JP2003529626A5 - - Google Patents
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- JP2003529626A5 JP2003529626A5 JP2001514039A JP2001514039A JP2003529626A5 JP 2003529626 A5 JP2003529626 A5 JP 2003529626A5 JP 2001514039 A JP2001514039 A JP 2001514039A JP 2001514039 A JP2001514039 A JP 2001514039A JP 2003529626 A5 JP2003529626 A5 JP 2003529626A5
- Authority
- JP
- Japan
- Prior art keywords
- screw
- mpa
- break
- carbon black
- melt index
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000463 material Substances 0.000 description 4
- 229920000122 Acrylonitrile butadiene styrene Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ZUROCNHARMFRKA-UHFFFAOYSA-N 4,5-dibromo-1H-pyrrole-2-carboxylic acid Chemical compound OC(=O)C1=CC(Br)=C(Br)N1 ZUROCNHARMFRKA-UHFFFAOYSA-N 0.000 description 1
- 102100016574 YBX3 Human genes 0.000 description 1
- 101710003767 YBX3 Proteins 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
【０００７】
【発明を実施するための最良の形態】
実施例１〜３
ＡＢＳを基礎材料として用いた。このＡＢＳ樹脂は強靭性高流動性材料である。そのメルトインデックス（ＭＩ）は３〜４ｇ／１０min、単純梁ノッチ付衝撃強度は２５〜３５ＫＪ／ｍ２、引張強さは４０〜６０Ｍｐａである。熱可塑性ポリエステル弾性体を強靭化剤として用いた。この弾性体は Du Pont製HYTREL4533であり、その破断点引張強さは３０Ｍｐａ、破断点伸びは６００％であり、アイゾットノッチ付き衝撃試験でも、破断されない。メルトインデックスは８．５／１０min、融点は１９３℃、ビカー軟化点は１５８℃である。カーボンブラックを導電性フィラーとして用いた。そのカーボンブラックの比表面積は２５４ｍ２／ｇ、粒径は３０μｍ、ＤＢＰＡ値は１８８ｃｍ３／１００ｇであり、密度は９７ｇ／ｌである。各組成物中のそれら成分の含有量（重量部）を表１に示す。前記含有量の各成分を高速混合機で１〜２分間混含し、その混合物を２軸押出機のホッパーに入れて、スクリューの各段の温度を２１０〜２４０℃とし、スクリューの回転数を３００ｒｐｍとして、押出された物質を水冷し、粉砕し、乾燥した後、製品を得た。該顆粒製品を射出成形で標準試験片に押出して、性能の測定と試験のために供した。その結果を表２に示す。
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
Examples 1-3
ABS was used as a base material. This ABS resin is a tough and highly fluid material. The melt index (MI) is 3-4 g / 10 min, the impact strength with a simple beam notch is 25-35 KJ / m 2 , and the tensile strength is 40-60 Mpa. A thermoplastic polyester elastomer was used as a toughening agent. This elastic material is HYTREL4533 manufactured by Du Pont, and has a tensile strength at break of 30 Mpa and an elongation at break of 600%. The melt index is 8.5 / 10 min, the melting point is 193 ° C, and the Vicat softening point is 158 ° C. Carbon black was used as a conductive filler. The specific surface area of the carbon black is 254m 2 / g, particle size 30 [mu] m, DBPA value is 188cm 3 / 100g, density is 97 g / l. Table 1 shows the contents (parts by weight) of these components in each composition. Each component of the content is mixed for 1 to 2 minutes with a high-speed mixer, the mixture is placed in a hopper of a twin-screw extruder, the temperature of each stage of the screw is set to 210 to 240 ° C, and the number of rotations of the screw is increased. The extruded material was cooled with water at 300 rpm, pulverized and dried to obtain a product. The granulated product was extruded into standard specimens by injection molding and provided for performance measurements and tests. Table 2 shows the results.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991139321A CN1160409C (en) | 1999-07-29 | 1999-07-29 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
| CN99113932.1 | 1999-07-29 | ||
| PCT/CN2000/000154 WO2001009241A1 (en) | 1999-07-29 | 2000-06-12 | High fluidible, impact resistant conductive acrylonitrile-butadiene-styrene terpolymer material and preparing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003529626A JP2003529626A (en) | 2003-10-07 |
| JP2003529626A5 true JP2003529626A5 (en) | 2006-09-21 |
Family
ID=5277070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001514039A Pending JP2003529626A (en) | 1999-07-29 | 2000-06-12 | High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2003529626A (en) |
| CN (1) | CN1160409C (en) |
| AU (1) | AU5386500A (en) |
| WO (1) | WO2001009241A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002256125A (en) * | 2001-02-28 | 2002-09-11 | Daicel Chem Ind Ltd | Conductive resin composition |
| CN102002206A (en) * | 2010-12-21 | 2011-04-06 | 四川大学 | High-glossiness high-toughness scratch resistant molding composition |
| CN102585429B (en) * | 2011-01-11 | 2015-02-25 | 合肥杰事杰新材料股份有限公司 | Resin material, preparation method and applications of resin material |
| CN102582188A (en) * | 2012-02-16 | 2012-07-18 | 仙居县一远静电科技有限公司 | Antistatic ABS (Acrylonitrile Butadiene Styrene) laminated board |
| CN103360718B (en) * | 2013-07-14 | 2015-11-18 | 上海秋橙新材料科技有限公司 | anti-aging ABS-TPU plastic alloy |
| KR101860388B1 (en) | 2017-03-10 | 2018-05-24 | (주)티엘씨코리아 | ABS composition for 3D printer filament having excellent discoloration resistance and low shrinkage and filament manufactured therefrom |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52124043A (en) * | 1976-04-13 | 1977-10-18 | Kokoku Rubber Ind | Electrical conductive resin composition for plating |
| JPS5950259B2 (en) * | 1980-11-17 | 1984-12-07 | 住友ベークライト株式会社 | Resin composition for plating |
| JPS58222135A (en) * | 1982-06-19 | 1983-12-23 | Nippon Steel Chem Co Ltd | Electrically conductive resin composition |
| JPH072885B2 (en) * | 1986-10-14 | 1995-01-18 | 東レ株式会社 | Thermoplastic resin composition |
| JP2917049B2 (en) * | 1990-07-23 | 1999-07-12 | 住化エイビーエス・ラテックス株式会社 | Method for producing filler-containing resin composition |
| JPH0657153A (en) * | 1992-08-10 | 1994-03-01 | Daicel Chem Ind Ltd | Antistatic resin composition |
| JPH0665508A (en) * | 1992-08-18 | 1994-03-08 | Daicel Chem Ind Ltd | Antistatic resin composition |
| JP3465340B2 (en) * | 1994-04-01 | 2003-11-10 | Ｊｓｒ株式会社 | Thermoplastic resin composition |
| US5989723A (en) * | 1997-05-16 | 1999-11-23 | Far Eastern Textile Ltd. | Conductive polyester-based alloy sheet |
-
1999
- 1999-07-29 CN CNB991139321A patent/CN1160409C/en not_active Expired - Lifetime
-
2000
- 2000-06-12 JP JP2001514039A patent/JP2003529626A/en active Pending
- 2000-06-12 WO PCT/CN2000/000154 patent/WO2001009241A1/en active Application Filing
- 2000-06-12 AU AU53865/00A patent/AU5386500A/en not_active Abandoned
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