CN107880473A - A kind of antistatic material easy to clean and preparation method thereof - Google Patents
A kind of antistatic material easy to clean and preparation method thereof Download PDFInfo
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- CN107880473A CN107880473A CN201610875519.3A CN201610875519A CN107880473A CN 107880473 A CN107880473 A CN 107880473A CN 201610875519 A CN201610875519 A CN 201610875519A CN 107880473 A CN107880473 A CN 107880473A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention relates to a kind of antistatic material easy to clean and preparation method thereof.A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles and following component;In terms of the mass percent of the first thermoplastic plastic parent particles, antistatic additive is 8% the 39% of the first thermoplastic plastic parent particles, silica is less than the 8% of the first thermoplastic plastic parent particles, zirconium aluminate is less than the 6.1% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate is less than the 18% of the first thermoplastic plastic parent particles, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, stearate is less than the 3.9% of the first thermoplastic plastic parent particles, and acetone is less than the 7.2% of the first thermoplastic plastic parent particles.During preparation, each component compounding is mixed, injection molding to together by proportioning.Antistatic material easy to clean of the present invention and preparation method thereof has the advantages that antistatic and easy to clean.
Description
Technical field
The invention belongs to field of material technology, more particularly to a kind of antistatic material easy to clean and preparation method thereof.
Background technology
The phenomenon of dust stratification often occurs during use for some plastic products, such as:Dust in air can be with
Suspension, bacterium floating, can surface deposit, also can dynamic friction air, cause Electrostatic Absorption dust.Not only need often clear
Reason operation is cumbersome, and can influence the service life of equipment.It is specifically introduced below by taking flabellum or impeller as an example.
By taking outdoor machine of air-conditioner impeller as an example, the impeller of long-term dust stratification can cause air conditioner refrigerating efficiency decay more than 30%, air-conditioning
In use, dust easily in its surface attachment and then deposition, influences air quantity, efficiency, and easy shape to interior machine ducting part
Into secondary pollution, many bacteriums harm health can be grown, therefore, improve material surface property so that surface, which is not easy to be stained with ash, to be become
Highly significant.
During running at high speed, flabellum (impeller leaf) produces dynamic static friction with air interaction for electric fan and impeller,
Dust adsorption charged ion can be caused.Positively or negatively, same sex electric charge mutually repels enhancing to about 90%-95% suspension
The degree of stability of dust in air, the flabellum and windage band that the charges of different polarity mutually attract to promote dust accumulation and settle rotation
Upper electric charge, and electrical body has the property for attracting slight small item body, so dust can be attracted on flabellum.According to the literature in air
Particle diameter is less than 75 μm of solid suspension, and the especially more decentralization in the dust of 0.1-10 μ ms of particle diameter are higher, of dust
Grain is more tiny, and the showy time is longer in atmosphere, and dust also has a bacterium corpse in atmosphere, oil stain, moisture, some
The fiber of batting shape so that the aerial dust pattern that suspends is extremely complex, and so multi-component dust, which is easier to be enriched with, to be glued
On impeller or flabellum, long-term flabellum or impeller just gradually become very dirty, and in the inside leaf of the electrical equipment such as air-conditioning, dust catcher
Wheel, if being stained with ash for a long time on radiator fan impeller, its normal operating efficiency can be influenceed, thus a kind of imperial ash flabellum easy to clean with
Impeller can become extremely important.
The operating for a long time of existing unmodified flabellum or impeller stands a period of time, will be deposited on impeller or flabellum
Many dusts, flabellum impeller just gradually become very dirty, have a strong impact on the outward appearance of flabellum impeller.And as in air-conditioning, dust catcher
Deng the internal impeller of electrical equipment, if being stained with ash for a long time on radiator fan impeller, can influence inside its normal operating efficiency, such as air-conditioning
Impeller, windage increase can seriously be caused by being stained with ash, influence the refrigeration of complete machine, and dust is enriched with flabellum in addition, can influence flabellum
The dynamic balancing of rotation, have a strong impact on the influence of flabellum and impeller place air output and other side.Existing technical scheme is exactly
Regular to take cleaning dust apart, operation is inconvenient and time-consuming, and especially cleaning can be pretty troublesome, and cleaning meeting airborne dust is harmful.Therefore,
By antistatic additive modified plastics surface characteristic, the adhesion for reducing dust and plastic interface is significant.
The content of the invention
In view of the problems of prior art, the present invention provides antistatic material easy to clean and preparation method thereof, has
The advantages that antistatic, imperial grey and easy to clean.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, silica, zirconium aluminate,
Dodecyl sodium sulfate, glycol ester, stearate and acetone;In terms of the mass percent of the first thermoplastic plastic parent particles,
Antistatic additive is the 8%-39% of the first thermoplastic plastic parent particles, and silica is less than the 8% of the first thermoplastic plastic parent particles,
Zirconium aluminate is less than the 6.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplastic plastic parent particles
Less than 18%, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
Less than 3.9%, acetone be the first thermoplastic plastic parent particles less than 7.2%.
The beneficial effects of the invention are as follows:
Inventor is found surprisingly that under study for action, and the antistatic of proper ratio is added in the first thermoplastic plastic parent particles
Agent, on the premise of ensureing that the original performance of material is unaffected, while the antistatic property of obtained material can be improved, make system
The material obtained has the effect for driving ash.When the addition proper ratio on the basis of the first thermoplastic plastic parent particles and antistatic additive
One or more in silica, zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone, pass through dioxy
SiClx, zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone and antistatic additive are used cooperatively, Ke Yijin
One step strengthens anlistatig effect.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, by percentage to the quality, silica be the first thermoplastic plastic parent particles 0.5%-8%, zirconium aluminate
For the 0.5%-6.1% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate is the 1.2%- of the first thermoplastic plastic parent particles
18%.
Further, glycol ester is the 0.2%-11% of the first thermoplastic plastic parent particles.
Further, stearate is the 0.1%-3.9% of the first thermoplastic plastic parent particles.
Further, acetone is the 0.5%-7.2% of the first thermoplastic plastic parent particles.
It is using the beneficial effect of such scheme:
Inventor be found surprisingly that under study for action the addition silica of proper ratio, zirconium aluminate, dodecyl sodium sulfate,
Glycol ester, stearate and acetone and antistatic additive are used cooperatively, and participate in the modifying process of material, and blending chemistry occurs
Reaction so that antistatic active principle can be preferably dispersed, so as to lift the antistatic effect of material, significantly improves system
Imperial grey effect of the material obtained.
First thermoplastic plastic parent particles of the present invention are thermoplastic, and material of the invention can use any kind
Thermoplastic can be but be not limited to following title as the first thermoplastic plastic parent particles:First thermoplastic
Master batch is selected from acrylonitritrile-styrene resin, PA plastics, polyethylene, polypropylene, polyvinyl chloride, polystyrene, acrylonitrile-fourth
One or more of compoundings in diene-styrene copolymerized compound and the medium Common thermoplastic's plastics of makrolon.
Further, the particle diameter of the silica is:1-100nm.
It is using the beneficial effect of such scheme:Using the silica of appropriate particle size, further improve material prescription
Processing characteristics, nano silicon, which improves antistatic additive and base-material, slippage effect, and a small amount of nano silicon can play
Increase rubbing action, improve processing characteristics.
Further, the particle diameter of the silica is that the particle diameter of 1-30nm or described silica is 31-39nm.
It is using the beneficial effect of such scheme:The particle diameter of silica is smaller, and specific surface area is larger, less addition
Can significantly improves the performance of material.
Further, the particle diameter of the silica is:40-50nm.
It is using the beneficial effect of such scheme:Be advantageous to silica surface processing and it is dispersed.
Further, the particle diameter of the silica is:51-80nm.
It is using the beneficial effect of such scheme:Industrialized production is convenient.
Further, the particle diameter of the silica is:81-100nm.
It is using the beneficial effect of such scheme:Particle is bigger, easily scattered.
Further, the silica is nano silicon, and nano silicon is surface treated nanometer two
Silica;It the treating method comprises following steps:Silica is mixed with ethanol solution, instills compounding coupling agent, compounding
The mass percent of coupling agent and silica dioxide granule is 0.5-2%, and the compounding coupling agent is by silane coupler and titanate esters
Coupling agent compounding forms, and is stirred by ultrasonic, and filters, and dries, grinding.
It is using the beneficial effect of such scheme:Be advantageous to improve the performance of silica, had using the aqueous solution of ethanol
Beneficial to hydrolysis coupling agent so that in resin matrix dispersedly evenly, surface treatment improves inorganic nano two to silica
The compatibility of silica and resin matrix.
Further, it is antistatic to be selected from cationic antistatic agent, anionic antistatic agents, nonionic for the antistatic additive
Agent, the CNT of modification, graphene, copolymer, metal powder and one kind or several in electrically conductive graphite of polyethers and polyamide
Kind.
It is using the beneficial effect of such scheme:
Because the specific insulation of existing material is generally up to 2x1012-1020Ω/, easily put aside electrostatic and endanger
It is stained with nearly and easily ash.Using the antistatic additive of mentioned kind isolated electric charge can be enabled to be pulled away, conductive material surface
Electric charge, the electric charge of material surface institute band is reduced, so that dust is not easy to be bonded at the surface of material.
Further, the cationic antistatic agent is selected from quaternary ammonium alkyl, phosphate and the polymerization of naphthenic acid salt high-molecular of long-chain
It is one or more of in thing.
It is using the beneficial effect of such scheme:Being coordinated using the cationic antistatic agent of mentioned kind with other components is made
With being advantageous to further improve antistatic effect.
Further, it is thio to be selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and two for the anionic antistatic agents
One or more in carbamic alkali metal salt.
It is using the beneficial effect of such scheme:Being coordinated using the anionic antistatic agents of mentioned kind with other components is made
With being advantageous to further improve antistatic effect.
Further, the non-ionic antistatic agent is selected from ethoxylated fat race alkylamine, macrogol ester or ether, fat
One or more in fat acid esters and glycollic amide.
It is using the beneficial effect of such scheme:Being coordinated using the non-ionic antistatic agent of mentioned kind with other components is made
With being advantageous to further improve antistatic effect.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch
For the 0.1%-76.9% of the first thermoplastic plastic parent particles.
It is using the beneficial effect of such scheme:, can be with by adding the modified thermoplastic master batch of proper ratio
Further improve and the antistatic performance for being not easy to be stained with putty material is made.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch
For the 0.1%-6.49% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch
For the 6.50%-76.9% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch
For the 6.5%-18% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch
For the 19%-45% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch
For the 46%-76.9% of the first thermoplastic plastic parent particles.
Beneficial effect using above-mentioned several schemes is:The modified thermoplastic master batch for adding above-mentioned different proportion can be with
Imperial grey performance of the different degrees of whole material of raising.
Further, the modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and/or Si modification thermoplasticity
Plastic master batch.
It is using the beneficial effect of such scheme:Silicon atom can form one layer of " Si- exposed to the surface of moulding
The good stabilized zone of O-Si " keys, the low-surface-energy of organosilicon so that it has good hydrophobic waterproof.Fluorine richness thermoplasticity
Plastic master batch, be mainly using C-F chain links are short, the surface energy of C-F keys is also low, Si-C-F by with low-surface-energy change
Kind product surface stain resistance so that surface can reach hydrophobic oleophobic, surface stain resistance increase so that dust is not easy to be stained with
In blade surface, the interface of dust and low-surface-energy acts on plus antistatic additive so that adhesion of the dust at interface diminishes, ash
If the dust that the first layer at interface adheres to is seldom, the dust on interface is just more difficult to be further continued on the dust of first layer dirt
Adsorb more dusts so that the adhesive capacity of overall dust is reduced, and makes the dust for sticking in surface be easy to clear up.
Further, the fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, and described
Two thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the fluorine auxiliary agent and
The mass percent of one thermoplastic plastic parent particles is more than 0 and less than or equal to 70%.
Further, the fluorine auxiliary agent is selected from fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound, fluorine and connect
One or more in the small organic molecule and fluorine silicon graft compound of branch.
It is using the beneficial effect of such scheme:Can be further using above-mentioned fluorine auxiliary agent and suitable adding proportion
Reduce material surface is stained with ash quantity.
Further, the Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, and described
Three thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the silicon additive and
The mass percent of one thermoplastic plastic parent particles is more than 0 and less than or equal to 17.3%.
Further, the silicon additive is selected from silicone oil, silicone, SOLID ORGANIC silicon, liquid silicone, silicate and nano-silica
One or more in the siliceous or fluorosilicone compound that SiClx, silane coupler, silane-based compound are modified.
Nano silicon can be that nano Si 0 is generated in sol-gel process with the alkoxide of silicon, aluminium, titanium and zirconium2,
Can also be hydridization silica, in the preparation, can direct physical blending, can also first with coupling agent treatment silicon additive again
Si modification thermoplastic plastic parent particles are prepared by extruding pelletization.Silicon source presoma is anti-in base catalyst and certain solvent condition
SiO should be generated2Nano sol, then with alkyl silane or silicon fluoride graft modification (Nano-meter SiO_22Graft modification).
It is using the beneficial effect of such scheme:Can be further using above-mentioned silicon additive and suitable adding proportion
Improve imperial grey performance of material.
The present invention provides a kind of preparation method of antistatic material easy to clean, comprises the following steps:According to above-mentioned proportioning
By each component compounding to together, mix, be granulated.
It is using the beneficial effect of such scheme:The present invention has preparation method simple, has antistatic and imperial ash etc. excellent
Point.
The present invention provides a kind of antistatic product easy to clean, and the material of the product includes above-mentioned antistatic material easy to clean
Material.The product prepared by using above-mentioned material has good antistatic property and drives grey performance.The product can be but
It is not limited to:Fan, impeller, the aerofoil fan of air-conditioning, steam cleaner dust stratification bucket, plastic sheeting, electric appliance casing or electric plastics
Device etc..
Brief description of the drawings
Fig. 1 is that dust is stained with the microgram connect with base material.
Fig. 2 is the schematic diagram for being stained with grey situation of the antistatic material easy to clean of the present invention.
Fig. 3 is the schematic diagram for being stained with grey situation of general material (non-antistatic material easy to clean).
Fig. 4 is the testing result of X50 times of light microscope;Left side part A expression comparative example is stained with grey situation, right side B tables
That shows embodiment 8 is stained with grey situation.
Fig. 5 is the testing result of general camera, and left side part A represents the grey situation of being stained with of comparative example, and right side B represents embodiment
1 is stained with grey situation.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit
Determine the scope of the present invention.
Component of the present invention can be prepared by the conventional method of this area or purchased in market obtained unless otherwise noted
.
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, silica, zirconium aluminate,
Dodecyl sodium sulfate, glycol ester, stearate and acetone;In terms of the mass percent of the first thermoplastic plastic parent particles,
Antistatic additive is the 8%-39% of the first thermoplastic plastic parent particles, and silica is less than the 8% of the first thermoplastic plastic parent particles,
Zirconium aluminate is less than the 6.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplastic plastic parent particles
Less than 18%, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
Less than 3.9%, acetone be the first thermoplastic plastic parent particles less than 7.2%.
Preferably, by percentage to the quality, silica be the first thermoplastic plastic parent particles 0.5%-8%, zirconium aluminate
For the 0.5%-6.1% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate is the 1.2%- of the first thermoplastic plastic parent particles
18%, glycol ester is the 0.2%-11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
0.1%-3.9%, acetone are the 0.5%-7.2% of the first thermoplastic plastic parent particles.
First thermoplastic plastic parent particles are thermoplastic, first thermoplastic plastic parent particles be selected from acrylonitrile-
Styrol copolymer (AS plastic), PA plastics, polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polystyrene (PS),
One or more in acrylonitrile-butadiene-styrene copolymerized compound (ABS) and makrolon (PC).
The particle diameter of the silica is:1-100nm.Preferably, the particle diameter of the silica can be selected from following
Scope:The particle diameter of the silica is 1-30nm;Or the particle diameter of the silica is 31-39nm;Or the silica
Particle diameter be 40-50nm;Or the particle diameter of the silica is 51-80nm;Or the particle diameter of the silica is 81-100nm.
The silica is nano silicon, and nano silicon is surface treated nano silicon;
It the treating method comprises following steps:Silica is mixed with ethanol solution, instill compounding coupling agent, compounding coupling agent with
The mass percent of silica dioxide granule is 0.5-2%, and the compounding coupling agent is answered by silane coupler and titanate coupling agent
With into, be stirred by ultrasonic, filter, dry, grinding.
Specifically, following operation can be used:The screen pack screening nanometer silicon dioxide particle of 50-100 mesh is first passed through,
(volume fraction of ethanol is 98%, and 2%) volume fraction of water is, drop these powder granules are poured into the aqueous solution of ethanol
Entering a certain amount of compounding coupling agent, (compounding coupling agent includes silane coupler and titanate coupling agent, and silane coupler is selected from
One or more of compoundings in KH550, KH560 and KH570), the quality for compounding coupling agent is nanometer silicon dioxide particle
The 0.5-2% of quality, 1.5-3h is stirred in 80-95 DEG C of ultrasound of ultrasonic cleaning tank, scattered suspension is depressurized and filtered, in 50-65
DEG C addition drying, it is standby to be ground into homopolymerization particle.
The antistatic additive is selected from cationic antistatic agent, anionic antistatic agents, non-ionic antistatic agent, modification
One or more in CNT, graphene, the copolymer of polyethers and polyamide, metal powder and electrically conductive graphite.It is antistatic
The principle of agent is:1) the electrostatic partial electrostatic for being gathered in impeller surface is guided so that electrostatic less concentration of local;2) moulding
Material substrate surface is formed can repel same electric charge dust with counterions so that static electrification dust and substrate surface
With reference to weaker;3) antistatic additive can capture electronics and neutralize opposite Electrostatic Electron (such as:Static electrification dust granule).
The copolymer of polyethers and polyamide can also write " polyether-polyamide block copolymer ", " polyamide-polyether is more
The form of presentation such as block copolymer ", " copolymer of polyamide-block and polyether block ".The copolymerization of polyethers and polyamide of the present invention
Thing does the understanding of broad sense, and can be grafted electrolyte side chain can not also be grafted electrolyte side chain, such as can be grafted band potassium ion
Electrolyte side chain etc..Such as:Polyethers and polyamide form support polyelectrolyte side chain and are mutually wound with like charges
Network structure, the i.e. powered microballoon similar to cage structure, the electronics (on these electronics source dusts) of oppositely charged can be caught,
The electronics (charged dust) of the electric charge can gradually be buried in oblivion.
It is a kind of in quaternary ammonium alkyl of the cationic antistatic agent selected from long-chain, phosphate and naphthenic acid salt high-molecular polymer
It is or several.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid
Alkali metal salt in one or more.
The non-ionic antistatic agent is selected from ethoxylated fat race alkylamine, macrogol ester or ether, fatty acid ester
With the one or more in glycollic amide.
Modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic can also be included in above-mentioned formula
Property plastic master batch be the first thermoplastic plastic parent particles 0.1%-76.9%.The dosage of modified thermoplastic master batch can select
Following scope:By percentage to the quality, the modified thermoplastic master batch is the first thermoplastic plastic parent particles
0.1%-6.49%;Or the 6.50%-76.9% that the modified thermoplastic master batch is the first thermoplastic plastic parent particles;Or institute
State the 6.5%-18% that modified thermoplastic master batch is the first thermoplastic plastic parent particles;Or the modified thermoplastic master batch
For the 19%-45% of the first thermoplastic plastic parent particles;Or the modified thermoplastic master batch is the first thermoplastic plastic parent particles
46%-76.9%.
The modified thermoplastic master batch in above-mentioned is fluorine richness thermoplastic plastic parent particles and/or Si modification thermoplasticity
Plastic master batch.
The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the fluorine auxiliary agent and the first thermoplasticity
Plastic master batch is more than 0 and less than or equal to 70%.
Fluorine richness can be fluorination treatment, fluoride grafting modification plastic substrate, fluorine auxiliary agent blending and modifying or fluorination
Thing is modified with matrix plastic melt blending.
The fluorine auxiliary agent is selected from fluorocarbons (may also be referred to as carbon fluorine organic), fluorinated ethylene propylene copolymer, fluorine
One or more in small organic molecule and fluorine silicon graft compound that alkyl compound, fluorine are grafted.
The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the silicon additive and the first thermoplasticity
The mass percent of plastic master batch is more than 0 and less than or equal to 17.3%.
The silicon additive is selected from silicone oil, silicone, SOLID ORGANIC silicon, liquid silicone, silicate, nano silicon, silicon
One or more in the siliceous or fluorosilicone compound that alkane coupling agent, silane-based compound are modified.
The species of second thermoplastic plastic parent particles and the first thermoplastic plastic parent particles can be the same or different, such as PC
Base material, the ABS modified master batch of fluorine additive modification can be used, injection is blended together with pure PC master batches.
3rd thermoplastic plastic parent particles are identical from the species of the first thermoplastic plastic parent particles can also be different, such as:Can be with
It is carrier with PE, the PP passed through, the pure mother such as PC, ABS or PET can be added come modified PE, PP, the modified master batch of addition with silicon
Grain.
In above-mentioned formula, fluorine auxiliary agent and silicon additive content can be zero, i.e., this element can add, it is not necessary to contain
Auxiliary agent.
A kind of preparation method of antistatic material easy to clean, comprises the following steps:Each component is answered according to above-mentioned proportioning
It is fitted on together, mixes, is granulated.
When using the formula containing silicon additive or fluorine auxiliary agent, if silicon additive or fluorine auxiliary agent are liquid, in preparation process,
Silicon additive or fluorine auxiliary agent can be fed in extruder liquid addition port region by constant current motor-mount pump, then using twin-screw by silicon
Auxiliary agent or fluorine auxiliary agent and other components melt blending, extruding pelletization.
It is of the present invention to be formulated the antistatic modified scheme that can be used for all plastics.
A kind of antistatic product easy to clean, the material of the product include above-mentioned antistatic material easy to clean.The product
For fan, impeller, the aerofoil fan of air-conditioning, steam cleaner dust stratification bucket, electric appliance casing, plastic sheeting or electric plastics device.
Plastic sheeting can be to need the plastic sheetings such as anlistatig PET, PI or PVC.
Compounding in the present invention is not simply being blended for single various formulas, also further indicate that it is dispersed,
Various components match, chemically and physically intermiscibility, order of addition, addition manner and technique.
Due to the effect of electrostatic, dust is easy to be stained with the surface for being connected on plastic basis material, as shown in figure 1, the table of plastic basis material
Face is covered by dust, influences normal use.The present invention has antistatic well and imperial ash by the setting being reasonably formulated
Effect, as shown in Fig. 2 grey situation is stained with for meet the material of technical solution of the present invention, it is (non-imperial with the general material of Fig. 3 signals
Putty material) grey situation of being stained with compare, technical solution of the present invention has the obvious effect for reducing material surface amount of dust, is using
When, dust is easily cleared up, ensures the normal work of the material.
It is introduced below by some specific embodiments.
Embodiment 1
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
1nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch;With
The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 8% of the first thermoplastic plastic parent particles, silica the
The 0.5% of one thermoplastic plastic parent particles, zirconium aluminate are the 0.5% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate the
The 1.2% of one thermoplastic plastic parent particles, glycol ester are the 0.2% of the first thermoplastic plastic parent particles, and stearate is the first heat
The 0.1% of thermoplastic plastic master batch, acetone are the 0.5% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is first
The 6.5% of thermoplastic plastic parent particles.
Silica-treated method comprises the following steps:Silica dioxide granule is screened by the screen pack of 50 mesh, will be screened
Silica dioxide granule afterwards is poured into the aqueous solution of ethanol, and wherein the volume fraction of ethanol is 98%, instills compounding coupling agent, multiple
Mass percent with coupling agent and silica dioxide granule is 0.5%, and the compounding coupling agent is by silane coupler and titanate esters
Coupling agent compounding forms, and 80 DEG C of ultrasounds stir 1.5h, and decompression filters, dried under the conditions of 50 DEG C, be ground into homopolymerization particle.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from the quaternary ammonium alkyl of cationic antistatic agent long-chain.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic
Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described
Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 180 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 180 DEG C.
Embodiment 2
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
100nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch;With
The mass percent meter of first thermoplastic plastic parent particles, antistatic additive are the 39% of the first thermoplastic plastic parent particles, silica
For the 8% of the first thermoplastic plastic parent particles, zirconium aluminate is the 6.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is
The 18% of first thermoplastic plastic parent particles, glycol ester are the 11% of the first thermoplastic plastic parent particles, and stearate is the first heat
The 3.9% of thermoplastic plastic master batch, acetone are the 7.2% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is first
The 76.9% of thermoplastic plastic parent particles.
Silica-treated method comprises the following steps:Silica dioxide granule is screened by the screen pack of 100 mesh, will be screened
Silica dioxide granule afterwards is poured into the aqueous solution of ethanol, and wherein the volume fraction of ethanol is 98%, instills compounding coupling agent, multiple
Mass percent with coupling agent and silica dioxide granule is 2%, and the compounding coupling agent is even by silane coupler and titanate esters
Connection agent compounding forms, and 95 DEG C of ultrasounds stir 3h, and decompression filters, dried under the conditions of 65 DEG C, be ground into homopolymerization particle.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is anionic antistatic agents.The anionic antistatic agents are alkyl sulfonic acid.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles.The fluorine richness thermoplastic plastic parent particles
Including fluorine auxiliary agent and the second thermoplastic plastic parent particles, the kind of second thermoplastic plastic parent particles and the first thermoplastic plastic parent particles
Class is identical, and by percentage to the quality, the fluorine auxiliary agent is the 42% of the first thermoplastic plastic parent particles.The fluorine auxiliary agent is fluorination second
Allyl alkene copolymer.
During preparation, it can adopt in the following method:
(1) preparation method of fluorine richness thermoplastic plastic parent particles, comprises the following steps:It is by proportioning that fluorine auxiliary agent and second is warm
Thermoplastic plastic master batch is added to extrusion blending in dual-screw-stem machine by proportioning and is granulated, and the temperature of granulation is 200 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 200 DEG C.
Embodiment 3
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
50nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch;With
The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is
The 5% of first thermoplastic plastic parent particles, zirconium aluminate are the 3% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate first
The 5% of thermoplastic plastic parent particles, glycol ester are the 5% of the first thermoplastic plastic parent particles, and stearate is moulded for the first thermoplasticity
Expect the 2% of master batch, acetone is the 5% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is the first thermoplastic
The 30% of master batch.
Silica-treated method comprises the following steps:Silica dioxide granule is screened by the screen pack of 70 mesh, will be screened
Silica dioxide granule afterwards is poured into the aqueous solution of ethanol, and wherein the volume fraction of ethanol is 98%, instills compounding coupling agent, multiple
Mass percent with coupling agent and silica dioxide granule is 1%, and the compounding coupling agent is even by silane coupler and titanate esters
Connection agent compounding forms, and 90 DEG C of ultrasounds stir 2h, and decompression filters, dried under the conditions of 55 DEG C, be ground into homopolymerization particle.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is non-ionic antistatic agent.The non-ionic antistatic agent is ethoxylated fat race alkane
Base amine.
The modified thermoplastic master batch is Si modification thermoplastic plastic parent particles.The Si modification thermoplastic plastic parent particles
Including silicon additive and the 3rd thermoplastic plastic parent particles, the kind of the 3rd thermoplastic plastic parent particles and the first thermoplastic plastic parent particles
Class is identical, and by percentage to the quality, the silicon additive is the 10.3% of the first thermoplastic plastic parent particles.The silicon additive is silicon
Ketone.
During preparation, it can adopt in the following method:
(1) preparation method of Si modification thermoplastic plastic parent particles, comprises the following steps:It is by proportioning that silicon additive and the 3rd is warm
Thermoplastic plastic master batch is added to extrusion blending in dual-screw-stem machine by proportioning and is granulated, and the temperature of granulation is 190 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 190 DEG C.
Embodiment 4
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
20nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch;With
The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 10% of the first thermoplastic plastic parent particles, and silica is
The 2.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 2.5% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is
The 3.2% of first thermoplastic plastic parent particles, glycol ester are the 3.2% of the first thermoplastic plastic parent particles, stearate first
The 2.9% of thermoplastic plastic parent particles, acetone are the 2.5% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is the
The 8.5% of one thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent and the compound of anionic antistatic agents.
The cationic antistatic agent is the compound of phosphate and naphthenic acid salt high-molecular polymer, phosphate and naphthenic acid salt
The mass ratio of high molecular polymer is 1:1.
The anionic antistatic agents are carboxylate and phosphatic compound, the carboxylate and phosphatic mass ratio
For 1:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles
Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity
The 12% of plastic master batch.Compound of the fluorine auxiliary agent in fluorinated ethylene propylene copolymer, fluoroalkyle compound, fluorination
Ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 1:1.2.The Si modification thermoplastic plastic parent particles include silicon additive
With the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, with
Mass percent meter, the silicon additive are the 5.9% of the first thermoplastic plastic parent particles.The silicon additive be selected from liquid silicone and
The mass ratio of the compound of silicate, liquid silicone and silicate is 0.3:1.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 185 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 185 DEG C.
Embodiment 5
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
30nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch;With
The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 13% of the first thermoplastic plastic parent particles, and silica is
The 5.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 1.5% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is
The 6.2% of first thermoplastic plastic parent particles, glycol ester are the 1.2% of the first thermoplastic plastic parent particles, stearate first
The 1.1% of thermoplastic plastic parent particles, acetone are the 1.5% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is the
The 11.5% of one thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, the first thermoplastic plastic parent particles acrylonitrile-fourth two
Alkene-styrene copolymerized compound.
The antistatic additive is selected from the compound of modified CNT, graphene and metal powder, CNT, graphene
Mass ratio with metal powder is 1:1:1.
The modified thermoplastic master batch includes fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.
The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles
Identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
25%.Three kinds in fluorocarbons, fluorinated ethylene propylene copolymer and fluoroalkyle compound of the fluorine auxiliary agent are answered
With thing, the mass ratio of fluorocarbons, fluorinated ethylene propylene copolymer and fluoroalkyle compound is 1:1:1.The Si modification heat
Thermoplastic plastic master batch includes silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and the first thermoplasticity
The species of plastic master batch is identical, and by percentage to the quality, the silicon additive is the 12.7% of the first thermoplastic plastic parent particles.It is described
Three kind of compounding of the silicon additive in liquid silicone, silicate, nano silicon, liquid silicone, silicate, nanometer
The compounding that three kinds of silica.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 185 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 185 DEG C.
Embodiment 6
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
40nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch;With
The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 23% of the first thermoplastic plastic parent particles, and silica is
The 6.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 4.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is
The 10.1% of first thermoplastic plastic parent particles, glycol ester are the 8.4% of the first thermoplastic plastic parent particles, stearate first
The 3.3% of thermoplastic plastic parent particles, acetone are the 6% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is first
The 46% of thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is answering for cationic antistatic agent, non-ionic antistatic agent, metal powder and electrically conductive graphite
With thing, cationic antistatic agent, non-ionic antistatic agent, the mass ratio of metal powder and electrically conductive graphite are 1:1:1:1.
Three kinds in quaternary ammonium alkyl of the cationic antistatic agent selected from long-chain, phosphate and naphthenic acid salt high-molecular polymer
Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 0.5:0.7:1:1.2.
The non-ionic antistatic agent is selected from ethoxylated fat race alkylamine, macrogol ester, fatty acid ester and second
Four kinds of compounding in alkylolamides, ethoxylated fat race alkylamine, macrogol ester, the quality of fatty acid ester and glycollic amide
Than for 1:0.2:1:2.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles
Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity
The 30% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three
The compounding of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 1:1:2.The Si modification
Thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and the first thermoplastic
Property plastic master batch species it is identical, by percentage to the quality, the silicon additive be the first thermoplastic plastic parent particles 15.1%.Institute
State four kind of compounding of the silicon additive in silicone oil, silicone, SOLID ORGANIC silicon and silicate, silicone oil, silicone, SOLID ORGANIC silicon and
The mass ratio of silicate is 0.1:1.4:1.2:3.3.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 185 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 185 DEG C.
Embodiment 7
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
60nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch;With
The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 35% of the first thermoplastic plastic parent particles, and silica is
The 7.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 5.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is
The 15% of first thermoplastic plastic parent particles, glycol ester are the 10.1% of the first thermoplastic plastic parent particles, stearate first
The 3.5% of thermoplastic plastic parent particles, acetone are the 7% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is first
The 66% of thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent, anionic antistatic agents, the CNT of modification, graphene, poly-
The copolymer of ether and polyamide, metal powder and electrically conductive graphite with mass ratio 1:0.4:1:1.7:1:2.1:After 1.3 compoundings
Compound.
The cationic antistatic agent is the quaternary ammonium alkyl of long-chain, three kinds of phosphate and naphthenic acid salt high-molecular polymer
Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 1:2.3:0.4.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid
Alkali metal salt in five kinds of compounding, alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, the alkali of phosphate and aminodithioformic acid
Metal salt mass ratio is 1.2:0.4:1:1.7:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles
Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity
The 38% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three
The compound of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 0.3:1:0.8.It is described
Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and
The species of one thermoplastic plastic parent particles is identical, and by percentage to the quality, the silicon additive is the first thermoplastic plastic parent particles
16%.Five kind of compounding of the silicon additive in silicone oil, silicone, liquid silicone, silicate, nano silicon, silicon
Oil, silicone, liquid silicone, the mass ratio of silicate and nano silicon are 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 185 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 185 DEG C.
Embodiment 8
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive and modified thermoplastic
Master batch;In terms of the mass percent of the first thermoplastic plastic parent particles, antistatic additive is the 8% of the first thermoplastic plastic parent particles,
Modified thermoplastic master batch is the 6.5% of the first thermoplastic plastic parent particles.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.The antistatic additive is the copolymer of polyethers and polyamide.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles
Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity
The 2% of plastic master batch.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd
Thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, with quality hundred
Divide than meter, the silicon additive is the 0.9% of the first thermoplastic plastic parent particles.It is organic that the silicon additive is selected from silicone oil, silicone, liquid
Five kinds of compounding in silicon, silicate, nano silicon, silicone oil, silicone, liquid silicone, silicate and nanometer titanium dioxide
The mass ratio of silicon is 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 185 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 185 DEG C.
Embodiment 9
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, dodecyl sodium sulfate,
Glycol ester, stearate, acetone and modified thermoplastic master batch;With the mass percent of the first thermoplastic plastic parent particles
Meter, antistatic additive are the 8% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplastic plastic parent particles
15%, glycol ester is the 10.1% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
3.5%, acetone is the 7% of the first thermoplastic plastic parent particles;Modified thermoplastic master batch is the first thermoplastic plastic parent particles
6.5%.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent, anionic antistatic agents, the CNT of modification, graphene, poly-
The copolymer of ether and polyamide, metal powder and electrically conductive graphite with mass ratio 1:0.4:1:1.7:1:2.1:After 1.3 compoundings
Compound.
The cationic antistatic agent is the quaternary ammonium alkyl of long-chain, three kinds of phosphate and naphthenic acid salt high-molecular polymer
Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 1:2.3:0.4.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid
Alkali metal salt in five kinds of compounding, alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, the alkali of phosphate and aminodithioformic acid
Metal salt mass ratio is 1.2:0.4:1:1.7:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles
Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity
The 2% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three
The compound of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 0.3:1:0.8.It is described
Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and
The species of one thermoplastic plastic parent particles is identical, and by percentage to the quality, the silicon additive is the first thermoplastic plastic parent particles
0.9%.Five kind of compounding of the silicon additive in silicone oil, silicone, liquid silicone, silicate, nano silicon, silicon
Oil, silicone, liquid silicone, the mass ratio of silicate and nano silicon are 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 185 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 185 DEG C.
Embodiment 10
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
60nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone and modified thermoplastic master batch;With the first thermoplasticity
The mass percent meter of plastic master batch, antistatic additive are the 8% of the first thermoplastic plastic parent particles, and silica is the first thermoplasticity
The 7.5% of plastic master batch, zirconium aluminate are the 5.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplasticity
The 15% of plastic master batch, glycol ester are the 10.1% of the first thermoplastic plastic parent particles, and acetone is the first thermoplastic plastic parent particles
7%;Modified thermoplastic master batch is the 6.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent, anionic antistatic agents, the CNT of modification, graphene, poly-
The copolymer of ether and polyamide, metal powder and electrically conductive graphite with mass ratio 1:0.4:1:1.7:1:2.1:After 1.3 compoundings
Compound.
The cationic antistatic agent is the quaternary ammonium alkyl of long-chain, three kinds of phosphate and naphthenic acid salt high-molecular polymer
Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 1:2.3:0.4.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid
Alkali metal salt in five kinds of compounding, alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, the alkali of phosphate and aminodithioformic acid
Metal salt mass ratio is 1.2:0.4:1:1.7:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles
Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity
The 2% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three
The compound of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 0.3:1:0.8.It is described
Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and
The species of one thermoplastic plastic parent particles is identical, and by percentage to the quality, the silicon additive is the first thermoplastic plastic parent particles
0.9%.Five kind of compounding of the silicon additive in silicone oil, silicone, liquid silicone, silicate, nano silicon, silicon
Oil, silicone, liquid silicone, the mass ratio of silicate and nano silicon are 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method:
(1) preparation method of modified thermoplastic master batch, comprises the following steps:By proportioning by fluorine auxiliary agent, silicon additive, fluorine
The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning
Middle extrusion blending is granulated;The temperature of granulation is 185 DEG C;
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding
For 185 DEG C.
Embodiment 11
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
31nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and modified thermoplastic master batch;With the first heat
The mass percent meter of thermoplastic plastic master batch, antistatic additive are the 18.5% of the first thermoplastic plastic parent particles, silica the
The 1.2% of one thermoplastic plastic parent particles, zirconium aluminate are the 0.82% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate the
The 3% of one thermoplastic plastic parent particles, glycol ester are the 2.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic
Property plastic master batch 0.5%, modified thermoplastic master batch be the first thermoplastic plastic parent particles 43%.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e.
Ethoxylated fat race alkylamine) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene
For 10:8:0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic
Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described
Silicon additive is the 17.3% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 12
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
51nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, modified thermoplastic master batch;It is female with the first thermoplastic
The mass percent meter of grain, antistatic additive are the 20.5% of the first thermoplastic plastic parent particles, and silica is moulded for the first thermoplasticity
Expect the 0.6% of master batch, zirconium aluminate is the 0.41% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is moulded for the first thermoplasticity
Expect the 10% of master batch, glycol ester is the 5.5% of the first thermoplastic plastic parent particles, and modified thermoplastic master batch is the first thermoplastic
The 1.6% of property plastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane
Base sulfonic acid) and graphene.The mass ratio of cationic antistatic agent, anionic antistatic agents and graphene is 4:16:0.5.
The modified thermoplastic master batch is Si modification thermoplastic plastic parent particles.The Si modification thermoplastic plastic parent particles
Including silicon additive and the 3rd thermoplastic plastic parent particles, the kind of the 3rd thermoplastic plastic parent particles and the first thermoplastic plastic parent particles
Class is identical, and by percentage to the quality, the silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 3
Embodiment 13
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
80nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone, modified thermoplastic master batch;Moulded with the first thermoplasticity
Expect the mass percent meter of master batch, antistatic additive is the 20.5% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic
Property plastic master batch 0.8%, zirconium aluminate be the first thermoplastic plastic parent particles 0.72%, dodecyl sodium sulfate is the first thermoplastic
Property plastic master batch 2%, glycol ester be the first thermoplastic plastic parent particles 1.5%, acetone is the first thermoplastic plastic parent particles
0.5%, modified thermoplastic master batch be the first thermoplastic plastic parent particles 20.75%.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e.
Ethoxylated fat race alkylamine) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene
For 4:16:0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic
Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described
Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 14
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
81nm), zirconium aluminate, glycol ester, stearate;In terms of the mass percent of the first thermoplastic plastic parent particles, antistatic additive
For the 21.5% of the first thermoplastic plastic parent particles, silica is the 1.2% of the first thermoplastic plastic parent particles, zirconium aluminate first
The 1.05% of thermoplastic plastic parent particles, glycol ester are the 5.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic
The 0.5% of property plastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain) and graphene.Cationic antistatic
The mass ratio of agent and graphene is 20:1.5.
The preparation method of modified thermoplastic master batch, comprises the following steps:The each component in formula is compounded by proportioning
Together, mix, be granulated, injection molding, the temperature of injection molding is 185 DEG C.
Embodiment 15
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, zirconium aluminate, dodecyl
Sodium sulfonate, glycol ester, modified thermoplastic master batch;In terms of the mass percent of the first thermoplastic plastic parent particles, resist quiet
Electric agent is the 20% of the first thermoplastic plastic parent particles, and zirconium aluminate is the 0.63% of the first thermoplastic plastic parent particles, dodecyl sulphur
Sour sodium is the 1% of the first thermoplastic plastic parent particles, and glycol ester is the 0.8% of the first thermoplastic plastic parent particles, modified thermoplastic
Plastic master batch is the 5.8% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from anionic antistatic agents (i.e. alkyl sulfonic acid), non-ionic antistatic agent (i.e. ethyoxyl
Change aliphatic alkylamine).Anionic antistatic agents, the mass ratio of non-ionic antistatic agent are 3:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic
Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described
Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 16
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone;With the first thermoplastic plastic parent particles
Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles
0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles
0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e.
Ethoxylated fat race alkylamine) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene
For 5:1:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 17
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
5nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, modified thermoplastic master batch;With the first thermoplastic
Property plastic master batch mass percent meter, antistatic additive be the first thermoplastic plastic parent particles 22.5%, silica first
The 0.5% of thermoplastic plastic parent particles, zirconium aluminate are the 0.3% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate first
The 2% of thermoplastic plastic parent particles, glycol ester are the 5.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplasticity
The 0.62% of plastic master batch, modified thermoplastic master batch are the 16.25% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane
Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from
The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 20:1:0.5:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic
Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described
Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 18
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
10nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone, modified thermoplastic master batch;Moulded with the first thermoplasticity
Expect the mass percent meter of master batch, antistatic additive is the 21% of the first thermoplastic plastic parent particles, and silica is the first thermoplasticity
The 1% of plastic master batch, zirconium aluminate are the 0.82% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is moulded for the first thermoplasticity
Expect the 2.5% of master batch, glycol ester is the 1% of the first thermoplastic plastic parent particles, and acetone is the first thermoplastic plastic parent particles
1%, modified thermoplastic master batch is the 30.25% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane
Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from
The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 12:6:2:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic
Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described
Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 19
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
15nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone, modified thermoplastic master batch;Moulded with the first thermoplasticity
Expect the mass percent meter of master batch, antistatic additive is the 22.5% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic
Property plastic master batch 0.6%, zirconium aluminate be the first thermoplastic plastic parent particles 0.80%, dodecyl sodium sulfate is the first thermoplastic
Property plastic master batch 6%, glycol ester be the first thermoplastic plastic parent particles 3.5%, acetone is the first thermoplastic plastic parent particles
0.5%, modified thermoplastic master batch be the first thermoplastic plastic parent particles 0.41%.Modified thermoplastic master batch is silicon
Modified thermoplastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane
Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from
The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 10:10:2:0.5.
The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplasticity
Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the silicon additive is the first thermoplasticity
The 0.09% of plastic master batch.The silicon additive is the fluorosilicone compound thing that silane-based compound is modified.The method of modifying of silicon additive
With reference to the method for modifying of silica.
The preparation method of antistatic material easy to clean is with reference to embodiment 3.
Embodiment 20
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
20nm), dodecyl sodium sulfate, glycol ester, stearate, modified thermoplastic master batch;With the first thermoplastic
The mass percent meter of master batch, antistatic additive are the 22.5% of the first thermoplastic plastic parent particles, and silica is the first thermoplasticity
The 1.0% of plastic master batch, dodecyl sodium sulfate are the 1% of the first thermoplastic plastic parent particles, and glycol ester is the first thermoplasticity
The 4.2% of plastic master batch, stearate are the 1% of the first thermoplastic plastic parent particles, and modified thermoplastic master batch is the first heat
The 32.75% of thermoplastic plastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane
Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from
The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 10:10:2:0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic
Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described
Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is the siliceous of silane-based compound modification.Silicon additive
Method of modifying of the method for modifying with reference to silica.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 21
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
25nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, modified thermoplastic master batch;With the first thermoplastic
Property plastic master batch mass percent meter, antistatic additive be the first thermoplastic plastic parent particles 20.5%, silica first
The 2% of thermoplastic plastic parent particles, zirconium aluminate are the 1.05% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first heat
The 5% of thermoplastic plastic master batch, glycol ester are the 1.2% of the first thermoplastic plastic parent particles, and stearate is moulded for the first thermoplasticity
Expect the 0.25% of master batch, modified thermoplastic master batch is the 28% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from anionic antistatic agents (i.e. alkyl sulfonic acid), non-ionic antistatic agent (i.e. ethyoxyl
Change aliphatic alkylamine) and graphene.The mass ratio of anionic antistatic agents, non-ionic antistatic agent and graphene is 10:
10:0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles.The fluorine richness thermoplastic plastic parent particles
Including fluorine auxiliary agent and the second thermoplastic plastic parent particles, the kind of second thermoplastic plastic parent particles and the first thermoplastic plastic parent particles
Class is identical, and by percentage to the quality, the fluorine auxiliary agent is the 2% of the first thermoplastic plastic parent particles.The fluorine auxiliary agent is that fluorine silicon connects
Cladodification compound.Preparation method is with reference to embodiment 2.
Embodiment 22
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
30nm), dodecyl sodium sulfate, glycol ester, acetone, stearate, modified thermoplastic master batch;With the first thermoplasticity
The mass percent meter of plastic master batch, antistatic additive are the 20.5% of the first thermoplastic plastic parent particles, and silica is the first heat
The 0.8% of thermoplastic plastic master batch, dodecyl sodium sulfate are the 7.5% of the first thermoplastic plastic parent particles, glycol ester first
The 1% of thermoplastic plastic parent particles, acetone are the 0.75% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic
The 0.25% of master batch, modified thermoplastic master batch are the 16.75% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane
Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from
The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 7.5:2.5:10:0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute
Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with
The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles
2%.The fluorine auxiliary agent is that fluorine is grafted small organic molecule.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd heat
Thermoplastic plastic master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, with quality percentage
Than meter, the silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silane coupler.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 23
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone;With the first thermoplastic plastic parent particles
Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles
0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles
0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e.
Fatty acid ester) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene is 5:2:4.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 24
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone;With the first thermoplastic plastic parent particles
Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles
0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles
0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. phosphate and naphthenic acid salt high-molecular polymer), nonionic
Antistatic additive (i.e. macrogol ester) and modified CNT.Cationic antistatic agent, non-ionic antistatic agent and modification
CNT mass ratio be 5:1:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 25
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone;With the first thermoplastic plastic parent particles
Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles
0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles
0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e.
Glycollic amide) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene is 5:2:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 26
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica
90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone;With the first thermoplastic plastic parent particles
Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles
0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles
0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles
0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth
Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e.
Ethoxylated fat race alkylamine) and electrically conductive graphite.The quality of cationic antistatic agent, non-ionic antistatic agent and graphene
Than for 5:3:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Comparative example:The first thermoplastic plastic parent particles are comprised only, i.e., pure ABS material.
Each embodiment and comparative example are subjected to effect detection respectively.
1st, the detection method of surface resistivity is:
Surface resistivity is parallel in electric potential gradient and surface unit width by the sense of current on material surface
The ratio between electric current, use ohms.
Surface resistivity can directly be detected using sheet resistance tester, and operating method may refer to specification.
The surface resistivity tester of all Data Detections is QUICK 499D.
In use, measuring instrument is placed in into testee surface, feeler switch is pressed, then shows the sheet resistance of testee
Coefficient surface resistivity uses ASTM standard D-257 parallel pole method for sensing, uses the integrated amplifications of high-precision OP-AMP
Device carries out automatic measurement.
Surface resistivity:The parameter is used for the certain thin-film material of thickness, and it is defined as the straight of unit length on surface
Stream pressure drop flows through the ratio between electric current with unit width.
The numerical value of surface resistivity is the smaller the better.The smaller explanation antistatic effect of numerical value of surface resistivity is strong, does not allow more
Easily it is stained with ash.
Experimental result is shown in Table 1.
2nd, the detection method of surface energy is:
Surface energy is the measurement destroyed when creating material surface to intermolecular chemical bond.First first with contact angle detection instrument
, can be using YGG equations, harmonic equation or geometric equation come computational chart after device detects the contact angle on the surface of object to be measured
Face energy.The numerical value of surface energy is the smaller the better, and interface does not adhere to organic matter and water, and dust-proof effect will be better.Surface energy value
Smaller explanation is less susceptible to be stained with ash.Experimental result is shown in Table 1.
3rd, driving grey detection method is:
Prepared by each comparative example and each embodiment example into fan respectively to be put into inside the ducting system of a connection, it is periodically past
The standard dust of the addition true dust of simulated atmosphere inside ducting system, every 2 hours, to ducting system the inside addition standard
Dust 20g.Fan stops a period of time after operation a period of time, is considered as a cycle.Each cycle, soot blowing 10 minutes are quiet
Put 10 minutes, soot blowing speed is 1-2m/s.Cycle is continuously 2 days.After experiment terminates, the ash quantity of being stained with of each testing sample is counted
Summation.Repeatedly and carry out statistical analysis.And calculate and drive grey effect, drive grey effect and refer to being modified flabellum in material prescription
Relatively primitive flabellum (i.e. comparative example) is stained with ash quantity down ratio above in the case of change.Grey effect numerical value is driven to be the bigger the better.Experiment
It the results are shown in Table 1.
The testing result of table 1
" Ω/ " refers to square resistance in table 1.
It is can be seen that by the data of table 1 by adding antistatic additive, silica, zirconium aluminate, dodecyl sodium sulfonate
Sodium, glycol ester, stearate and acetone can reduce surface resistivity and surface energy, improve the effect for driving ash.
The addition of fluorine auxiliary agent is have adjusted on the basis of embodiment 2, remaining is same as Example 2.Detect data
As a result it is as shown in table 2.
The testing result of material after the addition adjustment of the fluorine auxiliary agent of table 2
Data in table 1 can be seen that addition (i.e. the fluorine auxiliary agent and the first thermoplastic plastic parent particles of fluorine auxiliary agent
Mass percent) effect of imperial ash can be improved further in the range of 10%-30% and 40%-60%.
Inventor further have adjusted the adding proportion of modified thermoplastic master batch on the basis of embodiment 1, with
The mass percent of first thermoplastic plastic parent particles is reference, modified thermoplastic master batch is respectively 0.1%, 5%,
6.49%th, 10%, 18%, 19%, 45%, 46%, 60%, 76.9%.Result of study shows, homogeneous in the proportioning of other components
With under conditions of, can have preferably imperial ash effect between 0.1-76.9% in the addition of modified thermoplastic master batch
Fruit.
Inventor further have adjusted the particle diameter of silica, the particle diameter point of silica on the basis of embodiment 1
Not Wei 2nm, 20nm, 30nm, 31nm, 35nm, 39nm, 40nm, 45nm, 40nm, 50nm, 51nm, 60nm, 80nm, 90nm and
100nm, result of study show, in other conditions under the same conditions, in the range of 1-30nm or 31-39nm, silica compared with
Few addition can plays the effect for driving ash, in the range of 40-50nm, is advantageous to silica surface processing and uniformly divides
Dissipate, in the range of 51-80nm, be easy to industrialized production, in the range of 81-100nm, it is easier to be scattered.
Fig. 4 and Fig. 5 is the results of comparison for being stained with grey situation of comparative example and embodiment.Fig. 4 and Fig. 5 is in the imperial ash of same detection
System in the result that is detected.Amount of dust and concentration in the system is very big, periodically adds dust inside, when testing one section
Between material surface be stained with grey picture (test is the effect of dynamic bind static state dust stratification), specific operating procedure is the same as above-mentioned imperial ash
Detection method.According to Fig. 4 as can be seen that comparative example to be stained with ash more, and embodiment 8 is stained with that ash is fewer, and embodiment 8 is when shorter
Interior or even imperial ash.According to Fig. 5 as can be seen that comparative example be stained with ash it is more, and embodiment 1 be stained with ash it is fewer, embodiment 1 is shorter
In time or even non-sticky ash.
Inventor has attempted with acrylonitritrile-styrene resin, PA plastics, polyethylene, polypropylene, polyvinyl chloride, poly- again
One or more of compoundings in styrene, acrylonitrile-butadiene-styrene copolymerized compound and makrolon are as the first heat
Thermoplastic plastic master batch, it can also obtain conclusion consistent with the above.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (24)
1. a kind of antistatic material easy to clean, it is characterised in that including the first thermoplastic plastic parent particles, antistatic additive, titanium dioxide
Silicon, zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone;With the quality of the first thermoplastic plastic parent particles
Percentages, antistatic additive are the 8%-39% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles
Less than 8%, zirconium aluminate be the first thermoplastic plastic parent particles less than 6.1%, dodecyl sodium sulfate be the first thermoplasticity modeling
Expect less than the 18% of master batch, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplasticity
Less than the 3.9% of plastic master batch, acetone are less than the 7.2% of the first thermoplastic plastic parent particles.
A kind of 2. antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, titanium dioxide
Silicon be the first thermoplastic plastic parent particles 0.5%-8%, zirconium aluminate be the first thermoplastic plastic parent particles 0.5%-6.1%, ten
Dialkyl sulfonates are the 1.2%-18% of the first thermoplastic plastic parent particles.
A kind of 3. antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, ethylene glycol
Ester is the 0.2%-11% of the first thermoplastic plastic parent particles.
A kind of 4. antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, stearic acid
Ester is the 0.1%-3.9% of the first thermoplastic plastic parent particles.
5. a kind of antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, acetone is
The 0.5%-7.2% of first thermoplastic plastic parent particles.
A kind of 6. antistatic material easy to clean according to claim 1, it is characterised in that first thermoplastic plastic parent particles
For thermoplastic, first thermoplastic plastic parent particles are selected from acrylonitritrile-styrene resin, PA plastics, polyethylene, poly- third
One or more in alkene, polyvinyl chloride, polystyrene, acrylonitrile-butadiene-styrene copolymerized compound and makrolon.
7. a kind of antistatic material easy to clean according to claim 1, it is characterised in that the particle diameter of the silica is:
1-100nm。
8. a kind of antistatic material easy to clean according to claim 7, it is characterised in that the particle diameter of the silica is 1-
30nm;Or the particle diameter of the silica is 31-39nm;Or the particle diameter of the silica is 40-50nm;Or the titanium dioxide
The particle diameter of silicon is 51-80nm;Or the particle diameter of the silica is 81-100nm.
9. according to the antistatic material easy to clean of the described one kind of any one of claim 1-8, it is characterised in that the silica is
Nano silicon, nano silicon are surface treated nano silicon;It the treating method comprises following step
Suddenly:Silica is mixed with ethanol solution, instills compounding coupling agent, compounds the quality percentage of coupling agent and silica dioxide granule
Than being formed, being stirred by ultrasonic by silane coupler and titanate coupling agent compounding, filtered, dried for 0.5-2%, the compounding coupling agent
It is dry, grinding.
A kind of 10. antistatic material easy to clean according to claim 1, it is characterised in that the antistatic additive be selected from sun from
Sub- antistatic additive, anionic antistatic agents, non-ionic antistatic agent, the CNT of modification, graphene, polyethers and polyamide
Copolymer, the one or more in metal powder and electrically conductive graphite.
A kind of 11. antistatic material easy to clean according to claim 10, it is characterised in that the cationic antistatic agent choosing
It is one or more of from the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer.
A kind of 12. antistatic material easy to clean according to claim 10, it is characterised in that the anionic antistatic agents choosing
One or more from the alkali metal salt of alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid.
A kind of 13. antistatic material easy to clean according to claim 10, it is characterised in that the non-ionic antistatic agent
One or more in ethoxylated fat race alkylamine, macrogol ester or ether, fatty acid ester and glycollic amide.
14. a kind of antistatic material easy to clean according to claim 1, it is characterised in that also including modified thermoplastic
Master batch, by percentage to the quality, the modified thermoplastic master batch are the 0.1%-76.9% of the first thermoplastic plastic parent particles.
15. a kind of antistatic material easy to clean according to claim 14, it is characterised in that also including modified thermoplastic
Master batch, by percentage to the quality, the modified thermoplastic master batch are the 0.1%-6.49% of the first thermoplastic plastic parent particles
Or the 6.50%-76.9% that the modified thermoplastic master batch is the first thermoplastic plastic parent particles.
16. a kind of antistatic material easy to clean according to claim 15, it is characterised in that also including modified thermoplastic
Master batch, by percentage to the quality, the modified thermoplastic master batch are the 6.5%-18% of the first thermoplastic plastic parent particles;Or
The modified thermoplastic master batch is the 19%-45% of the first thermoplastic plastic parent particles;Or the modified thermoplastic is female
Grain is the 46%-76.9% of the first thermoplastic plastic parent particles.
17. a kind of antistatic material easy to clean according to claim 14, it is characterised in that the modified thermoplastic is female
Grain is fluorine richness thermoplastic plastic parent particles and/or Si modification thermoplastic plastic parent particles.
A kind of 18. antistatic material easy to clean according to claim 17, it is characterised in that the fluorine richness thermoplastic
Master batch includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic
The mass percent of master batch is more than 0 and less than or equal to 70%.
19. a kind of antistatic material easy to clean according to claim 18, it is characterised in that the fluorine auxiliary agent is carbonized selected from fluorine
In small organic molecule and fluorine silicon graft compound that compound, fluorinated ethylene propylene copolymer, fluoroalkyle compound, fluorine are grafted
It is one or more of.
A kind of 20. antistatic material easy to clean according to claim 17, it is characterised in that the Si modification thermoplastic
Master batch includes silicon additive and the 3rd thermoplastic plastic parent particles, by percentage to the quality, the silicon additive accounts for the first thermoplastic
The mass percent of master batch is more than 0 and less than or equal to 17.3%.
A kind of 21. antistatic material easy to clean according to claim 20, it is characterised in that the silicon additive be selected from silicone oil,
Silicone, SOLID ORGANIC silicon, liquid silicone, silicate, nano silicon, silane coupler, silane-based compound are modified
One or more in siliceous or fluorosilicone compound.
22. a kind of preparation method of antistatic material easy to clean, it is characterised in that comprise the following steps:According to claim 1-
Each component compounding to together, is mixed, is granulated by the proportioning described in 21 any one.
23. a kind of antistatic product easy to clean, it is characterised in that the material of the product is included described in claim any one of 1-21
Antistatic material easy to clean.
A kind of 24. antistatic product easy to clean according to claim 23, it is characterised in that the product be fan, impeller,
Aerofoil fan, steam cleaner dust stratification bucket, electric appliance casing, plastic sheeting or the electric plastics device of air-conditioning.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101033316A (en) * | 2006-03-08 | 2007-09-12 | 天津乐金塑钢门窗有限公司 | Polyvinyl chloride antistatic dust-proof modified window section bar and producing method thereof |
CN101864142A (en) * | 2010-06-30 | 2010-10-20 | 银禧工程塑料(东莞)有限公司 | Highlight high-hardness dustproof ABS (Acrylonitrile Butadiene-Styrene) alloy material for electronic and electric products and preparation method thereof |
CN102585429A (en) * | 2011-01-11 | 2012-07-18 | 合肥杰事杰新材料股份有限公司 | Resin material, preparation method and applications of resin material |
CN102634191A (en) * | 2012-05-15 | 2012-08-15 | 金发科技股份有限公司 | Permanent antistatic nylon elastomer material and preparation method thereof |
-
2016
- 2016-09-30 CN CN201610875519.3A patent/CN107880473A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101033316A (en) * | 2006-03-08 | 2007-09-12 | 天津乐金塑钢门窗有限公司 | Polyvinyl chloride antistatic dust-proof modified window section bar and producing method thereof |
CN101864142A (en) * | 2010-06-30 | 2010-10-20 | 银禧工程塑料(东莞)有限公司 | Highlight high-hardness dustproof ABS (Acrylonitrile Butadiene-Styrene) alloy material for electronic and electric products and preparation method thereof |
CN102585429A (en) * | 2011-01-11 | 2012-07-18 | 合肥杰事杰新材料股份有限公司 | Resin material, preparation method and applications of resin material |
CN102634191A (en) * | 2012-05-15 | 2012-08-15 | 金发科技股份有限公司 | Permanent antistatic nylon elastomer material and preparation method thereof |
Cited By (9)
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---|---|---|---|---|
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CN109134904B (en) * | 2018-08-20 | 2021-04-23 | 蚌埠市维光塑胶制品有限公司 | Method for preparing anti-fogging anti-adhesion plastic film by using nano silicon dioxide-cage type silsesquioxane |
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CN109651704A (en) * | 2018-12-11 | 2019-04-19 | 金旸(厦门)新材料科技有限公司 | A kind of dedicated automatically cleaning master batch of intelligent closestool and flame-retarding high-lustre PP composite material and preparation method |
CN111875884A (en) * | 2020-07-31 | 2020-11-03 | 海信(山东)空调有限公司 | Filter screen and air conditioner |
CN114716746A (en) * | 2021-01-06 | 2022-07-08 | 中国石油天然气股份有限公司 | Hydrophobic and oleophobic polyethylene master batch, preparation method thereof and polyethylene pipeline material |
CN115536931A (en) * | 2022-01-11 | 2022-12-30 | 诺曼化学(盘锦)有限公司 | Color master batch with antistatic function and preparation method thereof |
CN115536931B (en) * | 2022-01-11 | 2023-10-27 | 诺曼化学(盘锦)有限公司 | Masterbatch with antistatic function and preparation method thereof |
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