CN106280227A - A kind of antistatic high tenacity ABS composite material and preparation method thereof - Google Patents
A kind of antistatic high tenacity ABS composite material and preparation method thereof Download PDFInfo
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- CN106280227A CN106280227A CN201610921485.7A CN201610921485A CN106280227A CN 106280227 A CN106280227 A CN 106280227A CN 201610921485 A CN201610921485 A CN 201610921485A CN 106280227 A CN106280227 A CN 106280227A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/06—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene-diene terpolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
Abstract
The present invention relates to a kind of antistatic high tenacity ABS composite material and preparation method thereof, be made up of the component of following weight portion: ABS is 60 parts 80 parts；Nano titanium nitride is 10 parts 16 parts；EPDM g GMA is 0.2 part 0.6 part；Antioxidant is 0.1 part 0.5 part；Lubricant is 0.4 part 0.8 part.The Nano titanium nitride that the technical program provides, after silane coupler processes, can be better dispersed in ABS, this physical property being conducive to keeping ABS composite material.EPDM is nonpolar and ABS is polarity, and both are incompatible.Creative glytidyl methacrylate is grafted on EPMD of the technical program, forms EPDM g GMA, so makes nonpolar EPDM obtain polarity, solves the compatible problem of EPDM and ABS.
Description
Technical field
The invention belongs to technical field of polymer materials, particularly relate to a kind of antistatic high tenacity ABS composite material and
Preparation method.
Background technology
Acrylonitrile-butadiene-phenylethylene (ABS) because it is cheap, excellent performance, source extensively, easily process, become modern
One of most widely used plastics.Along with the raising of living standards of the people, to the requirement (antistatic behaviour, toughness) of material also by
Step improves.Ethylene propylene diene rubber (EPDM) is conventional toughener, but it is nonpolar, incompatible with the ABS of polarity.
Summary of the invention
It is an object of the invention to provide a kind of antistatic high tenacity ABS composite material and preparation method thereof, with solve ABS with
The problem that the EPDM compatibility is the best.
The present invention is achieved by the following technical solutions:
A kind of antistatic high tenacity ABS composite material, is made up of the component of following weight portion:
The preparation method of described EPDM-g-GMA, comprises the following steps:
(1) ethylene propylene diene rubber, glytidyl methacrylate and cumyl peroxide are reacted 5-10 at banbury
Minute, graft EPDM-g-GMA is taken out, is chopped into graininess；
(2) being completely dissolved by the graft EPDM-g-GMA dimethylbenzene in step (1), reflux at 80-120 DEG C 10-
15h, adds acetone in solution and purifies；
(3) step (2) solution is filtered, at 80-100 DEG C, be vacuum dried 2-4h, the EPDM-g-GMA material after being purified
Material.
The mass ratio of ethylene propylene diene rubber, glytidyl methacrylate and the cumyl peroxide of described step poly-(1)
For 40-60:30-50:2-8.
Described banbury includes six humidity provinces sequentially arranged, district's temperature 120～150 DEG C, two district's temperature 170～
200 DEG C, three district's temperature 170～200 DEG C, four district's temperature 170～200 DEG C, five district's temperature 170～200 DEG C, six district's temperature 170～
200 DEG C, head temperature 170～200 DEG C；Screw speed 180～260r/min.
Described Nano titanium nitride be particle diameter be the Nano titanium nitride of 3-7nm.
Described Nano titanium nitride is through coupling agent treatment.
Described antioxidant is three (2,4-di-t-butyl) phenyl-phosphite, four [β-(3,5-di-tert-butyl-hydroxy phenyls)
Propanoic acid] one or many in pentaerythritol ester or 1,3,5-trimethyl-2,4,6-(3,5-di-t-butyl-4-hydroxyphenylmethyl) benzene
Kind.
Described lubricant is one or both combinations in calcium stearate or stearic acid sodium.
The preparation method of the antistatic high tenacity ABS composite material of a kind of any of the above-described, comprises the steps:
(1) ABS that weight portion is 60 parts-80 parts, the Nano titanium nitride of 10 parts-16 parts, the antioxygen of 0.1 part-0.5 part are weighed
Agent and the mix lubricant of 0.4 part-0.8 part also stir, and obtain compound；
(2) the compound extruding pelletization that will obtain in step (1), i.e. obtains ABS composite material.
Described Nano titanium nitride in step (1) is the Nano titanium nitride through coupling agent treatment, and processing method is, will receive
Ultrasonic disperse in the ethanol solution of rice titanium nitride addition coupling agent, is dried after filtration, obtains the Nano titanium nitride processed；
Described Nano titanium nitride is 40-60:2-6 with the mass ratio of described coupling agent；
Described coupling agent is the one in silane coupler KH560 or KH570.
Preferably, described step (2) particularly as follows:
The compound obtained in step (1) is put into extruding pelletization in the hopper of double screw extruder, wherein, described double
Screw extruder includes six humidity provinces sequentially arranged, district's temperature 190～210 DEG C, two district's temperature 230～270 DEG C, 3rd district
Temperature 230～270 DEG C, four district's temperature 230～270 DEG C, five district's temperature 230～270 DEG C, six district's temperature 230～270 DEG C, head
Temperature 230～270 DEG C；Screw speed 200～260r/min.
The invention has the beneficial effects as follows:
1, the Nano titanium nitride that the technical program provides is after silane coupler processes, and can be better dispersed in ABS, this
Be conducive to keeping the physical property of ABS composite material.
2, the addition of Nano titanium nitride reduces the surface resistivity of material, improves the antistatic property of material, and this is right
The extension of the application of ABS material plays a significant role.
3, EPDM is nonpolar and ABS is polarity, and both are incompatible.The technical program creative metering system
Acid polyglycidyl be grafted on EPMD, formed EPDM-g-GMA, so make nonpolar EPDM obtain polarity, solve EPDM and
The compatible problem of ABS.
Detailed description of the invention
Describing technical scheme by the following examples in detail, below example is only exemplary, only
Can be used for explaining and illustrate technical scheme, and be not to be construed as the restriction to technical solution of the present invention.
The application provides a kind of antistatic high tenacity ABS composite material and preparation method thereof, by the component of following weight portion
Make:
Described Nano titanium nitride be particle diameter be the Nano titanium nitride of 3-7nm.
Described Nano titanium nitride is through coupling agent treatment.
The preparation method of described EPDM-g-GMA, comprises the following steps:
(1) by ethylene propylene diene rubber (EPDM), glytidyl methacrylate (GMA) and cumyl peroxide (DCP)
React 5-10 minute at banbury, graft EPDM-g-GMA is taken out, is chopped into graininess.
(2) being completely dissolved by the graft EPDM-g-GMA dimethylbenzene in step (1), reflux at 80-120 DEG C 10-
15h, adds acetone in solution and purifies.
(3) step (2) solution is filtered, at 80-100 DEG C, be vacuum dried 2-4h, the EPDM-g-GMA material after being purified
Material.
Preferably, the mass ratio of EPDM, GMA, DCP in step (1) is (40-60): (30-50): (2-8), described close
Refining machine includes six humidity provinces sequentially arranged, district's temperature 120～150 DEG C, two district's temperature 170～200 DEG C, three district's temperature
170～200 DEG C, four district's temperature 170～200 DEG C, five district's temperature 170～200 DEG C, six district's temperature 170～200 DEG C, head temperature
170～200 DEG C；Screw speed 180～260r/min.
Described antioxidant is three (2,4-di-t-butyl) phenyl-phosphite (Irganox168), four [β-(tertiary fourths of 3,5-bis-
Base-4-hydroxy phenyl) propanoic acid] pentaerythritol ester (Irganox1010) and 1,3,5-trimethyl-2,4,6-(3,5-di-t-butyl-
4-hydroxyphenylmethyl) one or more in benzene (Irganox1330).
Described lubricant is one or both combinations in calcium stearate or stearic acid sodium.
The preparation method of the antistatic high tenacity ABS composite material of a kind of any of the above-described, comprises the steps:
(1) ABS that weight portion is 60 parts-80 parts, the Nano titanium nitride of 10 parts-16 parts, the antioxygen of 0.1 part-0.5 part are weighed
Agent and the mix lubricant of 0.4 part-0.8 part also stir, and obtain compound；
(2) the compound extruding pelletization that will obtain in step (1), i.e. obtains ABS composite material.
Each raw material in step (1) first can be dried 5h before combination at 100 DEG C.
Preferably, the Nano titanium nitride in described step (1), through coupling agent treatment, specifically comprises the following steps that
Nano titanium nitride is added ultrasonic disperse in the ethanol solution of coupling agent, is dried after filtration.
It is highly preferred that described coupling agent is the one in silane coupler KH560 or KH570.
It is highly preferred that the mass ratio of described Nano titanium nitride and coupling agent is (40-60): 2-6).
Preferably, described step (2) is particularly as follows: put into double screw extruder by the compound obtained in step (1)
Extruding pelletization in hopper, i.e. obtains ABS composite material, and wherein, described double screw extruder includes six temperature sequentially arranged
District, district's temperature 190～210 DEG C, two district's temperature 230～270 DEG C, three district's temperature 230～270 DEG C, four district's temperature 230～270
DEG C, five district's temperature 230～270 DEG C, six district's temperature 230～270 DEG C, head temperature 230～270 DEG C；Screw speed 200～
260r/min。
Raw material used in various embodiments of the present invention is as follows:
PS (model PA-747R), Taiwan is the most beautiful；Nano titanium nitride, Shanghai surpasses prestige nano material；Antioxidant (model
Irganox1010, Irganox168, Irganox1330), Switzerland's Ciba；Calcium stearate, expects chemical industry in Hubei；Stearic acid
Sodium, Hubei emerging milky way chemical industry；EDPM (model 3722P), LG-DOW；GMA, Ningbo Thailand value work；DCP, Hefei An Hai chemical industry；
Silane coupler (KH560, KH570), the sincere chemical industry of Nanjing Olympic.
Test instrunment used by the present invention is as follows:
ZSK30 type double screw extruder, W&P company of Germany；Banbury, Dalian China Korea Spro's rubber and plastic；JL-1000 type pull test
Machine, Guangzhou Guang Cai experimental apparatus company produces；HTL900-T-5B type injection (mo(u)lding) machine, Hai Tai plastics machinery company limited is raw
Produce；XCJ-500 type shock-testing machine, Chengde testing machine factory produces；QT-1196 type tester for elongation, Dongguan City height Thailand detector
Device company limited；QD-GJS-B12K type homogenizer, Beijing perseverance Order instrument and meter company limited.
Embodiment 1
(1) weigh weight portion be 60 parts of ABS, 10 parts of Nano titanium nitrides through coupling agent treatment, 0.2 part of EPDM-g-
GMA, 0.1 part of Irganox1330 and 0.4 part of stearic acid sodium are mixed and stirred for uniformly, obtaining compound；
(2) compound obtained in step (1) is put into extruding pelletization in the hopper of double screw extruder, i.e. obtains
ABS composite material P1, wherein, the temperature of the first humidity province of double screw extruder is 190 DEG C, and the temperature of the second humidity province is
230 DEG C, the temperature of the 3rd humidity province is 230 DEG C, and the temperature of the 4th humidity province is 230 DEG C, and the temperature of the 5th humidity province is 230
DEG C, the temperature of the 6th humidity province is 230 DEG C, and the head temperature of described double screw extruder is 230 DEG C, and screw speed is 200r/
min。
Embodiment 2
(1) weigh weight portion be 80 parts of ABS, 16 parts of Nano titanium nitrides through coupling agent treatment, 0.6 part of EPDM-g-
GMA, 0.3 part of Irganox1010,0.2 part of Irganox168,0.4 part of stearic acid sodium and 0.4 part of stearic acid potassium are mixed and stirred for all
Even, obtain compound；
(2) compound obtained in step (1) is put into extruding pelletization in the hopper of double screw extruder, i.e. obtains
ABS composite material P2, wherein, the temperature of the first humidity province of double screw extruder is 210 DEG C, and the temperature of the second humidity province is
270 DEG C, the temperature of the 3rd humidity province is 270 DEG C, and the temperature of the 4th humidity province is 270 DEG C, and the temperature of the 5th humidity province is 270
DEG C, the temperature of the 6th humidity province is 270 DEG C, and the head temperature of described double screw extruder is 270 DEG C, and screw speed is 260r/
min。
Embodiment 3
(1) weigh weight portion be 70 parts of ABS, 13 parts of Nano titanium nitrides through coupling agent treatment, 0.4 part of EPDM-g-
GMA, 0.2 part of Irganox1330,0.1 part of Irganox168,0.3 part of calcium stearate and 0.3 part of stearic acid sodium are mixed and stirred for all
Even, obtain compound；
(2) compound obtained in step (1) is put into extruding pelletization in the hopper of double screw extruder, i.e. obtains
ABS composite material P3, wherein, the temperature of the first humidity province of double screw extruder is 200 DEG C, and the temperature of the second humidity province is
250 DEG C, the temperature of the 3rd humidity province is 250 DEG C, and the temperature of the 4th humidity province is 250 DEG C, and the temperature of the 5th humidity province is 250
DEG C, the temperature of the 6th humidity province is 250 DEG C, and the head temperature of described double screw extruder is 250 DEG C, and screw speed is 230r/
min。
Embodiment 4
(1) weigh weight portion be 75 parts of ABS, 12 parts of Nano titanium nitrides through coupling agent treatment, 0.3 part of EPDM-g-
GMA, 0.1 part of Irganox1330,0.1 part of Irganox1010,0.5 part of stearic acid sodium are mixed and stirred for uniformly, obtaining compound；
(2) compound obtained in step (1) is put into extruding pelletization in the hopper of double screw extruder, i.e. obtains
ABS composite material P4, wherein, the temperature of the first humidity province of double screw extruder is 205 DEG C, and the temperature of the second humidity province is
240 DEG C, the temperature of the 3rd humidity province is 240 DEG C, and the temperature of the 4th humidity province is 240 DEG C, and the temperature of the 5th humidity province is 240
DEG C, the temperature of the 6th humidity province is 240 DEG C, and the head temperature of described double screw extruder is 240 DEG C, and screw speed is 240r/
min。
Embodiment 5
(1) weigh weight portion be 75 parts of ABS, 11 parts of Nano titanium nitrides through coupling agent treatment, 0.3 part of EPDM-g-
GMA, 0.2 part of Irganox1010,0.1 calcium stearate and 0.5 part of stearic acid sodium are mixed and stirred for uniformly, obtaining compound；
(2) compound obtained in step (1) is put into extruding pelletization in the hopper of double screw extruder, i.e. obtains
ABS composite material P5, wherein, the temperature of the first humidity province of double screw extruder is 200 DEG C, and the temperature of the second humidity province is
245 DEG C, the temperature of the 3rd humidity province is 245 DEG C, and the temperature of the 4th humidity province is 245 DEG C, and the temperature of the 5th humidity province is 245
DEG C, the temperature of the 6th humidity province is 245 DEG C, and the head temperature of described double screw extruder is 245 DEG C, and screw speed is 260r/
min。
Comparative example 1
(1) weigh weight portion be 75 parts of ABS, 0.2 part of Irganox1010,0.1 calcium stearate and 0.5 part of stearic acid sodium mixes
Merging stirs, and obtains compound；
(2) compound obtained in step (1) is put into extruding pelletization in the hopper of double screw extruder, i.e. obtains
ABS composite material D1, wherein, the temperature of the first humidity province of double screw extruder is 200 DEG C, and the temperature of the second humidity province is
240 DEG C, the temperature of the 3rd humidity province is 240 DEG C, and the temperature of the 4th humidity province is 240 DEG C, and the temperature of the 5th humidity province is 240
DEG C, the temperature of the 6th humidity province is 240 DEG C DEG C, and the head temperature of described double screw extruder is 240 DEG C, and screw speed is
250r/min。
ABS composite material injection machine prepared by above-described embodiment 1-5 and comparative example 1 is made batten test, tests number
According to such as following table:
Be can be seen that by the contrast of upper table, in the ABS composite material that the present invention prepares relatively comparative example, ABS compares, and not only resists quiet
Electrical property is greatly improved, and toughness have also been obtained raising, and this is greatly expanded the application of ABS composite material,
There is the most real meaning.
Below it is only the description of the preferred embodiment of the present invention, it is noted that due to the finiteness of literal expression, and
Objectively there is unlimited concrete structure, for those skilled in the art, without departing from the principle of the invention
On the premise of, it is also possible to making some improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (10)
1. an antistatic high tenacity ABS composite material, it is characterised in that be made up of the component of following weight portion:
The preparation method of described EPDM-g-GMA, comprises the following steps:
(1) ethylene propylene diene rubber, glytidyl methacrylate and cumyl peroxide are reacted 5-10 minute at banbury,
Graft EPDM-g-GMA is taken out, is chopped into graininess；
(2) being completely dissolved by the graft EPDM-g-GMA dimethylbenzene in step (1), reflux at 80-120 DEG C 10-15h, to
Solution adds acetone purify；
(3) step (2) solution is filtered, at 80-100 DEG C, be vacuum dried 2-4h, the EPDM-g-GMA material after being purified.
Antistatic high tenacity ABS composite material the most according to claim 1, it is characterised in that walk the EPDM of poly-(1)
The mass ratio of rubber, glytidyl methacrylate and cumyl peroxide is 40-60:30-50:2-8.
Antistatic high tenacity ABS composite material the most according to claim 1, it is characterised in that described banbury includes suitable
Six humidity provinces of secondary arrangement, district's temperature 120～150 DEG C, two district's temperature 170～200 DEG C, three district's temperature 170～200 DEG C,
Four district's temperature 170～200 DEG C, five district's temperature 170～200 DEG C, six district's temperature 170～200 DEG C, head temperature 170～200 DEG C；
Screw speed 180～260r/min.
Antistatic high tenacity ABS composite material the most according to claim 1, it is characterised in that described Nano titanium nitride is
Particle diameter is the Nano titanium nitride of 3-7nm.
Antistatic high tenacity ABS composite material the most according to claim 1, it is characterised in that described Nano titanium nitride warp
Cross coupling agent treatment.
Antistatic high tenacity ABS composite material the most according to claim 1, it is characterised in that described antioxidant be three (2,
4-di-t-butyl) phenyl-phosphite, four [β-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester or 1,3,5-tri-
One or more in methyl-2,4,6-(3,5-di-t-butyl-4-hydroxyphenylmethyl) benzene.
Antistatic high tenacity ABS composite material the most according to claim 1, it is characterised in that described lubricant is stearic
One or both combinations in acid calcium or stearic acid sodium.
8. a preparation method for the antistatic high tenacity ABS composite material any one of the claims 1 to 7, its feature
It is, comprises the steps:
(1) weigh the ABS that weight portion is 60 parts-80 parts, the Nano titanium nitride of 10 parts-16 parts, the antioxidant of 0.1 part-0.5 part and
The mix lubricant of 0.4 part-0.8 part also stirs, and obtains compound；
(2) the compound extruding pelletization that will obtain in step (1), i.e. obtains ABS composite material.
The preparation method of antistatic high tenacity ABS composite material the most according to claim 8, it is characterised in that step (1)
In described Nano titanium nitride be the Nano titanium nitride through coupling agent treatment, processing method is, adds even by Nano titanium nitride
Ultrasonic disperse in the ethanol solution of connection agent, is dried after filtration, obtains the Nano titanium nitride processed；
Described Nano titanium nitride is 40-60:2-6 with the mass ratio of described coupling agent；
Described coupling agent is the one in silane coupler KH560 or KH570.
The preparation method of antistatic high tenacity ABS composite material the most according to claim 8, it is characterised in that described step
Suddenly (2) particularly as follows: put into extruding pelletization in the hopper of double screw extruder, wherein, institute by the compound obtained in step (1)
State six humidity provinces that double screw extruder includes sequentially arranging, district's temperature 190～210 DEG C, two district's temperature 230～270 DEG C,
Three district's temperature 230～270 DEG C, four district's temperature 230～270 DEG C, five district's temperature 230～270 DEG C, six district's temperature 230～270 DEG C,
Head temperature 230～270 DEG C；Screw speed 200～260r/min.
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| CN109943009A (en) * | 2018-11-19 | 2019-06-28 | 任静儿 | A kind of high tenacity ABS composite material |
| CN110511484A (en) * | 2019-08-26 | 2019-11-29 | 广东圆融新材料有限公司 | Polypropylene material and preparation method thereof |
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