JP2003529626A - High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same - Google Patents

High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same

Info

Publication number
JP2003529626A
JP2003529626A JP2001514039A JP2001514039A JP2003529626A JP 2003529626 A JP2003529626 A JP 2003529626A JP 2001514039 A JP2001514039 A JP 2001514039A JP 2001514039 A JP2001514039 A JP 2001514039A JP 2003529626 A JP2003529626 A JP 2003529626A
Authority
JP
Japan
Prior art keywords
impact resistance
composition
abs
butadiene
styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001514039A
Other languages
Japanese (ja)
Other versions
JP2003529626A5 (en
Inventor
桂生 楊
永東 陳
青 徐
Original Assignee
上海▲傑▼事▲傑▼新材料股▲分▼有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 上海▲傑▼事▲傑▼新材料股▲分▼有限公司 filed Critical 上海▲傑▼事▲傑▼新材料股▲分▼有限公司
Publication of JP2003529626A publication Critical patent/JP2003529626A/en
Publication of JP2003529626A5 publication Critical patent/JP2003529626A5/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/919—Thermal treatment of the stream of extruded material, e.g. cooling using a bath, e.g. extruding into an open bath to coagulate or cool the material

Abstract

(57)【要約】 本発明は、高流動性耐衝撃性導電性アクリロニトリル・ブタジエン・スチレン三次元共重合体組成物およびその製造方法に関する。この組成物は、以下の組成（質量％）：ＡＢＳ６０〜６５、カーボンブラック１５〜２５、耐衝撃性改良剤１５〜２０、抗酸化剤０．１〜０．２、紫外線吸収剤０．２〜０．３を有する。上記組成の全成分を高速混合機で混合し、次いで２軸押出機により押出し、押出物を水冷し、粉砕し、乾燥した後、製品を得る。従来技術と比較して、本発明の製品は、高流動性、高耐衝撃性の点で有利であり、導電性である。   (57) [Summary] The present invention relates to a high-fluidity impact-resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and a method for producing the same. This composition has the following composition (% by mass): ABS 60 to 65, carbon black 15 to 25, impact resistance improver 15 to 20, antioxidant 0.1 to 0.2, ultraviolet absorber 0.2 to 0.3. All the components of the above composition are mixed in a high-speed mixer and then extruded by a twin-screw extruder, and the extrudate is water-cooled, pulverized and dried to obtain a product. Compared with the prior art, the product of the present invention is advantageous in terms of high fluidity and high impact resistance, and is conductive.

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【技術分野】【Technical field】

本発明は、プラスチック材料とその製造方法に関し、特に高流動性、耐衝撃性
および導電性を持つアクリロニトリル・ブタジエン・スチレン三次元共重合体（
ＡＢＳ）組成物とその製造方法に関する。The present invention relates to a plastic material and a method for producing the same, and more particularly to an acrylonitrile-butadiene-styrene three-dimensional copolymer (having high fluidity, impact resistance and conductivity).
ABS) compositions and methods for making the same.

【０００２】[0002]

【背景技術】[Background technology]

アクリロニトリル・ブタジエン・スチレン三次元共重合体（ＡＢＳ）樹脂は、
優れた総合的な力学特性を持ち、表面が光沢を有し、電子、家電、通信等家電業
界における電話、コンピューター、テレビ等のハウジングなどの部品の製造に広
く応用されている。しかし、一般のＡＢＳ樹脂は絶縁材料であるため、その比体
積抵抗と比表面抵抗はかなり高いので、製品の表面には摩擦等による静電荷が発
生し易い。このように、製品の表面には粉塵が吸着されし易いので、その外観に
影響することになる。一方、集まった静電荷が火花を生じて、放電してしまう。
したがって、半導体集積回路の正常動作に影響することになる。さらに極端な場
合、操作使用者を電気的に傷つけることがある。また、外部からの妨害電磁波は
容易に絶縁のＡＢＳハウジングを通過し、その内部電気回路のシステムの正常動
作に影響を与えることになる。一方、コンピューター、電話、テレビ等のシステ
ムは、作動中に生じた電磁波等のような信号を外部へ放射し、周辺の他の電子通
信設備の回路システムの正常動作を妨害し、さらに人体の健康に影響を与えるこ
とになる。Acrylonitrile-butadiene-styrene three-dimensional copolymer (ABS) resin is
It has excellent comprehensive mechanical properties, has a glossy surface, and is widely applied to the manufacture of parts such as housings for telephones, computers, TVs, etc. in the home electronics industry such as electronics, home appliances and communications. However, since the general ABS resin is an insulating material, its specific volume resistance and specific surface resistance are considerably high, so that electrostatic charges are easily generated on the surface of the product due to friction or the like. As described above, since dust is easily adsorbed on the surface of the product, its appearance is affected. On the other hand, the collected electrostatic charges generate sparks and are discharged.
Therefore, it affects the normal operation of the semiconductor integrated circuit. In more extreme cases, it may electrically injure the operating user. In addition, electromagnetic waves from the outside easily pass through the insulated ABS housing and affect the normal operation of the system of its internal electric circuit. On the other hand, systems such as computers, telephones and televisions radiate signals such as electromagnetic waves generated during operation to the outside, interfere with the normal operation of the circuit system of other electronic communication equipment in the vicinity, and further improve the health of human body. Will be affected.

【０００３】 ＡＢＳ樹脂に一定の導電性能を与えると、製品の表面に集まった静電荷が人体
に与える危害を排除するだけでなく、電磁波を遮蔽する機能を果たし、外部から
の電磁波が施設の電気回路システムの正常作動に与える妨害を効率的に防止する
ことができる。 これまで、世界の各国における導電性ＡＢＳに関する開発と製造は，主にＡＢ
Ｓ樹脂基材に金属粉末、ファイバーとグラファイト(黒鉛)、カーボンブラック、
カーボンファイバーなどのような導電性を持つフィラーを充填することにより行
なわれていた。しかし、金属粉末とファイバーは、表面が酸化し易い、加工しに
くい、重量が重い、材料の機械力学性能を著しく劣化させる等の欠点が有るので
、その応用は極端に制約されていた。一方、グラファイトの比抵抗値は、より大
きく、導電性もあまりよくない。カーボンファイバーは高価である。これらの要
素はそれらの工業的応用に影響することになる。これまで、カーボンブラックを
ＡＢＳに充填する方法が、より多く用いられるが、カーボンブラックとＡＢＳ基
体との接着性能は劣るので、カーボンブラックを充填した後、複合材料の耐撃性
と流動性が大きく低下し、材料の加工性能と製品の最終の使用効果が著しく影響
を受ける。When ABS resin is given a certain conductivity, it not only eliminates the harm caused to the human body by the electrostatic charge collected on the surface of the product, but also serves to shield the electromagnetic wave, and the electromagnetic wave from the outside causes the electricity of the facility to flow. It is possible to effectively prevent the interference with the normal operation of the circuit system. Until now, the development and manufacturing of conductive ABS in each country in the world has been mainly
S resin base material with metal powder, fiber and graphite (graphite), carbon black,
This has been done by filling a conductive filler such as carbon fiber. However, the metal powder and the fiber have drawbacks such that the surface is easily oxidized, difficult to process, heavy, and the mechanical mechanical performance of the material is remarkably deteriorated, so that the application thereof is extremely limited. On the other hand, the specific resistance value of graphite is larger and the conductivity is not so good. Carbon fiber is expensive. These factors will affect their industrial application. Up until now, the method of filling carbon black into ABS has been used more frequently, but the adhesion performance between carbon black and ABS substrate is inferior, so after the carbon black is filled, the composite material has a high impact resistance and fluidity. The material processing performance and the final use effect of the product are significantly affected.

【０００４】[0004]

【発明の開示】DISCLOSURE OF THE INVENTION

本発明の目的は、前記従来技術に存在している欠点を克服して、優れた加工流
動性と耐衝撃性を持つ導電性ＡＢＳ組成物の製造方法を提供することである。 本発明の目的は下記の形態によって実施することができる。 前記材料を製造するための成分組成（質量％）が ＡＢＳ ６０〜６５ カーボンブラック １５〜２５ 耐衝撃性改良剤 １５〜２０ 抗酸化剤 ０．１〜０．２ 紫外線吸収剤 ０．２〜０．３ であることを特徴とする高流動性、耐衝撃性および導電性を持つアクリロニトリ
ル・ブタジエン・スチレン三次元共重合体（ＡＢＳ）組成物。The object of the present invention is to overcome the drawbacks existing in the prior art and to provide a method for producing a conductive ABS composition having excellent process flowability and impact resistance. The object of the present invention can be implemented by the following modes. The component composition (mass%) for producing the material is ABS 60-65 carbon black 15-25 impact resistance improver 15-20 antioxidant 0.1-0.2 ultraviolet absorber 0.2-0. An acrylonitrile-butadiene-styrene three-dimensional copolymer (ABS) composition having high fluidity, impact resistance and conductivity, which is characterized in that

【０００５】 前記耐衝撃性改良剤は熱可塑性ポリエステル弾性体あってよい。 または、前記耐衝撃性改良剤は熱可塑性ポリウレタンＴＰＵであってよい。 さらに、前記耐衝撃性改良剤は核−殻の構造を持つグラフト・ポリマーＭＢＳ
であってよい。The impact modifier may be a thermoplastic polyester elastomer. Alternatively, the impact modifier may be a thermoplastic polyurethane TPU. Further, the impact modifier is a graft polymer MBS having a core-shell structure.
May be

【０００６】 また、本発明は、各成分を高速混合機で１〜２分間混合し、その混合物を２軸
押出機のホッパーに入れ、スクリューの各段の温度を２１０〜２４０℃とし、ス
クリューの回転数を３００ｒｐｍとして押出された物質を水冷し、粉砕し、乾燥
した後、製品を得ることを特徴とする、高流動性、耐衝撃性、導電性を持つアク
リロニトリル・ブタジエン・スチレン三次元共重合体（ＡＢＳ）組成物の製造方
法である。Further, in the present invention, the respective components are mixed by a high-speed mixer for 1 to 2 minutes, the mixture is put into a hopper of a twin-screw extruder, and the temperature of each stage of the screw is set to 210 to 240 ° C. Acrylonitrile-butadiene-styrene three-dimensional co-polymer having high fluidity, impact resistance and conductivity, characterized in that the extruded material is rotated at a rotation speed of 300 rpm, water-cooled, crushed and dried to obtain a product. It is a method for producing an integrated (ABS) composition.

【０００７】[0007]

【発明を実施するための最良の形態】BEST MODE FOR CARRYING OUT THE INVENTION

実施例１〜３ ＡＢＳを基礎材料として用いた。このＡＢＳ樹脂は強靭性高流動性材料である
。そのメルトインデックス（ＭＩ）は３〜４ｇ／１０min、簡支梁ノッチ付衝撃
強度は２５〜３５ＫＪ／ｍ２、引張強さは４０〜６０Ｍｐａである。熱可塑性ポ
リエステル弾性体を強靭化剤として用いた。この弾性体は Du Pont製HYTREL4533
であり、その破断点引張強さは３０Ｍｐａ、破断点伸びは６００％であり、アイ
ゾットノッチ付き衝撃試験でも、破断されない。メルトインデックスは８．５／
１０min、融点は１９３℃、ビカー軟化点は１５８℃である。カーボンブラック
を導電性フィラーとして用いた。そのカーボンブラックの比表面積は２５４ｍ２ ／ｇ、粒径は３０μｍ、ＤＢＰＡ値は１８８ｃｍ３／１００ｇであり、密度は９
７ｇ／ｌである。各組成物中のそれら成分の含有量（重量部）を表１に示す。前
記含有量の各成分を高速混合機で１〜２分間混含し、その混合物を２軸押出機の
ホッパーに入れて、スクリューの各段の温度を２１０〜２４０℃とし、スクリュ
ーの回転数を３００ｒｐｍとして、押出された物質を水冷し、粉砕し、乾燥した
後、製品を得た。該顆粒製品を射出成形で標準試験片に押出して、性能の測定と
試験のために供した。その結果を表２に示す。Examples 1-3 ABS was used as the base material. This ABS resin is a tough, highly fluid material. The melt index (MI) is 3 to 4 g / 10 min, the impact strength with the support beam notch is 25 to 35 KJ / m 2 , and the tensile strength is 40 to 60 Mpa. A thermoplastic polyester elastomer was used as a toughening agent. This elastic body is made by Du Pont HYTREL4533
The tensile strength at break is 30 MPa, the elongation at break is 600%, and it is not broken even in the impact test with Izod notch. Melt index is 8.5 /
10 min, melting point 193 ° C, Vicat softening point 158 ° C. Carbon black was used as the conductive filler. The specific surface area of the carbon black is 254m 2 / g, particle size 30 [mu] m, DBPA value is 188cm 3 / 100g, density 9
7 g / l. The contents (parts by weight) of those components in each composition are shown in Table 1. Each component having the above content is mixed by a high-speed mixer for 1 to 2 minutes, and the mixture is put into a hopper of a twin-screw extruder, the temperature of each stage of the screw is set to 210 to 240 ° C., and the rotation speed of the screw is changed. The extruded material was water cooled at 300 rpm, crushed and dried to obtain the product. The granular product was extruded into standard test pieces and subjected to performance measurements and testing. The results are shown in Table 2.

【０００８】[0008]

【表１】 [Table 1]

【表２】 [Table 2]

【０００９】 実施例４〜６ ＡＢＳを基礎材料（材料性能は実施例１と同じ）として用い、熱可塑性ポリウ
レタンＴＰＵを強靭化剤として用い、カーボンブラックを導電性フィラー（実施
例１と同じ）として用いた。組成物中のこれら成分の含有量を表３に示す。前記
含有量の各成分を高速混合機で１〜２分間混合し、その混合物を２軸押出機のホ
ッパーに入れて、スクリューの各段温度を２１０〜２４０℃とし、スクリューの
回転数を３００ｒｐｍとして、押出された物質を水冷し、粉砕し、乾燥した後、
製品を得た。該顆粒製品を射出成形で標準試験片に押出して、性能の測定と試験
のために供した。その結果を表４に示す。Examples 4 to 6 ABS is used as a basic material (material performance is the same as that of Example 1), thermoplastic polyurethane TPU is used as a toughening agent, and carbon black is a conductive filler (same as Example 1). Using. The contents of these components in the composition are shown in Table 3. The components having the above contents were mixed by a high-speed mixer for 1 to 2 minutes, and the mixture was put into a hopper of a twin-screw extruder, the temperature of each stage of the screw was 210 to 240 ° C., and the rotation speed of the screw was 300 rpm. Water-cooling the extruded material, crushing and drying,
Got the product. The granular product was extruded into standard test pieces and subjected to performance measurements and testing. The results are shown in Table 4.

【００１０】[0010]

【表３】 [Table 3]

【表４】 [Table 4]

【００１１】 実施例７〜８ ＡＢＳを基礎材斜（材料性能は実施例１と同じ）として用い、熱可塑性の核−
殻の構造を持つグラフト・ポリマーＭＢＳ（米国ROHM HASS社の製品）を強靭化
剤として用い、カーボンブラックを導電性フィラー（実施例１と同じ）として用
い、組成物中のこれら成分の含有量を表５に示す。前記含有量の各成分を高速合
機で１〜２分間混合し、その混合物を２軸押出機のホッパーに入れて、スクリュ
ーの各段の温度を２１０〜２４０℃とし、スクリューの回転数を３００ｒｐｍと
して、押出された物質を水冷し、粉砕し、乾燥した後、製品を得た。該顆粒製品
を射出成形で標準試験片に押出して、性能の測定と試験のために供した。その結
果を表６に示す。Examples 7 to 8 Using ABS as a base material diagonal (the material performance is the same as in Example 1), a thermoplastic core-
Graft polymer MBS (product of ROHM HASS, USA) having a shell structure was used as a toughening agent, carbon black was used as a conductive filler (same as in Example 1), and the content of these components in the composition was adjusted. It shows in Table 5. The components of the above contents were mixed for 1 to 2 minutes with a high-speed compounding machine, the mixture was put into the hopper of a twin-screw extruder, the temperature of each stage of the screw was 210 to 240 ° C., and the rotation speed of the screw was 300 rpm. As, the extruded material was water cooled, crushed and dried to obtain the product. The granular product was extruded into standard test pieces and subjected to performance measurements and testing. The results are shown in Table 6.

【００１２】 要するに、軟−硬セグメント構造を持つ熱可塑性ポリエステル弾性体、熱可塑
性ポリウレタンＴＰＵ及び核−殼の構造を持つグラフトポリマーＭＢＳを強靭化
剤として、材料の導電性能を保持すると同時に、カーボンブラックを充填した複
合材料の耐衝撃性能を改善したばかりでなく、この複合材料の加工流動性能を著
しく高めることができたので、構造が複雑で大きい部品といったような製品の製
造要求を満足することができる。また、本発明の製品は、比表面抵抗が１０６〜
１０７Ωで、材料の静電防止性能の要求を満たしているため、特にテレビ、コン
ピューター、電話、プリンターのハウジング及び電子周転箱等、その他部品の製
造に適用する。In short, a thermoplastic polyester elastic body having a soft-hard segment structure, a thermoplastic polyurethane TPU, and a graft polymer MBS having a core-shell structure are used as a toughening agent to retain the conductive performance of the material and at the same time, carbon black. In addition to improving the impact resistance performance of the composite material filled with, it was possible to significantly improve the process flow performance of this composite material, so that it is possible to satisfy the manufacturing requirements of products such as parts with complicated structures and large parts. it can. Further, the product of the present invention has a specific surface resistance of 10 6 to
Since it is 10 7 Ω and satisfies the requirement of the antistatic property of the material, it is particularly applied to the production of other parts such as televisions, computers, telephones, printer housings and electronic rotating boxes.

【００１３】[0013]

【表５】 [Table 5]

【表６】 [Table 6]

【００１４】 従来技術と比べて本発明の異なる点は、導電カーボンブラックを導電性フィラ
ーとして、またＡＢＳ−カーボンブラック系の中に、ＡＢＳ樹脂と相容性がよい
高分子耐衝撃性改良剤、例えば、熱可塑性ポリエステル弾性体、熱可塑性ポリウ
レタンＴＰＵ、核−殻構造を持つグラフト・ポリマーＭＢＳを強靭化剤として適
切に選択しているので、カーボンブラック充填した複合材料の耐衝撃性能を改善
できるばかりでなく、この複合材料の加工流動性能を著しく高めることができる
ので、構造が複雑で大きい部品のような製品の製造要求を満足することができる
。The present invention is different from the prior art in that conductive carbon black is used as a conductive filler, and a polymer impact resistance improver that is compatible with ABS resin in the ABS-carbon black system, For example, thermoplastic polyester elastomer, thermoplastic polyurethane TPU, and graft polymer MBS having a core-shell structure are appropriately selected as the toughening agent, so that the impact resistance performance of the carbon black-filled composite material can be improved. In addition, since the working flow performance of this composite material can be remarkably enhanced, it is possible to satisfy the manufacturing requirements of products such as parts having complicated structures and large sizes.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０８Ｋ 3/04 Ｃ０８Ｋ 3/04 Ｃ０８Ｌ 51/04 Ｃ０８Ｌ 51/04 67/00 67/00 75/04 75/04 // Ｂ２９Ｋ 33:18 Ｂ２９Ｋ 33:18 105:06 105:06 (81)指定国 ＥＰ(ＡＴ，ＢＥ，ＣＨ，ＣＹ， ＤＥ，ＤＫ，ＥＳ，ＦＩ，ＦＲ，ＧＢ，ＧＲ，ＩＥ，Ｉ Ｔ，ＬＵ，ＭＣ，ＮＬ，ＰＴ，ＳＥ)，ＯＡ(ＢＦ，ＢＪ ，ＣＦ，ＣＧ，ＣＩ，ＣＭ，ＧＡ，ＧＮ，ＧＷ，ＭＬ， ＭＲ，ＮＥ，ＳＮ，ＴＤ，ＴＧ)，ＡＰ(ＧＨ，ＧＭ，Ｋ Ｅ，ＬＳ，ＭＷ，ＭＺ，ＳＤ，ＳＬ，ＳＺ，ＴＺ，ＵＧ ，ＺＷ)，ＥＡ(ＡＭ，ＡＺ，ＢＹ，ＫＧ，ＫＺ，ＭＤ， ＲＵ，ＴＪ，ＴＭ)，ＡＥ，ＡＧ，ＡＬ，ＡＭ，ＡＴ， ＡＵ，ＡＺ，ＢＡ，ＢＢ，ＢＧ，ＢＲ，ＢＹ，ＣＡ，Ｃ Ｈ，ＣＲ，ＣＵ，ＣＺ，ＤＥ，ＤＫ，ＤＭ，ＤＺ，ＥＥ ，ＥＳ，ＦＩ，ＧＢ，ＧＤ，ＧＥ，ＧＨ，ＧＭ，ＨＲ， ＨＵ，ＩＤ，ＩＬ，ＩＮ，ＩＳ，ＪＰ，ＫＥ，ＫＧ，Ｋ Ｐ，ＫＲ，ＫＺ，ＬＣ，ＬＫ，ＬＲ，ＬＳ，ＬＴ，ＬＵ ，ＬＶ，ＭＡ，ＭＤ，ＭＧ，ＭＫ，ＭＮ，ＭＷ，ＭＸ， ＭＺ，ＮＯ，ＮＺ，ＰＬ，ＰＴ，ＲＯ，ＲＵ，ＳＤ，Ｓ Ｅ，ＳＧ，ＳＩ，ＳＫ，ＳＬ，ＴＪ，ＴＭ，ＴＲ，ＴＴ ，ＴＺ，ＵＡ，ＵＧ，ＵＳ，ＵＺ，ＶＮ，ＹＵ，ＺＡ， ＺＷ (72)発明者 徐 青 中華人民共和国201109上海市閔行区北橋鎮 北松路800号 Ｆターム(参考） 4F070 AA06 AA18 AA32 AA33 AA47 AA53 AB08 AC04 AC73 AC76 AC83 AC88 AC89 AE03 DA43 DA46 DA48 DA50 DA55 FA01 FA03 FC05 4F201 AA13 AB01 AB06 AB13 AB18 AE03 AH33 AH41 AR06 AR09 BA01 BC01 BC03 BC12 BC37 BK01 BK02 BK13 BK15 BK27 BK74 4J002 BN151 BN162 CF102 CK022 DA036 FD058 FD077 GQ00─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C08K 3/04 C08K 3/04 C08L 51/04 C08L 51/04 67/00 67/00 75/04 75 / 04 // B29K 33:18 B29K 33:18 105: 06 105: 06 (81) Designated countries EP (AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT , LU, MC, NL, PT, SE), OA (BF, BJ, CF, CG, CI, CM, GA, GN, GW, ML, MR, NE, SN, TD, TG), AP (GH, GM) , KE, LS, MW, MZ, SD, SL, SZ, TZ, UG, ZW), EA (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), AE, AG, AL, AM, AT, AU , AZ, BA, BB, BG, BR, BY, CA, CH, CR, CU, CZ, DE, DK, DM, DZ, EE, ES, FI, GB, GD, GE, GH, GM, HR, HU, ID, IL, IN, IS, JP, KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MA, MD, MG, MK, MN, MW, MX , MZ, NO, NZ, PL, PT, RO, RU, SD, SE, SG, SI, SK, SL, TJ, TM, TR, TT, TZ, UA, UG, US, UZ, VN, YU, ZA, ZW (72) Inventor Xu Qing People's Republic of China 201109 No. 800 F-term, North Song Road, North Bridge Town, Minhang District, Shanghai 4F070 AA06 AA18 AA32 AA33 AA47 AA53 AB08 AC04 AC73 AC76 AC83 AC88 AC89 AE03 DA43 DA46 DA48 DA50 DA55 FA01 FA03 FC05 4F201 AA13 AB01 AB06 AB13 AB18 AE03 AH33 AH41 AR06 AR09 BA01 BC01 BC03 BC12 BC37 BK0 1 BK02 BK13 BK15 BK27 BK74 4J002 BN151 BN162 CF102 CK022 DA036 FD058 FD077 GQ00

Claims (5)

【特許請求の範囲】[Claims] 【請求項１】 下記組成（質量％）： ＡＢＳ ６０〜６５ カーボンブラック １５〜２５ 耐衝撃性改良剤 １５〜２０ 抗酸化剤 ０．１〜０．２ 紫外線吸収剤 ０．２〜０．３ を有することを特徴とする高流動性、耐衝撃性および導電性を持つアクリロニト
リル・ブタジエン・スチレン三次元共重合体（ＡＢＳ）組成物。1. The following composition (% by mass): ABS 60-65 carbon black 15-25 impact resistance improver 15-20 antioxidant 0.1-0.2 ultraviolet absorber 0.2-0.3. An acrylonitrile-butadiene-styrene three-dimensional copolymer (ABS) composition having high fluidity, impact resistance and conductivity, which is characterized by having. 【請求項２】 前記の耐衝撃性改良剤は、熱可塑性ポリエステル弾性体であ
ることを特徴とする、請求項１記載の高流動性、耐衝撃性および導電性を持つＡ
ＢＳ組成物。2. The high flowability, impact resistance and conductivity A according to claim 1, wherein the impact resistance improver is a thermoplastic polyester elastic body.
BS composition. 【請求項３】 前記の耐衝撃性改良剤は熱可塑性ポリウレタンＴＰＵである
ことを特徴とする、請求項１記載の高流動性、耐衝撃性および導電性を持つＡＢ
Ｓ組成物。3. High flowability, impact resistance and conductivity AB as claimed in claim 1, characterized in that said impact modifier is a thermoplastic polyurethane TPU.
S composition. 【請求項４】 前記の耐衝撃性改良剤は、核−殻の構造を持つグラフトポリ
マーＭＢＳであることを特徴とする、請求項１記載の高流動性、耐衝撃性および
導電性を持つＡＢＳ組成物。4. The ABS having high fluidity, impact resistance and conductivity according to claim 1, wherein the impact resistance improver is a graft polymer MBS having a core-shell structure. Composition. 【請求項５】 各成分を高速混合機で１〜２分間混合し、その混合物を２軸
押出機のホッパーに入れ、スクリューの各段の温度を２１０〜２４０℃とし、ス
クリューの回転数を３００ｒｐｍとして押出された物質を水冷し、粉砕し、乾燥
した後、製品を得ることを特徴とする、請求項１記載の高流動性、耐衝撃性、導
電性を持つアクリロニトリル・ブタジエン・スチレン三次元共重合体（ＡＢＳ）
組成物の製造方法。5. The respective components are mixed by a high speed mixer for 1 to 2 minutes, the mixture is put into a hopper of a twin-screw extruder, the temperature of each stage of the screw is set to 210 to 240 ° C., and the rotation speed of the screw is 300 rpm. 3. The three-dimensional acrylonitrile-butadiene-styrene three-dimensional copolymer having high fluidity, impact resistance and conductivity according to claim 1, characterized in that the product extruded as water is cooled, crushed and dried to obtain a product. Polymer (ABS)
A method for producing a composition.
JP2001514039A 1999-07-29 2000-06-12 High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same Pending JP2003529626A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CNB991139321A CN1160409C (en) 1999-07-29 1999-07-29 High-flowability, impact-resistant and electrically conductive temary acrylonitrile-butadiene-styrene copolymer and its preparing process
CN99113932.1 1999-07-29
PCT/CN2000/000154 WO2001009241A1 (en) 1999-07-29 2000-06-12 High fluidible, impact resistant conductive acrylonitrile-butadiene-styrene terpolymer material and preparing method thereof

Publications (2)

Publication Number Publication Date
JP2003529626A true JP2003529626A (en) 2003-10-07
JP2003529626A5 JP2003529626A5 (en) 2006-09-21

Family

ID=5277070

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001514039A Pending JP2003529626A (en) 1999-07-29 2000-06-12 High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same

Country Status (4)

Country Link
JP (1) JP2003529626A (en)
CN (1) CN1160409C (en)
AU (1) AU5386500A (en)
WO (1) WO2001009241A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101860388B1 (en) 2017-03-10 2018-05-24 (주)티엘씨코리아 ABS composition for 3D printer filament having excellent discoloration resistance and low shrinkage and filament manufactured therefrom

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002256125A (en) * 2001-02-28 2002-09-11 Daicel Chem Ind Ltd Conductive resin composition
CN102002206A (en) * 2010-12-21 2011-04-06 四川大学 High-glossiness high-toughness scratch resistant molding composition
CN102585429B (en) * 2011-01-11 2015-02-25 合肥杰事杰新材料股份有限公司 Resin material, preparation method and applications of resin material
CN102582188A (en) * 2012-02-16 2012-07-18 仙居县一远静电科技有限公司 Antistatic ABS (Acrylonitrile Butadiene Styrene) laminated board
CN103360718B (en) * 2013-07-14 2015-11-18 上海秋橙新材料科技有限公司 anti-aging ABS-TPU plastic alloy

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52124043A (en) * 1976-04-13 1977-10-18 Kokoku Rubber Ind Electrical conductive resin composition for plating
JPS5785994A (en) * 1980-11-17 1982-05-28 Sumitomo Bakelite Co Ltd Resin composition for plating
JPS58222135A (en) * 1982-06-19 1983-12-23 Nippon Steel Chem Co Ltd Electrically conductive resin composition
JPS6397653A (en) * 1986-10-14 1988-04-28 Toray Ind Inc Thermoplastic resin composition
JPH0480249A (en) * 1990-07-23 1992-03-13 Sumitomo Dow Ltd Production of filled resin composition
JPH0657153A (en) * 1992-08-10 1994-03-01 Daicel Chem Ind Ltd Antistatic resin composition
JPH0665508A (en) * 1992-08-18 1994-03-08 Daicel Chem Ind Ltd Antistatic resin composition
JPH07268170A (en) * 1994-04-01 1995-10-17 Japan Synthetic Rubber Co Ltd Thermoplastic resin composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5989723A (en) * 1997-05-16 1999-11-23 Far Eastern Textile Ltd. Conductive polyester-based alloy sheet

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52124043A (en) * 1976-04-13 1977-10-18 Kokoku Rubber Ind Electrical conductive resin composition for plating
JPS5785994A (en) * 1980-11-17 1982-05-28 Sumitomo Bakelite Co Ltd Resin composition for plating
JPS58222135A (en) * 1982-06-19 1983-12-23 Nippon Steel Chem Co Ltd Electrically conductive resin composition
JPS6397653A (en) * 1986-10-14 1988-04-28 Toray Ind Inc Thermoplastic resin composition
JPH0480249A (en) * 1990-07-23 1992-03-13 Sumitomo Dow Ltd Production of filled resin composition
JPH0657153A (en) * 1992-08-10 1994-03-01 Daicel Chem Ind Ltd Antistatic resin composition
JPH0665508A (en) * 1992-08-18 1994-03-08 Daicel Chem Ind Ltd Antistatic resin composition
JPH07268170A (en) * 1994-04-01 1995-10-17 Japan Synthetic Rubber Co Ltd Thermoplastic resin composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101860388B1 (en) 2017-03-10 2018-05-24 (주)티엘씨코리아 ABS composition for 3D printer filament having excellent discoloration resistance and low shrinkage and filament manufactured therefrom

Also Published As

Publication number Publication date
CN1160409C (en) 2004-08-04
CN1282762A (en) 2001-02-07
AU5386500A (en) 2001-02-19
WO2001009241A1 (en) 2001-02-08

Similar Documents

Publication Publication Date Title
JP2001503799A (en) Conductive composition and method for producing the same
JP2002538272A (en) Conductive thermoplastic elastomers and products made therefrom
JP6490682B2 (en) Carbon fiber reinforced plastic molding material
JP2002536799A (en) Conductive composition and method for producing the same
CN107216649A (en) It is a kind of to exempt from spraying daiamid composition and preparation method thereof with metallic luster
CN103436012B (en) Ultrahigh-molecular weight polyethylene modified nylon 66 and preparation method thereof
JP2003529626A (en) High fluidity impact resistant conductive acrylonitrile-butadiene-styrene three-dimensional copolymer composition and method for producing the same
CN111423723A (en) Reinforced polyphenylene sulfide composition for 5G and preparation method thereof
CN102827411B (en) High-molecular composite nanometer voltage variable resistance soft film and manufacturing method
KR101165420B1 (en) Electro-conductive resin composition
CN113930003B (en) MPPO material, mineral filled master batch and preparation method thereof
CN102863783A (en) High-toughness electric conduction nylon composite material and preparation method thereof
CN112745630B (en) Super-tough high-fluidity regenerated ABS/PA6 composite material and preparation method and application thereof
JPS5911332A (en) Blending of thermoplastic resin with additive
CN114181456A (en) High-hardness polypropylene composite material and preparation method thereof
CN109721841B (en) Long-acting antistatic PP material and preparation method thereof
JP2002188007A (en) Composite material and circuit board
JPH06306201A (en) Electromagnetic wave shielding resin composition
JP2003529626A5 (en)
CN111073326A (en) Preparation method of rice hull powder/PBAT composite material
JPH08311242A (en) Conductive thermosetting resin composition and housing for electric and electronic apparatus
JP2001261975A (en) Electroconductive thermoplastic resin composition
CN108276755A (en) A kind of composite material and preparation method for electromagnetic shielding
JP2020002243A (en) Resin composition
JPH1180468A (en) Resin molding material containing conductive filler

Legal Events

Date Code Title Description
A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060725

A524 Written submission of copy of amendment under section 19 (pct)

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20060725

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060725

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20090219

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090317

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090617

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090624

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090717

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090727

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090817

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090824

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090916

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100323

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20100727