JP2005335151A - Metallically sheeny decorative sheet and decorative material - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To ensure that a successful metallically sheeny finish can be revealed without the generation of cracks in a metallically sheeny layer of a decorative sheet, when an interior finish material such as a fitting material or a furniture material, or a facing decorative material for furniture/utensils such as residential facilities equipment, home appliances or a television set pedestal for a liquid crystal TV set or a plasma TV set, or a decorative material for interior/exterior automotive trims, is manufactured by deep drawing process or three-dimensional shaping process. <P>SOLUTION: This decorative sheet is constituted of a thermoplastic resin base material layer 4, a pattern layer 6 and a transparent thermoplastic resin layer 8. On the surface of the thermoplastic resin base material layer 4, the pattern layer 6 printed on a transfer sheet composed of a biaxially oriented polyethylene terephthalate resin using a printing ink with a metallic sheeny pigment 10 added, is formed by transfer. Further, the metallic sheeny pigment 10 is added to the thermoplastic resin base material layer 4 and/or the transparent thermoplastic resin layer 8. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention is applied to interior and exterior materials such as artificial materials, exterior sheet materials such as furniture and fixtures such as living equipment, home appliances, television stands such as liquid crystal televisions and plasma televisions, and interior and exterior of vehicles such as automobiles. Metallic glossy decorative sheet for use in wearing sheet materials, etc., and simultaneous injection molding by bending, stretching, wrapping, or three-dimensional molding by vacuum forming, vacuum / pressure forming, and in-mold forming for the above sheet materials The present invention relates to a decorative metallic luster-like decorative material.

  Conventionally, as a decorative sheet having a metallic luster tone, there is a decorative sheet in which a metal layer is applied to a thermoplastic resin substrate made of polyvinyl chloride resin. For example, a thermoplastic resin substrate layer / metal layer / adhesive layer / 2 axes. A metallic glossy decorative sheet comprising a stretched polyethylene terephthalate resin layer / adhesive layer / fluororesin layer is disclosed in JP-A-7-251632 (Patent Document 1 below).

  The above metallic glossy decorative sheet was able to exhibit a metallic design effect, but the decorative sheet was not stretched because the biaxially stretched polyethylene terephthalate resin layer was used as the intermediate layer, and therefore the stretchability was good. In addition, the unevenness followability when this drawing sheet was subjected to deep drawing processing or three-dimensional shape processing was not good.

  Japanese Patent Application Laid-Open No. 2000-225672 (Patent Document 2 below) includes a high-crystalline polypropylene resin layer / soft polypropylene resin layer / high-crystalline polypropylene resin layer / pattern layer / adhesive layer / transparent acrylic resin layer as a decorative sheet. However, it is technically difficult to express a metallic design because there is no metal layer as the laminated structure.

  JP 2000-334609 (Patent Document 3) discloses a backer layer (0.1 mm thick) / ABS resin sheet layer / acrylonitrile-butadiene-styrene copolymer resin (hereinafter referred to as ABS resin) / There is a decorative sheet for in-mold molding having a laminated structure composed of a pattern layer / transparent acrylic resin sheet layer, but similarly, it is difficult to express a metallic design as a decorative sheet.

  Japanese Patent Laid-Open No. 2000-337295 (Patent Document 4 below) discloses a laminate composed of an amorphous crystalline polyester resin layer / a non-crystalline polyester resin (PET-G) sheet base material layer / acrylic resin layer. Although there is a decorative sheet having a configuration, similarly, it is difficult to express a metallic design as a decorative sheet.

  Japanese Patent Laid-Open No. 2002-46230 (Patent Document 5 below) has a decorative sheet for in-mold molding for automobiles having a laminated structure composed of a thermoplastic resin layer / metallic ink layer / acrylic resin layer made of ABS resin. However, when this decorative sheet is stretched as a decorative material by three-dimensional molding or the like, the metallic ink layer may be cracked.

The known patent documents are described below.
Japanese Patent Laid-Open No. 7-251632 JP 2000-225672 A JP 2000-334609 A JP 2000-337295 A JP 2002-46230 A

  An object of the present invention is to draw a metallic glossy decorative sheet, such as bending, stretching, lapping, vacuum forming, three-dimensional forming by vacuum / pressure forming, injection molding simultaneous decorating by in-mold forming, etc. Or by processing three-dimensional shapes, such as exterior materials such as interior materials such as construction materials, joinery materials, furniture and fixtures such as housing equipment, home appliances, TV sets for LCD TVs and plasma TVs, In producing decorative materials for interior and exterior of a vehicle such as an automobile, the metallic gloss layer of the decorative sheet does not generate cracks, and a good metallic gloss tone can be expressed. .

  The invention according to claim 1 of the present invention is a decorative sheet comprising a thermoplastic resin base layer 4, a pattern layer 6, and a transparent thermoplastic resin layer 8. The surface of the thermoplastic resin base layer 4 is biaxial. The said pattern layer 6 printed using the printing ink which added the metallic glossy pigment 10 to the transfer sheet which consists of an extending | stretching polyethylene terephthalate resin is formed by transcription | transfer, the said thermoplastic resin base material layer 4 and / or transparent thermoplastic resin The layer 8 is a metallic glossy decorative sheet to which a metallic glossy pigment 10 is added.

  The invention according to claim 2 of the present invention is the metallic glossy decorative sheet according to claim 1, wherein the metallic glossy pigment 10 is a glitter pigment made of mica pigment and / or metal powder. It is a metallic glossy decorative sheet.

  The invention according to claim 3 of the present invention is the metallic glossy decorative sheet according to claim 1 or 2, wherein the metallic glossy pigment 10 is the thermoplastic resin substrate layer 4 and / or the transparent thermoplastic resin layer. The metallic glossy decorative sheet is characterized by containing 0.5 to 20 parts by weight per 100 parts by weight of the resin No. 8.

  The invention according to claim 4 of the present invention is the metallic glossy decorative sheet according to any one of claims 1 to 3, wherein the metallic gloss pigment is formed on the surface of the thermoplastic resin substrate layer on which the pattern layer is formed. The transparent thermoplastic resin layer and the polyvinylidene fluoride are added together, and the transparent thermoplastic resin layer is laminated with the polyvinylidene fluoride as an adhesive layer on the pattern layer forming surface of the thermoplastic resin base layer. A metallic glossy decorative sheet characterized by being laminated.

  According to a fifth aspect of the present invention, in the metallic glossy decorative sheet according to any one of the first to fourth aspects, a thermoplastic resin is provided on the surface of the thermoplastic resin base layer 4 opposite to the pattern layer 6. A metallic glossy decorative sheet, wherein the backer layer 2 is laminated.

  The invention according to claim 6 of the present invention is a metallic glossy decorative material characterized by being three-dimensionally molded using the metallic glossy decorative sheet according to any one of the first to fifth aspects.

According to the metallic glossy decorative sheet of the present invention, after the pattern layer 6 made of metallic ink added with the metallic glossy pigment 10 is printed on the transfer sheet made of biaxially stretched polyethylene terephthalate resin, Since the material is transferred onto the entire surface or a partial surface of the thermoplastic resin base material layer 4, a decorative sheet with a metallic gloss tone is obtained by the pattern layer 6 using a high gloss metallic ink on the surface layer of the decorative sheet. It is done.

  Further, according to the metallic glossy decorative sheet of the present invention, the ink binder resin of the metallic ink of the pattern layer 6 used for printing and transfer is made of an easily stretchable resin. Since the resin is also easy to stretch, even if the decorative sheet is subjected to three-dimensional molding such as deep drawing or three-dimensional molding, the metallic glossy pattern layer 6 is cracked. It is possible to maintain a highly glossy metallic luster tone without the occurrence of.

  In addition, according to the metallic glossy decorative sheet of the present invention, the metallic glossy pigment 10 is added to the thermoplastic resin base layer 4 and the transparent thermoplastic resin layer 8 in addition to the pattern layer 6. The design effect of the metallic luster tone by the thermoplastic resin base material layer 4 and the transparent thermoplastic resin layer 8 is synergistically expressed with respect to the metallic luster tone design effect by the layer 6, and a higher design effect as a decorative sheet is achieved. It is something that demonstrates.

  Furthermore, using the metallic glossy decorative sheet of the present invention, deep drawing processing and tertiary processing such as bending processing, stretching processing, lapping processing, three-dimensional molding processing by vacuum and pressure forming, injection molding simultaneous decorating processing by in-mold molding, etc. Even if the original shape is processed, the pattern layer 6 as the metallic luster layer of the decorative sheet does not crack and can exhibit a good metallic luster tone. Metal glossy cosmetic materials for exteriors such as furniture, furniture and fixtures such as materials, housing equipment, home appliances, TV stands for LCD TVs and plasma televisions, and metal glossy cosmetics for interiors and exteriors of vehicles such as automobiles The material can be manufactured.

  In FIG. 1, the structure of the cross section in one Example of the metallic glossy decorative sheet 12 of this invention is shown. The metallic glossy decorative sheet 12 in this example is composed of a thermoplastic resin base layer 4, a pattern layer 6 of printing ink to which a metallic glossy pigment 10 is added, and a transparent thermoplastic resin layer 8. Is one which is once printed on the transfer sheet surface of the biaxially stretched polyethylene terephthalate resin sheet using the printing ink to which the metallic glossy pigment 10 is added, and then transferred to the thermoplastic resin substrate layer 4.

  In addition, the metallic glossy decorative sheet 12 of the present invention may have an adhesive layer 7 interposed when the thermoplastic resin base material layer 4 on which the pattern layer 6 is formed and the transparent thermoplastic resin layer 8 are laminated and bonded. Good.

  Moreover, in this invention, as shown in FIG. 1, the metallic gloss pigment 10 may be added and kneaded to any one or both of the transparent thermoplastic resin layer 8 and the thermoplastic resin base material layer 4. .

  In FIG. 2, the structure of the cross section in one Example of the metallic glossy decorative sheet 13 of this invention is shown. In this embodiment, the metallic glossy decorative sheet 13 has a primer layer 1 and a thermoplastic resin backer layer 2 on the back surface of the thermoplastic resin base material layer 4 of the metallic glossy decorative sheet 12 shown in FIG. The surface protective layer 9 is laminated and bonded to the surface of the transparent thermoplastic resin layer 8 of the metallic glossy decorative sheet 12 shown in FIG. 1 via the transparent adhesive layer 11 made of transparent polyvinylidene fluoride resin. It is.

  Further, as shown in FIG. 2, the metallic glossy decorative sheet 13 of the present invention is bonded when the thermoplastic resin base material layer 4 on which the pattern layer 6 is formed and the transparent thermoplastic resin layer 8 are laminated and bonded. An agent layer 7 may be interposed. Further, a primer layer 5 may be interposed between the thermoplastic resin base material layer 4 and the pattern layer 6.

  In the present invention, the metallic gloss pigment 10 may be added and kneaded to one or both of the transparent thermoplastic resin layer 8 and the thermoplastic resin substrate layer 4 shown in FIG.

  The thermoplastic resin backer layer 2 of the metallic glossy decorative sheet 13 shown in FIG. 2 includes a known amorphous polyester resin, amorphous crystalline polyethylene terephthalate resin, crystalline polyethylene terephthalate resin, polypropylene resin, polyethylene resin, methyl Methacrylate resin, polymethyl methacrylate resin, ABS resin, polybutylene terephthalate resin, ionomer resin (copolymer resin in which ethylene and methacrylic acid are neutralized with metal ions), ethylene-vinyl acetate copolymer resin, ethylene-vinyl alcohol A copolymer resin, vinyl chloride resin or the like to which a known organic or inorganic color pigment, a heat stabilizer, a light stabilizer, an ultraviolet absorber, or the like is added can be used. The thickness of the backer layer 2 can be about 50 μm to 250 μm.

Further, the outer surface of the thermoplastic resin backer layer 2 may be subjected to corona treatment as necessary, or as shown in FIG. 2, a primer layer 1 (after drying, such as silica added to a two-component urethane resin) Application amount 0.5 to 2 g / m ² ) may be applied.

  The adhesive layer 3 or the adhesive layer 7 is a two-component urethane resin adhesive obtained by adding an isocyanate-based curing agent as a curing agent to a polyol such as polyester polyol or polycarbonate polyol. Those coated at 12 μm can be used. The thermoplastic resin backer layer 2 and the thermoplastic resin substrate layer 4 may not be used depending on the resin system, and the pattern layer 6 and the transparent thermoplastic resin layer 8 may be used depending on the resin system.

  The thermoplastic resin base material layer 4 includes a known amorphous polyester resin, amorphous crystalline polyethylene terephthalate resin, crystalline polyethylene terephthalate resin, polypropylene resin, polyethylene resin, methyl methacrylate resin, polymethyl methacrylate resin. , ABS resins, polybutylene terephthalate resins, ionomer resins (copolymer resins obtained by neutralizing ethylene and methacrylic acid with metal ions), ethylene-vinyl acetate copolymer resins, ethylene-vinyl alcohol copolymer resins, etc. And inorganic color pigments, heat stabilizers, light stabilizers, ultraviolet absorbers and the like can be used. The thickness of the thermoplastic resin base material layer 4 can be about 50 μm to 150 μm.

  The thickness of the thermoplastic resin base material layer 4 is desirably 45 μm to 200 μm, but in the case of the in-mold molding method, 90 μm to 160 μm is particularly desirable. Moreover, as thickness suitable for vacuum moldability, about 50 micrometers-100 micrometers are suitable.

  Moreover, when adding the metallic luster pigment 10 (metal powder) to the thermoplastic resin base material layer 4, 0.5 to 80 parts by weight is added to 100 parts by weight of the resin. Moreover, you may add a ultraviolet absorber, a light stabilizer, and a heat stabilizer.

The surface of the thermoplastic resin substrate layer 4 may be subjected to corona treatment as necessary. Further, as shown in FIG. 2, a primer layer 5 is provided on the surface of the thermoplastic resin base material layer 4 as necessary, and a resin obtained by adding silica or the like to a two-component urethane resin as the primer layer 5 is dried. after the coating amount 0.5 g / m ² may be coated about to 2 g / m ^2, resin-based pattern layer 6 (e.g., vinyl chloride - vinyl acetate copolymer resin, etc.) by an acrylic resin - polyester resin - may be applied coating amount after drying a primer layer 5 made of - (vinyl acetate copolymer resin vinyl ^{chloride) 1g / m 2 ~10g / m} 2.

As the pattern layer 6, a gravure ink using an ink binder resin such as a two-component urethane resin system, a vinyl chloride-vinyl acetate copolymer resin system, or a mixed system of a vinyl chloride-vinyl acetate copolymer resin system and an acrylic resin system. Can be used. As the pigment added to the ink binder resin, organic pigments, inorganic pigments, metallic luster pigments 10 (gold powder, silver powder, aluminum powder, flake-shaped aluminum powder), mica, and the like can be used.

  The gravure printing of the pattern layer 6 is performed by completely or partially placing a pattern layer to be the pattern layer 6 on a transfer sheet (for example, smooth surface of the transfer sheet; mirror surface) of a biaxially stretched polyester resin film that has not been corona-treated. After the printing, the pattern layer to be the pattern layer 6 is thermally transferred to the thermoplastic resin base layer 4.

  Thereby, the ink surface of the pattern layer 6 transferred and formed on the thermoplastic resin base layer 4 becomes a smooth surface (or mirror surface) by the smooth surface of the transfer sheet, and in particular, the ink used for the pattern layer 6 is scaly. When the metallic luster pigment 10 such as aluminum powder is added, the surface of the pattern layer 6 becomes a mirror surface equivalent to the case where the pattern is formed on a smooth film by an evaporation method such as vacuum evaporation.

  The transparent thermoplastic resin layer 8 includes a transparent or translucent methyl methacrylate resin and a known metallic luster pigment 10 such as aluminum powder, flaky aluminum, stainless steel powder, brass powder, indium powder, gold powder, silver powder, pearl powder. , Mica, etc., and mixtures thereof can also be used.

As shown in FIG. 2, when the surface protective layer 9 is applied to the surface of the decorative sheet, a two-component urethane resin to which a known ultraviolet absorber, light stabilizer and the like are added is applied in an amount of 6 g / m after drying. ² or coated with, a side chain of an acrylic urethane resin, an esterification reaction (alcohol with the hydroxyl groups of the organopolysiloxane alkylol compounds having the said carboxyl group of the acrylic polyol compound, a hydroxyl-terminated with a carboxyl group and a silicone-modified acrylic urethane resin produced by the dehydration reaction of a carboxylic acid), coating amount 5g / m ² ~15g / m ² was applied after drying and dried by applying a surface protective layer 9.

In the case of vacuum forming or the like using the metallic glossy decorative sheet of the present invention, as shown in FIG. 2, a primer made of a resin in which silica or the like is added to a two-component urethane resin as an easy adhesion layer on the back surface of the decorative sheet 13 the layers 1, it is possible by coating with a dry weight after 0.9g / m ² ~1.5g / m ² to obtain a metallic luster decorative sheet 13 of the present invention.

  Specific examples of the present invention will be described below.

<Example 1>
In a binder resin composed of an acrylic resin and a vinyl chloride-vinyl acetate copolymer resin, with a gravure printing ink in which flaky aluminum powder is added as the metallic luster pigment 10, a hairline-like pattern that becomes the pattern layer 6 is obtained. After printing on a 25 μm-thick biaxially stretched polyester resin film as a transfer sheet, the hairline pattern to be the pattern layer 6 of the transfer sheet is 8 parts by weight of aluminum powder as a metallic luster pigment with respect to 100 weights of the copolyester resin. The pattern layer 6 was obtained by thermal transfer to a metallic luster-like thermoplastic resin base material layer 4 made of a copolyester resin having a thickness of 100 μm added and kneaded.

  Next, a transparent thermoplastic resin layer 8 made of a transparent methyl methacrylate resin having a thickness of 100 μm is formed on the surface of the pattern layer 6 of the metallic luster-like thermoplastic resin substrate layer 4 as a transparent adhesive layer 7 to a thickness of 100 μm. 1 is heated and pressed at 200 ° C. through a transparent transparent copolyester resin, and the metallic glossy decorative sheet 12 shown in FIG. 1 (the metallic thermoplastic pigment 10 is not added to the transparent thermoplastic resin layer 8). Stuff).

<Example 2>
As the transparent thermoplastic resin layer 8 of Example 1, the pearl pigment (ME100 manufactured by Nippon Koken Co., Ltd.) and the aluminum powder are each 1 part by weight as the metallic luster pigment 10 with respect to 100 parts by weight of the transparent methyl methacrylate resin. A metallic glossy decorative sheet 12 (with the metallic gloss pigment 10 added to the transparent thermoplastic resin layer 8) shown in FIG. 1 is obtained in the same manner as in Example 1 except that the kneaded one by one is used. It was.

<Example 3>
On the surface of the transparent thermoplastic resin layer 8 of Example 2 above, polydimethyl having a weight average molecular weight of about 500 with respect to 100 parts by weight of an acrylic polyol having a weight average molecular weight of about 25,000 and an average number of hydroxyl groups per molecule of about 25. The surface protective layer 9 is formed by applying and drying a coating solution containing 10 parts by weight of siloxane propylol and 10 parts by weight of hexamethylene diisocyanate curing agent at a weight of 12 g / m ² after drying. Except for this, the metallic glossy decorative sheet 12 shown in FIG. 1 (the surface protective layer 9 formed on the surface of the transparent thermoplastic resin layer 8) was obtained in the same manner as in Example 2 above.

<Example 4>
The metallic gloss tone shown in FIG. 1 is the same as that of the above Example 2 except that the resin system of the metallic gloss tone thermoplastic resin base layer 4 and the transparent adhesive layer 7 in Example 2 is ABS resin. A decorative sheet (those having the metallic luster pigment 10 added to the transparent thermoplastic resin layer 8) was obtained.

<Example 5>
In Example 2 above, the transparent adhesive layer 7 was not laminated, and the liquid adhesive obtained by adding silica or the like to the two-component urethane resin as the adhesive layer 3 on the back surface of the metallic glossy thermoplastic resin base material layer 4 was dried. It was coated at a coating amount of weight 0.9 g / m ² to 1.5 g / m ² after, except for forming the backer layer 2 via the adhesive layer 3, in the same manner as in example 2 Thus, the metallic glossy decorative sheet 12 of the present invention shown in FIG. 1 was obtained.

<Example 6>
The transparent thermoplastic resin layer 8 in Example 2 and the transparent adhesive layer 11 made of transparent polyvinylidene fluoride resin were coextruded at a thickness ratio of 35 μm / 15 μm, respectively, and then passed through the transparent adhesive layer 11. 1 except that the surface protective layer 9 in Example 3 was formed, in the same manner as in Example 3 above, the metallic glossy decorative sheet 12 shown in FIG. 1 (the surface protective layer 9 was formed on the surface of the transparent thermoplastic resin layer 8). Formation).

<Comparative Example 1>
Instead of the hairline-like pattern layer 6 formed by thermal transfer using a transfer sheet on the metallic luster-like thermoplastic resin base material layer 4 of Example 1, a hairline-like pattern pattern by aluminum deposition of 700 nm is used. A metallic glossy decorative sheet having the same laminated structure as the metallic glossy decorative sheet shown in FIG. 1 was obtained in the same manner as in Example 1 except that the layer 6 was used.

<Performance Evaluation 1> Vacuum Forming A two-part curable adhesive (urethane-modified vinyl resin aqueous adhesive CVC555: cross-linking agent V) is used as an adhesive on the surface of a rectangular medium density fiberboard having a radius of curvature of 5 mmR and a thickness of 25 mm. = 100: 5 (manufactured by Konishi Co., Ltd.)) by spray coating at an application amount of 60 g / m ² wet, and then each metallic glossy decorative sheet obtained in Examples 1 to 6 and Comparative Example 1 is used as a sheet. Vacuum forming at a temperature of 120 ° C. and bonding were performed to obtain metallic glossy decorative materials (decorative plates).

As a result of evaluating the appearance performance of each of the obtained metallic luster-like decorative materials, cracks were not generated in the metallic luster-like layers (pattern layers 6) of the respective sheets of Examples 1 to 6 and were good. It was. In the metal glossy layer of the deposited layer of the sheet of Comparative Example 1, cracks were observed.

<Performance evaluation 2> In-mold molding Between the female mold and the male mold of the injection mold, each of the metallic glossy decorative sheets of Examples 1 to 6 and Comparative Example 1 is applied to the transparent adhesive layer 7 (or backer). After the layer 7) was inserted toward the male mold and brought into close contact with the female mold by vacuum forming, a molten resin was injected from the male mold to prepare metallic glossy decorative materials.

  As a result of evaluating the appearance performance of each of the obtained metallic luster-like decorative materials, cracks were not generated in the metallic luster-like layers (pattern layers 6) of the respective sheets of Examples 1 to 6 and were good. It was. In the metal glossy layer of the deposited layer of the sheet of Comparative Example 1, cracks were observed.

<Performance Evaluation 3> Metallic Glossiness When the appearances of the metallic glossy decorative sheet obtained in Examples 1 to 6 and the metallic glossy decorative sheet obtained in Comparative Example 1 are visually inspected. Examples 1-6 were superior to Comparative Example 1 in metallic luster.

  The present invention is a metal for use in interior materials such as artificial materials and fittings, furniture fixtures, exteriors of residential equipment and home appliances, fixtures such as liquid crystal and plasma television sets, and vehicle interiors and exteriors such as automobiles. It can be used as a glossy decorative sheet. More specifically, it can be used as a metallic luster-like decorative material for the above-mentioned members, which is simultaneously decorated by injection molding such as bending processing, stretching processing, lapping, vacuum forming, three-dimensional forming processing using vacuum / pressure air, and in-mold molding.

The lamination sectional view explaining an example of the metallic luster tone decorative sheet in the present invention. The lamination sectional view explaining other examples of the metallic luster tone decorative sheet in the present invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 ... Primer layer 2 ... Thermoplastic resin backer layer 3 ... Adhesive layer 4 ... Thermoplastic resin base material layer 5 ... Primer layer 6 ... Picture layer 7 ... Transparent adhesive layer (or backer layer)
8 ... Transparent thermoplastic resin layer 9 ... Surface protective layer 10 ... Metal luster pigment 11 ... Transparent adhesive layer (transparent polyvinylidene fluoride resin layer)
12 ... Metal glossy decorative sheet 13 ... Metal glossy decorative sheet

Claims (6)

  In a decorative sheet composed of a thermoplastic resin base layer, a pattern layer, and a transparent thermoplastic resin layer, a metallic gloss pigment is added to a transfer sheet composed of a biaxially stretched polyethylene terephthalate resin on the surface of the thermoplastic resin base layer. The pattern layer printed using the printed ink is formed by transfer, and a metallic gloss pigment is added to the thermoplastic resin base layer and / or the transparent thermoplastic resin layer. Metal glossy decorative sheet.   2. The metallic glossy decorative sheet according to claim 1, wherein the metallic glossy pigment is a glitter pigment made of mica pigment and / or metal powder.   The metallic glossy decorative sheet according to claim 1 or 2, wherein the metallic glossy pigment is 0.5 parts by weight with respect to 100 parts by weight of the resin of the thermoplastic resin substrate layer and / or the transparent thermoplastic resin layer. To 20 parts by weight of a metallic glossy decorative sheet.   4. The metallic glossy decorative sheet according to any one of claims 1 to 3, wherein the transparent thermoplastic resin layer and a polyfluorinated layer to which a metallic glossy pigment is added on a pattern layer forming surface of the thermoplastic resin base material layer. A metallic gloss control characterized in that the transparent thermoplastic resin layer is laminated and laminated with the polyvinylidene fluoride adhesive layer on the surface of the thermoplastic resin substrate layer on which the pattern layer is formed by co-extrusion with vinylidene. Makeup sheet.   The metallic glossy decorative sheet according to any one of claims 1 to 4, wherein a thermoplastic resin backer layer is laminated on the surface opposite to the pattern layer of the thermoplastic resin base material layer. Glossy decorative sheet.   A metallic glossy decorative material, which is three-dimensionally molded using the metallic glossy decorative sheet according to any one of claims 1 to 5.

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