JP2004513086A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2004513086A5 JP2004513086A5 JP2002525083A JP2002525083A JP2004513086A5 JP 2004513086 A5 JP2004513086 A5 JP 2004513086A5 JP 2002525083 A JP2002525083 A JP 2002525083A JP 2002525083 A JP2002525083 A JP 2002525083A JP 2004513086 A5 JP2004513086 A5 JP 2004513086A5
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- reaction
- aromatic
- general formula
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 description 18
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
- 239000010457 zeolite Substances 0.000 description 15
- 229910021536 Zeolite Inorganic materials 0.000 description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 14
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical class NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 6
- 150000003961 organosilicon compounds Chemical class 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 238000006462 rearrangement reaction Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2000MI001959A IT1318686B1 (it) | 2000-09-07 | 2000-09-07 | Procedimento per la sintesi di miscele di metilendianilina e suoiomologhi superiori con distribuzione controllata degli isomeri. |
| ITMI2000A001959 | 2000-09-07 | ||
| PCT/EP2001/010369 WO2002020458A1 (en) | 2000-09-07 | 2001-09-07 | Process for the synthesis of mixtures of methane diphenyl diamine and its higher homologues with a controlled isomer distribution |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004513086A JP2004513086A (ja) | 2004-04-30 |
| JP2004513086A5 true JP2004513086A5 (enExample) | 2008-10-30 |
| JP4890727B2 JP4890727B2 (ja) | 2012-03-07 |
Family
ID=11445761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002525083A Expired - Fee Related JP4890727B2 (ja) | 2000-09-07 | 2001-09-07 | 制御された異性体分布をもったメタンジフェニルジアミンとその高級同族体の混合物の合成方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6936737B2 (enExample) |
| EP (1) | EP1355874B1 (enExample) |
| JP (1) | JP4890727B2 (enExample) |
| KR (1) | KR100817008B1 (enExample) |
| CN (1) | CN1257148C (enExample) |
| AT (1) | ATE464282T1 (enExample) |
| AU (1) | AU2001293801A1 (enExample) |
| BR (1) | BR0113790A (enExample) |
| IT (1) | IT1318686B1 (enExample) |
| PT (1) | PT1355874E (enExample) |
| WO (1) | WO2002020458A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010019844A1 (en) | 2008-08-14 | 2010-02-18 | Dow Global Technologies Inc. | Production of mixtures of methylenedianiline and its higher homologues using calcined metal oxide-silica catalysts |
| EP2495032A1 (de) | 2011-03-03 | 2012-09-05 | Umicore Ag & Co. Kg | SCR-Katalysator mit verbesserter Kohlenwasserstoffresistenz |
| JP5972913B2 (ja) * | 2011-03-03 | 2016-08-17 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトＵｍｉｃｏｒｅ ＡＧ ＆ Ｃｏ．ＫＧ | 窒素酸化物の選択的触媒還元を行うための触媒活性材料および触媒コンバータ |
| KR20170031157A (ko) | 2014-07-07 | 2017-03-20 | 코베스트로 도이칠란트 아게 | 디페닐메탄 시리즈의 디아민 및 폴리아민의 제조 방법 |
| US10538480B2 (en) | 2016-06-30 | 2020-01-21 | Covestro Deutschland Ag | Process for the production of di- and polyamines of the diphenylmethane series |
| WO2025086031A1 (zh) * | 2023-10-23 | 2025-05-01 | 万华化学集团股份有限公司 | 一种二苯基甲烷系列二胺和多胺的制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3442795A (en) * | 1963-02-27 | 1969-05-06 | Mobil Oil Corp | Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom |
| US3728408A (en) * | 1969-05-05 | 1973-04-17 | Mobil Oil Corp | Conversion of polar compounds using highly siliceous zeolite-type catalysts |
| US4039581A (en) * | 1975-06-27 | 1977-08-02 | The Upjohn Company | Process for the preparation of di(amino phenyl)methanes |
| US4039580A (en) * | 1975-07-24 | 1977-08-02 | The Upjohn Company | Process for preparing di(aminophenyl)methanes |
| US4294987A (en) * | 1979-12-31 | 1981-10-13 | The Upjohn Company | Process for preparing methylene dianilines |
| DE3783199T2 (de) * | 1986-10-22 | 1993-04-29 | Enichem Sintesi | Verfahren zur herstellung von 4,4' diaminodiphenylmethan und derivaten davon. |
| US5241119A (en) * | 1986-10-22 | 1993-08-31 | Eniricerche S.P.A. | Process for the preparation of 4,4'-diaminodiphenyl-methane and its derivatives |
| AU612786B2 (en) * | 1988-02-15 | 1991-07-18 | Mitsui Petrochemical Industries, Ltd. | Method of preparing 4,4'-methylenedianiline |
| IT1312331B1 (it) * | 1999-05-27 | 2002-04-15 | Enichem Spa | Procedimento per la produzione di diamminodifenilmetano e suoiomologhi superiori. |
-
2000
- 2000-09-07 IT IT2000MI001959A patent/IT1318686B1/it active
-
2001
- 2001-09-07 CN CNB018152147A patent/CN1257148C/zh not_active Expired - Fee Related
- 2001-09-07 JP JP2002525083A patent/JP4890727B2/ja not_active Expired - Fee Related
- 2001-09-07 US US10/363,881 patent/US6936737B2/en not_active Expired - Fee Related
- 2001-09-07 AU AU2001293801A patent/AU2001293801A1/en not_active Abandoned
- 2001-09-07 KR KR1020037003323A patent/KR100817008B1/ko not_active Expired - Fee Related
- 2001-09-07 WO PCT/EP2001/010369 patent/WO2002020458A1/en not_active Ceased
- 2001-09-07 PT PT01974234T patent/PT1355874E/pt unknown
- 2001-09-07 BR BR0113790-5A patent/BR0113790A/pt not_active Application Discontinuation
- 2001-09-07 EP EP01974234A patent/EP1355874B1/en not_active Expired - Lifetime
- 2001-09-07 AT AT01974234T patent/ATE464282T1/de not_active IP Right Cessation
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1024654C (zh) | 将芳香化合物烷基化制备富含对位取代异构体的烷基化物的方法 | |
| US4740620A (en) | Alkylation of aromatic amines in the presence of acidic, crystalline molecular sieves | |
| CN1057529C (zh) | 使用表面酸性减活化的沸石催化剂生产三亚乙基二胺 | |
| JP3049602B2 (ja) | 触媒として塩基処理されたゼオライトを使用するトリエチレンジアミンの合成 | |
| JP2004513086A5 (enExample) | ||
| KR100385779B1 (ko) | 디아미노디페닐메탄 및 그것의 고급 동족체의 제조 방법 | |
| WO2016099408A1 (en) | A process for improving stability of zeolite catalyst to use in cumene production by alkylation of benzene with isopropyl alchol | |
| JP2003529577A5 (ja) | メチレンジアニリン及びその高級同族体製品の混合物の製造方法 | |
| JP4890727B2 (ja) | 制御された異性体分布をもったメタンジフェニルジアミンとその高級同族体の混合物の合成方法 | |
| US5874621A (en) | Preparation of amines from olefins over NU-85 zeolites | |
| JPH053462B2 (enExample) | ||
| US6143934A (en) | Preparation of amines from olefins over boron beta-zeolites | |
| US20140100401A1 (en) | Catalyst for the alkylation of aromatic hydrocarbons | |
| EP0286029B1 (en) | Alkylation of aromatic amines over a1 exchanged zeolites | |
| CN1266114C (zh) | 具有受控异构体分布的甲烷二苯基二胺及其高级同系物的混合物的合成方法 | |
| JP2004532232A5 (enExample) | ||
| DE3881491T2 (de) | Verfahren zur Herstellung von N-acyl-Anilinen. | |
| JP3972443B2 (ja) | ジアリールアミン類の製造法 | |
| JP3972444B2 (ja) | ジアリールアミン類の製造方法 | |
| JP4168622B2 (ja) | ジアリールアミン類の製造方法 | |
| JP4168620B2 (ja) | ジアリールアミン類の製造方法 | |
| US20050192469A1 (en) | Zeolite catalyst for the alkylation of aromatic compounds with olefins, alcohols or polyalkylated aromatic compounds | |
| JP2001172230A (ja) | ジアリールアミン類の製造方法 | |
| De Cuihau Kexue Yu Jishu et al. | De Angelis et a | |
| CN118475406A (zh) | 用于过氧化氢异丙苯分解的催化剂及其制备方法 |