CN107880473A - A kind of antistatic material easy to clean and preparation method thereof - Google Patents

A kind of antistatic material easy to clean and preparation method thereof Download PDF

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Publication number
CN107880473A
CN107880473A CN201610875519.3A CN201610875519A CN107880473A CN 107880473 A CN107880473 A CN 107880473A CN 201610875519 A CN201610875519 A CN 201610875519A CN 107880473 A CN107880473 A CN 107880473A
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thermoplastic plastic
parent particles
plastic parent
thermoplastic
antistatic
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徐前
熊玉明
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Midea Group Co Ltd
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Midea Group Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of antistatic material easy to clean and preparation method thereof.A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles and following component；In terms of the mass percent of the first thermoplastic plastic parent particles, antistatic additive is 8% the 39% of the first thermoplastic plastic parent particles, silica is less than the 8% of the first thermoplastic plastic parent particles, zirconium aluminate is less than the 6.1% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate is less than the 18% of the first thermoplastic plastic parent particles, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, stearate is less than the 3.9% of the first thermoplastic plastic parent particles, and acetone is less than the 7.2% of the first thermoplastic plastic parent particles.During preparation, each component compounding is mixed, injection molding to together by proportioning.Antistatic material easy to clean of the present invention and preparation method thereof has the advantages that antistatic and easy to clean.

Description

A kind of antistatic material easy to clean and preparation method thereof
Technical field
The invention belongs to field of material technology, more particularly to a kind of antistatic material easy to clean and preparation method thereof.
Background technology
The phenomenon of dust stratification often occurs during use for some plastic products, such as：Dust in air can be with Suspension, bacterium floating, can surface deposit, also can dynamic friction air, cause Electrostatic Absorption dust.Not only need often clear Reason operation is cumbersome, and can influence the service life of equipment.It is specifically introduced below by taking flabellum or impeller as an example.
By taking outdoor machine of air-conditioner impeller as an example, the impeller of long-term dust stratification can cause air conditioner refrigerating efficiency decay more than 30%, air-conditioning In use, dust easily in its surface attachment and then deposition, influences air quantity, efficiency, and easy shape to interior machine ducting part Into secondary pollution, many bacteriums harm health can be grown, therefore, improve material surface property so that surface, which is not easy to be stained with ash, to be become Highly significant.
During running at high speed, flabellum (impeller leaf) produces dynamic static friction with air interaction for electric fan and impeller, Dust adsorption charged ion can be caused.Positively or negatively, same sex electric charge mutually repels enhancing to about 90%-95% suspension The degree of stability of dust in air, the flabellum and windage band that the charges of different polarity mutually attract to promote dust accumulation and settle rotation Upper electric charge, and electrical body has the property for attracting slight small item body, so dust can be attracted on flabellum.According to the literature in air Particle diameter is less than 75 μm of solid suspension, and the especially more decentralization in the dust of 0.1-10 μ ms of particle diameter are higher, of dust Grain is more tiny, and the showy time is longer in atmosphere, and dust also has a bacterium corpse in atmosphere, oil stain, moisture, some The fiber of batting shape so that the aerial dust pattern that suspends is extremely complex, and so multi-component dust, which is easier to be enriched with, to be glued On impeller or flabellum, long-term flabellum or impeller just gradually become very dirty, and in the inside leaf of the electrical equipment such as air-conditioning, dust catcher Wheel, if being stained with ash for a long time on radiator fan impeller, its normal operating efficiency can be influenceed, thus a kind of imperial ash flabellum easy to clean with Impeller can become extremely important.
The operating for a long time of existing unmodified flabellum or impeller stands a period of time, will be deposited on impeller or flabellum Many dusts, flabellum impeller just gradually become very dirty, have a strong impact on the outward appearance of flabellum impeller.And as in air-conditioning, dust catcher Deng the internal impeller of electrical equipment, if being stained with ash for a long time on radiator fan impeller, can influence inside its normal operating efficiency, such as air-conditioning Impeller, windage increase can seriously be caused by being stained with ash, influence the refrigeration of complete machine, and dust is enriched with flabellum in addition, can influence flabellum The dynamic balancing of rotation, have a strong impact on the influence of flabellum and impeller place air output and other side.Existing technical scheme is exactly Regular to take cleaning dust apart, operation is inconvenient and time-consuming, and especially cleaning can be pretty troublesome, and cleaning meeting airborne dust is harmful.Therefore, By antistatic additive modified plastics surface characteristic, the adhesion for reducing dust and plastic interface is significant.
The content of the invention
In view of the problems of prior art, the present invention provides antistatic material easy to clean and preparation method thereof, has The advantages that antistatic, imperial grey and easy to clean.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, silica, zirconium aluminate, Dodecyl sodium sulfate, glycol ester, stearate and acetone；In terms of the mass percent of the first thermoplastic plastic parent particles, Antistatic additive is the 8%-39% of the first thermoplastic plastic parent particles, and silica is less than the 8% of the first thermoplastic plastic parent particles, Zirconium aluminate is less than the 6.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplastic plastic parent particles Less than 18%, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles Less than 3.9%, acetone be the first thermoplastic plastic parent particles less than 7.2%.
The beneficial effects of the invention are as follows：
Inventor is found surprisingly that under study for action, and the antistatic of proper ratio is added in the first thermoplastic plastic parent particles Agent, on the premise of ensureing that the original performance of material is unaffected, while the antistatic property of obtained material can be improved, make system The material obtained has the effect for driving ash.When the addition proper ratio on the basis of the first thermoplastic plastic parent particles and antistatic additive One or more in silica, zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone, pass through dioxy SiClx, zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone and antistatic additive are used cooperatively, Ke Yijin One step strengthens anlistatig effect.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, by percentage to the quality, silica be the first thermoplastic plastic parent particles 0.5%-8%, zirconium aluminate For the 0.5%-6.1% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate is the 1.2%- of the first thermoplastic plastic parent particles 18%.
Further, glycol ester is the 0.2%-11% of the first thermoplastic plastic parent particles.
Further, stearate is the 0.1%-3.9% of the first thermoplastic plastic parent particles.
Further, acetone is the 0.5%-7.2% of the first thermoplastic plastic parent particles.
It is using the beneficial effect of such scheme：
Inventor be found surprisingly that under study for action the addition silica of proper ratio, zirconium aluminate, dodecyl sodium sulfate, Glycol ester, stearate and acetone and antistatic additive are used cooperatively, and participate in the modifying process of material, and blending chemistry occurs Reaction so that antistatic active principle can be preferably dispersed, so as to lift the antistatic effect of material, significantly improves system Imperial grey effect of the material obtained.
First thermoplastic plastic parent particles of the present invention are thermoplastic, and material of the invention can use any kind Thermoplastic can be but be not limited to following title as the first thermoplastic plastic parent particles：First thermoplastic Master batch is selected from acrylonitritrile-styrene resin, PA plastics, polyethylene, polypropylene, polyvinyl chloride, polystyrene, acrylonitrile-fourth One or more of compoundings in diene-styrene copolymerized compound and the medium Common thermoplastic's plastics of makrolon.
Further, the particle diameter of the silica is：1-100nm.
It is using the beneficial effect of such scheme：Using the silica of appropriate particle size, further improve material prescription Processing characteristics, nano silicon, which improves antistatic additive and base-material, slippage effect, and a small amount of nano silicon can play Increase rubbing action, improve processing characteristics.
Further, the particle diameter of the silica is that the particle diameter of 1-30nm or described silica is 31-39nm.
It is using the beneficial effect of such scheme：The particle diameter of silica is smaller, and specific surface area is larger, less addition Can significantly improves the performance of material.
Further, the particle diameter of the silica is：40-50nm.
It is using the beneficial effect of such scheme：Be advantageous to silica surface processing and it is dispersed.
Further, the particle diameter of the silica is：51-80nm.
It is using the beneficial effect of such scheme：Industrialized production is convenient.
Further, the particle diameter of the silica is：81-100nm.
It is using the beneficial effect of such scheme：Particle is bigger, easily scattered.
Further, the silica is nano silicon, and nano silicon is surface treated nanometer two Silica；It the treating method comprises following steps：Silica is mixed with ethanol solution, instills compounding coupling agent, compounding The mass percent of coupling agent and silica dioxide granule is 0.5-2%, and the compounding coupling agent is by silane coupler and titanate esters Coupling agent compounding forms, and is stirred by ultrasonic, and filters, and dries, grinding.
It is using the beneficial effect of such scheme：Be advantageous to improve the performance of silica, had using the aqueous solution of ethanol Beneficial to hydrolysis coupling agent so that in resin matrix dispersedly evenly, surface treatment improves inorganic nano two to silica The compatibility of silica and resin matrix.
Further, it is antistatic to be selected from cationic antistatic agent, anionic antistatic agents, nonionic for the antistatic additive Agent, the CNT of modification, graphene, copolymer, metal powder and one kind or several in electrically conductive graphite of polyethers and polyamide Kind.
It is using the beneficial effect of such scheme：
Because the specific insulation of existing material is generally up to 2x1012-1020Ω/, easily put aside electrostatic and endanger It is stained with nearly and easily ash.Using the antistatic additive of mentioned kind isolated electric charge can be enabled to be pulled away, conductive material surface Electric charge, the electric charge of material surface institute band is reduced, so that dust is not easy to be bonded at the surface of material.
Further, the cationic antistatic agent is selected from quaternary ammonium alkyl, phosphate and the polymerization of naphthenic acid salt high-molecular of long-chain It is one or more of in thing.
It is using the beneficial effect of such scheme：Being coordinated using the cationic antistatic agent of mentioned kind with other components is made With being advantageous to further improve antistatic effect.
Further, it is thio to be selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and two for the anionic antistatic agents One or more in carbamic alkali metal salt.
It is using the beneficial effect of such scheme：Being coordinated using the anionic antistatic agents of mentioned kind with other components is made With being advantageous to further improve antistatic effect.
Further, the non-ionic antistatic agent is selected from ethoxylated fat race alkylamine, macrogol ester or ether, fat One or more in fat acid esters and glycollic amide.
It is using the beneficial effect of such scheme：Being coordinated using the non-ionic antistatic agent of mentioned kind with other components is made With being advantageous to further improve antistatic effect.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch For the 0.1%-76.9% of the first thermoplastic plastic parent particles.
It is using the beneficial effect of such scheme：, can be with by adding the modified thermoplastic master batch of proper ratio Further improve and the antistatic performance for being not easy to be stained with putty material is made.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch For the 0.1%-6.49% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch For the 6.50%-76.9% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch For the 6.5%-18% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch For the 19%-45% of the first thermoplastic plastic parent particles.
Further, in addition to modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic master batch For the 46%-76.9% of the first thermoplastic plastic parent particles.
Beneficial effect using above-mentioned several schemes is：The modified thermoplastic master batch for adding above-mentioned different proportion can be with Imperial grey performance of the different degrees of whole material of raising.
Further, the modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and/or Si modification thermoplasticity Plastic master batch.
It is using the beneficial effect of such scheme：Silicon atom can form one layer of " Si- exposed to the surface of moulding The good stabilized zone of O-Si " keys, the low-surface-energy of organosilicon so that it has good hydrophobic waterproof.Fluorine richness thermoplasticity Plastic master batch, be mainly using C-F chain links are short, the surface energy of C-F keys is also low, Si-C-F by with low-surface-energy change Kind product surface stain resistance so that surface can reach hydrophobic oleophobic, surface stain resistance increase so that dust is not easy to be stained with In blade surface, the interface of dust and low-surface-energy acts on plus antistatic additive so that adhesion of the dust at interface diminishes, ash If the dust that the first layer at interface adheres to is seldom, the dust on interface is just more difficult to be further continued on the dust of first layer dirt Adsorb more dusts so that the adhesive capacity of overall dust is reduced, and makes the dust for sticking in surface be easy to clear up.
Further, the fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, and described Two thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the fluorine auxiliary agent and The mass percent of one thermoplastic plastic parent particles is more than 0 and less than or equal to 70%.
Further, the fluorine auxiliary agent is selected from fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound, fluorine and connect One or more in the small organic molecule and fluorine silicon graft compound of branch.
It is using the beneficial effect of such scheme：Can be further using above-mentioned fluorine auxiliary agent and suitable adding proportion Reduce material surface is stained with ash quantity.
Further, the Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, and described Three thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the silicon additive and The mass percent of one thermoplastic plastic parent particles is more than 0 and less than or equal to 17.3%.
Further, the silicon additive is selected from silicone oil, silicone, SOLID ORGANIC silicon, liquid silicone, silicate and nano-silica One or more in the siliceous or fluorosilicone compound that SiClx, silane coupler, silane-based compound are modified.
Nano silicon can be that nano Si 0 is generated in sol-gel process with the alkoxide of silicon, aluminium, titanium and zirconium2, Can also be hydridization silica, in the preparation, can direct physical blending, can also first with coupling agent treatment silicon additive again Si modification thermoplastic plastic parent particles are prepared by extruding pelletization.Silicon source presoma is anti-in base catalyst and certain solvent condition SiO should be generated2Nano sol, then with alkyl silane or silicon fluoride graft modification (Nano-meter SiO_22Graft modification).
It is using the beneficial effect of such scheme：Can be further using above-mentioned silicon additive and suitable adding proportion Improve imperial grey performance of material.
The present invention provides a kind of preparation method of antistatic material easy to clean, comprises the following steps：According to above-mentioned proportioning By each component compounding to together, mix, be granulated.
It is using the beneficial effect of such scheme：The present invention has preparation method simple, has antistatic and imperial ash etc. excellent Point.
The present invention provides a kind of antistatic product easy to clean, and the material of the product includes above-mentioned antistatic material easy to clean Material.The product prepared by using above-mentioned material has good antistatic property and drives grey performance.The product can be but It is not limited to：Fan, impeller, the aerofoil fan of air-conditioning, steam cleaner dust stratification bucket, plastic sheeting, electric appliance casing or electric plastics Device etc..
Brief description of the drawings
Fig. 1 is that dust is stained with the microgram connect with base material.
Fig. 2 is the schematic diagram for being stained with grey situation of the antistatic material easy to clean of the present invention.
Fig. 3 is the schematic diagram for being stained with grey situation of general material (non-antistatic material easy to clean).
Fig. 4 is the testing result of X50 times of light microscope；Left side part A expression comparative example is stained with grey situation, right side B tables That shows embodiment 8 is stained with grey situation.
Fig. 5 is the testing result of general camera, and left side part A represents the grey situation of being stained with of comparative example, and right side B represents embodiment 1 is stained with grey situation.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
Component of the present invention can be prepared by the conventional method of this area or purchased in market obtained unless otherwise noted .
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, silica, zirconium aluminate, Dodecyl sodium sulfate, glycol ester, stearate and acetone；In terms of the mass percent of the first thermoplastic plastic parent particles, Antistatic additive is the 8%-39% of the first thermoplastic plastic parent particles, and silica is less than the 8% of the first thermoplastic plastic parent particles, Zirconium aluminate is less than the 6.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplastic plastic parent particles Less than 18%, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles Less than 3.9%, acetone be the first thermoplastic plastic parent particles less than 7.2%.
Preferably, by percentage to the quality, silica be the first thermoplastic plastic parent particles 0.5%-8%, zirconium aluminate For the 0.5%-6.1% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate is the 1.2%- of the first thermoplastic plastic parent particles 18%, glycol ester is the 0.2%-11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles 0.1%-3.9%, acetone are the 0.5%-7.2% of the first thermoplastic plastic parent particles.
First thermoplastic plastic parent particles are thermoplastic, first thermoplastic plastic parent particles be selected from acrylonitrile- Styrol copolymer (AS plastic), PA plastics, polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polystyrene (PS), One or more in acrylonitrile-butadiene-styrene copolymerized compound (ABS) and makrolon (PC).
The particle diameter of the silica is：1-100nm.Preferably, the particle diameter of the silica can be selected from following Scope：The particle diameter of the silica is 1-30nm；Or the particle diameter of the silica is 31-39nm；Or the silica Particle diameter be 40-50nm；Or the particle diameter of the silica is 51-80nm；Or the particle diameter of the silica is 81-100nm.
The silica is nano silicon, and nano silicon is surface treated nano silicon； It the treating method comprises following steps：Silica is mixed with ethanol solution, instill compounding coupling agent, compounding coupling agent with The mass percent of silica dioxide granule is 0.5-2%, and the compounding coupling agent is answered by silane coupler and titanate coupling agent With into, be stirred by ultrasonic, filter, dry, grinding.
Specifically, following operation can be used：The screen pack screening nanometer silicon dioxide particle of 50-100 mesh is first passed through, (volume fraction of ethanol is 98%, and 2%) volume fraction of water is, drop these powder granules are poured into the aqueous solution of ethanol Entering a certain amount of compounding coupling agent, (compounding coupling agent includes silane coupler and titanate coupling agent, and silane coupler is selected from One or more of compoundings in KH550, KH560 and KH570), the quality for compounding coupling agent is nanometer silicon dioxide particle The 0.5-2% of quality, 1.5-3h is stirred in 80-95 DEG C of ultrasound of ultrasonic cleaning tank, scattered suspension is depressurized and filtered, in 50-65 DEG C addition drying, it is standby to be ground into homopolymerization particle.
The antistatic additive is selected from cationic antistatic agent, anionic antistatic agents, non-ionic antistatic agent, modification One or more in CNT, graphene, the copolymer of polyethers and polyamide, metal powder and electrically conductive graphite.It is antistatic The principle of agent is:1) the electrostatic partial electrostatic for being gathered in impeller surface is guided so that electrostatic less concentration of local；2) moulding Material substrate surface is formed can repel same electric charge dust with counterions so that static electrification dust and substrate surface With reference to weaker；3) antistatic additive can capture electronics and neutralize opposite Electrostatic Electron (such as：Static electrification dust granule).
The copolymer of polyethers and polyamide can also write " polyether-polyamide block copolymer ", " polyamide-polyether is more The form of presentation such as block copolymer ", " copolymer of polyamide-block and polyether block ".The copolymerization of polyethers and polyamide of the present invention Thing does the understanding of broad sense, and can be grafted electrolyte side chain can not also be grafted electrolyte side chain, such as can be grafted band potassium ion Electrolyte side chain etc..Such as：Polyethers and polyamide form support polyelectrolyte side chain and are mutually wound with like charges Network structure, the i.e. powered microballoon similar to cage structure, the electronics (on these electronics source dusts) of oppositely charged can be caught, The electronics (charged dust) of the electric charge can gradually be buried in oblivion.
It is a kind of in quaternary ammonium alkyl of the cationic antistatic agent selected from long-chain, phosphate and naphthenic acid salt high-molecular polymer It is or several.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid Alkali metal salt in one or more.
The non-ionic antistatic agent is selected from ethoxylated fat race alkylamine, macrogol ester or ether, fatty acid ester With the one or more in glycollic amide.
Modified thermoplastic master batch, by percentage to the quality, the modified thermoplastic can also be included in above-mentioned formula Property plastic master batch be the first thermoplastic plastic parent particles 0.1%-76.9%.The dosage of modified thermoplastic master batch can select Following scope：By percentage to the quality, the modified thermoplastic master batch is the first thermoplastic plastic parent particles 0.1%-6.49%；Or the 6.50%-76.9% that the modified thermoplastic master batch is the first thermoplastic plastic parent particles；Or institute State the 6.5%-18% that modified thermoplastic master batch is the first thermoplastic plastic parent particles；Or the modified thermoplastic master batch For the 19%-45% of the first thermoplastic plastic parent particles；Or the modified thermoplastic master batch is the first thermoplastic plastic parent particles 46%-76.9%.
The modified thermoplastic master batch in above-mentioned is fluorine richness thermoplastic plastic parent particles and/or Si modification thermoplasticity Plastic master batch.
The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the fluorine auxiliary agent and the first thermoplasticity Plastic master batch is more than 0 and less than or equal to 70%.
Fluorine richness can be fluorination treatment, fluoride grafting modification plastic substrate, fluorine auxiliary agent blending and modifying or fluorination Thing is modified with matrix plastic melt blending.
The fluorine auxiliary agent is selected from fluorocarbons (may also be referred to as carbon fluorine organic), fluorinated ethylene propylene copolymer, fluorine One or more in small organic molecule and fluorine silicon graft compound that alkyl compound, fluorine are grafted.
The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the silicon additive and the first thermoplasticity The mass percent of plastic master batch is more than 0 and less than or equal to 17.3%.
The silicon additive is selected from silicone oil, silicone, SOLID ORGANIC silicon, liquid silicone, silicate, nano silicon, silicon One or more in the siliceous or fluorosilicone compound that alkane coupling agent, silane-based compound are modified.
The species of second thermoplastic plastic parent particles and the first thermoplastic plastic parent particles can be the same or different, such as PC Base material, the ABS modified master batch of fluorine additive modification can be used, injection is blended together with pure PC master batches.
3rd thermoplastic plastic parent particles are identical from the species of the first thermoplastic plastic parent particles can also be different, such as：Can be with It is carrier with PE, the PP passed through, the pure mother such as PC, ABS or PET can be added come modified PE, PP, the modified master batch of addition with silicon Grain.
In above-mentioned formula, fluorine auxiliary agent and silicon additive content can be zero, i.e., this element can add, it is not necessary to contain Auxiliary agent.
A kind of preparation method of antistatic material easy to clean, comprises the following steps：Each component is answered according to above-mentioned proportioning It is fitted on together, mixes, is granulated.
When using the formula containing silicon additive or fluorine auxiliary agent, if silicon additive or fluorine auxiliary agent are liquid, in preparation process, Silicon additive or fluorine auxiliary agent can be fed in extruder liquid addition port region by constant current motor-mount pump, then using twin-screw by silicon Auxiliary agent or fluorine auxiliary agent and other components melt blending, extruding pelletization.
It is of the present invention to be formulated the antistatic modified scheme that can be used for all plastics.
A kind of antistatic product easy to clean, the material of the product include above-mentioned antistatic material easy to clean.The product For fan, impeller, the aerofoil fan of air-conditioning, steam cleaner dust stratification bucket, electric appliance casing, plastic sheeting or electric plastics device. Plastic sheeting can be to need the plastic sheetings such as anlistatig PET, PI or PVC.
Compounding in the present invention is not simply being blended for single various formulas, also further indicate that it is dispersed, Various components match, chemically and physically intermiscibility, order of addition, addition manner and technique.
Due to the effect of electrostatic, dust is easy to be stained with the surface for being connected on plastic basis material, as shown in figure 1, the table of plastic basis material Face is covered by dust, influences normal use.The present invention has antistatic well and imperial ash by the setting being reasonably formulated Effect, as shown in Fig. 2 grey situation is stained with for meet the material of technical solution of the present invention, it is (non-imperial with the general material of Fig. 3 signals Putty material) grey situation of being stained with compare, technical solution of the present invention has the obvious effect for reducing material surface amount of dust, is using When, dust is easily cleared up, ensures the normal work of the material.
It is introduced below by some specific embodiments.
Embodiment 1
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 1nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch；With The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 8% of the first thermoplastic plastic parent particles, silica the The 0.5% of one thermoplastic plastic parent particles, zirconium aluminate are the 0.5% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate the The 1.2% of one thermoplastic plastic parent particles, glycol ester are the 0.2% of the first thermoplastic plastic parent particles, and stearate is the first heat The 0.1% of thermoplastic plastic master batch, acetone are the 0.5% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is first The 6.5% of thermoplastic plastic parent particles.
Silica-treated method comprises the following steps：Silica dioxide granule is screened by the screen pack of 50 mesh, will be screened Silica dioxide granule afterwards is poured into the aqueous solution of ethanol, and wherein the volume fraction of ethanol is 98%, instills compounding coupling agent, multiple Mass percent with coupling agent and silica dioxide granule is 0.5%, and the compounding coupling agent is by silane coupler and titanate esters Coupling agent compounding forms, and 80 DEG C of ultrasounds stir 1.5h, and decompression filters, dried under the conditions of 50 DEG C, be ground into homopolymerization particle.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from the quaternary ammonium alkyl of cationic antistatic agent long-chain.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 180 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 180 DEG C.
Embodiment 2
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 100nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch；With The mass percent meter of first thermoplastic plastic parent particles, antistatic additive are the 39% of the first thermoplastic plastic parent particles, silica For the 8% of the first thermoplastic plastic parent particles, zirconium aluminate is the 6.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is The 18% of first thermoplastic plastic parent particles, glycol ester are the 11% of the first thermoplastic plastic parent particles, and stearate is the first heat The 3.9% of thermoplastic plastic master batch, acetone are the 7.2% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is first The 76.9% of thermoplastic plastic parent particles.
Silica-treated method comprises the following steps：Silica dioxide granule is screened by the screen pack of 100 mesh, will be screened Silica dioxide granule afterwards is poured into the aqueous solution of ethanol, and wherein the volume fraction of ethanol is 98%, instills compounding coupling agent, multiple Mass percent with coupling agent and silica dioxide granule is 2%, and the compounding coupling agent is even by silane coupler and titanate esters Connection agent compounding forms, and 95 DEG C of ultrasounds stir 3h, and decompression filters, dried under the conditions of 65 DEG C, be ground into homopolymerization particle.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is anionic antistatic agents.The anionic antistatic agents are alkyl sulfonic acid.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles.The fluorine richness thermoplastic plastic parent particles Including fluorine auxiliary agent and the second thermoplastic plastic parent particles, the kind of second thermoplastic plastic parent particles and the first thermoplastic plastic parent particles Class is identical, and by percentage to the quality, the fluorine auxiliary agent is the 42% of the first thermoplastic plastic parent particles.The fluorine auxiliary agent is fluorination second Allyl alkene copolymer.
During preparation, it can adopt in the following method：
(1) preparation method of fluorine richness thermoplastic plastic parent particles, comprises the following steps：It is by proportioning that fluorine auxiliary agent and second is warm Thermoplastic plastic master batch is added to extrusion blending in dual-screw-stem machine by proportioning and is granulated, and the temperature of granulation is 200 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 200 DEG C.
Embodiment 3
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 50nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch；With The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is The 5% of first thermoplastic plastic parent particles, zirconium aluminate are the 3% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate first The 5% of thermoplastic plastic parent particles, glycol ester are the 5% of the first thermoplastic plastic parent particles, and stearate is moulded for the first thermoplasticity Expect the 2% of master batch, acetone is the 5% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is the first thermoplastic The 30% of master batch.
Silica-treated method comprises the following steps：Silica dioxide granule is screened by the screen pack of 70 mesh, will be screened Silica dioxide granule afterwards is poured into the aqueous solution of ethanol, and wherein the volume fraction of ethanol is 98%, instills compounding coupling agent, multiple Mass percent with coupling agent and silica dioxide granule is 1%, and the compounding coupling agent is even by silane coupler and titanate esters Connection agent compounding forms, and 90 DEG C of ultrasounds stir 2h, and decompression filters, dried under the conditions of 55 DEG C, be ground into homopolymerization particle.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is non-ionic antistatic agent.The non-ionic antistatic agent is ethoxylated fat race alkane Base amine.
The modified thermoplastic master batch is Si modification thermoplastic plastic parent particles.The Si modification thermoplastic plastic parent particles Including silicon additive and the 3rd thermoplastic plastic parent particles, the kind of the 3rd thermoplastic plastic parent particles and the first thermoplastic plastic parent particles Class is identical, and by percentage to the quality, the silicon additive is the 10.3% of the first thermoplastic plastic parent particles.The silicon additive is silicon Ketone.
During preparation, it can adopt in the following method：
(1) preparation method of Si modification thermoplastic plastic parent particles, comprises the following steps：It is by proportioning that silicon additive and the 3rd is warm Thermoplastic plastic master batch is added to extrusion blending in dual-screw-stem machine by proportioning and is granulated, and the temperature of granulation is 190 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 190 DEG C.
Embodiment 4
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 20nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch；With The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 10% of the first thermoplastic plastic parent particles, and silica is The 2.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 2.5% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is The 3.2% of first thermoplastic plastic parent particles, glycol ester are the 3.2% of the first thermoplastic plastic parent particles, stearate first The 2.9% of thermoplastic plastic parent particles, acetone are the 2.5% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is the The 8.5% of one thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent and the compound of anionic antistatic agents.
The cationic antistatic agent is the compound of phosphate and naphthenic acid salt high-molecular polymer, phosphate and naphthenic acid salt The mass ratio of high molecular polymer is 1:1.
The anionic antistatic agents are carboxylate and phosphatic compound, the carboxylate and phosphatic mass ratio For 1:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity The 12% of plastic master batch.Compound of the fluorine auxiliary agent in fluorinated ethylene propylene copolymer, fluoroalkyle compound, fluorination Ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 1:1.2.The Si modification thermoplastic plastic parent particles include silicon additive With the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, with Mass percent meter, the silicon additive are the 5.9% of the first thermoplastic plastic parent particles.The silicon additive be selected from liquid silicone and The mass ratio of the compound of silicate, liquid silicone and silicate is 0.3:1.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 185 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 185 DEG C.
Embodiment 5
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 30nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch；With The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 13% of the first thermoplastic plastic parent particles, and silica is The 5.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 1.5% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is The 6.2% of first thermoplastic plastic parent particles, glycol ester are the 1.2% of the first thermoplastic plastic parent particles, stearate first The 1.1% of thermoplastic plastic parent particles, acetone are the 1.5% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is the The 11.5% of one thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, the first thermoplastic plastic parent particles acrylonitrile-fourth two Alkene-styrene copolymerized compound.
The antistatic additive is selected from the compound of modified CNT, graphene and metal powder, CNT, graphene Mass ratio with metal powder is 1:1:1.
The modified thermoplastic master batch includes fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles. The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles Identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 25%.Three kinds in fluorocarbons, fluorinated ethylene propylene copolymer and fluoroalkyle compound of the fluorine auxiliary agent are answered With thing, the mass ratio of fluorocarbons, fluorinated ethylene propylene copolymer and fluoroalkyle compound is 1:1:1.The Si modification heat Thermoplastic plastic master batch includes silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and the first thermoplasticity The species of plastic master batch is identical, and by percentage to the quality, the silicon additive is the 12.7% of the first thermoplastic plastic parent particles.It is described Three kind of compounding of the silicon additive in liquid silicone, silicate, nano silicon, liquid silicone, silicate, nanometer The compounding that three kinds of silica.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 185 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 185 DEG C.
Embodiment 6
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 40nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch；With The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 23% of the first thermoplastic plastic parent particles, and silica is The 6.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 4.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is The 10.1% of first thermoplastic plastic parent particles, glycol ester are the 8.4% of the first thermoplastic plastic parent particles, stearate first The 3.3% of thermoplastic plastic parent particles, acetone are the 6% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is first The 46% of thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is answering for cationic antistatic agent, non-ionic antistatic agent, metal powder and electrically conductive graphite With thing, cationic antistatic agent, non-ionic antistatic agent, the mass ratio of metal powder and electrically conductive graphite are 1:1:1:1.
Three kinds in quaternary ammonium alkyl of the cationic antistatic agent selected from long-chain, phosphate and naphthenic acid salt high-molecular polymer Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 0.5:0.7:1:1.2.
The non-ionic antistatic agent is selected from ethoxylated fat race alkylamine, macrogol ester, fatty acid ester and second Four kinds of compounding in alkylolamides, ethoxylated fat race alkylamine, macrogol ester, the quality of fatty acid ester and glycollic amide Than for 1:0.2:1:2.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity The 30% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three The compounding of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 1:1:2.The Si modification Thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and the first thermoplastic Property plastic master batch species it is identical, by percentage to the quality, the silicon additive be the first thermoplastic plastic parent particles 15.1%.Institute State four kind of compounding of the silicon additive in silicone oil, silicone, SOLID ORGANIC silicon and silicate, silicone oil, silicone, SOLID ORGANIC silicon and The mass ratio of silicate is 0.1:1.4:1.2：3.3.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 185 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 185 DEG C.
Embodiment 7
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 60nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, acetone and modified thermoplastic master batch；With The mass percent meter of one thermoplastic plastic parent particles, antistatic additive are the 35% of the first thermoplastic plastic parent particles, and silica is The 7.5% of first thermoplastic plastic parent particles, zirconium aluminate are the 5.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is The 15% of first thermoplastic plastic parent particles, glycol ester are the 10.1% of the first thermoplastic plastic parent particles, stearate first The 3.5% of thermoplastic plastic parent particles, acetone are the 7% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is first The 66% of thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent, anionic antistatic agents, the CNT of modification, graphene, poly- The copolymer of ether and polyamide, metal powder and electrically conductive graphite with mass ratio 1:0.4:1:1.7:1:2.1:After 1.3 compoundings Compound.
The cationic antistatic agent is the quaternary ammonium alkyl of long-chain, three kinds of phosphate and naphthenic acid salt high-molecular polymer Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 1:2.3:0.4.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid Alkali metal salt in five kinds of compounding, alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, the alkali of phosphate and aminodithioformic acid Metal salt mass ratio is 1.2:0.4:1:1.7:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity The 38% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three The compound of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 0.3:1:0.8.It is described Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and The species of one thermoplastic plastic parent particles is identical, and by percentage to the quality, the silicon additive is the first thermoplastic plastic parent particles 16%.Five kind of compounding of the silicon additive in silicone oil, silicone, liquid silicone, silicate, nano silicon, silicon Oil, silicone, liquid silicone, the mass ratio of silicate and nano silicon are 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 185 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 185 DEG C.
Embodiment 8
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive and modified thermoplastic Master batch；In terms of the mass percent of the first thermoplastic plastic parent particles, antistatic additive is the 8% of the first thermoplastic plastic parent particles, Modified thermoplastic master batch is the 6.5% of the first thermoplastic plastic parent particles.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.The antistatic additive is the copolymer of polyethers and polyamide.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity The 2% of plastic master batch.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd Thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, with quality hundred Divide than meter, the silicon additive is the 0.9% of the first thermoplastic plastic parent particles.It is organic that the silicon additive is selected from silicone oil, silicone, liquid Five kinds of compounding in silicon, silicate, nano silicon, silicone oil, silicone, liquid silicone, silicate and nanometer titanium dioxide The mass ratio of silicon is 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 185 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 185 DEG C.
Embodiment 9
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, dodecyl sodium sulfate, Glycol ester, stearate, acetone and modified thermoplastic master batch；With the mass percent of the first thermoplastic plastic parent particles Meter, antistatic additive are the 8% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplastic plastic parent particles 15%, glycol ester is the 10.1% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles 3.5%, acetone is the 7% of the first thermoplastic plastic parent particles；Modified thermoplastic master batch is the first thermoplastic plastic parent particles 6.5%.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent, anionic antistatic agents, the CNT of modification, graphene, poly- The copolymer of ether and polyamide, metal powder and electrically conductive graphite with mass ratio 1:0.4:1:1.7:1:2.1:After 1.3 compoundings Compound.
The cationic antistatic agent is the quaternary ammonium alkyl of long-chain, three kinds of phosphate and naphthenic acid salt high-molecular polymer Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 1:2.3:0.4.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid Alkali metal salt in five kinds of compounding, alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, the alkali of phosphate and aminodithioformic acid Metal salt mass ratio is 1.2:0.4:1:1.7:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity The 2% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three The compound of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 0.3:1:0.8.It is described Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and The species of one thermoplastic plastic parent particles is identical, and by percentage to the quality, the silicon additive is the first thermoplastic plastic parent particles 0.9%.Five kind of compounding of the silicon additive in silicone oil, silicone, liquid silicone, silicate, nano silicon, silicon Oil, silicone, liquid silicone, the mass ratio of silicate and nano silicon are 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 185 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 185 DEG C.
Embodiment 10
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 60nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone and modified thermoplastic master batch；With the first thermoplasticity The mass percent meter of plastic master batch, antistatic additive are the 8% of the first thermoplastic plastic parent particles, and silica is the first thermoplasticity The 7.5% of plastic master batch, zirconium aluminate are the 5.1% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first thermoplasticity The 15% of plastic master batch, glycol ester are the 10.1% of the first thermoplastic plastic parent particles, and acetone is the first thermoplastic plastic parent particles 7%；Modified thermoplastic master batch is the 6.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is cationic antistatic agent, anionic antistatic agents, the CNT of modification, graphene, poly- The copolymer of ether and polyamide, metal powder and electrically conductive graphite with mass ratio 1:0.4:1:1.7:1:2.1:After 1.3 compoundings Compound.
The cationic antistatic agent is the quaternary ammonium alkyl of long-chain, three kinds of phosphate and naphthenic acid salt high-molecular polymer Compound, the mass ratio of the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer is 1:2.3:0.4.
The anionic antistatic agents are selected from alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid Alkali metal salt in five kinds of compounding, alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, the alkali of phosphate and aminodithioformic acid Metal salt mass ratio is 1.2:0.4:1:1.7:1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles Compound.The fluorine richness thermoplastic plastic parent particles include fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplasticity The 2% of plastic master batch.The fluorine auxiliary agent in fluorocarbons, fluorinated ethylene propylene copolymer, fluoroalkyle compound three The compound of kind, fluorocarbons, fluorinated ethylene propylene copolymer, the mass ratio of fluoroalkyle compound are 0.3:1:0.8.It is described Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplastic plastic parent particles and The species of one thermoplastic plastic parent particles is identical, and by percentage to the quality, the silicon additive is the first thermoplastic plastic parent particles 0.9%.Five kind of compounding of the silicon additive in silicone oil, silicone, liquid silicone, silicate, nano silicon, silicon Oil, silicone, liquid silicone, the mass ratio of silicate and nano silicon are 3.2:7.4:1:6.7:0.5.
During preparation, it can adopt in the following method：
(1) preparation method of modified thermoplastic master batch, comprises the following steps：By proportioning by fluorine auxiliary agent, silicon additive, fluorine The second modified thermoplastic plastic parent particles and the 3rd thermoplastic plastic parent particles of Si modification are added to dual-screw-stem machine by proportioning Middle extrusion blending is granulated；The temperature of granulation is 185 DEG C；
(2) each component in formula is compounded together by proportioning, mixes, be granulated, injection molding, the temperature of injection molding For 185 DEG C.
Embodiment 11
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 31nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and modified thermoplastic master batch；With the first heat The mass percent meter of thermoplastic plastic master batch, antistatic additive are the 18.5% of the first thermoplastic plastic parent particles, silica the The 1.2% of one thermoplastic plastic parent particles, zirconium aluminate are the 0.82% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate the The 3% of one thermoplastic plastic parent particles, glycol ester are the 2.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic Property plastic master batch 0.5%, modified thermoplastic master batch be the first thermoplastic plastic parent particles 43%.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e. Ethoxylated fat race alkylamine) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene For 10:8：0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described Silicon additive is the 17.3% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 12
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 51nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, modified thermoplastic master batch；It is female with the first thermoplastic The mass percent meter of grain, antistatic additive are the 20.5% of the first thermoplastic plastic parent particles, and silica is moulded for the first thermoplasticity Expect the 0.6% of master batch, zirconium aluminate is the 0.41% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is moulded for the first thermoplasticity Expect the 10% of master batch, glycol ester is the 5.5% of the first thermoplastic plastic parent particles, and modified thermoplastic master batch is the first thermoplastic The 1.6% of property plastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane Base sulfonic acid) and graphene.The mass ratio of cationic antistatic agent, anionic antistatic agents and graphene is 4:16：0.5.
The modified thermoplastic master batch is Si modification thermoplastic plastic parent particles.The Si modification thermoplastic plastic parent particles Including silicon additive and the 3rd thermoplastic plastic parent particles, the kind of the 3rd thermoplastic plastic parent particles and the first thermoplastic plastic parent particles Class is identical, and by percentage to the quality, the silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 3
Embodiment 13
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 80nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone, modified thermoplastic master batch；Moulded with the first thermoplasticity Expect the mass percent meter of master batch, antistatic additive is the 20.5% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic Property plastic master batch 0.8%, zirconium aluminate be the first thermoplastic plastic parent particles 0.72%, dodecyl sodium sulfate is the first thermoplastic Property plastic master batch 2%, glycol ester be the first thermoplastic plastic parent particles 1.5%, acetone is the first thermoplastic plastic parent particles 0.5%, modified thermoplastic master batch be the first thermoplastic plastic parent particles 20.75%.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e. Ethoxylated fat race alkylamine) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene For 4:16：0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 14
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 81nm), zirconium aluminate, glycol ester, stearate；In terms of the mass percent of the first thermoplastic plastic parent particles, antistatic additive For the 21.5% of the first thermoplastic plastic parent particles, silica is the 1.2% of the first thermoplastic plastic parent particles, zirconium aluminate first The 1.05% of thermoplastic plastic parent particles, glycol ester are the 5.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic The 0.5% of property plastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain) and graphene.Cationic antistatic The mass ratio of agent and graphene is 20：1.5.
The preparation method of modified thermoplastic master batch, comprises the following steps：The each component in formula is compounded by proportioning Together, mix, be granulated, injection molding, the temperature of injection molding is 185 DEG C.
Embodiment 15
A kind of antistatic material easy to clean, including the first thermoplastic plastic parent particles, antistatic additive, zirconium aluminate, dodecyl Sodium sulfonate, glycol ester, modified thermoplastic master batch；In terms of the mass percent of the first thermoplastic plastic parent particles, resist quiet Electric agent is the 20% of the first thermoplastic plastic parent particles, and zirconium aluminate is the 0.63% of the first thermoplastic plastic parent particles, dodecyl sulphur Sour sodium is the 1% of the first thermoplastic plastic parent particles, and glycol ester is the 0.8% of the first thermoplastic plastic parent particles, modified thermoplastic Plastic master batch is the 5.8% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from anionic antistatic agents (i.e. alkyl sulfonic acid), non-ionic antistatic agent (i.e. ethyoxyl Change aliphatic alkylamine).Anionic antistatic agents, the mass ratio of non-ionic antistatic agent are 3：1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 16
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone；With the first thermoplastic plastic parent particles Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles 0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles 0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles 0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e. Ethoxylated fat race alkylamine) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene For 5:1:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 17
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 5nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, modified thermoplastic master batch；With the first thermoplastic Property plastic master batch mass percent meter, antistatic additive be the first thermoplastic plastic parent particles 22.5%, silica first The 0.5% of thermoplastic plastic parent particles, zirconium aluminate are the 0.3% of the first thermoplastic plastic parent particles, dodecyl sodium sulfate first The 2% of thermoplastic plastic parent particles, glycol ester are the 5.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplasticity The 0.62% of plastic master batch, modified thermoplastic master batch are the 16.25% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 20:1：0.5：1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 18
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 10nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone, modified thermoplastic master batch；Moulded with the first thermoplasticity Expect the mass percent meter of master batch, antistatic additive is the 21% of the first thermoplastic plastic parent particles, and silica is the first thermoplasticity The 1% of plastic master batch, zirconium aluminate are the 0.82% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is moulded for the first thermoplasticity Expect the 2.5% of master batch, glycol ester is the 1% of the first thermoplastic plastic parent particles, and acetone is the first thermoplastic plastic parent particles 1%, modified thermoplastic master batch is the 30.25% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 12:6：2：1.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silicone oil.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 19
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 15nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, acetone, modified thermoplastic master batch；Moulded with the first thermoplasticity Expect the mass percent meter of master batch, antistatic additive is the 22.5% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic Property plastic master batch 0.6%, zirconium aluminate be the first thermoplastic plastic parent particles 0.80%, dodecyl sodium sulfate is the first thermoplastic Property plastic master batch 6%, glycol ester be the first thermoplastic plastic parent particles 3.5%, acetone is the first thermoplastic plastic parent particles 0.5%, modified thermoplastic master batch be the first thermoplastic plastic parent particles 0.41%.Modified thermoplastic master batch is silicon Modified thermoplastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 10:10：2：0.5.
The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic plastic parent particles, the 3rd thermoplasticity Plastic master batch is identical with the species of the first thermoplastic plastic parent particles, and by percentage to the quality, the silicon additive is the first thermoplasticity The 0.09% of plastic master batch.The silicon additive is the fluorosilicone compound thing that silane-based compound is modified.The method of modifying of silicon additive With reference to the method for modifying of silica.
The preparation method of antistatic material easy to clean is with reference to embodiment 3.
Embodiment 20
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 20nm), dodecyl sodium sulfate, glycol ester, stearate, modified thermoplastic master batch；With the first thermoplastic The mass percent meter of master batch, antistatic additive are the 22.5% of the first thermoplastic plastic parent particles, and silica is the first thermoplasticity The 1.0% of plastic master batch, dodecyl sodium sulfate are the 1% of the first thermoplastic plastic parent particles, and glycol ester is the first thermoplasticity The 4.2% of plastic master batch, stearate are the 1% of the first thermoplastic plastic parent particles, and modified thermoplastic master batch is the first heat The 32.75% of thermoplastic plastic master batch.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 10:10：2：0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is fluorocarbons.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd thermoplastic Master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, by percentage to the quality, described Silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is the siliceous of silane-based compound modification.Silicon additive Method of modifying of the method for modifying with reference to silica.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 21
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 25nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate, modified thermoplastic master batch；With the first thermoplastic Property plastic master batch mass percent meter, antistatic additive be the first thermoplastic plastic parent particles 20.5%, silica first The 2% of thermoplastic plastic parent particles, zirconium aluminate are the 1.05% of the first thermoplastic plastic parent particles, and dodecyl sodium sulfate is the first heat The 5% of thermoplastic plastic master batch, glycol ester are the 1.2% of the first thermoplastic plastic parent particles, and stearate is moulded for the first thermoplasticity Expect the 0.25% of master batch, modified thermoplastic master batch is the 28% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from anionic antistatic agents (i.e. alkyl sulfonic acid), non-ionic antistatic agent (i.e. ethyoxyl Change aliphatic alkylamine) and graphene.The mass ratio of anionic antistatic agents, non-ionic antistatic agent and graphene is 10: 10：0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles.The fluorine richness thermoplastic plastic parent particles Including fluorine auxiliary agent and the second thermoplastic plastic parent particles, the kind of second thermoplastic plastic parent particles and the first thermoplastic plastic parent particles Class is identical, and by percentage to the quality, the fluorine auxiliary agent is the 2% of the first thermoplastic plastic parent particles.The fluorine auxiliary agent is that fluorine silicon connects Cladodification compound.Preparation method is with reference to embodiment 2.
Embodiment 22
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 30nm), dodecyl sodium sulfate, glycol ester, acetone, stearate, modified thermoplastic master batch；With the first thermoplasticity The mass percent meter of plastic master batch, antistatic additive are the 20.5% of the first thermoplastic plastic parent particles, and silica is the first heat The 0.8% of thermoplastic plastic master batch, dodecyl sodium sulfate are the 7.5% of the first thermoplastic plastic parent particles, glycol ester first The 1% of thermoplastic plastic parent particles, acetone are the 0.75% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic The 0.25% of master batch, modified thermoplastic master batch are the 16.75% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), anionic antistatic agents (i.e. alkane Base sulfonic acid), non-ionic antistatic agent (i.e. ethoxylated fat race alkylamine) and graphene.Cationic antistatic agent, it is cloudy from The mass ratio of sub- antistatic additive, non-ionic antistatic agent and graphene is 7.5:2.5：10：0.5.
The modified thermoplastic master batch is fluorine richness thermoplastic plastic parent particles and Si modification thermoplastic plastic parent particles.Institute Stating fluorine richness thermoplastic plastic parent particles includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, second thermoplastic plastic parent particles with The species of first thermoplastic plastic parent particles is identical, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic plastic parent particles 2%.The fluorine auxiliary agent is that fluorine is grafted small organic molecule.The Si modification thermoplastic plastic parent particles include silicon additive and the 3rd heat Thermoplastic plastic master batch, the 3rd thermoplastic plastic parent particles are identical with the species of the first thermoplastic plastic parent particles, with quality percentage Than meter, the silicon additive is the 0.9% of the first thermoplastic plastic parent particles.The silicon additive is silane coupler.
The preparation method of antistatic material easy to clean is with reference to embodiment 1.
Embodiment 23
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone；With the first thermoplastic plastic parent particles Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles 0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles 0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles 0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e. Fatty acid ester) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene is 5:2:4.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 24
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone；With the first thermoplastic plastic parent particles Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles 0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles 0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles 0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. phosphate and naphthenic acid salt high-molecular polymer), nonionic Antistatic additive (i.e. macrogol ester) and modified CNT.Cationic antistatic agent, non-ionic antistatic agent and modification CNT mass ratio be 5:1:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 25
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone；With the first thermoplastic plastic parent particles Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles 0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles 0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles 0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e. Glycollic amide) and graphene.The mass ratio of cationic antistatic agent, non-ionic antistatic agent and graphene is 5:2:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Embodiment 26
A kind of antistatic material easy to clean, including (particle diameter is for the first thermoplastic plastic parent particles, antistatic additive, silica 90nm), zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone；With the first thermoplastic plastic parent particles Mass percent meter, antistatic additive are the 18% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles 0.7%, zirconium aluminate be the first thermoplastic plastic parent particles 0.56%, dodecyl sodium sulfate is the first thermoplastic plastic parent particles 0.8%, glycol ester is the 1.5% of the first thermoplastic plastic parent particles, and stearate is the first thermoplastic plastic parent particles 0.5%, acetone is the 0.5% of the first thermoplastic plastic parent particles.
Silica-treated method is the same as embodiment 1.
First thermoplastic plastic parent particles are thermoplastic, and first thermoplastic plastic parent particles are acrylonitrile-fourth Diene-styrene copolymerized compound.
The antistatic additive is selected from cationic antistatic agent (i.e. the quaternary ammonium alkyl of long-chain), non-ionic antistatic agent (i.e. Ethoxylated fat race alkylamine) and electrically conductive graphite.The quality of cationic antistatic agent, non-ionic antistatic agent and graphene Than for 5:3:3.
The preparation method of antistatic material easy to clean is with reference to embodiment 14.
Comparative example：The first thermoplastic plastic parent particles are comprised only, i.e., pure ABS material.
Each embodiment and comparative example are subjected to effect detection respectively.
1st, the detection method of surface resistivity is：
Surface resistivity is parallel in electric potential gradient and surface unit width by the sense of current on material surface The ratio between electric current, use ohms.
Surface resistivity can directly be detected using sheet resistance tester, and operating method may refer to specification. The surface resistivity tester of all Data Detections is QUICK 499D.
In use, measuring instrument is placed in into testee surface, feeler switch is pressed, then shows the sheet resistance of testee Coefficient surface resistivity uses ASTM standard D-257 parallel pole method for sensing, uses the integrated amplifications of high-precision OP-AMP Device carries out automatic measurement.
Surface resistivity：The parameter is used for the certain thin-film material of thickness, and it is defined as the straight of unit length on surface Stream pressure drop flows through the ratio between electric current with unit width.
The numerical value of surface resistivity is the smaller the better.The smaller explanation antistatic effect of numerical value of surface resistivity is strong, does not allow more Easily it is stained with ash.
Experimental result is shown in Table 1.
2nd, the detection method of surface energy is：
Surface energy is the measurement destroyed when creating material surface to intermolecular chemical bond.First first with contact angle detection instrument , can be using YGG equations, harmonic equation or geometric equation come computational chart after device detects the contact angle on the surface of object to be measured Face energy.The numerical value of surface energy is the smaller the better, and interface does not adhere to organic matter and water, and dust-proof effect will be better.Surface energy value Smaller explanation is less susceptible to be stained with ash.Experimental result is shown in Table 1.
3rd, driving grey detection method is：
Prepared by each comparative example and each embodiment example into fan respectively to be put into inside the ducting system of a connection, it is periodically past The standard dust of the addition true dust of simulated atmosphere inside ducting system, every 2 hours, to ducting system the inside addition standard Dust 20g.Fan stops a period of time after operation a period of time, is considered as a cycle.Each cycle, soot blowing 10 minutes are quiet Put 10 minutes, soot blowing speed is 1-2m/s.Cycle is continuously 2 days.After experiment terminates, the ash quantity of being stained with of each testing sample is counted Summation.Repeatedly and carry out statistical analysis.And calculate and drive grey effect, drive grey effect and refer to being modified flabellum in material prescription Relatively primitive flabellum (i.e. comparative example) is stained with ash quantity down ratio above in the case of change.Grey effect numerical value is driven to be the bigger the better.Experiment It the results are shown in Table 1.
The testing result of table 1
" Ω/ " refers to square resistance in table 1.
It is can be seen that by the data of table 1 by adding antistatic additive, silica, zirconium aluminate, dodecyl sodium sulfonate Sodium, glycol ester, stearate and acetone can reduce surface resistivity and surface energy, improve the effect for driving ash.
The addition of fluorine auxiliary agent is have adjusted on the basis of embodiment 2, remaining is same as Example 2.Detect data As a result it is as shown in table 2.
The testing result of material after the addition adjustment of the fluorine auxiliary agent of table 2
Data in table 1 can be seen that addition (i.e. the fluorine auxiliary agent and the first thermoplastic plastic parent particles of fluorine auxiliary agent Mass percent) effect of imperial ash can be improved further in the range of 10%-30% and 40%-60%.
Inventor further have adjusted the adding proportion of modified thermoplastic master batch on the basis of embodiment 1, with The mass percent of first thermoplastic plastic parent particles is reference, modified thermoplastic master batch is respectively 0.1%, 5%, 6.49%th, 10%, 18%, 19%, 45%, 46%, 60%, 76.9%.Result of study shows, homogeneous in the proportioning of other components With under conditions of, can have preferably imperial ash effect between 0.1-76.9% in the addition of modified thermoplastic master batch Fruit.
Inventor further have adjusted the particle diameter of silica, the particle diameter point of silica on the basis of embodiment 1 Not Wei 2nm, 20nm, 30nm, 31nm, 35nm, 39nm, 40nm, 45nm, 40nm, 50nm, 51nm, 60nm, 80nm, 90nm and 100nm, result of study show, in other conditions under the same conditions, in the range of 1-30nm or 31-39nm, silica compared with Few addition can plays the effect for driving ash, in the range of 40-50nm, is advantageous to silica surface processing and uniformly divides Dissipate, in the range of 51-80nm, be easy to industrialized production, in the range of 81-100nm, it is easier to be scattered.
Fig. 4 and Fig. 5 is the results of comparison for being stained with grey situation of comparative example and embodiment.Fig. 4 and Fig. 5 is in the imperial ash of same detection System in the result that is detected.Amount of dust and concentration in the system is very big, periodically adds dust inside, when testing one section Between material surface be stained with grey picture (test is the effect of dynamic bind static state dust stratification), specific operating procedure is the same as above-mentioned imperial ash Detection method.According to Fig. 4 as can be seen that comparative example to be stained with ash more, and embodiment 8 is stained with that ash is fewer, and embodiment 8 is when shorter Interior or even imperial ash.According to Fig. 5 as can be seen that comparative example be stained with ash it is more, and embodiment 1 be stained with ash it is fewer, embodiment 1 is shorter In time or even non-sticky ash.
Inventor has attempted with acrylonitritrile-styrene resin, PA plastics, polyethylene, polypropylene, polyvinyl chloride, poly- again One or more of compoundings in styrene, acrylonitrile-butadiene-styrene copolymerized compound and makrolon are as the first heat Thermoplastic plastic master batch, it can also obtain conclusion consistent with the above.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (24)

1. a kind of antistatic material easy to clean, it is characterised in that including the first thermoplastic plastic parent particles, antistatic additive, titanium dioxide Silicon, zirconium aluminate, dodecyl sodium sulfate, glycol ester, stearate and acetone；With the quality of the first thermoplastic plastic parent particles Percentages, antistatic additive are the 8%-39% of the first thermoplastic plastic parent particles, and silica is the first thermoplastic plastic parent particles Less than 8%, zirconium aluminate be the first thermoplastic plastic parent particles less than 6.1%, dodecyl sodium sulfate be the first thermoplasticity modeling Expect less than the 18% of master batch, glycol ester is less than the 11% of the first thermoplastic plastic parent particles, and stearate is the first thermoplasticity Less than the 3.9% of plastic master batch, acetone are less than the 7.2% of the first thermoplastic plastic parent particles.
A kind of 2. antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, titanium dioxide Silicon be the first thermoplastic plastic parent particles 0.5%-8%, zirconium aluminate be the first thermoplastic plastic parent particles 0.5%-6.1%, ten Dialkyl sulfonates are the 1.2%-18% of the first thermoplastic plastic parent particles.
A kind of 3. antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, ethylene glycol Ester is the 0.2%-11% of the first thermoplastic plastic parent particles.
A kind of 4. antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, stearic acid Ester is the 0.1%-3.9% of the first thermoplastic plastic parent particles.
5. a kind of antistatic material easy to clean according to claim 1, it is characterised in that by percentage to the quality, acetone is The 0.5%-7.2% of first thermoplastic plastic parent particles.
A kind of 6. antistatic material easy to clean according to claim 1, it is characterised in that first thermoplastic plastic parent particles For thermoplastic, first thermoplastic plastic parent particles are selected from acrylonitritrile-styrene resin, PA plastics, polyethylene, poly- third One or more in alkene, polyvinyl chloride, polystyrene, acrylonitrile-butadiene-styrene copolymerized compound and makrolon.
7. a kind of antistatic material easy to clean according to claim 1, it is characterised in that the particle diameter of the silica is： 1-100nm。
8. a kind of antistatic material easy to clean according to claim 7, it is characterised in that the particle diameter of the silica is 1- 30nm；Or the particle diameter of the silica is 31-39nm；Or the particle diameter of the silica is 40-50nm；Or the titanium dioxide The particle diameter of silicon is 51-80nm；Or the particle diameter of the silica is 81-100nm.
9. according to the antistatic material easy to clean of the described one kind of any one of claim 1-8, it is characterised in that the silica is Nano silicon, nano silicon are surface treated nano silicon；It the treating method comprises following step Suddenly：Silica is mixed with ethanol solution, instills compounding coupling agent, compounds the quality percentage of coupling agent and silica dioxide granule Than being formed, being stirred by ultrasonic by silane coupler and titanate coupling agent compounding, filtered, dried for 0.5-2%, the compounding coupling agent It is dry, grinding.
A kind of 10. antistatic material easy to clean according to claim 1, it is characterised in that the antistatic additive be selected from sun from Sub- antistatic additive, anionic antistatic agents, non-ionic antistatic agent, the CNT of modification, graphene, polyethers and polyamide Copolymer, the one or more in metal powder and electrically conductive graphite.
A kind of 11. antistatic material easy to clean according to claim 10, it is characterised in that the cationic antistatic agent choosing It is one or more of from the quaternary ammonium alkyl of long-chain, phosphate and naphthenic acid salt high-molecular polymer.
A kind of 12. antistatic material easy to clean according to claim 10, it is characterised in that the anionic antistatic agents choosing One or more from the alkali metal salt of alkyl sulfonic acid, alkyl sodium sulfate, carboxylate, phosphate and aminodithioformic acid.
A kind of 13. antistatic material easy to clean according to claim 10, it is characterised in that the non-ionic antistatic agent One or more in ethoxylated fat race alkylamine, macrogol ester or ether, fatty acid ester and glycollic amide.
14. a kind of antistatic material easy to clean according to claim 1, it is characterised in that also including modified thermoplastic Master batch, by percentage to the quality, the modified thermoplastic master batch are the 0.1%-76.9% of the first thermoplastic plastic parent particles.
15. a kind of antistatic material easy to clean according to claim 14, it is characterised in that also including modified thermoplastic Master batch, by percentage to the quality, the modified thermoplastic master batch are the 0.1%-6.49% of the first thermoplastic plastic parent particles Or the 6.50%-76.9% that the modified thermoplastic master batch is the first thermoplastic plastic parent particles.
16. a kind of antistatic material easy to clean according to claim 15, it is characterised in that also including modified thermoplastic Master batch, by percentage to the quality, the modified thermoplastic master batch are the 6.5%-18% of the first thermoplastic plastic parent particles；Or The modified thermoplastic master batch is the 19%-45% of the first thermoplastic plastic parent particles；Or the modified thermoplastic is female Grain is the 46%-76.9% of the first thermoplastic plastic parent particles.
17. a kind of antistatic material easy to clean according to claim 14, it is characterised in that the modified thermoplastic is female Grain is fluorine richness thermoplastic plastic parent particles and/or Si modification thermoplastic plastic parent particles.
A kind of 18. antistatic material easy to clean according to claim 17, it is characterised in that the fluorine richness thermoplastic Master batch includes fluorine auxiliary agent and the second thermoplastic plastic parent particles, and by percentage to the quality, the fluorine auxiliary agent is the first thermoplastic The mass percent of master batch is more than 0 and less than or equal to 70%.
19. a kind of antistatic material easy to clean according to claim 18, it is characterised in that the fluorine auxiliary agent is carbonized selected from fluorine In small organic molecule and fluorine silicon graft compound that compound, fluorinated ethylene propylene copolymer, fluoroalkyle compound, fluorine are grafted It is one or more of.
A kind of 20. antistatic material easy to clean according to claim 17, it is characterised in that the Si modification thermoplastic Master batch includes silicon additive and the 3rd thermoplastic plastic parent particles, by percentage to the quality, the silicon additive accounts for the first thermoplastic The mass percent of master batch is more than 0 and less than or equal to 17.3%.
A kind of 21. antistatic material easy to clean according to claim 20, it is characterised in that the silicon additive be selected from silicone oil, Silicone, SOLID ORGANIC silicon, liquid silicone, silicate, nano silicon, silane coupler, silane-based compound are modified One or more in siliceous or fluorosilicone compound.
22. a kind of preparation method of antistatic material easy to clean, it is characterised in that comprise the following steps：According to claim 1- Each component compounding to together, is mixed, is granulated by the proportioning described in 21 any one.
23. a kind of antistatic product easy to clean, it is characterised in that the material of the product is included described in claim any one of 1-21 Antistatic material easy to clean.
A kind of 24. antistatic product easy to clean according to claim 23, it is characterised in that the product be fan, impeller, Aerofoil fan, steam cleaner dust stratification bucket, electric appliance casing, plastic sheeting or the electric plastics device of air-conditioning.
CN201610875519.3A 2016-09-30 2016-09-30 A kind of antistatic material easy to clean and preparation method thereof Pending CN107880473A (en)

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CN109134904A (en) * 2018-08-20 2019-01-04 蚌埠市维光塑胶制品有限公司 A method of anti-droplet, which is prepared, with nano silica-cage-type silsesquioxane prevents adhesion plastic film
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CN109651704A (en) * 2018-12-11 2019-04-19 金旸（厦门）新材料科技有限公司 A kind of dedicated automatically cleaning master batch of intelligent closestool and flame-retarding high-lustre PP composite material and preparation method
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CN115536931A (en) * 2022-01-11 2022-12-30 诺曼化学(盘锦)有限公司 Color master batch with antistatic function and preparation method thereof
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CN115322485A (en) * 2022-09-15 2022-11-11 芜湖聚发新材料有限公司 Halogen-free flame-retardant polypropylene material and preparation method thereof

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