CN102585429B - Resin material, preparation method and applications of resin material - Google Patents
Resin material, preparation method and applications of resin material Download PDFInfo
- Publication number
- CN102585429B CN102585429B CN201110004394.4A CN201110004394A CN102585429B CN 102585429 B CN102585429 B CN 102585429B CN 201110004394 A CN201110004394 A CN 201110004394A CN 102585429 B CN102585429 B CN 102585429B
- Authority
- CN
- China
- Prior art keywords
- parts
- resin material
- resin
- compatilizer
- screw
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention belongs to the technical field of high-polymer materials and discloses a resin material, a preparation method and applications of the resin material. The resin material disclosed by the invention comprises the following components in parts by weight: 70-95 parts of high-polymer resin, 1-15 parts of conducting material, 3-14 parts of compatilizer, 0.5-1 part of antioxidation aid and 0.5-1 part of processing aid. The preparation method for the resin material disclosed by the invention comprises the following steps of: weighing 70-95 parts of high-polymer resin, 1-15 parts of conducting material, 3-14 parts of compatilizer, 0.5-1 part of antioxidation aid and 0.5-1 part of processing aid; putting in a high-speed mixing machine and fully mixing; delivering a mixed material into a twin-screw extruder by using a metering material conveying device; fully mixing the material under the shearing actions of screws; performing extrusion, bracing, cooling and grain cutting on a molten blend; and packaging into a finished product. The resin material disclosed by the invention has an anti-static dustproof effect, is excellent in surface effect and can be used for manufacturing card readers or electrical equipment enclosures and the like.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of resin material, preparation method and application thereof.
Background technology
Plastic part shell, as electronic apparatus shell, the POS etc., because of its surface long term ingress of air, particularly in winter, its surface is easy to accumulate electrostatic, the harm that electrostatic produces is apparent, swiping card equipment to be magnetic material because of its Long Term Contact, and through friction of repeatedly swiping the card back and forth, its surface sediment electrostatic, our card can be caused to swipe the card unsuccessful, POS internal electronic component is damaged, the people of contact body also may be made to be hurt, make equipment surface easily because electrostatic produces adsorption generation dust suction etc., this just needs us to carry out anti-electrostatic dust removal process to these equipment, existing plastic part sheating material does not have anti-electrostatic dust-proof effect more, the POS is many easily there is the repeated situation of failure of swiping the card.The importance of the electrostatic of thorough elimination article surface is apparent, and this will make resin material possess electrostatic-proof function.
Summary of the invention
The object of this invention is to provide a kind of resin material.
Another object of the present invention is to provide a kind of preparation method of above-mentioned resin material.
3rd object of the present invention is to provide the purposes of a kind of above-mentioned resin material as general plastics sheating material and POS material, to overcome the defect that currently available products exists, meets the needs of electronic enterprises development to material.
Technical scheme of the present invention is as follows:
The invention provides a kind of resin material, this resin material comprises following component and weight part:
High-polymer resin 70 ~ 95 parts,
Conducting material 1 ~ 15 part,
Compatilizer 3 ~ 14 parts,
Anti-oxidant auxiliary agent 0.5 ~ 1 part,
Processing aid 0.5-1 part.
Described high-polymer resin is selected from the mixture of one or more in acrylonitrile-butadiene-phenylethene grafted copolymer (ABS), polycarbonate (PC), acrylonitrile-styrene-acrylic terpolymer (ASA), polypropylene (PP), polyethylene (PE), polymeric amide or polyoxymethylene (POM).
Described conducting material is selected from the composition of one or more in graphitized carbon black, electrically conductive graphite, carbon fiber or carbon nanotube.
Described compatilizer is selected from maleic anhydride graft acrylonitrile-butadiene-phenylethene grafted copolymer, maleic anhydride and cinnamic multipolymer, maleic anhydride inoculated polypropylene multipolymer, the multipolymer of ethene and octene, styrene-butadiene-styrene block copolymer, acryl-butadiene-styrol copolymer, alkylmethacrylate polymer, the terpolymer of MBS, ethylacrylate copolymer, ethylacrylate copolymer, the blend of one or more in butyl propyleneglycol acid ester copolymer or organo-silicone rubber.
Described anti-oxidant auxiliary agent is selected from the mixture of one or more in alkylation of hindered phenol, diphenyl phosphite, triphenyl phosphite, thioester, alkylation of hindered amine or hydroxybenzotriazole; Preferred alkyl Hinered phenols material four (β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester (Irganox1010) or tricresyl phosphite (2,4-di-tert-butyl-phenyl) ester (Irganox168).
Described processing aid is selected from the mixture of one or more in lubricant, coupling agent or processing and lubrication auxiliary agent, process and shaping time effectively can improve each component disperses and reduce harmful friction; Wherein, lubricant is selected from the mixture of one or more in soap or fatty acid amide; Coupling agent is selected from the composition of one or more in silane coupling agent, titanic acid ester or Aluminate compound; Processing and lubrication auxiliary agent is selected from the mixture of one or more in solid paraffin, whiteruss, low molecular weight polyethylene, calcium stearate, Zinic stearas, stearic amide, pentaerythritol stearate (PETS), ethylene bis stearic acid amide (EBS) or N, N-ethylene bis stearic acid amide.
Present invention also offers a kind of preparation method of above-mentioned resin material, the method comprises the following steps:
Take 70-95 part high-polymer resin, 3-14 part compatilizer, the anti-oxidant auxiliary agent of 0.5-1 part and 0.5-1 part processing aid, put into high-speed mixer and fully mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, utilize lateral feeding machine in screw rod, add 1-15 part conducting material, the blend of melting is through extruding, and tie rod, cools, pelletizing, is packaged into finished product;
Or
Take 70-95 part high-polymer resin, 1-15 part conducting material, 3-14 part compatilizer, the anti-oxidant auxiliary agent of 0.5-1 part and 0.5-1 part processing aid, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, the blend of melting is through extruding, and tie rod, cools, pelletizing, is packaged into finished product.
The length-to-diameter ratio of described twin screw extruder is greater than 40: 1, and screw speed is at 150 ~ 600 revs/min, and twin-screw extrusion working temperature is interval different because each macromolecule matrix is different; Preferred length-to-diameter ratio is 40: 1 ~ 45: 1, and screw speed is 300 ~ 450 revs/min.
Resin material of the present invention, its performance meets general plastics sheating material and POS material performance requirement, and therefore, technical scheme of the present invention comprises the purposes that resin material of the present invention is used as general plastics sheating material and POS material.
The described POS is selected from the one in the swiping card equipment of depositing and withdrawing of bank, retail terminal POSE machine, automatic terminal atm device, time clock or brush magnetic bar code tabulating equipment.
Compared with the existing technology, tool has the following advantages and beneficial effect in the present invention:
1, a kind of resin material of the present invention, adopt twin screw extrusion process preparation, products obtained therefrom has the advantages such as anti-electrostatic is dust-proof; While maintenance material property, improve the anti-electrostatic dust-proof effect of product, reduce material and the use of product is endangered, everybody can be allowed to the relieved safe use of the POS.
2, the antistatic brush card machine material of patented invention of the present invention, its antistatic effect is permanent, causes the conducting material of use to have an effect for a long time, really plays anti-electrostatic dustproof effect.
3, the antistatic brush card machine material of patented invention of the present invention, because its antistatic effect is excellent, therefore it is not easy the small particle size impurity such as attract dust, makes plastic casing surface clean, makes product more attractive in appearance.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
High-polymer resin is that the acrylonitrile-butadiene-phenylethene grafted copolymer ABS750 of Jin Hu company of Korea S or Japan go out photochemical polycarbonate 2200.
Conducting material is the carbon fiber HTC493 of graphitized carbon black G250 or II east nation chemistry or the carbon nanotube VGCF of III Showa chemistry of I Te Migao chemistry.
Compatilizer is the terpolymer EM500A of the MBS of ILG chemistry or the maleic anhydride graft acrylonitrile-butadiene-phenylethene grafted copolymer ABS-G of II Jie Shijie company or the maleic anhydride of III oil of SPC and cinnamic multipolymer SMA218.
Anti-oxidant auxiliary agent is alkylated hindered phenolic material four (β-(3 of CIBA, 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester Irganox1010 and tricresyl phosphite (2,4-di-tert-butyl-phenyl) ester Irganox168.
Processing aid is domestic ethylene bis stearic acid amide EBS or pentaerythritol stearate PETS.
Embodiment 1
Take ABS resin 70 parts, compatilizer I 5 parts, compatilizer II 9 parts, processing aid EBS 0.5 part, anti-oxidant auxiliary agent 1,010 0.2 parts and 168 0.3 parts, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, utilize lateral feeding machine in screw rod, add 15 parts of conducting material I, wherein the length-to-diameter ratio of twin screw extruder is 42: 1, screw speed is at 300 revs/min, twin-screw extrusion working temperature interval range is 180 ~ 240 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.Mixture prepared by each embodiment is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Embodiment 2
Take ABS resin 82 parts, compatilizer II 5 parts, processing aid EBS 0.5 part, anti-oxidant auxiliary agent 1,010 0.1 and 168 0.4 parts, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, utilize lateral feeding machine in screw rod, add 12 parts of conducting material I, wherein the length-to-diameter ratio of twin screw extruder is 40: 1, screw speed is at 350 revs/min, twin-screw extrusion working temperature interval range is 180 ~ 240 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.The mixture of preparation is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Embodiment 3
Take ABS resin 88 parts, compatilizer III 5 parts, processing aid EBS 1 part, anti-oxidant auxiliary agent 1,010 0.4 parts and 1680.6 parts, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, utilize lateral feeding machine in screw rod, add 5 parts of conducting material II, wherein the length-to-diameter ratio of twin screw extruder is 44: 1, screw speed is at 300 revs/min, twin-screw extrusion working temperature interval range is 180 ~ 240 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.The mixture of preparation is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Embodiment 4
Take ABS resin 92 parts, compatilizer II 5 parts, conducting material III 2 parts, processing aid EBS 0.5 part, anti-oxidant auxiliary agent 1,010 0.2 parts and 168 0.3 parts, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, the wherein length-to-diameter ratio 45: 1 of twin screw extruder, screw speed is at 420 revs/min, and twin-screw extrusion working temperature interval range is 180 ~ 240 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.The mixture of preparation is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Embodiment 5
Take PC resin 83 parts, compatilizer I 5 parts, processing aid PETS 0.5 part, anti-oxidant auxiliary agent 1,010 0.2 parts and 168 0.3 parts, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, utilize lateral feeding machine in screw rod, add 11 parts of conducting material I, wherein the length-to-diameter ratio of twin screw extruder is 40: 1, screw speed is at 400 revs/min, twin-screw extrusion working temperature interval range is 250 ~ 300 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.The mixture of preparation is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Embodiment 6
Take PC resin 88 parts, compatilizer I 5 parts, processing aid PETS 1 part, anti-oxidant auxiliary agent 1,010 0.4 parts and 1680.6 parts, put into high-speed mixer fully mixing metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, utilize lateral feeding machine in screw rod, add 5 parts of conducting material II, wherein the length-to-diameter ratio of twin screw extruder is 42: 1, screw speed is at 350 revs/min, twin-screw extrusion working temperature interval range is 250 ~ 300 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.The mixture of preparation is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Embodiment 7
Take PC resin 92 parts, compatilizer I 5 parts, conducting material III 2 parts, processing aid PETS 0.5 part, anti-oxidant auxiliary agent 1,010 0.2 parts and 168 0.3 parts, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, wherein the length-to-diameter ratio of twin screw extruder is 44: 1, screw speed is at 380 revs/min, twin-screw extrusion working temperature interval range is 250 ~ 300 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.The mixture of preparation is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Embodiment 8
Take ABS resin 95 parts, compatilizer III 2 parts, conducting material III 2 parts, processing aid EBS 0.5 part, anti-oxidant auxiliary agent 1,010 0.1 parts and 168 0.4 parts, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, wherein the length-to-diameter ratio of twin screw extruder is 40: 1, and screw speed is at 450 revs/min, and twin-screw extrusion working temperature interval range is 180 ~ 240 DEG C, the blend of melting is through extruding, tie rod, cooling, pelletizing.Be packaged into finished product.The mixture of preparation is injection molded into the standard batten of test by standard size, physicals is respectively according to China's national standard test, as shown in table 1.The performance test results is in table 2.
Table 1
| Physicals | Testing method |
| Tensile strength | GB/T 1040 |
| Flexural strength | GB/T 9341 |
| Modulus in flexure | GB/T 9341 |
| Izod notched Izod impact strength | GB/T 1843 |
| Izod unnotched impact strength | GB/T 1843 |
| Surface resistivity | GB/T 1410 |
Table 2
In table 2, test event surface resistivity can reflect the surface anti-static ability of this kind of material, and within the specific limits, this numerical value is lower, and show that its anti-static effect is better, usual resistance value is 10
11more than Ω cm is called isolator; Resistance value is 10
4~ 10
10semi-conductor or anti-electrostatic body is called within the scope of Ω cm; Resistance value is 10
4below Ω cm is called electrical conductor; Resistance value is 10
2what below Ω cm was even lower is called high conductor.
Above-mentioned is can understand and apply the invention for ease of those skilled in the art to the description of embodiment.Person skilled in the art obviously easily can make various amendment to these embodiments, and General Principle described herein is applied in other embodiments and need not through performing creative labour.Therefore, the invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (6)
1. a resin material, is characterized in that: this resin material comprises following component and weight part,
Described conducting material is the graphitized carbon black G250 of Te Migao chemistry or the carbon fiber HTC493 of eastern nation chemistry;
Described processing aid is domestic ethylene bis stearic acid amide EBS or pentaerythritol stearate PETS;
Described compatilizer is selected from the terpolymer EM500A of MBS or maleic anhydride graft acrylonitrile-butadiene-phenylethene grafted copolymer ABS-G or maleic anhydride and cinnamic multipolymer SMA218;
Described anti-oxidant auxiliary agent is alkylated hindered phenolic material four (β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester Irganox1010 and tricresyl phosphite (2,4-di-tert-butyl-phenyl) ester Irganox168.
2. resin material according to claim 1, is characterized in that: described high-polymer resin is selected from the mixture of one or more in acrylonitrile-butadiene-phenylethene grafted copolymer, polycarbonate, acrylonitrile-styrene-acrylic terpolymer, polypropylene, polyethylene, polymeric amide or polyoxymethylene.
3. the preparation method of the resin material described in claim 1 or 2, is characterized in that: the method comprises the following steps,
Take 70-95 part macromolecule resin, 3-14 part compatilizer, the anti-oxidant auxiliary agent of 0.5-1 part and 0.5-1 part processing aid, put into high-speed mixer and fully mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, in extruder screw stage casing, utilize lateral feeding machine in screw rod, add 11-15 part conducting material, the blend of melting is through extruding, and tie rod, cools, pelletizing, is packaged into finished product;
Or
Take 70-95 part macromolecule resin, 11-15 part conducting material, 3-14 part compatilizer, the anti-oxidant auxiliary agent of 0.5-1 part and 0.5-1 part processing aid, put into high-speed mixer fully to mix, with metering material conveying device, mixed material is sent in twin screw extruder, through the shearing action of screw rod, sufficient mixing, the blend of melting is through extruding, and tie rod, cools, pelletizing, is packaged into finished product.
4. the preparation method of resin material according to claim 3, it is characterized in that: the length-to-diameter ratio of described twin screw extruder is greater than 40:1, screw speed is at 150 ~ 600 revs/min, and twin-screw extrusion working temperature is interval different because each macromolecule matrix is different.
5. the resin material described in claim 1 or 2 is used as the purposes of general plastics sheating material and POS material.
6. the purposes of resin material according to claim 5, is characterized in that: the described POS is selected from the one in the swiping card equipment of depositing and withdrawing of bank, retail terminal POSE machine, automatic terminal atm device, time clock or brush magnetic bar code tabulating equipment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110004394.4A CN102585429B (en) | 2011-01-11 | 2011-01-11 | Resin material, preparation method and applications of resin material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110004394.4A CN102585429B (en) | 2011-01-11 | 2011-01-11 | Resin material, preparation method and applications of resin material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102585429A CN102585429A (en) | 2012-07-18 |
| CN102585429B true CN102585429B (en) | 2015-02-25 |
Family
ID=46474707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110004394.4A Active CN102585429B (en) | 2011-01-11 | 2011-01-11 | Resin material, preparation method and applications of resin material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102585429B (en) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807763A (en) * | 2012-07-27 | 2012-12-05 | 苏州市兴吴工程塑胶有限公司 | Formula of carbon nanofiber plastic |
| CN102863783B (en) * | 2012-10-15 | 2014-04-23 | 合肥利美科技有限公司 | High-toughness electric conduction nylon composite material and preparation method thereof |
| DE102012022482A1 (en) | 2012-11-19 | 2014-05-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Polymer composition with improved long-term stability, moldings produced therefrom and uses |
| DE102013005307A1 (en) | 2013-03-25 | 2014-09-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Use of organic oxyimides as flame retardants for plastics and flame-retardant plastic composition and molded part produced therefrom |
| CN104163991A (en) * | 2013-05-20 | 2014-11-26 | 常熟卡斯玛因厨具有限公司 | Preparation method of halogen-free fire-retardation electric-conduction polypropylene composite material |
| CN104177709A (en) * | 2013-05-20 | 2014-12-03 | 常熟卡斯玛因厨具有限公司 | Halogen-free flame-retardant conductive polypropylene composite material |
| CN104277322A (en) * | 2013-07-03 | 2015-01-14 | 合肥杰事杰新材料股份有限公司 | Antistatic high-luster polypropylene composite material and preparation method thereof |
| CN103435996B (en) * | 2013-08-10 | 2016-03-23 | 福建联迪商用设备有限公司 | Financial POS machine plastic casing of a kind of antibacterial antistatic and preparation method thereof |
| CN103709513B (en) * | 2013-12-26 | 2016-05-11 | 苏州万图明电子软件有限公司 | A kind of polyformaldehyde and Composite Modification for Polypropylene plastics |
| CN103740032A (en) * | 2013-12-27 | 2014-04-23 | 安徽科聚新材料有限公司 | Thermoplastic elastomer material and preparation method thereof |
| CN103772950A (en) * | 2014-01-24 | 2014-05-07 | 南通红石科技发展有限公司 | Conductive PC (Polycarbonate) material and preparation method thereof |
| CN103804878A (en) * | 2014-02-26 | 2014-05-21 | 苏州市涵信塑业有限公司 | Shell for household appliance |
| DE102014210214A1 (en) | 2014-05-28 | 2015-12-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Use of oxyimide-containing copolymers or polymers as flame retardants, stabilizers, rheology modifiers for plastics, initiators for polymerization and grafting processes, crosslinking or coupling agents, and also plastic molding compositions containing such copolymers or polymers |
| DE102014211276A1 (en) | 2014-06-12 | 2015-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Use of hydroxybenzotriazole derivatives and / or hydroxyindazole derivatives as flame retardants for plastics and flame-retardant plastic molding compound |
| CN104031350B (en) * | 2014-06-17 | 2017-08-25 | 东莞市德诚塑化科技有限公司 | A kind of capacitance pen writing pencil materials, preparation method and its usage |
| CN104194250B (en) * | 2014-09-16 | 2016-06-22 | 江阴润玛电子材料股份有限公司 | A kind of preparation method of circuit conductive plastics |
| CN104672753A (en) * | 2015-02-04 | 2015-06-03 | 苏州康华净化系统工程有限公司 | Conductive ABS material and preparation method thereof |
| CN104744917B (en) * | 2015-04-14 | 2017-01-04 | 张家港大塚化学有限公司 | A kind of high conduction performance polycarbonate composite material preparation method |
| CN105153626A (en) * | 2015-07-09 | 2015-12-16 | 镇江荣诚管业有限公司 | High mass-production green type pipe and preparation method thereof |
| CN106366395A (en) * | 2015-07-20 | 2017-02-01 | 江苏爱福特科技开发有限公司 | Composite electric conduction plastic and preparation method thereof |
| CN105131504B (en) * | 2015-08-31 | 2018-08-07 | 宁波海雨新材料科技有限公司 | A kind of high-modulus ABS engineering plastics and preparation method thereof |
| CN105315566A (en) * | 2015-11-30 | 2016-02-10 | 东莞市松燊塑料科技有限公司 | Antistatic PS modified material and preparation method thereof |
| CN105504661B (en) * | 2016-01-29 | 2018-09-18 | 青岛海信电器股份有限公司 | A kind of remote controller casing material and preparation method with antibacterial functions |
| CN106398095A (en) * | 2016-08-31 | 2017-02-15 | 宁波威丰新材料有限公司 | Magnetron sputtering plastic target film |
| CN106398097A (en) * | 2016-08-31 | 2017-02-15 | 宁波威丰新材料有限公司 | Two-way stretching embossing co-extruded film |
| CN107880473A (en) * | 2016-09-30 | 2018-04-06 | 美的集团股份有限公司 | A kind of antistatic material easy to clean and preparation method thereof |
| CN106280227A (en) * | 2016-10-21 | 2017-01-04 | 安徽江淮汽车股份有限公司 | A kind of antistatic high tenacity ABS composite material and preparation method thereof |
| CN106519555B (en) * | 2016-11-18 | 2018-11-16 | 孙克忠 | A kind of antistatic high temperature resistant polyformaldehyde and preparation method thereof |
| CN108690260A (en) * | 2017-04-11 | 2018-10-23 | 合肥杰事杰新材料股份有限公司 | A kind of polypropene composition material and preparation method thereof |
| CN109135041A (en) * | 2017-06-16 | 2019-01-04 | 合肥杰事杰新材料股份有限公司 | A kind of anti-static polyolefin composite material and preparation method |
| CN107501842A (en) * | 2017-08-17 | 2017-12-22 | 河南科技学院 | Plastic cement operating desk and preparation method and the multi-functional refrigerating plant of cold fresh meat production |
| CN107629389B (en) * | 2017-09-19 | 2019-11-15 | 佛山市南海精置塑料有限公司 | A kind of preparation method of composite conductive plastic |
| CN107501658A (en) * | 2017-10-19 | 2017-12-22 | 安徽天裕汽车零部件制造有限公司 | A kind of production technology of automobile dustproof sleeve pipe |
| CN108192207A (en) * | 2017-12-28 | 2018-06-22 | 聚威工程塑料(上海)有限公司 | A kind of high-performance conductive PP composite material and preparation method |
| CN109178597B (en) * | 2018-08-09 | 2020-04-17 | 合肥洁纯塑料包装有限公司 | Lining barrel of anti-static chemical raw material barrel |
| CN109608858A (en) * | 2018-11-28 | 2019-04-12 | 江苏松上科技有限公司 | A kind of permanent conductive PC plastic particle and preparation method thereof |
| CN110093023A (en) * | 2019-04-08 | 2019-08-06 | 苏州博驰新材料有限公司 | A kind of glass fiber reinforced PC/PP plastic alloy |
| CN110564127B (en) * | 2019-08-27 | 2020-11-13 | 珠海格力电器股份有限公司 | Anti-static composite material, preparation method, anti-static shell and purifier |
| CN113061316B (en) * | 2020-01-02 | 2024-01-05 | 合肥杰事杰新材料股份有限公司 | Graphite whisker filled ABS composition and preparation method thereof |
| CN111117147A (en) * | 2020-01-15 | 2020-05-08 | 东莞市耐格美塑胶制品有限公司 | Permanently anti-static surface matte reinforced POM (polyoxymethylene) board and preparation method thereof |
| CN111319331A (en) * | 2020-02-26 | 2020-06-23 | 江苏斯迪克新材料科技股份有限公司 | Antistatic high-transmittance protective film |
| CN112745629B (en) * | 2020-12-14 | 2022-08-19 | 金发科技股份有限公司 | Reinforced ABS composition and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1282762A (en) * | 1999-07-29 | 2001-02-07 | 上海杰事杰新材料股份有限公司 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
| CN101215413A (en) * | 2008-01-02 | 2008-07-09 | 苏州奥美光学材料有限公司 | Polycarbonate conductive material and thin film or sheet processed by the same |
| CN101591469A (en) * | 2009-06-15 | 2009-12-02 | 惠州市沃特新材料有限公司 | A kind of conductive polycarbonate moulding compound and preparation method thereof |
| CN101778894A (en) * | 2007-08-08 | 2010-07-14 | 第一毛织株式会社 | electro-conductive thermoplastic resin compositions and articles manufactured therefrom |
| CN101805503A (en) * | 2010-04-02 | 2010-08-18 | 金发科技股份有限公司 | Polycarbonate/polyethylene alloy conductive composite material and preparation method thereof |
-
2011
- 2011-01-11 CN CN201110004394.4A patent/CN102585429B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1282762A (en) * | 1999-07-29 | 2001-02-07 | 上海杰事杰新材料股份有限公司 | High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process |
| CN101778894A (en) * | 2007-08-08 | 2010-07-14 | 第一毛织株式会社 | electro-conductive thermoplastic resin compositions and articles manufactured therefrom |
| CN101215413A (en) * | 2008-01-02 | 2008-07-09 | 苏州奥美光学材料有限公司 | Polycarbonate conductive material and thin film or sheet processed by the same |
| CN101591469A (en) * | 2009-06-15 | 2009-12-02 | 惠州市沃特新材料有限公司 | A kind of conductive polycarbonate moulding compound and preparation method thereof |
| CN101805503A (en) * | 2010-04-02 | 2010-08-18 | 金发科技股份有限公司 | Polycarbonate/polyethylene alloy conductive composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102585429A (en) | 2012-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102585429B (en) | Resin material, preparation method and applications of resin material | |
| CN101724241B (en) | Antistatic thermoplastic polycarbonate composition and preparation method thereof | |
| CN109423024B (en) | Halogen-free flame-retardant PC/CF antistatic material and product thereof | |
| CN108264749A (en) | A kind of high good surface carbon fiber reinforced polycarbonate composite material of flowing and preparation method thereof | |
| CN103013119A (en) | Low-cost modified polyphenylene sulfide composition and preparation method thereof | |
| CN101463163A (en) | Permanent antistatic polypropylene material and preparation thereof | |
| CN104371162A (en) | Flame-retardant wear-resisting modified polypropylene material and preparation method thereof | |
| CN109627580B (en) | Light-colored permanent antistatic modified polypropylene material and preparation method thereof | |
| CN103214783A (en) | Novel conductive polyformaldehyde material and preparation method | |
| CN104592722A (en) | High-luster low-warpage glass fiber reinforced PBT/PP (Polybutylene Terephthalate/Polypropylene) alloy and preparation method thereof | |
| CN102850733B (en) | Polybutylene terephthalate composition and its preparation method | |
| CN101759921B (en) | Novel antistatic polypropylene material and preparation method thereof | |
| CN103073790A (en) | Polypropylene composite material resistant to surface friction damage and preparation method thereof | |
| CN111499973B (en) | Conductive carbon fiber resin composition and preparation method thereof | |
| CN103834115A (en) | Glass fiber reinforced fire retardation styrene-acrylonitrile material and preparation method thereof | |
| CN102070824A (en) | Antistatic polypropylene composition and preparation method thereof | |
| CN111004478B (en) | High-performance antistatic polyester material and preparation method thereof | |
| CN114621562A (en) | Conductive glass fiber reinforced PBT (polybutylene terephthalate) and preparation method thereof | |
| WO2023071795A1 (en) | Pc composite material, preparation method therefor, and application thereof | |
| CN104448806A (en) | Low-warping-rate halogen-free flame retardant carbon fiber-reinforced nylon alloy material and preparation method | |
| CN114163746B (en) | Glass fiber reinforced AS composition and application thereof | |
| CN113292838B (en) | Halogen-free low-warpage low-linear-expansion-coefficient extrusion-grade thin-wall flame-retardant polycarbonate composite material and preparation method thereof | |
| CN102558677A (en) | Novel scratch-resistant polypropylene composite material and preparation method thereof | |
| JP3164696B2 (en) | Polyacetal resin composition | |
| CN109867936B (en) | Colored halogen-free flame-retardant PC antistatic material and product thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |