JP2003507387A5 - - Google Patents
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- JP2003507387A5 JP2003507387A5 JP2001517539A JP2001517539A JP2003507387A5 JP 2003507387 A5 JP2003507387 A5 JP 2003507387A5 JP 2001517539 A JP2001517539 A JP 2001517539A JP 2001517539 A JP2001517539 A JP 2001517539A JP 2003507387 A5 JP2003507387 A5 JP 2003507387A5
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- JP
- Japan
- Prior art keywords
- group
- substituted
- carbon atoms
- meaning
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 125000003936 heterocyclopentadienyl group Chemical group 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 125000002877 alkyl aryl group Chemical group 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 125000001072 heteroaryl group Chemical group 0.000 description 5
- 125000000623 heterocyclic group Chemical group 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical class [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 2
- -1 iodine, hydrogen Chemical class 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- RYZGGGMGTVKVLI-UHFFFAOYSA-N [Mo].[CH]1C=CC=C1 Chemical class [Mo].[CH]1C=CC=C1 RYZGGGMGTVKVLI-UHFFFAOYSA-N 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052798 chalcogen Inorganic materials 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 125000005493 quinolyl group Chemical group 0.000 description 1
- 150000003254 radicals Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ANEFWEBMQHRDLH-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl) borate Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1OB(OC=1C(=C(F)C(F)=C(F)C=1F)F)OC1=C(F)C(F)=C(F)C(F)=C1F ANEFWEBMQHRDLH-UHFFFAOYSA-N 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/373,715 US6437161B1 (en) | 1999-08-13 | 1999-08-13 | Monocyclopentadienyl complexes of chromium, molybdenum or tungsten |
| US09/373,715 | 1999-08-13 | ||
| PCT/EP2000/007442 WO2001012641A1 (de) | 1999-08-13 | 2000-08-01 | Monocyclopentadienylkomplexe von chrom, molybdän oder wolfram mit einer donorbrücke |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003507387A JP2003507387A (ja) | 2003-02-25 |
| JP2003507387A5 true JP2003507387A5 (enExample) | 2007-09-06 |
| JP4804687B2 JP4804687B2 (ja) | 2011-11-02 |
Family
ID=23473564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001517539A Expired - Fee Related JP4804687B2 (ja) | 1999-08-13 | 2000-08-01 | クロム、モリブデンまたはタングステンのモノシクロペンタジエニル錯体 |
Country Status (11)
| Country | Link |
|---|---|
| US (4) | US6437161B1 (enExample) |
| EP (2) | EP1288219B1 (enExample) |
| JP (1) | JP4804687B2 (enExample) |
| KR (1) | KR100732108B1 (enExample) |
| CN (1) | CN100354287C (enExample) |
| AT (2) | ATE293631T1 (enExample) |
| AU (1) | AU6569100A (enExample) |
| BR (1) | BR0013223B1 (enExample) |
| DE (2) | DE50010129D1 (enExample) |
| ES (2) | ES2240642T3 (enExample) |
| WO (1) | WO2001012641A1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6437161B1 (en) * | 1999-08-13 | 2002-08-20 | Basf Aktiengesellschaft | Monocyclopentadienyl complexes of chromium, molybdenum or tungsten |
| US6919412B1 (en) * | 1999-08-13 | 2005-07-19 | Basell Polyolefine Gmbh | Monocyclopentadienyl complexes of chromium, molybdenum or tungsten with a donor bridge |
| US6265504B1 (en) * | 1999-09-22 | 2001-07-24 | Equistar Chemicals, Lp | Preparation of ultra-high-molecular-weight polyethylene |
| US6723675B1 (en) * | 2000-05-25 | 2004-04-20 | Univation Technologies, Llc | Catalyst for the production of olefin polymers |
| EP1172385A1 (fr) * | 2000-07-14 | 2002-01-16 | SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) | Procédé pour la polymérisation des alpha-oléfines |
| ATE334151T1 (de) * | 2000-09-28 | 2006-08-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von hochverzweigten ethylenpolymerisaten |
| WO2003025028A1 (de) * | 2001-09-14 | 2003-03-27 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von olefinen |
| DE10145453A1 (de) * | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
| BR0215086B1 (pt) * | 2001-12-20 | 2013-02-05 | sistema catalisador de conversço de hidrocarboneto, e, processo para a oligomerizaÇço de olefinas. | |
| WO2003053890A1 (en) * | 2001-12-20 | 2003-07-03 | Sasol Technology (Pty) Ltd | Trimerisation and oligomerisation of olefins using a chromium based catalyst |
| US6635728B2 (en) * | 2002-01-10 | 2003-10-21 | Equistar Chemicals, Lp | Preparation of ultra-high-molecular-weight polyethylene |
| US7202373B2 (en) | 2002-08-22 | 2007-04-10 | Basell Polyolefine Gmbh | Monocyclopentadienyl complexes |
| DE60321822D1 (de) * | 2002-12-20 | 2008-08-07 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
| US7534847B2 (en) * | 2002-12-20 | 2009-05-19 | Basell Polyolefine Gmbh | Copolymers of ethylene with α-olefins |
| US7226661B2 (en) * | 2003-02-03 | 2007-06-05 | Board Of Regents, The University Of Texas System | Synthesis of quinones and phenols on solid support |
| EP1464657A1 (en) * | 2003-03-06 | 2004-10-06 | ATOFINA Research | Hydrogenated metallocene catalyst |
| BRPI0417575A (pt) * | 2003-12-16 | 2007-03-20 | Basell Polyolefine Gmbh | complexo de monociclopentadienila, sistema catalisador, uso do mesmo, processos para preparar poliolefinas, e sistemas de ciclopentadieno, sistema de ciclopentadieno, e, ciclopentenona |
| EP1694719A2 (en) * | 2003-12-19 | 2006-08-30 | Basell Polyolefine GmbH | Monocyclopentadienyl complexes |
| DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE102004039877A1 (de) * | 2004-08-17 | 2006-02-23 | Basell Polyolefine Gmbh | Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6 |
| DE102004058578A1 (de) * | 2004-12-03 | 2006-06-08 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Katalysatorsystemen später Übergangsmetalle |
| DE102004061618A1 (de) * | 2004-12-17 | 2006-06-22 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
| ATE475633T1 (de) * | 2005-03-09 | 2010-08-15 | Exxonmobil Chem Patents Inc | Verfahren zur oligomerisation von olefinen |
| US7414006B2 (en) * | 2005-03-09 | 2008-08-19 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins |
| DE102005014395A1 (de) * | 2005-03-24 | 2006-09-28 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
| US20090227748A1 (en) * | 2005-09-06 | 2009-09-10 | Basell Polyolefine Gmbh | Process for Preparing Olff in Polymers in the Presence of Catalyst Systems Having Photochromic Groups |
| AU2006301483A1 (en) * | 2005-10-14 | 2007-04-19 | Basell Polyolefine Gmbh | Hybrid catalyst systems supported on magnesium halide |
| DE102005057559A1 (de) * | 2005-11-30 | 2007-05-31 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| US8003839B2 (en) * | 2006-02-03 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Process for generating linear apha olefin comonomers |
| US8076524B2 (en) * | 2006-02-03 | 2011-12-13 | Exxonmobil Chemical Patents Inc. | Process for generating alpha olefin comonomers |
| US7982085B2 (en) * | 2006-02-03 | 2011-07-19 | Exxonmobil Chemical Patents Inc. | In-line process for generating comonomer |
| US8404915B2 (en) * | 2006-08-30 | 2013-03-26 | Exxonmobil Chemical Patents Inc. | Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations |
| WO2008052673A1 (en) * | 2006-10-30 | 2008-05-08 | Basell Polyolefine Gmbh | Process for the polymerization of olefins using catalyst systems based on an organic transition metal complex |
| KR100999592B1 (ko) * | 2007-02-15 | 2010-12-08 | 주식회사 엘지화학 | 새로운 시클로펜타디에닐 리간드를 갖는 4족 전이금속화합물, 이의 제조방법 및 이를 이용한 올레핀계 중합체의제조방법 |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| WO2009080216A1 (en) | 2007-12-19 | 2009-07-02 | Basell Polyolefine Gmbh | Mono-hydroindacenyl complexes |
| WO2010094450A1 (en) * | 2009-02-20 | 2010-08-26 | Basell Polyolefine Gmbh | Ethylene copolymers, catalyst system and process for preparing the same |
| US20120010377A1 (en) | 2009-03-30 | 2012-01-12 | Basell Polyolefine Gmbh | Catalyst System for the Polymerization of Alpha-Olefins |
| CN101704848B (zh) * | 2009-11-02 | 2012-09-05 | 中国科学院长春应用化学研究所 | 限制几何构型稀土烯丙基配合物及制法和在共轭双烯烃高顺1,4选择性聚合中的应用 |
| WO2011089017A1 (en) | 2010-01-22 | 2011-07-28 | Basell Polyolefine Gmbh | Ultra-high molecular weight polyethylene |
| US20110213107A1 (en) * | 2010-03-01 | 2011-09-01 | Sandor Nagy | Activation of monocyclopentadienyl group 6 complexes |
| CN103764613B (zh) | 2011-08-31 | 2017-02-15 | 昭和电工株式会社 | 2－烯基胺化合物的制造方法 |
| JP6000257B2 (ja) | 2011-08-31 | 2016-09-28 | 昭和電工株式会社 | ２−アルケニルアミン化合物の製造方法 |
| WO2014052642A1 (en) | 2012-09-28 | 2014-04-03 | Advanced Technology Materials, Inc. | Fluorine free tungsten ald/cvd process |
| WO2014060252A1 (en) | 2012-10-16 | 2014-04-24 | Teijin Aramid B.V. | Process for the synthesis of disentangled uhmw-pe using a cr or ti catalyst |
| WO2021011638A1 (en) * | 2019-07-18 | 2021-01-21 | Exxonmobil Chemical Patents Inc. | Silyl-bridged pyridylamide catalysts and methods thereof |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| US4015059A (en) | 1975-12-29 | 1977-03-29 | Union Carbide Corporation | Fused ring catalyst and ethylene polymerization process therewith |
| JPS5337644A (en) * | 1976-09-14 | 1978-04-06 | Mitsubishi Chem Ind Ltd | Transition metal complexes of 5,6-diaminocalicenes |
| CN1171794A (zh) | 1994-10-31 | 1998-01-28 | Dsm有限公司 | 用于烯烃聚合的催化剂组合物及方法 |
| DE19516801A1 (de) * | 1995-05-08 | 1996-11-14 | Hoechst Ag | Organometallverbindung |
| DE19710615A1 (de) | 1997-03-14 | 1998-09-17 | Studiengesellschaft Kohle Mbh | Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation |
| EP0915896A1 (de) * | 1996-07-30 | 1999-05-19 | Studiengesellschaft Kohle mbH | Organochrom-verbindungen enthaltende katalysatoren und ihre verwendung in der alkenpolymerisation |
| DE19630580A1 (de) | 1996-07-30 | 1998-02-05 | Studiengesellschaft Kohle Mbh | Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation |
| WO2001012687A1 (de) | 1999-08-13 | 2001-02-22 | Basell Polyolefine Gmbh | COPOLYMERE VON ETHYLEN MIT C3-C12 α-OLEFINEN |
| US6437161B1 (en) * | 1999-08-13 | 2002-08-20 | Basf Aktiengesellschaft | Monocyclopentadienyl complexes of chromium, molybdenum or tungsten |
| US6723675B1 (en) | 2000-05-25 | 2004-04-20 | Univation Technologies, Llc | Catalyst for the production of olefin polymers |
-
1999
- 1999-08-13 US US09/373,715 patent/US6437161B1/en not_active Expired - Lifetime
-
2000
- 2000-08-01 AT AT02026562T patent/ATE293631T1/de not_active IP Right Cessation
- 2000-08-01 JP JP2001517539A patent/JP4804687B2/ja not_active Expired - Fee Related
- 2000-08-01 DE DE50010129T patent/DE50010129D1/de not_active Expired - Lifetime
- 2000-08-01 ES ES02026562T patent/ES2240642T3/es not_active Expired - Lifetime
- 2000-08-01 ES ES00953135T patent/ES2192538T3/es not_active Expired - Lifetime
- 2000-08-01 CN CNB008143021A patent/CN100354287C/zh not_active Expired - Fee Related
- 2000-08-01 WO PCT/EP2000/007442 patent/WO2001012641A1/de not_active Ceased
- 2000-08-01 EP EP02026562A patent/EP1288219B1/de not_active Expired - Lifetime
- 2000-08-01 AU AU65691/00A patent/AU6569100A/en not_active Abandoned
- 2000-08-01 DE DE50001252T patent/DE50001252D1/de not_active Expired - Lifetime
- 2000-08-01 KR KR1020027001864A patent/KR100732108B1/ko not_active Expired - Fee Related
- 2000-08-01 AT AT00953135T patent/ATE232539T1/de not_active IP Right Cessation
- 2000-08-01 EP EP00953135A patent/EP1212333B1/de not_active Expired - Lifetime
- 2000-08-01 BR BRPI0013223-3A patent/BR0013223B1/pt not_active IP Right Cessation
-
2002
- 2002-06-11 US US10/166,130 patent/US6699948B2/en not_active Expired - Lifetime
- 2002-06-11 US US10/166,068 patent/US6838563B2/en not_active Expired - Lifetime
- 2002-06-11 US US10/166,140 patent/US6787498B2/en not_active Expired - Lifetime
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