with a stirrer, adjusted to block 1, pressed, and cured for 2 days. The block 1 spontaneously solidifies and gradually increases in hardness. FIG. 3 shows the block 1 after solidification.
Recycled foam glass of the compound itself is lightweight and retains water absorption, but it is suitable for natural drying because it has moderate evaporation.
On the other hand, the bending strength of the block body of the present invention is determined by the amount of Portland cement and mountain sand, foam glass, nonionic surfactant, pressure applied by the molding machine, etc., and can be easily crushed with a crusher or the like when the block body is discarded. The amount is preferably 5 to 15 and 20 to 30 g, respectively. If it is this range, the bending strength of this invention block body is securable 3-4MPa.
Further, the composition of the present invention uses a material that can be reduced to natural soil at the time of disposal, and is a block body that can be reduced to natural soil as it is.
As for the physical properties of the block body based on the above formulation, the bending strength is 3 to 4 MPa, and the specific gravity is 1.1 to 1.3 g / cm 3 . Permeability showed 1 × 10 one 4 cm / sec and forth.

又、次の実施例の配合を表2に示す。 Table 2 shows the composition of the following examples.

Figure 2006183431
Figure 2006183431

本実施例2は、吸水性等は実施例1と同様であるが、溶融スラグが、、比重では山砂とほぼ同等の性状を呈し、硬度が高く、これを配合することで、 ブロック表面に硬度が上がり、耐摩耗性を向上させることができた。   In Example 2, the water absorption and the like are the same as in Example 1. However, the molten slag exhibits almost the same properties as mountain sand in specific gravity, and has high hardness. The hardness was increased and the wear resistance was improved.

本発明は、大きな荷重の加わる車道には適さないが、それを除いた歩道や公園等に広く応用することができる。 The present invention is not suitable for a roadway with a heavy load, but can be widely applied to sidewalks, parks, and the like other than that.

図1は、本発明の粒度分布状態の模式図FIG. 1 is a schematic diagram of the particle size distribution state of the present invention. 図2は、ブロック体の調整状況図Fig. 2 shows the adjustment status of the block body 図3は、脱型後のブロック体Fig. 3 shows the block body after demolding

符号の説明Explanation of symbols

a 粗い粒径
b 細かい粒径
c 微粒径
d 空隙
A 山砂
B セメント
C 空隙
A‘ 山砂
B‘ セメント
C‘ 空隙
1 ブロック体
a Coarse particle size b Fine particle size c Fine particle size d Cavity A Mountain sand B Cement C Cavity A 'Mountain sand B' Cement C 'Cavity 1 Block body

Claims (2)

重量比で山砂50〜70%、ポルトランドセメント5〜15%とリサイクル発泡ガラス20〜30%及びノニオン系界面活性剤及び顔料等の添加剤を混合させて保水性と透水性を兼備することを特徴とする土ブロック。 Mixing water sand and water permeability by mixing sand sand 50-70%, Portland cement 5-15%, recycled foamed glass 20-30%, and nonionic surfactants and pigments. A featured soil block. 重量比で山砂15〜60%、溶融スラグ10〜35、ポルトランドセメント5〜15%とリサイクル発泡ガラス20〜30%及びノニオン系界面活性剤及び顔料等の添加剤を混合させて保水性と透水性を兼備することを特徴とする土ブロック。 Water retention and water permeability by mixing 15-60% mountain sand, molten slag 10-35, Portland cement 5-15%, recycled foam glass 20-30%, and nonionic surfactants and pigments. A soil block characterized by having sex.
JP2004381105A 2004-12-28 2004-12-28 Soil block with both water retention and water permeability Expired - Fee Related JP4662336B2 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103043956A (en) * 2012-12-09 2013-04-17 广西壮族自治区建筑科学研究院 Method for preparing energy-saving wall material by utilizing waste foam glass
WO2015194958A1 (en) * 2014-06-20 2015-12-23 Ceves-Vergeer Bv Dry mortar mixture with grains of expanded glass
CN105777018A (en) * 2016-04-13 2016-07-20 广东省建筑科学研究院集团股份有限公司 Foam concrete containing recycled inorganic lightweight aggregate and preparation method thereof
US20170152182A1 (en) 2014-06-20 2017-06-01 Ceves-Vergeer Bv Dry mortar mixture with grains of expanded glass

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01230801A (en) * 1988-03-11 1989-09-14 Nippon Hodo Co Ltd Construction of adiabatic pavement structure
JP2002275814A (en) * 2001-03-19 2002-09-25 Sugawara Doboku Kk Weed preventive pavement structure

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01230801A (en) * 1988-03-11 1989-09-14 Nippon Hodo Co Ltd Construction of adiabatic pavement structure
JP2002275814A (en) * 2001-03-19 2002-09-25 Sugawara Doboku Kk Weed preventive pavement structure

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103043956A (en) * 2012-12-09 2013-04-17 广西壮族自治区建筑科学研究院 Method for preparing energy-saving wall material by utilizing waste foam glass
WO2015194958A1 (en) * 2014-06-20 2015-12-23 Ceves-Vergeer Bv Dry mortar mixture with grains of expanded glass
US20170152182A1 (en) 2014-06-20 2017-06-01 Ceves-Vergeer Bv Dry mortar mixture with grains of expanded glass
US10364186B2 (en) 2014-06-20 2019-07-30 Ceves-Vergeer Bv Dry mortar mixture with grains of expanded glass
US10662115B2 (en) 2014-06-20 2020-05-26 Ceves-Vergeer Bv Dry mortar mixture with grains of expanded glass
CN105777018A (en) * 2016-04-13 2016-07-20 广东省建筑科学研究院集团股份有限公司 Foam concrete containing recycled inorganic lightweight aggregate and preparation method thereof

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