JP2005522513A5 - - Google Patents

Download PDF

Info

Publication number
JP2005522513A5
JP2005522513A5 JP2003584070A JP2003584070A JP2005522513A5 JP 2005522513 A5 JP2005522513 A5 JP 2005522513A5 JP 2003584070 A JP2003584070 A JP 2003584070A JP 2003584070 A JP2003584070 A JP 2003584070A JP 2005522513 A5 JP2005522513 A5 JP 2005522513A5
Authority
JP
Japan
Prior art keywords
group
atoms
independently
ligand
hydrocarbyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2003584070A
Other languages
English (en)
Japanese (ja)
Other versions
JP4576126B2 (ja
JP2005522513A (ja
Filing date
Publication date
Application filed filed Critical
Priority claimed from PCT/US2003/009071 external-priority patent/WO2003087114A1/en
Publication of JP2005522513A publication Critical patent/JP2005522513A/ja
Publication of JP2005522513A5 publication Critical patent/JP2005522513A5/ja
Application granted granted Critical
Publication of JP4576126B2 publication Critical patent/JP4576126B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

JP2003584070A 2002-04-12 2003-03-24 アザボロリル4族金属錯体、触媒及びオレフィン重合方法 Expired - Fee Related JP4576126B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37246202P 2002-04-12 2002-04-12
PCT/US2003/009071 WO2003087114A1 (en) 2002-04-12 2003-03-24 Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process

Publications (3)

Publication Number Publication Date
JP2005522513A JP2005522513A (ja) 2005-07-28
JP2005522513A5 true JP2005522513A5 (enExample) 2006-05-18
JP4576126B2 JP4576126B2 (ja) 2010-11-04

Family

ID=29250858

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003584070A Expired - Fee Related JP4576126B2 (ja) 2002-04-12 2003-03-24 アザボロリル4族金属錯体、触媒及びオレフィン重合方法

Country Status (7)

Country Link
US (1) US7074865B2 (enExample)
EP (1) EP1495038B1 (enExample)
JP (1) JP4576126B2 (enExample)
AU (1) AU2003230726A1 (enExample)
CA (1) CA2480006A1 (enExample)
DE (1) DE60322365D1 (enExample)
WO (1) WO2003087114A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8283427B2 (en) * 2010-05-06 2012-10-09 Lewis Stewart P Heterogeneous perfluoroaryl substituted Lewis acid catalysts for cationic polymerizations
CN114437273B (zh) * 2020-10-30 2023-07-25 中国石油天然气股份有限公司 一种丁基橡胶的制备方法

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US5124418A (en) * 1985-11-15 1992-06-23 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5264405A (en) * 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5229478A (en) * 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5210352A (en) * 1991-05-09 1993-05-11 Phillips Petroleum Company Fluorene compounds
US5399636A (en) * 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
ES2087339T3 (es) * 1991-05-27 1996-07-16 Hoechst Ag Procedimiento para la preparacion de poliolefinas con amplia distribucion de masas moleculares.
US5594078A (en) * 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
US5391789A (en) * 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
TW300901B (enExample) * 1991-08-26 1997-03-21 Hoechst Ag
EP0537686B1 (de) * 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
ATE141609T1 (de) 1991-11-30 1996-09-15 Hoechst Ag Metallocene mit benzokondensierten indenylderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
DK0574597T3 (da) * 1992-06-13 1998-09-14 Targor Gmbh Fremgangsmåde til fremstilling af brosluttede chirale metallocenkatalysatorer af bisindenyltypen
TW294669B (enExample) * 1992-06-27 1997-01-01 Hoechst Ag
ES2148204T3 (es) * 1992-09-04 2000-10-16 Bp Chem Int Ltd Composiciones cataliticas y procedimiento para la preparacion de poliolefinas.
JP3301123B2 (ja) * 1992-09-09 2002-07-15 東ソー株式会社 芳香族ビニル化合物重合用触媒
EP0590486A3 (en) * 1992-09-24 1994-08-24 Idemitsu Kosan Co Polymerization catalysts and process for producing polymers
GB9300934D0 (en) * 1993-01-19 1993-03-10 Bp Chem Int Ltd Metallocene complexes
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5563219A (en) * 1993-07-16 1996-10-08 Mitsui Toatsu Chemicals, Inc. Process for Preparing block copolymer of monoolefin
JPH07173214A (ja) * 1993-10-27 1995-07-11 Nippon Oil Co Ltd オレフィン類重合用触媒成分
EP0654476B1 (de) * 1993-11-24 2001-01-24 TARGOR GmbH Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
DE4342713A1 (de) * 1993-12-15 1995-06-22 Bayer Ag Verfahren zur Abtrennung von Methanol aus einem Gemisch von Dimethylcarbonat und Methanol
FI945959L (fi) * 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
JPH07258322A (ja) * 1994-03-23 1995-10-09 Idemitsu Kosan Co Ltd 重合用触媒及び重合体の製造方法
KR100368194B1 (ko) * 1994-10-13 2003-04-03 니혼폴리올레핀 가부시키가이샤 폴리올레핀제조용촉매성분,당해촉매성분을포함하는폴리올레핀제조용촉매및당해촉매존재하의폴리올레핀의제조방법
US5539124A (en) * 1994-12-19 1996-07-23 Occidental Chemical Corporation Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring
DE4447066A1 (de) * 1994-12-29 1996-07-04 Hoechst Ag Heterocyclische Carbene enthaltende Metallkomplexverbindungen
US5554775A (en) * 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
KR19990008050A (ko) * 1995-04-25 1999-01-25 폰티노트제이.릭 올레핀 중합 촉매로서의 아자보롤리닐 금속 착화합물
US6228958B1 (en) * 1995-04-25 2001-05-08 Equistar Chemicals, L.P. Azaborolinyl metal complexes as olefin polymerization catalysts
US5519099A (en) * 1995-06-07 1996-05-21 Industrial Technology Research Institute Organometallic catalysts containing hydrotris(pyrazolyl) borate and cyclopentadienyl groups, and processes of employing the same
JPH09110917A (ja) * 1995-10-17 1997-04-28 Ube Ind Ltd オレフィン重合用触媒
EP0791608B1 (en) * 1996-02-23 2000-05-10 Tosoh Corporation Olefin polymerization catalyst based on organometallic complexes and processes for production of polyolefins using the catalyst
US5747404A (en) * 1996-05-28 1998-05-05 Lyondell Petrochemical Company Polysiloxane supported metallocene catalysts
US5712354A (en) * 1996-07-10 1998-01-27 Mobil Oil Corporation Bridged metallocene compounds
US5756611A (en) * 1997-02-21 1998-05-26 Lyondell Petrochemical Company α-olefin polymerization catalysts
US6150297A (en) * 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
US6025407A (en) * 1997-10-30 2000-02-15 Occidental Chemical Corporation Photo-polymerization of vinyl chloride using metallocene catalysts
CA2225014A1 (en) * 1997-12-16 1999-06-16 Peter Zoricak B-n heterocyclic ligands
US6008394A (en) * 1998-08-07 1999-12-28 Arco Chemicals Technology, L.P. Sulfonyl catalysts and method of using the same
US5914408A (en) * 1998-08-07 1999-06-22 Equistar Chemicals, Lp Olefin polymerization catalysts containing benzothiazole
PL347324A1 (en) * 1998-10-08 2002-03-25 Dow Chemical Co Bridged metal complexes
US6420299B1 (en) * 1999-06-04 2002-07-16 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
US6281155B1 (en) * 1999-11-19 2001-08-28 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
US6727331B2 (en) * 2001-12-28 2004-04-27 Equistar Chemicals, Lp Preparation of polyethylene

Similar Documents

Publication Publication Date Title
JP3275211B2 (ja) 付加重合触媒の製造方法
JP2004505019A5 (enExample)
KR950701651A (ko) 금속중심 산화를 완화시킨 루이스 산에 의한 부가중합 촉매의 제조방법(preparation of addition polymerization catalystsvia lewis acid mitigated metal center oxidation)
JP2006512410A5 (enExample)
JP2005508413A5 (enExample)
JP2001527135A5 (enExample)
Wang et al. Synthesis, structural characterization, and olefin polymerization behavior of group 4 metal complexes with constrained-geometry carborane ligands
JP2009509003A5 (enExample)
JP2006509860A5 (enExample)
JP2002530286A5 (enExample)
JP2006509861A5 (enExample)
JP2005522513A5 (enExample)
JP2006009003A5 (enExample)
JP2006028489A5 (enExample)
JP2019031686A5 (enExample)
JP2002530285A5 (enExample)
JP2007515421A5 (enExample)
JP2004530664A5 (enExample)
JPH09143217A (ja) オレフィン重合用触媒及びオレフィン重合体の製造方法
CA2483326A1 (en) Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
JP2004500450A (ja) 極性モノマー及び無極性モノマーの(共)重合方法
RU2004132850A (ru) Получение замещенных инденов
JP2850152B2 (ja) エチレン系共重合体の製造方法
CN1284785C (zh) 含吡啶取代茚配体二价稀土金属配合物及其应用
CN1049439C (zh) 负载型金属茂催化剂、其制备及应用