JP2003105668A - Liquid softener composition - Google Patents

Abstract

(57) Abstract: (a) a cationic compound having a specific unsaturated aliphatic group, and (b) a fatty acid having a specific average iodine value and a ratio of cis-form of unsaturated group, and / or A liquid softener composition comprising an esterification reaction product of a fatty acid and a lower alcohol, and (c) a specific silicone. According to the present invention, a liquid softener composition comprising a soft base material which imparts excellent flexibility even when dried in the sun, exhibits an excellent antistatic effect, and has good biodegradability. Is obtained.

Description

DETAILED DESCRIPTION OF THE INVENTION [0001] BACKGROUND OF THE INVENTION 1. Field of the Invention
Suitable as a softening agent for textiles used in products
For the softener composition, more specifically, when dried in the sun
Gives excellent flexibility and excellent antistatic effect
In addition, liquid soft
It relates to a softener composition. [0002] 2. Description of the Related Art
To add flexibility to the textiles after washing,
Various cationizations to prevent generation
Liquid softening agent for textiles containing
Used. In addition, Japanese Patent Publication No. Hei 8-507766,
Table Hei 11-507419, Tokio Hei 11-507106
Publications include liquid softener compositions for textile products.
Long chain hydrocarbons containing unsaturated groups to maintain low viscosity
It discloses the use of elementary groups. [0003] However, carboxylic acids containing unsaturated hydrocarbon groups
Liquid fabric softener for textiles using thionic compounds
When the clothes treated with the product are dried under sunlight,
Flexibility and static electricity compared to drying inside
There is a problem in that the effect of preventing the occurrence of the phenomenon is reduced. [0004] Therefore, deterioration of flexibility is prevented,
To prevent the generation of air, the amount of cationic compound
Although some efforts have been made to increase the
The viscosity of the liquid softener composition for textiles
It is not preferable because problems such as addition occur. In addition, special table
In Japanese Patent Application Laid-Open No. 5-507073, at least 40%
Made from monounsaturated fatty acids containing a lance-type double bond
Although quaternized compounds are disclosed, the improvement is still insufficient.
You. Accordingly, cations containing unsaturated hydrocarbon groups
Liquid softener composition for textiles using conductive compounds
Poor flexibility even when treated clothes are dried in sunlight
For textile products that can suppress the formation of the product and show an excellent antistatic effect
Liquid softener composition is not yet available
It is. The present invention has been made in view of the above circumstances.
The main component is a cationic compound containing an unsaturated hydrocarbon group.
Liquid softener composition comprising
Excellent flexibility and static electricity when dried in sunlight
Ingredients that exhibit anti-preventive effects and have excellent viscosity stability during storage
Provide liquid softener composition consisting of soft base material with good resolvability
The purpose is to do. [0007] Means for Solving the Problems and Embodiments of the Invention
The inventors have diligently studied to achieve the above object.
As a result, (a) a specific cationic compound, (b) a specific fat
S of fatty acid and / or specific fatty acid and lower alcohol
Tellurization reaction product, (c) a specific silicone as an essential component
The above problem can be solved by combining
And completed the present invention. That is, the present invention provides (a) the following general formula (1)
With an alkanolamine represented by
An esterification reaction product with a tyl ester,
Fatty acid or fatty acid methyl ester has an average iodine value of 1
0 to 80, and the ratio of the cis-form of the unsaturated group is 50%.
One or more unsaturated fatty acids, unsaturated fatty acids and
Saturated fatty acids, one or more unsaturated fatty acid methyl esters or
Are unsaturated fatty acid methyl esters and saturated fatty acid methyl esters
Esterification reaction product which is a stele, the esterification reaction
Neutralizing the product and the esterification reaction product
One or more selected from quaternized reaction products
And a compound of [0009] Embedded image (However, in the above formula (1), R¹, R^Two, R^ThreeAt least
One is that there are few hydrogen atoms in the alkyl group having 2 to 6 carbon atoms.
Hydroxyal substituted with one hydroxyl group
It is a kill group. A, B and C each independently have 2 carbon atoms
O, p and q are the following oxyalkylene groups:
Each is independently an integer of 0 to 10. ) (B) an average iodine value is 10 to 80,
And at least one kind in which the ratio of cis isomer of unsaturated group is less than 50%
Above unsaturated fatty acid or a mixture of unsaturated fatty acid and saturated fatty acid
Synthetic fatty acids and / or the above unsaturated fatty acids or the above mixed fats
An esterification reaction product of a fatty acid and a lower alcohol,
(C) Silicon containing a polyoxyalkylene group in the molecule
Liquid softener set characterized by containing corn
Provide a product. Hereinafter, the present invention will be described in more detail.
The liquid softener composition of the present invention comprises (a) a specific cationic compound
(B) a specific fatty acid and / or a specific fatty acid and low
Esterification reaction product with secondary alcohol and (c) identification
Of silicone as an essential component. This
Here, as the cationic compound of the component (a) of the present invention,
Is an alkanolamine represented by the following general formula (1)
And a specific fatty acid or a specific fatty acid methyl ester
It is an esterification reaction product,
The tyl ester has a specific average iodine value and is
Unsaturated fatty acids in which the ratio of the cis-form of the saturated group is in a specific range,
Two or more types of unsaturation combined to have the above properties
Japanese fatty acids, one of which is combined to have the above properties
Or two or more unsaturated fatty acids and one or two or more saturated fatty acids
Fatty acids, unsaturated fatty acid methyl esters having the above properties
, Two or more types combined to have the above characteristics
Unsaturated fatty acid methyl ester, having the above properties
One or more unsaturated fatty acid methyls combined with
Esters and one or more saturated fatty acid methyl esters
(Hereinafter, in some cases, these are collectively referred to simply as
Fatty acid or fatty acid ester ”)
Reaction product, neutralized product of the esterification reaction product, and
Is the quaternization reaction product obtained by further quaternizing the tellurization reaction product?
One or more cationic compounds selected from
Are used in an appropriate combination. [0012] Embedded image In the above general formula (1), R¹, R^Two, R
^ThreeIs an alkyl group having 1 to 6, preferably 1 to 3 carbon atoms,
An aminoalkyl group or a hydroxyalkyl group;
¹, R^Two, R^ThreeAt least one has 2 to 6 carbon atoms, preferably
Or at least one hydrogen atom of 2 to 4 alkyl groups
A hydroxyalkyl group substituted with a hydroxyl group of
Specifically, for example, -CH_Three, -C_TwoH_FourOH, -C_Three
H₆NH_Two, -CH_TwoCH (OH) -CH_TwoOH etc.
It is. A, B and C each independently have 2 to 6 carbon atoms.
Preferable are 2 to 4 oxyalkylene groups, specifically
Is, for example, an oxyethylene group, an oxypropylene group,
Xybutylene groups and the like. Also, o, p, and q are
Show the average number of moles of each oxyalkylene group,
Each is independently 0 to 10, more preferably 0 to 10.
6, more preferably 0-4, most preferably 0-3
You. The oxyethylene unit represented by A, B or C
Position, oxypropylene unit or oxybutylene unit, etc.
May be arranged in blocks or randomly
No. An alkanol represented by the above general formula (1)
More specifically, as the amine, for example, triethanol
Amine, tripropanolamine, N-methyldiethanol
Amine, N-methyldiisopropanolamine, N
-Methyl-N- (2-methyl-2-hydroxyethyl)
Ethanolamine, N-methyl-N- (2-hydroxy
Ethyl) propanediamine, N, N-dimethyl, 2,3
-Dihydroxypropylamine and the like;
Among them, particularly preferred alkanolamines are triethano
Amine, N-methyldiethanolamine, N-methyl
Ru-N- (2-hydroxyethyl) propanediamine,
N, N-dimethyl-2,3-dihydroxypropylamido
Etc. In addition, the final composition (liquid softener composition)
To improve liquid properties such as transparency and viscosity control,
Ethylene oxide, propylene
Alkylene oxides such as butoxide and butylene oxide
Sides may be used alone or in combination of two or more.
It is preferred to use added alkanolamines. A
As shown by the above formula (1), alkylene oxide is
Derived from an oxyalkylene group having from 2 to 6 carbon atoms,
Those having 2 to 4 are more preferable. The above alkanolamine
Can be used alone or as a mixture. The component (a) of the present invention comprises the alkanol
Esters of amines with fatty acids or fatty acid methyl esters
It is an esterification reaction product produced by an esterification reaction.
Here, it is used when producing the above-mentioned esterification reaction product.
Examples of the fatty acid or fatty acid methyl ester
Has a specific average iodine value, and
Unsaturated fatty acids whose body ratio is in a specific range,
Two or more unsaturated fatty acids combined to have
One or more types combined to have the above properties
Unsaturated fatty acids and one or more saturated fatty acids,
Unsaturated fatty acid methyl ester having the above-mentioned properties,
Of two or more unsaturated fatty acids combined to have a property
Methyl ester, combined to have the above properties
One or more unsaturated fatty acid methyl esters and 1
Species or two or more kinds of saturated fatty acid methyl esters are used
You. Here, the average iodine of the above fatty acid or fatty acid ester
The prime value is 10 to 80, preferably 20 to 70, more preferably
Specifically, it is 30 to 60. In addition, fatty acids or fatty acid methyl
Ratio of cis-isomer in unsaturated group of
Fatty acid or unsaturated fatty acid methyl
Is less than 50%).
And preferably 20% or more and less than 50%, more preferably
30% or more and less than 50%. Average iodine value too small
If the ratio of cis isomers in unsaturated groups is too large,
The desired effect cannot be obtained. In the present invention, the iodine value is determined by
Established Japan Oil Chemistry Association Standard Oil and Fat Analysis Test Method (199
0) Based on 2.4.5, the cis-form ratio was determined by4
0, 109 (1991).¹³Measured by C-NMR method
Values shown. The raw material fatty acid or raw material for the above esterification reaction
Unsaturated fatty acids used as fatty acid methyl esters,
Saturated fatty acid, unsaturated fatty acid methyl ester, saturated fatty acid
As long as the methyl ester has the above properties,
Although the type is not particularly limited, fatty acids and fats
Fatty acid methyl esters having 16 to 24 carbon atoms are preferred.
New However, even if those having 10 to 14 carbon atoms are included
Good. In this case, the ratio of those having 16 to 18 carbon atoms is
80% by mass or more from the viewpoint of imparting flexibility to fibers and clothing
It is preferable that Specifically, in the case of the present invention, the raw material fat
As the acid or the raw material fatty acid methyl ester, animal and vegetable fats and oils
Are more preferably derived from, more specifically,
For example, tallow, palm oil, palm kernel oil, soybean oil, lard,
Derived from sunflower oil, olive oil, safflower oil, etc.
Fatty acid or fatty acid methyl ester. Ma
Lauric acid, myristic acid, palmitic acid, stear
Phosphoric acid, palmito oleic acid, oleic acid, elaidin
10 carbon atoms such as acid, linoleic acid, linolenic acid, erucic acid
To 24 saturated or unsaturated fatty acids, methyl laurate
Ester, myristic acid methyl ester, palmitin
Acid methyl ester, stearic acid methyl ester, pal
Methyl oleate, methyl oleate
10 to 2 carbon atoms such as ter and elaidic acid methyl ester
4 saturated or unsaturated fatty acid methyl esters, etc.
By one kind alone or by appropriately mixing two or more kinds,
The above raw material fatty acid having the desired cis-form ratio and iodine value or
Can prepare a raw material fatty acid methyl ester.
It is also possible to use hydrogenated or partially hydrogenated versions of the above compounds.
Can be. In addition, the raw material fatty acid, raw material fatty acid methyl
The ratio of cis to trans isomers in esters is
Reaction conditions for hydrogenation of Japanese fatty acids and unsaturated fatty acid esters
Or by heat treatment in the presence of a catalyst.
For more details, see JP-A-2001-181244,
2001-181678, JP-A-2001-181167
Utilizing the method described in the detailed description of the invention in Japanese Patent Publication No. 2
Can be Este for producing component (a) of the present invention
The reaction can be carried out by a generally known method.
You. The alkanolamine during the esterification reaction,
Moles of the above raw material fatty acid or raw material fatty acid methyl ester
Although the ratio is not particularly limited, the softness of the final composition is not limited.
From the viewpoint of imparting softness, 1.0 to 2.5 is preferable,
Manufacturability with higher flexibility and reduced viscosity increase during manufacturing
In order to improve the range, the range of 1.3 to 2.0 is preferable.
And more preferably 1.5 to 1.9, most preferably 1.
It is in the range of 5-1.8. The reaction temperature is between 170.degree.
It is preferable that the reaction time is 6 to 10 hours.
It is. If the reaction temperature is too high, the aroma of the reaction product deteriorates
However, the fragrance of the composition may deteriorate.
You. At this time, butylated hydroxytoluene and
Antioxidants such as droxyethane diphosphonic acid,
Before the esterification reaction of one or more of the reducing agent and the reducing agent,
During the reaction, if added to at least one step after the reaction,
Aroma deterioration of products and compositions can be suppressed. one
If the reaction temperature is too low or the reaction time is too short,
Good flexibility when made into a composition
It may not be possible. Efficient esterification reaction
KOH, NaOH, Mg
It is preferable to use a solid catalyst such as O and silica. Incidentally, the esterification reaction of the component (a) of the present invention
Reaction products include two or more fatty acids or fatty acid methyl
When an ester is used as a raw material, as described above,
Cis-form of an unsaturated group having an average iodine value of 10 to 80 and an unsaturated group
The above raw material fat mixed so that the ratio of the raw material is less than 50%
Manufactured using acid or raw fatty acid methyl ester
It is preferred, but do not mix these, each
Manufactured as raw fatty acid or raw fatty acid methyl ester
The two or more reaction products are used as raw material fatty acids or raw material fats.
Average iodine value calculated from the sum of acid methyl esters
And the ratio of cis isomers of unsaturated groups is within the above range.
The mixture may also be obtained by esterification reaction of the component (a) of the present invention.
Contained in the reaction product. The component (a) of the present invention includes
Neutralized product of the reaction product can also be used.
Use any inorganic or organic acid as neutralized material
be able to. Such acids include, for example, hydrochloric acid, sulfuric acid.
Acid, phosphoric acid, dialkyl sulfate, alkyl sulfate, dialky
Carbonic acid, benzoic acid, paratoluenesulfonic acid, acetic acid,
Enic acid, malic acid, succinic acid, lactic acid, glycolic acid, etc.
Carboxylic acids, acrylic acid oligomers and polymers,
Droxyethane diphosphonic acid, tripolyphosphoric acid, phytic
Acid, ethylenediaminetetraacetic acid or the like can be used,
Of these, hydrochloric acid, sulfuric acid, and methyl sulfate are particularly preferred.
No. Further, the component (a) of the present invention includes
A quaternization reaction product obtained by further quaternizing the esterification reaction product
The quaternization reaction is generally known.
Peralkylation method to bond alkyl group to existing nitrogen atom
Can be performed. As the quaternizing agent, for example,
Alkyl sulfate, dialkyl carbonate, alkyl halide, etc.
Can be used. More specifically, for example, dimethyl
Sulfuric acid, diethyl sulfate, dimethyl carbonate, benzyl chloride, iodine
Methyl chloride, methyl chloride, ethyl chloride, butyl bromide, etc.
Among these, dimethyl sulfate and methyl chloride
More preferred. Also uses epichlorohydrin, etc.
can do. In the present invention, in the above quaternization reaction,
A molar ratio of the esterification reaction product to the quaternizing agent,
There are no particular restrictions on the reaction conditions and the like.
It can be appropriately selected depending on the type of the agent, for example,
In the case of quaternization with dimethyl sulfate, the above esterification reaction
0.9 to 0.99 times the mole of the reaction product
Preferably, the reaction temperature at that time is 80 ° C to 11 ° C.
0 ° C. is preferred. When quaternized with methyl chloride
Is 1: 1 with respect to the number of moles of the esterification reaction product.
It is preferably used in an amount of 0 to 1.2 times the molar amount.
The reaction temperature is preferably from 80C to 110C. The present invention
Reaction and quaternization reaction described in JP-A-2
001-181244, 2001-181678
JP-A-6-228063, JP-A-2001-181
672, the invention of JP-A-2001-181973.
The method described in the detailed description can also be used. The above-mentioned esterification reaction as component (a)
If a neutralized product is used, some non-neutralized
included. Depending on the degree of neutralization, the content of non-neutralized substances differs
You. The degree of neutralization is high from the viewpoint of adsorption to clothing.
The neutralized product is preferably 50% or more.
Good. The quaternization reaction produced as the component (a)
When using a product, the amount of quaternizing agent, reaction temperature, reaction
The amount of quaternized compounds varies depending on the time, presence or absence of reaction solvent, and type.
Become The esterification reaction product is completely quaternized.
Is almost impossible, and the esterification reaction products and 4
Includes neutralized substances generated in the reaction process of the grading reaction
You. During quaternization, the starting alkanolamine is
In the case of ethanolamine, the quaternary esterification reaction product
As the agent, dimethyl sulfate is preferable, and its quaternization ratio
Can be 60% or more. Also, the raw material alkano
N-methyldiethanolamine, N-methylamine
Cyl-N- (2-hydroxyethyl) propanediami
, N, N, -dimethyl-2,3-dihydroxypropyl
Luamine, triethanolamine
Quaternization is easier. Of the esterification reaction product
When methyl chloride is used as the quaternizing agent, its quaternary
The conversion can be 80% or more. In the above (a), alkanolamides
Alkanolamine methyl sulfate, hydrochloride, etc.
Neutralized products, quaternized alkanolamines, etc.
Compounds from the raw materials used in the production. like this
The compound derived from the raw material of the component (a) is usually
0 to 20% is contained at the time of minute generation. In the present invention, the above
Alkanolamine, its neutralized product, its quaternized product
By containing at least one in the composition at 0.1% or more.
Of the clothing caused by chlorine in tap water during soft treatment
The effect of preventing fading is exhibited. Further, the component (a)
Reaction products with long chain groups also exhibit the above-mentioned fading prevention effect
I do. Therefore, when the above compound is used for producing the above component (a),
0.1% or more.
The present invention also relates to compositions having
include. The cationic compound of the above component (a)
(The above esterification reaction product, its neutralized product, its quaternization
Long-chain group (10-24 carbon atoms, provided that polio
(Excluding the xyalkylene chain portion) is the number of raw materials
Alkanolamine and the above fatty acids or fatty acid methyl esters
It is determined by the molar ratio with Ter. High flexibility performance
For this purpose, the number of long-chain groups contained in one molecule is two or
It is preferable to increase the proportion of three or more
Their proportion in the on-compounds is preferably 50
% By mass or more, more preferably 65% by mass or more. However
From the viewpoint of antiseptic, bactericidal, and antibacterial activities.
To increase the proportion of one long chain group
preferable. Control the number of long chain groups in cationic compounds
And the composition enhancing the above effects, and the composition claimed.
Can be manufactured. Usually the length of the cationic compound
The number of chain groups is 1 to 2 mixtures or 1 to 3 mixtures
Used. In recent years, close-ups have been made due to environmental issues.
With regard to the biodegradability, the above (a) component of the present invention
The component is a flexible substrate that has been used in the past.
Octadecyl dimethyl ammonium chloride, diole
Il dimethyl ammonium chloride, hardened beef tallow dimethi
Luammonium chloride, partially cured palm oleyl di
Dilong chain dimethyl alcohol such as methylammonium chloride
Nmmonium compound, mono-long chain trimethylammonium
It is superior to compounds. In the liquid softener composition of the present invention,
(A) The amount of the component is determined by drying the clothes under sunlight.
Even with excellent flexibility and antistatic effect, biodegradable
To provide a liquid softener composition comprising a good soft base material
From the viewpoint, the liquid softener composition of the present invention contains 3 to 5
It is preferable to mix 0 mass%, more preferably 3 to
It is 30% by mass, more preferably 3 to 25% by mass. Distribution
If the combined amount is too small, the above-mentioned effects aimed at by the present invention are obtained.
If it is too much, more compounding
May not be economical, and may be uneconomical.
You. It should be noted that reaction products produced from different raw materials
The effect is not adversely affected, and two or more reaction products are mixed.
Combinations can also be used. The above component (a) is used during the production of the composition and during transportation.
60% by mass due to economical benefits of handling, storage, and time
A premix with the above concentration is preferred
No. More preferably, it is 70 to 95% by mass. This place
Ethanol, isopropyl alcohol, ethylene glycol
Recall, hexylene glycol, glycerin, etc.
To a melting point of 60 ° C or lower by adding alcohol, water, etc.
Is preferred. In addition, in order to suppress aroma deterioration, it will be described later.
Flavor stabilizers such as chelating agents, antioxidants and reducing agents
It is preferred to add. The component (b) of the present invention comprises a specific fatty acid and
/ Or esterification reaction between the fatty acid and lower alcohol
It is an adult. Here, the fatty acid of the component (b) is
Like the component (a), it has a specific average iodine value, and
Fats in which the ratio of cis isomers of one unsaturated group is within a specific range
Acids, two or more types combined to have the above properties
Unsaturated fatty acids, combined to have the above properties
One or more unsaturated fatty acids and one or two or more
Is a saturated fatty acid. The average iodine value of the above fatty acids is 1
0-80, preferably 20-70, more preferably 30
~ 60. In addition, the cis form in the unsaturated group of the above fatty acid
Is less than 50%, preferably 20% to 50%.
%, More preferably 30% or more and less than 50%.
Average iodine value is too small or ratio of cis isomer in unsaturated group
If the rate is too large, the effect intended by the present invention cannot be obtained.
No. Estes with the above fatty acids and lower alcohols
Fatty acids that are the raw materials for the oxidation reaction products have carbon numbers
Those having 16 to 24 carbon atoms are preferred, but those having 10 to 14 carbon atoms are also preferred.
May be included. At that time, the carbon number of 16-18
What is 80% by mass or more in all fatty acids from the viewpoint of flexibility
It is preferable that Also, the above-mentioned lower alcohol charcoal
Compounds having a prime number of 1 to 6, preferably 1 to 5 are preferred.
Moreover, a monohydric alcohol or a polyhydric alcohol may be used.
Specifically, methanol, ethanol, ethylene glycol
, Glycerin, isopropyl alcohol, propa
And pentaerythritol. Specifically, the above fatty acid or the above fatty acid and
Esterification reaction products with lower alcohols include
Those derived from vegetable fats and oils are preferred. More specifically
Is tallow, palm oil, palm kernel oil, soybean oil, lard, castor
Derived from wax oil, olive oil, safflower oil, etc.
Fatty acids and / or the fatty acids
Sterilization reaction products are preferred. Also, lauric acid,
Myristic acid, palmitic acid, stearic acid, palmito
Oleic acid, oleic acid, elaidic acid, linoleic acid,
C12-24 saturated fats such as linolenic acid and erucic acid
Acid or unsaturated fatty acid, lauric acid methyl ester, millimeter
Succinic acid methyl ester, methyl palmitate
, Stearic acid methyl ester, palmito oleic acid
Methyl ester, Oleic acid methyl ester, Elage
Acid methyl ester, stearic acid ethyl ester,
Ethyl oleate, methyl erucate, etc.
A saturated fatty acid or unsaturated fat having 12 to 24 carbon atoms
Esterification reaction products with rucol, tallow-derived fatty acids, etc.
Of mono- and diesters of ethylene glycol and ethylene glycol
Products, things such as glycerin and fatty acids derived from palm oil,
Mix a mixture of diesters, triesters, etc.
Having the desired cis-form ratio and iodine value
Esterification of the fatty acid or the fatty acid with a lower alcohol
A reaction product can be prepared. In addition, the above unsaturated
Hydrogenated or partially hydrogenated group-containing compounds can also be used.
The method described in the above publication is used in the same manner as the component (a).
You can also. The fatty acid and lower alcohol of the above component (b)
The production of the esterification reaction product with
It can be performed by the esterification method described in the production.
You. The esterification reaction product of the component (b) of the present invention
As the component (a), two or more fatty acids
When using as a raw material, these are used for the above average iodine value.
And a mixture of unsaturated groups in a cis ratio.
Even if used as raw material fatty acids, do not mix them
Thus, two or more types of each produced as a raw fatty acid
The average amount of iodine calculated from the sum of
Such that the prime value and the cis ratio of the unsaturated group are within the above ranges.
They may be mixed in a ratio. In the liquid softener composition of the present invention,
The amount of the component (b) is based on the liquid softener composition of the present invention.
And preferably 0.3 to 30% by mass, more preferably
0.5 to 20% by mass, more preferably 1 to 20% by mass
Are combined. Even if the amount is too small or too large, the present invention
May not be able to achieve the desired effect. Also,
Viewpoint of dispersion stability of composition and adsorptivity of composition to fiber
Therefore, the amount of the component (a) is determined by the distribution of the component (b).
It is preferred that it is larger than the combined amount. The component (c) of the present invention comprises
It is a silicone containing a silalkylene group. Polio
The alkylene group is directly or alkylated on the Si atom in the main chain.
Pendant type, which is suspended through
Some are directly bonded to Si atoms and are contained in the main chain
Or one end and / or both ends of the main chain
Etc. are included. Contains polyoxyalkylene group in the molecule
Specifically, polyether-modified silicone
Silicone, aminopolyether modified silicone, click
On-polyether-modified silicone, amide polyate
Modified silicone, carboxy polyether modified silicone
, Epoxy polyether-modified silicone, alkyl
Polyether-modified silicone, alkyl aralkyl poly
Examples include ether-modified silicone. Such a change
Shin-Etsu Chemical Co., Ltd. KF35
1A, 352A, 615A, 945, 6008A etc.
KF series, Polon SR-Conc, MF-1
3 and other Polon series, Toray Dow Corning
SF such as SF8421 and 8419 manufactured by Silicone Co., Ltd.
Series, SH3746, 3771, 3772, 377
3, 3775, 3775C, 3775M, 8410, etc.
SH series, BY16-837, 893, 878,
891, 874, 845, etc.
Nikka Co., Ltd. L-720, FZ-722, 2123,
L-7001, FZ-2104, 2161, 2164,
SILWET series such as 2171, F1-009-
01, -02, 09, -13, -54, FZ-2222
ABN SILWET series, F2-019-
Hydrophilic aminosilicone such as 01, -02 and -03
TSF4440, TS manufactured by GE Toshiba Silicone Co., Ltd.
Polyoxyal with TSF series such as F4446
Use products consisting of silicones containing modified molybdenum groups
be able to. The silicone of the component (c) of the present invention
Can be used in the form of an oil or an emulsion. Particularly, the component (c) is represented by the following general formula (2)
Is a polyoxyalkylene-modified silicone represented by
In some cases, it has a better antistatic effect and
Scattered pollen, dust, and emissions from diesel vehicles
It also prevents the adsorption of air pollutants such as quality. In addition, the fiber
Improves slipperiness and maintains firmness and stiffness without getting worn on clothing.
Reduce wrinkles formed by holding and washing processes, fading clothing
Prevents losing shape and shape, prevents yellowing, and gives clothes good flexibility
It has the effect of giving. The above effects are also the effects of the present invention.
Included in the fruit. [0040] Embedded image (However, in the above formula (2), -Z¹, -Z
^TwoIs independently -R, -OR, -OH, -O-
XR and -OXH. R is the same or different
All of which may be saturated or unsaturated linear or branched
Is a hydrocarbon group having 1 to 4 carbon atoms;
It is a alkylene group. -Y is -R^Four-OXR^FiveOr-
O-X-R^FiveAnd R^FourIs saturated with 1 to 4 carbon atoms or
An unsaturated linear or branched hydrocarbon group,^FiveIs hydrogen
A saturated or unsaturated straight-chain having 1 to 4 carbon atoms or
It is a branched hydrocarbon group. L is 0 to 50, M is 1 to 10
00 and N are 10 to 10000. However, polyoxy
Mass ratio of polyoxyethylene chain in alkylene group X
If not, 10% or more and 60% or less based on the mass of the entire molecule
Is full). In the above general formula (2), -Z¹, -Z^Two
Are preferably each independently -R or -OH
No. R represents a methyl group, an ethyl group, a propyl group, a butyl group
And the like, and among them, a methyl group is preferred.
Good. R^FourIs methylene, ethylene, propylene
Group, a saturated hydrocarbon group such as a butylene group is preferable.
Is preferably a propylene group. R^FiveIs a hydrocarbon group
In the case, methyl group, ethyl group, propyl group, butyl group
Any saturated hydrocarbon groups are preferred. Particularly preferred R ^FiveIs
It is a hydrogen atom or a methyl group. In the above general formula (2), X is
Represents a lioxyalkylene group. X is polyoxyethylene
Group, polyoxypropylene group, polyoxybutylene group
Or an oxyethylene unit,
Cypropylene units or oxybutylene units, etc.
Locked or randomly arranged
No. However, the mass ratio of the polyoxyethylene chain portion in X
Is 10% or more and less than 60% based on the mass of the whole molecule
And preferably 15% to 45%, more preferably
Or 20% to 35%. Also, polyoxyalkylene
Of the polyoxyethylene chain portion based on the mass of the
The mass ratio is preferably from 50% to 100%,
More preferably, it is 5 to 100%. Further, in the general formula (2), L, M
And N each represent the average value of the number of each repeating unit;
L is 0 to 50, preferably 0 to 10, and more preferably 0.
And M is 1 to 1000, preferably 1 to 30
0, more preferably 1 to 50, and N is 10 to 100.
00, preferably 20-3000, more preferably 20
~ 500. The variable represented by the general formula (2)
Functional silicone is composed of repeating units arranged in blocks.
Even if it has a block copolymer structure
Well, or each repeat unit is randomly arranged
Having a random copolymer structure.
No. The modified silicone represented by the general formula (2)
The method of manufacturing the component is not particularly limited. For example,
Silicone Handbook (edited by Kunio Ito, Nikkan Kogyo Shimbun)
Co., Ltd., first edition first edition issued on August 31, 1990), revised new edition
Recon-Its Basics and Applications-(written by Kunio Ito, Wood Co., Ltd.)
DeBook, Revised September 15, 1997, Second Edition, Third Edition
Line), Silicone Material Handbook (edited and published by Toray)
・ Dow Corning Silicone Co., Ltd., published 1993
(August), new silicone and its application (edited by Toshiba Silicon)
Co., Ltd., Tosyl Techno Service Co., Ltd.
Shiba Silicone Co., Ltd., issued on April 1, 1994)
What was manufactured by the method of description can be used. The polyoxy component (c) of the present invention
Silicones having a silalkylene group have a Si-H group.
Silicone and polyoxyalkylene or carbon-carbon
Addition with polyoxyalkylene having a double bond at the terminal
It can be produced by a reaction. During production,
Polyalkylene or poly-carbon double bond
Lioxyalkylene, 4- to hexamer cyclic silicone, etc.
Unreacted raw material, cyclic silicone, is about 8 to 50 mer
What has become annular remains or forms in the product. So
These compounds are based on raw material charge, manufacturing temperature,
Although the amount varies depending on the production method such as ping time, the present invention
When producing the above-mentioned component (c), the content of
It may be contained up to 0%. Ethanol, isop
Solvents that can be used in the production of propyl alcohol, etc.
Effect of the present invention even if a trace amount of a catalyst
Does not affect The weight average molecule of the component (c) used in the present invention
The amount is preferably in the range of 1,000 to 2,000,000
No. More preferably 2,000 to 300,000, most
Preferably it is 3,000-50,000. Also book
The kinematic viscosity at 25 ° C. of the component (c) used in the present invention is
100 to 100,000mm due to handling^Two・ S^{- 1}
And more preferably 100 to 10,000.
0mm^Two・ S^-1It is. Also, silicone is oil
Or emulsified with a surfactant, etc.
Can be used. The above-mentioned liquid softener composition of the present invention
The compounding amount of the silicone of the component (c) is determined according to the liquid flexibility of the present invention.
0.1 to 20% by mass of the agent composition is suitable.
More preferably 0.3 to 10% by mass, most preferably
Is 0.5 to 7% by mass. If the amount is too small,
If the effect of the present invention is difficult to obtain even if it is too long
There is. In addition, silicon with different denaturation degree and denaturation type
The effect is not adversely affected by the combination of Further, the liquid softener composition of the present invention contains
In addition to the components (a) to (c), the effects of the present invention are not hindered.
Within a suitable range, viscosity stability, performance improvement, function addition, productivity
Above, the following changes for the purpose of appearance change, appearance improvement, fragrance improvement, etc.
Compounded and usually incorporated into fabric softener compositions
Known components can be blended as component (d).
You. For the purpose of improving dispersibility in the composition,
Add alkylene oxide to coal or amine or fatty acid
Added non-ionic surfactants can be used. carbon
The chain portion may be branched or straight, and
May be. Further, the carbon chains may have a distribution. Carbon chain
May be a short chain or a long chain, but is preferably 6 to 20,
More preferably, it is 8-18. When the carbon chain is straight
Preferably have 6 to 14 carbon atoms, more preferably
From 8 to 12, most preferably from 8 to 10. Carbon chain
When is a branched chain, those having 6 to 17 carbon atoms are preferred.
Preferably, more preferably 9-17, most preferably 13
It is. [0051] The raw materials used were Exxon Chemical Co., Ltd.
Searl, Lutensol series, EM manufactured by BASF
ULAN series, Kyowa Hakko Kogyo Co., Ltd. Oxocall C
13. Genapol series manufactured by Hoechst AG
(C series, T series), Shell Doba
Nol series etc. can be used. Also,
1 in the case of an alkylene oxide adduct of alcohol
Primary or secondary alcohol can be used, but primary
The use of alcohol provides better dispersibility of the composition.
You. The alcohol having 13 carbon atoms is produced from dodecene.
Butylene is used as the starting material
Len is fine. When the carbon chain contains an unsaturated group, the carbon number
Is preferably 18, and is a stereoisomer structure of an unsaturated group.
The structure can be either cis or trans, or a mixture of both.
But the ratio of cis / trans is preferably 2
It is preferably 5/75 to 100/0 (mass ratio).
No. As the alkylene oxide, ethylene oxide
(EO) is preferred, but together with ethylene oxide
Propylene oxide (PO) or butylene oxide
(BO) may be added. Average number of moles of EO added
Is 10 to 100 mol, preferably 20 to 8
It is 0 mol, particularly preferably 30 to 60 mol. Also,
The average number of moles of PO or BO added with EO and
Is 1 to 10, preferably 1 to 5 mol.
At this time, after adding EO, add PO or BO
Or after adding PO or BO, then adding EO
It does not matter. More specific examples of the above nonionic surfactant
Typically, an average EO9PO1 adduct of nonyl alcohol,
An average EO 40 mole adduct of primary isononyl alcohol,
An average EO 20 mole adduct of primary isodecyl alcohol,
An average EO 20 mole adduct of lauryl alcohol, primary
An average EO 60 mole adduct of sohexadecyl alcohol,
Average EO 40 mole addition of primary isotridecyl alcohol
Products, average EO60 adduct of tallow alkylamine, tallow
Average EO60 adduct of alkylamine,
With an average EO50 adduct and an average EO of 20 mol of lauric acid
Additives and the like. Such nonionic surfactant
Emarex series of Nippon Emulsion Co., Ltd.
, Sanyo Chemical Co., Ltd.'s Emulmin Series, Rio
NDA's TDA series, Esomine series,
Softanols such as Softanol 300 manufactured by Nippon Shokubai Co., Ltd.
Series, Lutensol series, BASF E
The MULAN series or the like can be used. Also,
The above compounds include alcohols, amines, poly
Ethylene glycol, polypropylene glycol, poly
Polyalkylene glycol such as butylene glycol
Are slightly contained as unreacted components. They alone
Can also be used as a mixture. Further, the raw material of the nonionic surfactant is
0 to 10% by weight of alcohol contained in the nonionic surfactant
You can go out. The nonionic compounding amount is 0 to 10 mass
%, More preferably 0.1 to 5% by mass, particularly
Preferably it is 0.3 to 3% by mass. As the amphoteric surfactant, a long chain group (carbon number)
10 to 24 are preferable, and more preferably 14 to 22)
Sulfobetaine or carboxybetai having one or two
Can be used. Long chain groups are hydrocarbon groups.
Ester group, amide group, ether group
May be included. In addition, the saturated type of hydrocarbon group /
Ratio of unsaturated type, carbon chain length distribution, cis-form / unsaturated unsaturated group
The lance ratio is not particularly limited. Component (a) described above
Raw material fatty acid, fatty acid methyl ester or
Fatty acids and fatty acid short-chain d
It may be a hydrocarbon group derived from stel. Specifically, for example, N, N-diacyloxy
Siethyl-N-methylammonioethyl sulfate and
Betaines such as ethyl carboxylate, N-acyl
Oxyethyl-N-hydroxyethyl-N-methylan
Moniobetaines, N-acylamidopropyl-N, N
-Dimethylammoniobetaines, N-acylamidop
Ropyl-N, N'-dimethyl-N'-β-hydroxyp
Ropyrammonio betaine and the like can be used. Also long chain
The groups are of one-chain type and two-chain type.
Can be used. In addition, the above compounds include
Compounds whose elemental atoms are not quaternized, alkano as raw material
Auramines, neutralized products thereof and / or quaternized products thereof.
Contains some minobetaine. However, they alone,
Two or more kinds may be blended. The above compound in the composition
Can be blended in an amount of 0 to 10% by mass, preferably 0 to 10% by mass.
The content is 5% by mass, more preferably 0 to 3% by mass. As liquid hydrocarbons, liquid paraffin
And the like, which is liquid at room temperature,
10 to 10% by mass, more preferably 0 to 3% by mass
Can be. Further, a wax or polyurethane can be used
Used as a control agent for improving water absorption and release
be able to. Alkanes, alkes
Hydrocarbons or animal and plant-based waxes selected from
Use of one or more of a mixture of substances
Can be. When the solid fat is an alkane, the carbon number
Is more preferably 22 or more.
Sun, Trichosan, Tetracosan, Pentacosan, Heki
Sacosan, heptacosan, octacosan, nonacosan,
Triacontan, Hentriacontan, Dotriaconta
, Tritriacontan, tetratriacontan, pen
Tatriacontan, hexatriacontan, heptatri
Acontan, Octatoriacontan, Nonatriaconta
And the like. In addition, the alkane has a hydrocarbon
Like linear, branched, or polyalkylene
They may be connected three-dimensionally. When the solid fat or oil is an alkene, carbon
Most preferably, the number is 24 or more.
-Tetracosene, 1-hexacocene, 1-octacose
1-triacocene, 1-dotriaconten, 1-te
Tratria content, 1-hexatria content, 1-
Octatria content, 1-tetra content and the like
Can be When the solid fat is petroleum wax,
Paraffin wax with a melting point of 40 ° C or higher, micro
Most preferred are crystallin wax and petrolatum,
Specific examples of commercially available petroleum waxes include HNP
-3, HNP-12, HNP-14G, SP-016
0, SP-1035, Hi-Mic-1045, Hi-
Mic-2045, JP-1500, JP-105, J
P-131T (all manufactured by Nippon Seiro Co., Ltd.)
No. When the solid fat is an animal or vegetable wax
If specifically, candelilla wax, carnauba
Box, hydrogenated jojoba wax, wood wax, beeswax, whale wax
And c. The above compound is in the form of an emulsion
It can also be used in a state. Specifically, on the other hand
High-melting point polyethylene emulsion eponou manufactured by Kogyo Co., Ltd.
900 and the same polyurethane emulsion UPM-212
HN and Ciba Specialty Chemicals Co., Ltd. Silicon
Such as TINOTEXFSA, which is an emulsion containing
Can be used. The above compounds are preferred in the composition.
Or 0 to 20% by mass, more preferable
0 to 10% by mass, more preferably 0 to 5% by mass.
is there. Further, an eye for controlling the viscosity of the composition
Inorganic or organic water-soluble salts can be used.
Specifically, sodium chloride, potassium chloride, calcium chloride
Cium, magnesium chloride, aluminum chloride, sodium sulfate
Thorium, sodium sulfite, sodium hydrogen sulfate, sulfur
Magnesium acid, potassium sulfate, sodium nitrate, nitric acid
Magnesium, sodium p-toluenesulfonate,
Sodium recholate, sodium acetate, potassium acetate
System, sodium glycolate, sodium acetate, potassium acetate
Lium, potassium glycolate, sodium lactate, etc.
No. Of these, calcium chloride is preferred.
, Magnesium chloride, sodium sulfate, magnesium sulfate
It is sium. The compounding amount is preferably 0 to 3% by mass.
More preferably 0 to 2% by mass, more preferably 0 to 1% by mass
%. Salts can be added at any stage during the manufacture of the composition.
I do not care. However, when the concentration of the component (a) in the composition is high
In order to keep the viscosity low, increase the salt concentration twice
It is preferable to add them separately. Particularly preferably,
0 to 0.5% by mass during production of the composition, 0 to 0.5% after production
% By mass. After production from the amount added during production
By increasing the amount of added, the viscosity of the composition is reduced.
Can be made. Improvement in handling properties for the production of the composition
In order to stabilize the composition at low temperatures and to make the composition transparent,
10 to 10 alcohols can be blended. Also,
In order to improve the handleability of component (a)
Used as a reaction solvent for the component (a) or a slurry solvent
May be carried in during the manufacture of the composition
There is. Also, carry-on as unreacted raw material for component (b)
In some cases, it will be lost. Alcohol having 1 to 10 carbon atoms
Specific examples of ethanol, isopropanol,
Propylene glycol, ethylene glycol, diethylene
Glycol, dipropylene glycol, 1,2 pentane
Diol, hexylene glycol, trimethylpentane
Diol, benzyl alcohol, diethylene glycol
Monobutyl ether, glycerin, 2-phenoxyeta
And 2-phenylethanol. One or more
Can be used in combination. In the composition
Is usually contained in an amount of 0 to 15% by mass. Low grade alco
For sodium benzoate, 8-acetyl
With denaturants such as sucrose, brucine, orange and citrus
Those which have been modified can also be used. For the purpose of making the composition transparent, use a method disclosed in
Mono-O described in 2000-505155
, C6 diol, C7 diol, octane diol
, Butanediol derivative, trimethylpentanedio
Isomers, ethylmethylpentanediol isomers,
Ropyrpentanediol isomer, dimethylhexanedione
Isomer, ethylhexanediol isomer, methyl
Butanediol isomer, octanediol isomer, nona
Diol isomer, alkyl glyceryl ether, di
(Hydroxyalkyl) ether, arylglyceryl
Ether, aromatic glyceryl ether, alicyclic diol
And derivatives, C3-C7 diol alkoxylated derivatives,
Use of aromatic diols and unsaturated diols
Can be. Particularly preferred main solvents are 1,2-hexane
Diol or 2-ethyl-1,3-hexanediol
Hexanediol and 2,2,4-trimethyl-
Pentanediol such as 1,3-pentanediol
Can be used. The amount used in the composition is preferably 0
~ 40%, more preferably 10 ~ 35%, even more preferably
Is 12 to 25%. Further, a chelating agent, an antioxidant and a reducing agent are used.
By blending, the component (a) and the soft finish for textile products
It can improve the stability of the fragrance and color length of the lift composition.
it can. Specifically, hydroxyethanediphosphonic acid
(Lion Corporation Ferriox CY-115), ethi
Diamine amine tetraphosphonic acid (Monsanto Dequ
est2041), 1-hydroxyethylidene-1,1
-Diphosphonic acid (etidronic acid: quest 201
0), D-2000, D-2066, etc.
Acid chelating agent, ethylenediaminetetraacetic acid, nitrilot
Acetic acid, citric acid, captocatechuic acid, tripolyline
Acid, ethylenediamine disuccinic acid, methyl glycine divinegar
Acid, iminodisuccinic acid, hydroxyiminodisuccinic acid,
Aspartic acid, polyglyoxy acid, polyasparagine
Acid, polyacrylic acid, acrylic acid-maleic acid copolymer
(The molecular weight of the polymer is arbitrary) and their sodium, etc.
And a chelating agent such as a salt thereof. Also, Japanese Patent Publication No. 2000-505155
The compounds described in the literature can also be used. Furthermore, ass
Corbic acid, ascorbic acid palmitate, gallic acid
A mixture of ropyl, BHT (butylated hydroxytoluene)
), BHA (butylated hydroxyanisole), erosion
Mixture of propyl citrate and citric acid, tertiary butyl hydride
Roquinone, natural tocopherol, long chain S of gallic acid
Ter (C8-C22) such as dodecyl gallate, chiba
Irgano available from Specialty Chemicals, Inc.
Ox-based compound, preferably Irganox 3125,
Irganox 1425, Irganox 3114, and
And their mixtures, isopropyl citrate, Kodak
4,5-dihydroxy-m-benzenesulfur available from
Tyrone, which has the chemical name of fonic acid / sodium salt,
included. The chelating agent is 0 to 3%, and the antioxidant is
0-1% and 0-3% of a reducing agent can be used. Use
Before use, the component (a) should be prepared,
It does not impair the effects of the present invention, such as before and after the production of a product.
It may be added in any number of places at any time.
-Combination use of two or more kinds of agents, antioxidants and reducing agents
Can be For the purpose of enhancing antiseptic and sterilizing power, the following
One or more of the compounds can be used in combination
You. 1) Isothiazolone-based organic sulfur compounds
Therefore, a compound containing a 3-isothiazolone group is preferred.
No. These compounds are described in Le May 5, 1981
US Patent No. 4,265,899 to Wis et al.
It is shown. An example is 5-chloro-2-methyi.
Ru-4-isothiazolin-3-one, 2-n-butyl-
3-isothiazolone, 2-benzyl-3-isothiazolo
2-phenyl-3-isothiazolone, 2-methyl-
4,5-dichloroisothiazolone, 5-chloro-2-me
Tyl-3-isothiazolone, 2-methyl-4-isothia
Zolin-3-one, and mixtures thereof. A more preferred preservative / bactericide is 5-chloro
-2-methyl-4-isothiazolin-3-one and 2-meth
Water-soluble mixture with tyl-4-isothiazolin-3-one
And more preferably about 77% of 5-chloro-2-me
Tyl-4-isothiazolin-3-one and about 23% of 2-
Water-soluble mixing with methyl-4-isothiazolin-3-one
Things. Rohm and Haas Caisson CG /
ICP (about 1.5% by mass aqueous solution),
Junside silicide (including about 5% by mass aqueous solution)
Commercially available ones such as a column can be used. 2) Benzoisothiazoline organic sulfuration
As the compound, 1,2-benzisothiazoline-3-O
2-methyl-4,5-trimethylene-4-isothia
Zolin-3-one, and the like.
Also uses thio-2,2-bis (benzmethylamide)
And they can be used in any mixing ratio.
Examples of such a compound include a proxy made by Avicia Co., Ltd.
Cell series [BDN (effective content 33% by mass), BD20
(Effective component 20% by mass), XL-2 (active component 10% by mass)
%), GXL (effective mass 20% by mass), LV (effective mass 20%)
Mass%), TN (effective mass 60% by mass)], Denicide B
Commercial products such as IT / NIPA can be used. 3) 5-bromo-5-nitro-1,3-di
Oxane or 2-bromo-2-nitropropane-1,3
-Diol or 5-chloro-5-nitro-1,3-dio
Xan or 2-chloro-2-nitropropane-1,3
-Diols and the like can be used. Made by Henkel
BronidoxL, Bronopo manufactured by Inolex
1, Brotopol manufactured by Yoshitomi Pharmaceutical Co., Ltd.
DoBT, BASF MyAside Pharma BP, etc.
Commercial products can be used. 4) Benzoic acids or phenol compounds
Benzoic acid or its salt, salicylic acid or its salt,
Lahydroxybenzoic acid or its salt, p-hydroxybenzoic acid
Methyl, ethyl paraoxybenzoate, paraoxybenzoate
Propyl acid, butyl paraoxybenzoate, paraoxy ammonium
Benzyl benzoate, 3-methyl-3-isopropylpheno
, O-phenylphenol, 2-isopropyl-5
-Methylphenol, resorcin, cresol, 2,6
Using di-tert-butyl-p-cresol or the like
be able to. 5) The case where the total carbon number of the long-chain group is 30 or less
Surfactants can also be used. In particular,
Monoalkyl-type cation having a long-chain group having a carbon chain length of 8 to 20
Surfactants (for example, Arcard T manufactured by Lion Akzo)
-800, T833), beef tallow and / or palm oil
Derived alkyl ammonium salts, partially hydrogenated
, Those hydrogenated, benzalkonium chloride
(E.g., Lion Akzo Arcard CB-50,
Sanyo Kasei cation G-40, G-50, M, same
M-50), use of benzethonium chloride salt, etc.
Can be. In addition, a dial having a carbon chain length of 8 to 14 of a long chain group
Kill-type cationic surfactant, didecyl dimethyl ammonium
Um salt (for example, Lion Card Azocard 210
-50, Sanyo Kasei Cation DDC-50)
Can be used. Furthermore, the carbon chain length of the long chain group is 4 to 1
0 trialkyl cationic surfactant, trioctyl
Methyl ammonium salt, trihexyl methyl ammonium
Salt and the like can also be used. The above compounds 1) to 3) are used in
The amount is preferably 0 to 0.1% by mass, more preferably
A new compounding amount is 0.00001 to 0.03 mass%, more
Preferably it is 0.00005 to 0.02% by mass. Ma
In addition, the compounds of the above 4) to 5) are used in an amount of 0 to 3 with respect to the composition.
% By mass, more preferably
Is 0.01 to 2% by mass. Two or more compounds of the above 1) to 5)
To enhance the preservative and sterilizing power by using
And reduce the amount of expensive compounds used.
Wear. In this case, caisson CG / ICP, proxel
Leeds BDN, Myaside BT, Benzoic acid, Didecyl
Dimethyl ammonium salt, benzalkonium chloride salt 2
It is particularly preferred to use more than one kind in combination,
0.00001 to 3% by mass is preferable, and further preferable.
Is 0.00001 to 2% by mass, more preferably 0.0
0005 to 1% by mass. Further, the above compounds 1) to 3) are
For gold such as zinc, copper, calcium, magnesium
Group ions and acids such as hydrochloric acid, nitric acid, sulfuric acid and propylene glycol
Cole, added to the composition in the presence of dipropylene glycol
Is preferably added. Further, for the purpose of improving the preservative / sterilizing power,
One or more of the following compounds in a composition of 0 to 0.5
%, Preferably 0 to 0.1% by mass
You. Sodium pyrithione, 1,3-bis (H
(Droxymethyl) -5,5-dimethyl-2,4-imida
Zolidinedione, dimethylol dimethylhydantoin,
DM Hydantoin (Glydant manufactured by Lonza, or
Is Glydan Plus), N- [1,3-bis (H
Droxymethyl) 2,5-dioxo-4-imidazolidy
Nil] -N, N'-bis (hydroxymethyl) urea (one
Generally sold under the name of diazolidinyl urea), N,
N "-methylenebis" N "-[1- (hydroxymethyl
Ru) -2,5-dioxo-4-imidazolidinyl] urine
Element, commonly known as imidazolidinyl urea
Imidazolidinedione compounds, such as polymethoxide
Bicyclic oxazolidine compound, formaldehyde, glue
Low molecular weight aldehydes such as taraldehyde, formula HCl
NH_Two− (CH_Two)_Three-[-(CH_Two)_Three-NH-C (= N
H) -NH-C (= NH.HCl) -NH- (CH_Two)_Three
−]_x− (CH_Two)_Three-NH-C (= NH) -NH.CN
Also known as polyhexamethylene biguanide with
Polyaminopropyl biguanide, polyaminopro
Pyrbiguanide, commonly known as chlorhexidine
1,1'-hexamethylenebis (5- (p-chloro
Rophenyl) biguanide), acetic acid and digluconic acid
Digluconate salt, its diacetate salt, Avicia
Use a commercially available product such as Proxel IB
Can be used. Also, 1- (3-chloralyl)-
3,5,7-triaza-1-azoniaadamantancro
Lido, for example, from Dow Chemical to Dowick
Dehid, sold under the trade name il 200
Acetic acid, commonly known as propamidine isethionate
4,4'-diamidino-α, ω-diphenoxy
Propane diisethionate, generally hexamidine isethiate
4,4'-diamidino-, known as onate
α, ω-diphenoxyhexane diisethionate, 12
-(4'-thiazolyl) -benzimidazole, 2-
(4-thiocyanomethylthio) benzothiazole, methyl
Imida such as ru-2-benzimidazole carbamide
With sol or thiazole antibacterial agents, chlorobutanol
1,1,1-trichloro-2-
Methylpropan-2-ol, chlorobutanol, 4,
4 '-(trimethylenedioxy) bis- (3-bromobe
Nsamidine) didiisethionate or dibromopropa
3,4,4'-tomidine, dibromoprohamidine, etc.
Also known as Lichlorocarbanilide or Triclocarban
N- (4-chlorophenyl) -N '-(3,4-
Dichlorophenyl) urea, as triclosan-generally
Known 2,4,4'-trichloro-2'-hydro
Xydiphenyl ether, 4,4'-dichloro-2-hi
Droxydiphenyl ether, trade name is Cibas
Chinosan HP100 manufactured by Pesticide Chemicals Co., Ltd.
And zinc compounds such as zinc chloride. Further, the liquid softener composition of the present invention contains
In addition to the component (c), improved water absorption of fibers and iron slip
In order to further improve the properties, dimethylpolysiloxane and
And modified dimethylpolysiloxane having various organic functional groups
Silicones selected from the group consisting of one or a mixture of two or more.
Any combination can be used as a compound. Silico
Silicone is used when the resin is dimethylpolysiloxane.
Has a viscosity at 25 ° C. of 10 cSt to 1,000,000 cSt.
It is preferably in the range, more preferably 10c
St-100,000 cSt, most preferably 10,000 cSt-10
10,000 cSt. The above silicone is modified dimethylpoly.
When siloxane, the organic functional groups may be amino,
De, alkyl, aralkyl, carboxyl, fluoroa
Ruquil, higher alcohol ester, epoxy, carbino
, Mercapto, phenol, methacrylic and amidopo
Modified silico such as reether, alkyl alcohol
Can be used, and two or more modified
Can be used. Here, the bonding position of the organic functional group
Is a side chain to the main chain of dimethylpolysiloxane, or
Any one of the terminals may be used.
Alternatively, both ends may be used. Also, dimethyl polysiloxy
The mass ratio of organic functional groups to sun may be arbitrary
Yes, it is not particularly limited. Further, the modified dimethyl policy
As a precursor for introducing organic functional groups as loxane
Some hydrogenated dimethylpolysiloxanes or hydroxylated
Tylpolysiloxanes can be used alone or
Mixed with modified dimethylpolysiloxane having a group
May be. Even if various silicones are used as oils,
It may be used as a marsion. These silicone
The compound is preferably used in an amount of 0 to 10% by mass in the composition.
be able to. Further, the liquid softener composition of the present invention contains
Various cellulose and / or cellulose derivatives as softeners
The body can be used in combination. Preferred amounts are
It is 0 to 10% by mass, more preferably 0 to 5% by mass.
Specific examples of powdered cellulose include Rettenmeier
BE-600 / 10, BE00, BE600 / 3
0, FD600 / 30, BWW-40, BC200, B
ARBOCEL series such as E-600 / 20 and Japan
KC Flock series manufactured by Paper Manufacturing Co., Ltd., and the like. crystalline
As a specific example of cellulose, Avicel of Asahi Kasei Corporation
PH series and Avicel FD series. This
Among them, the fiber length is preferably 1 to 500 μm.
m, more preferably 5 to 400 μm, even more preferably 1 to 400 μm.
It is preferably from 0 to 300 μm. Cationic surfactants are household softeners
Is used as the main base material, and has a carbon chain length of 8 to 24.
2-chain long-chain cationic surfactant, having a carbon chain length of 8 to 24
1-chain long-chain cationic surfactant having a carbon chain length of 8 to 2
4, a three-chain long-chain cationic surfactant can be used.
You. The cationic surfactant includes an amine, an amine salt,
Quaternary ammonium salts are included. The raw material for producing the above cationic surfactant is
Tearic acid, palmitic acid, myristic acid, lauric acid
Saturated fatty acids such as oleic acid, elaidic acid, linole
High unsaturation of acids, linolenic acid, erucic acid, brassic acid, etc.
Beef tallow, lard, palm oil, soybean oil, par
Of natural oils and fats such as oil and olive oil
Fatty acid, fatty acid methyl ester, etc.
It is derived from steles and the like. It also has unsaturated groups.
To be cured or partially cured
I do not care. Among these, the long-chain group is olein
Acid, stearic acid, palmitic acid, tallow fatty acid, partially hardened
Beef tallow fatty acid, hardened tallow fatty acid, palm oil fatty acid, part
Preferred are those derived from hardened palm fatty acids and hardened palm oil fatty acids.
Good. The long-chain group may be either saturated or unsaturated.
May be used as a mixture. Handling during the manufacture of the composition
Because of its simplicity, long-chain groups may contain unsaturated groups.
preferable. However, it increases the sliminess of the fiber after processing.
Therefore, it is preferable to increase the ratio of the saturated type. Unfortunate
The stereoisomer structure of the saturated group may be cis or trans.
Or a mixture of both. However, usually,
The ratio of cis-form / trans-form is 25 / 75-100 / 0
(Mass ratio) is often used. One long chain group
Per unit containing two or more unsaturated groups
It is possible, but 10% by mass or less is more preferable in terms of aroma stability.
More preferably, it is 5% by mass or less. Specifically, dioctadecyldimethylan
Monium chloride, dioleyl dimethyl ammonium
Chloride, hardened tallow dimethyl ammonium chloride
, Partially cured palm oleyl dimethyl ammonium chloride
Ride alkyl trimethyl ammonium chloride,
Alkylamine hydrochloride, coconut amine acetate,
Alkylamine acetate, alkyl dimethyl phenyla
Ammonium chloride, didecyl dimethyl ammonium
Chloride, octadecyltrimethylammonium chloride
Ride, alkyl amine oxide, alkyl biguani
, Alkyldimethylbenzylammonium salt, alkyl
Rupyridinium salt, alkyl quinolinium salt, alkyl
Isoquinolinium salt, alkyl imidazoline salt, alk
Louisimidazolinium salt, having a polyoxyalkylene group
And the like. The above cation activity
Fatty acid and / or fatty acid methyl that can be used for the production of an agent
Esters can also be used in the production of the following compounds:
Wear. The component (b) and the above-mentioned nonionic surfactant
Alkoxylated and / or esterified in addition to
Alternatively, a nonionic surfactant may be used. For example,
Alkyl phenols, ethoxylated polyhydric alcohol fatty acids
Esters, ethoxylated fatty acid amides, sorbitan fatty acids
Esters, ethoxylated sorbitan fatty acid esters,
Esters and ethoxylation with sugars such as sugar fatty acid esters
Esters can be used. HLB value of 5-20
Those in the range are preferred, and those in the range of 8 to 16 are particularly preferred.
Good. Further, the above compound having a polyoxyalkylene group
Compounds can also be used. Also, cetyl alcohol
, Stearyl alcohol, arakinyl alcohol,
Cosanol, tetracosanol hexacosanol, oct
Higher alcohols such as tacosanol can also be used.
Wear. Examples of anionic surfactants include higher alky
Chole sulfate ester salt, alkyl phenyl ether sulfate
Ester salt, alkyl benzene sulfonate, higher alkyl
Chol phosphate ester salt, alkoxylated compound
Compounds, especially ethoxylated alkyl phenyl ether sulfate
Ester salts, ethoxylated higher alcohol phosphates, etc.
No. Also, having a polyoxyalkylene group
The above compounds can also be used. Cationic surfactant
Excellent flexibility when the specific molar ratio of the and the anionic surfactant
Expresses sex. Anionic surfactant / cationic surfactant
Agent = 0.1-0.9, preferably 0.2-0.8, more
When 0.3 to 0.6 is preferred, excellent flexibility is exhibited.
You. In addition, alkylbenzene sulfonate and α-sulfate
It has a bulky structure like fatty acid methyl ester salt.
The combined use of anionic surfactants
To reduce the water absorption of cotton towels etc.
Can be restored. The liquid softener composition of the present invention has an appearance
Any dye and / or pigment for the purpose of improving
Can be Preferably, acid dyes, direct dyes, salts
Choose from basic dyes, reactive dyes and mordant / acid mordant dyes
One or more water-soluble dyes. Dye ingredients that can be added
An example is the Handbook of Dyes (edited by the Society of Synthetic Organic Chemistry, Japan, 1971)
Issued on Mar. 20, Maruzen Co., Ltd.). Fiber
For storage stability and fiber of liquid softener composition for textile products
From the viewpoint of dyeing properties, hydroxyl and sulfone
At least one selected from an acid group, an amino group, and an amide group
Acid dyes having a kind of functional group, reactive dyes are preferred,
The amount is preferably 1 to 50 ppm, more preferably
Is 1 to 30 ppm. Dye used in liquid softener composition of the present invention
Fees include Japanese Patent Application No. 2000-102614 and Japanese Patent Application No. 1
1-369323, JP-A-11-43865,
JP-A-10-77576, JP-A-9-25008
No. 5, JP-A-8-27669, JP-A 7-1
8573, JP-A-6-123082, JP-A-6-123082
Using a dye described in JP-A-6-123081
You can also. Adding a fragrance for the aroma of the composition
Can be. The list of fragrance ingredients used as fragrances is
Various references, such as "Perfume and Fla
vol Chemicals, "Vol. I and
  II, Steffen Arctander, All
ured Pub. Co. (1994), "Synthetic flavoring
Science and Product Knowledge ”, Motoichi Indo, Chemical Daily (199
6), “Perfume and Flavor Ma”
terials of Natural Origin
n ", Steffen Arctander, Allu
red Pub. Co. (1994), "A hundred of scents
, Japan Fragrance Association, Asakura Shoten (1989) and "P
erfumery Material Perform
ance V. 3.3 ", Boelens Aroma
  Chemical Information Ser
visit (1996) and "Flower oils"
andFloral Compounds In Pe
rfumery ", Danute Lajaujis
Anonis, Allured Pub. Co. (19
93) etc.
Part of the disclosure of the handbook. The following are representative examples of fragrances.
It is not limited. <Hydrocarbon compounds> Osimene, dihydromyrcene,
Arnesene, cedrene, α-pinene, β-pinene, limo
Nen, dipentene, camphen, ferrandrene, tel
Pinene, 3-carene, terpinolene, bisabolene, β
-Caryophyllene, Kadinen, Valensen, Tsuyobse
, Guayen, Aloosimen, Milsen, Longhihole
Veldracin (1,3,5-undecatriene),
p-cymene, 4-isopropyl-1-methyl-2-p
Lophenylbenzene, diphenyl, diphenylmethane,
Range terpenes, lemon terpenes, bergamot terpenes
, Peppermint terpene, spearmint terpene, la
Imterpen, vetiver terpene, rose wax, di
Jasmine wax, limonene dimer, pentane, hex
Sun, heptane, octane, nonane, decane, undeca
, Dodecane, tridecane, tetradecane, pentadeca
, Hexadecane, heptadecane, octadecane, nona
Deccan, Ikosan, Henikosan, Dokosan, Tricosa
, Tetracosane, pentacosane, hexacosane, hep
Takosan, Octacosan, Nonacosan, Triacontan
And the like. <Alcohol compound> 3-Methyl-1-
Pentanol, geraniol, cedrol, citronello
, Rosinol, nerol, dihydrolinalool,
Narole, tetrahydrolinalool, dimethyloctano
, Tetrahydromugol, mugol, myrseno
, Dihydromyrcenol, oximenol, tetrahydride
Romyrcenol, lavandulol, isodihydrolaba
Ndurol, hydroxycitronellol, nonadil
(6,8-dimethyl-2-nonanol), ethyl linalo
, Isopulegol, terpineol, dihydroter
Pinneol, terpineol-4, perilla alcohol,
4-tanol, 3-tanol, farnesol, ne
Lolidol, α-bisabolol, β-caryophyllena
Rucol, santa roll, vetiver roll, cedrenault
, Patchouli alcohol, dihydrocarbeol,
Tall, isophytol, sclareol, carveo
, Menthol, 1-heptanol, 2-heptanol
, 3-heptanol, 1-octanol, 2-octa
Nord, 3-octanol, 2-ethylhexanol,
1-nonanol, 2-nonanol, isononyl alcohol
(3,5,5-trimethyl-1-hexanol), 1
-Decanol, 1-undecanol, 2-undecanol
, 1-dodecanol, prenol (3-methyl-2-
Buten-1-ol), 2-methyl-3-buten-2-
All, β-pentenol (1-penten-3-O
), Leaf alcohol (cis-3-hexeno)
Trans) -2-hexenol, trans-3
-Hexenol, cis-4-hexenol, 2,4-
Hexadiene-1-ol, matsutakeol (1-octane
Ten-3-ol), cis-6-nonenonel, cucca
Alcohol (2,6-nonadienol), and
Roll (1-nonen-3-ol), Rosalba (9-de
Senol), 1-undesenol, undecabertole
(4-methyl-3-decene-5-ol), osylol
(3,7-dimethyl-7-methoxy-2-octano
), Santalinol (2-methyl-4- (2,2,3
-Trimethyl-3-cyclopenten-1-yl) -2-
Buten-1-ol), p, α-dimethylbenzylal
Cole, 2,2,6-trimethylcyclohexyl-3-
Hexanol, 1,2-pentanediol, benzyla
Alcohol, anis alcohol, β-phenylethyl alcohol
Chole, styralyl alcohol (1-phenyl-1-hi)
Droxyethane), hydratropa alcohol, methyl β
-Phenylethyl alcohol, α-propylphenyl
Tyl alcohol, vanillyl alcohol, decahydro β-
Naphthol, furfuryl alcohol, 3-methyl-1-
Phenyl-3-pentanol, amylcinnamic al
Coal, cinnamic alcohol, phenoxanol
(3-methyl-5-phenylpentanol), 1,2-
Pentanediol, 2-ethylhexanol, dimetho
(2,6-dimethylheptanol), 3,6-dimethyl
Ru-3-octanol, cohinol (3,4,5,6,
6-pentamethyl-2-heptanol), Brahamano
(Methyltrimethylcyclopentenyl butanol),
Bagdanol (2-ethyl-4- (2,2,3-trime
Tyl-3-cyclopenten-1-yl) -2-butene-
1-ol), sandalore (3-methyl-5- (2,
2,3-trimethylcyclopenta-3-en-yl)-
Pentan-2-ol), cyclohexylethyl alcohol
, Apopachon (p-isopropylcyclohexano
), Floralol (2,4-dimethyl-3-cyclo)
Hexene-1-methanol), Pacheon (p-tert)
-Butylcyclohexanol), belldol (o-te
rt-butylcyclohexanol), Mayol (p-
Isopropylcyclohexylmethanol), cyclomethyl
Rencitronellol, Ambrinol (2,5,5-to
Trimethyl-octahydro-2-naphthol), methylsa
Nefflor (5 'or 6'-methylnorborn-5'
-En-2-yl) -2-methylpent-1-en-3
-Ol), Timberol (2,2,6-trimethylsi
Clohexyl-3-hexanol), polysanthol
(3,3-dimethyl-5- (2,2,3-trimethyl-
3-cyclopenten-1-yl) -4-pentene-2-
Oar), hydroxycitronellol, nonadil
(6,8-dimethyl-2-nonanol), isopregou
, Isocyclogeraniol, myrtenol, nopol
(6,6-dimethylbicyclo [3.1.1] hept-2
-En-2-ethanol), pinocalveol, α-fu
Enchil alcohol, borneol, isoborneol
Le, pachomint (2- (3,3-dimethylbicyclo)
[2.2.1] Hept-2-ylidene) ethanol),
Camecol (trimethylnorbornanemethanol), di
Methylcyclomol, Santarex T (Isocampi)
Rucyclohexanol), geranyl linalool, cumin
Alcohol, 2-methoxyphenylethyl alcohol,
Phenoxyethyl alcohol (1-hydroxy-2-f
Enoxyethane), α, α-dimethylphenylethyla
Alcohol, isobutylbenzylcarbinol, p-methyl
Rubenzylcarbinol, hydrocinamic alcohol
Le, centiphor (1,1-dimethyl-3-phenyl)
Propanol-1), muget alcohol (2,2-
Dimethyl-3-phenylpropanol), phenylhexyl
Sanol, decahydro β-naphthol, AR-1 (3,
6-dimethyloctane-3-ol), abitol (H
Droabiethyl alcohol), α-propylphenyle
Tyl alcohol, p-methyldimethylbenzylcarbino
, Mugetanol (1- (4-isopropylcyclohexane)
Xyl) ethanol), Florol (2-isobutyl-
4-hydroxy-4-methyltetrahydropyran),
Propylene glycol, dipropylene glycol, hexyl
Len glycol and the like can be mentioned. <Phenol type and phenol ether type>
Compound> Anisole, Estragole, Cavicol,
Anethole, cresol, carvacrol, p-cure
Sol, p-cresyl methyl ether, β-naphthol
Methyl ether, β-naphthol ethyl ether, β-
Naphthol isobutyl ether, veratrol (1,2
-Dimethoxybenzene), 1,3-dimethoxybenze
, 1,4-dimethoxybenzene, catechol, resor
Sinol, guaiacol, balspice (4-methyl
Ayacol), 4-ethyl guaiacol, orcinyl 3
(3-methoxy-5-methylphenol), thymol,
Methyl thymol, propenyl guaetol (trans
-2-ethoxy-5- (1-propenyl) -pheno
), O-ethylphenol, m-ethylphenol,
p-ethylphenol, 2-tert-butylphenol
, Syringol (2,6-dimethoxyphenol),
Hydroquinone dimethyl ether, resorcinol dimethyl
Ether, eugenol, isoeugenol, dihydro
Eugenol, methyl eugenol, methyl isoeugen
Nol, ethylisoeugenol, benzyleugenol
Benzylisoeugenol, diosphenol, arsenic
Nokitiol, banitrop (1-ethoxy-2-hydride)
Roxy-4-propenylbenzene), shogaol,
Gingerol, acetyl eugenol, acetyl iso
Igenol safrole, isosafrole, diphenylo
Oxide, vetiver ether (tert-butyl hydride
Roquinone dimethyl ether) and the like. <Aldehyde Compound> Citronellal,
Citral, 3,7-dimethyl-1-octanal, arsenic
Droxycitronellal, methoxycitronellal, pe
Rilaldehyde, Miltenal, Caryophyllene alde
Hyd, n-hexanal, 2-methylbutanal, iso
Valeraldehyde, n-valeraldehyde, acetoal
Aldehyde, n-heptanal, n-octanal, n-no
Nanal, 2-methyloctanal, 3,5,5-tri
Methyl hexanal, 1-decanal, undecanar
, Dodecanal, 2-methyldecanal, 2-methyl
Undecanal, tridecanal, tetradecanal,
2-pentenal, cis-3-hexenal, tra
ns-2-hexenal, trans-2-heptenor
, 4-heptenal, trans-2-octenar
, Trans-2-nonenal, cis-6-nonena
, Melonal (2,6-dimethyl-5-heptenor
), Trans-4-decenal, cis-4-decenyl
Nal, trans-2-decenal, grinal
(2,5,6-trimethyl-4-heptenal), 10
-Undecenal, trans-2-undecenal,
trans-2-dodecenal, mandarin aldehyde
(3-dodecenal), trans-2-tridecenal
Adoxal (2,6,10-trimethyl-9-u
Ndecene-1-al), 2,4-hexadienal,
2,4-heptadienal, 2,4-octadiener
Le, 2,4-nonadienal, 2,6-nonadienal
Le, 2,4-decadienal, 2,4-undecadienal
, 2,4-dodecadienal, geraldaldehyde (5,
9-dimethyl-4,8-decadienal), trimener
(3,7,9-trimethyl-2,6-decadiene-1
-Earl), oncidar (2,6,10-trimethyl)
-5,9-undecadienal), bergamal (α-
Methylene citronellal), camphorenaldehyde,
Cyclocitral, isocyclocitral, safraner
(2,6,6-trimethyl-1,3-cyclohexadi
En-1-carboxaldehyde), mugealdehyde
(6,10-dimethyl-3-oxa-9-undesena
Geranyloxyacetaldehyde, tripral
(Dimethyltetrahydrobenzaldehyde), chrysan
Tar (3-propylbicyclo [2,2,1] -5-
Pentene-2-carboxaldehyde), centenal
(Methoxydicyclopentadiene carboxyaldehyde
C), Dupical (4-tricyclodecylidenebutana)
), 4- (4-methyl-3-cyclohexenylidene)
-1) Pentanal, myrac aldehyde (4 (3)
-(4-methyl-3-penten-1-yl) -3-cycl
Rohexene-1-carboxaldehyde), setnal
(Trimethylcyclohexenemethylbutanal), ino
Nal (2-methyl-4- (2,6,6-trimethyl-
1 (2) -cyclohexenyl) -butenal), teres
Toral (4-cyclooctene-1-carboxyalde
Hydr), benzaldehyde, p-tolylaldehyde,
Phenylacetaldehyde, trifernal (3-Fe
Nilbutanal), cuminaldehyde, p-methylphen
Nylacetaldehyde, p-isopropylphenylacetate
Toaldehyde, hydratropaldehyde, p-methylhydr
Doratropaldehyde, p-isopropylhydratropa
Aldehyde, phenylpropionaldehyde, β-methyl
Lehydrocinnamic aldehyde, jasmorandi (2
-Methyl-3- (4-methylphenyl) -propaner
), Burgeonal (p-tert-butylhydro
Cinamic aldehyde), cyclamen aldehyde (2
-Methyl-3- (p-isopropylphenyl) -propyl
Onaldehyde), Florarozone (p-ethyl-α, α)
-Dimethylhydrocinnamic aldehyde), Suzala
(P-isobutyl-α-methylhydrocinamic acid)
Aldehyde), cinnamaldehyde, salicylaldehyde
Hyd, anisaldehyde, o-methoxybenzaldehyde
De, o-methoxycinnamic aldehyde, cantoxa
(2-methyl-3- (p-methoxyphenyl) -propyl
Ropanal), vanillin, ethyl vanillin, methyl vanillin
Phosphorus (3,4-dimethoxybenzaldehyde), helio
Tropine, helional (α-methyl-3,4-methyle
Dioxyhydrocinnamic aldehyde), phenoki
Siacetaldehyde, p-methylphenoxyacetal
Aldehyde, furfural, 5-methylfurfural, 5-
Hydroxymethyl-2-furfural, furyl acrole
In, liral (4 (3)-(4-hydroxy-4-me
Tylpentyl) -3-cyclohexene-1-carboxy
Aldehyde), Bernaldehyde (1-methyl-4-
(4-methylpentyl) -3-cyclohexenecarboxy
Aldehyde), homomyrac aldehyde (1-meth
-4 (4-methyl-3-pentenyl) -3-cyclohexyl
Xencarboxaldehyde), junipal (4
(5) -formyl-7,7,9-trimethylbicyclo
[4.3.0] -nonene), wertral (octahi)
Dro-4,7-methanoindenecarboxyaldehyde
Do), Lilyal (p-tert-butyl-α-methyl)
Hydrocinnamic aldehyde), mefranal (3-
Methyl-5-phenylvaleraldehyde), eglanter
(4-methyl-2-phenyl-2-pentenal),
Cocal (5-methyl-2-phenyl-2-hexena)
), Α-methylcinamic aldehyde, α-butyl
Cinnamic aldehyde, α-amylcinnamic al
Dehyde, α-hexylcinnamic aldehyde, holmi
Ruethyltetramethyltetralin (6-ethyl-7-f
Olmil-1,1,4,4-tetramethyl-1,2,2
3,4-tetrahydronaphthalene) and the like. <Acetal and ketal compounds>
Gunolan (2,4-dimethyl-4,4a, 5,9b-te
Trahydroindeno [1.2d] -1,3-dioxa
), Anthoxane (4-isopropyl-5,5-dimension)
Chill-1,3-dioxane), indoflor (dihid)
Loindenyl-2,4-dioxane), boasambrene
Forte (formaldehyde cyclododecylethyl ace
Tar), acetaldehyde diethyl acetal, lee
Facetal (acetaldehyde ethyl hexenyl ace
Tar), acetaldehyde ethylhexyl acetate
, Citronellyl methyl acetal, erin tar (A
Cetaldehyde ethyl linalyl acetal), Bonaro
(2,4-dioxane-3-methyl-7,10-mex)
Tanospiro [5.5] undecane), ephetal (A
Cetaldehyde ethyl phenyl acetal), acetoacetate
Aldehyde ethyl isoeugenyl acetal, acetal
R (acetaldehyde phenylethyl n-propylacetate
Tar), Fluoropearl (acetaldehyde 2-phenyl)
2,4-pentanediol acetal), spirof
Roll (3-ethyl-2,4-dioxaspiro [5.
5] undecen-8-ene), ethyldimethyldioxa
Spiroundecene, herboxane (2-butyl-4,
4,6-trimethyl-1,3-dioxane), carana
(2- (2,4-dimethylcyclohex-3-cene-1)
-Yl) -5-methyl-5 (1-methylpropyl) 1,
3-dioxane), hexanal dimethyl acetal,
Hexanal diethyl acetal, hexanal propyl
Renglycol acetal, carotene (4,7-dihi
Dro-2- (3-pentanyl) -1,3-dioxepi
), 2-hexenal diethyl acetal, cis-
3-hexenal diethyl acetal, heptanal di
Methyl acetal, heptanal diethyl acetal,
Heptanal ethylene glycol acetal, 2-hex
Sil-5-methyl-1,3-dioxolan, 5-methyl
-5-propyl-2- (1-methylbutyl) -1,3-
Dioxane, Octanal dimethyl acetal, Octa
Naral diethyl acetal, nonanal dimethyl aceta
, Nonanal diethyl acetal, decanal dime
Tyl acetal, decanal diethyl acetal, 2-
Methylundecanal dimethyl acetal, dodecana
Dimethyl acetal, citral dimethyl acetal
Citral diethyl acetal, citral propi
Len glycol acetal, citronellal cyclomono
Glycol acetal, hydroxycitronellal dime
Tilacetal, hydroxycitronellal diethyla
Cetal, cis-3-hexenal diethyl acetate
, Benzaldehyde dimethyl acetal, benzal
Dehyde diethyl acetal, benzaldehyde propyle
Glycol acetal, benzaldehyde glycerin
Acetal, phenylacetaldehyde dimethyl aceta
, Phenylacetaldehyde ethylene glycol
Cetal, phenylacetaldehyde diisobutyl ace
Tar, phenylacetaldehyde propylene glycol
Luacetal, phenylacetaldehyde 2,3-buty
Len glycol acetal, phenylacetaldehyde
Glyceryl acetal, Resedabody (phenylacetate
Aldehyde-2,4-dihydroxy-2-methylpentane
Acetal), 3-phenylpropionaldehydedi
Methyl acetal, hydratropaldehyde dimethyla
Cetal, hydratropaldehyde aldehyde
Acetal, Osminal DMA (Amircinamic
Aldehyde dimethyl acetal), osminal DEA
(Amylcinnamic aldehyde diethyl acetater
Le), heliotropin dimethyl acetal, heliotro
Pin diethyl acetal, vanillin propylene glycol
Luacetal, verdoxane (2,2,5,5-tetra
Methyl-4-isopropyl-1,3-dioxane),
Converse (4,7-dihydro-2-isopentyl-
2-methyl-1,3-dioxepin), acetoketal
(2,5,5-trimethyl-2-phenyl-1,3-di
Oxane), jasmonane (2-butyl-4-dioxa)
Spiro [4.4] nonanone), fraystone (ethyl-
2,4-dimethyl-1,3-dioxolan-2-acete
), Fructon (ethyl-2-methyl-1,3-di)
Oxolan-2-acetate) and the like. <Ketone Compound> Acetyl Caryo Fillet
, Carvone, pulegone, piperitenone, piperiton,
Mentone, show brain, oxosedran, isolongifo
Ranone, nootkatone, 2-heptanone, 2-pentano
, 3-hexanone, 3-heptanone, 4-heptano
2-octanone, 3-octanone, 2-nonanone,
3-nonanone, 2-undecanone, 2-tridecanone,
Methyl isopropyl ketone, ethyl isoamyl ketone,
Mesityl oxide, butylideneacetone, methylhept
Tadienone, methylheptenone, dimethyloctenone,
Corebon (4-methylene-3,5,6,6-tetramethi)
2-heptanone), geranylacetone, farnesi
Luacetone, acetoin, butyroin (5-hydroxy
-4-octanone), methyl lavender ketone (3-h
Droxymethyl-2-nonane), diacetyl, 2,3-
Pentadione, 2,3-hexadione, 3,4-hexa
Dione, 2,3-heptadione, acetyl isovaleri
Amylcyclopentanone, amylcyclopenteno
, 2-cyclopentylcyclopentanone, hexyl
Clopentanone, fluuramon (2-n-heptylsic)
Lopentanone), cis-jasmon, dihydrojas
Mon, Isojasmon, Trimethylpentylcyclopen
Tanone, Sedamon (2-butylidene-3,5,5 (3,
3,5) -Trimethylcyclopentanone), Sandeck
(3-methyl-5- (2,2,3-trimethyl-3-
Cyclopentenyl) -3-penten-2-one), cyclo
Rotene, coronol (3,5-dimethyl-1,2-sic
Lopentadione), methylcorylone (3,4-dimethyl)
1,2-cyclopentadione), verdone (2-ter)
t-butylcyclohexanone), p-tert-butyl
Cyclohexanone, Hellbach (3,3-dimethylcycline)
Rohexyl methyl ketone), frescommente (2-se
c-butylcyclohexanone), artemon (1-acetone)
Tyl-3,3-dimethyl-1-cyclohexene), cell
Leeketone (3-methyl-5-propyl-2-cyclohe
Xenon), krypton (4-isopropyl-2-sic)
Rohexanone), oribbon (p-tert-pentilsi)
Clohexanone), methylcyclocitron (2,3,5)
-Trimethyl-4-cyclohexenyl-1-methylketo
), Nelon (1- (p-menten-6-yl) -1-
Propane), Vetival (4-cyclohexyl-4-meth)
Tyl-2-pentanone), havanol (2- (1-sic)
Rohexen-1-yl) -cyclohexanone), malto
, Ethyl maltol, oxide ketone (cis-
2-acetonyl-4-methyl-tetrahydropyran),
Emoxifuron (5-ethyl-3-hydroxy-4-me
Chill-2 [5H] -furanone), homofurol (2-E)
Tyl-4-hydroxy-5-methyl-3 [2H] -fura
Non and 5-ethyl-4-hydroxy-2-methyl
-3 [2H] -furanone), sotolone (3-hydroxy
C-4,5-dimethyl-2 [5H] -furanone), fura
Neol (2,5-dimethyl-4-hydroxy-3 [2
H] -furanone), acetyldimethylfuran, furfura
Acetone, 2-acetyl-5-methylfuran, 2-
Acetylfuran, methyltetrahydrofuranone, diben
Zyl ketone, benzophenone, methyl naphthyl ketone,
4-Damaschol (5-phenyl-5-methyl-3-he
Xanone), Veticone (4-methyl-4-phenyl-2)
-Pentanone), α-methylanisalacetone, helio
Tropylacetone, anisylideneacetone, anisylua
Seton, p-methoxyphenylacetone, raspberry
Ton (4- (p-hydroxyphenyl) -2-butano
), Labandone (3-methyl-4-phenyl-3-)
Buten-2-one), benzylideneacetone, p-meth
Xyacetophenone, p-methylacetophenone, pro
Piophenone, acetophenone, damacenone, damasco
, Isodamascon, α-dynascon (1- (5,5
-Dimethylcyclohexen-1-yl) -4-pentene
-1-one), iriton (4- (2,4,6-trimethyi)
Ru-3-cyclohexen-1-yl) -3-butene-2
-On and 4-3,5,6-trimethyl-3-si
Clohexen-1-yl) -3-buten-2-one),
Yonone, pseudoyonone, methylyonone, methylirito
(3-methyl-4- (2,4,6-trimethyl-3-
Cyclohexenyl) -3-buten-2-one), cyclo
Wood (2,4-di-tert-butylcyclohexano
), Iron, allylyonone, 2,6,6-trimethyl
-2-cyclohexene-1,4-dione, Kamek DH
(2-acetyl-3,3-dimethylnorbornane),
Rolex (6-ethylideneoctahydro-5,8-me
Tano-2H-1-benzopyran-2-one), plicato
(4-methyltricyclo [6.2.1.0^2,7] Eun
Decane-5-one), oxosedran, beltfic
(9-acetyl-2,6,6,8-tetramethyltri
Cyclo [5.3.1^1,7. 0^1,5-8-undecene),
Verbenone (4,6,6-trimethyl- (1R) -bis
Clohept-3-en-2-one), fencon, caro
(7-methyl-3,5-dihydro-2H-benzodione
Xepin-3-one), Trimofix O (2,6,
10-trimethyl-1-acetyl-2,5,9-cyclo
Dodecatriene), Vitalide (acetyl dimethyl teto)
Lahydroventindan), Epiton (7 (8) -ace
Tyl-5-isopropyl-2-methylbicyclo [2.
2.2] Oct-2-ene), atrinone (4 (5)-
Acetyl-7,7,9 (7,7,9) -trimethylbis
Black [4.3.0] -1-nonene), cashmeren
(6,7-dihydro-1,1,2,3,3-pentamethyl
-4 (5H) -indanone), muscone (3-methyl)
Cyclopentadecanone-1), cibetone (cyclohepta)
Deca-9-en-1-one), exaltone (cyclope
Ntadecanone), Musk TM-II (cyclohexadece
Non), phantolide (5-acetyl-1,1,2,2,
3,3,6-hexamethylindane), celestride
(4-acetyl-6-tert-butyl-1,1-dimethyl
Tilindane), traseolide (5-acetyl-3-
Isopropyl-1,1,2,6-tetramethylinda
), Tonalide (6-acetyl-1,1,2,4,4,4)
7-hexamethyltetrahydronaphthalene), Vitalai
(Acetyldimethyltetrahydrobenzindane),
IsoE Super (7-acetyl-1,2,3,
4,5,6,7,8-octahydro-1,1,6,7-
Tetramethylnaphthalene), dihydrocarbon, dios
Examples include phenol and zingerone. <Ether Compound> Methylhexyl A
Ter, decyl methyl ether, decyl vinyl ether,
Diethylene glycol monomethyl ether, diethylene
Glycol monoethyl ether, citronellyl ethyl ether
-Tel, geranyl ethyl ether, α-terpinylmethy
Ruether, herber belt (3,3,5-trimethylsi
Clohexyl ethyl ether), isobornyl methyl ether
-Tel, tricyclodecenyl methyl ether, isopro
Xene (2-ethylidene-6-isopropoxybicyclo
[2.2.1] heptane), junipalome (methoxy
Dimethyltricyclo [5.2.1.0 ^2,6] Decane),
Cyclododecyl methyl ether, Madrox (1-
Tyl cyclododecyl methyl ether), fizeol
(2-ethoxy-2,6,6-trimethyl-9-methyle
Bicyclo [3.3.1] -nonane), cedlumbar
(Cedrol methyl ether), methylbenzyl ether
, Methylphenylethyl ether, ethyl 2-methoxy
Cibenzyl ether, allyl phenyl ethyl ether,
Isoamyl benzyl ether, Answer (isoamylph
Enyl ethyl ether), jacene (2-methyl-2-
Butenyl phenyl ethyl ether), dibenzyl ether
, Cyclohexyl phenyl ether, myroxide
(Ocimene epoxide), limonene oxide (p-meth
Nt-8-ene-1,2-epoxide), rubofix
(Spiro [1,4-methanonaphthalene-2 (1H),
2'-oxirane],-3,4,4a, 5,8,8a-
Hexahydro-3 ', 7-dimethyl and spiro
[1,4-methanonaphthalene-2 (1H), 2'-oxo
Silane],-3,4,4a, 5,8,8a-hexahydride
B-3 ', 6-dimethyl), trimethylcyclododecato
Liene epoxide, caryophyllene oxide, cedre
Epoxide, isolongifolene epoxide, linalo
Oxide, citrooxide (2,2-dimethyl
-5 (1-methyl-1-propenyl) -tetrahydrof
Run), herbooxide (5-isopropenyl-2-)
Methyl-2-vinyltetrahydrofuran), rose fura
(3-methyl-2- (3-methyl-2-butenyl)-
Furan), heptabelt (2-heptyltetrahydroph)
Orchid), mentfuran, theaspirane, oxybed
(2-oxaspiro [4,7] dodecane), muscogen
(3-oxabicyclo [103.0] -6-pentade
Sen), cyclambar (13-oxabicyclo [10.
3.0] pentadecane), ambroxane (decahydro
-3a, 6,6,9a-tetramethylnaphtho [2.1-
b] furan), grisalva (3a-ethyldodecahydro)
-6,6,9a-Trimethylnaphtho [2.1-b] fura
), 1,8-cineole, 1,4-cineole, gala
Xolide (1,3,4,6,7,8-hexahydro-
4,6,6,7,8,8-hexamethylcyclopenta-
γ-2-benzopyran), rose oxide, nerol
Oxide, Limetol (2,2,6-trimethyl-6
-Vinyl tetrahydropyran), dilan (2-butyl-
4,6-dimethyldihydropyran), dremox (te
Trahydro-4-methyl-2-phenyl-2H-pyra
), Rubofloor (9-ethylidene-3-oxatrici)
Black [6.2.1.0^2,7] Undecane), hexahide
Loindenopyran and the like. <Acid compound> Gellanic acid, acetic acid, propio
Acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid,
2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric
Acid, 3-methylvaleric acid, hexanoic acid, isohexanoic acid,
2-hexanoic acid, 4-pentenoic acid, 2-methyl-2-pe
Acid, heptanoic acid, 2-methylheptanoic acid, octa
Acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylene
Acid, dodecanoic acid, myristic acid, palmitic acid,
Aric acid, anthranilic acid, oleic acid, levulinic acid,
Lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, 3-phenylene
Lupropionic acid, vanillic acid, valine, abietic acid,
And sorbic acid. <Lactone compound> Pentalide (cyclo
Pentadecanolide), havanolide (oxacyclohexa)
Decene-2-one), ambrettolide, cyclohexa
Decanolide, 10-oxahexadecanolide, 11-o
Xahexadecanolide, 12-oxahexadecanolide
Do, ethylene dodecandioate, γ-butyrolact
Γ-valerolactone, angelica lactone, γ-f
Xalactone, γ-heptalactone, γ-octalactone
, Γ-nonalactone, whiskey lactone (3-meth
Le-4-octanolide), γ-decalactone, γ-un
Decalactone, γ-dodecalactone, γ-jasmorak
Tons, jasmine lactone, cis jasmon lactone,
Lactojasmon (4-methyl-4-decanolide), di
Jasmolactone (tetrahydro-6- (3-pentenyl)
Ru) -2H-pyran-2-one), mentalactone
(3,6-dimethyl-5,6,7,7a-tetrahydro
-2 (4H) -benzofuranone), n-butylphthalic
, Propylidenephthalide, butylidenephthalide, δ-
Hexalactone, δ-octalactone, trivalon
(4,6,6 (4,4,6) -trimethyltetrahydro
Pyran-2-one), δ-nonalactone, δ-decalact
Ton, δ-2-decenolactone, δ-undecalact
Δ-dodecalactone, δ-tridecalactone, δ-
Tetradecalactone, lactoscatone (decahydro-
4, α-hydroxy-2,8,8-trimethylnaphthali
2-carboxyacid-δ-lactone), Kumari
, Dihydrocoumarin, cyclohexyllactone, 6-
Methyl coumarin, ε-decalactone, ε-dodecalact
And the like. <Ester Compounds> Ethyl formate, formic acid
Ropyl, butyl formate, amyl formate, isoamyl formate,
Hexyl acid, cis-3-hexenyl formate, octyl formate
, Linalyl formate, citronellyl formate, geranyl formate,
Neryl formate, rosinyl formate, terpinyl formate, sed formate
Ril, caryofeiren formate, afermat (α,
3,3-trimethylcyclohexanemethylforme
G), oxyoctaline formate, benzyl formate, syn formate
Namyl, phenylethyl formate, anisyl formate, oily formate
Genyl, decahydro-β-naphthyl formate, methyl acetate,
Ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate
Butyl, isobutyl acetate, 2-methylbutyl acetate,
Soamyl, amyl acetate, prenyl acetate, hexyl acetate,
Cis-3-hexenyl acetate, trans-2-hexyl acetate
Xenyl, 2-ethylhexyl acetate, heptyl acetate, vinegar
Octyl acid, 3-octyl acetate, octenyl acetate, acetic acid
Nonyl, decyl acetate, trimethylhexyl acetate,
Cenyl, nonanediol acetate, dodecyl acetate, dimethyl acetate
Chillundecadienyl, diacetyl, diacetin, tri
Acetin, ethylene glycol diacetate, ethylene
Glycol monobutyl ether acetate, allylamido
Luglycolate, osimenyl acetate, myrsenyl acetate, vinegar
Dihydromyrcenyl acid, dimethyloctanyl acetate, acetic acid
Linalyl, citronellyl acetate, rosinyl acetate, galley acetate
Nyl, neryl acetate, tetrahydromugol acetate, acetic acid
Tillinalil, lavandulyl acetate, isohydrola acetate
Vanjuril, nerolidol acetate, carbyl acetate, acetic acid
Dihydrocarbyl, dihydrocuminyl acetate, terpi acetate
Nyl, isopulegol acetate, menthyl acetate, citri acetate
, Miltenyl acetate, nopyryl acetate, fenquil acetate, vinegar
Bornyl acid, isobornyl acetate, ceryl acetate, kario
Filen acetate, Santalyl acetate, Vetiveri acetate
Guaiac, methyl cyclopentylidene acetate,
Cyclohexyl acetate, p-isopropylcyclohexyl acetate
Sanil, tert-amylcyclohexyl acetate, di acetate
Hydroterpinyl, cyclohexylethyl acetate, Flora
Rate (2,4-dimethyl-3-cyclohexenyl acetate)
Methyl), rosamsk (α, 3,3-trimethyl acetate)
Clohexanemethyl), Vertenex (p-te acetate)
rt-butylcyclohexyl), Belldox (acetic acid o)
-Tert-butylcyclohexyl), 1-ethynyl acetate
Lecyclohexyl, dihydroambrate (1-acetoacetate)
Xy-2-sec-butyl-1-vinylcyclohexa
), Mirardil acetate (4 (3)-(4-methyl-3)
-Pentenyl) -3-cyclohexenylmethyl acetate
G), tricyclodecenyl acetate, tricyclodecyl acetate
Benzyl acetate, p-cresyl acetate, phenyl acetate
Chill, styryl acetate, p-methylbenzyl acetate, acetic acid
Anisyl, piperonyl acetate, acetyl vanillin, rose
Phenone, hydratropyl acetate, 2,4-dimethyl acetate
Benzyl, cinnamyl acetate, phenylpropyl acetate, vinegar
Cuminyl acid, dimethylbenzylcarbinyl acetate, phenyl
Leglycol diacetate, dimethylphenylethyl acetate
Rucarbyl, phenylethyl methylethyl carb
Nyl, beticol acetate (4-methyl-4-phenyl)
2-pentyl acetate), α-amylcinna acetate
Mimill, jasmarol (trans-decahydro-β
-Naphthyl acetate), furfuryl acetate, tetraacetate
Hydrofurfuryl, jasmar (3-pentylte acetate)
Trahydropyranyl), Jasmeria (5-methyl acetate)
-3-butyltetrahydropyranyl), ethyl acetoacetate
Gesate (ethyl 2-hexylacetoacetate),
Ethyl benzylacetoacetate, cyclohexyl acetate
, Cyclohexenyl isopropyl acetate, propionic acid
Ethyl, propyl propionate, allyl propionate,
Butyl propionate, isobutyl propionate, propionate
Isoamyl onion, hexyl propionate, propion
Acid cis-3-hexenyl, propionic acid trans-
2-hexenyl, decenyl propionate, propionic acid
Linalyl, citronellyl propionate, ropropionate
Zinyl, geranyl propionate, neryl propionate,
Carbyl propionate, terpinyl propionate, pro
Menthyl pionate, bornyl propionate, propion
Isobornyl acid, tricyclodecenyl propionate,
Benzyl lopionate, stiralyl propionate, propyl
Anisyl onion, phenylethyl propionate, propyl
Cinnamyl onate, phenylpropyl propionate,
Dimethylbenzylcarboxy lopionate, propionic acid
Phenoxyethyl, propylene glycol propionate
Dipropionate, Rabdanax (3-hydroxy-
Ethyl 3-phenylpropionate), furanpropionic acid
Isobutyl, methyl butyrate, ethyl butyrate, propyl butyrate,
Isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyrate
Butyl, amyl butyrate, isoamyl butyrate, hexyl butyrate,
Heptyl butyrate, cis-3-hexenyl butyrate, tr butyrate
ans-2-hexenyl, octyl butyrate, propylene glycol
Recall dibutyrate, linalyl butyrate, citronelli butyrate
Rosinyl butyrate, geranyl butyrate, neryl butyrate,
Lupinyl, cyclohexyl butyrate, benzyl butyrate,
Nnamyl, phenylethyl butyrate, dimethylbenzyl butyrate
Carvinyl, tetrahydrofurfuryl butyrate, Santa butyrate
Ryl, methyl isobutyrate, ethyl isobutyrate, isobutyric acid pro
Pill, isopropyl isobutyrate, butyl isobutyrate, isobutyrate
Isobutylate, isoamyl isobutyrate, hexyl isobutyrate
Cis-3-hexenyl isobutyrate, 2,4 isobutyric acid
-Hexadienyl, isopentylate (1,3 isobutyric acid)
-Dimethyl-3-butenyl), octyl isobutyrate, iso-
Linalyl butyrate, citronellyl isobutyrate, rosini isobutyrate
, Geranyl isobutyrate, neryl isobutyrate, ter isobutyrate
Pinyl, tricyclodecenyl isobutyrate, benzyl isobutyrate
, P-cresyl isobutyrate, cinnamyl isobutyrate,
Phenylethyl butyrate, phenylpropyl isobutyrate, iso
Styralyl butyrate, dimethylcarbyl isobutyrate, isobutyrate
Acid dimethylphenylethylcarbinyl, floranol
(Phenoxyethyl isobutyrate), decahydro isobutyrate-
β-naphthyl, methyl 2-methylbutyrate, 2-methylbutyric acid
Ethyl, 2-methylbutyl 2-methylbutyrate, Sidran
(Hexyl 2-methylbutyrate), cis- 2-methylbutyrate
3-hexenyl, benzyl 2-methylbutyrate, 2-methyl
Phenylethyl butyrate, allyl 2-ethylbutyrate, 3-hydrido
Ethyl roxybutyrate, methyl valerate, ethyl valerate, valer
Butylate, isobutyl valerate, amyl valerate, valerate c
is-3-hexenyl, benzyl valerate, phenyl valerate
Ethyl, furfuryl valerate, methyl isovalerate, iso
Ethyl valerate, propyl isovalerate, isopisovalerate
Ropyl, allyl isovalerate, butyl isovalerate, isovaler
Isobutyl valerate, isoamyl isovalerate, isovalerate
Mill, 2-methylbutyl isovalerate, cis isovalerate
-3-hexenyl, hexyl isovalerate, o-isovalerate
Cutyl, linalyl isovalerate, citronelli isovalerate
, Geranyl isovalerate, menthyl isovalerate, isovaler
Terpinyl valerate, cyclohexyl isovalerate, isovalerate
Benzyl, phenylethyl isovalerate, isovalerate
Phenyl, cinnamyl isovalerate, manzanate
(Ethyl 2-methylvalerate), phenyl salicylate,
Peranato (2-methylpentylester 2-methylvalerate)
M), methyl hexanoate, ethyl hexanoate, hexane
Propyl acid, isopropyl hexanoate, ant hexanoate
Butyl, hexanoate, isobutyl hexanoate, hexa
Amyl phosphate, isoamyl hexanoate, hexyl hexanoate
Cis-3-hexenyl hexanoate, hexanoic acid t
trans-2-hexenyl, heptyl hexanoate, hexyl
Linalyl sanate, citronellyl hexanoate, hexanoic acid
Geranyl, citronellyl hexanoate, benzenohexanoate
, Methyl isohexanoate, methyl 2-hexenoate, t
trans-2-ethyl hexenoate, 3-hexenoic acid methyl
, Ethyl 3-hexenoate, 3-hydroxyhexanoic acid
Methyl, ethyl 3-hydroxyhexanoate, 2-ethyl
Ethyl hexanoate, Mersat (3,5,5-trimethyl
Ethyl hexanoate), beliflo (ethyl 6-acetoxy)
Cihexanoate), methyl heptanoate, heptanoate
Chill, propyl heptanoate, allyl heptanoate, hepta
Octyl phosphate, methyl octanoate, ethyl octanoate,
Amyl octoate, butyl octoate, octoate pro
Pill, allyl octanoate, isoamyl octanoate, octane
Hexyl tannate, heptyl octanoate, octanoic acid
Tyl, linalyl octanoate, benzyl octanoate, octane
Phenylethyl tannate, p-cresyl octoate, 2-
Ethyl octenoate, methyl nonanoate, ethyl nonanoate,
Phenylethyl nonanoate, Boubaltate (2-nonene
Acid), methyl 3-nonenoate, methyl decanoate, de
Ethyl citrate, isopropyl decanoate, butyrate decanoate
, Isoamyl decanoate, ethyl 2-decenoate, 2,4
-Ethyl decadienate, 2,4-decadienoate propyl
Methyl, undecylenate, butyl undecylenate,
Isoamyl undecylenate, methyl dodecanoate, dodecane
Ethyl acid, butyl dodecanoate, isoamyl dodecanoate,
Ethyl myristate, methyl myristate, myristine
Isopropyl acid, ethyl palmitate, stearic acid
Chill, butyl stearate, methyl oleate, oley
Ethyl phosphate, methyl benzoate, ethyl benzoate, benzoate
Propylate, isopropyl benzoate, allyl benzoate,
Isobutyl benzoate, isoamyl benzoate, benzoate
Renyl, hexyl benzoate, cis-3-hexyl benzoate
Cenyl, linalyl benzoate, geranyl benzoate, benzoate
Benzyl, phenylethyl benzoate, cinnabenzoate
Mill, methyl anisate, ethyl anisate, o-methoxy
Methyl benzoate, ethyl o-methoxybenzoate, tigly
Ethylate, hexyl tiglate, cis-tiglate
3-hexenyl, citronellyl tiglate, tiglic acid
Geranyl, benzyl tiglate, phenyl tiglate
Chill, cinnamyl tiglate, methyl angelica,
Butyl angelic acid, isobutyl angelic acid, angelic acid
Isoamyl catenate, prenyl angelic acid, angelic acid
cis-3-hexenyl, angelic acid 3-methyl pen
Chill, phenylethyl angelic acid, ethyl acrylate
Phenylethyl methacrylate, ethyl crotonate,
Isobutyl crotonate, cyclohexyl crotonate,
Rutinato (4-methyl-pentan-2-ol-croto
), Piroprunate (2-cyclopentyl-cyclo)
Pentyl crotonate), datilato (1-cyclohexyl)
Ethyl crotonate), ethyl levulinate, levulin
Butyl acid, isoamyl levulinate, methyl lactate, lactate
Chill, amyl lactate, isobutyl lactate, cis-3-lactate
Hexenyl, butyl butyryl lactate, ethyl pyruvate,
Methyl gellanate, ethyl gellanate, methyl cyclogelate
, Ethyl cyclogelanoate, furtate (ethyl trisyl
Black [5.2.1.0^2,6] Decan-2-yl carbo
Xylate), divescon (ethyl-2-ethyl-6,6)
6-dimethyl-2-cyclohexene-1-carboxyle
And & ethyl-2,3,6,6-tetramethyl-2
-Cyclohexene carboxylate), ethyl safrane
(Ethyl dehydrocyclogeranate), cyclohexyl
Allyl silpropionate, cyclogalvanate (allyl
Cyclohexyloxyacetate), calixol (d
Tyl-2-methyl-6-pentyl-4-oxocyclohe
Xy-2-enecarboxylate), taclisate (meth
Tyl-1-methyl-3-cyclohexenecarboxylate
G), floramate (ethyl-2-tert-butyloxy)
Clohexyl carbonate), jasma cyclate (meth
Tyl cyclooctyl carbonate), mahgonate (1
-Methyl-4-isopropyl-2-carbomethoxybis
Clo [2,2,2] -oct-5-ene), pivalic acid
Enylethyl, methyl jasmonate, hedion (Jihi
Methyl droyasmonate), veramos (methyl-3,6)
-Dimethyl-β-resorcylate), furancarboxylic acid
Methyl, ethyl furancarboxylate, furanacrylate
Lopir, Methyl heptinecarboxylate, Heptincarboxylic
Ethyl acid, isoamyl heptinecarboxylate, octinka
Methyl rubonate, ethyl octyne carboxylate, desinka
Methyl rubonate, glycol (3- (bicyclo [2.
2.1] Hept-5-en-2-yl) -3-methyloxo
Methyl ester of silane carboxyacid), phenyl
Methyl luglycidate, ethyl phenylglycidate, al
Dehydration C-16 (3-methyl-3-phenylglycidic acid
Ethyl), aldehyde C-20 (p-methyl-β-fe
Ethyl nylglycidate), methyl p-tolylglycidic acid
Ethyl, ethyl citronellyl oxalate, diethyl succinate
Dimethyl succinate, diethyl malonate, dietartrate
Chill, diethyl adipate, diethyl sebacate, que
Triethyl phosphate, dimethyl phthalate, diethyl phthalate
, Dibutyl phthalate, methyl phenylacetate, phenyl
Ethyl acetate, isopropyl phenylacetate, phenylacetic acid
Butyl, propyl phenylacetate, isobutyl phenylacetate
, Isoamyl phenylacetate, hexyl phenylacetate,
Cis-3-hexenyl phenylacetate, phenylacetate
Toneryl, Rosinyl phenylacetate, Gela phenylacetate
Nyl, menthyl phenylacetate, benzyl phenylacetate,
Phenylethyl phenylacetate, p-Credit phenylacetate
, Eugenyl phenylacetate, isoeugen phenylacetate
Nil, methyl cinnamate, ethyl cinnamate, cinnamate pro
Pill, isopropyl cinnamate, allyl cinnamate, cinnamon
Isobutyl acid, isoamyl cinnamate, linalic cinnamate
Benzyl cinnamate, cinnamyl cinnamate, cinnamic acid
Phenylethyl, methyl salicylate, ethyl salicylate
Butyl, salicylate, isobutyl salicylate, salicy
Amyl luate, isoamyl salicylate, hexyl salicylate
Cis-3-hexenyl salicylate, salicylic acid
Clohexyl, phenyl salicylate, benzyl salicylate
Phenylethyl salicylate, cyclopidene (methyl
Cyclopentylidene acetate), ethyl-2,2,6
-Trimethylcyclohexane carbonate, avaline
(Methyl aviate), herculin (methyl dihydro)
Aviate), p-cresyl salicylate, phenoxy
Allyl acetate, ethyl phenylpropionate, ethylene
Rasilate, triacetin and the like can be mentioned. <Nitrogen-containing compound> Methyl anthranilate
, Ethyl anthranilate, butyl anthranilate,
Cis-3-hexenyl anthranilate, anthranilic acid
Phenylethyl, cinnamyl anthranilate, N-methyl
Methyl luanthranilate, auran thiol (hydroxy
Schifftronellal-Methylanthranilate Schiffbe
), Mevantral (methyl propyl acetoalde)
Hyd-methylanthranilate Schiff base), ja
Sumentin (α-amylcinamic aldehyde-methyl
Luang Suranilate Schiff Base), Ligantrall
(Methyl- (3,5-dimethyl-3-cyclohexene-
1-yl) methylene anthranilate), indole,
Skatole, Clonal (dodecanenitrile), Tanji
Eneil (2-tridecennitrile), citraluba (ge
Ranilnitrile), citronellyl nitrile, lemonyl
(3,7-dimethyl-2,6-nonadienitrile),
Minyl nitrile, cinnamalva (cinnamyl nitrile
), Trimethylamine, pyridine, 3-ethylpyridyl
2-acetylpyridine, 3-acetylpyridine, 2
-Isobutylpyridine, 3-isobutylpyridine, 2-
n-pentylpyridine, 5-ethyl-2-methylpyridi
, Methyl nicotinate, 4- (1,4,8-trimethyl
-3,7-nonadienyl) pyridine, quinoline, isoki
Norin, p-methylquinoline, tetrahydro-p-methyl
Lucinoline, 6-isopropylquinoline, isobutyl
Norin, 2-isobutylquinoline, 6-sec-butyl
Quinoline, 8-sec-butylquinoline, 6 (p) -t
tert-butylquinoline, 2-tert-butylquinolin
, Pyrazine, 2-methylpyrazine, 2,5-dimethyl
Pyrazine, 2,6-dimethylpyrazine, 2,3,5-to
Limethylpyrazine, 2-ethylpyrazine, 2-ethyl-
3-methylpyrazine, 2-ethyl-5-methylpyrazine
2-ethyl-3,5 (3,6) -dimethylpyrazine
2,3-diethylpyrazine, 2,3-diethyl-5
-Methylpyrazine, tetramethylpyrazine, 2-methyl
-5-vinylpyrazine, methoxypyrazine, 2-methoxy
Ci-3-methylpyrazine, 2-methoxy-3-ethylpi
Azine, 2-methoxy-3-isopropylpyrazine, 2
-Isobutyl-3-methoxypyrazine, 2-acetylpyrazine
Razine, 2-acetyl-3-ethylpyrazine, methylthio
Omethylpyrazine, corylonepyrazine (5-methyl-
6,7-dihydrocyclopentapyrazine), 5-methyl
Quinoxaline, cyclohexapyrazine (5,6,7,8
-Tetrahydroquinoxaline), 1-methylpyrrole,
2-acetylpyrrole, pyrrolidine, indolene (in
Dol-hydroxycitronellal Schiff base),
2-methylbenzoxazole, decahydrocyclodode
Caoxazole, 5-methyl-3-heptanoneoxy
Bucoxime (bicyclo [3.2.1] octane-8
-One, 1,5-dimethyl-, oxime), Gardamai
(N-methyl-N-phenyl-2-methylbutylamido)
C), musk xylol, musk ketone, musk umbu
Lett, Muskti Betten, Mosken, 2,6-Lutiji
, Piperidine, 2- (1,4,8-trimethyl-3,
7-nonadienyl) pyridine, 2- (2-pinene-10)
-Ylmethyl) pyridine, 4- (2-pinene-10-i
Somethyl) pyridine, piperine, capsaicin, nonane
Acid vanillylamide, quinine, perillartin (L-peri
Laaldehyde α-anti-aldoxime), 2-a
Sopropyl-4-methylthiazole, 2-isobutylthio
Azole and the like. <Sulfur-containing compounds> Thiazole, 4-methyl
Luthiazole, 4,5-dimethylthiazole, trimethyl
Luthiazole, 2-methyl-5-methoxythiazole,
2-isopropyl-4-methylthiazole, 4-methyl
-5-vinylthiazole, 2-isobutylthiazole,
Sulfurol (4-methyl-5-thiazoleethanol
), Sulfuryl acetate (4-methyl-5-thia)
Sol-ethanol acetate), 2-acetylthiazolate
, 5-acetyl-2,4-dimethylthiazole, ben
Zothiazole, propyl mercaptan, hydrogen sulfide, iso
Propyl mercaptan, 2-methyl-3-butanethio
, Allyl mercaptan, isoamyl mercaptan,
Ogeraniol, limonene thiol, sulfox
(8-mercaptomentone) phenyl mercaptan, o
-Thiocresol, 2-ethylthiophenol, 2-na
Futyl mercaptan, furfuryl mercaptan, 2-me
Tyl-3-furanthiol, dimethyl sulfide, dime
Tyl disulfide, dimethyl trisulfide, methyl sulfide
Ropir disulfide, methylpropyl trisulfide,
Propyl disulfide, dipropyl trisulfide, di
Allyl sulfide, diallyl disulfide, dibutyls
Sulfide, methionol (3- (methylthio) -1-p
Ropanol), 3-methylthio-1-hexanol,
Thional (3- (methylthio) propionaldehyde
C), mint sulfide, dithiospirofuran, furf
Rylmethyl sulfide, 2-methyl-5-methylthiophene
Orchid, methylfurfuryl disulfide, furfuryldis
Sulfide, thiophene, tetrahydrothiophene, 3-
Thiophenecarboxaldehyde, 5-methyl-2-thio
Offencarboxaldehyde, tetrahydrothiophene
N-3-one, trithioacetone, thioglycolic acid,
Methyl methylthioacetate, ethyl methylthioacetate,
Rucaptopropionic acid, pineapple mercaptan (meth
Tylmercaptomethylpropionate), 3-methylthio
Ethyl thiopropionate, ethyl thioacetate, thioacetate full
Furyl, furfuryl thiopropionate, methylthiobutyrate
, Methyl methane thiosulfonate, isothiocyan
Allyl acid, benzyl isothiocyanate, thiardine
(2,4,6-trimethyl-4,5-dihydro-1,
3,5-dithiazone), oxane (2-methyl-4-p)
Ropyl-1,3-oxathiane) and the like. <Natural fragrance> Asafetida resinoid,
Ajowan oil, Star anise oil, Abies oi
Le, Amyris oil, Ambrette seed oil, Ann
Berglist tincture, ylang-ylang oil, ylang-ylang
Absolute, Iris resinoid, Iris absolute
, Iris oil, winter green oil, ele
Myoleoresin, Elemiresinoid Absolute, D
Remit tincture, oak moss concrete, oak moss
Solut, oak moss resin, oak moss resinoi
De, okotia oil, osmanthus absolute,
Osmanthus Concrete, Opopanax Resinoi
Do, Opopanax Absolute, Opopanax
Il, Olivernum Resinoid, Olivernum Absolute
G, olivenum oil, allspice oil, orega
Oil, oregano oleoresin, orange oil, o
Range Flower Absolute, Orange Flower Con
Cleats, cananga oil, garjun balsam, gar
Junbal sam oil, cascari bark oil, kas
Thorium absolute, Cassie absolute, mosquito
Flower oil, cassia oil, gardenia
Bussolut, Carne Absolute, Cabru
Oil, chamomile oil, cardamom oil, gal
Banam Oil, Galvanum Resin, Galvanam Resinoi
De, caraway seed oil, carrot seed oy
Guaiac wood oil, guaiac resin, gua
Yack concrete, camphor oil, Kubeba oil,
Cumin oil, cumin absolute, cumin oleoresin
Gin, clary sage oil, grapefruit oil,
Clove oil, Costas oil, Copaiba balsam,
Copaiba balsam oil, copaiba balsam resin, cocoa
Leander oil, sassafras oil, sandalwood
Oil, Gene Absolute, Perilla oil, Citro
Nera oil, jasmine absolute, jasmine
Concrete, juniper berry oil, civet abso
Lute, civet tincture, john kill absolute
, Agarwood oil, ginger oil, cinnamon
Oil, cinnamon bark oil, cinnamon leaf oy
, Cedar oil, styrax oil, styraxle
Zinoid, spearmint oil, savory oil,
Oil, cedar oil, cedar leaf oil, zera
Nium oil, celery seed oil, thyme oil,
Tugget oil, tarragon oil, tuberose absolute
Lute, dill oil, tea tree oil, tree
Moss Absolute, True Balsam, Nutmeg Oy
Le, narcissus absolute, neroli oil, bio
Lett Absolute, Pine Oil, Basil O
Il, parsley relief oil, parsley seed oil, parsley
Reherb oil, patchouli oil, peppermint oil, bani
Ra Absolute, Honeysuckle Absolute, Pa
Lumarosa oil, valerian oil, bitter orange
Oil, hyssop oil, hiba oil, hyacinth abu
Solut, fennel oil, figabsolue
, Petitgren oil, Butch oil, Vetiva oil
Le, Penny Royal Oil, Pepper Oil, Peppermi
Oil, bergamot oil, Peruvian balsam,
Nzoin tincture, benzoin resinoid, boad rose
Oil, oil, hop oil, hopcon
Cleats, Hop Absolute, Marjoram Oy
, Mandarin oil, mandarin oil, mimosa concrete
, Mimosa Absolute, Mimosa Oil, Milregi
Noid, mill absolute, mill oil, musk abu
Solut, muskutuki, eucalyptus oil, yuzuoi
, Mugwort oil, lime oil, lab d'anum oil,
Lavdanum resinoid, lavender oil, lavender
Absolute, Lavandin oil, Lavandin Abso
Lute, linaloe oil, lemon oil, lemongrass
Oil, rose oil, rose absolute, raw
Concrete, rosemary oil, robeggioi
, Laurel oil, laurel leaf oil, worm
Oil, musk, spirit cat incense, dragon incense, sea tanuki incense, musk
・ Cibata and the like. <Prepared perfume> Further, a perfume component was combined.
There are the following fragrance-based bases that are compounded fragrances. Remo
Tone, lime tone, orange tone, sweet orange tone, ma
Citrus-type bases such as Darling and Bergamot
, Petitgren, Neroli, Lemongrass, Aggle
Men type, fresh type base, apple style, pi
Peach, strawberry, coconut, pineapple
Tone, raspberry tone, watermelon tone etc.
Type base, rose tone, jasmine tone, mug tone, rye
Rack tone, carnation tone, hyacinth tone, tubero
Tones, gardenia, mimosa, narciss, bio
Flora in red, Iranian, floral bouquet, etc.
Base, cinnamon bark, cinnamon leaf
Tone, clove tone, Pimento berry tone, nutmeg tone, pe
Par tone, cardamom tone, coriander tone, cumin tone etc.
Spicy type base, cedar wood style, vetiver
Tone, sandalwood tone, guaiac wood tone, woody
Woody type base such as amber and woody iris
Leather type such as su, smoky tone, quinoline tone, bani
La, Tonka, Honey, Pure Balsam
ゥ Eat type base, other Aldehi Dick Thailand
Base, amber type base, animal type base
, Anise type base, aromatic herbal tie
Base, agar type base, aqua type base,
Camphor Cineol Type Base, Green Type Base
Sauce, seed type base, herb type base, pie
Type base, patchouli type base, balsamic
Type base, mint type base, musk type base
, Moss type base, lavender type base, lina
Roll type base, resin type base, etc.
You. Further, as the fragrance solvent, ethanol,
Acetin (triacetin), MMB acetate (3-meth
Toxi-3-methylbutyl acetate), ethylene glycol
Choledibutyrate, hexylene glycol, dibutyl
Sebacate, Delchil Extra (Isopropyl Milli
State), methyl carbitol (diethylene glycol)
Monomethyl ether), carbitol (diethylene glycol)
Recohol monoethyl ether), TEG (triethylene
Glycol), benzyl benzoate, propylene glycol
, Diethyl phthalate, tripropylene glycol,
Borin (dimethyl phthalate), Deltyl Prime (I
Sopropyl palmitate), dipropylene glycol D
PG-FC (dipropylene glycol), farnese
Dioctyl adipate, tributyrin (glyceryl
Tributanoate), hydrolite-5 (1,2-pen
Tandiol), propylene glycol diacetate,
Cetyl acetate (hexadecyl acetate), ethyl
Aviate, Avaline (Methyl Aviate), Cit
Roflex A-2 (acetyltriethylcitrate
G), Citroflex A-4 (tributyl acetyl
Toreto), Citroflex No. 2 (triethylsi
Toreto), Citroflex No. 4 (tributyl
Tolate), Durafix (methyldihydroavier)
TET), MITD (isotridecyl myristate),
Polylimonene (limonene polymer), propylene glyco
And 1,3-butylene glycol. The solvent described above is added to the perfume composition in an amount of 0.1%.
９９99% by mass. Preferably, 1 to 50% by mass
Be blended. In addition, as a flavor stabilizer, dibutyl hydrogen
Droxytoluene, butylhydroxyanisole, Vita
Min E and its derivatives, catechin compounds, flavonoids
Compounds, polyphenol compounds, etc., in the fragrance composition
0.0001 to 10% by mass, preferably
Is compounded in an amount of 0.001 to 5% by mass. Among these,
Preferred stabilizers include dibutylhydroxytoluene.
It is. The fragrance composition refers to the fragrance component described above,
It is a mixture comprising a solvent, a flavor stabilizer and the like. Of the present invention
In the composition, the fragrance composition is 0.001 to 30% by mass.
%, Preferably 0.005 to 15% by mass
Be blended. From an economic viewpoint, 0 to 5% is preferable. The liquid softener composition of the present invention comprises the above (a)
To improve the adsorptivity of amine compounds contained in
To prevent hydrolysis of the ester group.
Is preferably in the range of 1.0 to 6.0.
1.5 to 5.5, more preferably pH 2.0 to 4.5
Range. For pH adjustment, use any inorganic or organic acids and
And alkalis, specifically, hydrochloric acid,
Sulfuric acid, phosphoric acid, dialkyl sulfate, alkyl sulfate, dial
Killed carbonic acid, benzoic acid, paratoluenesulfonic acid, acetic acid,
Citric acid, ring acid, succinic acid, lactic acid, glycolic acid
Which carboxylic acid, high molecular acrylic acid such as acrylic acid,
Hydroxyethanediphosphonic acid, tripolyphosphoric acid,
Citrate, ethylenediaminetetraacetic acid, triethanol
Min, diethanolamine, dimethylamine, N-methyl
Ruethanolamine, N-methyldiethanolamine,
N-methyl-N- (2-hydroxyethyl) -N- (2
-Cyanoethyl) amine, N-methyl-N- (2-hydrido)
Roxyethyl) propanediamine, 2,3-dihydroxy
C-N, N-dimethylpropylamine, N, N-di (2
Short-chain amines such as -hydroxyethyl) propanediamine
Compounds or their alkylene oxide adducts to nitrogen
A long-chain amine compound having 8 to 36 carbon atoms to be linked or the same
These alkylene oxide adducts, and the salts described above also
Can be used, alkali metal hydroxide, alkali gold
It is also possible to use genus carbonate, alkali metal silicate, etc.
Wear. Among them, hydrochloric acid, methyl sulfate, sodium hydroxide
Lium, diethanolamine, triethanolamine
preferable. The liquid softener composition of the present invention further comprises
As long as the effects of the present invention are not impaired, the viscosity
Water-soluble inorganic salt, polymer as control and stabilizer
Compounds, hydrotropes, urea, manufacturing handling
Alcohols, cyclodextrins, etc.
Which fragrance time control agent, polystyrene emulsion
As an emulsifier, opacifier, and function improver
Stopper, anti-wrinkle agent, shape retainer, drape retention
Agent, ironing improver, oxygen bleach inhibitor, brightener, whitening
Agent, fabric softening clay, antistatic agent, polyvinylpyrroli
Dye transfer inhibitors, polymer dispersants, stain release agents,
Cam dispersant, 4,4-bis (2-sulfostyryl) bif
Enildisodium (Ciba Specialty Chemicals
Fluorescent whitening agents such as Tinopearl CBS-X)
Ciba (registered trademark) manufactured by B Specialty Chemicals Co., Ltd.
Mark) TINSORB (registered trademark) FR, FD, C
IBAFAST (registered trademark), benzothiazole purple
External ray absorbent, dye fixing agent, 1,4-bis (3-aminop
Anti-fading agents such as ropir) piperazine, stain removers, textiles
Cellulase, amylase, protea as fiber surface modifier
Enzymes such as lyase, lipase, and keratinase, foam inhibitors, water
It should be able to impart silk texture and functions such as absorption and release properties
Silk protein powders, their surface modification, milk
And specifically, K-50, K-30, and K-
10, A-705, S-702, L-710, FP series
(Idemitsu Petrochemical Co., Ltd.), hydrolyzed silk solution
(Jomo Corporation), Silk Silk G Solble S (Ichimaru Fal
Kos Co., Ltd.), alkylene terephthalate and / or
Alkylene isophthalate unit and polyoxyalkylene unit
Nonionic high molecular compounds, such as
FR627 manufactured by Sangyo Co., Ltd., manufactured by Clariant Japan Co., Ltd.
Can contain a contamination inhibitor such as SRC-1
You. A container for containing the liquid softener composition of the present invention;
Then, from the following measuring cap and nozzle cap body
Can be suitably used. Where weighing
A typical example of the cap material is high-density polyethylene.
, Low-density polyethylene, polyethylene terephthalate
G, polypropylene, polycarbonate, acrylic resin
And the like, and the inner volume is 10-80 mL
desirable. The cross-sectional shape of the measuring cap is generally circular.
However, it may be a polygon such as a square, hexagon, or octagon.
No. Also, for capacity display on the inner or outer surface as required
Engraving or printing, or knurling for non-slip
Can be applied. In addition, pigments, antistatic agents,
It may also contain a collector, a slipping agent, and the like. The nozzle cap is assembled to the mouthpiece of the main body.
It is a cap body, and it is
Provide a partition wall vertically separated, and pour the contents into this partition wall
Has a spout. The material used here is high density
Polyethylene, low density polyethylene, polyethylene tele
Phthalate, polypropylene, polycarbonate,
A material such as a ril resin is selected. Also, pigments, bands
Contains antistatic agents, ultraviolet absorbers, slipping agents, etc.
You can also. The container body is made of high density polyethylene, low density
Polyethylene, polyethylene terephthalate, polypro
Of materials such as pyrene, polycarbonate, acrylic resin, etc.
Things are chosen. The cross-sectional shape of the main body is circular, elliptical, etc.
Any content, but the content is about 200-3000mL
Is used. Used with handles, labels, etc.
It can also improve the performance. Also, pigments, antistatic agents,
Can also contain UV absorbers, slipping agents, etc.
You. Further, the liquid softener composition of the present invention has a multilayer
It can also be put in a storage bag made of film. Figure 1
The liquid softener composition of the present invention can be suitably accommodated.
FIG. 1 shows a liquid softener composition of the present invention.
An example of a storage bag that can be stored properly
A storage bag containing the liquid softener composition of the present invention is
It is not limited to this. The self-supporting storage bag 1 shown in FIG.
The seal part 2 formed by heat sealing the film
It has a cutting guide wire 5 that separates the bag body 3 from the cutting portion 4
And the cutting guide wire from the liquid material storage section 6 of the storage bag body.
It has a tubular closing circuit 7 extending to a position exceeding 5.
This closed circuit 7 cuts the cut portion 4 along the cutting guide line 5.
Of liquid material with the position of the cutting guide wire 5 as the outlet 9
The road 8 is formed. The pouring path 8 has a cylindrical shape bulging outward.
Thus, the liquid transfer can be easily performed. Ma
In addition, there is a rib 11 near the pouring path,
The role of preventing the replacement container from bending and blocking the spout
It plays a part. Further, at least in the vicinity of the pouring outlet 9 of the pouring path 8
Are accompanied by seal portions 2a, 2a formed on the upper and lower sides thereof.
Therefore, it is formed so as to protrude from the storage bag main body 3.
The shape of the spout 10 is not particularly limited. Outlet location
Is particularly preferably at the upper corner of the container. Cut the spout with scissors
Storage bag that can be either cut or cut by hand
I do not care. If the film is cut by hand, the film
Or at least one string with a carbon dioxide laser
A continuous or discontinuous perforated line
You may. Also, with a spout equipped with a pipe
Is also good. The materials constituting the multilayer film include:
Property stability and aroma stability of containers, strength of storage bags, economy
Nylon, polyethylene, polyester
Propylene, ethylene vinyl alcohol copolymer, and
And polyethylene terephthalate.
You. Although two or more multilayer films are used, the same film may be used.
Two or more films may be used. Special among them
, Nylon, polyethylene, polypropylene, polye
Combination of two or more types of Tylene terephthalate
It is desirable to use. Using multi-layer film,
When manufacturing packing, the film used for each layer must be laminated
Can be done by heat and heat sealing,
It is not limited to a specific molding method. [0119] The thickness of the storage bag depends on the property stability of the contents and the incense.
20-40 from the viewpoint of air stability, strength of the package, and economy
Preferably it is in the range of 0 μm. Less than 20 μm
And the strength of the package becomes weaker,
The contents may leak. Larger than 400 μm
Not only is it not economical and burdens the environment,
The whole package becomes hard and poor in usability when used by consumers
In some cases. The method for preparing the liquid softener composition of the present invention is as follows.
Use of various methods without any particular limitation
However, in particular, JP-A-2-68137 and JP-A-5-68137
32788, JP-A-5-32789, JP-A-10-
The method described in 237762 is preferred. That is, the oil phase containing the component (a) is added to the aqueous phase.
Of the oil phase or the oil phase to a part of the aqueous phase.
To form a liquid crystal phase of the cationic activator,
A method of mixing the liquid crystal phase and the remaining aqueous phase to invert the liquid crystal phase
By the method, the liquid softener composition of the present invention can be prepared.
it can. Component (b), component (c), component (d)
Ingredients and other optional ingredients are easy to handle such as solubility
From the viewpoint of water phase or oil phase,
You. However, even those with poor solubility can be used in combination with emulsifiers and solvents.
It is possible to put them in both phases. In addition, general
It is preferable that the component (b) is put in the oil phase. Ma
In addition, the component (c) may be in either phase, but has high water solubility.
The water phase can be put in the water phase, and the water-soluble phase can be put in the oil phase.
preferable. Salts, which are viscosity control agents, are
It can be added in several portions. Split the aqueous phase
If used in water, it may be added to each aqueous phase.
And may be added after the production is completed. The liquid softener composition of the present invention can be used for ordinary laundry.
At the time of rinsing after washing is finished, fabric softener and
Used as However, liquid softener composition without cleaning process
The thing may be used alone. Detergent in the washing process,
Even with anionic detergents, nonionic detergents
And may include other surfactants and function improvers.
All detergents sold in Japan and overseas
It can be used in a rinsing step. Controls washing models
There is no limit, and it can be used for all commercially available models.
Wear. The liquid of the present invention when finishing textile products
The concentration of the softener composition used should be
From a perspective, the preparation of textiles filled in the washing bath during the rinsing process
The concentration of the component (a) is 5
It is desirable to use in an amount that will be
Good. More preferably from 10 ppm to 100 ppm
You. However, if the user uses a washing machine, the amount of textiles, the amount of water, etc.
In consideration of the desired texture, you can get the desired effect
It is most preferable to appropriately adjust the amount used. Ma
Also, when using in hand washing such as a pail,
Taking into account the amount of water and the amount of textile products,
It is possible to adjust the usage amount appropriately so as to obtain the only effect
preferable. Further, treatment with the liquid softener composition of the present invention is performed.
Before drying the clothes in the sun, dry them with a dryer.
It can also be used to reduce to some extent. However,
From the viewpoint of preventing washing wrinkles, it is not completely dried in the dryer,
Hang it on a hanger etc. in a slightly wet state, indoors or outdoors
It is preferred to be dried by hanging. Further, the liquid softener composition of the present invention is
Prevention of liquid dripping from water, reduction of cleaning work in case of accidental spillage,
For the purpose of labor saving, for example, in the rinsing process of washing
Use by encapsulating in a capsule made of a material that dissolves in the bath
You can also. In this case, the liquid softener composition of the present invention
A capsule containing about 3 to 30 ml of
One to several units can be inserted and used.
Naturally 1-2 capsules, more preferably 1 capsule
You. For those with a softener inlet,
Capsules of materials that dissolve quickly in the inlet or in the washing bath
It is preferable to select a file. Further, the liquid softener composition of the present invention may contain
Can be provided to consumers in sealed containers. So
The container of the present invention has the effects of the present invention (including all effects described later).
) Can be described. Examples of effects include
(1) In addition to flexibility, which is the basic performance of softener,
It can suppress the deterioration of flexibility even when dried in the sun
(2) good viscosity stability during storage, (3) raw
A soft finish consisting of a degradable soft substrate is obtained,
(4) Pollen, dust and air pollution by preventing static electricity from being generated on clothing
It is possible to reduce the adhesion of dyes, stains, etc.
(5) Fading and yellowing of clothing due to repeated wearing and washing
(6) less out of shape clothing,
(7) Prevents damage to clothing that can retain its appearance
(8) Improve the slipperiness of clothing
(9) Improve stiffness, (10) Appearance
(11) Formed by washing process
(12) Reduction of wrinkles during drying, (1)
3) Appearance retention during storage of clothes after drying. Ma
In addition, improved water absorption of fiber, improved iron sliding property, antibacterial property
Addition, UV protection, good aroma, long lasting aroma, etc.
Can appeal. [0127] According to the present invention, even when dried in the sun, it is excellent.
Provides excellent flexibility and excellent antistatic effect
In addition, liquid flexible made of flexible base material with good biodegradability
Agent composition is obtained. [0128] The present invention will be described below with reference to Examples and Comparative Examples.
However, the present invention is not limited to these.
Not. [Examples 1 to 54 and Comparative Examples 1 to 25] Table
1 to 1 kg of liquid softener composition using the components shown in Table 17
Was blended. First, the oil phase mixture, the aqueous phase mixture and the oil phase mixture
After mixing the mixture and the aqueous phase mixture, prepare the last component to be added
Keep it. However, oil phase mixture, water phase mixture and oil phase mixture
After mixing the product and the aqueous phase mixture, the total
Balance the aqueous phase mixture with purified water to 990 g.
Was. Then, if necessary, add hydrochloric acid (reagent 5 mol / L,
To Chemical Co., Ltd.) or sodium hydroxide (reagent 5m
ol / L, manufactured by Kanto Chemical Co., Ltd.)
And further refined so that the total mass is 1000g
Water was added. Component (a), component (b), component (c)
(General 99 synthetic undenatured alcohol (Nippon Ethanol
(Premixed with 3% by mass) and distributed in the oil phase shown below.
Components to be combined (described as oil phase) and added to the oil phase in the margin of Table 7
In the oil phase mixture containing
Water (described as an aqueous phase) and water containing an aqueous phase in Table 7
Add 40% of phase mixture to form liquid crystal phase of cationic activator
And then mixing the liquid crystal phase with the remaining aqueous phase to form a liquid crystal phase.
Depending on the method of phase inversion, the liquid softness shown in Tables 18 to 21
Agent composition was obtained. In addition, the oil phase mixture and the aqueous phase mixture
The mixture was heated to 60 ° C and mixed. In preparing the above composition, pad
Using a mixer, before and after liquid crystal phase inversion. P. In M
Mix for 5 minutes each. Further, the liquids described in Tables 20 and 21
The softener composition contains a nonionic surfactant as a component (d).
0 to 5% by mass (aqueous phase), amphoteric surfactant 0 to 5% by mass
% (Oil phase), 0.6% by mass of calcium chloride (Toku Co., Ltd.)
Yama; 0.3% by mass of water phase, oil phase mixture and aqueous phase mixture
After mixing (after inverting the liquid crystal phase), 0.3% by mass was added. However
Then, about Example 45, anhydrous sodium sulfate (pure
Chemical Co., Ltd.) was used.
Uses magnesium sulfate (Junsei Chemical Co., Ltd.), ethylene
Glycol 5% by mass (Mitsubishi Chemical Corporation (oil phase)), fragrance
Composition 0.6% by mass (oil phase), polyethylene glycol
(Dow Chemical; average molecular weight 1500) 0.2% by mass
(Aqueous phase), Caisson CG (Rohm & Haas Co., Ltd.)
0.02% by mass (aqueous phase), Myside Pharma BP
(BASF) 0.02% by mass (aqueous phase), pigment 5-30
ppm (aqueous phase), BHT (Sumitomo Chemical Co., Ltd.) 0.02 quality
% (Oil phase) and other ingredients. (A) ~
(D) The amount of each component is shown as it is. this
The following tests were performed on each of these compositions. result
Are also shown in Tables 18 to 21. The component (a) is an alkano listed in Table 1.
Amine and the fatty acids and / or fatty acid
Using the tyl ester, the combination described in Table 3 below is used.
Reacted by esterification, neutralization and quaternization
A composition was prepared. The component (b) is the same as the fatty acid of (a).
At 190 ° C. for 10 hours. (C) Component is a commercial product
And what was prepared according to a conventional method was used. (1) Esterification reaction Alkanolamine and fatty acid or fatty acid methyl ester
Stell and a specific molar ratio.
10 hours at 190 ° C, in case of fatty acid methyl ester
The reaction was performed at 190 ° C. for 6 hours. Also, fatty acid methyl es
In the case of ter, alkanolamine and fatty acid as catalysts
0.1% by mass of KOH based on the total amount of methyl ester
added. (2) Neutralization reaction of esterification reaction product While stirring the esterification reaction product, acid or alcohol
Neutralized by adding potash. After neutralization, chelating agent
Hydroxyethane diphosphonic acid (lion
83.3 ppm, EDTA 50 ppm
Was. (3) Quaternization reaction 1) When dimethyl sulfate is used as a quaternizing agent 0.98 based on the number of moles of the esterification reaction product.
2 hours at 100 ° C while adding twice the molar amount of dimethyl sulfate
Reacted. After the reaction is completed, hydroxy
Ethanediphosphonic acid (Lion Corporation) 83.3 pp
m, EDTA was added at 50 ppm. 2) When methyl chloride is used as the quaternizing agent
Combination For the number of moles of the esterification reaction product of the above reaction product,
100 ° C while blowing 1.1 times mole of methyl chloride
For 10 hours. After completion of the reaction, as a chelating agent
Hydroxyethane diphosphonic acid (Lion Corporation) 8
3.3 ppm and 50 ppm of EDTA were added. <Method of Testing Fabric Finishing Composition for Textile Products>
Law> (1) Flexibility test of sun-dried fiber
1 and the same below) Commercial cotton towel and cashmere acrylic jersey (mass ratio
7/3, 1.5 kg in total)
Using a standard amount of “P” (manufactured by Lion Corporation)
Using a rinsing machine (Mitsubishi Electric Corporation CW-C30A1-H)
And washed. Then, for the third time of rinsing,
7 g of the raising agent composition is added to 30 L of water, and 3 minutes
During that time, the fabric was soft-finished. Washing and rinsing
In the process, dehydration was performed for 1 minute. Then, in the sunlight 6
Hung and dried for hours. Dry weather is fine, south wind
2 m, the average temperature was 26 ° C., and the average humidity was 60%.
Di-hardened tallow dimethyl ammonium chloride (lion
For textile products containing 15% of Akzo Arcard 2HT)
Cotton towel, cashmere finished with fabric softener composition
5 panelists with Ron acrylic jersey as a control
Performs paired comparisons according to the following criteria and is flexible
Was evaluated. In addition, the dried test cloth or clothing is 20
℃, 35% humidity in the room, the next day after about 15 hours
In addition, a test was conducted in the storage room and the average
The rounded values are shown in the table. The same test applies to the following tests.
Went on the matter. <Evaluation Criteria> +2: clearly softer than the control +1: slightly softer than the control 0: almost the same as the control -1: the control is slightly softer -2: Control is clearly softer (2) Antistatic test (Test 2) According to JIS-L-1094A, flexible for textile
Charges the clothing finished with the finish composition and charges it
The half-life of the pressure was measured. The test cloth is sun-dried as described above.
Acrylic jersey was used. (A) Finish only with component
The half-life is reduced to less than 1/2 for the half-life of the treated fiber
+2 if the half-life is equal to 半
0 if equivalent half-life is shown, half-life is 1-2 times
-1 and -2 when the half-life was twice or more. (3) Finishing performance test 1) Washing-rinsing-dehydration using a commercially available polyester cloth
-The drying step is performed twice as in (1) and the following tests are performed.
Was. Di-hardened tallow dimethyl ammonium chloride (La
Fiber containing 15% of Aeon Akzo Arcard 2HT)
Polyester finished with fabric softener composition
The slip property of the fiber (Test 3) was compared with
5 paired comparisons were conducted according to the following evaluation criteria.
The finish performance was evaluated. 2) Using a commercially available polo shirt (100% cotton)
I felt that I was wearing clothes on a hanger,
Can you maintain firmness and firmness (hardness) (Test 4)
And that wrinkles formed in the washing process are reduced (washing
1) Except for the test (Test 5)
The same was done. 3) Using a commercially available T-shirt (100% cotton)
Washing, rinsing, dehydrating and drying steps were performed 20 times
The clothes, hung the clothes, or the color of the clothes
No change in color (fading) (Test 6), clothing out of shape
Test that the appearance is retained (appearance retention)
(Test 7) Except having performed, it carried out similarly to 1). 4) Washing using commercial cotton towel (100% cotton)
Performing the steps of -rinsing-dehydrating-drying 20 times; and
Except that the degree of yellowing was tested (Test 8), 1) and
Performed similarly. 5) Using a commercially available cotton towel, 20
Tested indoor drying at 35 ° C, 35%, flexibility
(Test 9) was performed in the same manner as in 1), except that the test was performed. <Evaluation Criteria> +2: clearly better than control +1: slightly better than control 0: almost the same as the control -1: the control is slightly better -2: the control is clearly better [0144] [Table 1] [0145] [Table 2] [0146] [Table 3][0147] [Table 4] [0148] [Table 5] [0149] [Table 6][0150] [Table 7][0151] [Table 8][0152] [Table 9][0153] [Table 10][0154] [Table 11][0155] [Table 12][0156] [Table 13][0157] [Table 14][0158] [Table 15][0159] [Table 16][0160] [Table 17] [0161] [Table 18][0162] [Table 19][0163] [Table 20] [0164] [Table 21]

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic plan view illustrating a configuration example of a storage bag suitable for storing the liquid softener composition of the present invention. [Explanation of symbols] 1 Storage bag

   ────────────────────────────────────────────────── ─── Continuation of front page    (72) Inventor Ken Sumita             Rio, 1-3-7, Honjo, Sumida-ku, Tokyo             Incorporated F term (reference) 4L033 AC02 BA16 BA19 BA46 BA53                       CA59 CA61

Claims (1)

Claims 1. (a) An esterification reaction product of an alkanolamine represented by the following general formula (1) and a fatty acid or a fatty acid methyl ester, wherein the fatty acid or the fatty acid methyl ester is The average iodine value is 10 to 80, and the ratio of cis isomers of unsaturated groups is less than 50% 1
Or more unsaturated fatty acids, unsaturated fatty acids and saturated fatty acids,
One or more unsaturated fatty acid methyl esters or esterified reaction products which are unsaturated fatty acid methyl esters and saturated fatty acid methyl esters, neutralized products of the esterification reaction products, and further quaternized the esterification reaction products One or more compounds selected from the quaternized reaction products described above; (However, in the above formula (1), at least one of R ¹ , R ² , and R ³ is a hydroxyalkyl group in which a hydrogen atom of an alkyl group having 2 to 6 carbon atoms is substituted with at least one hydroxyl group. A, B and C each independently have 2 carbon atoms
And o, p, and q are each independently an integer of 0 to 10. (B) one or more unsaturated fatty acids or a mixed fatty acid of an unsaturated fatty acid and a saturated fatty acid having an average iodine value of 10 to 80 and a ratio of cis isomers of the unsaturated group of less than 50%, and / or Or a liquid softener composition comprising: an esterification reaction product of the unsaturated fatty acid or the mixed fatty acid with a lower alcohol; and (c) a silicone having a polyoxyalkylene group in a molecule. object.