JP2003113398A - Detergent composition for drainpipe - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a detergent composition for drainpipe, excellent in adhesive retention, realizing good detergency, having little viscosity shift due to temperature variation, capable of supplying preparations having stable quality and so suitable for applying to drainpipes in a bathroom, a lavatory and a kitchen. SOLUTION: This detergent composition for drainpipe is characterized by containing (1) 0.1-10 mass% alkali metal hypophosphite, (2) 0.1-5 mass% alkaline chemicals and (3) 0.1-5 mass% surfactant and having 10-120 ms/cm electrical conductivity at 25 deg.C.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel drain pipe cleaning composition, and more specifically, it exhibits excellent adhesion and retention properties, has a small viscosity change with temperature change, and has good stability over time. The present invention relates to a drain pipe cleaning composition that can be suitably used for drain pipes in bathrooms, washbasins, kitchens, and the like.

[0002]

PRIOR ART AND PROBLEM TO BE SOLVED BY THE INVENTION Bathroom,
In drainage pipes of wash basins, kitchens, etc., stains caused by microorganisms and hair, soap residue, oil, etc. are accumulated and clogged. In order to deal with these phenomena, a method of decomposing soil with enzymes and microorganisms, a method of using an alkaline carbonate and an acid, etc. are known, but these methods are insufficient in terms of detergency. A method using an alkali metal chlorite and an alkali has excellent detergency and is widely used as a drain pipe cleaning agent.

At this time, in order to improve the cleaning power for dirt adhering to the wall surface of the pipe, it is necessary to improve the retention property of adhering to the vertical surface or the inclined surface. As a method for increasing the viscosity of a composition of an alkali metal hypochlorite, a composition in which a natural clay mineral and a surfactant are blended (JP-A-60-12470).
No. 0) and an example in which a specific cross-linking polymer is blended (JP-A-63-108100). However, all of these conventional compositions have a problem that when they are stored at low temperature for a long period of time, the thickening component precipitates in the lower part and the original uniform state is not restored.

Further, examples have been disclosed in which a specific surface active agent as a thickening component, and a pH stabilizer, an organic counterion, and the like are mixed therein (JP-A-57-8298 and JP-A-60).
-92398, JP-A-63-175099, JP-A-06-322399, JP-A-07-331294,
Tokuyo Hei 09-502747, Tokuyo Hei 09-51099
7 publication). However, all of the compositions containing these surfactants have a problem that a stable quality and a retention property due to adhesion cannot be obtained because the viscosity changes greatly with the temperature change.

Therefore, an object of the present invention is to exhibit excellent adhesion and retention properties to an object to be soiled such as a vertical surface or an inclined surface, and the viscosity change due to temperature change is small, and the stability with time is good. Another object of the present invention is to provide a drain pipe cleaning composition.

[0006]

Means for Solving the Problems As a result of intensive studies to solve the above problems, the inventors of the present invention each contain a specific amount of an alkali metal hypochlorite, an alkali agent, and a surfactant, The drain pipe cleaning composition having an electric conductivity adjusted to a specific range at 25 ° C. exhibits excellent adhesion and retention properties on a dirty object such as a vertical surface or an inclined surface, and has a small viscosity change with temperature change. Then, they found that the stability was good, and completed the present invention. That is, according to the present invention, (1) an alkali metal hypochlorite salt; 0.1 to 10
% By mass, (2) alkali agent; 0.1-5% by mass, (3)
Provided is a drainage pipe cleaning composition comprising 0.1 to 5 mass% of a surfactant and having an electric conductivity of 10 to 120 ms / cm at 25 ° C.

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described in more detail below. Examples of (1) alkali metal hypochlorite used in the present invention include sodium hypochlorite and potassium hypochlorite, and sodium hypochlorite is particularly preferable. The content of alkali metal hypochlorite is
Usually, 0.1 to 10 mass% of the entire drain pipe cleaning composition,
It is preferably in the range of 1 to 5% by mass. Content is 0.1
If the amount is less than 10% by mass, the detergency is insufficient, and the amount is 10% by mass.
Even if it exceeds, the detergency is not particularly improved.

The alkali agent (2) used in the present invention is not particularly limited, but examples thereof include caustic alkali and silicates. Sodium hydroxide as caustic,
Potassium hydroxide and the like are used as the silicate, and sodium metasilicate and the like are used. Among these, sodium hydroxide is particularly preferable. The content of the alkaline agent is usually 0.1 to 5% by mass, preferably 0.1% by weight of the entire drain pipe cleaning composition.
It is in the range of 5 to 3 mass%. If the content is less than 0.1% by mass, stability over time will deteriorate, and if it exceeds 5% by mass, adverse effects on the skin and mucous membranes of the eyes may occur.

The surfactant (3) used in the present invention is not particularly limited, and for detergents such as anionic surfactants, nonionic surfactants, amphoteric surfactants and cationic surfactants. The following surfactants (a) to (c): (a) an alkali metal salt of a fatty acid, (b) an amine oxide, and (c) an alkylbenzene sulfonate are mixed. It is preferable to use.

The component (a), which is an alkali metal salt of a fatty acid, is not particularly limited, but an alkali metal salt of a fatty acid containing a straight chain or branched chain unsaturation having 8 to 20 carbon atoms is preferable. Suitable alkali metal salts of fatty acids containing unsaturation include, for example, coconut fatty acid containing 12 carbons on average (derived from coconut oil) and tallow fatty acid containing 18 carbon atoms on average (derived from tallow fat). ), Sodium salts such as oleic acid and linoleic acid, and potassium salts. These alkali metal salts of unsaturated fatty acids may be used alone, for example, a mixture of unsaturated fatty acids such as oleic acid and linoleic acid with saturated fatty acids such as lauric acid, myristic acid, palmitic acid and stearic acid. Sodium salt, potassium salt, etc. may be used. The proportion of this unsaturated fatty acid salt is 2% by mass or more in the component (a), especially 7
It is preferably at least mass%. If the proportion of unsaturated fatty acids is too small, the viscosity of the system is lowered, and as a result, the adhesion retention property is deteriorated, which is not preferable. The content of the (a) alkali metal salt of fatty acid is in the range of 0.01 to 3% by mass, preferably 0.1 to 2% by mass, based on the entire drain pipe cleaning composition. If the content of the component is less than 0.01% by mass, the retention of adhesion will be poor, and if it exceeds 3% by mass, the stability of the system will be deteriorated.

As the amine oxide as the component (b),
Although not particularly limited, a tertiary amine oxide is preferable, and a tertiary amine oxide represented by the general formula R ₁ R ₂ R ₃ N → O is more preferable. In the above general formula, examples of the alkyl group having 8 to 20 carbon atoms represented by R ₁ include an octyl group, a decyl group, a dodecyl group,
Examples thereof include a mixture of tetradecyl group, hexadecyl group, and alkyl groups having different carbon numbers derived from natural products. Among these, dodecyl group and coconut oil-derived alkyl group are preferable. R ₂ and R ₃ are alkyl groups having 1 to ₃ carbon atoms, and examples thereof include a methyl group, an ethyl group and a propyl group, but a methyl group is preferable. Specific examples of the tertiary amine oxide include coconut dimethylamine oxide, lauryldimethylamine oxide and the like. The content of the (b) amine oxide is 0.01 to 5% by mass, and preferably 0.1 to 5% by mass of the entire drain pipe cleaning composition.
Is in the range of 3% by mass. If the content is less than 0.01% by mass, the adhesion retention property will be poor, and if it exceeds 5% by mass, the stability of the alkali metal hypochlorite will deteriorate over time.

The alkylbenzene sulfonate as the component (c) is not particularly limited, but the alkyl group substituted on the benzene ring has 8 to 20 carbon atoms, preferably 12 to 1 carbon atoms.
It is 4 and the linear one is preferable. The content of the (c) alkylbenzene sulfonate is 0.01 to 1% by mass, preferably 0.05, of the entire drain pipe cleaning composition.
Is in the range of 0.5 mass%. Content is 0.01% by mass
If it is less than 1% by weight, the retention of adhesion is poor, and if it exceeds 1% by mass, the stability of the system is deteriorated.

The drain pipe cleaning composition of the present invention has an electric conductivity at 25 ° C. of 10 to 120 ms / cm, preferably 20 to 100 ms / cm, more preferably 40 to 80 ms.
Adjusted to ms / cm. Electrical conductivity is 10 ms / cm
If it is less than 120 m, the composition cannot be thickened properly,
When it exceeds s / cm, the viscosity of the composition decreases with increasing temperature,
Also, it is not preferable because the stability of the system over time cannot be suppressed.

In order to adjust the electric conductivity within a predetermined range, the drain pipe cleaning composition of the present invention has a chlorine ion content in terms of sodium chloride molar concentration relative to the molar concentration of the alkali metal hypochlorite salt. It is preferably 0.05 to 1.2 times, more preferably 0.1 to 0.5 times.

In order to make the content of chlorine ions 1.2 times or less in terms of sodium chloride molar concentration with respect to the molar concentration of alkali metal hypochlorite, the alkali metal hypochlorite salt solution is used as a raw material. There is a method of adjusting the content of sodium chloride present in, for example, when producing a sodium hypochlorite solution by absorbing chlorine gas into a sodium hydroxide solution, the concentration of sodium hypochlorite produced The content of sodium chloride can be adjusted by various settings. In addition, the sodium chloride content can be adjusted by separating the produced sodium hypochlorite solution with a centrifuge, or chlorine ions can be removed by an electrodialysis method.

The viscosity of the drain pipe cleaning composition of the present invention at 25 ° C. is 20 to 300 mPa · s, preferably 50 to 250 mPa · s. Viscosity is 20 mPa
If it is less than s, the adhesion retention property is poor, and if it exceeds 300 mPa · s, the stability of the system is deteriorated.

The drain pipe cleaning composition of the present invention contains the above-mentioned components (1) to (3) as essential components, but as other builders for improving the cleaning performance, toluene sulfonate, xylene sulfonate, etc. Aromatic sulfonates, EO and PO adducts of lower alcohols, solvents such as propylene glycol, EDTA, citric acid or its salts, chelating agents such as glycolic acid, organic polymers, thickeners such as inorganic clay minerals, BHT It is also possible to mix optional components such as antioxidants, dyes, and fragrances. Compounds of these optional components are usually used in detergents, and may be any as long as they do not impair the effects of the present invention,
It is not particularly limited. Further, the compounding amounts of these optional components can be set to normal amounts within a range that does not impair the effects of the present invention. The detergent of the present invention can be prepared by a conventional method by adding a balanced amount of water to the above-mentioned essential components and other optional components.

The drain pipe cleaning composition of the present invention usually contains
Add perfume. A list of perfume raw materials used as perfumes can be found in various publications, eg “Perfume and
"Flavor Chemicals", Vol. Ia
nd II, Steffen Arctander, Al
lured Pub. Co. (1994) and "Synthetic Perfume Chemistry and Product Knowledge", Genichi Indo, Kagaku Kogyo Nipposha (1996) and "Perfume and Fla.
vor Materials of Natural
Origin ", Steffen Arctande
r, Allured Pub. Co. (1994) and "Aroma Encyclopedia", edited by The Japan Fragrance Association, Asakura Shoten (198)
9) and “Perfumery Material
Performance V. 3.3 ", Boelen
s Aroma Chemical Information
Ion Service (1996) and "Flow
er oils and Floral Compou
nds In Perfumery ", Danute
Lajaujis Anonis, Allured P
ub. Co. (1993) and the like, each of which is incorporated by reference. Typical examples of the fragrances will be given below, but the fragrances are not limited to these.

<Hydrocarbon compound> Ocimene, dihydromyrcene, farnesene, sedrene, α-pinene, β-
Pinene, limonene, dipentene, camphene, ferlandrene, terpinene, 3-carene, terpinolene, bisabolene, β-caryophyllene, kadinene, valensen, tsuyopsene, guayen, aloocimene, myrcene, longifolene, veldrasin (1,3,5-undecatriene ), P-cymene, 4-isopropyl-1-
Methyl-2-propenylbenzene, diphenyl, diphenylmethane, orange terpene, lemon terpene, bergamot terpene, peppermint terpene, spearmint terpene, lime terpene, vetiver terpene, rose wax, jasmine wax, limonene dimer,
Pentane, hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, Icosan, henicosan, docosan, tricosan, tetracosan, pentacosan, hexacosan, octacosan, octacosan, nococosan.
Examples include triacontane.

<Alcohol type compound> 3-methyl-1-
Pentanol, geraniol, cedrol, citronellol, rosinol, nerol, dihydrolinalool, linalool, tetrahydrolinalool, dimethyloctanol, tetrahydromugol, mugol, myrcenol, dihydromyrcenol, osimenol, tetrahydromyrcenol, lavandulol, isodihydro Lavandulol, hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), ethyl linalool, isopulegol, terpineol, dihydroterpineol, terpineol-4, perilla alcohol,
4-tunanol, 3-tunanol, farnesol, nerolidol, α-bisabolol, β-caryophyllene alcohol, santalol, betiverol, cedrenol, patchouli alcohol, dihydrocarbeol, phytol, isophytol, sclareol, carveol, menthol, 1-heptanol , 2-heptanol, 3-heptanol, 1-octanol, 2-octanol, 3-octanol, 2-ethylhexanol,
1-nonanol, 2-nonanol, isononyl alcohol (3,5,5-trimethyl-1-hexanol), 1
-Decanol, 1-undecanol, 2-undecanol, 1-dodecanol, prenol (3-methyl-2-
Butene-1-ol), 2-methyl-3-butene-2-
All, β-pentenol (1-penten-3-ol), leaf alcohol (cis-3-hexenol), trans-2-hexenol, trans-3
-Hexenol, cis-4-hexenol, 2,4-
Hexadiene-1-ol, matsutakeol (1-octen-3-ol), cis-6-nonenol, cucumber alcohol (2,6-nonadienol), androl (1-nonen-3-ol), rosalva (9 -Decenol), 1-undecenol, undecabertol (4-methyl-3-decen-5-ol), ocilol (3,7-dimethyl-7-methoxy-2-octanol), santalinol (2-methyl-). 4- (2,2,3
-Trimethyl-3-cyclopenten-1-yl) -2-
Butene-1-ol), p, α-dimethylbenzyl alcohol, 2,2,6-trimethylcyclohexyl-3-
Hexanol, 1,2-pentanediol, benzyl alcohol, anis alcohol, β-phenylethyl alcohol, styralyl alcohol (1-phenyl-1-hydroxyethane), hydratropa alcohol, methyl β
-Phenylethyl alcohol, α-propylphenylethyl alcohol, vanillyl alcohol, decahydro β-
Naphthol, furfuryl alcohol, 3-methyl-1-
Phenyl-3-pentanol, amylcinnamic alcohol, cinnamic alcohol, phenoxanol (3-methyl-5-phenylpentanol), 1,2-
Pentanediol, 2-ethylhexanol, dimethol (2,6-dimethylheptanol), 3,6-dimethyl-3-octanol, cohinol (3,4,5,6,6)
6-pentamethyl-2-heptanol), brahamanol (methyltrimethylcyclopentenylbutanol),
Bactanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-butene-
1-ol), sandalol (3-methyl-5- (2,
2,3-Trimethylcyclopent-3-en-yl)-
Pentan-2-ol), cyclohexylethyl alcohol, apopachon (p-isopropylcyclohexanol), fluoralol (2,4-dimethyl-3-cyclohexene-1-methanol), pachone (p-tert).
-Butylcyclohexanol), Belldol (o-te
rt-butylcyclohexanol), mayol (p-
Isopropylcyclohexylmethanol), cyclomethylene citronellol, ambrinol (2,5,5-trimethyl-octahydro-2-naphthol), methylsandeflor (5'or6'-methylnorborn-5 ')
-En-2-yl) -2-methylpent-1-ene-3
-Ol), timbelol (2,2,6-trimethylcyclohexyl-3-hexanol), polysanthol (3,3-dimethyl-5- (2,2,3-trimethyl-
3-Cyclopenten-1-yl) -4-pentene-2-
All), hydroxycitronellol, nonadyl (6,8-dimethyl-2-nonanol), isopulegol, isocyclogeraniol, myrtenol, nopol (6,6-dimethylbicyclo [3.1.1] hept-2)
-Ene-2-ethanol), pinocarbeol, α-phenalkyl alcohol, borneol, isoborneol, patchhomint (2- (3,3-dimethylbicyclo [2.2.1] hept-2-ylidene) ethanol),
Camecol (trimethylnorbornanemethanol), dimethylcyclomol, Santarex T (isocamphylcyclohexanol), geranyl linalool, cumin alcohol, 2-methoxyphenylethyl alcohol,
Phenoxyethyl alcohol (1-hydroxy-2-phenoxyethane), α, α-dimethylphenylethyl alcohol, isobutylbenzylcarbinol, p-methylbenzylcarbinol, hydrocinnamic alcohol, centifold (1,1-dimethyl-3) -Phenyl propanol-1), muguet alcohol (2,2-
Dimethyl-3-phenylpropanol), phenylhexanol, decahydro β-naphthol, AR-1 (3,
6-dimethyloctane-3-ol), avitol (hydroabietyl alcohol), α-propylphenylethyl alcohol, p-methyldimethylbenzylcarbinol, mugetanol (1- (4-isopropylcyclohexyl) ethanol), fluorol (2- Isobutyl-
4-hydroxy-4-methyltetrahydropyran), propylene glycol, dipropylene glycol, hexylene glycol and the like.

<Phenolic and phenol ether compounds> Anisole, estragal, chabicol,
Anethole, cresol, carvacrol, p-cresol, p-cresyl methyl ether, β-naphthol methyl ether, β-naphthol ethyl ether, β-
Naphthol isobutyl ether, veratrol (1,2
-Dimethoxybenzene), 1,3-dimethoxybenzene, 1,4-dimethoxybenzene, catechol, resorcinol, guaiacol, valspice (4-methylguaiacol), 4-ethylguaiacol, orcinyl-3.
(3-methoxy-5-methylphenol), thymol,
Methylthymol, propenyl guaetol (trans
-2-ethoxy-5- (1-propenyl) -phenol), o-ethylphenol, m-ethylphenol,
p-ethylphenol, 2-tert-butylphenol, syringol (2,6-dimethoxyphenol),
Hydroquinone dimethyl ether, resorcinol dimethyl ether, eugenol, isoeugenol, dihydroeugenol, methyleugenol, methylisoeugenol, ethylisoeugenol, benzyleugenol, benzylisoeugenol, diosphenol, hinokitiol, banitrop (1-ethoxy-2-hydroxy-4-propenyl Benzene), shogaol,
Examples thereof include gingerol, acetyleugenol, acetylisoeugenol safrole, isosaflor, diphenyl oxide, vetiver ether (tert-butylhydroquinone dimethyl ether) and the like.

<Aldehyde compound> Citronellal,
Citral, 3,7-dimethyl-1-octanal, hydroxycitronellal, methoxycitronellal, perilaldehyde, myrtenal, caryophyllene aldehyde, n-hexanal, 2-methylbutanal, isovaleraldehyde, n-valeraldehyde, acetaldehyde. , N-heptanal, n-octanal, n-nonanal, 2-methyloctanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal, dodecanal, 2-methyldecanal, 2-methylundecanal, tride Canal, tetradecanal,
2-pentenal, cis-3-hexenal, tra
ns-2-hexenal, trans-2-heptenal, 4-heptenal, trans-2-octenal, trans-2-nonenal, cis-6-nonenal, melonal (2,6-dimethyl-5-heptenal), trans-4 -Decenal, cis-4-decenal, trans-2-decenal, grinal (2,5,6-trimethyl-4-heptenal), 10
-Undecenal, trans-2-Undecenal,
trans-2-dodecenal, mandarin aldehyde (3-dodecenal), trans-2-tridecenal, adoxal (2,6,10-trimethyl-9-undecen-1-al), 2,4-hexadienal,
2,4-heptadienal, 2,4-octadienal, 2,4-nonadienal, 2,6-nonadienal, 2,4-decadienal, 2,4-undecadienal, 2,4-dodecadienal, geralaldehyde (5 ，
9-dimethyl-4,8-decadienal), trimenal (3,7,9-trimethyl-2,6-decadiene-1)
-Earl), oncidar (2,6,10-trimethyl-5,9-undecadienal), bergamar (α-
Methylene citronellal), camphorene aldehyde,
Cyclocitral, isocyclocitral, safranal (2,6,6-trimethyl-1,3-cyclohexadiene-1-carboxaldehyde), muguealdehyde (6,10-dimethyl-3-oxa-9-undecenal), geranyloxy Acetaldehyde, tripral (dimethyltetrahydrobenzaldehyde), chrysantal (3-propylbicyclo [2,2,1] -5-heptene-2-carboxaldehyde), centenal (methoxydicyclopentadienecarboxaldehyde), dupicar (4-tricyclodecyl) Ridenbutanal), 4- (4-methyl-3-cyclohexenylidene-1) pentanal, mylacaldehyde (4 (3)
-(4-Methyl-3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), setonal (trimethylcyclohexenemethylbutanal), inonal (2-methyl-4- (2,6,6-trimethyl) −
1 (2) -cyclohexenyl) -butenal), terestral (4-cyclooctene-1-carboxaldehyde), benzaldehyde, p-tolylaldehyde, phenylacetaldehyde, trifernal (3-phenylbutanal), cuminaldehyde, p -Methylphenylacetaldehyde, p-isopropylphenylacetaldehyde, hydratropaldehyde, p-methylhydratropaldehyde, p-isopropylhydratropaldehyde, phenylpropionaldehyde, β-methylhydrocinnamic aldehyde, jasmolandi (2
-Methyl-3- (4-methylphenyl) -propanal), burgeonal (p-tert-butylhydrocinnamic aldehyde), cyclamenaldehyde (2
-Methyl-3- (p-isopropylphenyl) -propionaldehyde), Florarozone (p-ethyl-α, α)
-Dimethylhydrocinnamic aldehyde), Suzral (p-isobutyl-α-methylhydrocinnamic aldehyde), cinnamic aldehyde, salicylaldehyde, anisaldehyde, o-methoxybenzaldehyde, o-methoxycinnamic aldehyde, canthoxal (2-methyl -3- (p-methoxyphenyl) -propanal), vanillin, ethylvanillin, methylvanillin (3,4-dimethoxybenzaldehyde), heliotropin, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde) ), Phenoxyacetaldehyde, p-methylphenoxyacetaldehyde, furfural, 5-methylfurfural, 5-
Hydroxymethyl-2-furfural, furyl acrolein, lyral (4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), bernaldehyde (1-methyl-4-)
(4-methylpentyl) -3-cyclohexenecarboxaldehyde), homomylacaldehyde (1-methyl-4 (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde), junipearl (4
(5) -Formyl-7,7,9-trimethylbicyclo [4.3.0] -nonene), vertoral (octahydro-4,7-methanoindenecarboxaldehyde), lilial (p-tert-butyl-α-). Methylhydrocinnamic aldehyde), Mefuranal (3-
Methyl-5-phenylvaleraldehyde), englandal (4-methyl-2-phenyl-2-pentenal),
Cocar (5-methyl-2-phenyl-2-hexenal), α-methylcinnamic aldehyde, α-butylcinnamic aldehyde, α-amylcinnamic aldehyde, α-hexylcinnamic aldehyde, formylethyltetramethyltetralin (6 -Ethyl-7-formyl-1,1,4,4-tetramethyl-1,2,
3,4-tetrahydronaphthalene) and the like.

<Acetal-based and ketal-based compounds> Magnolane (2,4-dimethyl-4,4a, 5,9b-tetrahydroindeno [1.2d] -1,3-dioxane), anthoxane (4-isopropyl-) 5,5-dimethyl-1,3-dioxane), indoflor (dihydroindenyl-2,4-dioxane), boasanbrenforte (formaldehyde cyclododecylethyl acetal), acetaldehyde diethyl acetal, leaf acetal (acetaldehyde ethylhexenyl acetal). ), Acetaldehyde ethylhexyl acetal, citronellyl methyl acetal, elletal (acetaldehyde ethyl linalyl acetal), Bonalox (2,4-dioxane-3-methyl-7,10-methanospiro [5.5]. Decane), efetal (acetaldehyde ethyl phenyl acetal), acetaldehyde ethyl isoeugenyl acetal, acetal R (acetaldehyde phenyl ethyl n-propyl acetal), fluoropearl (acetaldehyde 2-phenyl-2,4-pentanediol acetal), spiroflor ( 3-Ethyl-2,4-dioxaspiro [5.
5] undecene-8-ene), ethyldimethyldioxaspiroundecene, herboxane (2-butyl-4,
4,6-trimethyl-1,3-dioxane), caranal (2- (2,4-dimethylcyclohex-3-cene-1)
-Yl) -5-methyl-5 (1-methylpropyl) 1,
3-dioxane), hexanal dimethyl acetal,
Hexanal diethyl acetal, hexanal propylene glycol acetal, carotene (4,7-dihydro-2- (3-pentanyl) -1,3-dioxepin), 2-hexenal diethyl acetal, cis-
3-hexenal diethyl acetal, heptanal dimethyl acetal, heptanal diethyl acetal,
Heptanal ethylene glycol acetal, 2-hexyl-5-methyl-1,3-dioxolane, 5-methyl-5-propyl-2- (1-methylbutyl) -1,3-
Dioxane, octanal dimethyl acetal, octanal diethyl acetal, nonanal dimethyl acetal, nonanal diethyl acetal, decanal dimethyl acetal, decanal diethyl acetal, 2-
Methyl undecanal dimethyl acetal, dodecanal dimethyl acetal, citral dimethyl acetal, citral diethyl acetal, citral propylene glycol acetal, citronellal cyclomonoglycol acetal, hydroxy citronellal dimethyl acetal, hydroxy citronellal diethyl acetal, cis-3- Hexenal diethyl acetal, benzaldehyde dimethyl acetal, benzaldehyde diethyl acetal, benzaldehyde propylene glycol acetal, benzaldehyde glycerin acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde ethylene glycol acetal, phenylacetaldehyde diisobutyl acetal, phenylacetal Toaldehyde propylene glycol acetal, phenylacetaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde glyceryl acetal, resedabody (phenylacetaldehyde-2,4-dihydroxy-2-methylpentane acetal), 3-phenylpropionaldehyde dimethyl acetal, hydratropa Aldehyde dimethyl acetal, hydratropaldehyde aldehyde ethylene glycol acetal, osminal DMA (amylcinnamic aldehyde dimethyl acetal), osminal DEA
(Amylcinnamic aldehyde diethyl acetal), heliotropin dimethyl acetal, heliotropin diethyl acetal, vanillin propylene glycol acetal, verdoxane (2,2,5,5-tetramethyl-4-isopropyl-1,3-dioxane), amber sage (4,7-Dihydro-2-isopentyl-
2-Methyl-1,3-dioxepin), acetoketal (2,5,5-trimethyl-2-phenyl-1,3-dioxane), jasmonan (2-butyl-4-dioxaspiro [4.4] nonanone), Freiston (Ethyl-
2,4-dimethyl-1,3-dioxolane-2-acetate), fructon (ethyl-2-methyl-1,3-dioxolane-2-acetate) and the like can be mentioned.

<Ketone-based compound> Acetyl caryophyllene, carvone, pulegone, piperitenone, piperiton,
Menthone, Shaw Brain, Oxocedran, Isolongiforanone, Nootkatone, 2-heptanone, 2-pentanone, 3-hexanone, 3-heptanone, 4-heptanone, 2-octanone, 3-octanone, 2-nonanone,
3-nonanone, 2-undecanone, 2-tridecanone,
Methyl isopropyl ketone, ethyl isoamyl ketone,
Mesityl oxide, butylideneacetone, methylheptadienone, methylheptenone, dimethyloctenone,
Coabon (4-methylene-3,5,6,6-tetramethyl-2-heptanone), geranylacetone, farnesylacetone, acetoin, butyroin (5-hydroxy-4-octanone), methyl lavender ketone (3-hydroxymethyl-). 2-nonane), diacetyl, 2,3-
Pentadione, 2,3-hexadione, 3,4-hexadione, 2,3-heptadione, acetylisovaleryl, amylcyclopentanone, amylcyclopentenone, 2-cyclopentylcyclopentanone, hexylcyclopentanone, fluuramon (2 -N-heptylcyclopentanone), cis-jasmon, dihydrojasmon, isojasmon, trimethylpentylcyclopentanone, sedamone (2-butylidene-3,5,5 (3,3)
3,5) -Trimethylcyclopentanone), Sandex (3-methyl-5- (2,2,3-trimethyl-3-)
Cyclopentenyl) -3-penten-2-one), cyclotene, coronol (3,5-dimethyl-1,2-cyclopentadione), methylchorilone (3,4-dimethyl1,2-cyclopentadione), belldone ( 2-ter
t-butylcyclohexanone), p-tert-butylcyclohexanone, Hellback (3,3-dimethylcyclohexylmethylketone), frescomente (2-se)
c-butylcyclohexanone), Artemon (1-acetyl-3,3-dimethyl-1-cyclohexene), celery ketone (3-methyl-5-propyl-2-cyclohexenone), krypton (4-isopropyl-2-cyclohexanone) , Oribbon (p-tert-pentylcyclohexanone), Methylcyclocitron (2,3,5
-Trimethyl-4-cyclohexenyl-1-methylketone), Nerone (1- (p-menthen-6-yl) -1-)
Propane), vetiver (4-cyclohexyl-4-methyl-2-pentanone), havanol (2- (1-cyclohexen-1-yl) -cyclohexanone), maltol, ethyl maltol, oxide ketone (cis-).
2-acetonyl-4-methyl-tetrahydropyran),
Emoxiflon (5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone), homoflor (2-ethyl-4-hydroxy-5-methyl-3 [2H] -furanone and 5-ethyl-4-hydroxy. 2-Methyl-3 [2H] -furanone), Sotron (3-hydroxy-4,5-dimethyl-2 [5H] -furanone), Furaneol (2,5-dimethyl-4-hydroxy-3 [2]
H] -furanone), acetyldimethylfuran, furfural acetone, 2-acetyl-5-methylfuran, 2-
Acetylfuran, methyltetrahydrofuranone, dibenzyl ketone, benzophenone, methylnaphthyl ketone,
4-Damascol (5-phenyl-5-methyl-3-hexanone), Bethicone (4-methyl-4-phenyl-2)
-Pentanone), α-methylanisalacetone, heliotropylacetone, anisylideneacetone, anisylacetone, p-methoxyphenylacetone, raspberry ketone (4- (p-hydroxyphenyl) -2-butanone), labandone (3- Methyl-4-phenyl-3-
Butene-2-one), benzylideneacetone, p-methoxyacetophenone, p-methylacetophenone, propiophenone, acetophenone, damacenone, damascon, isodamascon, α-dynascon (1- (5,5
-Dimethylcyclohexen-1-yl) -4-penten-1-one), iriton (4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2
-One and 4-3,5,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one),
Ionone, pseudoionone, methylionone, methylyriton (3-methyl-4- (2,4,6-trimethyl-3-
Cyclohexenyl) -3-buten-2-one), cyclowood (2,4-di-tert-butylcyclohexanone), iron, allylionone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, Kamek DH
(2-acetyl-3,3-dimethylnorbornane), Florex (6-ethylidene octahydro-5,8-methano-2H-1-benzopyran-2-one), plicaton (4-methyltricyclo [6.2] .1.0 ^2,7] undecane-5-one), Okisosedoran, belt fix (9-acetyl -2,6,6,8- tetramethyl tricyclo ^[5.3.1 1,7 ^{.0 1,5} ] -8-Undecene), berbenone (4,6,6-trimethyl- (1
R) -bicyclohepto-3-en-2-one), fencon, caron (7-methyl-3,5-dihydro-2H-)
Benzodioxepin-3-one), Trimofix O
(2,6,10-trimethyl-1-acetyl-2,5,
9-cyclododecatriene), bitalide (acetyldimethyltetrahydrobenzindane), epiton (7
(8) -Acetyl-5-isopropyl-2-methylbicyclo [2.2.2] oct-2-ene), atrinone (4 (5) -acetyl-7,7,9 (7,7,9)- Trimethylbicyclo [4.3.0] -1-nonene), cachemeran (6,7-dihydro-1,1,2,3,3-pentamethyl-4 (5H) -indanone), Muscon (3
-Methylcyclopentadecanone-1), civetone (cycloheptadec-9-en-1-one), exalton (cyclopentadecanone), musk TM-II (cyclohexadecenone), phantolide (5-acetyl-1) ，
1,2,3,3,6-hexamethylindane), cerestolide (4-acetyl-6-tert-butyl-1,1)
-Dimethylindane), traseolide (5-acetyl-3-isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4,4)
4,7-hexamethyltetrahydronaphthalene), bitteride (acetyldimethyltetrahydrobenzindane), iso-E-super (7-acetyl-1,2,2)
3,4,5,6,7,8-octahydro-1,1,6
7-tetramethylnaphthalene), dihydrocarvone, diosphenol, zingerone and the like.

<Ether-type compound> Methylhexyl ether, decyl methyl ether, decyl vinyl ether,
Diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, citronellyl ethyl ether, geranyl ethyl ether, α-terpinyl methyl ether, Herbabert (3,3,5-trimethylcyclohexyl ethyl ether), isobornyl methyl ether, tricyclode Cenyl methyl ether, isoproxen (2-ethylidene-6-isopropoxybicyclo [2.2.1] heptane), juniparome (methoxydimethyltricyclo [5.2.1.0 ^2,6 ] decane), cyclododecyl Methyl ether, Madrox (1-methylcyclododecyl methyl ether), Phizeol (2-ethoxy-2,6,6-trimethyl-9-
Methylenebicyclo [3.3.1] -nonane), cedramber (cedrol methyl ether), methylbenzyl ether, methylphenylethyl ether, ethyl 2-methoxybenzyl ether, allylphenylethyl ether, isoamylbenzyl ether, answer (isoamylphenylethyl) Ether), jacene (2-methyl-
2-butenyl phenyl ethyl ether), dibenzyl ether, cyclohexyl phenyl ether, myrooxide (ocimene epoxide), limonene oxide (p
-Mentha-8-ene-1,2-epoxide), rubofix (spiro [1,4-methanonaphthalene-2 (1
H), 2'-oxirane],-3,4,4a, 5,8,
8a-Hexahydro-3 ', 7-dimethyl and spiro [1,4-methanonaphthalene-2 (1H), 2'-
Oxirane], -3,4,4a, 5,8,8a-hexahydro-3 ', 6-dimethyl), trimethylcyclododecatriene epoxide, caryophyllene oxide, cedrene epoxide, isolongifolene epoxide, linalool oxide, citrooxide (2,2-Dimethyl-5 (1-methyl-1-propenyl) -tetrahydrofuran), Herboxoxide (5-isopropenyl-
2-methyl-2-vinyltetrahydrofuran), rosefuran (3-methyl-2- (3-methyl-2-butenyl) -furan), heptabelt (2-heptyltetrahydrofuran), mentofuran, theaspirane, oxybet (2- Oxaspiro [4,7] dodecane), Muscogen (3-oxabicyclo [10.3.0] -6-pentadecene), Cicamba (13-oxabicyclo [1])
0.3.0] Pentadecane), ambroxane (decahydro-3a, 6,6,9a-tetramethylnaphtho [2.
1-b] furan), glycalva (3a-ethyldodecahydro-6,6,9a-trimethylnaphtho [2.1-b].
Franc), 1,8-cineole, 1,4-cineole,
Galaxolid (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-γ-2-benzopyran), rose oxide, nerol oxide, rimitol (2 , 2,6-Trimethyl-
6-vinyltetrahydropyran), dirane (2-butyl-4,6-dimethyldihydropyran), doremox (tetrahydro-4-methyl-2-phenyl-2H-pyran), ruvofluor (9-ethylidene-3-oxatricyclo). [6.2.1.0 ^2,7 ] undecane), hexahydroindenopyran and the like.

<Acid compounds> Gellan acid, acetic acid, propionic acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid,
2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, hexanoic acid, isohexanoic acid,
2-hexanoic acid, 4-pentenoic acid, 2-methyl-2-pentenoic acid, heptanoic acid, 2-methylheptanoic acid, octanoic acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylenic acid, dodecanoic acid, myristic acid , Palmitic acid, stearic acid, anthranilic acid, oleic acid, levulinic acid,
Lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, 3-phenylpropionic acid, vanillic acid, valine, abietic acid,
Examples thereof include sorbic acid.

<Lactone compound> Pentalide (cyclopentadecanolide), havanolide (oxacyclohexadecen-2-one), ambrettolide, cyclohexadecanolide, 10-oxahexadecanolide, 11-oxahexa Decanolide, 12-oxahexadecanolide, ethylenedodecanedioate, γ-butyrolactone, γ-valerolactone, angelicalactone, γ-hexalactone, γ-heptalactone, γ-octalactone, γ-nonalactone, whiskey lactone (3-methyl-4-octanolide), γ-decalactone, γ-undecalactone, γ-dodecalactone, γ-jasmolactone, jasmine lactone, cis-jasmon lactone,
Lactojasmon (4-methyl-4-decanolide), Jasmolactone (tetrahydro-6- (3-pentenyl) -2H-pyran-2-one), Mentalactone (3,6-Dimethyl-5,6,7, 7a-tetrahydro-2 (4H) -benzofuranone), n-butylphthalide, propylidenephthalide, butylidenephthalide, δ-
Hexalactone, δ-octalactone, trivalon (4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one), δ-nonalactone, δ-decalactone, δ-2-decenolactone, δ-undeca Lactone, δ-dodecalactone, δ-tridecalactone, δ-
Tetradecalactone, lactocatone (decahydro-
4, α-hydroxy-2,8,8-trimethylnaphthalene-2-carboxyacid-δ-lactone), coumarin, dihydrocoumarin, cyclohexyl lactone, 6-
Methylcoumarin, ε-decalactone, ε-dodecalactone and the like can be mentioned.

<Ester Compound> Ethyl formate, propyl formate, butyl formate, amyl formate, isoamyl formate, hexyl formate, cis-3-hexenyl formate, octyl formate, linalyl formate, citronellyl formate, geranyl formate,
Neryl formate, rosinyl formate, terpinyl formate, ceryl formate, cariofeylene formate, afermat (α,
3,3-trimethylcyclohexanemethyl formate), oxyoctaline formate, benzyl formate, cinnamyl formate, phenylethyl formate, anisyl formate, eugenyl formate, decahydro-β-naphthyl formate, methyl acetate,
Ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, 2-methylbutyl acetate, isoamyl acetate, amyl acetate, prenyl acetate, hexyl acetate,
Cis-3-hexenyl acetate, trans-2-hexenyl acetate, 2-ethylhexyl acetate, heptyl acetate, octyl acetate, 3-octyl acetate, octenyl acetate, nonyl acetate, decyl acetate, trimethylhexyl acetate, decenyl acetate, nonanediol acetate, Dodecyl acetate, dimethyl undecadienyl acetate, diacetyl, diacetin, triacetin, ethylene glycol diacetate, ethylene glycol monobutyl ether acetate, allyl amyl glycolate, ocimenyl acetate, myrcenyl acetate, dihydromyrcenyl acetate, dimethyl octanyl acetate, linalyl acetate , Citronellyl acetate, rosinyl acetate, geranyl acetate, neryl acetate, tetrahydromugol acetate, ethyl linalyl acetate, lavandulyl acetate, isohydrolavandryl acetate, vinegar Nerolidol, carbyl acetate, dihydrocarbyl acetate, dihydrocuminyl acetate, terpinyl acetate, isopulegol acetate, menthyl acetate, citryl acetate, mirtenyl acetate, nopyr acetate, phenalkyl acetate, bornyl acetate, isobornyl acetate, cedolyl acetate, caryophyllene acetate, santalyl acetate , Vetiveryl acetate, guaiac acetate, cyclopentylidene methyl acetate,
Cyclohexyl acetate, p-isopropylcyclohexanyl acetate, tert-amyl cyclohexyl acetate, dihydroterpinyl acetate, cyclohexyl ethyl acetate, fluorolate (2,4-dimethyl-3-cyclohexenylmethyl acetate), rosamsk (α, 3 acetate). 3-trimethylcyclohexanemethyl), Vertenex (acetic acid p-te
rt-Butylcyclohexyl), Belldox (acetic acid o
-Tert-butylcyclohexyl), 1-ethynylcyclohexyl acetate, dihydroambulate (1-acetoxy-2-sec-butyl-1-vinylcyclohexane), miraldyl acetate (4 (3)-(4-methyl-3)
-Pentenyl) -3-cyclohexenyl methyl acetate), tricyclodecenyl acetate, tricyclodecyl acetate, benzyl acetate, p-cresyl acetate, phenylethyl acetate, styralyl acetate, p-methylbenzyl acetate, anisyl acetate, piperonyl acetate , Acetyl vanillin, rosephenone, hydratropyl acetate, 2,4-dimethylbenzyl acetate, cinnamyl acetate, phenylpropyl acetate, cuminyl acetate, dimethylbenzylcarbyl acetate, phenylglycol diacetate, dimethylphenylethylcarbyl acetate, phenylethylmethyl acetate Ethylcarbinyl, beticol acetate (4-methyl-4-phenyl-2-pentylacetate), α-amylcinnamimiyl acetate, jasmalol (trans-decahydro-β)
-Naphthyl acetate), furfuryl acetate, tetrahydrofurfuryl acetate, jasmar (3-pentyltetrahydropyranyl acetate), jasmeria (5-methyl-3-butyltetrahydropyranyl acetate), ethyl acetoacetate, gesate (2-hexylacetoacetic acid) ethyl),
Ethyl benzyl acetoacetate, allyl cyclohexyl acetate, isopropyl cyclohexenyl acetate, ethyl propionate, propyl propionate, allyl propionate,
Butyl propionate, isobutyl propionate, isoamyl propionate, hexyl propionate, cis-3-hexenyl propionate, trans-propionate
2-hexenyl, decenyl propionate, linalyl propionate, citronellyl propionate, rosinyl propionate, geranyl propionate, neryl propionate,
Carbyl propionate, terpinyl propionate, menthyl propionate, bornyl propionate, isobornyl propionate, tricyclodecenyl propionate, benzyl propionate, styralyl propionate, anisyl propionate, phenylethyl propionate, cinnamyl propionate, propionate Acid phenylpropyl, dimethylbenzylcarbinyl propionate, phenoxyethyl propionate, propylene glycol dipropionate propionate, labdanax (3-hydroxy-
3 phenyl propionate), isobutyl furanpropionate, methyl butyrate, ethyl butyrate, propyl butyrate,
Isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyl butyrate, amyl butyrate, isoamyl butyrate, hexyl butyrate,
Heptyl butyrate, cis-3-hexenyl butyrate, tr butyrate
ans-2-hexenyl, octyl butyrate, propylene glycol dibutyrate, linalyl butyrate, citronellyl butyrate, rosinyl butyrate, geranyl butyrate, neryl butyrate, terpinyl butyrate, cyclohexyl butyrate, benzyl butyrate, cinnamyl butyrate, phenylethyl butyrate, dimethylbenzylcarbyl butyrate , Tetrahydrofurfuryl butyrate, santaryl butyrate, methyl isobutyrate, ethyl isobutyrate, propyl isobutyrate, isopropyl isobutyrate, butyl isobutyrate, isobutyl isobutyrate, isoamyl isobutyrate, hexyl isobutyrate, cis-3-hexenyl isobutyrate, isobutyrate Butyric acid 2,4
-Hexadienyl, isopentylate (isobutyric acid 1,3
-Dimethyl-3-butenyl), octyl isobutyrate, linalyl isobutyrate, citronellyl isobutyrate, rosinyl isobutyrate, geranyl isobutyrate, neryl isobutyrate, terpinyl isobutyrate, tricyclodecenyl isobutyrate, benzyl isobutyrate, isobutyric acid p-cresyl, cinnamyl isobutyrate, phenylethyl isobutyrate, phenylpropyl isobutyrate, styrylyl isobutyrate, dimethylcarbinyl isobutyrate, dimethylphenylethylcarbinyl isobutyrate, floranol (phenoxyethyl isobutyrate), decahydroisobutyrate-
β-naphthyl, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, 2-methylbutyl 2-methylbutyrate, sidorane (hexyl 2-methylbutyrate), cis-2-methylbutyrate
3-hexenyl, benzyl 2-methylbutyrate, phenylethyl 2-methylbutyrate, allyl 2-ethylbutyrate, ethyl 3-hydroxybutyrate, methyl valerate, ethyl valerate, butyl valerate, isobutyl valerate, amyl valerate, yoshi Herb acid c
is-3-hexenyl, benzyl valerate, phenylethyl valerate, furfuryl valerate, methyl isovalerate, ethyl isovalerate, propyl isovalerate, isopropyl isovalerate, allyl isovalerate, butyl isovalerate, iso Isobutyl valerate, isoamyl isovalerate, amyl isovalerate, 2-methylbutyl isovalerate, isovaleric acid cis
-3-hexenyl, hexyl isovalerate, octyl isovalerate, linalyl isovalerate, citronellyl isovalerate, geranyl isovalerate, menthyl isovalerate, terpinyl isovalerate, cyclohexyl isovalerate, benzyl isovalerate, Phenylethyl isovalerate, phenylpropyl isovalerate, cinnamyl isovalerate, manzanate (ethyl 2-methylvalerate), phenyl salicylate,
Peranato (2-methylvaleric acid 2-methylpentyl ester), methyl hexanoate, ethyl hexanoate, propyl hexanoate, isopropyl hexanoate, allyl hexanoate, butyl hexanoate, isobutyl hexanoate, amyl hexanoate, isoamyl hexanoate, Hexyl hexanoate, cis-3-hexenyl hexanoate, hexanoate t
rans-2-hexenyl, heptyl hexanoate, linalyl hexanoate, citronellyl hexanoate, geranyl hexanoate, citronellyl hexanoate, benzyl hexanoate, methyl isohexanoate, methyl 2-hexenoate, t
ethyl trans-2-hexenoate, methyl 3-hexenoate, ethyl 3-hexenoate, methyl 3-hydroxyhexanoate, ethyl 3-hydroxyhexanoate, ethyl 2-ethylhexanoate, mersat (3,5,5-trimethyl Ethyl hexanoate), berifuro (ethyl 6-acetoxyhexanoate), methyl heptanoate, ethyl heptanoate, propyl heptanoate, allyl heptanoate, octyl heptanoate, methyl octanoate, ethyl octanoate,
Amyl octanoate, butyl octanoate, propyl octanoate, allyl octanoate, isoamyl octanoate, hexyl octanoate, heptyl octanoate, octyl octanoate, linalyl octanoate, benzyl octanoate, phenylethyl octanoate, p-cresyl octanoate , 2-
Ethyl octenoate, methyl nonanoate, ethyl nonanoate,
Phenylethyl nonanoate, bouvartate (methyl 2-nonenate), methyl 3-nonenate, methyl decanoate, ethyl decanoate, isopropyl decanoate, butyl decanoate, isoamyl decanoate, ethyl 2-decenoate, 2,4
-Ethyl decadienoate, propyl 2,4-decadienoate, methyl undecylenate, butyl undecylenate, isoamyl undecylenate, methyl dodecanoate, ethyl dodecanoate, butyl dodecanoate, isoamyl dodecanoate,
Ethyl myristate, methyl myristate, isopropyl myristate, ethyl palmitate, ethyl stearate, butyl stearate, methyl oleate, ethyl oleate, methyl benzoate, ethyl benzoate, propyl benzoate, isopropyl benzoate, benzoic acid Allyl,
Isobutyl benzoate, isoamyl benzoate, prenyl benzoate, hexyl benzoate, cis-3-hexenyl benzoate, linalyl benzoate, geranyl benzoate, benzyl benzoate, phenylethyl benzoate, cinnamyl benzoate, methyl anisate, anise. Ethyl acid salt, methyl o-methoxybenzoate, ethyl o-methoxybenzoate, ethyl tiglate, hexyl tiglate, cis-tiglate
3-hexenyl, citronellyl tiglate, geranyl tiglate, benzyl tiglate, phenylethyl tiglate, cinnamyl tiglate, methyl angelica, butyl angelica, isobutyl angelica, isoamyl angelica, prenyl angelica, cis-3 angelica. -Hexenyl, 3-methylpentyl angelica, phenylethyl angelica, ethyl acrylate, phenylethyl methacrylate, ethyl crotonate,
Isobutyl crotonic acid, cyclohexyl crotonic acid, flutinato (4-methyl-pentan-2-ol-crotonate), pyroprunato (2-cyclopentyl-cyclopentyl crotonate), datilato (1-cyclohexylethyl crotonate), levulinate, levulinic acid Butyl, isoamyl levulinate, methyl lactate, ethyl lactate, amyl lactate, isobutyl lactate, cis-3-lactate
Hexenyl, butyl butyryl lactate, ethyl pyruvate,
Methyl gellanate, ethyl gellanate, methyl cyclogelanate, ethyl cyclogelanate, frutetate (ethyltricyclo [5.2.1.0 ^2,6 ] decan-2-yl carboxylate), divescon (ethyl-2-ethyl-
6,6-Dimethyl-2-cyclohexene-1-carboxylate & ethyl-2,3,6,6-tetramethyl-2-cyclohexenecarboxylate), ethyl safranate (ethyl dehydrocyclogeranate), allyl cyclohexylpropionate , Cyclogalvanate (allylcyclohexyloxyacetate), calixol (ethyl-2-methyl-6-pentyl-4-oxocyclohex-2-enecarboxylate), tachrysate (methyl-1-methyl-3-cyclohexenecarboxylate) , Floramate (ethyl-2-tert-butylcyclohexyl carbonate), jasma cyclate (methyl cyclooctyl carbonate), mahagonate (1-methyl-4-isopropyl-2-carbomethoxybicyclo [2,2,2] ] - oct-5-ene), phenylethyl pivalate, methyl jasmonate, Hedion (methyl dihydrojasmonate), Beramosu (methyl -
3,6-dimethyl-β-resorcylate), methyl furancarboxylate, ethyl furancarboxylate, propyl furan acrylate, methyl heptine carboxylate, ethyl heptine carboxylate, isoamyl heptine carboxylate, methyl octinecarboxylate, octyne Ethyl carboxylate, methyl decynecarboxylate, glycomel (methyl ester of 3- (bicyclo [2.2.1] hept-5-en-2-yl) -3 methyloxirane carboxylic acid),
Methyl phenylglycidate, ethyl phenylglycidate, aldehyde C-16 (3-methyl-3-phenylglycidate ethyl), aldehyde C-20 (p-methyl-
β-phenyl glycidate), methyl p-tolyl glycidate, ethyl citronellyl oxalate, diethyl succinate, dimethyl succinate, diethyl malonate, diethyl tartrate, diethyl adipate, diethyl sebacate, triethyl citrate, phthalate Dimethyl acid, Diethyl phthalate, Dibutyl phthalate, Methyl phenylacetate, Ethyl phenylacetate, Isopropyl phenylacetate, Butyl phenylacetate, Propyl phenylacetate, Isobutyl phenylacetate, Isoamyl phenylacetate, Hexyl phenylacetate, cis-3-Hexenyl phenylacetate , Phenylacetate citronellyl, phenylacetate rosinyl, phenylacetate geranyl, phenylacetate menthyl, phenylacetate benzyl, phenylethyl phenylacetate, phenylacetate p-
Cresyl, eugenyl phenylacetate, isoeugenyl phenylacetate, methyl cinnamate, ethyl cinnamate, propyl cinnamate, isopropyl cinnamate, allyl cinnamate,
Isobutyl cinnamate, isoamyl cinnamate, linalyl cinnamate, benzyl cinnamate, cinnamyl cinnamate, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, butyl salicylate, isobutyl salicylate, amyl salicylate, isoamyl salicylate, salicylate Hexyl, cis-3-hexenyl salicylate, cyclohexyl salicylate, phenyl salicylate, benzyl salicylate, phenylethyl salicylate, cyclopidene (methylcyclopentylidene acetate), ethyl-2,2,2.
6-Trimethylcyclohexane carbonate, avalin (methyl abietate), hercoline (methyl dihydroabietate), p-cresyl salicylate, allyl phenoxyacetate, ethyl phenylpropionate, ethylene brushlate, triacetin and the like can be mentioned.

<Nitrogen-containing compound> Methyl anthranilate, ethyl anthranilate, butyl anthranilate, cis-3-hexenyl anthranilate, phenylethyl anthranilate, cinnamyl anthranilate, methyl N-methylanthranilate, auranthiol (hydroxy Citronellal-methylanthranilate Schiff base), mevantoral (methylpropylacetaldehyde-methylanthranilate Schiff base), jasmentin (α-amylcinnamic aldehyde-methylanthranilate Schiff base), ligantral (methyl- (3 , 5-dimethyl-3-cyclohexene-
1-yl) methylene anthranilate), indole,
Skatole, clonal (dodecane nitrile), tangerine (2-tridecene nitrile), citralva (geranyl nitrile), citronellyl nitrile, lemonyl (3,7-dimethyl-2,6-nonadienitrile), cuminyl nitrile, cinnamalva (cinna) (Milnitrile), trimethylamine, pyridine, 3-ethylpyridine, 2-acetylpyridine, 3-acetylpyridine, 2
-Isobutylpyridine, 3-isobutylpyridine, 2-
n-pentylpyridine, 5-ethyl-2-methylpyridine, methyl nicotinate, 4- (1,4,8-trimethyl-3,7-nonadienyl) pyridine, quinoline, isoquinoline, p-methylquinoline, tetrahydro-p- Methylquinoline, 6-isopropylquinoline, isobutylquinoline, 2-isobutylquinoline, 6-sec-butylquinoline, 8-sec-butylquinoline, 6 (p) -t
ert-butylquinoline, 2-tert-butylquinoline, pyrazine, 2-methylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5-trimethylpyrazine, 2-ethylpyrazine, 2-ethyl. −
3-methylpyrazine, 2-ethyl-5-methylpyrazine, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2,3-diethylpyrazine, 2,3-diethyl-5.
-Methylpyrazine, tetramethylpyrazine, 2-methyl-5-vinylpyrazine, methoxypyrazine, 2-methoxy-3-methylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3-isopropylpyrazine, 2
-Isobutyl-3-methoxypyrazine, 2-acetylpyrazine, 2-acetyl-3-ethylpyrazine, methylthiomethylpyrazine, corylonepyrazine (5-methyl-
6,7-dihydrocyclopentapyrazine), 5-methylquinoxaline, cyclohexapyrazine (5,6,7,8)
-Tetrahydroquinoxaline), 1-methylpyrrole,
2-acetylpyrrole, pyrrolidine, indole (Schiff base of indole-hydroxycitronellal),
2-methylbenzoxazole, decahydrocyclododecaxazole, 5-methyl-3-heptanone oxime, bucoxime (bicyclo [3.2.1] octane-8
-One, 1,5-dimethyl-, oxime), Gardamide (N-methyl-N-phenyl-2-methylbutyramide), Musk xylol, Musk ketone, Musk ambrette, Musk tibetan, Mosken, 2,6-lutidine, piperidine , 2- (1,4,8-trimethyl-3,
7-nonadienyl) pyridine, 2- (2-pinene-10)
-Ylmethyl) pyridine, 4- (2-pinene-10-isomethyl) pyridine, piperine, capsaicin, nonanoic acid vanillylamide, quinine, perillartine (L-perilaldehyde α-anti-aldoxime), 2-isopropyl-4-methylthiazole , 2-isobutylthiazole and the like.

<Sulfur-containing compound> Thiazole, 4-methylthiazole, 4,5-dimethylthiazole, trimethylthiazole, 2-methyl-5-methoxythiazole,
2-isopropyl-4-methylthiazole, 4-methyl-5-vinylthiazole, 2-isobutylthiazole,
Sulfurol (4-methyl-5-thiazole ethanol), Sulfuryl acetate (4-methyl-5-thiazole ethanol acetate), 2-acetylthiazole, 5-acetyl-2,4-dimethylthiazole, benzothiazole, propylmercaptan, Hydrogen sulfide, isopropyl mercaptan, 2-methyl-3-butanethiol, allyl mercaptan, isoamyl mercaptan, thiogeraniol, limonene thiol, sulfox (8-mercaptomenthone) phenyl mercaptan, o
-Thiocresol, 2-ethylthiophenol, 2-naphthyl mercaptan, furfuryl mercaptan, 2-methyl-3-furanthiol, dimethyl sulfide, dimethyl disulfide, dimethyl trisulfide, methylpropyl disulfide, methylpropyl trisulfide,
Propyl disulfide, dipropyl trisulfide, diallyl sulfide, diallyl disulfide, dibutyl sulfide, methionol (3- (methylthio) -1-propanol), 3-methylthio-1-hexanol, methional (3- (methylthio) propionaldehyde), mint Sulfide, dithiospirofuran, furfurylmethyl sulfide, 2-methyl-5-methylthiofuran, methylfurfuryl disulfide, furfuryl disulfide, thiophene, tetrahydrothiophene, 3-
Thiophene carboxaldehyde, 5-methyl-2-thiophene carboxaldehyde, tetrahydrothiophen-3-one, trithioacetone, thioglycolic acid,
Methyl methylthioacetate, ethyl methylthioacetate, 2-mercaptopropionic acid, pineapple mercaptan (methylmercaptomethylpropionate), ethyl 3-methylthiopropionate, ethyl thioacetate, furfuryl thioacetate, furfuryl thiopropionate, methyl thiobutyrate, methyl Methanethiosulfonate, allyl isothiocyanate, benzyl isothiocyanate, thirazine (2,4,6-trimethyl-4,5-dihydro-1,
3,5-dithiazone), oxane (2-methyl-4-propyl-1,3-oxathiane) and the like.

<Natural fragrance> Asafetide daresinoid,
Ajowan Oil, Star Anise Oil, Avies Oil, Amiris Oil, Amblet Seed Oil, Ambergris tincture, Ylang Ylang Oil, Ylang Ylang Absolute, Iris Resinoid, Iris Absolute, Iris Oil, Wintergreen Oil, Elemiole Resin, Elemi Resinoid Absolute , Eremitinki, oakmos concrete, oakmos absolute, oakmoss resin, oakmoss resinoid, ocotia oil, osmanthus absolute,
Osmanthus Concrete, Opopanax Resinoid, Opopanax Absolute, Opopanax Oil, Olivananum Resinoid, Olivanum Absolute, Olivanamu Oil, Allspice Oil, Oregano Oil, Oreganooleoresin, Orange Oil, Orange Flower Absolute, Orange Flower Concrete, Cananga oil, garjun balsam, garjun balsam oil, cascari rubber lacquer oil, castorium absolute, cassi absolute, cassiflower oil, cassia oil, gardenia absolute, carnations absolute, cabreuba oil, camomil oil, cardamom oil, galbanum oil, Galvanum Resin, Galvanum Resinoid, Carawash Dooiru, carrot seed oil, Guadalmedina Yak wood oil, Guadalmedina Yak resin, Guadalmedina Yak concrete, camphor oil, Kubebaoiru,
Cumin oil, cumin absolute, cumin oleoresin, clary sage oil, grapefruit oil,
Clove oil, Costas oil, Copaiba balsam,
Copaiba balsam oil, copaiba balsam resin, coriander oil, sassafras oil, sandalwood oil, june absolute, perilla oil, citronella oil, jasmine absolute, jasmine concrete, juniper berry oil, civet absolute, civet tincture, john kill absolute, agarwood oil, Ginger oil, cinnamon oil, cinnamon bark oil, cinnamon leaf oil, cedar oil, styrax oil, styrax resinoid, spearmint oil, savory oil, sage oil, cedar oil, cedar leaf oil, geranium oil, celery seed oil, thyme oil,
Taguette oil, tarragon oil, tuberose absolute, dill oil, tea tree oil, torimos absolute, true balsam, nutmeg oil, narcissus absolute, neroli oil, violet leaf absolute, pine oil, basil oil, parsley relief oil, parsley seed oil, Parsley herb oil, patchouli oil, peppermint oil, vanilla absolute, honeysuckle absolute, palmarosa oil, valerian oil, bitter orange oil, hyssop oil, hiba oil, hyacinth absolute, fennel oil, figua solute, petitgrain oil, butchu oil, vetiver oil, penny. Royal oil, pepper oil, peppermint oil, bergamo Oil, peruvian balsam, benzoin tincture, benzoin resinoid, boad rose oil, borax oil, hop oil, hop concrete, hop absolute, marjoram oil, mandarin oil, mandarin oil, mimosa concrete, mimosa absolute, mimosa oil, millresinoid, mill Absolute, Mill oil, Musk absolute, Muskuki, Eucalyptus oil, Yuzu oil, Wormwood oil, Lime oil, Labdanum oil,
Labdanum Resinoid, Lavender Oil, Lavender Absolute, Lavandin Oil, Lavandin Absolute, Linaloe Oil, Lemon Oil, Lemongrass Oil, Rose Oil, Rose Absolute, Rose Concrete, Rosemary Oil, Lobage Oil, Laurel Oil, Laurel Leaf Oil, Wormwood Oil , Musk, spirit cat incense, dragon incense, raccoon incense, musk, chibata, etc.

<Prepared fragrance> Further, there are the following fragrance bases which are prepared fragrances in which fragrance components are combined. Citrus type base such as lemon tone, lime tone, orange tone, sweet orange tone, mandarin tone, bergamot tone, petit gren tone, neroli tone, lemongrass tone, a gourmet tone, etc. fresh type base, apple tone, peach tone, strawberry Tone, coconut tone, pineapple tone, raspberry tone, watermelon tone etc. fruity type base, rose tone, jasmine tone, muguet tone, lilac tone, carnation tone, hyacinth tone, tuberose tone, gardenia tone, mimosa tone, narciss tone, Floral type base such as violet tone, Iran tone, floral bouquet tone, cinnamon bark tone, cinnamon leaf tone, clove tone, Pimentoberry tone, nutmeg tone, pepper tone, cardamom tone, coriander tone, cumin tone etc. Wood, cedarwood, vetiver, sandalwood, guaiac wood, woody bar, woody iris and other woody type bases, smoky and quinoline leather types, vanilla, tonka, honey, pure Sweet type base such as balsam tone, other aldehideic type base, amber type base, animal type base, anise type base, aromatic herbal type base, agar type base, aqua type base,
Camphor cineole type base, green type base, seed type base, herb type base, pine type base, patchouli type base, balsamic type base, mint type base, musk type base, moss type base, lavender type base, linalool type base, resin Type base etc. are mentioned.

Further, as a solvent for the fragrance, ethanol,
Acetine (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, deltil extra (isopropyl myristate), methyl carbitol (diethylene glycol monomethyl ether), Carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate, propylene glycol, diethyl phthalate, tripropylene glycol, aborin (dimethyl phthalate), deltyl prime (isopropyl palmitate), dipropylene glycol D
PG-FC (dipropylene glycol), farnesene, dioctyl adipate, tributyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate,
Cetyl acetate (hexadecyl acetate), ethyl abietate, avalin (methyl abietate), citroflex A-2 (acetyltriethyl citrate), citroflex A-4 (tributylacetyl citrate), citroflex No. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate), Durafix (methyl dihydroabietate), MITD (isotridecyl myristate),
Examples include polylimonene (limonene polymer), propylene glycol, 1,3-butylene glycol and the like.

These solvents are contained in the perfume composition in an amount of 0.1 to 9
9% by mass, preferably 1 to 50% by mass. In addition, examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E and its derivatives, catechin compounds, flavonoid compounds, polyphenol compounds, and the like.
001 to 10% by mass, preferably 0.001 to 5% by mass
Contained. Of these, the preferred stabilizer is dibutylhydroxytoluene. What is a fragrance composition?
It is a mixture of the above-mentioned perfume ingredients, solvent, perfume stabilizer and the like. The drainage pipe detergent composition of the present invention contains a fragrance composition in an amount of 0.001 to 20% by mass, preferably 0.01 to 10%.
It is contained by mass%.

The drain pipe cleaning composition of the present invention may contain a 2,2,6-trimethylcyclohexanecarboxylic acid ester compound as a fragrance other than the above fragrances. This 2,2,6-trimethylcyclohexanecarboxylic acid ester compound is highly preferable because it has the effect of reducing the muses originating from the alkali metal hypochlorite (chlorine odor). As the 2,2,6-trimethylcyclohexanecarboxylic acid ester compound, ethyl 2,2,6-trimethylcyclohexanecarboxylic acid is preferable in terms of aroma,
Of the two geometric isomers of ethyl 2,2,6-trimethylcyclohexanecarboxylate, the trans isomer is particularly preferable in terms of aroma characteristics. Further, among the four optically active forms of ethyl 2,2,6-trimethylcyclohexanecarboxylate, the (1R, 6S) -form is most preferable in terms of aroma intensity. The method for producing the 2,2,6-trimethylcyclohexanecarboxylic acid ester compound is not particularly limited,
For example, the method described in Japanese Patent No. 2840899 is adopted. The content of the 2,2,6-trimethylcyclohexanecarboxylic acid ester compound is not particularly limited,
The total amount of the composition is 0.001 to 1% by mass, preferably 0.005 to 0.1% by mass.

[0036]

EFFECTS OF THE INVENTION Since the drain pipe cleaning composition of the present invention is excellent in adhesion retention property, it is extremely difficult for the applied agent to drip against stains adhering to the wall surface of the drain pipe which is a vertical surface or an inclined surface. It has excellent detergency and a small change in viscosity due to temperature changes and can supply a stable quality formulation, so it is suitable for use in drainage pipes in bathrooms, washrooms, kitchens and the like.

[0037]

The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.

[0038]

Examples 1 to 10 Various drainage pipe cleaning compositions having the compositions shown in Tables 1 and 2 were prepared, and the viscosity, electric conductivity, adhesion retention, and storage stability were evaluated based on the following criteria. ..
The obtained results are shown in Tables 1 and 2.

<Chloride Ion Content> The chlorine ion content is shown by the molar concentration of sodium chloride relative to the molar concentration of alkali metal hypochlorite. As the sodium hypochlorite of Examples 1 to 5 and 9, the one containing 2% by mass of sodium chloride in a 12% by mass sodium hypochlorite aqueous solution was used, and the sodium hypochlorite of Example 6 was 12% by mass. % Sodium hypochlorite aqueous solution containing 4% by mass of sodium chloride is used. Sodium hypochlorite of Example 7 contains 6% by mass of sodium chloride in a 12% by mass aqueous solution of sodium hypochlorite. The sodium hypochlorite used in Example 8 contained 8% by mass of sodium chloride in a 12% by mass aqueous sodium hypochlorite solution, and the sodium hypochlorite used in Example 10 was A 12 mass% sodium hypochlorite aqueous solution containing 12 mass% sodium chloride was used.

<Measurement of Viscosity> Various drain pipe cleaning compositions adjusted to 10 ° C., 25 ° C. and 40 ° C. were measured with a B type viscometer (TO
KIMEC; DVL-B2) used, rotation speed 60 rp
The value after 1 minute was measured with a m.

<Measurement of Electric Conductivity> Various drain pipe cleaning compositions were measured by an automatic temperature conversion mode (25 ° C.) of a conductivity meter (manufactured by Horiba, Ltd .; DS-14).

<Measurement Method of Adhesion Retention Rate> After 2 g of various drainage pipe detergent compositions were thinly and evenly spread on the top of a panel (30 × 30 cm; polyvinyl chloride), the panel was erected vertically and left for 1 minute. Later weigh the panel. The adhesion retention rate is calculated by the following formula. Do this test 3 times,
The average value of three times is set as the adhesion retention rate.

[Equation 1]

<Evaluation Method of Storage Stability> 90 g of various drain pipe detergent compositions were filled in a transparent container made of polyethylene terephthalate (JOY-120, manufactured by Takemoto Container Co., Ltd.), and the container was covered with a constant temperature bath at 40 ° C. ( 3.5 cycles (7 days) was put in a low temperature tank (Tabay Espec: Platinus PU 4SP) that repeats 0 ° C and -15 ° C every 24 hours for 1 month in Tabai Espec: Platinum PU-4SP. After that, take it out and observe the appearance change with the naked eye,
It evaluated by the following evaluation criteria.

Evaluation criteria; ○: No change Δ: Precipitates and precipitates are slightly seen ×: A considerable amount of precipitates and precipitates are seen

[0045]

[Table 1]

[0046]

[Table 2]

Fragrance A: ethyl (1R, 6S) -2,2,6-trimethylcyclohexanecarboxylate (tesalone:
Takasago Fragrance Co., Ltd. Fragrances B to E: (continuously listed in Tables 3 to 9)

[0048]

[Table 3]

[0049]

[Table 4]

[0050]

[Table 5]

[0051]

[Table 6]

[0052]

[Table 7]

[0053]

[Table 8]

[0054]

[Table 9]

─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) C11D 1/75 B08B 9/06 F term (reference) 3B116 AA13 AB51 3B201 AA13 AB51 BB92 BB94 BB95 BB96 4H003 AB03 AB19 AC15 DA13 EA21 ED02 EE08 FA16 FA26 FA30 FA42

Claims (4)

[Claims] (1) An alkali metal hypochlorite salt;
1 to 10% by mass, (2) alkali agent; 0.1 to 5% by mass, (3) surfactant; 0.1 to 5% by mass, and 2
A drain pipe cleaning composition, which has an electric conductivity of 10 to 120 ms / cm at 5 ° C. 2. A B-type viscometer at 25 ° C. and a rotation speed of 60.
Viscosity measured at rpm is 20 to 300 mPa · s
The drain pipe cleaning composition according to claim 1, which is in the range of 1. 3. The surfactant comprises the following surfactants (a) to (c): (a) an alkali metal salt of a fatty acid; 0.01 to
3% by mass, (b) amine oxide; 0.01 to 5% by mass, (c) alkylbenzene sulfonate; 0.01 to
It is 1 mass%, The drain pipe cleaning composition of Claims 1-2. 4. The chlorine ion content in the drain pipe cleaning composition is 0.05 to 1.2 times the molar concentration of alkali metal hypochlorite in terms of sodium chloride molar concentration. The drain pipe cleaning composition according to any one of claims 1 to 3.