JP2005519192A - 金属生産用の電気化学電池 - Google Patents
金属生産用の電気化学電池 Download PDFInfo
- Publication number
- JP2005519192A JP2005519192A JP2003572043A JP2003572043A JP2005519192A JP 2005519192 A JP2005519192 A JP 2005519192A JP 2003572043 A JP2003572043 A JP 2003572043A JP 2003572043 A JP2003572043 A JP 2003572043A JP 2005519192 A JP2005519192 A JP 2005519192A
- Authority
- JP
- Japan
- Prior art keywords
- cathode
- oxide
- metal
- battery
- uranium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 22
- 239000002184 metal Substances 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title description 4
- 238000000034 method Methods 0.000 claims abstract description 62
- 150000003839 salts Chemical class 0.000 claims abstract description 28
- 239000000446 fuel Substances 0.000 claims abstract description 19
- 230000008569 process Effects 0.000 claims abstract description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000001301 oxygen Substances 0.000 claims abstract description 14
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 14
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 12
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 12
- 239000003792 electrolyte Substances 0.000 claims abstract description 9
- 150000001768 cations Chemical class 0.000 claims abstract description 7
- 238000001556 precipitation Methods 0.000 claims abstract description 4
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 claims description 11
- 229910000439 uranium oxide Inorganic materials 0.000 claims description 11
- 229910052770 Uranium Inorganic materials 0.000 claims description 8
- 239000002915 spent fuel radioactive waste Substances 0.000 claims description 8
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 7
- 229910000310 actinide oxide Inorganic materials 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000008188 pellet Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 150000003841 chloride salts Chemical class 0.000 claims description 3
- 238000011946 reduction process Methods 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- SHZGCJCMOBCMKK-KGJVWPDLSA-N beta-L-fucose Chemical compound C[C@@H]1O[C@H](O)[C@@H](O)[C@H](O)[C@@H]1O SHZGCJCMOBCMKK-KGJVWPDLSA-N 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- OOAWCECZEHPMBX-UHFFFAOYSA-N oxygen(2-);uranium(4+) Chemical compound [O-2].[O-2].[U+4] OOAWCECZEHPMBX-UHFFFAOYSA-N 0.000 claims description 2
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 claims description 2
- 238000003466 welding Methods 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 abstract description 7
- 239000006227 byproduct Substances 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 5
- 150000002739 metals Chemical class 0.000 abstract description 4
- 238000000752 ionisation method Methods 0.000 abstract 1
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 229910018068 Li 2 O Inorganic materials 0.000 description 2
- 229910001093 Zr alloy Inorganic materials 0.000 description 2
- 229910052768 actinide Inorganic materials 0.000 description 2
- 150000001255 actinides Chemical class 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003758 nuclear fuel Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910000882 Ca alloy Inorganic materials 0.000 description 1
- 229910000925 Cd alloy Inorganic materials 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910052778 Plutonium Inorganic materials 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003671 uranium compounds Chemical class 0.000 description 1
- -1 uranium ions Chemical class 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
- G21C19/42—Reprocessing of irradiated fuel
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/34—Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0204671.2A GB0204671D0 (en) | 2002-02-28 | 2002-02-28 | Electrochemical cell for metal production |
| PCT/GB2003/000792 WO2003073436A1 (en) | 2002-02-28 | 2003-02-24 | Electrochemical cell for metal production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005519192A true JP2005519192A (ja) | 2005-06-30 |
| JP2005519192A5 JP2005519192A5 (enExample) | 2006-04-13 |
Family
ID=9931943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003572043A Pending JP2005519192A (ja) | 2002-02-28 | 2003-02-24 | 金属生産用の電気化学電池 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20050139474A1 (enExample) |
| EP (1) | EP1481401B1 (enExample) |
| JP (1) | JP2005519192A (enExample) |
| KR (1) | KR20040093726A (enExample) |
| CN (1) | CN1639803A (enExample) |
| AU (1) | AU2003207344A1 (enExample) |
| GB (1) | GB0204671D0 (enExample) |
| RU (1) | RU2004127170A (enExample) |
| WO (1) | WO2003073436A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013505367A (ja) * | 2009-10-13 | 2013-02-14 | ソク,サンヨプ | 接触比表面積を増大させた有価金属回収用電解槽 |
| JP2013224488A (ja) * | 2012-04-23 | 2013-10-31 | Ge-Hitachi Nuclear Energy Americas Llc | コリウムおよび使用済み核燃料の安定化処理方法 |
| JP2013227631A (ja) * | 2012-04-26 | 2013-11-07 | Toshiba Corp | 電解還元装置 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0113749D0 (en) * | 2001-06-06 | 2001-07-25 | British Nuclear Fuels Plc | Actinide production |
| US7756490B2 (en) | 2005-03-08 | 2010-07-13 | Atc Technologies, Llc | Methods, radioterminals, and ancillary terrestrial components for communicating using spectrum allocated to another satellite operator |
| CN101346851B (zh) * | 2005-12-27 | 2010-09-01 | 川崎设备系统株式会社 | 用于从锂二次电池中回收贵重物质的回收装置和回收方法 |
| RU2340021C1 (ru) * | 2007-06-05 | 2008-11-27 | Николай Викторович СТЕПАНОВ | Способ переработки отработавшего ядерного топлива |
| CN101994133B (zh) * | 2010-11-24 | 2012-10-17 | 中国原子能科学研究院 | 用于氧化物乏燃料干法后处理的熔盐体系 |
| US8900439B2 (en) * | 2010-12-23 | 2014-12-02 | Ge-Hitachi Nuclear Energy Americas Llc | Modular cathode assemblies and methods of using the same for electrochemical reduction |
| GB201102023D0 (en) * | 2011-02-04 | 2011-03-23 | Metalysis Ltd | Electrolysis method, apparatus and product |
| AU2013204396B2 (en) * | 2012-05-16 | 2015-01-29 | Lynas Services Pty Ltd | Electrolytic cell for production of rare earth metals |
| US9382632B2 (en) | 2013-06-21 | 2016-07-05 | Savannah River Nuclear Solutions, Llc | Electrochemical fluorination for processing of used nuclear fuel |
| WO2017158335A1 (en) * | 2016-03-16 | 2017-09-21 | Scott Dr Ian Richard | Conversion of spent uranium oxide fuel into molten salt reactor fuel |
| CN107385484B (zh) * | 2017-07-14 | 2020-03-31 | 南京信息工程大学 | 一种单连接线电沉积钨涂层的方法 |
| RU2716137C1 (ru) * | 2019-10-18 | 2020-03-06 | Федеральное государственное унитарное предприятие "Горно-химический комбинат" (ФГУП "ГХК") | Установка для волоксидации отработавшего ядерного топлива |
| CN110820016A (zh) * | 2019-11-06 | 2020-02-21 | 中国原子能科学研究院 | 一种氧化铀粉末电化学还原的装置和方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4837319A (enExample) * | 1971-09-14 | 1973-06-01 | ||
| JPH0375597A (ja) * | 1989-08-17 | 1991-03-29 | Central Res Inst Of Electric Power Ind | 溶融塩電解精製装置 |
| WO2001041152A2 (en) * | 1999-12-03 | 2001-06-07 | British Nuclear Fuels Plc | Actinide production |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3982928A (en) * | 1975-01-03 | 1976-09-28 | The United States Of America As Represented By The United States Energy Research And Development Administration | Separation of uranium from (Th,U)O2 solid solutions |
| US5378325A (en) * | 1991-09-17 | 1995-01-03 | Aluminum Company Of America | Process for low temperature electrolysis of metals in a chloride salt bath |
| US5160367A (en) * | 1991-10-03 | 1992-11-03 | The United States Of America As Represented By The United States Department Of Energy | Salt transport extraction of transuranium elements from lwr fuel |
| US5640902A (en) * | 1995-03-23 | 1997-06-24 | Pitney Bowes Inc. | Single motor meter drum and shutter bar drive of a postage meter |
| US5650053A (en) * | 1995-11-24 | 1997-07-22 | The United States Of America As Represented By The United States Department Of Energy | Electrorefining cell with parallel electrode/concentric cylinder cathode |
| ATE263259T1 (de) * | 1999-01-08 | 2004-04-15 | Moltech Invent Sa | Aluminium-elektrogewinnungszelle mit sauerstoffentwickelnden anoden |
| US6419813B1 (en) * | 2000-11-25 | 2002-07-16 | Northwest Aluminum Technologies | Cathode connector for aluminum low temperature smelting cell |
| US6540902B1 (en) * | 2001-09-05 | 2003-04-01 | The United States Of America As Represented By The United States Department Of Energy | Direct electrochemical reduction of metal-oxides |
-
2002
- 2002-02-28 GB GBGB0204671.2A patent/GB0204671D0/en not_active Ceased
-
2003
- 2003-02-24 RU RU2004127170/06A patent/RU2004127170A/ru not_active Application Discontinuation
- 2003-02-24 KR KR10-2004-7013442A patent/KR20040093726A/ko not_active Withdrawn
- 2003-02-24 CN CNA038048892A patent/CN1639803A/zh active Pending
- 2003-02-24 EP EP03704816A patent/EP1481401B1/en not_active Expired - Lifetime
- 2003-02-24 US US10/505,262 patent/US20050139474A1/en not_active Abandoned
- 2003-02-24 JP JP2003572043A patent/JP2005519192A/ja active Pending
- 2003-02-24 AU AU2003207344A patent/AU2003207344A1/en not_active Abandoned
- 2003-02-24 WO PCT/GB2003/000792 patent/WO2003073436A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4837319A (enExample) * | 1971-09-14 | 1973-06-01 | ||
| JPH0375597A (ja) * | 1989-08-17 | 1991-03-29 | Central Res Inst Of Electric Power Ind | 溶融塩電解精製装置 |
| WO2001041152A2 (en) * | 1999-12-03 | 2001-06-07 | British Nuclear Fuels Plc | Actinide production |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013505367A (ja) * | 2009-10-13 | 2013-02-14 | ソク,サンヨプ | 接触比表面積を増大させた有価金属回収用電解槽 |
| JP2013224488A (ja) * | 2012-04-23 | 2013-10-31 | Ge-Hitachi Nuclear Energy Americas Llc | コリウムおよび使用済み核燃料の安定化処理方法 |
| JP2013227631A (ja) * | 2012-04-26 | 2013-11-07 | Toshiba Corp | 電解還元装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2004127170A (ru) | 2005-05-10 |
| EP1481401B1 (en) | 2005-11-16 |
| WO2003073436A1 (en) | 2003-09-04 |
| US20050139474A1 (en) | 2005-06-30 |
| AU2003207344A1 (en) | 2003-09-09 |
| KR20040093726A (ko) | 2004-11-08 |
| EP1481401A1 (en) | 2004-12-01 |
| GB0204671D0 (en) | 2002-04-10 |
| CN1639803A (zh) | 2005-07-13 |
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