JP2005023306A - Phosphor for ultraviolet excitation luminescent element - Google Patents
Phosphor for ultraviolet excitation luminescent element Download PDFInfo
- Publication number
- JP2005023306A JP2005023306A JP2004172244A JP2004172244A JP2005023306A JP 2005023306 A JP2005023306 A JP 2005023306A JP 2004172244 A JP2004172244 A JP 2004172244A JP 2004172244 A JP2004172244 A JP 2004172244A JP 2005023306 A JP2005023306 A JP 2005023306A
- Authority
- JP
- Japan
- Prior art keywords
- phosphor
- manufactured
- formula
- ultraviolet
- sio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Luminescent Compositions (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Abstract
Description
本発明は、液晶ディスプレイ用バックライトの冷陰極管に代表される小型の蛍光ランプおよび３波長型蛍光ランプなどの紫外線励起発光素子に好適な蛍光体に関するものである。 The present invention relates to a phosphor suitable for an ultraviolet-excited light emitting device such as a small fluorescent lamp represented by a cold cathode tube of a backlight for a liquid crystal display and a three-wavelength fluorescent lamp.
蛍光体は、液晶ディスプレイ用バックライトの冷陰極管や３波長型蛍光ランプなどの紫外線励起発光素子に用いられている。ここで、紫外線とは、波長が２００ｎｍより長く、４００ｎｍより短い範囲の光であり、紫外線励起発光素子において励起紫外線として、例えば波長２５４ｎｍの水銀輝線などが用いられている。紫外線励起発光素子用蛍光体には高い輝度を示すことが求められており、ＣａＭｇＳｉ2Ｏ6：Ｅｕが提案されている（例えば、特許文献１参照。）が、輝度は十分ではなかった。 Phosphors are used in ultraviolet-excited light-emitting elements such as cold-cathode tubes for liquid crystal display backlights and three-wavelength fluorescent lamps. Here, the ultraviolet light is light having a wavelength longer than 200 nm and shorter than 400 nm. For example, a mercury emission line having a wavelength of 254 nm is used as the excitation ultraviolet light in the ultraviolet excitation light emitting element. The phosphor for ultraviolet-excited light emitting device is required to exhibit high luminance, and CaMgSi 2 O 6 : Eu has been proposed (for example, see Patent Document 1), but the luminance is not sufficient.
本発明の目的は、高い輝度を示す紫外線励起発光素子用の蛍光体を提供することにある。 An object of the present invention is to provide a phosphor for an ultraviolet-excited light emitting device that exhibits high luminance.
本発明者らは、上記の課題を解決すべく蛍光体の組成について鋭意研究を重ねた結果、アルカリ土類金属元素とＭｇおよび／またはＺｎとを含有する特定のケイ酸塩および／またはゲルマン酸塩に付活剤としてＥｕおよび／またはＭｎを含有させてなる蛍光体が、紫外線励起により高い輝度を示すこと見出し、本発明を完成するに到った。 As a result of intensive studies on the composition of the phosphor to solve the above-mentioned problems, the present inventors have found that a specific silicate and / or germanic acid containing an alkaline earth metal element and Mg and / or Zn. It has been found that a phosphor containing Eu and / or Mn as an activator in a salt exhibits high luminance by ultraviolet excitation, and has completed the present invention.
すなわち本発明は、式Ｍ1Ｍ2Ｍ2 3Ｏ6（式中のＭ1はＣａ、ＳｒおよびＢａからなる群より選ばれる２種以上またはＳｒまたはＢａであり、Ｍ2はＭｇおよびＺｎからなる群より選ばれる１種以上であり、Ｍ3はＳｉおよびＧｅからなる群より選ばれる１種以上である。）で表される化合物に付活剤としてＥｕおよびＭｎからなる群より選ばれる１種以上が含有されてなることを特徴とする紫外線励起発光素子用蛍光体を提供する。また本発明は、ディオプサイド（Ｄｉｏｐｓｉｄｅ、透輝石）と同じ結晶構造を有する上記記載の蛍光体を提供する。また本発明は、式（Ｍ1 1-aＥｕa）Ｍ2Ｍ3 2Ｏ6（式中のＭ1、Ｍ2およびＭ3は前記と同じ意味を有し、ａは０を超え０．１以下である。）で表される化合物からなる上記いずれかに記載の蛍光体を提供する。また本発明は、一般式Ｃａ1-b-cＳｒbＥｕcＭｇＳｉ2Ｏ6（ｂは０．０５以上０．４以下、ｃは０を超え０．１以下である。）で表される化合物からなる上記いずれかに記載の蛍光体を提供する。さらに本発明は、上記のいずれかの蛍光体を用いてなることを特徴とする紫外線励起発光素子を提供する。 That is, the present invention relates to the formula M 1 M 2 M 2 3 O 6 (wherein M 1 is two or more selected from the group consisting of Ca, Sr and Ba, or Sr or Ba, and M 2 is selected from Mg and Zn). 1 or more selected from the group consisting of Eu and Mn as an activator for the compound represented by the following formula: M 3 is one or more selected from the group consisting of Si and Ge. Provided is a phosphor for an ultraviolet-excited light emitting device characterized by containing at least seeds. The present invention also provides the above-described phosphor having the same crystal structure as that of diopside. In the present invention, the formula (M 1 1-a Eu a ) M 2 M 3 2 O 6 (wherein M 1 , M 2 and M 3 have the same meaning as described above, 1 or less.) The phosphor according to any one of the above, comprising the compound represented by formula (1): The present invention has the general formula Ca 1-bc Sr b Eu c MgSi 2 O 6 (b 0.05 to 0.4, c is more than 0 is 0.1 or less.) From the compounds represented by A phosphor according to any one of the above is provided. Furthermore, the present invention provides an ultraviolet-excited light emitting device characterized by using any of the phosphors described above.
本発明の紫外線励起発光素子用の蛍光体は、紫外線励起による発光の輝度が高く、液晶ディスプレイ用バックライトの冷陰極管に代表される小型の蛍光ランプ、３波長型蛍光ランプ等の紫外線励起発光素子に用いると、高い輝度を示す紫外線励起発光素子が実現できるので、工業的に極めて有用である。 The phosphor for ultraviolet-excited light emitting device of the present invention has high luminance of light emission by ultraviolet excitation, and ultraviolet-excited light emission such as a small fluorescent lamp represented by a cold cathode tube of a backlight for a liquid crystal display and a three-wavelength fluorescent lamp. When used in an element, an ultraviolet-excited light-emitting element exhibiting high luminance can be realized, which is extremely useful industrially.
本発明の蛍光体は、式（Ｉ）
Ｍ1Ｍ2Ｍ2 3Ｏ6 ・・・（Ｉ）
で示される化合物に付活剤が含有されてなる蛍光体である。式（Ｉ）のＭ1は２価の金属元素であり、Ｃａ、ＳｒおよびＢａからなる群より選ばれる２種以上またはＳｒまたはＢａであり、Ｍ1がＣａの場合は紫外線励起によって高い輝度を示す蛍光体とはならない。式（Ｉ）のＭ2は２価の金属元素であり、ＭｇおよびＺｎからなる群より選ばれる１種以上である。式（Ｉ）のＭ3は４価の金属元素であり、ＳｉおよびＧｅからなる群より選ばれる１種類以上である。付活剤としては、ＥｕおよびＭｎからなる群より選ばれる１種以上を含有する。
The phosphor of the present invention has the formula (I)
M 1 M 2 M 2 3 O 6 (I)
A phosphor in which an activator is contained in the compound represented by M 1 in the formula (I) is a divalent metal element, and two or more selected from the group consisting of Ca, Sr and Ba, or Sr or Ba. When M 1 is Ca, high luminance is obtained by ultraviolet excitation. It is not the phosphor shown. M 2 in the formula (I) is a divalent metal element and is at least one selected from the group consisting of Mg and Zn. M 3 in the formula (I) is a tetravalent metal element and is at least one selected from the group consisting of Si and Ge. The activator contains one or more selected from the group consisting of Eu and Mn.
式（Ｉ）で示される化合物としては、ディオプサイド（Ｄｉｏｐｓｉｄｅ、透輝石）と同じ結晶構造を有する化合物が、それ以外の結晶構造を有する化合物より輝度が高くなる可能性があり、好ましい。 As the compound represented by the formula (I), a compound having the same crystal structure as that of diopside (diopside) may have higher luminance than a compound having another crystal structure, which is preferable.
さらに付活剤としてはＥｕが好ましいので、式（II）
（Ｍ1 1-aＥｕa）Ｍ2Ｍ3 2Ｏ6 ・・・（II）
（式中のＭ1、Ｍ2およびＭ3は前記と同じ意味を有する。）で表される化合物からなる蛍光体がより好ましい。ここで、式（II）において、ａは０．１以下である方がより輝度が高くなる可能性があり好ましい。ただし、ａが０の場合は付活剤のＥｕが含まれないので蛍光体とはならない。
Further, Eu is preferred as the activator, so that the formula (II)
(M 1 1-a Eu a ) M 2 M 3 2 O 6 (II)
A phosphor composed of a compound represented by the formula (M 1 , M 2 and M 3 have the same meaning as described above) is more preferred. Here, in the formula (II), it is preferable that a is 0.1 or less because the luminance may be higher. However, when a is 0, Eu as an activator is not included, so that it does not become a phosphor.
さらに、前記式（III）のＭ1としてはＣａとＳｒの両方が含有される場合、Ｍ2としてはＭｇ、Ｍ3としてはＳｉが好ましいので、式（III）
Ｃａ1-b-cＳｒbＥｕcＭｇＳｉ2Ｏ6 ・・・（III）
で示される化合物からなる蛍光体がさらに好ましい。ここで、式（III）において、ｂは０．０５以上０．４以下の範囲、ｃは０を超え０．１以下の範囲である方が輝度が高くなる可能性があり、好ましい。さらに、ｂは０．２以上０．４以下の範囲、ｃは０．００３を超え０．０５以下の範囲である方がより輝度が高くなる可能性があるのでより好ましい。
Furthermore, when both Ca and Sr are contained as M 1 in the formula (III), Mg is preferable as M 2 and Si is preferable as M 3.
Ca 1-bc Sr b Eu c MgSi 2 O 6 (III)
A phosphor comprising the compound represented by the formula is more preferred. Here, in the formula (III), it is preferable that b is in the range of 0.05 or more and 0.4 or less and c is in the range of more than 0 and 0.1 or less because the luminance may be increased. Furthermore, it is more preferable that b is in the range of 0.2 or more and 0.4 or less and c is in the range of more than 0.003 and 0.05 or less because the luminance may be higher.
また、本発明の蛍光体のうち平均粒径が０．５μｍ以上１５μｍ以下であるものはさらに輝度が高くなる傾向があるので好ましく、平均粒径が２μｍ以上８μｍ以下であるものがより好ましく、３μｍ以上５μｍ以下であるものがさらに好ましい。 Further, among the phosphors of the present invention, those having an average particle diameter of 0.5 μm or more and 15 μm or less are preferable because the luminance tends to be further increased, and those having an average particle diameter of 2 μm or more and 8 μm or less are more preferable, and 3 μm. More preferably, it is 5 μm or less.
次に、本発明の蛍光体の製造方法について説明する。
本発明の蛍光体は、次のようにして製造することができるが、製造方法はこれに限られるものではない。本発明の蛍光体は、焼成により、式（Ｉ）で示される化合物に付活剤としてＥｕおよびＭｎからなる群より選ばれる１種以上を含有させてなる蛍光体となる金属化合物混合物を焼成することにより製造することができる。すなわち、対応する金属元素を含む化合物を所定の組成となるように秤量し、混合した後に焼成することにより製造することができる。例えば、好ましい組成の一つである組成式Ｃａ0.692Ｓｒ0.296Ｅｕ0.012ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体は、ＣａＣＯ3、ＳｒＣＯ3、Ｅｕ2Ｏ3、ＭｇＯ、ＳｉＯ2を、モル比がＣａ：Ｓｒ：Ｅｕ：Ｍｇ：Ｓｉ＝０．６９２：０．２９６：０．０１２：１：２となるように秤量し、混合した後に焼成することにより製造することができる。
Next, a method for manufacturing the phosphor of the present invention will be described.
The phosphor of the present invention can be produced as follows, but the production method is not limited to this. The phosphor of the present invention is fired by firing a metal compound mixture that becomes a phosphor comprising the compound represented by formula (I) containing at least one selected from the group consisting of Eu and Mn as an activator. Can be manufactured. That is, it can be produced by weighing a compound containing a corresponding metal element so as to have a predetermined composition, mixing, and firing. For example, a phosphor composed of a compound represented by the composition formula Ca 0.692 Sr 0.296 Eu 0.012 MgSi 2 O 6 , which is one of preferred compositions, contains CaCO 3 , SrCO 3 , Eu 2 O 3 , MgO, and SiO 2 in moles. It can be manufactured by weighing so that the ratio is Ca: Sr: Eu: Mg: Si = 0.692: 0.296: 0.012: 1: 2, mixing, and firing.
対応する金属元素を含む化合物としては、カルシウム化合物、ストロンチウム化合物、バリウム化合物、マグネシウム化合物、亜鉛化合物、ケイ素化合物、ゲルマニウム化合物として、例えば高純度（９９％以上）の水酸化物、炭酸塩、硝酸塩、ハロゲン化物、シュウ酸塩など高温で分解して酸化物になりうるものかまたは高純度（純度９９重量％以上）の酸化物が使用できる。 As a compound containing a corresponding metal element, calcium compound, strontium compound, barium compound, magnesium compound, zinc compound, silicon compound, germanium compound, for example, high purity (99% or more) hydroxide, carbonate, nitrate, A halide, an oxalate, or the like that can be decomposed into an oxide at a high temperature or an oxide having a high purity (purity 99% by weight or more) can be used.
付活剤となるＥｕおよびＭｎを含む化合物としては、例えばそれらの金属元素の高純度（純度９９重量％以上）の水酸化物、炭酸塩、硝酸塩、ハロゲン化物、シュウ酸塩など高温で分解し酸化物になりうるものかまたは高純度（純度９９重量％以上）の酸化物が使用できる。 Examples of compounds containing Eu and Mn as activators decompose at high temperatures such as high purity (purity 99 wt% or more) hydroxides, carbonates, nitrates, halides and oxalates of those metal elements. An oxide which can be an oxide or a high purity (purity 99% by weight or more) can be used.
これらの原料の混合には、例えばボールミル、Ｖ型混合機、攪拌機等の通常工業的に用いられている装置を用いることができる。 For mixing these raw materials, for example, a generally industrially used apparatus such as a ball mill, a V-type mixer or a stirrer can be used.
混合した後、例えば９００℃以上１５００℃以下の温度範囲にて１〜１００時間保持して焼成することにより本発明の蛍光体が得られる。原料に水酸化物、炭酸塩、硝酸塩、ハロゲン化物、シュウ酸塩など高温で分解し酸化物になりうるものを使用した場合、本焼成の前に、例えば４００℃以上９００℃未満の温度範囲にて仮焼して酸化物としたり、結晶水を除去することも可能である。 After mixing, for example, the phosphor of the present invention is obtained by holding and firing for 1 to 100 hours in a temperature range of 900 ° C. or more and 1500 ° C. or less. When using raw materials that can be decomposed into oxides at high temperatures such as hydroxide, carbonate, nitrate, halide, oxalate, etc., before the main firing, for example, in a temperature range of 400 ° C. or higher and lower than 900 ° C. It can be calcined to form an oxide or crystal water can be removed.
焼成雰囲気としては、特に限定されるものではないが、例えば水素を０．１〜１０体積％含む窒素やアルゴン等の還元性雰囲気で焼成することが好ましい。またさらに強い還元雰囲気で焼成するために、適量の炭素を添加して焼成してもよい。また仮焼の雰囲気は、大気雰囲気、還元性雰囲気のいずれでもよい。 The firing atmosphere is not particularly limited. For example, firing is preferably performed in a reducing atmosphere such as nitrogen or argon containing 0.1 to 10% by volume of hydrogen. Further, in order to fire in a stronger reducing atmosphere, an appropriate amount of carbon may be added and fired. The calcination atmosphere may be either an air atmosphere or a reducing atmosphere.
また、カルシウム化合物、ストロンチウム化合物、バリウム化合物、マグネシウム化合物、亜鉛化合物、ユーロピウム化合物、マンガン化合物として、フッ化物、塩化物を用いることにより、生成する蛍光体の結晶性を高めることおよび／または平均粒径を大きくすることができる。生成する蛍光体の結晶性を高めるためおよび／または平均粒径を大きくするために、適量のフラックスを添加してもよい。フラックスとしては、例えば、ＬｉＦ、ＮａＦ、ＫＦ、ＬｉＣｌ、ＮａＣｌ、ＫＣｌ、Ｌｉ2ＣＯ3、Ｎａ2ＣＯ3、Ｋ2ＣＯ3、ＮａＨＣＯ3、ＮＨ4Ｃｌ、ＮＨ4Ｉなどを挙げることができる。 In addition, the use of fluorides and chlorides as calcium compounds, strontium compounds, barium compounds, magnesium compounds, zinc compounds, europium compounds and manganese compounds increases the crystallinity of the phosphors produced and / or the average particle size. Can be increased. In order to increase the crystallinity of the phosphor to be produced and / or to increase the average particle size, an appropriate amount of flux may be added. Examples of the flux include LiF, NaF, KF, LiCl, NaCl, KCl, Li 2 CO 3 , Na 2 CO 3 , K 2 CO 3 , NaHCO 3 , NH 4 Cl, and NH 4 I.
さらに、上記に説明した製造方法により得られる蛍光体を、例えばボールミル、ジェットミル等を用いて粉砕することができる。また、洗浄、分級することができる。また、得られる蛍光体の輝度をさらに向上させるために、再焼成を行うこともできる。 Furthermore, the phosphor obtained by the manufacturing method described above can be pulverized using, for example, a ball mill, a jet mill or the like. It can also be washed and classified. Moreover, in order to further improve the brightness | luminance of the fluorescent substance obtained, rebaking can also be performed.
ここで、本発明の蛍光体を用いてなる紫外線励起発光表示素子の例として、高負荷蛍光ランプ（ランプの管壁の単位面積当りの消費電力が大きな小型の蛍光ランプ）を挙げてその製造方法について説明する。高負荷蛍光ランプの作製方法としては例えば、特開平１０−２５１６３６号公報に開示されているような公知の方法が使用できる。すなわち、青色、緑色、赤色発光用各種蛍光体を、例えば、ポリエチレンオキサイド水溶液などに分散して蛍光体塗布液を作製する。この塗布液をガラス管内壁に塗布し乾燥を行ったあと、３００〜６００℃の温度範囲で焼成し、蛍光体層を形成させる。これに、フィラメントを装着したのち、排気など通常の工程を経て、低圧のＡｒ、ＫｒやＮｅ等の希ガスおよび水銀を封入して口金を取り付けて放電空間を形成させることにより、高負荷蛍光ランプを作製することができる。 Here, as an example of an ultraviolet-excited light-emitting display element using the phosphor of the present invention, a high-load fluorescent lamp (a small fluorescent lamp with large power consumption per unit area of the lamp tube wall) is given and its manufacturing method Will be described. As a method for producing a high load fluorescent lamp, for example, a known method as disclosed in JP-A-10-251636 can be used. That is, various phosphors for emitting blue, green, and red light are dispersed in, for example, a polyethylene oxide aqueous solution to prepare a phosphor coating solution. This coating solution is applied to the inner wall of the glass tube and dried, and then baked in a temperature range of 300 to 600 ° C. to form a phosphor layer. A high load fluorescent lamp is formed by attaching a filament to this, passing through a normal process such as exhaust, enclosing rare gas such as low pressure Ar, Kr and Ne and mercury and attaching a base to form a discharge space. Can be produced.
本発明によって得られる蛍光体は、例えば、紫外線（例えば、波長２５４ｎｍの水銀輝線）の励起により青色に強く発光するので、液晶ディスプレイ用バックライトの冷陰極管に代表される小型の蛍光ランプ、３波長型蛍光ランプ等の紫外線励起発光素子用に好適である。 The phosphor obtained by the present invention, for example, emits strong blue light when excited by ultraviolet rays (for example, a mercury emission line having a wavelength of 254 nm). Therefore, a small fluorescent lamp typified by a cold cathode tube of a backlight for liquid crystal displays, 3 It is suitable for an ultraviolet-excited light emitting element such as a wavelength fluorescent lamp.
次に、本発明を実施例によりさらに詳しく説明するが、本発明はこれらの実施例に限定されるものではない。 EXAMPLES Next, although an Example demonstrates this invention further in detail, this invention is not limited to these Examples.
比較例１
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素ＳｉＯ2（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．９９２：０．００４：１：２になるように秤量し、混合した後、２体積％Ｈ2含有Ｎ2雰囲気中で１２００℃の温度で２時間保持して焼成した。焼成は３回行った。このようにして組成式がＣａ0.992Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。得られた蛍光体の走査型電子顕微鏡による写真から平均粒径をインターセプト法により測定した結果、０．４μｍであった。この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示した。得られた輝度を１００とし、以下の実施例における蛍光体の輝度は相対輝度により示した。
Comparative Example 1
Calcium carbonate (manufactured by Ube Materials Co., CaCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate (manufactured by Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide SiO 2 ( Nippon Aerosil Co., Ltd., SiO 2 ) Each raw material was weighed and mixed so that the molar ratio of CaCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 was 0.992: 0.004: 1: 2. Thereafter, it was fired in a N 2 atmosphere containing 2% by volume of H 2 at a temperature of 1200 ° C. for 2 hours. Firing was performed three times. Thus, a phosphor composed of a compound represented by the composition formula Ca 0.992 Eu 0.008 MgSi 2 O 6 was obtained. As a result of measuring the average particle diameter by the intercept method from a photograph of the obtained phosphor by a scanning electron microscope, it was 0.4 μm. When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light. The obtained luminance was set to 100, and the luminance of the phosphors in the following examples was represented by relative luminance.
実施例１
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素ＳｉＯ2（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．９３２：０．０６：０．００４：１：２になるように秤量し、混合した後、２体積％Ｈ2含有Ｎ2雰囲気中で１１８０℃の温度で２時間保持して焼成した。焼成は３回行った。このようにして組成式がＣａ0.932Ｓｒ0.06Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。
Example 1
Calcium carbonate (manufactured by Ube Materials Co., Ltd., CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide SiO 2 (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) Each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 is 0 932: 0.06: 0.004: 1: 2 were weighed and mixed, and then calcined by holding at a temperature of 1180 ° C. for 2 hours in a N 2 atmosphere containing 2 % by volume of H 2 . Firing was performed three times. Thus, a phosphor composed of a compound represented by the composition formula Ca 0.932 Sr 0.06 Eu 0.008 MgSi 2 O 6 was obtained.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示した。その相対輝度は１３６であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light. Its relative luminance was 136.
実施例２
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素ＳｉＯ2（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．８９２：０．１０：０．００４：１：２になるように秤量し、混合した後、２体積％Ｈ2含有Ｎ2雰囲気中で１２００℃の温度で２時間保持して焼成した。焼成は３回行った。このようにして組成式がＣａ0.892Ｓｒ0.1Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。得られた蛍光体の走査型電子顕微鏡による写真から平均粒径をインターセプト法により測定した結果、０．８μｍであった。
Example 2
Calcium carbonate (manufactured by Ube Materials, CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide SiO 2 (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) Each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 is 0 892: 0.10: 0.004: 1: 2 Weighed and mixed, and then calcined by maintaining at a temperature of 1200 ° C. for 2 hours in a N 2 atmosphere containing 2 % by volume of H 2 . Firing was performed three times. Thus, a phosphor composed of a compound represented by the composition formula Ca 0.892 Sr 0.1 Eu 0.008 MgSi 2 O 6 was obtained. The average particle size was measured by the intercept method from a photograph taken with a scanning electron microscope of the obtained phosphor. As a result, it was 0.8 μm.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示した。その相対輝度は１６３であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light. Its relative luminance was 163.
実施例３
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．７９２：０．２：０．００４：１：２になるように秤量し、混合した後、２体積％Ｈ2含有Ｎ2雰囲気中で１１８０℃の温度で２時間保持して焼成した。焼成は３回行った。このようにして組成式がＣａ0.792Ｓｒ0.2Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。
Example 3
Calcium carbonate (manufactured by Ube Materials Co., Ltd., CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ), each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 of 0.792. : Weighed to 0.2: 0.004: 1: 2, mixed, and then calcined by holding at a temperature of 1180 ° C. for 2 hours in an N 2 atmosphere containing 2 % by volume of H 2 . Firing was performed three times. Thus, a phosphor composed of a compound represented by the composition formula Ca 0.792 Sr 0.2 Eu 0.008 MgSi 2 O 6 was obtained.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示した。その相対輝度は２１３であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light. Its relative luminance was 213.
実施例４
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．６９２：０．３：０．００４：１：２になるように秤量し、混合した後、２体積％Ｈ2含有Ｎ2雰囲気中で１１８０℃の温度で２時間保持して焼成した。焼成は３回行った。このようにして組成式がＣａ0.692Ｓｒ0.3Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。
Example 4
Calcium carbonate (manufactured by Ube Materials Co., Ltd., CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 of 0.692. : 0.3: 0.004: 1: 2 Weighed and mixed, and then calcined by holding at 1180 ° C. for 2 hours in N 2 atmosphere containing 2 % by volume H 2 . Firing was performed three times. Thus, a phosphor composed of a compound represented by the composition formula Ca 0.692 Sr 0.3 Eu 0.008 MgSi 2 O 6 was obtained.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示した。その相対輝度は２２６であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light. Its relative luminance was 226.
実施例５
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．６９２：０．２９６：０．００６：１：２になるように秤量し、混合した後、２体積％Ｈ2含有Ｎ2雰囲気中で１１８０℃の温度で２時間保持して焼成した。焼成は３回行った。このようにして組成式がＣａ0.692Ｓｒ0.296Ｅｕ0.012ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。
Example 5
Calcium carbonate (manufactured by Ube Materials Co., Ltd., CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 of 0.692. : 0.296: 0.006: 1: 2 Weighed and mixed, and then calcined by holding at 1180 ° C. for 2 hours in N 2 atmosphere containing 2 % by volume of H 2 . Firing was performed three times. Thus, a phosphor comprising a compound represented by the composition formula Ca 0.692 Sr 0.296 Eu 0.012 MgSi 2 O 6 was obtained.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示した。その相対輝度は２３１であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light. Its relative luminance was 231.
実施例６
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、フッ化ユーロピウム（和光純薬工業（株）製、ＥｕＦ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：ＥｕＦ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．９２：０．０５：０．０３：１：２になるように秤量し、混合した後、２体積％Ｈ2含有Ｎ2雰囲気中で１２００℃の温度で２時間保持して焼成した。焼成は２回行った。このようにして組成式がＣａ0.92Ｓｒ0.05Ｅｕ0.03ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。得られた蛍光体の走査型電子顕微鏡による写真から平均粒径をインターセプト法により測定した結果、３μｍであった。
Example 6
Calcium carbonate (Ube Materials Co., Ltd., CaCO 3 ), Strontium carbonate (Wako Pure Chemical Industries, Ltd., SrCO 3 ), Europium fluoride (Wako Pure Chemical Industries, Ltd., EuF 3 ), magnesium carbonate (Made by Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) Each raw material has a molar ratio of CaCO 3 : SrCO 3 : EuF 3 : MgCO 3 : SiO 2 of 0.92: After weighing and mixing so as to be 0.05: 0.03: 1: 2, the mixture was calcined by holding at a temperature of 1200 ° C. for 2 hours in a N 2 atmosphere containing 2 % by volume of H 2 . Firing was performed twice. Thus, a phosphor composed of a compound represented by the composition formula Ca 0.92 Sr 0.05 Eu 0.03 MgSi 2 O 6 was obtained. It was 3 micrometers as a result of measuring the average particle diameter by the intercept method from the photograph by the scanning electron microscope of the obtained fluorescent substance.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示した。その相対輝度は２１０であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light. Its relative luminance was 210.
実施例７
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素ＳｉＯ2（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．８９２：０．１０：０．００４：１：２になるように秤量し、混合した後、さらに塩化アンモニウム（和光純薬工業株式会社製、ＮＨ4Ｃｌ）を前記金属化合物の混合物との合計量に対して５重量％になるように秤取し、混合した。得られた混合物を大気中で１１００℃で２時間保持して焼成した後、さらに２体積％Ｈ2含有Ｎ2雰囲気中で１１８０℃の温度で２時間保持して焼成した。このようにして組成式がＣａ0.892Ｓｒ0.1Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。得られた蛍光体の走査型電子顕微鏡による写真から平均粒径をインターセプト法により測定した結果、１．０μｍであった。
Example 7
Calcium carbonate (manufactured by Ube Materials Co., Ltd., CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide SiO 2 (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) Each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 is 0 .892: 0.10: 0.004: 1: 2 Weighed and mixed, and then ammonium chloride (manufactured by Wako Pure Chemical Industries, Ltd., NH 4 Cl) was added to the mixture of the metal compounds. The sample was weighed so as to be 5% by weight and mixed. The obtained mixture was calcined by being held at 1100 ° C. for 2 hours in the atmosphere, and further calcined by being kept at a temperature of 1180 ° C. for 2 hours in a N 2 atmosphere containing 2 % by volume of H 2 . Thus, a phosphor composed of a compound represented by the composition formula Ca 0.892 Sr 0.1 Eu 0.008 MgSi 2 O 6 was obtained. The average particle diameter was measured by the intercept method from a photograph taken with a scanning electron microscope of the obtained phosphor. As a result, it was 1.0 μm.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示し、その相対輝度は２１４であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light, and its relative luminance was 214.
実施例８
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素ＳｉＯ2（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．８９２：０．１０：０．００４：１：２になるように秤量し、混合した後、さらに塩化アンモニウム（和光純薬工業株式会社製、ＮＨ4Ｃｌ）を前記金属化合物の混合物との合計量に対して５重量％になるように秤取し、混合した。得られた混合物を大気中で１１８０℃で２時間保持して焼成した後、さらに２体積％Ｈ2含有Ｎ2雰囲気中で１１８０℃の温度で２時間保持して焼成した。このようにして組成式がＣａ0.892Ｓｒ0.1Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。得られた蛍光体の走査型電子顕微鏡による写真から平均粒径をインターセプト法により測定した結果、１．６μｍであった。
Example 8
Calcium carbonate (manufactured by Ube Materials Co., CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide SiO 2 (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) Each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 is 0 .892: 0.10: 0.004: 1: 2 Weighed and mixed, and then ammonium chloride (manufactured by Wako Pure Chemical Industries, Ltd., NH 4 Cl) was added to the mixture of the metal compounds. The sample was weighed to 5% by weight and mixed. The obtained mixture was baked by being held at 1180 ° C. for 2 hours in the air, and further baked by being held at a temperature of 1180 ° C. for 2 hours in an N 2 atmosphere containing 2 % by volume of H 2 . Thus, a phosphor composed of a compound represented by the composition formula Ca 0.892 Sr 0.1 Eu 0.008 MgSi 2 O 6 was obtained. The average particle diameter was measured by the intercept method from a photograph taken with a scanning electron microscope of the obtained phosphor. As a result, it was 1.6 μm.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示し、その相対輝度は２２５であった。 When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light and had a relative luminance of 225.
実施例９
炭酸カルシウム（宇部マテリアルズ（株）製、ＣａＣＯ3）、炭酸ストロンチウム（和光純薬工業（株）製、ＳｒＣＯ3）、酸化ユーロピウム（信越化学（株）製、Ｅｕ2Ｏ3）、炭酸マグネシウム（協和化学（株）製、ＭｇＣＯ3）、酸化ケイ素ＳｉＯ2（日本アエロジル（株）製、ＳｉＯ2）各原料をＣａＣＯ3：ＳｒＣＯ3：Ｅｕ2Ｏ3：ＭｇＣＯ3：ＳｉＯ2のモル比が０．８９２：０．１０：０．００４：１：２になるように秤量し、混合した後、さらに塩化アンモニウム（和光純薬工業株式会社製、ＮＨ4Ｃｌ）を前記金属化合物の混合物との合計量に対して５重量％になるように秤取し、混合した。得られた混合物を大気中で６００℃で６時間保持して焼成した後、さらに２体積％Ｈ2含有Ｎ2雰囲気中で１１８０℃の温度で２時間保持して焼成した。このようにして組成式がＣａ0.892Ｓｒ0.1Ｅｕ0.008ＭｇＳｉ2Ｏ6で表される化合物からなる蛍光体を得た。得られた蛍光体の走査型電子顕微鏡による写真から平均粒径をインターセプト法により測定した結果、２．０μｍであった。
Example 9
Calcium carbonate (manufactured by Ube Materials Co., Ltd., CaCO 3 ), strontium carbonate (manufactured by Wako Pure Chemical Industries, Ltd., SrCO 3 ), europium oxide (manufactured by Shin-Etsu Chemical Co., Ltd., Eu 2 O 3 ), magnesium carbonate ( Kyowa Chemical Co., Ltd., MgCO 3 ), silicon oxide SiO 2 (manufactured by Nippon Aerosil Co., Ltd., SiO 2 ) Each raw material has a molar ratio of CaCO 3 : SrCO 3 : Eu 2 O 3 : MgCO 3 : SiO 2 is 0 .892: 0.10: 0.004: 1: 2 Weighed and mixed, and then ammonium chloride (manufactured by Wako Pure Chemical Industries, Ltd., NH 4 Cl) was added to the mixture of the metal compounds. The sample was weighed so as to be 5% by weight and mixed. The obtained mixture was baked by holding at 600 ° C. for 6 hours in the atmosphere, and further baked by holding at 1180 ° C. for 2 hours in a N 2 atmosphere containing 2 % by volume of H 2 . Thus, a phosphor composed of a compound represented by the composition formula Ca 0.892 Sr 0.1 Eu 0.008 MgSi 2 O 6 was obtained. It was 2.0 micrometers as a result of measuring an average particle diameter by the intercept method from the photograph with the scanning electron microscope of the obtained fluorescent substance.
この蛍光体を波長２５４ｎｍの水銀輝線の紫外線により励起すると、青色の発光を示し、その相対輝度は２３３であった。
When this phosphor was excited by ultraviolet rays with a mercury emission line having a wavelength of 254 nm, it emitted blue light and had a relative luminance of 233.
Claims (5)
An ultraviolet-excited light emitting element comprising the phosphor according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004172244A JP4572588B2 (en) | 2003-06-11 | 2004-06-10 | Phosphor for UV-excited light emitting device |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003166085 | 2003-06-11 | ||
| JP2004172244A JP4572588B2 (en) | 2003-06-11 | 2004-06-10 | Phosphor for UV-excited light emitting device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005023306A true JP2005023306A (en) | 2005-01-27 |
| JP4572588B2 JP4572588B2 (en) | 2010-11-04 |
Family
ID=34196960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004172244A Expired - Fee Related JP4572588B2 (en) | 2003-06-11 | 2004-06-10 | Phosphor for UV-excited light emitting device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4572588B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006152137A (en) * | 2004-11-30 | 2006-06-15 | Sumitomo Chemical Co Ltd | Fluorescent substance for ultraviolet ray-excited light-emitting element |
| JP2006219635A (en) * | 2005-02-14 | 2006-08-24 | Univ Of Tokyo | Phosphor, manufacturing method trhereof and plasma display panel using the phosphor |
| JP2006232906A (en) * | 2005-02-23 | 2006-09-07 | Sumitomo Chemical Co Ltd | Fluorescent substance and light-emitting apparatus using the same |
| EP1764403A2 (en) | 2005-09-07 | 2007-03-21 | Canon Kabushiki Kaisha | Fluorescent material,fluorescent substance, display, and process for preparing fluorescent substance |
| KR101261076B1 (en) * | 2005-02-23 | 2013-05-06 | 스미또모 가가꾸 가부시끼가이샤 | Phosphor, light emitting device and white light emitting diode |
| EP2677017A4 (en) * | 2011-02-14 | 2015-08-19 | Koito Mfg Co Ltd | Method for producing fluorescent substance |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002285147A (en) * | 2001-03-22 | 2002-10-03 | Nec Lighting Ltd | Fluorescent substance and lamp using the same |
| JP2002332481A (en) * | 2000-09-29 | 2002-11-22 | Sumitomo Chem Co Ltd | Fluorescent substance for vacuum ultraviolet-exited light emitting diode |
| JP2003142004A (en) * | 2001-10-31 | 2003-05-16 | Hitachi Ltd | Luminous device and display device using the same |
-
2004
- 2004-06-10 JP JP2004172244A patent/JP4572588B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002332481A (en) * | 2000-09-29 | 2002-11-22 | Sumitomo Chem Co Ltd | Fluorescent substance for vacuum ultraviolet-exited light emitting diode |
| JP2002285147A (en) * | 2001-03-22 | 2002-10-03 | Nec Lighting Ltd | Fluorescent substance and lamp using the same |
| JP2003142004A (en) * | 2001-10-31 | 2003-05-16 | Hitachi Ltd | Luminous device and display device using the same |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006152137A (en) * | 2004-11-30 | 2006-06-15 | Sumitomo Chemical Co Ltd | Fluorescent substance for ultraviolet ray-excited light-emitting element |
| JP2006219635A (en) * | 2005-02-14 | 2006-08-24 | Univ Of Tokyo | Phosphor, manufacturing method trhereof and plasma display panel using the phosphor |
| JP4683949B2 (en) * | 2005-02-14 | 2011-05-18 | 正純 石川 | Phosphor, method for manufacturing the same, and plasma display panel using the phosphor |
| JP2006232906A (en) * | 2005-02-23 | 2006-09-07 | Sumitomo Chemical Co Ltd | Fluorescent substance and light-emitting apparatus using the same |
| KR101261076B1 (en) * | 2005-02-23 | 2013-05-06 | 스미또모 가가꾸 가부시끼가이샤 | Phosphor, light emitting device and white light emitting diode |
| EP1764403A2 (en) | 2005-09-07 | 2007-03-21 | Canon Kabushiki Kaisha | Fluorescent material,fluorescent substance, display, and process for preparing fluorescent substance |
| EP2677017A4 (en) * | 2011-02-14 | 2015-08-19 | Koito Mfg Co Ltd | Method for producing fluorescent substance |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4572588B2 (en) | 2010-11-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100760882B1 (en) | Fluorescent substances for vacuum ultraviolet radiation excited light-emitting devices | |
| JP3985478B2 (en) | Phosphor for vacuum ultraviolet light-excited light emitting device | |
| JP2006232906A (en) | Fluorescent substance and light-emitting apparatus using the same | |
| JP4572588B2 (en) | Phosphor for UV-excited light emitting device | |
| JP2005272831A (en) | Method for producing silicate phosphor | |
| KR20030051345A (en) | Method for producing silicate phosphor | |
| JP4770160B2 (en) | Phosphor for UV-excited light emitting device | |
| US7791261B2 (en) | Ultraviolet excited light-emitting device | |
| JP4702565B2 (en) | Manganese-activated rare earth aluminate phosphor and fluorescent lamp using the same | |
| JP2004352936A (en) | Preparation method of silicate phosphor | |
| JP2006265377A (en) | Fluorophor for electron beam excitation light emitting devices | |
| JP4325364B2 (en) | Method for manufacturing phosphor | |
| JP4222099B2 (en) | Phosphor for vacuum ultraviolet light-emitting device | |
| JP4032173B2 (en) | Phosphor and light emitting device | |
| JP3915504B2 (en) | Method for producing silicate phosphor | |
| JP4228628B2 (en) | Phosphor for vacuum ultraviolet light-emitting device | |
| JP2008195807A (en) | Vacuum ultraviolet light-excited aluminate phosphor and device for emitting vacuum ultraviolet light-excited light by using the same | |
| JPH09157644A (en) | Aluminate fluorescent substance, its production and discharge apparatus using the same fluorescent substance | |
| JP2008208325A (en) | Alkali earth metal aluminate phosphor and fluorescent lamp using it | |
| JP2005126704A (en) | Fluorescent substance | |
| JP2005154770A (en) | Green light-emitting phosphor for vacuum ultraviolet-excited light-emitting device, method of preparing the same, and light-emitting device including the same | |
| JP2006104445A (en) | Fluorescent substance for vacuum ultraviolet-excited light-emitting diode | |
| JP2004091538A (en) | Vacuum ultraviolet light-exciting fluorescent substance and light-emitting element | |
| JP4656089B2 (en) | Phosphor for vacuum ultraviolet light-excited light emitting device | |
| JP4556310B2 (en) | Method for producing aluminate phosphor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070412 |
|
| RD05 | Notification of revocation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7425 Effective date: 20080130 |
|
| RD05 | Notification of revocation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7425 Effective date: 20080513 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20091117 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20091124 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091217 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100427 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100720 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100802 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130827 Year of fee payment: 3 |
|
| LAPS | Cancellation because of no payment of annual fees |