JP2003529572A - 置換多環式シクロペンタジエン及びその製造方法 - Google Patents

置換多環式シクロペンタジエン及びその製造方法

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Publication number
JP2003529572A
JP2003529572A JP2001572442A JP2001572442A JP2003529572A JP 2003529572 A JP2003529572 A JP 2003529572A JP 2001572442 A JP2001572442 A JP 2001572442A JP 2001572442 A JP2001572442 A JP 2001572442A JP 2003529572 A JP2003529572 A JP 2003529572A
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group
formula
metal
compound
carbon atoms
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JP2001572442A
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Japanese (ja)
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JP2003529572A5 (enExample
Inventor
パオロ ビアジニ
ディエゴ ヴィグリアロロ
ジアムピエトロ ボルソッティ
ロベルト サンティ
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Versalis SpA
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Polimeri Europa SpA
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Publication of JP2003529572A publication Critical patent/JP2003529572A/ja
Publication of JP2003529572A5 publication Critical patent/JP2003529572A5/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
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    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
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    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
JP2001572442A 2000-03-31 2001-03-20 置換多環式シクロペンタジエン及びその製造方法 Pending JP2003529572A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT2000A000680 2000-03-31
IT2000MI000680A IT1318436B1 (it) 2000-03-31 2000-03-31 Ciclopentadieni sostituiti policiclici e metodo per la loropreparazione.
PCT/EP2001/003127 WO2001074745A1 (en) 2000-03-31 2001-03-20 Substituted polycyclic cyclopentadienes and method for their preparation

Publications (2)

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JP2003529572A true JP2003529572A (ja) 2003-10-07
JP2003529572A5 JP2003529572A5 (enExample) 2008-05-15

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US (2) US6844478B2 (enExample)
EP (1) EP1268375B1 (enExample)
JP (1) JP2003529572A (enExample)
KR (1) KR100862128B1 (enExample)
AR (1) AR029503A1 (enExample)
AT (1) ATE286496T1 (enExample)
AU (1) AU2001239308A1 (enExample)
CA (1) CA2404549C (enExample)
DE (1) DE60108231T2 (enExample)
ES (1) ES2234819T3 (enExample)
IT (1) IT1318436B1 (enExample)
MX (1) MXPA02009374A (enExample)
MY (1) MY126014A (enExample)
TW (1) TWI222964B (enExample)
WO (1) WO2001074745A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004505019A (ja) * 2000-06-30 2004-02-19 ダウ　グローバル　テクノロジーズ　インコーポレーテッド 多環式、縮合環化合物、金属錯体及び重合方法
WO2020171073A1 (ja) * 2019-02-19 2020-08-27 株式会社 三和化学研究所 ベンゾアゼピン誘導体の製造方法及びその中間体

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* Cited by examiner, † Cited by third party
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EP2261292B1 (en) 2002-10-15 2014-07-23 ExxonMobil Chemical Patents Inc. Polyolefin adhesive compositions
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
WO2010077163A1 (en) * 2008-12-30 2010-07-08 Gosudarstvennoe Uchebno-Nauchnoe Uchrezhdenie Khimichesky Fakultet Moskovskogo Gosudarstvennogo Universiteta Im. M.V.Lomonosova Synthesis of substituted tetrahydroindenyl complexes, metallocenes produced therefrom and use of the metallocenes in polymerisation processes
CN111132988B (zh) * 2017-09-28 2023-06-20 尤尼威蒂恩技术有限责任公司 环状有机化合物和茂金属的合成

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JPH06340684A (ja) * 1990-11-12 1994-12-13 Hoechst Ag ２−置換インデニル誘導体のリガンドを含有するメタロセン、その製造方法およびその使用方法
JPH0841088A (ja) * 1994-03-22 1996-02-13 Pcd Polymere Gmbh メタロセン及びそれらをオレフィン重合に使用する方法
JPH09501184A (ja) * 1994-04-06 1997-02-04 モンテル テクノロジー カンパニー ビーブイ メタロセン化合物及びオレフィンの重合用触媒への使用
JPH0967326A (ja) * 1995-03-03 1997-03-11 Roussel Uclaf 新規な三環式誘導体、それらの製造法、光学活性又はラセミ形のコルヒチン及びチオコルヒチン並びにそれらの類似体又は誘導体の製造への使用並びに中間体
JPH10158288A (ja) * 1996-10-31 1998-06-16 Hoechst Ag 部分的に水素化されたπリガンドを含有するメタロセン
JPH10231314A (ja) * 1996-12-19 1998-09-02 Enichem Spa メタロセン、それらの製造およびアルファ−オレフィンの重合におけるそれらの使用
JP2001133886A (ja) * 1999-08-26 2001-05-18 Kuraray Co Ltd 背面投射形スクリーン用プラスチックシート
JP2002530286A (ja) * 1998-11-18 2002-09-17 モンテル テクノロジー カンパニー ビーブイ オレフィン重合触媒としてのビス（テトラヒドロ−インデニル）メタロセン

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06340684A (ja) * 1990-11-12 1994-12-13 Hoechst Ag ２−置換インデニル誘導体のリガンドを含有するメタロセン、その製造方法およびその使用方法
JPH0841088A (ja) * 1994-03-22 1996-02-13 Pcd Polymere Gmbh メタロセン及びそれらをオレフィン重合に使用する方法
JPH09501184A (ja) * 1994-04-06 1997-02-04 モンテル テクノロジー カンパニー ビーブイ メタロセン化合物及びオレフィンの重合用触媒への使用
JPH0967326A (ja) * 1995-03-03 1997-03-11 Roussel Uclaf 新規な三環式誘導体、それらの製造法、光学活性又はラセミ形のコルヒチン及びチオコルヒチン並びにそれらの類似体又は誘導体の製造への使用並びに中間体
JPH10158288A (ja) * 1996-10-31 1998-06-16 Hoechst Ag 部分的に水素化されたπリガンドを含有するメタロセン
JPH10231314A (ja) * 1996-12-19 1998-09-02 Enichem Spa メタロセン、それらの製造およびアルファ−オレフィンの重合におけるそれらの使用
JP2002530286A (ja) * 1998-11-18 2002-09-17 モンテル テクノロジー カンパニー ビーブイ オレフィン重合触媒としてのビス（テトラヒドロ−インデニル）メタロセン
JP2001133886A (ja) * 1999-08-26 2001-05-18 Kuraray Co Ltd 背面投射形スクリーン用プラスチックシート

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Title
JPN6011003206, ＫＯＮＤＯ，Ｔ． ｅｔ ａｌ, "１−ｅｘｏ− ａｎｄ １−ｅｎｄｏ（Ｔｒｉｍｅｔｈｙｌｓｉｌｙｌ）−２，３−ｆｅｒｒｏｃｅｎｏｉｎｄｅｎｅ． Ｐｒｅｐａｒａｔｉｏｎ ａｎｄ ｍｅｔｈａｎｏｌｙｓｉｓ ｉｎ ｔｈｅ ｐｒｅｓｅｎｃｅ", Ｊｏｕｒｎａｌ ｏｆ Ｏｒｇａｎｏｍｅｔａｌｌｉｃ Ｃｈｅｍｉｓｔｒｙ, 1973, Ｖｏｌ．６１, ｐ．３４７−５４ *
JPN6011003208, ＣＡＩＳ，Ｍ． ｅｔ ａｌ, "Ｏｒｇａｎｏｍｅｔａｌｌｉｃ ｓｔｕｄｉｅｓ． ＸＶＩＩ． Ａ ｎｏｖｅｌ ａｐｐｒｏａｃｈ ｔｏ ｔｈｅ ｓｙｎｔｈｅｓｉｓ ｏｆ ｔｈｅ ｂｅｎｚｏｐｅｎｔａｌｅｎｅ ｓｙｓｔｅｍ", Ｊｏｕｒｎａｌ ｏｆ ｔｈｅ Ａｍｅｒｉｃａｎ Ｃｈｅｍｉｃａｌ Ｓｏｃｉｅｔｙ, 1965, Ｖｏｌ．８７， Ｎｏ．２４, ｐ．５６０７−１４ *
JPN6011003211, ＡＬＶＡＲＥＺ，Ｍ． ｅｔ ａｌ, "Ｕｓｉｎｇ ｔｈｅ Ｎａｔｉｏｎａｌ Ｃａｎｃｅｒ Ｉｎｓｔｉｔｕｔｅ Ａｎｔｉｃａｎｃｅｒ Ｄｒｕｇ Ｓｃｒｅｅｎ ｔｏ ａｓｓｅｓｓ ｔｈｅ ｅｆｆｅｃｔ ｏｆ ＭＲＰ ｅｘｐｒｅｓｓｉｏｎ ｏｎ", Ｍｏｌｅｃｕｌａｒ Ｐｈａｒｍａｃｏｌｏｇｙ, 1998, Ｖｏｌ．５４， Ｎｏ．５, ｐ．８０２−８１４ *
JPN6011003214, ＲＩＥＤ，Ｗ． ｅｔ ａｌ, "Ｒｅａｃｔｉｏｎｓ ｗｉｔｈ ｃｙｃｌｏｐｅｎｔａｄｉｅｎｏｎｅｓ． ＸＸＶＩＩ． Ｒｅｄｕｃｔｉｏｎ ｏｆ ｓｕｂｓｔｉｔｕｔｅｄ ｃｙｃｌｏｐｅｎｔａｄｉｅｎｏｎｅｓ ｕｓｉｎｇ ｔｈｅ ｌｉ", Ｊｕｓｔｕｓ Ｌｉｅｂｉｇｓ Ａｎｎａｌｅｎ ｄｅｒ Ｃｈｅｍｉｅ, 1971, Ｖｏｌ．７５０, ｐ．９１−６ *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004505019A (ja) * 2000-06-30 2004-02-19 ダウ　グローバル　テクノロジーズ　インコーポレーテッド 多環式、縮合環化合物、金属錯体及び重合方法
WO2020171073A1 (ja) * 2019-02-19 2020-08-27 株式会社 三和化学研究所 ベンゾアゼピン誘導体の製造方法及びその中間体

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ES2234819T3 (es) 2005-07-01
US6930158B2 (en) 2005-08-16
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MY126014A (en) 2006-09-29
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IT1318436B1 (it) 2003-08-25
US6844478B2 (en) 2005-01-18
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