JP2005325442A - 硫黄ベースの腐食防止剤 - Google Patents
硫黄ベースの腐食防止剤 Download PDFInfo
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- JP2005325442A JP2005325442A JP2005090014A JP2005090014A JP2005325442A JP 2005325442 A JP2005325442 A JP 2005325442A JP 2005090014 A JP2005090014 A JP 2005090014A JP 2005090014 A JP2005090014 A JP 2005090014A JP 2005325442 A JP2005325442 A JP 2005325442A
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- Prior art keywords
- corrosion
- inhibitor
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- compound
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- 230000007797 corrosion Effects 0.000 title claims abstract description 161
- 238000005260 corrosion Methods 0.000 title claims abstract description 161
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 14
- 239000003112 inhibitor Substances 0.000 title abstract description 156
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract description 12
- 239000011593 sulfur Substances 0.000 title abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 53
- 239000002184 metal Substances 0.000 claims abstract description 53
- 150000001875 compounds Chemical class 0.000 claims abstract description 37
- 125000003118 aryl group Chemical group 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims description 48
- 239000000243 solution Substances 0.000 claims description 46
- 125000001424 substituent group Chemical group 0.000 claims description 31
- 239000007864 aqueous solution Substances 0.000 claims description 22
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 15
- -1 alkali metal cation Chemical class 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 9
- 125000004641 (C1-C12) haloalkyl group Chemical group 0.000 claims description 9
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims description 9
- 125000004171 alkoxy aryl group Chemical group 0.000 claims description 9
- 125000003282 alkyl amino group Chemical group 0.000 claims description 9
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 9
- 125000005157 alkyl carboxy group Chemical group 0.000 claims description 9
- 125000005001 aminoaryl group Chemical group 0.000 claims description 9
- 125000005026 carboxyaryl group Chemical group 0.000 claims description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 9
- 125000003106 haloaryl group Chemical group 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 125000005027 hydroxyaryl group Chemical group 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
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- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 6
- 239000008397 galvanized steel Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical group NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 4
- 229920001174 Diethylhydroxylamine Polymers 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 claims description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 53
- 239000010949 copper Substances 0.000 abstract description 46
- 229910052802 copper Inorganic materials 0.000 abstract description 44
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 30
- 239000000460 chlorine Substances 0.000 abstract description 30
- 229910052801 chlorine Inorganic materials 0.000 abstract description 30
- 150000004659 dithiocarbamates Chemical class 0.000 abstract description 9
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- 125000001931 aliphatic group Chemical group 0.000 abstract description 4
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- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 66
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 66
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 62
- 239000010408 film Substances 0.000 description 55
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- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 30
- 150000003852 triazoles Chemical class 0.000 description 30
- 238000003756 stirring Methods 0.000 description 29
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- 239000011541 reaction mixture Substances 0.000 description 23
- 239000012964 benzotriazole Substances 0.000 description 22
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 21
- 238000001816 cooling Methods 0.000 description 18
- 238000006731 degradation reaction Methods 0.000 description 16
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- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
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- 238000013019 agitation Methods 0.000 description 11
- 239000000498 cooling water Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 11
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- 238000002360 preparation method Methods 0.000 description 11
- 239000008399 tap water Substances 0.000 description 11
- 235000020679 tap water Nutrition 0.000 description 11
- 230000008901 benefit Effects 0.000 description 10
- 239000012990 dithiocarbamate Substances 0.000 description 10
- 229910000881 Cu alloy Inorganic materials 0.000 description 9
- 239000003139 biocide Substances 0.000 description 9
- 230000008439 repair process Effects 0.000 description 9
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 8
- 238000013459 approach Methods 0.000 description 8
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 238000000840 electrochemical analysis Methods 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
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- 239000002253 acid Substances 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 238000013213 extrapolation Methods 0.000 description 5
- GSFSVEDCYBDIGW-UHFFFAOYSA-N 2-(1,3-benzothiazol-2-yl)-6-chlorophenol Chemical compound OC1=C(Cl)C=CC=C1C1=NC2=CC=CC=C2S1 GSFSVEDCYBDIGW-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- 150000003851 azoles Chemical class 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 description 4
- 229950004394 ditiocarb Drugs 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- LPELBDSLUUVSGT-UHFFFAOYSA-N 4-tert-butyl-2h-benzotriazole Chemical compound CC(C)(C)C1=CC=CC2=C1N=NN2 LPELBDSLUUVSGT-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 238000010349 cathodic reaction Methods 0.000 description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000012989 trithiocarbonate Substances 0.000 description 3
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- NGCCQISMNZBKJJ-UHFFFAOYSA-N 2,6-dichloro-3-methylquinoline Chemical compound ClC1=CC=C2N=C(Cl)C(C)=CC2=C1 NGCCQISMNZBKJJ-UHFFFAOYSA-N 0.000 description 2
- QRNATDQRFAUDKF-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate Chemical compound NC(=S)SCCSC(N)=S QRNATDQRFAUDKF-UHFFFAOYSA-N 0.000 description 2
- FPEANFVVZUKNFU-UHFFFAOYSA-N 2-sulfanylbenzotriazole Chemical compound C1=CC=CC2=NN(S)N=C21 FPEANFVVZUKNFU-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- FRRUHIUCCOWADH-UHFFFAOYSA-L [Na+].[Na+].NC([S-])=S.NC([S-])=S.CC1=CC(=O)CC(C)(C)C1 Chemical compound [Na+].[Na+].NC([S-])=S.NC([S-])=S.CC1=CC(=O)CC(C)(C)C1 FRRUHIUCCOWADH-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- PCERBVBQNKZCFS-UHFFFAOYSA-N dibenzylcarbamodithioic acid Chemical compound C=1C=CC=CC=1CN(C(=S)S)CC1=CC=CC=C1 PCERBVBQNKZCFS-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 238000006056 electrooxidation reaction Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000013101 initial test Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
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- 238000003672 processing method Methods 0.000 description 2
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- 238000011160 research Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- FTLAZYFZXWKGHH-UHFFFAOYSA-M sodium;3-morpholin-4-ylpropan-1-amine;carbamodithioate Chemical compound [Na+].NC([S-])=S.NCCCN1CCOCC1 FTLAZYFZXWKGHH-UHFFFAOYSA-M 0.000 description 2
- DVHOMPKWTYENNE-UHFFFAOYSA-N sodium;morpholine-4-carbodithioic acid Chemical compound [Na+].SC(=S)N1CCOCC1 DVHOMPKWTYENNE-UHFFFAOYSA-N 0.000 description 2
- IUAIJFLWVIJYQA-UHFFFAOYSA-M sodium;n,n-bis(2-methylpropyl)carbamodithioate Chemical compound [Na+].CC(C)CN(C([S-])=S)CC(C)C IUAIJFLWVIJYQA-UHFFFAOYSA-M 0.000 description 2
- UCMANOMWSXCXDP-UHFFFAOYSA-M sodium;n,n-di(propan-2-yl)carbamodithioate Chemical compound [Na+].CC(C)N(C(C)C)C([S-])=S UCMANOMWSXCXDP-UHFFFAOYSA-M 0.000 description 2
- HUMLQUKVJARKRN-UHFFFAOYSA-M sodium;n,n-dibutylcarbamodithioate Chemical compound [Na+].CCCCN(C([S-])=S)CCCC HUMLQUKVJARKRN-UHFFFAOYSA-M 0.000 description 2
- DWVJEMMXXKPJTE-UHFFFAOYSA-M sodium;n,n-dipentylcarbamodithioate Chemical compound [Na+].CCCCCN(C([S-])=S)CCCCC DWVJEMMXXKPJTE-UHFFFAOYSA-M 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- HIZCIEIDIFGZSS-UHFFFAOYSA-L trithiocarbonate Chemical compound [S-]C([S-])=S HIZCIEIDIFGZSS-UHFFFAOYSA-L 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- NJBCRXCAPCODGX-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CNCC(C)C NJBCRXCAPCODGX-UHFFFAOYSA-N 0.000 description 1
- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- BWLUMTFWVZZZND-UHFFFAOYSA-N Dibenzylamine Chemical compound C=1C=CC=CC=1CNCC1=CC=CC=C1 BWLUMTFWVZZZND-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005284 basis set Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- USAIOOFEIMNEDN-UHFFFAOYSA-L disodium;carbonotrithioate Chemical compound [Na+].[Na+].[S-]C([S-])=S USAIOOFEIMNEDN-UHFFFAOYSA-L 0.000 description 1
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 238000009659 non-destructive testing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- ILNWEIMZWZNAKF-UHFFFAOYSA-M sodium;n,n-dipropylcarbamodithioate Chemical compound [Na+].CCCN(C([S-])=S)CCC ILNWEIMZWZNAKF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
- C23F11/162—Thioaldehydes; Thioketones
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55685104P | 2004-03-26 | 2004-03-26 | |
| US11/065,505 US8123982B2 (en) | 2004-03-26 | 2005-02-24 | Sulfur based corrosion inhibitors |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005325442A true JP2005325442A (ja) | 2005-11-24 |
| JP2005325442A5 JP2005325442A5 (https=) | 2008-05-01 |
Family
ID=34864119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005090014A Pending JP2005325442A (ja) | 2004-03-26 | 2005-03-25 | 硫黄ベースの腐食防止剤 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8123982B2 (https=) |
| EP (1) | EP1580301A1 (https=) |
| JP (1) | JP2005325442A (https=) |
| CN (1) | CN1683592A (https=) |
| CA (1) | CA2502255A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016204677A (ja) * | 2015-04-15 | 2016-12-08 | 栗田工業株式会社 | 緑青阻止剤及び緑青阻止方法 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10767268B2 (en) * | 2005-05-06 | 2020-09-08 | Swimc Llc | Articles having improved corrosion resistance |
| US7686980B2 (en) * | 2005-09-30 | 2010-03-30 | Teledyne Scientific & Imaging, Llc | Corrosion inhibitors, methods of production and uses thereof |
| US20110259476A1 (en) * | 2006-09-26 | 2011-10-27 | Corrxan Chemicals Ltd. | Methods for corrosion control of steel in aqueous environment using passive iron-sulphur layers |
| US7849641B2 (en) * | 2007-07-12 | 2010-12-14 | Thor Global Enterprises Ltd. | Undercarriage for a telescopic frame |
| TW200927998A (en) * | 2007-09-06 | 2009-07-01 | Ekc Technology Inc | Compositions and method for treating a copper surface |
| FR2933001B1 (fr) * | 2008-06-27 | 2010-08-20 | Inst Francais Du Petrole | Solution absorbante contenant un inhibiteur de degradation a fonction thiocarbonyle et methode pour limiter la degradation d'une solution absorbante |
| KR101353545B1 (ko) * | 2012-02-14 | 2014-01-23 | 재단법인 국방기술품질원 | 합금강의 부식억제방법 |
| US10323185B2 (en) | 2014-07-02 | 2019-06-18 | United Technologies Corporation | Chemical synthesis of hybrid inorganic-organic nanostructured corrosion inhibitive pigments and methods |
| EP3075883B1 (en) * | 2015-03-31 | 2023-09-20 | Mitsubishi Electric Corporation | Method for corrosion inhibition |
| KR102164614B1 (ko) | 2017-11-24 | 2020-10-12 | 주식회사 엘지화학 | 포토레지스트 조성물 및 이를 이용한 포토레지스트 필름 |
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| JPS51138548A (en) * | 1975-05-26 | 1976-11-30 | Katayama Chemical Works Co | Agent for preventing attaching of marine contaminants and for preventing corrosion of copper |
| JPS63121680A (ja) * | 1986-11-11 | 1988-05-25 | Katayama Chem Works Co Ltd | 銅系金属の防食方法 |
| JPH0625875A (ja) * | 1992-03-02 | 1994-02-01 | Wr Grace & Co Connecticut | 水系内酸素の捕捉方法 |
| JPH0657460A (ja) * | 1992-04-22 | 1994-03-01 | Nalco Chem Co | 水系の腐食防止剤の投与量を監視し制御する方法 |
| JPH09183763A (ja) * | 1995-12-28 | 1997-07-15 | Nippon Soda Co Ltd | ジチオカルバミン酸金属塩水溶液およびその製法 |
| JPH11106428A (ja) * | 1997-10-02 | 1999-04-20 | Kurita Water Ind Ltd | 水処理用ポリマー及び水処理方法 |
| JPH11286794A (ja) * | 1998-02-05 | 1999-10-19 | Mitsubishi Electric Corp | 銅または銅合金材料の表面処理方法 |
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| US2574576A (en) | 1949-10-12 | 1951-11-13 | Pure Oil Co | Prevention of corrosion of steel by brine containing dissolved oxygen |
| US2945781A (en) * | 1958-12-12 | 1960-07-19 | Monsanto Chemicals | Method of controlling nematodes employing alkali metal salt of n-(n-propyl) dithiocarbamate |
| GB1180216A (en) | 1966-04-25 | 1970-02-04 | Reckitt And Sons Ltd | Dithiocarbamates |
| ZA731375B (en) | 1972-03-03 | 1973-11-28 | Lacy G | Ink formulae and method of safeguarding ball pen ink cartridges against crystalline mass at entrance to brass or other copper alloy nib |
| US3898042A (en) * | 1974-01-02 | 1975-08-05 | Dow Chemical Co | Method and apparatus for continuously determining total copper in an aqueous stream |
| US4180469A (en) | 1977-12-30 | 1979-12-25 | Amchem Products, Inc. | Dithiocarbamate sulfonium salt inhibitor composition |
| JPS5538913A (en) | 1978-09-07 | 1980-03-18 | Japan Organo Co Ltd | Preventing method for corrosion of metal immersed in water |
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| JPS5983780A (ja) | 1982-11-04 | 1984-05-15 | Mitsubishi Heavy Ind Ltd | アルミニウム又はアルミニウム合金タンクの防食方法 |
| JPS60217274A (ja) | 1984-04-11 | 1985-10-30 | Mitsubishi Heavy Ind Ltd | 藻類防除、防食処理法 |
| US5089619A (en) | 1984-08-30 | 1992-02-18 | Petrolite Corporation | Methods for treating hydrocarbon recovery operations and industrial waters |
| US4826625A (en) | 1984-08-30 | 1989-05-02 | Petrolite Corporation | Methods for treating hydrocarbon recovery operations and industrial waters |
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| US6139610A (en) | 1996-01-05 | 2000-10-31 | Wayne Pigment Corp. | Hybrid pigment grade corrosion inhibitor compositions and procedures |
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-
2005
- 2005-02-24 US US11/065,505 patent/US8123982B2/en not_active Expired - Fee Related
- 2005-03-10 EP EP05005222A patent/EP1580301A1/en not_active Withdrawn
- 2005-03-24 CA CA002502255A patent/CA2502255A1/en not_active Abandoned
- 2005-03-25 JP JP2005090014A patent/JP2005325442A/ja active Pending
- 2005-03-25 CN CN200510062757.4A patent/CN1683592A/zh active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51138548A (en) * | 1975-05-26 | 1976-11-30 | Katayama Chemical Works Co | Agent for preventing attaching of marine contaminants and for preventing corrosion of copper |
| JPS63121680A (ja) * | 1986-11-11 | 1988-05-25 | Katayama Chem Works Co Ltd | 銅系金属の防食方法 |
| JPH0625875A (ja) * | 1992-03-02 | 1994-02-01 | Wr Grace & Co Connecticut | 水系内酸素の捕捉方法 |
| JPH0657460A (ja) * | 1992-04-22 | 1994-03-01 | Nalco Chem Co | 水系の腐食防止剤の投与量を監視し制御する方法 |
| JPH09183763A (ja) * | 1995-12-28 | 1997-07-15 | Nippon Soda Co Ltd | ジチオカルバミン酸金属塩水溶液およびその製法 |
| JPH11106428A (ja) * | 1997-10-02 | 1999-04-20 | Kurita Water Ind Ltd | 水処理用ポリマー及び水処理方法 |
| JPH11286794A (ja) * | 1998-02-05 | 1999-10-19 | Mitsubishi Electric Corp | 銅または銅合金材料の表面処理方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016204677A (ja) * | 2015-04-15 | 2016-12-08 | 栗田工業株式会社 | 緑青阻止剤及び緑青阻止方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1580301A1 (en) | 2005-09-28 |
| US20050211957A1 (en) | 2005-09-29 |
| CA2502255A1 (en) | 2005-09-26 |
| US8123982B2 (en) | 2012-02-28 |
| CN1683592A (zh) | 2005-10-19 |
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