JP2002146399A - Tablet detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a tablet detergent composition having more improved strength while maintaining a sufficient disintegrability at a low temperature, consequently useful as a tablet detergent having an excellent strength to stand shock in transportation, etc., excellent qualities to rapidly disintegrate even by using normal-temperature tap water in washing. SOLUTION: This tablet detergent composition is characterized in that a compression molding of a mixed particle comprising (A) a molten particle which contains a low-melting surfactant, etc., and is at least partially melted by heating to the melting point of the surfactant to 65 deg.C and (B) a nonmelting particle not melting by the heating is fused in an airtight container at the melting point of the surfactant to 65 deg.C.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a tablet detergent composition obtained by compression-molding a granular detergent into a tablet form.
More specifically, the present invention relates to a tablet detergent composition having improved strength while maintaining sufficient disintegration at low temperatures.

[0002]

BACKGROUND OF THE INVENTION Various proposals have heretofore been made to achieve both the strength of a tablet detergent composition and sufficient disintegration at low temperatures (Japanese Patent Application Laid-Open No. Sho 62-30197). No., JP-A-5-186800,
JP-A-5-331497, JP-A-7-286199
JP-A-10-183198, JP-A-10-183
No. 199, WO98 / 24875, Tokiohei 10-50
No. 4349, JP-A-2000-192098), in tablet detergent compositions, further improvement of such properties can be said to be an eternal problem.
It has been desired to develop a tablet detergent composition having both low temperature disintegration properties.

The present invention has been made in view of the above circumstances, and it is an object of the present invention to provide a tablet detergent composition having improved strength while maintaining sufficient disintegration at low temperatures.

[0004]

Means for Solving the Problems and Embodiments of the Invention The present inventors have conducted intensive studies to achieve the above object, and as a result, as shown in Examples and Comparative Examples described later, a surfactant having a low melting point was used. And molten particles in which the whole or a part of the particles are melted by heating in a temperature range from the melting point of the surfactant or the like to a specific temperature, and a non-melting agent such as a disintegrant that does not melt at the above heating temperature. When the compression molded product obtained by mixing and compressing the particles is subjected to a fusion treatment in the above temperature range in an airtight container, the strength of the tablet detergent composition is improved without lowering the disintegration at low temperatures. This led to the present invention.

That is, the present invention relates to (A) molten particles containing a surfactant having a low melting point and the like, wherein at least a part thereof is melted by heating at a temperature of from the melting point of the surfactant to 65 ° C .;
A tablet detergent composition obtained by subjecting a compression-molded product of mixed particles containing non-molten particles that are not melted by heating to a fusion treatment at a temperature of from the melting point of the surfactant to 65 ° C. in an airtight container. Offer things.

Hereinafter, the present invention will be described in more detail. The tablet detergent composition of the present invention contains (A) molten particles containing a surfactant and the like, and (B) non-molten particles. . Here, in the present invention, the melting particles of the above-mentioned surfactants and the like and the molten particles at least a part of which is melted by heating at 65 ° C., are subjected to a fusion treatment such as heating for 5 seconds to 30 days in the temperature range. It means that the molten component exudes to the particle surface.

[0007] The seepage can be determined by the following method. (A) A part of the molten particles containing a surfactant or the like is converted into oil violet (Fat Red 7).
B, CI-26050, manufactured by Tokyo Chemical Industry Co., Ltd.), and the surface of the particles is coated with molten particles that are not coated, (B) unfused particles, and then press-molded, and then subjected to compression molding. Is housed in an airtight container, and fusion treatment is performed in the airtight container.

[0008] When there is exudation from the molten particles,
Exudation can be easily confirmed by visually observing the transfer of the dye from the dye-coated particles on the tablet surface to other adjacent particles not coated with the dye. At this time, the coating amount of the oil-soluble dye to the molten particles is preferably 0.01 to 0.1% by mass based on the molten particles, and the ratio of the molten particles coated with the dye and the uncoated particles to the entire molten particles. Is 1/9 by mass ratio
It is preferable that the ratio is 9 to 5/95, because the determination becomes easier.

On the other hand, the non-molten particles (B) of the present invention, which are not melted by heating in the above temperature range, are defined as 5% in the above temperature range.
It refers to one that does not exude to the particle surface due to fusion treatment such as heating for seconds to 30 days. The absence of bleeding can be confirmed by observing that the dye does not move by the above-described determination method.

It is more preferable that at least a part of the molten particles is melted by heating at a melting point of the surfactant or the like to 65 ° C.

The type of the surfactant or the like contained in (A) the molten particles is not particularly limited as long as it has a low melting point and can be melted and solidified by a fusion treatment described later. For example, surfactants such as nonionic surfactants and polyethylene glycol are preferred. The melting point of the surfactant and the like is preferably 60 ° C or lower, more preferably 20 to 60 ° C, and further preferably 20 to 50 ° C. If the melting point is too high, the later-described fusing treatment may be difficult. If the melting point is too low, compression molding may be difficult.

More specifically, the above-mentioned surfactants include, for example, (1) polyoxyethylene having a linear or branched alkyl or alkenyl group having 10 to 20 carbon atoms and having ethylene oxide added thereto; Alkyl ether or polyoxyethylene alkenyl ether. (2) Polyoxyethylene polyoxypropylene alkyl ether or polyoxyethylene polyoxypropylene alkenyl ether having a linear or branched alkyl or alkenyl group having 10 to 20 carbon atoms and having ethylene oxide and propylene oxide added thereto. (3) A fatty acid ester type nonionic surfactant represented by the following general formula (I). R ¹ CO (OR ² ) _n OR ³ (I) (R ^{1 is} a linear or branched alkyl or alkenyl group having 9 to 19 carbon atoms. R ² is an alkylene group having 1 to 4 carbon atoms. There, it is preferable preferably constituting the oR ² by adding ethylene oxide alone or ethylene oxide and propylene oxide are mixed.
R ³ is an alkyl group having 1 to 4 carbon atoms, preferably an alkyl group having 1 to 2 carbon atoms. n: OR average addition mole number of ²⁾ (4) weight average molecular weight from 600 to 20,000, especially 600
~ 6000 polyethylene glycol. And the like. These can be used alone or in combination of two or more.

The amount of the surfactant and the like in the tablet detergent composition of the present invention is not particularly limited.
%, More preferably 1 to 5% by mass. If the amount of the surfactant or the like is too small, it may be difficult to obtain the desired strength of the present invention. If the amount is too large, compression molding may be difficult.

The amount of the surfactant and the like in the molten particles (A) is not particularly limited, but is preferably 1 to 10% by mass, and more preferably the total amount of the (A) molten particles. Is preferably 1 to 5% by mass. If the amount of the surfactant or the like is too small, it may be difficult to obtain the desired strength of the present invention. If the amount is too large, compression molding may be difficult.

At least a part of the molten particles (A) is melted or exuded by heating within the above-mentioned heating temperature range, and as long as the particles are fused together, a detergent composition other than the above-mentioned surfactants and the like is usually used. Various components to be blended in the product can be blended.

The above-mentioned components include, as optional components, surfactants, builders, and other components which will be described later. These components can be blended in a usual amount within a range not to hinder the melting of the molten particles (A). it can.

The non-molten particles (B) of the present invention contain a component such that the whole particle does not melt by heating at 65 ° C. or lower as described above. Such a component has a melting point of 65 ° C. Suitable components have a melting point of 70 ° C. or higher, more preferably 80 ° C. or higher. Examples of such components include components having the above-mentioned melting point among builders and other components described later, and these components are blended at a normal dose within a range that does not impair the non-meltability of the non-melted particles (B). can do. In the case of the present invention, the above components may be used alone to form non-melted particles, or two or more of the above components may be appropriately combined into granules to form non-molten particles. They can be mixed and blended.

Specific examples of the (B) non-molten particles of the present invention include, for example, ARBOCEL manufactured by Rettenmeier.
Disintegrant particles such as TF30HG, enzyme particles such as Novinor Disk's sabinase, cannase, evarase, lipolase, and cellzyme, and sodium percarbonate particles such as Mitsubishi Gas Chemical's SPC-D.

The tablet detergent composition of the present invention may contain components other than the above-mentioned (A) molten particles and (B) non-molten particles as long as the effects of the present invention are not impaired. Particles containing no activator or the like but melting at the heating temperature of the present invention, specifically, C _{12 to} C ₁₈ higher alcohols or mixtures thereof, C _{10 to} C ₁₈ higher fatty acids or mixtures thereof, Particles containing an alkyl ester or a mixture thereof, water, fragrance, dye, and the like can be blended with the mixed particles of the above-mentioned (A) molten particles and (B) non-molten particles as long as the effects of the present invention are not impaired. .

The tablet detergent composition of the present invention further comprises:
As described above, the (A) molten particles may contain the following components as optional components within a range that does not hinder the melting, and (B) as components of the non-molten particles, or
The following components can be contained as separate non-molten particles or as non-particles such as a liquid material as components other than the above-described specific components.

That is, the tablet detergent composition of the present invention comprises:
In addition to the above-mentioned (A) low-melting-point surfactants and the like, various surfactants can be used as the above-mentioned (A) molten particles or (B) non-melting particles in accordance with the melting point, blending amount and the like. It can be blended as particles, such surfactants include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and the like, and specific examples of the above-described anionic surfactants The following can be exemplified. (1) A linear alkylbenzene sulfonate having an alkyl group having 8 to 16 carbon atoms. (2) α-olefin sulfonate having 10 to 20 carbon atoms. (3) Sulfonates of saturated or unsaturated fatty acid lower alkyl (C1-3) esters having 8 to 20 carbon atoms or disalts of fatty acid sulfonated products. (4) An alkyl sulfate having 10 to 20 carbon atoms. (5) Alkyl ether sulfates or alkenyl ether sulfates having a linear or branched alkyl or alkenyl group having 10 to 20 carbon atoms and having an average of 0.5 to 8 mol of ethylene oxide added thereto. (6) A saturated or unsaturated fatty acid salt having 10 to 20 carbon atoms. As the counter ion in the anionic surfactant, an alkali metal salt such as sodium or potassium is generally suitable.

Specific examples of the nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbite fatty acid ester, polyoxyalkylene fatty acid alkyl ester, and polyoxyethylene alkyl ester. Ethylene polyoxypropylene alkyl ether, polyoxyethylene castor oil,
Polyoxyethylene hydrogenated castor oil, polyoxyethylene alkylamine, glycerin fatty acid ester, higher fatty acid alkanolamide, alkyl glycoside, alkylamine oxide and the like.

Specific examples of the cationic surfactant include a dialkyl type quaternary ammonium salt and a monoalkyl type quaternary ammonium salt. Examples of the amphoteric surfactant include carboxybetaine and sulfobetaine. In the present invention, the surfactant is usually used alone or in combination of two or more.

The tablet detergent composition of the present invention usually comprises
Melting point, compounding various builders to be added to detergent composition
(A) fused particles or (B) unmelted according to the amount etc.
Can be compounded as particles, with such builders
And inorganic and organic builders. The above inorganic
As builders, for example, sodium carbonate, potassium carbonate
, Sodium bicarbonate, potassium bicarbonate, sodium sulfite
Lium, potassium sulfite, sodium sesquicarbonate, silicic acid
Sodium, crystalline layered sodium silicate, amorphous layered
Alkaline salts such as sodium silicate, sodium sulfate, etc.
Neutral salts, orthophosphate, pyrophosphate, tripoly
Phosphate, metaphosphate, hexametaphosphate, phytin
Phosphates such as acid salts, general formula: x₁(M_TwoO) · Al_TwoO_Two・
y₁(SiO_Two) ・ W₁(H_TwoO) (where M is sodium)
Alkali metal atoms such as potassium and potassium, x₁, Y₁And w₁
Represents the number of moles of each component, and generally, x₁Is 0.7 ~
Number 1.5, y₁Is a number from 0.8 to 6, w₁Is any positive number
Crystalline aluminosilicate represented by the following general formula: x_Two
(M_TwoO) · Al_TwoO_Three・ Y_Two(SiO_Two) ・ W_Two(H_TwoO)
(Where M is an alkali metal source such as sodium, potassium, etc.)
Child, x_Two, Y_TwoAnd w_TwoIndicates the number of moles of each component.
Has x_TwoIs a number from 0.7 to 1.2, y_TwoIs 1.6 to 2.8
The number of w_TwoIs 0 or any positive number)
Aluminosilicate, general formula: x_Three(N_TwoO) · Al_TwoO_Three・
y_Three(SiO_Two) .Z_Three(P_TwoO_Five) ・ W_Three(H _TwoO) (expression
Wherein M is an alkali metal atom such as sodium or potassium;
x_Three, Y_Three, Z_ThreeAnd w_ThreeIndicates the number of moles of each component.
Has x_ThreeIs a number from 0.2 to 1.1, y_ThreeIs 0.2 to 4.0
The number of z_ThreeIs 0.001-0.8, w_ThreeIs 0 or any positive
Amorphous aluminosilicate represented by
It is. Among the above inorganic builders, sodium carbonate, charcoal
Potassium silicate, sodium sulfite, sodium silicate, al
Sodium minosilicate is preferred.

Examples of the organic builder include nitrilotriacetate, ethylenediaminetetraacetate, β-
Aminocarboxylates such as alanine diacetate, aspartate diacetate, methylglycine diacetate and iminodisuccinate; serine diacetate, hydroxyiminodisuccinate, hydroxyethylethylenediamine triacetate, dihydroxyethylglycine salt and the like Hydroxyamino carboxylate; hydroxy carboxylate such as hydroxy acetate, tartrate, citrate, gluconate; cyclocarboxylate such as pyromellitic acid, benzopolycarboxylate, cyclopentanetetracarboxylate An ether carboxylate such as carboxymethyl tartronate, carboxymethyloxysuccinate, oxydisuccinate, tartaric acid mono- or disuccinate; polyacrylic acid, acrylic acid-allyl alcohol copolymer, acrylic acid-maleic acid copolymer , Acrylic acid polymers and copolymers such as droxyacrylic acid polymer and polysaccharide-acrylic acid copolymer; maleic acid, itaconic acid, fumaric acid, tetramethylene 1,2-dicarboxylic acid, succinic acid, aspartic acid, etc. A polymer or copolymer of the following: polysaccharide oxides such as starch, cellulose, amylose, pectin and polysaccharides such as carboxymethyl cellulose; polyethylene excluding those contained in the low-melting surfactant contained in the component (A) Examples include non-dissociated polymer compounds such as glycol, polyvinyl alcohol, and polyvinylpyrrolidone. Among these organic builders, citrate, aminocarboxylate, polyacrylate, acrylic acid-maleic acid copolymer and the like are preferable. The above builders are usually used alone or in combination with 2
A mixture of more than one species is used. The amount of the builder is preferably 5 to 60% by mass, particularly preferably 10 to 50% by mass in the detergent composition in order to impart sufficient detergency.
It is desirable to mix so as to be included.

The tablet detergent composition of the present invention may further contain the following components which are usually contained in detergents. These components can be blended as the above-mentioned (A) molten particles or (B) non-molten particles during the granulation treatment step according to the melting point, the blending amount, and the like, or can be produced as non-particles such as a liquid material. It can also be mixed with detergent particles obtained by granulation.

Such components include, for example, fluorescent agents,
Enzymes, bleach, bleach activator, rinse agent, surface modifier,
Examples include a redeposition inhibitor, a porous oil absorbing agent, an oil gelling agent, a fragrance, and the like. [Tinopearl CBS-
X] and the like; lipase, protease, cellulase, amylase and the like; bleaching agents such as percarbonates and perborates; bleaching activators; alkanoyloxybenzenesulfonic acid / salts having 11 to 19 carbon atoms; Number 8
Alkanoyloxybenzoic acid / salts, etc., as rinsing agents, silicone oils, etc., as surface modifiers, finely divided calcium carbonate, finely divided zeolites, granular zeolites, polyethylene glycols, etc .; Derivatives, etc.
Examples of the porous oil absorbing agent include amorphous silicic anhydride and calcium silicate, and examples of the oil gelling agent include 12-hydroxystearic acid and metal soap.

As the above-mentioned fragrance used in the present invention, those which can be generally blended with a detergent can be used.
fume and Flavor Chemicals
Vol. Iand II, Stepeffen Ar
ctander, Allured Pub. Co. (1
994) and "Synthetic Fragrance Chemistry and Product Knowledge", Motoichi Indo, Kagaku Kogyo Nippo (1996) and "Perfu"
me and Flavor Materials o
f Natural Origin ", Steffe
n Arcstander, Allured Pub. C
o. (1994) and "Encyclopedia of Fragrance", edited by the Japan Fragrance Association, Asakura Shoten (1989) and "Perfumer"
y Material Performance V.Y.
3.3 ", Boelens Aroma Chemical
al Information Service (19
96) and "Flower oils and Fl
oral Compounds In Perfume
ry ", Danute Lajaujis Anoni
s, Allured Pub. Co. (1993), etc., each of which is incorporated herein by reference. The following are representative examples of fragrances, but are not limited thereto.

<Hydrocarbon compounds> Ocimene, dihydromyrcene, farnesene, cedrene, α-pinene, β-
Pinene, limonene, dipentene, camphene, ferrandrene, terpinene, 3-carene, terpinolene, bisabolene, β-caryophyllene, cadinene, valensen, tsuyosen, guaien, aroocimen, myrcene, longifolene, verdracin (1,3,5-undecatriene) ), P-cymene, 4-isopropyl-1-
Methyl-2-propenylbenzene, diphenyl, diphenylmethane, orange terpene, lemon terpene, bergamot terpene, peppermint terpene, spearmint terpene, lime terpene, vetiver terpene, rose wax, jasmine wax, limonene dimer,
Pentane, hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, icosane, hencicosane, docosane, trichosane, tetracosane, pentacosane, hexacosane, heptacosane, octacosane, nacosano
Triacontan and the like.

<Alcohol compound> 3-Methyl-1-
Pentanol, geraniol, cedrol, citronellol, rhinol, nerol, dihydrolinalool, linalool, tetrahydrolinalool, dimethyloctanol, tetrahydromugol, mugol, myrcenol, dihydromyrcenol, oximenol, tetrahydromyrcenol, lavandurol, isodihydro Lavandulol, hydroxycitronellol, nonadil (6,8-dimethyl-2-nonanol), ethyl linalool, isopulegol, terpineol, dihydroterpineol, terpineol-4, perilla alcohol,
4-Thuanol, 3-Thuanol, Farnesol, Nerolidol, α-Bisabolol, β-Caryophyllene alcohol, Santalol, Vetiverol, Cedrenol, Patchouli alcohol, Dihydrocarbeol, Phytol, Isophytol, Sclareol, Carveol, Menthol, 1-Heptanol , 2-heptanol, 3-heptanol, 1-octanol, 2-octanol, 3-octanol, 2-ethylhexanol,
1-nonanol, 2-nonanol, isononyl alcohol (3,5,5-trimethyl-1-hexanol), 1
-Decanol, 1-undecanol, 2-undecanol, 1-dodecanol, prenol (3-methyl-2-
Buten-1-ol), 2-methyl-3-buten-2-
All, β-pentenol (1-penten-3-ol), leaf alcohol (cis-3-hexenol), trans-2-hexenol, trans-3
-Hexenol, cis-4-hexenol, 2,4-
Hexadien-1-ol, matsutakeol (1-octen-3-ol), cis-6-nonenonel, cucumber alcohol (2,6-nonadienol), androl (1-nonen-3-ol), rosalva (9 -Decenol), 1-undecenol, undecavertol (4-methyl-3-decen-5-ol), osylol (3,7-dimethyl-7-methoxy-2-octanol), santalinol (2-methyl- 4- (2,2,3
-Trimethyl-3-cyclopenten-1-yl) -2-
Buten-1-ol), p, α-dimethylbenzyl alcohol, 2,2,6-trimethylcyclohexyl-3-
Hexanol, 1,2-pentanediol, benzyl alcohol, anis alcohol, β-phenylethyl alcohol, styryl alcohol (1-phenyl-1-hydroxyethane), hydratropa alcohol, methyl β
-Phenylethyl alcohol, α-propylphenylethyl alcohol, vanillyl alcohol, decahydro β-
Naphthol, furfuryl alcohol, 3-methyl-1-
Phenyl-3-pentanol, amylcinnamic alcohol, cinamic alcohol, phenoxanol (3-methyl-5-phenylpentanol), 1,2-
Pentanediol, 2-ethylhexanol, dimethol (2,6-dimethylheptanol), 3,6-dimethyl-3-octanol, cohinol (3,4,5,6)
6-pentamethyl-2-heptanol), brahamanol (methyltrimethylcyclopentenylbutanol),
Bagdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-butene-
1-ol), sandalore (3-methyl-5- (2,
2,3-trimethylcyclopenta-3-en-yl)-
Pentan-2-ol), cyclohexylethyl alcohol, apopachone (p-isopropylcyclohexanol), floralol (2,4-dimethyl-3-cyclohexene-1-methanol), pachone (p-tert)
-Butylcyclohexanol), belldol (o-te
rt-butylcyclohexanol), mayol (p-
Isopropylcyclohexylmethanol), cyclomethylene citronellol, ambrinol (2,5,5-trimethyl-octahydro-2-naphthol), methylsandefurol (5'or6'-methylnorborn-5 ')
-En-2-yl) -2-methylpent-1-ene-3
-Ol), Timberol (2,2,6-trimethylcyclohexyl-3-hexanol), Polysanthol (3,3-dimethyl-5- (2,2,3-trimethyl-
3-cyclopenten-1-yl) -4-pentene-2-
All), hydroxycitronellol, nonadil (6,8-dimethyl-2-nonanol), isopulegol, isocyclogeraniol, myrtenol, nopol (6,6-dimethylbicyclo [3.1.1] hept-2)
-En-2-ethanol), pinocalveol, α-phenalkyl alcohol, borneol, isoborneol, patchomint (2- (3,3-dimethylbicyclo [2.2.1] hept-2-ylidene) ethanol),
Camecol (trimethylnorbornanemethanol), dimethylcyclomol, Santalex T (isocamphyl cyclohexanol), geranyl linalool, cumin alcohol, 2-methoxyphenylethyl alcohol,
Phenoxyethyl alcohol (1-hydroxy-2-phenoxyethane), α, α-dimethylphenylethyl alcohol, isobutylbenzylcarbinol, p-methylbenzylcarbinol, hydrocinamic alcohol, centiphor (1,1-dimethyl-3) -Phenylpropanol-1), muget alcohol (2,2-
Dimethyl-3-phenylpropanol), phenylhexanol, decahydro β-naphthol, AR-1 (3,
6-dimethyloctane-3-ol), abitol (hydroabiethyl alcohol), α-propylphenylethyl alcohol, p-methyldimethylbenzylcarbinol, mugetanol (1- (4-isopropylcyclohexyl) ethanol), fluorolol (2- Isobutyl-
4-hydroxy-4-methyltetrahydropyran), propylene glycol, dipropylene glycol, hexylene glycol and the like.

<Phenol and Phenol Ether Compounds> Anisole, estragole, chavicol,
Anethole, cresol, carvacrol, p-cresol, p-cresyl methyl ether, β-naphthol methyl ether, β-naphthol ethyl ether, β-
Naphthol isobutyl ether, veratrol (1,2
-Dimethoxybenzene), 1,3-dimethoxybenzene, 1,4-dimethoxybenzene, catechol, resorcinol, guaiacol, valspice (4-methylguaiacol), 4-ethylguaiacol, orcinyl 3
(3-methoxy-5-methylphenol), thymol,
Methyl thymol, propenyl guaetol (trans
-2-ethoxy-5- (1-propenyl) -phenol), o-ethylphenol, m-ethylphenol,
p-ethylphenol, 2-tert-butylphenol, syringol (2,6-dimethoxyphenol),
Hydroquinone dimethyl ether, resorcin dimethyl ether, eugenol, isoeugenol, dihydroeugenol, methyl eugenol, methyl isoeugenol, ethyl isoeugenol, benzyl eugenol, benzyl isoeugenol, diosphenol, hinokitiol, banitrop (1-ethoxy-2-hydroxy-4-propenyl) Benzene), Shogaol,
Gingerol, acetyl eugenol, acetyl isoeugenol safrole, isosafrole, diphenyl oxide, vetiver ether (tert-butylhydroquinone dimethyl ether) and the like.

<Aldehyde compounds> Citronellal,
Citral, 3,7-dimethyl-1-octanal, hydroxycitronellal, methoxycitronellal, perilaldehyde, miltenal, caryophyllenaldehyde, n-hexal, 2-methylbutanal, isovaleraldehyde, n-valeraldehyde, acetaldehyde , N-heptanal, n-octanal, n-nonanal, 2-methyloctanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal,
Dodecanal, 2-methyldecanal, 2-methylundecanal, tridecanal, tetradecanal, 2-
Pentenal, cis-3-hexenal, trans
-2-hexenal, trans-2-heptenal,
4-heptenal, trans-2-octenal, t
ran-2-nonenal, cis-6-nonenal,
Melonal (2,6-dimethyl-5-heptenal),
trans-4-decenal, cis-4-decenal, trans-2-decenal, glynal (2,
5,6-trimethyl-4-heptenal), 10-undecenal, trans-2-undecenal, tra
ns-2-dodecenal, mandarin aldehyde (3-
Dodecenal), trans-2-tridecenal, adoxal (2,6,10-trimethyl-9-undecene-1-al), 2,4-hexadienal, 2,4
Heptadienal, 2,4-octadienal, 2,
4-nonadienal, 2,6-nonadienal, 2,4
-Decadienal, 2,4-undecadienal, 2,
4-dodecadienal, geraldaldehyde (5,9-dimethyl-4,8-decadienal), trimenal (3
7,9-trimethyl-2,6-decadien-1-al), oncidal (2,6,10-trimethyl-5,5).
9-undecadienal), bergamar (α-methylenecitronellal), camphorenaldehyde, cyclocitral, isocyclocitral, safranal (2,6,6-trimethyl-1,3-cyclohexadiene-1-carboxy) Aldehyde), mugealdehyde (6,10-dimethyl-3-oxa-9-undecenal), geranyloxyacetaldehyde, tripral (dimethyltetrahydrobenzaldehyde), chrysanal (3-propylbicyclo [2,2,1] -5-heptene- 2-carboxaldehyde), centenal (methoxydicyclopentadienecarboxaldehyde), dupical (4-tricyclodecylidenebutanal), 4- (4-methyl-3-cyclohexenylidene-1) pentanal, mylar Click aldehyde (4 (3)
-(4-methyl-3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), setnal (trimethylcyclohexenemethylbutanal), inonal (2-methyl-4- (2,6,6-trimethyl) −
1 (2) -cyclohexenyl) -butenal), terestral (4-cyclooctene-1-carboxaldehyde), benzaldehyde, p-tolylaldehyde, phenylacetaldehyde, trifernal (3-phenylbutanal), cuminaldehyde, p -Methylphenylacetaldehyde, p-isopropylphenylacetaldehyde, hydratropaldehyde, p-methylhydratropaldehyde, p-isopropylhydratropaldehyde, phenylpropionaldehyde, β-methylhydrocinnamic aldehyde, jasmorandi (2
-Methyl-3- (4-methylphenyl) -propanal), burgeonal (p-tert-butylhydrocinnamic aldehyde), cyclamenaldehyde (2
-Methyl-3- (p-isopropylphenyl) -propionaldehyde), florarozone (p-ethyl-α, α
-Dimethylhydrocinnamic aldehyde), suzaral (p-isobutyl-α-methylhydrocinnamic aldehyde), cinamic aldehyde, salicylaldehyde, anisaldehyde, o-methoxybenzaldehyde, o-methoxycinnamic aldehyde, canthoxal (2-methyl -3- (p-methoxyphenyl) -propanal), vanillin, ethyl vanillin, methyl vanillin (3,4-dimethoxybenzaldehyde), heliotropin, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde) ), Phenoxyacetaldehyde, p-methylphenoxyacetaldehyde, furfural, 5-methylfurfural, 5-
Hydroxymethyl-2-furfural, furyl acrolein, liral (4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), bernaldehyde (1-methyl-4-
(4-methylpentyl) -3-cyclohexenecarboxaldehyde), homomyracaldehyde (1-methyl-4 (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde), Junipearl (4
(5) -formyl-7,7,9-trimethylbicyclo [4.3.0] -nonene), vertral (octahydro-4,7-methanoindenecarboxaldehyde), lilial (p-tert-butyl-α-) Methylhydrocinnamic aldehyde), mefuranal (3-
Methyl-5-phenylvaleraldehyde), eglantal (4-methyl-2-phenyl-2-pentenal),
Cocal (5-methyl-2-phenyl-2-hexenal), α-methylcinnamic aldehyde, α-butyl cinnamic aldehyde, α-amyl cinnamic aldehyde, α-hexyl cinnamic aldehyde, formyl ethyl tetramethyl tetralin (6 -Ethyl-7-formyl-1,1,4,4-tetramethyl-1,2,2
3,4-tetrahydronaphthalene) and the like.

<Acetal and ketal compounds> Magnolan (2,4-dimethyl-4,4a, 5,9b-tetrahydroindeno [1.2d] -1,3-dioxane), anthoxane (4-isopropyl- 5,5-dimethyl-1,3-dioxane), indoflor (dihydroindenyl-2,4-dioxane), boasambrene forte (formaldehyde cyclododecylethyl acetal), acetaldehyde diethyl acetal, leaf acetal (acetaldehyde ethylhexenyl acetal) ), Acetaldehyde ethylhexyl acetal, citronellyl methyl acetal, erinal (acetaldehyde ethyl linalyl acetal), bonalox (2,4-dioxane-3-methyl-7,10-methanospiro [5.5]) Decane), ephetal (acetaldehyde ethyl phenyl acetal), acetaldehyde ethyl isoeugenyl acetal, acetal R (acetaldehyde phenyl ethyl n-propyl acetal), fluoropearl (acetaldehyde 2-phenyl-2,4-pentanediol acetal), spirofurol ( 3-ethyl-2,4-dioxaspiro [5.
5] undecen-8-ene), ethyldimethyldioxaspiroundecene, herboxane (2-butyl-4,
4,6-trimethyl-1,3-dioxane), calanal (2- (2,4-dimethylcyclohex-3-cene-1)
-Yl) -5-methyl-5 (1-methylpropyl) 1,
3-dioxane), hexanal dimethyl acetal,
Hexanal diethyl acetal, hexanal propylene glycol acetal, carotene (4,7-dihydro-2- (3-pentanyl) -1,3-dioxepin), 2-hexenal diethyl acetal, cis-
3-hexenal diethyl acetal, heptanal dimethyl acetal, heptanal diethyl acetal,
Heptanal ethylene glycol acetal, 2-hexyl-5-methyl-1,3-dioxolan, 5-methyl-5-propyl-2- (1-methylbutyl) -1,3-
Dioxane, octanal dimethyl acetal, octanal diethyl acetal, nonanal dimethyl acetal, nonanal diethyl acetal, decanal dimethyl acetal, decanal diethyl acetal, 2-
Methylundecanal dimethyl acetal, dodecanal dimethyl acetal, citral dimethyl acetal, citral diethyl acetal, citral propylene glycol acetal, citronellal cyclomonoglycol acetal, hydroxycitronellal dimethyl acetal, hydroxycitronellal diethyl acetal, cis-3- Hexenal diethyl acetal, benzaldehyde dimethyl acetal, benzaldehyde diethyl acetal, benzaldehyde propylene glycol acetal, benzaldehyde glycerin acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde ethylene glycol acetal, phenylacetaldehyde diisobutyl acetal, phenylacetate Tolaldehyde propylene glycol acetal, phenylacetaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde glyceryl acetal, resedabody (phenylacetaldehyde-2,4-dihydroxy-2-methylpentane acetal), 3-phenylpropionaldehyde dimethyl acetal, hydratropa Aldehyde dimethyl acetal, hydratropalaldehyde ethylene glycol acetal, osminal DMA (amylcinamic aldehyde dimethyl acetal), osminal DEA
(Amylcinamic aldehyde diethyl acetal), heliotropin dimethyl acetal, heliotropin diethyl acetal, vanillin propylene glycol acetal, verdoxane (2,2,5,5-tetramethyl-4-isopropyl-1,3-dioxane), amber sage (4,7-dihydro-2-isopentyl-
2-methyl-1,3-dioxepin), acetoketal (2,5,5-trimethyl-2-phenyl-1,3-dioxane), jasmonane (2-butyl-4-dioxaspiro [4.4] nonanone), fraystone (Ethyl-
2,4-dimethyl-1,3-dioxolan-2-acetate), fructon (ethyl-2-methyl-1,3-dioxolan-2-acetate) and the like.

<Ketone compounds> Acetylcaryophyllene, carvone, pulegone, piperitenone, piperiton,
Menthone, show brain, oxocedran, isolongiforanone, nootkatone, 2-heptanone, 2-pentanone, 3-hexanone, 3-heptanone, 4-heptanone, 2-octanone, 3-octanone, 2-nonanone,
3-nonanone, 2-undecanone, 2-tridecanone,
Methyl isopropyl ketone, ethyl isoamyl ketone,
Mesityl oxide, butylideneacetone, methylheptadienone, methylheptenone, dimethyloctenone,
Coabon (4-methylene-3,5,6,6-tetramethyl-2-heptanone), geranylacetone, farnesylacetone, acetoin, butyroin (5-hydroxy-4-octanone), methyl lavender ketone (3-hydroxymethyl- 2-nonane), diacetyl, 2,3-
Pentadione, 2,3-hexadione, 3,4-hexadione, 2,3-heptadione, acetylisovaleryl, amylcyclopentanone, amylcyclopentenone, 2-cyclopentylcyclopentanone, hexylcyclopentanone, fluuramon (2 -N-heptylcyclopentanone), cis-jasmon, dihydrojasmon, isojasmon, trimethylpentylcyclopentanone, sedamone (2-butylidene-3,5,5 (3,
3,5) -trimethylcyclopentanone), Sandex (3-methyl-5- (2,2,3-trimethyl-3-)
Cyclopentenyl) -3-penten-2-one), cycloten, coronol (3,5-dimethyl-1,2-cyclopentadione), methylcorylone (3,4-dimethyl-1,2-cyclopentadione), verdone ( 2-ter
t-butylcyclohexanone), p-tert-butylcyclohexanone, Hellbach (3,3-dimethylcyclohexylmethylketone), frescommente (2-se
c-butylcyclohexanone), artemon (1-acetyl-3,3-dimethyl-1-cyclohexene), celery ketone (3-methyl-5-propyl-2-cyclohexenone), krypton (4-isopropyl-2-cyclohexanone) , Oribbon (p-tert-pentylcyclohexanone), methylcyclocitron (2,3,5
-Trimethyl-4-cyclohexenyl-1-methyl ketone), nelon (1- (p-menten-6-yl) -1-)
Propane), vetival (4-cyclohexyl-4-methyl-2-pentanone), havanol (2- (1-cyclohexen-1-yl) -cyclohexanone), maltol, ethyl maltol, oxide ketone (cis-
2-acetonyl-4-methyl-tetrahydropyran),
Emoxifuron (5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone), homofurol (2-ethyl-4-hydroxy-5-methyl-3 [2H] -furanone and 5-ethyl-4-hydroxy- 2-methyl-3 [2H] -furanone), sotolone (3-hydroxy-4,5-dimethyl-2 [5H] -furanone), furaneol (2,5-dimethyl-4-hydroxy-3 [2
H] -furanone), acetyldimethylfuran, furfural acetone, 2-acetyl-5-methylfuran, 2-
Acetylfuran, methyltetrahydrofuranone, dibenzylketone, benzophenone, methylnaphthylketone,
4-damaschol (5-phenyl-5-methyl-3-hexanone), veticon (4-methyl-4-phenyl-2)
-Pentanone), α-methylanisalacetone, heliotropylacetone, anisylideneacetone, anisylacetone, p-methoxyphenylacetone, raspberry ketone (4- (p-hydroxyphenyl) -2-butanone), labandzone (3- Methyl-4-phenyl-3-
Buten-2-one), benzylideneacetone, p-methoxyacetophenone, p-methylacetophenone, propiophenone, acetophenone, damacenone, damascon, isodamascon, α-dynascone (1- (5,5
-Dimethylcyclohexen-1-yl) -4-penten-1-one), iriton (4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2
-One and 4-3,5,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one),
Yonone, pseudoyonone, methylyonone, methyliriton (3-methyl-4- (2,4,6-trimethyl-3-
Cyclohexenyl) -3-buten-2-one), cyclowood (2,4-di-tert-butylcyclohexanone), iron, allylyonone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, Kamek DH
(2-acetyl-3,3-dimethylnorbornane), Florex (6-ethylideneoctahydro-5,8-methano-2H-1-benzopyran-2-one), plicaton (4-methyltricyclo [6.2] .1.0 ^2,7] undecane-5-one), Okisosedoran, belt fix (9-acetyl -2,6,6,8- tetramethyl tricyclo [5.3.1 ^1,7 .0 ^1,5 -8-undecene),
Verbenone (4,6,6-trimethyl- (1R) -bicyclohept-3-en-2-one), fencon, caron (7-methyl-3,5-dihydro-2H-benzodioxepin-3-one) , Trimofix O (2, 6,
10-trimethyl-1-acetyl-2,5,9-cyclododecatriene), vitalide (acetyldimethyltetrahydrobentuindane), epiton (7 (8) -acetyl-5-isopropyl-2-methylbicyclo [2.
2.2] Oct-2-ene), atrinone (4 (5)-
Acetyl-7,7,9 (7,7,9) -trimethylbicyclo [4.3.0] -1-nonene), cashmeren (6,7-dihydro-1,1,2,3,3-pentamethyl- 4 (5H) -indanone), muscone (3-methylcyclopentadecanone-1), cibetone (cycloheptadec-9-en-1-one), exaltone (cyclopentadecanone), musk TM-II (cyclohexene) Sadesenone), phantolide (5-acetyl-1,1,2,2,3)
3,3,6-hexamethylindane), celestride (4-acetyl-6-tert-butyl-1,1-dimethylindane), traseolide (5-acetyl-3-)
Isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4,4,4)
7-hexamethyltetrahydronaphthalene), vitalide (acetyldimethyltetrahydrobenzindane),
IsoE Super (7-acetyl-1,2,3,
4,5,6,7,8-octahydro-1,1,6,7-
Tetramethylnaphthalene), dihydrocarbon, diosphenol, zingerone and the like.

<Ether compounds> Methylhexyl ether, decyl methyl ether, decyl vinyl ether,
Diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, citronellyl ethyl ether, geranyl ethyl ether, α-terpinyl methyl ether, Herberbert (3,3,5-trimethylcyclohexylethyl ether), isobornyl methyl ether, tricyclode Se methyl ether, isopropenyl cyclohexene (2-ethylidene-6-isopropoxide Sibi [2.2.1] heptane), Juniparomu (methoxydimethylsilyl tricyclo [5.2.1.0 ^{2, 6]} decane),
Cyclododecyl methyl ether, Madrox (1-methylcyclododecyl methyl ether), fizeol (2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo [3.3.1] -nonane), cedulambar (cedrol methyl ether) ), Methyl benzyl ether, methyl phenyl ethyl ether, ethyl 2-methoxybenzyl ether, allyl phenyl ethyl ether,
Isoamylbenzyl ether, answer (isoamylphenylethyl ether), jacene (2-methyl-2-
Butenyl phenyl ethyl ether), dibenzyl ether, cyclohexyl phenyl ether, mylooxide (osimene epoxide), limonene oxide (p-mentha-8-ene-1,2-epoxide), rubofix (spiro [1,4-methanonaphthalene) -2 (1H),
2'-oxirane],-3,4,4a, 5,8,8a-
Hexahydro-3 ', 7-dimethyl and spiro [1,4-methanonaphthalene-2 (1H), 2'-oxirane],-3,4,4a, 5,8,8a-hexahydro-3', 6-dimethyl ), Trimethylcyclododecatriene epoxide, caryophyllene oxide, cedrene epoxide, isolongifolene epoxide, linalool oxide, citrooxide (2,2-dimethyl-5 (1-methyl-1-propenyl) -tetrahydrofuran), herbooxide ( 5-isopropenyl-2-
Methyl-2-vinyltetrahydrofuran), rosefuran (3-methyl-2- (3-methyl-2-butenyl)-
Furan), heptabelt (2-heptyltetrahydrofuran), mentfuran, theaspirane, oxybet (2-oxaspiro [4,7] dodecane), muscogen (3-oxabicyclo [10.3.0] -6-pentadecene), cyclambar (13-oxabicyclo [10.
3.0] pentadecane), ambroxane (decahydro-3a, 6,6,9a-tetramethylnaphtho [2.1-
b] furan), glycalva (3a-ethyldodecahydro-6,6,9a-trimethylnaphtho [2.1-b] furan), 1,8-cineole, 1,4-cineole, galaxolide (1,3,4) , 6,7,8-Hexahydro-
4,6,6,7,8,8-hexamethylcyclopenta-
γ-2-benzopyran), rose oxide, nerol oxide, rimetol (2,2,6-trimethyl-6)
-Vinyltetrahydropyran), dilan (2-butyl-
4,6-dimethyldihydropyran), dremox (tetrahydro-4-methyl-2-phenyl-2H-pyran), rubofuro (9-ethylidene-3-oxatricyclo [6.2.1.0 ^2,7 ] undecane ), Hexahydroindenopyran and the like.

<Acid compound> Gellanic acid, acetic acid, propionic acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid,
2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, hexanoic acid, isohexanoic acid,
2-hexanoic acid, 4-pentenoic acid, 2-methyl-2-pentenoic acid, heptanoic acid, 2-methylheptanoic acid, octanoic acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylenic acid, dodecanoic acid, myristic acid , Palmitic acid, stearic acid, anthranilic acid, oleic acid, levulinic acid,
Lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, 3-phenylpropionic acid, vanillic acid, valine, abietic acid,
And sorbic acid.

<Lactone compounds> Pentalide (cyclopentadecanolide), havanolide (oxacyclohexadecen-2-one), ambretto, cyclohexadecanolide, 10-oxahexadecanolide, 11-oxahexa Decanolide, 12-oxahexadecanolide, ethylene dodecandioate, γ-butyrolactone, γ-valerolactone, angelica lactone, γ-hexalactone, γ-heptalactone, γ-octalactone, γ-nonalactone, whiskey lactone (3-methyl-4-octanolide), γ-decalactone, γ-undecalactone, γ-dodecalactone, γ-jasmolactone, jasmine lactone, cis jasmon lactone,
Lactojasmon (4-methyl-4-decanolide), jasmolactone (tetrahydro-6- (3-pentenyl) -2H-pyran-2-one), mentalactone (3,6-dimethyl-5,6,7, 7a-tetrahydro-2 (4H) -benzofuranone), n-butylphthalide, propylidenephthalide, butylidenephthalide, δ-
Hexalactone, δ-octalactone, tribarone (4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one), δ-nonalactone, δ-decalactone, δ-2-decenolactone, δ-undeca Lactone, δ-dodecalactone, δ-tridecalactone, δ-
Tetradecalactone, lactoscatone (decahydro-
4, α-hydroxy-2,8,8-trimethylnaphthalene-2-carboxyacid-δ-lactone), coumarin, dihydrocoumarin, cyclohexyllactone, 6-
Examples include methyl coumarin, ε-decalactone, ε-dodecalactone, and the like.

<Ester Compounds> Ethyl formate, propyl formate, butyl formate, amyl formate, isoamyl formate, hexyl formate, cis-3-hexenyl formate, octyl formate, linalyl formate, citronellyl formate, geranyl formate,
Neryl formate, rosinyl formate, terpinyl formate, cedril formate, caryopherylene formate, afermate (α,
3,3-trimethylcyclohexanemethylformate), oxyoctaline formate, benzyl formate, cinnamyl formate, phenylethyl formate, anisyl formate, eugenyl formate, decahydro-β-naphthyl formate, methyl acetate,
Ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, 2-methylbutyl acetate, isoamyl acetate, amyl acetate, prenyl acetate, hexyl acetate,
Cis-3-hexenyl acetate, trans-2-hexenyl acetate, 2-ethylhexyl acetate, heptyl acetate, octyl acetate, 3-octyl acetate, octenyl acetate, nonyl acetate, decyl acetate, trimethylhexyl acetate, decenyl acetate, nonanediol acetate, Dodecyl acetate, dimethyl undecadienyl acetate, diacetyl, diacetin, triacetin, ethylene glycol diacetate, ethylene glycol monobutyl ether acetate, allyl amyl glycolate, osimenyl acetate, myrcenyl acetate, dihydromyrcenyl acetate, dimethyloctanyl acetate, linalyl acetate , Citronellyl acetate, rosinyl acetate, geranyl acetate, neryl acetate, tetrahydromugol acetate, ethyl linalyl acetate, lavanjuril acetate, isohydrolavandulyl acetate, vinegar Nerolidol, carbyl acetate, dihydrocarbyl acetate, dihydrocuminyl acetate, terpinyl acetate, isopulegol acetate, menthyl acetate, citryl acetate, myrenyl acetate, nopyryl acetate, fenquil acetate, bornyl acetate, isobornyl acetate, ceryl acetate, caryophyllene acetate, santalyl acetate , Betiberyl acetate, guaiac acetate, methyl cyclopentylidene acetate,
Cyclohexyl acetate, p-isopropylcyclohexanyl acetate, tert-amylcyclohexyl acetate, dihydroterpinyl acetate, cyclohexylethyl acetate, fluorolate (2,4-dimethyl-3-cyclohexenylmethyl acetate), rosamsk (α, 3, acetic acid) 3-trimethylcyclohexanemethyl), Vertenex (p-te acetate)
rt-butylcyclohexyl), Veldox (acetic acid o)
-Tert-butylcyclohexyl), 1-ethynylcyclohexyl acetate, dihydroambrate (1-acetoxy-2-sec-butyl-1-vinylcyclohexane), mirardyl acetate (4 (3)-(4-methyl-3)
-Pentenyl) -3-cyclohexenylmethyl acetate), tricyclodecenyl acetate, tricyclodecyl acetate, benzyl acetate, p-cresyl acetate, phenylethyl acetate, styryl acetate, p-methylbenzyl acetate, anisyl acetate, piperonyl acetate , Acetylvanillin, rosephenone, hydratropyl acetate, 2,4-dimethylbenzyl acetate, cinnamyl acetate, phenylpropyl acetate, cuminyl acetate, dimethylbenzylcarbinyl acetate, phenylglycol diacetate, dimethylphenylethylcarbinyl acetate, phenylethylmethyl acetate Ethylcarbinyl, beticol acetate (4-methyl-4-phenyl-2-pentyl acetate), α-amylcinnamimyl acetate, jasmarol (trans-decahydro-β)
-Naphthyl acetate), furfuryl acetate, tetrahydrofurfuryl acetate, jasmar (3-pentyltetrahydropyranyl acetate), jasmeria (5-methyl-3-butyltetrahydropyranyl acetate), ethyl acetoacetate, jessate (2-hexylacetoacetic acid) ethyl),
Ethyl benzylacetoacetate, allyl cyclohexyl acetate, isopropyl cyclohexenyl acetate, ethyl propionate, propyl propionate, allyl propionate,
Butyl propionate, isobutyl propionate, isoamyl propionate, hexyl propionate, cis-3-hexenyl propionate, trans-propionate
2-hexenyl, decenyl propionate, linalyl propionate, citronellyl propionate, rosinyl propionate, geranyl propionate, neryl propionate,
Carbyl propionate, terpinyl propionate, menthyl propionate, bornyl propionate, isobornyl propionate, tricyclodecenyl propionate, benzyl propionate, styryl propionate, anisyl propionate, phenylethyl propionate, cinnamyl propionate, propionate Phenyl propylate, dimethyl benzyl carboxy propionate, phenoxyethyl propionate, propylene glycol dipropionate propionate, rabudanax (3-hydroxy-
Ethyl 3-phenylpropionate), isobutyl furanpropionate, methyl butyrate, ethyl butyrate, propyl butyrate,
Isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyl butyrate, amyl butyrate, isoamyl butyrate, hexyl butyrate,
Heptyl butyrate, cis-3-hexenyl butyrate, tr butyrate
ans-2-hexenyl, octyl butyrate, propylene glycol dibutyrate, linalyl butyrate, citronellyl butyrate, rosinyl butyrate, geranyl butyrate, neryl butyrate, terpinyl butyrate, cyclohexyl butyrate, benzyl butyrate, cinnamyl butyrate, phenylethyl butyrate, dimethylbenzyl carbyl butyrate , Tetrahydrofurfuryl butyrate, santaryl butyrate, methyl isobutyrate, ethyl isobutyrate, propyl isobutyrate, isopropyl isobutyrate, butyl isobutyrate, isobutyl isobutyrate, isoamyl isobutyrate, hexyl isobutyrate, cis-3-hexenyl isobutyrate, iso Butyric acid 2,4
-Hexadienyl, isopentylate (1,3 isobutyric acid)
-Dimethyl-3-butenyl), octyl isobutyrate, linalyl isobutyrate, citronellyl isobutyrate, rosinyl isobutyrate, geranyl isobutyrate, neryl isobutyrate, terpinyl isobutyrate, tricyclodecenyl isobutyrate, benzyl isobutyrate, isobutyric acid p-cresyl, cinnamyl isobutyrate, phenylethyl isobutyrate, phenylpropyl isobutyrate, styryl isobutyrate, dimethylcarbyl isobutyrate, dimethylphenylethylcarbyl isobutyrate, floranol (phenoxyethyl isobutyrate), decahydro isobutyrate
β-naphthyl, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, 2-methylbutyl 2-methylbutyrate, sidoran (hexyl 2-methylbutyrate), cis-methyl 2-butyrate
3-hexenyl, benzyl 2-methylbutyrate, phenylethyl 2-methylbutyrate, allyl 2-ethylbutyrate, ethyl 3-hydroxybutyrate, methyl valerate, ethyl valerate, butyl valerate, isobutyl valerate, amyl valerate, valley Herbic acid c
is-3-hexenyl, benzyl valerate, phenylethyl valerate, furfuryl valerate, methyl isovalerate, ethyl isovalerate, propyl isovalerate, isopropyl isovalerate, allyl isovalerate, butyl isovalerate, iso Isobutyl valerate, isoamyl isovalerate, amyl isovalerate, 2-methylbutyl isovalerate, cis isovalerate
-3-hexenyl, hexyl isovalerate, octyl isovalerate, linalyl isovalerate, citronellyl isovalerate, geranyl isovalerate, menthyl isovalerate, terpinyl isovalerate, cyclohexyl isovalerate, benzyl isovalerate, Phenylethyl isovalerate, phenylpropyl isovalerate, cinnamyl isovalerate, manzanate (ethyl 2-methylvalerate), phenyl salicylate,
Peranato (2-methylvaleric acid 2-methylpentyl ester), methyl hexanoate, ethyl hexanoate, propyl hexanoate, isopropyl hexanoate, allyl hexanoate, butyl hexanoate, isobutyl hexanoate, amyl hexanoate, isoamyl hexanoate, Hexyl hexanoate, cis-3-hexenyl hexanoate, hexanoic acid t
rans-2-hexenyl, heptyl hexanoate, linalyl hexanoate, citronellyl hexanoate, geranyl hexanoate, citronellyl hexanoate, benzyl hexanoate, methyl isohexanoate, methyl 2-hexenoate, t
trans-2-ethyl hexenoate, methyl 3-hexenoate, ethyl 3-hexenoate, methyl 3-hydroxyhexanoate, ethyl 3-hydroxyhexanoate, ethyl 2-ethylhexanoate, mersat (3,5,5-trimethyl Ethyl hexanoate), beryflo (ethyl 6-acetoxyhexanoate), methyl heptanoate, ethyl heptanoate, propyl heptanoate, allyl heptanoate, octyl heptanoate, methyl octanoate, methyl octanoate,
Amyl octoate, butyl octoate, propyl octoate, allyl octoate, isoamyl octoate, hexyl octoate, heptyl octoate, octyl octoate, linalyl octoate, benzyl octoate, phenylethyl octoate, p-cresyl octoate , 2-
Ethyl octenoate, methyl nonanoate, ethyl nonanoate,
Phenylethyl nonanoate, boubaltate (methyl 2-nonenoate), methyl 3-nonenoate, methyl decanoate, ethyl decanoate, isopropyl decanoate, butyl decanoate, isoamyl decanoate, ethyl 2-decenoate, 2,4
-Ethyl decadienate, propyl 2,4-decadienoate, methyl undecylenate, butyl undecylenate, isoamyl undecylenate, methyl dodecanoate, ethyl dodecanoate, butyl dodecanoate, isoamyl dodecanoate,
Ethyl myristate, methyl myristate, isopropyl myristate, ethyl palmitate, ethyl stearate, butyl stearate, methyl oleate, ethyl oleate, methyl benzoate, ethyl benzoate, propyl benzoate, isopropyl benzoate, benzoic acid Allyl,
Isobutyl benzoate, isoamyl benzoate, prenyl benzoate, hexyl benzoate, cis-3-hexenyl benzoate, linalyl benzoate, geranyl benzoate, benzyl benzoate, phenylethyl benzoate, cinnamyl benzoate, methyl anisate, anise Ethyl acid, methyl o-methoxybenzoate, ethyl o-methoxybenzoate, ethyl tiglate, hexyl tiglate, cis-tiglate
3-hexenyl, citronellyl tiglate, geranyl tiglate, benzyl tiglate, phenylethyl tiglate, cinnamyl tiglate, methyl angelica, butyl angelica, isobutyl angelica, isoamyl angelica, prenyl angelica, cis-3 angelica -Hexenyl, 3-methylpentyl angelic acid, phenylethyl angelica, ethyl acrylate, phenylethyl methacrylate, ethyl crotonic acid,
Isobutyl crotonate, cyclohexyl crotonate, flutinato (4-methyl-pentan-2-ol-crotonate), piroprunate (2-cyclopentyl-cyclopentyl crotonate), datilato (1-cyclohexylethyl crotonate), ethyl levulinate, levulinic acid Butyl, isoamyl levulinate, methyl lactate, ethyl lactate, amyl lactate, isobutyl lactate, cis-3-lactic acid
Hexenyl, butyl butyryl lactate, ethyl pyruvate,
Methyl gellanate, ethyl gellanate, methyl cyclogelanoate, ethyl cyclogelate, furtate (ethyltricyclo [5.2.1.0 ^2,6 ] decane-2-ylcarboxylate), divescone (ethyl-2-ethyl- 6,
6-dimethyl-2-cyclohexene-1-carboxylate & ethyl-2,3,6,6-tetramethyl-2
-Cyclohexene carboxylate), ethyl safranate (ethyl dehydrocyclogeranate), allyl cyclohexylpropionate, cyclogalvanate (allylcyclohexyloxyacetate), calixol (ethyl-2-methyl-6-pentyl-4-oxocyclohexyl-) 2-enecarboxylate), taclisate (methyl-1-methyl-3-cyclohexenecarboxylate), floramate (ethyl-2-tert-butylcyclohexylcarbonate), jasmacyclate (methylcyclooctyl carbonate), mahagonate (1
-Methyl-4-isopropyl-2-carbomethoxybicyclo [2,2,2] -oct-5-ene), phenylethyl pivalate, methyl jasmonate, hedion (methyl dihydrojasmonate), veramos (methyl-3, 6
-Dimethyl-β-resorcylate), methyl furancarboxylate, ethyl furancarboxylate, propylfuranacrylate, methylheptincarboxylate, ethylheptincarboxylate, isoamylheptincarboxylate, methyloctynecarboxylate, ethyloctynecarboxylate , Methyl decinecarboxylate, glycomer (3- (bicyclo [2.
2.1] Methyl ester of hept-5-en-2-yl) -3 methyloxiranecarboxyacid), methyl phenylglycidate, ethyl phenylglycidate, aldehyde C-16 (3-methyl-3-phenylglycol) Ethyl succinate), aldehyde C-20 (ethyl p-methyl-β-phenylglycidate), methyl methyl p-tolylglycidate, ethyl citronellyl oxalate, diethyl succinate, dimethyl succinate, diethyl malonate, diethyl tartrate , Diethyl adipate, diethyl sebacate, triethyl citrate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, methyl phenylacetate, ethyl phenylacetate, isopropylacetate, phenylacetate, butylacetate, propylacetate, phenylacetate, phenylacetate, phenylacetate Acetic acid Amyl, phenyl hexyl acetate,
Cis-3-hexenyl phenylacetate, citronellyl phenylacetate, rosinyl phenylacetate, geranyl phenylacetate, menthyl phenylacetate, benzyl phenylacetate,
Phenylethyl phenylacetate, p-cresyl phenylacetate, eugenyl phenylacetate, isoeugenyl phenylacetate, methyl cinnamate, ethyl cinnamate, propyl cinnamate, isopropyl cinnamate, allyl cinnamate, isobutyl cinnamate, cinnamate Isoamyl cinnamate, linalyl cinnamate, benzyl cinnamate, cinnamyl cinnamate, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, butyl salicylate, isobutyl salicylate, amyl salicylate, isoamyl salicylate, hexyl salicylate, cis-3 salicylate -Hexenyl, cyclohexyl salicylate, phenyl salicylate, benzyl salicylate, phenylethyl salicylate, cyclopidene (methylcyclopentylidene acetate), avaline (methyl aviate), Herco Down (methyl dihydro abietates), salicylic p- cresyl, phenoxyacetic acid allyl, phenylpropionic acid ethyl, ethylene brassylate, triacetin and the like.

<Nitrogen-containing compounds> Methyl anthranilate, ethyl anthranilate, butyl anthranilate, cis-3-hexenyl anthranilate, phenylethyl anthranilate, cinnamyl anthranilate, methyl N-methylanthranilate, aurantiol (hydroxy Citronellal-methylanthranilate (Schiff base), Mevantral (methyl propyl acetaldehyde-methyl anthranilate Schiff base), Jasmentin (α-amylcinnamaldehyde-methyl anthranilate Schiff base), Ligantral (methyl- (3 , 5-Dimethyl-3-cyclohexene-
1-yl) methylene anthranilate), indole,
Skatole, clonal (dodecanenitrile), tangenil (2-tridecennitrile), citralva (geranylnitrile), citronellylnitrile, lemonyl (3,7-dimethyl-2,6-nonadienitrile), cuminilnitrile, cinnamalva (cinnamal) Milnitrile), trimethylamine, pyridine, 3-ethylpyridine, 2-acetylpyridine, 3-acetylpyridine, 2
-Isobutylpyridine, 3-isobutylpyridine, 2-
n-pentylpyridine, 5-ethyl-2-methylpyridine, methyl nicotinate, 4- (1,4,8-trimethyl-3,7-nonadienyl) pyridine, quinoline, isoquinoline, p-methylquinoline, tetrahydro-p- Methylquinoline, 6-isopropylquinoline, isobutylquinoline, 2-isobutylquinoline, 6-sec-butylquinoline, 8-sec-butylquinoline, 6 (p) -t
tert-butylquinoline, 2-tert-butylquinoline, pyrazine, 2-methylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5-trimethylpyrazine, 2-ethylpyrazine, 2-ethyl −
3-methylpyrazine, 2-ethyl-5-methylpyrazine, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2,3-diethylpyrazine, 2,3-diethyl-5
-Methylpyrazine, tetramethylpyrazine, 2-methyl-5-vinylpyrazine, methoxypyrazine, 2-methoxy-3-methylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3-isopropylpyrazine,
-Isobutyl-3-methoxypyrazine, 2-acetylpyrazine, 2-acetyl-3-ethylpyrazine, methylthiomethylpyrazine, corylonepyrazine (5-methyl-
6,7-dihydrocyclopentapyrazine), 5-methylquinoxaline, cyclohexapyrazine (5,6,7,8
-Tetrahydroquinoxaline), 1-methylpyrrole,
2-acetylpyrrole, pyrrolidine, indolene (Schiff base of indole-hydroxycitronellal),
2-methylbenzoxazole, decahydrocyclododecaoxazole, 5-methyl-3-heptanone oxime, bucoxime (bicyclo [3.2.1] octane-8
-One, 1,5-dimethyl-, oxime), gulamide (N-methyl-N-phenyl-2-methylbutylamide), musk xylol, musk ketone, musk ambrette, musk tibeten, mosken, 2,6-lutidine, piperidine , 2- (1,4,8-trimethyl-3,
7-nonadienyl) pyridine, 2- (2-pinene-10)
-Ylmethyl) pyridine, 4- (2-pinene-10-isomethyl) pyridine, piperine, capsaicin, vanillyl nonanoate, quinine, perillartin (L-perylaldehyde α-anti-aldoxime), 2-isopropyl-4-methylthiazole , 2-isobutylthiazole and the like.

<Sulfur-containing compounds> Thiazole, 4-methylthiazole, 4,5-dimethylthiazole, trimethylthiazole, 2-methyl-5-methoxythiazole,
2-isopropyl-4-methylthiazole, 4-methyl-5-vinylthiazole, 2-isobutylthiazole,
Sulfurol (4-methyl-5-thiazoleethanol), sulfuryl acetate (4-methyl-5-thiazoleethanol acetate), 2-acetylthiazole, 5-acetyl-2,4-dimethylthiazole, benzothiazole, propylmercaptan, Hydrogen sulfide, isopropyl mercaptan, 2-methyl-3-butanethiol, allyl mercaptan, isoamyl mercaptan, thiogeraniol, limonene thiol, sulfox (8-mercaptomentone) phenyl mercaptan, o
-Thiocresol, 2-ethylthiophenol, 2-naphthylmercaptan, furfurylmercaptan, 2-methyl-3-furanthiol, dimethylsulfide, dimethyldisulfide, dimethyltrisulfide, methylpropyldisulfide, methylpropyltrisulfide,
Propyl disulfide, dipropyl trisulfide, diallyl sulfide, diallyl disulfide, dibutyl sulfide, methionol (3- (methylthio) -1-propanol), 3-methylthio-1-hexanol, methional (3- (methylthio) propionaldehyde), mint Sulfide, dithiospirofuran, furfurylmethyl sulfide, 2-methyl-5-methylthiofuran, methylfurfuryl disulfide, furfuryl disulfide, thiophene, tetrahydrothiophene, 3-
Thiophene carboxaldehyde, 5-methyl-2-thiophene carboxaldehyde, tetrahydrothiophen-3-one, trithioacetone, thioglycolic acid,
Methyl methylthioacetate, ethyl methylthioacetate, 2-mercaptopropionic acid, pineapple mercaptan (methylmercaptomethylpropionate), ethyl 3-methylthiopropionate, ethyl thioacetate, furfuryl thioacetate, furfuryl thiopropionate, methyl thiobutyrate, methyl Methanethiosulfonate, allyl isothiocyanate, benzyl isothiocyanate, thiazine (2,4,6-trimethyl-4,5-dihydro-1,
3,5-dithiazone), oxane (2-methyl-4-propyl-1,3-oxathiane) and the like.

<Natural fragrance> Asafetida resinoid,
Ajowan oil, Star anise oil, Avies oil, Amyris oil, Ambrette seed oil, Ambergris tincture, Ylang ylang oil, Ylang ylang absolute, Iris resinoid, Iris absolute, Iris oil, Winter green oil, Elemi oleoresin, Elemiresinoid absolute , Eremi tincture, oak moss concrete, oak moss absolute, oak moss resin, oak moss resinoid, okotia oil, osmanthus absolute,
Osmanthus Concrete, Opopanax Resinoid, Opopanax Absolute, Opopanax Oil, Olibanam Resinoid, Olibanam Absolute, Olibanam Oil, Allspice Oil, Oregano Oil, Oregano Oleoresin, Orange Oil, Orange Flower Absolute, Orange Flower Concrete, Kananga oil, Garjun balsam, Garjun balsam oil, Cascalli bark oil, Castorium absolute, Cassie absolute, Cassie flower oil, Cassia oil, Gardenia absolute, Carnation absolute, Cabrubba oil, Camomil oil, Cardamom oil, Galvanum oil, Galvanum resin, galvanum resinoid, caraway Dooiru, carrot seed oil, Guadalmedina Yak wood oil, Guadalmedina Yak resin, Guadalmedina Yak concrete, camphor oil, Kubebaoiru,
Cumin oil, cumin absolute, cumin oleoresin, clary sage oil, grapefruit oil,
Clove oil, Costas oil, Copaiba balsam,
Copaiba Balsam Oil, Copaiba Balsam Resin, Coriander Oil, Sassafras Oil, Sandalwood Oil, Gene Absolute, Perilla Oil, Citronella Oil, Jasmine Absolute, Jasmine Concrete, Juniper Berry Oil, Civet Absolute, Civet Tincture, John Kill Absolute, Agarwood Oil, Ginger oil, cinnamon oil, cinnamon bark oil, cinnamon leaf oil, cedar oil, styrax oil, styrax resinoid, spearmint oil, savory oil, sage oil, cedar oil, cedar leaf oil, geranium oil, celery seed oil, thyme oil,
Tugget oil, tarragon oil, tuberose absolute, dill oil, tea tree oil, trimos absolute, tolubal sam, nutmeg oil, narcissus absolute, neroli oil, violet leaf absolute, pine oil, basil oil, parsley relief oil, parsley seed oil, Parsley herb oil, patchouli oil, peppermint oil, vanilla absolute, honey sackle absolute, palmarosa oil, valerian oil, bitter orange oil, hyssop oil, hiba oil, hyacinth absolute, fennel oil, figabsolut, petitgrain oil, butch oil, vetiver oil, penny Royal oil, pepper oil, peppermint oil, bergamo Oil, peruvian balsam, benzoin tincture, benzoin resinoid, boad rose oil, boshaw oil, hop oil, hop concrete, hop absolute, marjoram oil, mandarin oil, mandarin oil, mimosa concrete, mimosa absolute, mimosa oil, milresinoid, mill Absolute, mill oil, musk absolute, mustinki, eucalyptus oil, yuzu oil, mugwort oil, lime oil, labdanum oil,
Rabdanum resinoid, lavender oil, lavender absolute, lavandin oil, lavandin absolute, linaloe oil, lemon oil, lemongrass oil, rose oil, rose absolute, rose concrete, rosemary oil, lobage oil, laurel oil, laurel leaf oil, wormwood oil , Musk, spirit cat incense, dragon incense, sea raccoon incense, musk and cibata, and the like.

<Prepared perfume> Further, there are the following perfumed bases which are prepared perfumes obtained by combining perfume components. Citrus type bases such as lemon, lime, orange, sweet orange, mandarin, bergamot, etc., fresh type bases such as petitgren, neroli, lemongrass, agmarian, etc., apple, peach, strawberry Tone, coconut tone, pineapple tone, raspberry tone, watermelon tone, etc. Floral type base such as violet, Iran, floral bouquet, etc., spicy type such as cinnamon bark, cinnamon leaf, clove, pimentoberry, nutmeg, pepper, cardamom, coriander, cumin, etc. Woody type bases such as leather, cedarwood, vetiver, sandalwood, guaiacwood, woody amber, woody iris, leather types such as smoky, quinoline, vanilla, tonka, honey, pure Sweet type base such as balsam, other Aldehidick type base, amber type base, animal type base, anise type base, aromatic herbal type base, agar type base, aqua type base,
Camphor Cineol Type Base, Green Type Base, Seed Type Base, Herb Type Base, Pine Type Base, Patchouli Type Base, Balsamic Type Base, Mint Type Base, Musk Type Base, Moss Type Base, Lavender Type Base, Linalool Type Base, Resin Type base and the like can be mentioned.

Further, as a fragrance solvent, ethanol,
Acetin (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), ethylene glycol dibutyrate, hexylene glycol, dibutyl sebacate, deltyl extra (isopropyl myristate), methyl carbitol (diethylene glycol monomethyl ether), Carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate, propylene glycol, diethyl phthalate, tripropylene glycol, avoline (dimethyl phthalate), deltyl prime (isopropyl palmitate), dipropylene glycol D
PG-FC (dipropylene glycol), farnesene, dioctyl adipate, tributyrin (glyceryl tributanoate), hydrolite-5 (1,2-pentanediol), propylene glycol diacetate,
Cetyl acetate (hexadecyl acetate), ethyl aviate, avaline (methyl aviate), citroflex A-2 (acetyl triethyl citrate), citroflex A-4 (tributyl acetyl citrate), Citroflex No. 2 (triethyl citrate), Citroflex No. 2 4 (tributyl citrate), Durafix (methyl dihydroabietate), MITD (isotridecyl myristate),
Polylimonene (limonene polymer), propylene glycol, 1,3-butylene glycol and the like can be mentioned.

The amount of these solvents used is 0.1 to 99% by mass in the fragrance composition, but preferably 1 to 5% by mass.
0 mass% is blended.

Examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E and its derivatives, catechin compounds, flavonoid compounds, polyphenol compounds, and the like. Although it is blended, preferably, it is blended in an amount of 0.001 to 5% by mass. Among these,
A preferred stabilizer is dibutylhydroxytoluene.

Here, in the present invention, the above-mentioned perfume composition is a mixture comprising the above-mentioned perfume component, solvent, perfume stabilizer and the like. It is preferable to blend such a fragrance composition into the tablet detergent composition of the present invention, and the blending amount is not particularly limited. , 0.01 to 5% by mass, particularly preferably 0.01 to 1% by mass.

In the tablet detergent composition of the present invention, the mixing ratio of (A) the molten particles and (B) the unmelted particles is as follows:
Although not particularly limited, (A) :( B) (mass ratio) = 95: 5-85 or more and less than 15 and particularly 91: 9-
It is more preferable to mix them so as to be 85 or more and less than 15. (A) If the mixing ratio of the molten particles is too low, the strength may not be improved by the fusion treatment, and if the mixing ratio is too high, the disintegration may decrease. In addition, the above ratio is applied to the particles after the treatment when a later-described coating treatment or the like is performed.

The tablet detergent composition of the present invention is obtained by mixing the above-mentioned optional components with the mixed particles of the above-mentioned (A) molten particles and the above-mentioned (B) unmelted particles, and compression-molding the mixture into a tablet form. After that, the compression-molded product is housed in an airtight container and subjected to a fusion treatment in the airtight container.

Here, the method for preparing the (A) molten particles and (B) non-molten particles is not particularly limited. Granulation method described in (Powder detergent) can be employed. In the case of the present invention, the (A) molten particles desirably have a high bulk density.
It is suitable to use high bulk density detergent particles having a bulk density of 0.6 g / mL or more, preferably 0.6 to 0.9 g / mL, as measured by the method of 3362.

In the present invention, the mixed particles of (A) the molten particles and (B) the unmelted particles have a particle size of 200 to 2000 μm, especially 300 to 150 μm before compression molding.
It is more preferable that the particles are sized so that the particles having a size of 0 μm are selected, because the strength can be further improved while maintaining sufficient disintegration at a low temperature. Further, the (A) molten particles may be subjected to a treatment such as coating (coating treatment) or coloring the particle surface with an appropriate component as long as the fusion treatment of the present invention is not hindered.

The method of compression-molding the mixed particles is not particularly limited, and can be carried out by a known tableting machine and tableting conditions employed in tablet detergents. The tableting pressure is not particularly limited, but may be 5
A pressure of 10 to 10 kN, particularly 6 to 9 kN, is preferable. If the tableting pressure is too high, sufficient low-temperature disintegration may not be obtained, and if it is too low, the desired strength may not be easily obtained. For the same reason, it is preferable to compress the compression molded product immediately after molding so that the tablet strength becomes 30 to 70 N, particularly 40 to 60 N, according to the measuring method described in Examples described later.

The temperature at which the mixed particles are compression molded is
Although not particularly limited, 15 to 35 ° C is preferable. If the temperature at the time of compression molding is too low, it may be necessary to perform the compression molding while cooling, and if it is too high, the good disintegration desired by the present invention may not be obtained.

Here, the size of the compression molded product of the present invention is:
Although not particularly limited, usually a diameter of 20 to 50 m
m, especially about 25 to 45 mm, and a thickness of 5 to 30 mm, especially about 10 to 20 mm. If it is too large, it may be difficult to obtain the desired disintegration and strength of the present invention, and if it is too small, it may be necessary to use a large number of tablet detergent compositions in order to use a single amount of the detergent. is not.

The tablet detergent of the present invention is obtained by heating the above-mentioned compression molded product in an airtight container at a temperature not lower than the melting point of the above-mentioned surfactant and the like, at 65 ° C
In the following, heating and fusion treatments are performed. Here, in the case of the present invention, it is important to perform the fusion treatment of the compression-molded product in an airtight container, and the hermetic container has an airtightness such that moisture of the compression-molded product does not fly due to the fusion process described below. It is important to have

Examples of the airtight container include a non-stretched polypropylene (CPP) film and a stretched polypropylene (O
PP) film, polyethylene terephthalate (PE)
T) film, stretched nylon (NY) film, polyethylene (PE) single-layer film such as film, OPP /
CPP, NY / PE, PET / CPP, PET / PE,
Two-layer film such as OPP / PE, PET / aluminum foil (AL) / PE, PET / AL / CPP, NY / aluminum-deposited PE (AL-PE) / PE, PET /
A packaging container obtained by using a three-layer film such as NY / CPP or PET / NY / PE as a packaging material and pillow-packing one or more of the above-mentioned compression molded products can be given.

The method of sealing the packaging material for forming the packaging container is not particularly limited as long as the compression molded product has an airtightness such that moisture does not fly out by the fusing treatment described later. A hot sealing method in which the adhesive is applied to the back surface of the film, and a cold sealing method in which the adhesive is pressed and sealed without applying heat is preferable, and the hot sealing method is particularly preferable.

The heating temperature at the time of fusing the compression molded product is from the melting point of the above-mentioned surfactant to 65 ° C., preferably from the melting point of the above-mentioned surfactant to 60 ° C. If the temperature during the fusion treatment is too high, the strength of the tablet detergent composition is improved, but the disintegration at low temperatures is impaired. In the present invention, the surfactant (A) having a low melting point of the molten particles (A)
When blending more than one kind, the fusion treatment temperature is set to be equal to or higher than the melting point of a surfactant having the lowest melting point.

Examples of the fusion treatment of the present invention include ordinary heating methods, high-frequency heating, microwave treatment, and ultrasonic treatment. These treatment conditions are as follows. For example, the high-frequency heating treatment conditions are preferably about 2 to 20 MHz, and the microwave treatment is preferably about 1000 MHz to 1000 GHz. In each processing method, it is desirable to confirm the temperature of the compression molded product by measuring the temperature at the center of the molded product.

Here, specific means for melting the (A) molten particles in the compression-molded mixed particles include, for example, a thermostatic chamber, a warehouse, a railway, an automobile, and the like.
By storing and leaving it in a transportation means such as a ship, the above-mentioned compression molded product has a melting point of not less than the melting point of the above-mentioned surfactant and the like.
After heating to a temperature of 5 ° C. or less, it can be realized by cooling to a temperature below the melting point of the above-mentioned surfactant or the like before use. Further, for example, after irradiating microwaves such as a microwave oven so that the compression molded product has a temperature of not less than the melting point of the surfactant and the like and not more than 65 ° C., the melting point of the surfactant and the like is not used until the time of use. It can be realized by cooling to the following temperature.

Here, the fusing time is not particularly limited. However, regardless of the method used, at least the whole of the compression-molded product has a desired temperature, and a uniform fusing is performed. It is desirable to heat until
In the case of normal heat treatment, 6 to 72 hours, particularly 12 to 48 hours
The time is preferably about 10 to 60 in the case of high-frequency heating.
Seconds, especially about 20 to 25 seconds;
The ultrasonic treatment is preferably performed for about 60 to 60 seconds, particularly about 10 to 15 seconds, and about 10 to 120 seconds, particularly about 40 to 50 seconds.

The time of the high frequency heating, the heating by microwaves and the fusing treatment time by ultrasonic treatment are as follows.
In the case where a plurality of pieces are simultaneously subjected to the fusion processing, the fusion processing time corresponding to the time obtained by multiplying the fusion processing time per one piece by the number is preferable. .

The tablet detergent composition of the present invention is subjected to a fusion treatment in an airtight container as described above to prevent the water content of the compression-molded product from decreasing and to provide sufficient disintegration at low temperatures. It is preferable that the water content of the tablet detergent composition after the fusion treatment is 7% by mass or more, preferably 7 to 13% by mass, more preferably 8 to 12% by mass. Further, it is preferable that the reduction rate of the water content due to the fusion treatment is 5% or less, particularly 3% or less of the water content in the tablet detergent composition.

The method of using the tablet detergent composition of the present invention is not particularly limited. Usually, a plurality of the tablet detergent compositions are stored in a box such as a coated ball or a cardboard box, and are transported and sold through a normal distribution channel. Thus, it can be used as a tablet-type detergent for clothing in accordance with a conventional method.

[0064]

According to the present invention, a tablet detergent composition having improved strength while maintaining sufficient disintegration at low temperatures can be obtained. Therefore, the tablet detergent composition of the present invention has excellent strength that can withstand shocks during transportation, for example, and excellent disintegration during washing even when using tap water at normal temperature. Useful as a tablet detergent having

[0065]

EXAMPLES Next, the present invention will be described more specifically with reference to examples and comparative examples, but the present invention is not limited to these examples.

Examples 1 to 40 and Comparative Examples 1 to 10 (i) Preparation of Detergent Granules (Molten Particles) Among the detergent compositions shown in Table 1, a nonionic surfactant and a part of zeolite (granule A type zeolite) Fine powder for coating A type zeolite), disintegrant (non-molten particles), sodium percarbonate (non-molten particles), granulated bleach activator (molten particles below), enzyme (non-molten particles), fragrance, dye A detergent slurry having a solid content of 40% by mass was prepared using each of the removed components, and this was spray-dried at 270 ° C. using a countercurrent drying tower to obtain a dry powder having a water content of 3% by mass. In addition, zeolite for detergent slurry is fine powder type A zeolite (Silton B,
Mizusawa Chemical) was used. This was put into a biaxial continuous kneader (KRC Kneader # 2 type, manufactured by Kurimoto Iron Works), kept at 40 ° C., together with a nonionic surfactant shown in Table 1 and water for adjusting water content to obtain a kneaded product.

Thereafter, the kneaded product is extruded by an extruder for 1-2 times.
It was chopped into dice having a square shape of cm and pulverized together with 2% by mass of granule type A zeolite (average particle size: 200 μm: manufactured by Cosmo Corporation). Crusher (Okada Seiko, Speed Mill ND-10)
And a screen with an opening diameter of 2 mm at a rotation speed of 1500 rpm. The obtained granules are coated with 1% by mass of fine powder type A zeolite (Silton B, Mizusawa Chemical), sprayed with a dye, and if necessary, the particle size is adjusted using a sieve before tableting to form a detergent granule (melt). Particles). In addition, each tablet adjusted the fine powder of 400 micrometers or less to 5 mass% before tableting.

(Ii) Granulated bleach activator (molten particles)
Preparation of bleach activator 4-decanoyloxybenzoic acid and polyethylene glycol (PEG) # 6000 (melting point 56
° C.) and were mixed so that a 70/25/5 by weight ratio C ₁₄ alpha olefin sulfonate sodium powder products were charged into a Hosokawa Micron Extrude-O Mix EM-6 type, by kneading extruder A noodle-shaped extruded product having a diameter of 0.8 mmφ was obtained. This extruded product (product temperature: 60 ° C.) is introduced from the same direction as the kneaded extruded granulated product is introduced by Fitzmill DKA-3 manufactured by Hosokawa Micron Corporation, and fine powder type A zeolite (Silton B) is used as an auxiliary agent. , Mizusawa Chemical Co., Ltd.) was similarly supplied and pulverized to obtain bleach activator granulated particles (melted particles) having an average particle size of 700 μm.

(Iii) Preparation of tablet The detergent granules (melted particles) prepared beforehand and the enzyme (non-melted particles) were mixed and sprayed with a fragrance. ) 1% by mass and disintegrant granules (non-molten particles) to 9% by mass, respectively. If necessary, sodium percarbonate (non-molten particles) and bleach activator granules (molten particles) are further added. The mixture was mixed well to obtain a mixture for tableting (mixed particles). Tableting mixture 40
g was placed in a tableting die having a diameter of 45 mm (flat shape: round, side shape: flat edge), and a single-shot tableting machine (N60E:
(Okada Seiko) at the temperature of the tableting mixture shown in Table 2 and compression molding was performed by adjusting the tableting pressure so that the tablet strength immediately after molding had the value shown in Table 2 by the following method. The strength of the obtained tablet was confirmed according to the following method for measuring the strength of the tablet.

Each tablet was treated according to the following treatment method 1 or treatment method 2 as shown in Tables 2 to 6, and the strength improving effect and disintegration time of each tablet after treatment were evaluated by the following methods. The results are also shown in Tables 2 to 6. The water content of each tablet after the fusion treatment was not different from that before the treatment.

(Iv) Tablet fusion treatment method <Treatment method 1> Each tablet prepared by the above method is a two-layer film (thickness) of an unstretched polypropylene (CPP) film and an oriented polypropylene (OPP) film. (CPP / OPP = 20 μm / 25 μm) as a wrapping material, followed by pillow packaging, followed by standing in a constant temperature chamber maintained at each temperature according to the heating temperature and heating time shown in Tables 2 to 6 for each time.

<Treatment method 2> Tablets prepared by the above method were pillow-packed by a conventional method using a two-layer film of CPP / OPP (thickness: CPP / OPP = 20 μm / 25 μm) as a packaging material, and then tablets were prepared. It was exposed to microwaves (frequency 2450 MHz, output 600 W) such that the temperature at the center became the heating temperature shown in Tables 2 to 6. In addition,
The temperature at the center of the tablet during the treatment was confirmed according to the following method for measuring the temperature at the center of the tablet.

(V) Method of Measuring Temperature of Tablet Central Part A digital thermometer (DIGITAL)
THERMOMETER MODEL2455: YO
KOGAWA) and measured.

(Vi) Method of Measuring Tablet Strength The tablet prepared by the above method was used as a tablet strength meter (TD-
50: Okada Seiko), the pressure arm was moved at a speed of 20 mm per minute, a force was applied in the diameter direction of the tablet, and the maximum stress until the tablet collapsed was defined as the tablet strength.

(Vii) Method of measuring disintegration time About 800 mL of water at 5 ° C. was placed in a 1-liter glass beaker, and a tablet placed on a small net having an opening of 1 cm was gently placed in water, and a tablet placed 2 to 3 cm from the surface of the water was placed. Keep in depth position. The time required for the tablet to be immersed in water, disintegrated and completely dropped from the net was regarded as disintegration time, and the disintegration within 30 seconds was judged to be good.

(Viii) Method of evaluating strength improving effect The tablet prepared by the above method was immediately dropped on a concrete floor surface from a height of 20 cm with the bottom face down immediately. The drop strength was evaluated by the number of times. The drop strength before and after the fusion process (iv) was evaluated, and the effect of the fusion process was determined by a strength improvement effect index calculated from the following formula. 1.
When 5 or more, the strength improvement effect was judged to be good. Strength improvement effect index = (fall strength after treatment) / (fall strength before treatment)

[0077] <Materials _{Used> LAS-K: C 10 ~} 13 linear potassium alkylbenzene sulfonate LAS-Na: C _{10 ~ 13} linear alkylbenzene sulfonate sodium AOS-K: Potassium C _{14 ~ 18} alpha olefin sulfonate α- _{SF-Na: C 14 ~ 16} α- sulfofatty acid methyl ester sodium AS-Na: C _{12 ~ 14} sodium alkyl sulfate

Nonion A: 25 mol of ethylene oxide adduct of Diadol 13 (Mitsubishi Chemical), melting point 45 ° C. Nonion B: 15 mol of ethylene oxide adduct of Diadol 13 (Mitsubishi Chemical), melting point 41 ° C. Nonion C: Diadol 13 (Mitsubishi Chemical) ethylene oxide 15 mol propylene oxide 3 mol block adduct, melting point 26 ° C. Nonion D: lauryl alcohol ethylene oxide 10 mol adduct, melting point 20 ° C. PEG1000: polyethylene glycol # 1000, melting point 35 ° C.

[0079] Soap: C _{12 ~ 18} fatty acid sodium salt Zeolite: 4A type zeolite polymeric builder: sodium salts of acrylic acid / maleic acid copolymer, trade name Sokalan CP7 (BASF) Potassium carbonate: Reagent grade sodium carbonate: Reagent grade silicate Sodium: JIS No. 1 sodium silicate Sodium sulfite: reagent grade Fluorescent whitening agent A: Tinopearl CBS-X (Ciba Specialty Chemicals) Fluorescent whitening agent B: Tinopearl AMS-GX (Ciba Specialty Chemicals)

Enzyme A: cannase 12T (Novo Nordisk) Enzyme B: Lipolase Ultra 50T (Novo Nordisk) Enzyme C: Evalase 8T (Novo Nordisk) Sodium percarbonate: SPC-D (Mitsubishi Gas Chemical) Bleaching activator Granulated product: (ii) Bleached activator granulated product shown in Preparation of granulated product Dye: Ultramarine (Dainichi Seika Kogyo) Perfume A: Perfume composition A shown in Tables 11 to 18 Perfume B: Fragrance composition B shown in Tables 11 to 18 Fragrance C: Fragrance composition C shown in Tables 11 to 18 Fragrance D: Fragrance composition D shown in Tables 11 to 18 Disintegrant: ARBOCEL TF30HG (Rettenmeier)

[0081]

[Table 1]

[0082]

[Table 2]

[0083]

[Table 3]

[0084]

[Table 4]

[0085]

[Table 5]

[0086]

[Table 6]

[Examples 41 to 52] (i) Preparation of detergent granules Detergent type A shown in Table 1 in the same manner as in Examples 1 to 40 described above.
And E were prepared as a tableting mixture (mixed particles).

(Ii) Preparation of tablet In Examples 1 to 40 described above, the mass of the tableting mixture was determined according to Table 8.
And tablets were prepared in the same manner as in Examples 1 to 40 except that the type of tableting mold was changed to that shown in Table 7 according to Table 8.

Each tablet was treated by the above-mentioned treatment method 1 under the heating conditions shown in Table 8, and the strength improvement effect and disintegration time of each tablet after treatment were evaluated in the same manner as in Examples 1 to 40 above. The results are shown in Table 8. The water content of each tablet after the fusion treatment was not different from that before the treatment.

[0090]

[Table 7]

[0091]

[Table 8]

[Comparative Example 11] A fusion treatment was carried out in the same manner as in Example 3 except that the tablet of Example 3 was subjected to the processing method 1 without pillow packaging, and a strength improving effect and disintegration were carried out in the same manner as in Example 3. When the time was evaluated, the strength improvement effect index was 0.4 and the disintegration time was 10 seconds. Processing method 1
The water content of the tablet after performing the above was 6% by mass.

[Examples 53 to 59] (i) Preparation of detergent granules A tableting mixture (mixed particles) of detergent type A shown in Table 1 was prepared in the same manner as in Examples 41 to 52 described above. The detergent granules used had the particle size distribution shown in Table 9.

(Ii) Preparation of Tablet In the above Examples 41 to 52, the mass of the tableting mixture was changed as shown in Table 10, and the type of tableting mold was changed to that shown in Table 7 according to Table 10. Except for the above Examples 41 to 41
A tablet was prepared in the same manner as in Example 52.

Each tablet was treated by the above-mentioned treatment method 1 under the heating conditions shown in Table 10, and the strength improvement effect and disintegration time of each treated tablet were evaluated in the same manner as in Examples 41 to 52. The results are shown in Table 10.

[0096]

[Table 9]

[0097]

[Table 10]

[0098]

[Table 11]

[0099]

[Table 12]

[0100]

[Table 13]

[0101]

[Table 14]

[0102]

[Table 15]

[0103]

[Table 16]

[0104]

[Table 17]

[0105]

[Table 18] * 1: [Flower oils and Flora
l CompoundsIn Performance]
Danute Lajaujis Anonis, Al
lured Pub. Co.

Continuation of the front page (72) Inventor Toshiyuki Watanabe 1-3-7 Honjo, Sumida-ku, Tokyo F-term in Lion Corporation (reference) 4H003 AB03 AB15 AB19 AB21 AB27 AB44 AC08 AC23 BA17 CA08 DA01 EA12 EA15 EA16 EA20 EA28 EB09 EB22 EB32 EB36 EC01 EC02 EC03 ED02 EE05 FA26 FA32

Claims (1)

[Claims] (1) It contains (A) a low melting point surfactant and the like,
A compression-molded product of mixed particles containing molten particles, at least a portion of which is melted by heating at a melting point of 65 ° C. to 65 ° C., and (B) non-melted particles that are not melted by heating, is placed in an airtight container. A tablet detergent composition obtained by fusing at a temperature of from the melting point of the above surfactant to 65 ° C.