JP2004502013A - テトラブロックコポリマー - Google Patents
テトラブロックコポリマー Download PDFInfo
- Publication number
- JP2004502013A JP2004502013A JP2002505905A JP2002505905A JP2004502013A JP 2004502013 A JP2004502013 A JP 2004502013A JP 2002505905 A JP2002505905 A JP 2002505905A JP 2002505905 A JP2002505905 A JP 2002505905A JP 2004502013 A JP2004502013 A JP 2004502013A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- copolymer
- component
- road marking
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920003046 tetrablock copolymer Polymers 0.000 title claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 44
- 229920001577 copolymer Polymers 0.000 claims abstract description 40
- 229920001400 block copolymer Polymers 0.000 claims abstract description 29
- 239000013032 Hydrocarbon resin Substances 0.000 claims abstract description 18
- 229920006270 hydrocarbon resin Polymers 0.000 claims abstract description 18
- 238000009472 formulation Methods 0.000 claims abstract description 13
- 229920002223 polystyrene Polymers 0.000 claims abstract description 12
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 10
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 10
- 239000004793 Polystyrene Substances 0.000 claims abstract description 9
- 229920001195 polyisoprene Polymers 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 5
- 150000002148 esters Chemical class 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920000428 triblock copolymer Polymers 0.000 claims description 15
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 claims description 2
- 238000002372 labelling Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 11
- 238000013019 agitation Methods 0.000 abstract description 3
- 238000000227 grinding Methods 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 18
- 229920000359 diblock copolymer Polymers 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 7
- 150000001993 dienes Chemical class 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000011324 bead Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60353000A | 2000-06-27 | 2000-06-27 | |
| US09/605,032 US6576686B1 (en) | 2000-06-27 | 2000-06-27 | Road marking compound comprising linear tetrablock copolymers |
| PCT/US2001/020289 WO2002000787A1 (fr) | 2000-06-27 | 2001-06-25 | Copolymeres tetrasequences |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004502013A true JP2004502013A (ja) | 2004-01-22 |
| JP2004502013A5 JP2004502013A5 (fr) | 2008-08-14 |
Family
ID=27084451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002505905A Withdrawn JP2004502013A (ja) | 2000-06-27 | 2001-06-25 | テトラブロックコポリマー |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1299475A1 (fr) |
| JP (1) | JP2004502013A (fr) |
| CN (1) | CN1219821C (fr) |
| BR (1) | BR0112354A (fr) |
| MX (1) | MXPA02012668A (fr) |
| WO (1) | WO2002000787A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008509254A (ja) * | 2004-08-05 | 2008-03-27 | ファイヤーストーン ポリマーズ エルエルシー | 機能性マルチブロックポリマーの単一工程合成 |
| WO2019167745A1 (fr) * | 2018-02-27 | 2019-09-06 | 日本ゼオン株式会社 | Copolymère tétra-séquencé, et composition polymère, et composition adhésive collante de fusion à chaud les utilisant |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1348737A1 (fr) | 2002-03-28 | 2003-10-01 | KRATON Polymers Research B.V. | Coposition bitumineuse |
| CN101583665B (zh) * | 2006-11-20 | 2011-09-14 | 陶氏环球技术有限责任公司 | 苯乙烯四嵌段共聚物以及基于该共聚物的聚合物共混组合物 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4168286A (en) * | 1977-09-23 | 1979-09-18 | Phillips Petroleum Co. | Tetrablock polymers and their hydrogenated analogs |
| US4161472A (en) * | 1978-01-23 | 1979-07-17 | The B. F. Goodrich Company | Impact modified vinyl chloride polymer composition |
| IT1227901B (it) * | 1988-12-23 | 1991-05-14 | Enichem Elastomers | Composizioni polimeriche e loro metodo di preparazione |
| GB9103150D0 (en) * | 1991-02-14 | 1991-04-03 | Shell Int Research | Process for marking a pavement |
| US5589542A (en) * | 1993-11-03 | 1996-12-31 | Shell Oil Company | Multiblock hydrogenated polymers for adhesives |
| GB2289681B (en) * | 1994-05-19 | 1997-11-19 | Nissin Kasei Co Limited | A binder composition for a colored pavement |
| GB9518223D0 (en) * | 1995-09-06 | 1995-11-08 | Exxon Chemical Patents Inc | Bitumen compositions |
| WO2000056796A1 (fr) * | 1999-03-25 | 2000-09-28 | Bridgestone Firestone Inc | Compositions d'adhesif contenant des copolymeres multisequences de polyisoprene-polystyrene et articles contenant ces dernieres |
-
2001
- 2001-06-25 BR BR0112354-8A patent/BR0112354A/pt not_active Application Discontinuation
- 2001-06-25 CN CN 01811948 patent/CN1219821C/zh not_active Expired - Fee Related
- 2001-06-25 JP JP2002505905A patent/JP2004502013A/ja not_active Withdrawn
- 2001-06-25 EP EP01950485A patent/EP1299475A1/fr not_active Withdrawn
- 2001-06-25 WO PCT/US2001/020289 patent/WO2002000787A1/fr active Application Filing
- 2001-06-25 MX MXPA02012668A patent/MXPA02012668A/es active IP Right Grant
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008509254A (ja) * | 2004-08-05 | 2008-03-27 | ファイヤーストーン ポリマーズ エルエルシー | 機能性マルチブロックポリマーの単一工程合成 |
| WO2019167745A1 (fr) * | 2018-02-27 | 2019-09-06 | 日本ゼオン株式会社 | Copolymère tétra-séquencé, et composition polymère, et composition adhésive collante de fusion à chaud les utilisant |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002000787A1 (fr) | 2002-01-03 |
| CN1441829A (zh) | 2003-09-10 |
| BR0112354A (pt) | 2003-05-06 |
| CN1219821C (zh) | 2005-09-21 |
| MXPA02012668A (es) | 2004-07-30 |
| EP1299475A1 (fr) | 2003-04-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080625 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080625 |
|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20091214 |