JP2003113392A - Perfuming/deodorizing composition and perfuming/ deodorizing agent for human body containing the perfuming/deodorizing composition - Google Patents
Perfuming/deodorizing composition and perfuming/ deodorizing agent for human body containing the perfuming/deodorizing compositionInfo
- Publication number
- JP2003113392A JP2003113392A JP2001308879A JP2001308879A JP2003113392A JP 2003113392 A JP2003113392 A JP 2003113392A JP 2001308879 A JP2001308879 A JP 2001308879A JP 2001308879 A JP2001308879 A JP 2001308879A JP 2003113392 A JP2003113392 A JP 2003113392A
- Authority
- JP
- Japan
- Prior art keywords
- acetate
- methyl
- ethyl
- fragrance
- deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 84
- 230000001877 deodorizing effect Effects 0.000 title abstract 9
- 239000002304 perfume Substances 0.000 claims abstract description 19
- 239000003205 fragrance Substances 0.000 claims description 151
- 239000002781 deodorant agent Substances 0.000 claims description 107
- -1 α-fencon Chemical compound 0.000 claims description 63
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 30
- 239000000796 flavoring agent Substances 0.000 claims description 21
- 235000019634 flavors Nutrition 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 18
- 229940022663 acetate Drugs 0.000 claims description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 239000004615 ingredient Substances 0.000 claims description 14
- 239000006210 lotion Substances 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 claims description 10
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims description 10
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims description 8
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims description 8
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 7
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 claims description 6
- WRYLYDPHFGVWKC-UHFFFAOYSA-N 4-terpineol Chemical compound CC(C)C1(O)CCC(C)=CC1 WRYLYDPHFGVWKC-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 6
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 6
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 6
- TVQGDYNRXLTQAP-UHFFFAOYSA-N ethyl heptanoate Chemical compound CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 claims description 6
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 claims description 6
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 claims description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 6
- YRHYCMZPEVDGFQ-UHFFFAOYSA-N methyl decanoate Chemical compound CCCCCCCCCC(=O)OC YRHYCMZPEVDGFQ-UHFFFAOYSA-N 0.000 claims description 6
- NUKZAGXMHTUAFE-UHFFFAOYSA-N methyl hexanoate Chemical compound CCCCCC(=O)OC NUKZAGXMHTUAFE-UHFFFAOYSA-N 0.000 claims description 6
- JGHZJRVDZXSNKQ-UHFFFAOYSA-N methyl octanoate Chemical compound CCCCCCCC(=O)OC JGHZJRVDZXSNKQ-UHFFFAOYSA-N 0.000 claims description 6
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 6
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 claims description 6
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims description 6
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 5
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 5
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 claims description 5
- 235000007173 Abies balsamea Nutrition 0.000 claims description 5
- 239000004857 Balsam Substances 0.000 claims description 5
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 5
- 244000018716 Impatiens biflora Species 0.000 claims description 5
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 claims description 5
- WDAXFOBOLVPGLV-UHFFFAOYSA-N ethyl isobutyrate Chemical compound CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 claims description 5
- YYZUSRORWSJGET-UHFFFAOYSA-N ethyl octanoate Chemical compound CCCCCCCC(=O)OCC YYZUSRORWSJGET-UHFFFAOYSA-N 0.000 claims description 5
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 5
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 claims description 5
- 229940100595 phenylacetaldehyde Drugs 0.000 claims description 5
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 4
- VHVMXWZXFBOANQ-UHFFFAOYSA-N 1-Penten-3-ol Chemical compound CCC(O)C=C VHVMXWZXFBOANQ-UHFFFAOYSA-N 0.000 claims description 4
- PZGMUSDNQDCNAG-UHFFFAOYSA-N 2-Propenyl octanoate Chemical compound CCCCCCCC(=O)OCC=C PZGMUSDNQDCNAG-UHFFFAOYSA-N 0.000 claims description 4
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 claims description 4
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 claims description 4
- INAXVXBDKKUCGI-UHFFFAOYSA-N 4-hydroxy-2,5-dimethylfuran-3-one Chemical compound CC1OC(C)=C(O)C1=O INAXVXBDKKUCGI-UHFFFAOYSA-N 0.000 claims description 4
- OALYTRUKMRCXNH-UHFFFAOYSA-N 5-pentyloxolan-2-one Chemical compound CCCCCC1CCC(=O)O1 OALYTRUKMRCXNH-UHFFFAOYSA-N 0.000 claims description 4
- GHBSPIPJMLAMEP-UHFFFAOYSA-N 6-pentyloxan-2-one Chemical compound CCCCCC1CCCC(=O)O1 GHBSPIPJMLAMEP-UHFFFAOYSA-N 0.000 claims description 4
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims description 4
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 claims description 4
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 claims description 4
- 241000723346 Cinnamomum camphora Species 0.000 claims description 4
- 241000402754 Erythranthe moschata Species 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 4
- XXIKYCPRDXIMQM-UHFFFAOYSA-N Isopentenyl acetate Chemical compound CC(C)=CCOC(C)=O XXIKYCPRDXIMQM-UHFFFAOYSA-N 0.000 claims description 4
- 244000246386 Mentha pulegium Species 0.000 claims description 4
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 4
- OCWLYWIFNDCWRZ-UHFFFAOYSA-N Methyl (S)-2-Methylbutanoate Chemical compound CCC(C)C(=O)OC OCWLYWIFNDCWRZ-UHFFFAOYSA-N 0.000 claims description 4
- UUQHKWMIDYRWHH-UHFFFAOYSA-N Methyl beta-orcinolcarboxylate Chemical compound COC(=O)C1=C(C)C=C(O)C(C)=C1O UUQHKWMIDYRWHH-UHFFFAOYSA-N 0.000 claims description 4
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 claims description 4
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 claims description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 4
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 claims description 4
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 claims description 4
- 229930008380 camphor Natural products 0.000 claims description 4
- 229960000846 camphor Drugs 0.000 claims description 4
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 claims description 4
- MIZGSAALSYARKU-UHFFFAOYSA-N cashmeran Chemical compound CC1(C)C(C)C(C)(C)C2=C1C(=O)CCC2 MIZGSAALSYARKU-UHFFFAOYSA-N 0.000 claims description 4
- 229930003633 citronellal Natural products 0.000 claims description 4
- 235000000983 citronellal Nutrition 0.000 claims description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 4
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 claims description 4
- HCRBXQFHJMCTLF-ZCFIWIBFSA-N ethyl (2r)-2-methylbutanoate Chemical compound CCOC(=O)[C@H](C)CC HCRBXQFHJMCTLF-ZCFIWIBFSA-N 0.000 claims description 4
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims description 4
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 4
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 claims description 4
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 4
- IFYYFLINQYPWGJ-UHFFFAOYSA-N gamma-decalactone Chemical compound CCCCCCC1CCC(=O)O1 IFYYFLINQYPWGJ-UHFFFAOYSA-N 0.000 claims description 4
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 claims description 4
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 claims description 4
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 claims description 4
- 229930002839 ionone Natural products 0.000 claims description 4
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 claims description 4
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 claims description 4
- XAOGXQMKWQFZEM-UHFFFAOYSA-N isoamyl propanoate Chemical compound CCC(=O)OCCC(C)C XAOGXQMKWQFZEM-UHFFFAOYSA-N 0.000 claims description 4
- ZYTMANIQRDEHIO-KXUCPTDWSA-N isopulegol Chemical compound C[C@@H]1CC[C@@H](C(C)=C)[C@H](O)C1 ZYTMANIQRDEHIO-KXUCPTDWSA-N 0.000 claims description 4
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims description 4
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 claims description 4
- GJQIMXVRFNLMTB-UHFFFAOYSA-N nonyl acetate Chemical compound CCCCCCCCCOC(C)=O GJQIMXVRFNLMTB-UHFFFAOYSA-N 0.000 claims description 4
- VSMOENVRRABVKN-UHFFFAOYSA-N oct-1-en-3-ol Chemical compound CCCCCC(O)C=C VSMOENVRRABVKN-UHFFFAOYSA-N 0.000 claims description 4
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 claims description 4
- YLYBTZIQSIBWLI-UHFFFAOYSA-N octyl acetate Chemical compound CCCCCCCCOC(C)=O YLYBTZIQSIBWLI-UHFFFAOYSA-N 0.000 claims description 4
- GGHMUJBZYLPWFD-UHFFFAOYSA-N patchoulialcohol Chemical compound C1CC2(C)C3(O)CCC(C)C2CC1C3(C)C GGHMUJBZYLPWFD-UHFFFAOYSA-N 0.000 claims description 4
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 claims description 4
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 claims description 4
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 claims description 4
- UHUFTBALEZWWIH-UHFFFAOYSA-N tetradecanal Chemical compound CCCCCCCCCCCCCC=O UHUFTBALEZWWIH-UHFFFAOYSA-N 0.000 claims description 4
- QRPLZGZHJABGRS-UHFFFAOYSA-N xi-5-Dodecanolide Chemical compound CCCCCCCC1CCCC(=O)O1 QRPLZGZHJABGRS-UHFFFAOYSA-N 0.000 claims description 4
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 claims description 4
- YASSLXHVJQGNOK-UHFFFAOYSA-N (1-ethynylcyclohexyl) acetate Chemical compound CC(=O)OC1(C#C)CCCCC1 YASSLXHVJQGNOK-UHFFFAOYSA-N 0.000 claims description 3
- HZYHMHHBBBSGHB-UHFFFAOYSA-N (2E,6E)-2,6-Nonadienal Natural products CCC=CCCC=CC=O HZYHMHHBBBSGHB-UHFFFAOYSA-N 0.000 claims description 3
- HZYHMHHBBBSGHB-DYWGDJMRSA-N (2e,6e)-nona-2,6-dienal Chemical compound CC\C=C\CC\C=C\C=O HZYHMHHBBBSGHB-DYWGDJMRSA-N 0.000 claims description 3
- CHLICZRVGGXEOD-UHFFFAOYSA-N 1-Methoxy-4-methylbenzene Chemical compound COC1=CC=C(C)C=C1 CHLICZRVGGXEOD-UHFFFAOYSA-N 0.000 claims description 3
- WAPNOHKVXSQRPX-UHFFFAOYSA-N 1-phenylethanol Chemical compound CC(O)C1=CC=CC=C1 WAPNOHKVXSQRPX-UHFFFAOYSA-N 0.000 claims description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 claims description 3
- BHQBQWOZHYUVTL-UHFFFAOYSA-N 2-(3-methylbutoxy)ethylbenzene Chemical compound CC(C)CCOCCC1=CC=CC=C1 BHQBQWOZHYUVTL-UHFFFAOYSA-N 0.000 claims description 3
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 claims description 3
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 claims description 3
- VNWOJVJCRAHBJJ-UHFFFAOYSA-N 2-pentylcyclopentan-1-one Chemical compound CCCCCC1CCCC1=O VNWOJVJCRAHBJJ-UHFFFAOYSA-N 0.000 claims description 3
- BJLRAKFWOUAROE-UHFFFAOYSA-N 2500-83-6 Chemical compound C12C=CCC2C2CC(OC(=O)C)C1C2 BJLRAKFWOUAROE-UHFFFAOYSA-N 0.000 claims description 3
- VLFBSPUPYFTTNF-UHFFFAOYSA-N 3-(4-methoxyphenyl)-2-methylpropanal Chemical compound COC1=CC=C(CC(C)C=O)C=C1 VLFBSPUPYFTTNF-UHFFFAOYSA-N 0.000 claims description 3
- 125000006041 3-hexenyl group Chemical group 0.000 claims description 3
- YXVSKJDFNJFXAJ-UHFFFAOYSA-N 4-cyclohexyl-2-methylbutan-2-ol Chemical compound CC(C)(O)CCC1=CC=CC=C1 YXVSKJDFNJFXAJ-UHFFFAOYSA-N 0.000 claims description 3
- 244000020998 Acacia farnesiana Species 0.000 claims description 3
- 241001672694 Citrus reticulata Species 0.000 claims description 3
- 235000007129 Cuminum cyminum Nutrition 0.000 claims description 3
- 244000304337 Cuminum cyminum Species 0.000 claims description 3
- XPPALVZZCMPTIV-ARJAWSKDSA-N Jasmine lactone Chemical compound CC\C=C/CC1CCCC(=O)O1 XPPALVZZCMPTIV-ARJAWSKDSA-N 0.000 claims description 3
- XPPALVZZCMPTIV-UHFFFAOYSA-N Jasmine lactone Natural products CCC=CCC1CCCC(=O)O1 XPPALVZZCMPTIV-UHFFFAOYSA-N 0.000 claims description 3
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 3
- 239000005640 Methyl decanoate Substances 0.000 claims description 3
- 239000005641 Methyl octanoate Substances 0.000 claims description 3
- 235000009421 Myristica fragrans Nutrition 0.000 claims description 3
- 241000220317 Rosa Species 0.000 claims description 3
- 240000000513 Santalum album Species 0.000 claims description 3
- 235000008632 Santalum album Nutrition 0.000 claims description 3
- 244000028419 Styrax benzoin Species 0.000 claims description 3
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 3
- 239000005844 Thymol Substances 0.000 claims description 3
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims description 3
- IRAQOCYXUMOFCW-CXTNEJHOSA-N cedrene Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1C(C)=CC2 IRAQOCYXUMOFCW-CXTNEJHOSA-N 0.000 claims description 3
- 229940043350 citral Drugs 0.000 claims description 3
- BLBJUGKATXCWET-UHFFFAOYSA-N cyclaprop Chemical compound C12CC=CC2C2CC(OC(=O)CC)C1C2 BLBJUGKATXCWET-UHFFFAOYSA-N 0.000 claims description 3
- IRAQOCYXUMOFCW-UHFFFAOYSA-N di-epi-alpha-cedrene Natural products C1C23C(C)CCC3C(C)(C)C1C(C)=CC2 IRAQOCYXUMOFCW-UHFFFAOYSA-N 0.000 claims description 3
- FQMZVFJYMPNUCT-UHFFFAOYSA-N geraniol formate Natural products CC(C)=CCCC(C)=CCOC=O FQMZVFJYMPNUCT-UHFFFAOYSA-N 0.000 claims description 3
- 235000001050 hortel pimenta Nutrition 0.000 claims description 3
- 150000002499 ionone derivatives Chemical class 0.000 claims description 3
- HRGPYCVTDOECMG-RHBQXOTJSA-N methyl cedryl ether Chemical compound C1[C@@]23[C@H](C)CC[C@H]2C(C)(C)[C@]1([H])[C@@](OC)(C)CC3 HRGPYCVTDOECMG-RHBQXOTJSA-N 0.000 claims description 3
- RGWPTUUKSDBWRA-UHFFFAOYSA-N methyl cyclooctanecarboxylate Chemical compound COC(=O)C1CCCCCCC1 RGWPTUUKSDBWRA-UHFFFAOYSA-N 0.000 claims description 3
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- WKOLLVMJNQIZCI-UHFFFAOYSA-N vanillic acid Chemical compound COC1=CC(C(O)=O)=CC=C1O WKOLLVMJNQIZCI-UHFFFAOYSA-N 0.000 description 1
- TUUBOHWZSQXCSW-UHFFFAOYSA-N vanillic acid Natural products COC1=CC(O)=CC(C(O)=O)=C1 TUUBOHWZSQXCSW-UHFFFAOYSA-N 0.000 description 1
- BALAUIYKESNHDW-UHFFFAOYSA-N verdyl propionate Chemical compound C1CC2C3C(OC(=O)CC)C=CC3C1C2 BALAUIYKESNHDW-UHFFFAOYSA-N 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 229920003169 water-soluble polymer Chemical class 0.000 description 1
- YJYLJPSYBMNHTG-UHFFFAOYSA-N xi-1-Ethoxy-1-hexyloxyethane Chemical compound CCCCCCOC(C)OCC YJYLJPSYBMNHTG-UHFFFAOYSA-N 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- HZRFVTRTTXBHSE-AYJHFOLZSA-N α-cedrene epoxide Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C1(C)OC1C2 HZRFVTRTTXBHSE-AYJHFOLZSA-N 0.000 description 1
- UZFLPKAIBPNNCA-FPLPWBNLSA-N α-ionone Chemical compound CC(=O)\C=C/C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-FPLPWBNLSA-N 0.000 description 1
- FUQAYSQLAOJBBC-PAPYEOQZSA-N β-caryophyllene alcohol Chemical compound C1C[C@](C2)(C)CCC[C@]2(O)[C@H]2CC(C)(C)[C@@H]21 FUQAYSQLAOJBBC-PAPYEOQZSA-N 0.000 description 1
- IHPKGUQCSIINRJ-UHFFFAOYSA-N β-ocimene Natural products CC(C)=CCC=C(C)C=C IHPKGUQCSIINRJ-UHFFFAOYSA-N 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
- SFEOKXHPFMOVRM-BQYQJAHWSA-N γ-ionone Chemical compound CC(=O)\C=C\C1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-BQYQJAHWSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、(A)トップノー
ト成分、(B)ミドルノート成分、(C)ベースノート
成分及び(D)天然香料の群から選ばれる少なくとも1
種以上の香料を含有する芳香・消臭組成物ならびにその
製法、および該芳香・消臭組成物を含有する人体用芳香
・消臭剤に関する。TECHNICAL FIELD The present invention relates to at least one selected from the group consisting of (A) top note ingredients, (B) middle note ingredients, (C) base note ingredients and (D) natural flavors.
The present invention relates to a fragrance / deodorant composition containing at least one fragrance, a method for producing the same, and a fragrance / deodorant for human body containing the fragrance / deodorant composition.
【0002】[0002]
【従来の技術】人体用芳香・消臭剤には各種の芳香・消
臭組成物が使用されている。これらをを人体用芳香・消
臭剤に賦香する場合、留意すべきことは臭気を如何にマ
スキングするかということにある。人体の消臭には、そ
の臭気が弱い場合には香水、オーデコロン等のいわゆる
ファイン・フレグランスによりマスキングすることが出
来るが、更に強い臭気の場合、芳香・消臭組成物に各種
の抗菌剤、制汗剤などを添加したデオドラントローショ
ン、デオドラントパウダー等の人体用芳香・消臭剤を用
いる必要がある。2. Description of the Related Art Various fragrance / deodorant compositions are used as fragrance / deodorants for human body. When perfuming these to a human body fragrance / deodorant, what should be noted is how to mask the odor. For deodorization of the human body, if the odor is weak, it can be masked by a so-called fine fragrance such as perfume or cologne. It is necessary to use deodorant lotion, deodorant powder, and other fragrances and deodorants for the human body to which sweat agents have been added.
【0003】これらの各種製品に共通に求められる香り
の特性としては、使用直後の爽快感、使用後もしばらく
匂い続ける持続性と残香性が必要である。特に残香性
は、汗臭、腋臭、頭髪臭、体臭等人体の臭気のマスキン
グに有効であり、また芳香・消臭組成物は、これら人体
用芳香・消臭剤に使用されている基剤のマスキングにも
有効である。従って、芳香・消臭組成物は上記人体用芳
香・消臭剤基剤自体のマスキング剤としての機能も要求
される。For the characteristics of the scent commonly required for these various products, it is necessary to have a refreshing feeling immediately after the use, and a persistence and a residual scent to continue to smell for a while even after the use. Especially, the residual aroma is effective for masking human odors such as sweat odor, axillary odor, hair odor, body odor, etc. It is also effective for masking. Therefore, the fragrance / deodorant composition is also required to function as a masking agent for the fragrance / deodorant base for the human body itself.
【0004】ところで香りと揮発度との関係は極めて重
要なものであり、芳香・消臭組成物の基本がこの揮発度
をもとに、一般的に行われており、芳香・消臭組成物の
素材となる天然および合成香料の特性として、それぞれ
の調合素材がどんな揮発度をもっているか認識する必要
がある。By the way, the relationship between fragrance and volatility is extremely important, and the basics of aroma and deodorant compositions are generally based on this volatility. As a characteristic of the natural and synthetic fragrances used as ingredients, it is necessary to recognize what kind of volatility each ingredient has.
【0005】揮発度を観察することは芳香・消臭組成物
を調製する上で有効な手段となる。合成香料は、通常、
揮発度の高いトップノート(A)、中程度のミドルノー
ト(B)および低揮発度のベースノート(C)に分類さ
れる。また、天然香料は広範囲の揮発度を有する化合物
の混合物であることから、ミックスノート(D)に分類
される。Observing the volatility is an effective means for preparing a fragrance / deodorant composition. Synthetic fragrances are usually
It is classified into a high volatile top note (A), a middle middle note (B) and a low volatile base note (C). In addition, since natural flavors are a mixture of compounds having a wide range of volatility, they are classified as mix notes (D).
【0006】一方、香料素材となる天然および合成香料
の揮発度を蒸気圧によって表すこともできるが、一般的
には後に述べる官能的に揮発度をとらえる方法が採用さ
れる。[0006] On the other hand, the volatility of natural and synthetic fragrances used as the fragrance material can be expressed by vapor pressure, but in general, the method of detecting volatility voluntarily as described later is adopted.
【0007】官能を主体とする芳香・消臭組成物の素材
の選択には、通常、上記のトップノート、ミドルノー
ト、ベースノートおよびミックスノートを基本に芳香・
消臭組成物が組み立てられる。The selection of the material of the fragrance / deodorant composition mainly composed of sensuality is usually based on the above-mentioned top note, middle note, base note and mix note.
The deodorant composition is assembled.
【0008】しかしながら、芳香・消臭組成物の素材と
なる天然および合成香料について、トップノート、ミド
ルノート、ベースノート及びミックスノートに分類した
例は、200種程度[香料 No.97, 17-24頁(1970)]であ
り、実務的には満足なものとは云えない。[0008] However, about 200 kinds of examples of natural and synthetic fragrances used as the material of the fragrance / deodorant composition are classified into top notes, middle notes, base notes and mixed notes [Fragrance No. 97, 17-24 Page (1970)], which is not satisfactory in practice.
【0009】さらには、上記のトップノート、ミドルノ
ート、ベースノート及びミックスノートを基本として組
み立てた芳香・消臭組成物を人体用芳香・消臭剤に適用
した例は、本発明者が知る限りにおいては知られていな
い。Further, as far as the present inventor knows, an example in which the aroma / deodorant composition assembled based on the above-mentioned top note, middle note, base note and mix note is applied to an aroma / deodorant for human body Unknown in.
【0010】[0010]
【発明が解決しようとする課題】本発明の目的は、芳香
・消臭組成物の素材として使用されている合成香料を官
能的に(A)トップノート成分、(B)ミドルノート成
分、(C)ベースノート成分に分類したそれぞれと、
(D)天然香料の各群から選ばれる少なくとも1種以上
の天然もしくは合成香料からなる芳香・消臭組成物、お
よびその製法、ならびに該芳香・消臭組成物を含有する
人体用芳香・消臭剤を提供することにある。DISCLOSURE OF THE INVENTION The object of the present invention is to sensually synthesize a synthetic perfume used as a raw material for an aroma and deodorant composition (A) a top note component, (B) a middle note component, and (C). ) Each classified into base note components,
(D) Fragrance / deodorant composition comprising at least one natural or synthetic fragrance selected from each group of natural fragrances, process for producing the same, and fragrance / deodorant for human body containing the fragrance / deodorant composition To provide the agent.
【0011】[0011]
【課題を解決するための手段】本発明者は上記のごとき
課題を解決すべく、芳香・消臭組成物の素材として通常
使用される千数百の合成香料を官能的に(A)トップノ
ート成分、(B)ミドルノート成分、(C)ベースノー
ト成分のそれぞれに分類したそれぞれと、(D)百数十
種類の天然香料の群から選ばれる少なくとも1種以上の
天然もしくは合成香料を適宜に配合することにより、従
来にくらべ、所望する芳香・消臭組成物が容易に調製で
きることを見い出し本発明を完成した。In order to solve the above-mentioned problems, the present inventor organoleptically (A) top notes a thousand or more hundreds of synthetic fragrances which are usually used as materials for aroma and deodorant compositions. Ingredients, (B) middle note ingredients, (C) base note ingredients, respectively, and (D) at least one or more natural or synthetic flavors selected from the group of hundreds of natural flavors. The present invention has been completed by discovering that a desired aroma and deodorant composition can be easily prepared by blending them, as compared with the prior art.
【0012】さらに、本発明の芳香・消臭組成物をデオ
ドラントローション、デオドラントパウダー、デオドラ
ントスプレー、デオドラントスティックなどの人体用芳
香・消臭剤にその適当量を配合することにより、調和の
とれた快い香りとともにマスキング効果を発揮できる人
体用芳香・消臭剤が得られることを見出し本発明を完成
した。Further, the fragrance / deodorant composition of the present invention is blended with an appropriate amount of the fragrance / deodorant for human body such as deodorant lotion, deodorant powder, deodorant spray, deodorant stick, etc. to make it harmonious and pleasant. The present invention has been completed by finding that a human body fragrance / deodorant capable of exerting a masking effect together with the scent can be obtained.
【0013】合成香料、天然香料の揮発度は、原料をエ
チルアルコールで約10%程度に希釈し、それを匂い紙
につけて室温に放置してどの位香りが持続するかを観察
することにより測定することができ、以下の4種類に分
類することができる。
1.トップノート(A);Top note
揮発度が高く、匂い紙につけておくとその全部もしくは
主要部分が約2時間程度以内に揮散してしまう香料であ
って、芳香・消臭組成物の匂いの第一印象を与えるため
に必要な部分。
2.ミドルノート(B);Middle note
中程度の揮発度を有し、匂い紙につけておくとその全部
もしくは主要部分が約2〜6時間程度匂いが持続する香
料であって、芳香・消臭組成物の骨格をなす部分。
3. ベースノート(C);Base note
揮発度が低く保留性に富み、約6時間以上匂い紙に匂い
が残る香料であって、芳香・消臭組成物の特徴を示す部
分。
4.ミックスノート(D);Mix note
上記のトップノート(A)とミドルノート(B)、ベー
スノート(C)がそれぞれ混合したもので、天然香料が
これに該当する。天然香料の種類によって、先立ちと中
間の保留性に富む成分が主成分であるもの、中間の保留
性と保留性に富む成分が主成分であるもの、先立ち、中
間程度の保留性、保留性に富む成分それぞれがバランス
のとれた割合で混合しているものがある。The volatility of synthetic flavors and natural flavors is measured by diluting the raw material to about 10% with ethyl alcohol, attaching it to odor paper and leaving it at room temperature to observe how long the fragrance lasts. It can be classified into the following four types. 1. Top note (A); Top note It is a fragrance that has a high volatility, and if it is attached to scented paper, the whole or main part of it will evaporate within about 2 hours. The part needed to make an impression. 2. Middle note (B); Middle note A fragrance / deodorant composition which has a moderate volatility, and when it is attached to odor paper, the whole or main part of the odor lasts for about 2 to 6 hours. The part that forms the skeleton of. 3. Base note (C); Base note A fragrance that has a low volatility, is highly retainable, and retains an odor on odor paper for about 6 hours or longer. 4. Mix note (D); Mix note A mixture of the above-mentioned top note (A), middle note (B), and base note (C), and natural flavors correspond to this. Depending on the type of natural fragrance, the main component is a component that is rich in the retention property between the preceding and intermediate properties, the main component is the component that is rich in the retention property and retention property in the middle, There are some where the rich components are mixed in balanced proportions.
【0014】本発明の芳香・消臭組成物は、上記のトッ
プノート(A)、ミドルノート(B)、ベースノート
(C)、ミックスノート(D)で示される揮発度の異な
る多数の合成香料あるいは天然香料を調合して、それぞ
れの芳香・消臭組成物に要求される所定の香質乃至香気
(例えば、シトラス、フルーティ、グリーン、フローラ
ル、アルデヒド、スパイシー、ウッディ、スイート、モ
ッシー、ムスキー、アンバー、アニマル、ハーバル、マ
リンおよびミントノートなど)を有する芳香・消臭組成
物を容易に調製することができる。The fragrance / deodorant composition of the present invention comprises a large number of synthetic fragrances having different volatility shown in the above-mentioned top note (A), middle note (B), base note (C) and mix note (D). Alternatively, a natural fragrance is blended, and a predetermined fragrance or aroma required for each fragrance / deodorant composition (for example, citrus, fruity, green, floral, aldehyde, spicy, woody, sweet, mossy, musky, amber). , Animal, herbal, marine, mint note, etc.) can be easily prepared.
【0015】本発明の芳香・消臭組成物の処方中におけ
る合成香料のノート成分による配合割合は、例えば
(A)トップノート成分が0〜100重量%、(B)ミ
ドルノート成分が0〜100重量%、(C)ベースノー
ト成分が0〜100重量%の範囲(D)ミックスノート
成分が0〜100重量%で使用されるが、通常は(A)
トップノート成分が5〜100重量%、(B)ミドルノ
ート成分が10〜50重量%、(C)ベースノート成分
が10〜50重量%、(D)天然香料であるミックスノ
ート成分が0.1〜30重量%程度の範囲で使用され
る。In the formulation of the aroma / deodorant composition of the present invention, the blending ratio of the synthetic perfume with the note component is, for example, 0 to 100% by weight of the top note component (A) and 0 to 100 for the middle note component (B). % By weight, (C) base note component in the range of 0-100% by weight (D) mixnote component is used in the range of 0-100% by weight, but usually (A)
The top note component is 5 to 100% by weight, (B) the middle note component is 10 to 50% by weight, (C) the base note component is 10 to 50% by weight, and (D) the mix note component which is a natural flavor is 0.1. It is used in the range of about 30% by weight.
【0016】芳香・消臭組成物に使用される(A)トッ
プノート成分に分類される合成香料としては、例えばα
−ピネン、β−ピネン、リモネン、p−サイメン、オシ
メン、ターピノーレン、ジヒドロミルセノール、シス−
3−ヘキセノール、トランス−3−ヘキセノール、イソ
プレゴール、l−メントール、1−オクテン−3−オー
ル、1−ペンテン−3−オール、ヘキサナール、ヘプタ
ナール、オクタナール、ノナナール、ベンズアルデヒ
ド、2,6−ジメチル−5−ヘプテン−1−アール<Me
lonal:Givaudan-Roure>、2,6−ノナジエナール、
1,8−シネオール、p−クレジルメチルエーテル、オ
クタナールジメチルアセタール、リモネンオキサイド、
ローズオキサイド、ギ酸ヘキシル、酢酸エチル、オクタ
ン酸アリル、2−エチル酪酸アリル、ヘキサン酸アリ
ル、ヘプタン酸エチル、デカン酸メチル、ヘキサン酸メ
チル、オクタン酸メチル、プロピオン酸イソアミル、酢
酸イソアミル、酢酸プレニル、酢酸ミルテニル、酢酸1
−オクテン−3−イル、酪酸メチル、酪酸エチル、酪酸
イソアミル、イソ酪酸イソアミル、ヘキサン酸エチル、
オクタン酸エチル、2−エチルヘキサン酸エチル、イソ
酪酸エチル、2−メチル酪酸メチル、2−メチル酪酸エ
チル、プロピオン酸エチル、ギ酸シス3−ヘキセニル、
イソ吉草酸シス3−ヘキセニル、プロピオン酸シス3−
ヘキセニル、アセト酢酸エチル、安息香酸メチル、フラ
ネオール、メチルヘプテノン、8−メルカプトメントン
などをあげることが出来る。*以上の化合物名の後の<
>内は主な商品名とそのメーカー名を示す。Examples of the synthetic perfume classified as the top note component (A) used in the fragrance / deodorant composition include α
-Pinene, β-pinene, limonene, p-cymene, ocimene, terpinolene, dihydromyrcenol, cis-
3-hexenol, trans-3-hexenol, isopulegol, 1-menthol, 1-octen-3-ol, 1-penten-3-ol, hexanal, heptanal, octanal, nonanal, benzaldehyde, 2,6-dimethyl-5- Hepten-1-R <Me
lonal: Givaudan-Roure>, 2,6-nonadienal,
1,8-cineole, p-cresyl methyl ether, octanal dimethyl acetal, limonene oxide,
Rose oxide, hexyl formate, ethyl acetate, allyl octanoate, allyl 2-ethylbutyrate, allyl hexanoate, ethyl heptanoate, methyl decanoate, methyl hexanoate, methyl octanoate, isoamyl propionate, isoamyl acetate, prenyl acetate, acetic acid Miltenyl, acetic acid 1
-Octen-3-yl, methyl butyrate, ethyl butyrate, isoamyl butyrate, isoamyl isobutyrate, ethyl hexanoate,
Ethyl octanoate, ethyl 2-ethylhexanoate, ethyl isobutyrate, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, ethyl propionate, cis-3-hexenyl formate,
Isovalerate cis 3-hexenyl, propionate cis 3-
Examples thereof include hexenyl, ethyl acetoacetate, methyl benzoate, furaneol, methylheptenone and 8-mercaptomenthone. * After the above compound names <
Items in parentheses are main product names and their manufacturer names.
【0017】また、(B)ミドルノート成分に分類され
る合成香料としては、例えばアセチルセドレン、アセチ
ルイソオイゲノール、ウンデカナール、ドデカナール、
アリルアミルグリコレート、4−イソプロピル−5,5
−ジメチル−1,3−ジオキサン<Anthoxan:Henkel
>、酢酸ベンジル、ベンジルアルコール、プロピオン酸
ベンジル、酢酸o−tert.−ブチルシクロヘキシル
<Verdox:IFF>、酢酸p−tert.−ブチルシクロヘ
キシル<Vertenex:IFF>、カルボン、シトラール、ゲラ
ニルニトリル、シトロネラール、シトロネロール、酢酸
シトロネリル、シトロネリルニトリル、クレゾール、酢
酸p−クレジル、イソ酪酸p−クレジル、酢酸トリシク
ロデセニル<Cyclacet:IFF>、プロピオン酸トリシクロ
デセニル<Cycloprop:IFF>、1−デセナール、2−ペ
ンチルシクロペンタノン<Delphone:Firmenich>、ジヒ
ドロリナロール、ジメチルベンジルカルビノール、酢酸
ジメチルベンジルカルビニル、ジメチルオクタナール、
酢酸3,7−ジメチルオクタニル、ジメチルフェネチル
カルビノール、酢酸ジメチルフェネチルカルビニル、ジ
フェニルオキサイド、ドデカナール、4−トリシクロデ
シリデンブタナール<Dupical:Quest>、エストラゴー
ル、p−エチル−α、α−ジメチルヒドロシンナムアル
デヒド、レブリン酸エチル、エチルリナロール、オイゲ
ノール、α−フェンコン、酢酸フェンキル、α−フェン
キルアルコール、ゲラニオール、酢酸ゲラニル、ギ酸ゲ
ラニル、グアイアコール、酢酸1−エチニルシクロヘキ
シル<Herbacet No.1:IFF>、アントラニル酸シス−3
−ヘキセニル、安息香酸シス−3−ヘキセニル、酪酸シ
ス−3−ヘキセニル、フェニルアセトアルデヒド、ハイ
ドラトロパアルデヒド ジメチルアセタール、ハイドラ
トロパアルデヒドエチレングリコールアセタール、ハイ
ドラトロピックアルデヒド、ヒドロキシシトロネラー
ル、ヒドロキシシトロネラールジメチルアセタール、イ
ンドール、アンゲリカ酸イソアミル、酢酸イソボルニ
ル、イソダマスコン、イソジャスモン、シクロオクチル
カルボン酸メチル<Jasmacyclat:Henkel>、酢酸5−メ
チル−3−ブチルテトラヒドロピラン−4−イル<Jasm
elia:IFF>、シス−ジャスモン、4−メチレン−3,
5,6,6−テトラメチル−2−ヘプタノン<Koavone:
IFF>、p−tert.−ブチル−α−メチルヒドロシ
ンナムアルデヒド<Lilial:Givaudan-Roure>、リナロ
ール、リナロールオキサイド、メントン、酢酸l−メン
チル、p−メチルアセトフェノン、アニス酸メチル、ヘ
プチンカルボン酸メチル、フェニルグリシド酸メチル、
サリチル酸メチル、2−メチルウンデカナール、マイラ
ックアルデヒド、ネラール、ネロール、酢酸ネリル、酢
酸ノニル、酢酸ノピル、1−オクタノール、酢酸オクチ
ル、酢酸3−ペンチルテトラヒドロピラン−4−イル、
フェニルアセトアルデヒドジメチルアセタール、フェニ
ルアセトアルデヒドプロピレングリコールアセタール、
酢酸フェネチル、α−フェネチルアルコール、β−フェ
ネチルアルコール、プロピオン酸2−フェネチル、酢酸
3−フェニルプロピル、3−フェニルプロピルアルコー
ル、イソ酪酸3−フェニルプロピル、酢酸ロジニル、9
−デセノール<Rosalva:IFF>、酢酸スチラリル、スチ
ラリルアルコール、ターピネン−4−オール、ターピネ
オール、酢酸ターピニル、テトラヒドロアロオシメノー
ル、テトラヒドロゲラニオール、テトラヒドロリナロー
ル、テトラヒドロムゴール、テトラヒドロミルセノー
ル、チオゲラニオール、チモール、ジメチルテトラヒド
ロベンズアルデヒド<Triplal:IFF>、ウンデカナー
ル、トランス−2−ウンデセナール、2−メチル−3−
(p−メトキシフェニル)−プロパナール<Canthoxal:
IFF>、マルトール、アセトアルデヒド2−フェニル−
2,4−ペンタンジオールアセタール<Vertacetal:Dra
goco>などをあげることができる。以上の化合物名の後
の< >内は主な商品名とそのそのメーカー名を示す。Further, (B) synthetic flavors classified as middle note components include, for example, acetyl cedrene, acetylisoeugenol, undecanal, dodecanal,
Allyl amyl glycolate, 4-isopropyl-5,5
-Dimethyl-1,3-dioxane <Anthoxan: Henkel
>, Benzyl acetate, benzyl alcohol, benzyl propionate, acetic acid o-tert. -Butylcyclohexyl <Verdox: IFF>, acetic acid p-tert. -Butylcyclohexyl <Vertenex: IFF>, carvone, citral, geranyl nitrile, citronellal, citronellol, citronellyl acetate, citronellyl nitrile, cresol, p-cresyl acetate, p-cresyl isobutyrate, tricyclodecenyl acetate <Cyclacet: IFF >, Tricyclodecenyl propionate <Cycloprop: IFF>, 1-decenal, 2-pentylcyclopentanone <Delphone: Firmenich>, dihydrolinalool, dimethylbenzylcarbinol, dimethylbenzylcarbinyl acetate, dimethyloctanal,
3,7-Dimethyloctanyl acetate, dimethylphenethylcarbinol, dimethylphenethylcarbinyl acetate, diphenyl oxide, dodecanal, 4-tricyclodecylidenebutanal <Dupical: Quest>, estragole, p-ethyl-α, α- Dimethylhydrocinnamaldehyde, ethyl levulinate, ethyl linalool, eugenol, α-phencon, fenkill acetate, α-fenkill alcohol, geraniol, geranyl acetate, geranyl formate, guaiacol, 1-ethynylcyclohexyl acetate <Herbacet No. 1: IFF> , Anthranilic acid cis-3
-Hexenyl, cis-3-hexenyl benzoate, cis-3-hexenyl butyrate, phenylacetaldehyde, hydratropaldehyde dimethyl acetal, hydratropaaldehyde ethylene glycol acetal, hydratropic aldehyde, hydroxycitronellal, hydroxycitronellal dimethyl Acetal, indole, isoamyl angelica, isobornyl acetate, isodamascon, isojasmon, methyl cyclooctylcarboxylate <Jasmacyclat: Henkel>, 5-methyl-3-butyltetrahydropyran-4-yl acetate <Jasm
elia: IFF>, cis-jasmon, 4-methylene-3,
5,6,6-Tetramethyl-2-heptanone <Koavone:
IFF>, p-tert. -Butyl-α-methylhydrocinnamaldehyde <Lilial: Givaudan-Roure>, linalool, linalool oxide, menthone, l-menthyl acetate, p-methylacetophenone, methyl anisate, methyl heptine carboxylate, methyl phenylglycidate,
Methyl salicylate, 2-methylundecanal, mylacaldehyde, neral, nerol, neryl acetate, nonyl acetate, nopyr acetate, 1-octanol, octyl acetate, 3-pentyltetrahydropyran-4-yl acetate,
Phenylacetaldehyde dimethyl acetal, phenylacetaldehyde propylene glycol acetal,
Phenethyl acetate, α-phenethyl alcohol, β-phenethyl alcohol, 2-phenethyl propionate, 3-phenylpropyl acetate, 3-phenylpropyl alcohol, 3-phenylpropyl isobutyrate, rosinyl acetate, 9
-Decenol <Rosalva: IFF>, styralyl acetate, styralyl alcohol, terpinen-4-ol, terpineol, terpinyl acetate, tetrahydroalloocimenol, tetrahydrogeraniol, tetrahydrolinalool, tetrahydromugol, tetrahydromyrcenol, thiogeraniol, thymol , Dimethyltetrahydrobenzaldehyde <Triplal: IFF>, undecanal, trans-2-undecenal, 2-methyl-3-
(P-Methoxyphenyl) -propanal <Canthoxal:
IFF>, maltol, acetaldehyde 2-phenyl-
2,4-Pentanediol acetal <Vertacetal: Dra
goco> and so on. The main product names and their manufacturer names are shown in <> after the above compound names.
【0018】また、(C)にベースノート成分を示す合
成香料としては、例えばテトラデカナール、γ−ウンデ
カラクトン、γ−ノナラクトン、アンブロックス<Ambr
oxan:Henkel>、サリチル酸アミル、8,9−エポキシ
セドラン、イソアミルフェネチルエーテル<Anther:Que
st>、アニスアルデヒド、オーランチオール、ベンジル
イソオイゲノール、サリチル酸ベンジル、6,7−ジヒ
ドロ−1,1,2,3,3−ペンタメチル−4−(5
H)−インダノン<Cashmeran:IFF>、セドリルメチル
エーテル<Cedramber:IFF>、セドレン、ギ酸セドリ
ル、セドロール、シンナミックアルコール、酢酸シンナ
ミル、ケイヒ酸シンナミル、クマリン、フェニル酢酸p
−クレジル、シクラメンアルデヒド、サリチル酸シクロ
ヘキシル、γ−デカラクトン、δ−デカラクトン、アン
トラニル酸ジメチル、酪酸ジメチルベンジルカルビニ
ル、δ−ドデカラクトン、ケイヒ酸エチル、エチルマル
トール、メチルフェニルグリシド酸エチル、エチルバニ
リン、フェニル酢酸オイゲニル、ファルネソール、酪酸
ゲラニル、イソ酪酸ゲラニル、イソ吉草酸ゲラニル、3
a−エチルドデカヒドロ−6,6,9a−トリメチルナ
フト[2.1b]フラン<Grisalva:IFF>、ジヒドロジ
ャスモン酸メチル<Hedione:Firmenich>、α−メチル
−3,4−メチレンジオキシヒドロシンナムアルデヒド
<Helional:IFF>、ヘリオトロピン、サリチル酸シス−
3−ヘキセニル、α−ヘキシルシンナムアルデヒド、サ
リチル酸ヘキシル、イソブチルキノリン、7−アセチル
−1,2,3,4,5,6,7,8−オクタヒドロ−
1,1,6,7−テトラメチルナフタレン<Iso E supe
r:IFF>、イソオイゲノール、イソロンギホラノン、ジ
ャスミンラクトン、γ−ジャスモラクトン、テトラヒド
ロ−6−(3−ペンテニル)−2H−ピラン−2−オン
<Jasmolactone:Firmenich>、4(3)−(4−ヒドロ
キシ−4−メチルペンチル)−シクロヘキセン−1−カ
ルボキシアルデヒド<Lyral:IFF>、1−(5,5−ジ
メチルシクロヘキセン−1−イル)−4−ペンテン−1
−オン<α-Dynascone:Firmenich>、2,4−ジヒドロ
キシ−3,6−ジメチル安息香酸メチル、β−ナフチル
イソブチルエーテル、β−ナフチルメチルエーテル、β
−ナフチルエチルエーテル、ネロリドール、γ−オクタ
ラクトン、パチョリアルコール、フェニルアセトアルデ
ヒド2,4−ジヒドロキシ−4−メチルペンタンアセタ
ール、ピバリン酸2−フェネチル、p−ヒドロキシフェ
ニルブタノン、ローズフェノン、1−(2,2,6−ト
リメチルシクロヘキサン−1−イル)−ヘキサン−3−
オール、クエン酸トリエチル、バニリン、酢酸ベチベリ
ル、ダマスコン類*、ダマセノン類*、イオノン類*、
メチルイオノン類*、合成サンダルウッド類*、合成ム
スク類*、イロン類*などを例示することができる。以
上の化合物名の後の< >内は主な商品名とそのそのメ
ーカー名を示す。更に、上記の*印を付した包括名称は
例えば以下の化合物を表す。
ダマスコン類;α-Damascone、β-Damascone、γ-Damasco
ne、δ-Damascone
ダマセノン類;α-Damascenone、β-Damascenone、γ-Dam
ascenone
イオノン類 ;α-Ionone、β-Ionone、γ-Ionone
メチルイオノン類;α-n-Methylionone、β-n-Methylion
one、γ-n-Methylionone,α-iso-Methylionone、β-iso-M
ethylionone、γ-iso-Methylionone
合成サンダルウッド類;Bacdanol(IFF);2-Ethyl-4-(2,
2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol
Brahamanol(Dragoco);2-Methyl-4-(2,2,3-trimethyl-3
-cyclopenten-1-yl)butanol
Madranol(Dragoco);β-2,2,3-Tetramethyl-3-cyclopen
tenyl-2-butenol
Sandalore(Givaudan);3-Methyl-5-(2,2,3-trimethylcy
clopent-3-en-1-yl)-pentan-2-ol
3,3-Dimethyl-5-(2,2,3-trimethylcyclopenten-1-yl)-p
ent-4-en-2-ol,Methyl sadeflor(TPC)、Sandeol(MS)な
ど
合成ムスク類;Cashmeran(IFF)、Galaxolide(IFF)、Tonal
ide(PFW)、Phantolide、Versalide、Exaltolide、Exaltone、
Oxalide、12-Oxahexadecanolide、Ethylene brassylate、M
usk ketone、Celestolide(IFF)、Traseolide(Quest)、Ethy
lenedodecanedioate、5-Cyclohexadecen-1-oneなど
イロン類 ;α-Irone、β-Irone、γ-Irone
また、(D)のミックスノートである天然香料として
は、イランイラン、イリス、ウインターグリーン、オー
クモス、オポパナックス、オレンジ、カモミール、カル
ダモン、クミン、クローブ、コリアンダー、サンダルウ
ッド、ジャスミン、ジュニパーベリー、ジンジャー、シ
ンナモン、スペアミント、シダー、ゼラニウム、タイ
ム、トルーバルサム、ナツメッグ、ショウノウ、バジ
ル、パチョリ、ハッカ(和種ハッカ)、バニラ、ベルガ
モット、ペルーバルサム、ベンゾイン、ホウショウ、ユ
ーカリ、ヨモギ、ライム、ラベンダー、レモン、ロー
ズ、ローズマリー、マンダリン、ローレルなどが例示さ
れる。なお、これらの天然香料はアブソリュート、コン
クリート、レジノイドなどの形状のものであることもで
きる。Examples of the synthetic fragrance having the base note component (C) include, for example, tetradecanal, γ-undecalactone, γ-nonalactone, and ambrox <Ambr
oxan: Henkel>, amyl salicylate, 8,9-epoxycedrane, isoamyl phenethyl ether <Anther: Que
st>, anisaldehyde, auranthiol, benzylisoeugenol, benzyl salicylate, 6,7-dihydro-1,1,2,3,3-pentamethyl-4- (5
H) -Indanone <Cashmeran: IFF>, Cedryl methyl ether <Cedramber: IFF>, Cedrene, Cedryl formate, Cedrol, Cynamic alcohol, Cinnamyl acetate, Cinnamyl cinnamate, Coumarin, Phenylacetate p
-Cresyl, cyclamenaldehyde, cyclohexyl salicylate, γ-decalactone, δ-decalactone, dimethyl anthranilate, dimethylbenzylcarbyl butyrate, δ-dodecalactone, ethyl cinnamate, ethyl maltol, ethyl methylphenylglycidate, ethyl vanillin, phenyl Eugenyl acetate, farnesol, geranyl butyrate, geranyl isobutyrate, geranyl isovalerate, 3
a-Ethyldodecahydro-6,6,9a-trimethylnaphtho [2.1b] furan <Grisalva: IFF>, methyl dihydrojasmonate <Hedione: Firmenich>, α-methyl-3,4-methylenedioxyhydrocinnamaldehyde <Helional: IFF>, Heliotropin, Salicylate cis-
3-hexenyl, α-hexylcinnamaldehyde, hexyl salicylate, isobutylquinoline, 7-acetyl-1,2,3,4,5,6,7,8-octahydro-
1,1,6,7-Tetramethylnaphthalene <Iso E supe
r: IFF>, isoeugenol, isolongiforanone, jasmine lactone, γ-jasmolactone, tetrahydro-6- (3-pentenyl) -2H-pyran-2-one <Jasmolactone: Firmenich>, 4 (3)- (4-Hydroxy-4-methylpentyl) -cyclohexene-1-carboxaldehyde <Lyral: IFF>, 1- (5,5-dimethylcyclohexen-1-yl) -4-pentene-1
-One <α-Dynascone: Firmenich>, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, β-naphthyl isobutyl ether, β-naphthyl methyl ether, β
-Naphthylethyl ether, nerolidol, γ-octalactone, patchouli alcohol, phenylacetaldehyde 2,4-dihydroxy-4-methylpentane acetal, 2-phenethyl pivalate, p-hydroxyphenylbutanone, rosephenone, 1- (2, 2,6-Trimethylcyclohexan-1-yl) -hexane-3-
Ol, triethyl citrate, vanillin, acetic vetiveryl, damascones such *, damascenone such *, ionones *,
Methyl ionone such *, synthetic sandalwood acids *, synthetic musks *, and the like can be exemplified nylon compounds *. The main product names and their manufacturer names are shown in <> after the above compound names. Furthermore, the above-mentioned comprehensive names marked with * represent, for example, the following compounds. Damascons: α-Damascone, β-Damascone, γ-Damasco
ne, δ-Damascone Damascenones; α-Damascenone, β-Damascenone, γ-Dam
ascenone Ionones; α-Ionone, β-Ionone, γ-Ionone Methylionones; α-n-Methylionone, β-n-Methylion
one, γ-n-Methylionone, α-iso-Methylionone, β-iso-M
ethylionone, γ-iso-Methylionone synthetic sandalwoods; Bacdanol (IFF); 2-Ethyl-4- (2,
2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol Brahamanol (Dragoco) ; 2-Methyl-4- (2,2,3-trimethyl-3
-cyclopenten-1-yl) butanol Madranol (Dragoco) ; β-2,2,3-Tetramethyl-3-cyclopen
tenyl-2-butenol Sandalore (Givaudan) ; 3-Methyl-5- (2,2,3-trimethylcy
clopent-3-en-1-yl) -pentan-2-ol 3,3-Dimethyl-5- (2,2,3-trimethylcyclopenten-1-yl) -p
Synthetic musks such as ent-4-en-2-ol, methyl sadeflor (TPC), Sandeol (MS); Cashmeran (IFF), Galaxolide (IFF), Tonal
ide (PFW), Phantolide, Versalide, Exaltolide, Exaltone,
Oxalide, 12-Oxahexadecanolide, Ethylene brassylate, M
usk ketone, Celestolide (IFF), Traseolide (Quest), Ethy
Irons such as lenedodecanedioate and 5-Cyclohexadecen-1-one; α-Irone, β-Irone, γ-Irone In addition, (D) mixed notes of natural flavors include ylang-ylang, iris, wintergreen, oakmoss, and opopanax. , Orange, chamomile, cardamom, cumin, clove, coriander, sandalwood, jasmine, juniper berry, ginger, cinnamon, spearmint, cedar, geranium, thyme, true balsam, nutmeg, camphor, basil, patchouli, peppermint (Japanese mint) , Vanilla, bergamot, peruvian balsam, benzoin, porcine, eucalyptus, mugwort, lime, lavender, lemon, rose, rosemary, mandarin, laurel and the like. In addition, these natural flavors may be in the form of absolute, concrete, resinoid, or the like.
【0019】(A)トップノート成分及び/又は(B)
ミドルノート成分及び/又は(C)ベースノート成分の
群から選ばれる少なくとも1種以上の合成香料からなる
本発明の芳香・消臭組成物、及びさらに(D)天然香料
を配合した芳香・消臭組成物はデオドラントローショ
ン、デオドラントパウダー、デオドラントスプレー、デ
オドラントスティックなどの人体用芳香・消臭剤に使用
することができる。(A) Top note component and / or (B)
Fragrance / deodorant composition of the present invention comprising at least one synthetic fragrance selected from the group consisting of middle note component and / or (C) base note component, and (D) fragrance / deodorant further containing natural flavor The composition can be used for aroma and deodorant for human body such as deodorant lotion, deodorant powder, deodorant spray and deodorant stick.
【0020】それぞれの芳香・消臭組成物に要求される
所定の香質乃至香気( 例えば、シトラス、フルーテ
ィ、グリーン、フローラル、アルデヒド、スパイシー、
ウッディ、スイート、モッシー、ムスキー、アンバー、
アニマル、ハーバル、マリン、およびミントノートな
ど)に調製された本発明の芳香・消臭組成物は、快い香
りで調和のとれた、適度の先立ち、適度の強さの芳香
と、拡散性および持続性をもつ特徴を有し、この芳香・
消臭組成物を配合したデオドラントローション、デオド
ラントパウダー、デオドラントスプレー、デオドラント
スティックなどの人体用芳香・消臭剤は、使用直後に爽
快な香りを示し、また、使用後もしばらく匂い続ける持
続性と残香性を有し、香料のマスキング機能により人体
の消臭に優れた効果を示し、かつ人体用芳香・消臭剤に
使用されている基剤自体のマスキングも可能であり、更
には香料によるアロマテラピー効果、ストレス緩和作
用、また抗菌性も期待できるなど優れた効果を発揮する
ことができる。Predetermined fragrance or aroma required for each aroma / deodorant composition (eg, citrus, fruity, green, floral, aldehyde, spicy,
Woody, sweet, mossy, musky, amber,
The fragrance / deodorant composition of the present invention prepared in animal, herbal, marine, and mint note, etc., has a pleasant scent and is moderately prominent, moderately strong, and has a diffusive and persistent fragrance. This fragrance
Deodorant lotions, deodorant powders, deodorant sprays, deodorant sticks, and other fragrances and deodorants for the human body that contain deodorant compositions have a refreshing fragrance immediately after use, and have a long-lasting and residual scent that continues to smell after use. It has an excellent effect on deodorization of the human body due to its fragrance masking function, and it is also possible to mask the base itself used for human fragrances and deodorants, and further, aromatherapy with fragrances. It is possible to exert excellent effects such as an effect, a stress relieving effect, and an antibacterial property.
【0021】なお、本発明の芳香・消臭組成物は上記の
人体用芳香・消臭剤以外にも、香水、オーデコロン、オ
ードトワレ、オードパルファム、フレッシュコロン、デ
オドラントコロン、アルコールフリー香水類、フレグラ
ンスパウダー、練香などの各種フレグランス製品はじ
め、各種の頭髪用化粧料、皮膚洗浄剤、身体洗浄剤、浴
剤、洗口剤(マウスウォッシュなど)、更には洗顔料、
化粧水、乳液、クリーム、ジェル、美容液、パック・マ
スク、ヒゲソリ用化粧料等の基礎化粧品、おしろい、フ
ァンデーション、口紅、頬紅、眉目類、美爪類等のメー
キャップ化粧品や、化粧品以外の製品、例えば防臭下
着、防臭靴敷など各種の防臭製品の賦香にも使用するこ
とが出来る。The fragrance / deodorant composition of the present invention is used in addition to the above-mentioned human fragrance / deodorant, perfume, eau de cologne, eau de toilette, eau de parfum, fresh cologne, deodorant cologne, alcohol-free perfume, fragrance powder, Various fragrance products such as paste, various hair cosmetics, skin cleaners, body cleaners, bath agents, mouthwashes (mouthwash, etc.), and face wash,
Basic cosmetics such as lotions, emulsions, creams, gels, beauty essences, packs / masks, shaving cosmetics, make-up cosmetics, foundations, lipsticks, blushers, eyebrows, nails, and other non-cosmetic products. For example, it can be used for perfuming various deodorant products such as deodorant underwear and deodorant shoe mats.
【0022】上記香料の他に本発明の芳香・消臭組成物
の素材として、(A)トップノート成分、(B)ミドル
ノート成分、(C)ベースノート成分として使用するこ
とのできる合成香料や、(D)天然香料としては、例え
ば表−1,表−2,表−3、表−4のそれぞれに記載の
ものがあげられる。表−1〜4に記載される合成および
天然香料を香り別に適宜に選択して、請求項5〜8に記
載のそれぞれの群に記載される香料に代えるか、または
添加して所望する香質乃至香気(例えば、シトラス、フ
ルーティ、グリーン、フローラル、アルデヒド、スパイ
シー、ウッディ、アルデヒド、スパイシー、スイート、
モッシー、ムスキー、アンバー、アニマル、ハーバル、
マリン、およびミントノートなど)を有する芳香・消臭
組成物を調製することができる。In addition to the above fragrances, synthetic fragrances that can be used as materials for the fragrance / deodorant composition of the present invention (A) top note component, (B) middle note component, (C) base note component, Examples of (D) natural fragrances include those listed in Table-1, Table-2, Table-3, and Table-4. The synthetic and natural fragrances listed in Tables 1 to 4 are appropriately selected for each scent, and the desired fragrance is obtained by replacing or adding the fragrances described in each group according to claims 5 to 8. To aroma (eg, citrus, fruity, green, floral, aldehyde, spicy, woody, aldehyde, spicy, sweet,
Mossy, musky, amber, animal, herbal,
Fragrance and deodorant compositions having marine, mint note, etc.) can be prepared.
【0023】表−1(A)トップノート
カンフェン、ミルセン、ヘキサナールジメチルアセター
ル、1,4−シネオール、2−オクタノン、トランス−
2−ヘキセナール、2,6−ジメチルヘプタン−2−オ
ール、2−メチル−3−ブテン−2−オール、プロピオ
ン酸アリル、酢酸イソブチル、酢酸アミル、酢酸シクロ
ヘキシル、酢酸ヘプチル、酪酸ブチル、酢酸2−エチル
ヘキシル、プロピオン酸ブチル、吉草酸ブチル、イソ吉
草酸エチル、イソ吉草酸イソアミルなど。 Table-1 (A) Top notes Camphene, Myrcene, Hexanal dimethyl acetal, 1,4-Cineol, 2-Octanone, Trans-
2-hexenal, 2,6-dimethylheptan-2-ol, 2-methyl-3-buten-2-ol, allyl propionate, isobutyl acetate, amyl acetate, cyclohexyl acetate, heptyl acetate, butyl butyrate, 2-ethylhexyl acetate , Butyl propionate, butyl valerate, ethyl isovalerate, isoamyl isovalerate and so on.
【0024】表−2(B)ミドルノート
アセトアルデヒドシトロネリルメチルアセタール、アセ
トアルデヒドエチルリナリルアセタール、アセトフェノ
ン、アロオシメノール、ヘプタナールジエチルアセター
ル、オクタナールジエチルアセタール、ノナナールジエ
チルアセタール、カプロン酸アミル、4−tert.−
アミルシクロヘキサノン<Orivone:IFF>、ベンズアル
デヒドジエチルアセタール、イソ吉草酸ベンジル、ボル
ネオール、酢酸ボルニル、カジネン、シクロデシルメチ
ルエーテル、酪酸ベンジル、酪酸シクロヘキシル、デカ
ナールジメチルアセタール、ドデカナールジメチルアセ
タール、安息香酸エチル、ノナン酸エチル、サリチル酸
エチル、ゲラニルアセトン、2,4−ヘプタジエナー
ル、ヘプタナールジエチルアセタール、酪酸ヘプチル、
酪酸イソブチル、ヘキサナールジエチルアセタール、酪
酸トランス−2−ヘキセニル、酪酸ヘキシル、イソ吉草
酸ヘキシル、イソボルネオール、乳酸イソアミル、安息
香酸イソブチル、4−イソプロピルシクロヘキサノー
ル、酢酸4−イソプロピルシクロヘキシル、ラバンジュ
ロール、酢酸ラバンジュリル、2,6,6−トリメチル
−6−ビニルテトラヒドロピラン<Limetol:Givaudan-R
oure>、ロンギフォレン、1−メチル−1−メトキシシ
クロドデカン<Madrox:Givaudan-Roure>、酢酸α−メ
チルベンジル、酢酸4−メチルベンジル、イソ吉草酸2
−メチルブチル、シクロゲラン酸メチル、ギ酸シトロネ
リル、フェニル酢酸メチル、2−メチルウンデカナー
ル、シトラールジエチルアセタール、シトラールジメチ
ルアセタール、ミュゲアルデヒド、ネロールオキサイ
ド、酪酸ネリル、イソ酪酸ネリル、ノナナールジエチル
アセタール、2−オクタノール、3−オクタノール、ペ
リラアルデヒド、イソ酪酸2−フェネチル、イソ吉草酸
2−フェネチル、2−メチル酪酸2−フェネチル、ピノ
カルベオール、ピペリテノン、ピペリトン、プレゴン、
イソ酪酸テルピニル、イソ吉草酸テルピニル、プロピオ
ン酸テルピニル、酢酸テトラヒドロムギル、10−ウン
デセナール、酪酸テルピニル、酢酸3,5,5−トリメ
チルヘキシル、酢酸トリシクロデセニル<Verdyl aceta
te:Givaudan-Roure>、プロピオン酸トリシクロデセニル
<Verdyl propionate:Givaudan-Roure>、酢酸4−メチ
ル−4−フェニル2−ペンチル<Veticol acetate:Drag
oco>など。以上表−2中、化合物名の後の< >内は主
な商品名とそのメーカー名を示す。 Table-2 (B) Middle note Acetaldehyde citronellyl methyl acetal, acetaldehyde ethyl linalyl acetal, acetophenone, aloosimenol, heptanal diethyl acetal, octanal diethyl acetal, nonanal diethyl acetal, amyl caproate, 4-tert . −
Amyl cyclohexanone <Orivone: IFF>, benzaldehyde diethyl acetal, benzyl isovalerate, borneol, bornyl acetate, cazinene, cyclodecyl methyl ether, benzyl butyrate, cyclohexyl butyrate, decanal dimethyl acetal, dodecanal dimethyl acetal, ethyl benzoate, nonane Ethyl acid, ethyl salicylate, geranylacetone, 2,4-heptadienal, heptanal diethyl acetal, heptyl butyrate,
Isobutyl butyrate, hexanal diethyl acetal, trans-2-hexenyl butyrate, hexyl butyrate, hexyl isovalerate, isoborneol, isoamyl lactate, isobutyl benzoate, 4-isopropylcyclohexanol, 4-isopropylcyclohexyl acetate, lavandulol, lavandulyl acetate. , 2,6,6-Trimethyl-6-vinyltetrahydropyran <Limetol: Givaudan-R
oure>, longifolene, 1-methyl-1-methoxycyclododecane <Madrox: Givaudan-Roure>, α-methylbenzyl acetate, 4-methylbenzyl acetate, isovaleric acid 2
-Methylbutyl, methyl cyclogeranate, citronellyl formate, methyl phenylacetate, 2-methylundecanal, citral diethyl acetal, citral dimethyl acetal, muguealdehyde, nerol oxide, neryl butyrate, neryl isobutyrate, nonanal diethyl acetal, 2-octanol , 3-octanol, perillaldehyde, 2-phenethyl isobutyrate, 2-phenethyl isovalerate, 2-phenethyl 2-methylbutyrate, pinocarveol, piperitenone, piperiton, pulegone,
Isobutyrate terpinyl, isovalerate terpinyl, propionate terpinyl, tetrahydromugyl acetate, 10-undecenal, terpinyl butyrate, 3,5,5-trimethylhexyl acetate, tricyclodecenyl acetate <Verdyl aceta
te: Givaudan-Roure>, tricyclodecenyl propionate <Verdyl propionate: Givaudan-Roure>, 4-methyl-4-phenyl-2-pentyl acetate <Veticol acetate: Drag
oco> etc. In Table 2 above, main product names and manufacturer names are shown in <> after the compound names.
【0025】表−3(C)ベースノート
フェノキシ酢酸アリル、、2,5,5−トリメチル−オ
クタヒドロナフトール<Ambrinol:Dragoco>、α−アミ
ルシンナムアルコール、酢酸α−アミルシンナミル、酢
酸アニシル、アニスアルコール、アニシルアセトン、安
息香酸ベンジル、α−ビサボロール、フェニル酢酸ブチ
ル、7−メチル−3,5−ジヒドロ−[2H]−ベンゾ
ジオキセピン−3−オン、β−カリオフィレン、α−セ
ドレンエポキサイド、ギ酸セドリル、酪酸シトロネリ
ル、フェニル酢酸シトロネリル、シベトン、13−オキ
サビシクロ[10.3.0]ペンタデカン<Cyclamber:
Henkel>、ジヒドロカルベオール、酢酸セドリル、酢酸
ジヒドロカルビル、ジヒドロジャスモンラクトン、プロ
ピオン酸ジメチルベンジルカルビニル、イソ酪酸ジメチ
ルフェネチルカルビニル、ジフェニルメタン、アントラ
ニル酸エチル、3−フェニルグリシド酸エチル、β−メ
チルナフチルケトン、p−メチル−β−フェニルグリシ
ド酸エチル、安息香酸ゲラニル、ゲラニルリナロール、
γ−ヘキサラクトン、フェニル酢酸シス−3−ヘキセニ
ル、安息香酸ヘキシル、フェニル酢酸ヘキシル、イオノ
ン、安息香酸イソアミル、イソアミルベンジルエーテ
ル、サリチル酸イソアミル、イソロンギホレンエポキサ
イド、ジャスミンラクトン、メチル−(3,5−ジメチ
ル−3−シクロヘキセン−1−イル)−メチレン<Liga
ntraal:Quest>、p−イソプロピルシクロヘキシルメタ
ノール<Mayol:IFF>、アントラニル酸メチル、ジャス
モン酸メチル、N−メチルアントラニル酸メチル、2−
メチル−4−(2,3,3−トリメチル−3−シクロペ
ンテン−1−イル)−2−ブテン−1−オール<Santal
inol>、δ−ノナラクトン、ヌートカトン、δ−オクタ
ラクトン、ペンタデカノリッド、酪酸2−フェネチル、
2−フェネチルイソアミルエーテル、フェニル酢酸フェ
ネチル、ロジノール、レゾルシノールジメチルエーテ
ル、2,6,10−トリメチル−1−アセチル−2,
5,9−シクロドデカトリエン<Trimofix O:IFF>、δ
−ウンデカラクトンなど。以上表−3中、化合物名の後
の< >内は主な商品名とそのメーカー名を示す。 Table 3 (C) Base note Allyl phenoxyacetate, 2,5,5-Trimethyl-octahydronaphthol <Ambrinol: Dragoco>, α-amylcinnamyl alcohol, α-amylcinnamyl acetate, anisyl acetate, anis alcohol , Anisylacetone, benzyl benzoate, α-bisabolol, butyl phenylacetate, 7-methyl-3,5-dihydro- [2H] -benzodioxepin-3-one, β-caryophyllene, α-cedrene epoxide, Cedolyl formate, citronellyl butyrate, citronellyl phenylacetate, civetone, 13-oxabicyclo [10.3.0] pentadecane <Cyclamber:
Henkel>, dihydrocarbeol, cedryl acetate, dihydrocarbyl acetate, dihydrojasmon lactone, dimethylbenzylcarbinyl propionate, dimethylphenethylcarbinyl isobutyrate, diphenylmethane, ethyl anthranilate, ethyl 3-phenylglycidate, β-methylnaphthyl Ketone, ethyl p-methyl-β-phenylglycidate, geranyl benzoate, geranyl linalool,
γ-hexalactone, cis-3-hexenyl phenylacetate, hexyl benzoate, hexyl phenylacetate, ionone, isoamyl benzoate, isoamyl benzyl ether, isoamyl salicylate, isolongifolene epoxide, jasmine lactone, methyl- (3,5- Dimethyl-3-cyclohexen-1-yl) -methylene <Liga
ntraal: Quest>, p-isopropylcyclohexylmethanol <Mayol: IFF>, methyl anthranilate, methyl jasmonate, methyl N-methylanthranilate, 2-
Methyl-4- (2,3,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol <Santal
inol>, δ-nonalactone, nootkatone, δ-octalactone, pentadecanolide, 2-phenethyl butyrate,
2-phenethylisoamyl ether, phenylethyl phenylacetate, rosinol, resorcinol dimethyl ether, 2,6,10-trimethyl-1-acetyl-2,
5,9-Cyclododecatriene <Trimofix O: IFF>, δ
-Undecalactone etc. In Table 3 above, the main product names and manufacturer names are shown in <> after the compound name.
【0026】表−4(D)天然香料
アンブレットシード、エレミ、オリバナム、カシア(ミ
モザ)、カナンガ、ガルバナム、カッシー、カッシャ、
キャラウェイ、クラリセージ、シダーウッド、ジュネ、
シトロネラ、シベット、ジョンキル、スターアニス、セ
ージ、チュベローズ、ディル、ナルシサス、バレリア
ン、プチグレン、ベチバー、ペニーローヤル、ペパーミ
ント、ボアドローズ、マージョラム、レモングラス、ロ
ベージ、ラバンジン、スィートフェンネル、ベイ、カッ
シーなど。 Table-4 (D) Natural fragrances Amblet seed, Elemi, Olivanam, Cassia (Mimosa), Kananga, Galvanum, Cassie, Cassia,
Caraway, clary sage, cedarwood, june,
Citronella, Civet, John Kill, Star Anise, Sage, Tuberose, Dill, Narcissus, Valerian, Petit Glen, Vetiver, Penny Royal, Peppermint, Boadrose, Marjoram, Lemongrass, Lovagin, Sweet Fennel, Bay, Cassie.
【0027】上記表−4に記載される天然香料は、アブ
ソリュート、コンクリート、レジノイドなどの形状のも
のであることもできる。The natural fragrances listed in Table 4 above can also be in the form of absolute, concrete, resinoid and the like.
【0028】さらに、上記香料以外に本発明の調合素材
として使用することのできる(A)トップノート成分、
(B)ミドルノート成分、(C)ベースノート成分の合
成香料、(D)ミックスノートである天然香料の例を下
記表5〜8に示した。表−5〜8に記載される合成香
料、天然香料を香り別に適宜に選択して、請求項5〜8
に記載のそれぞれの群に記載される香料に代えるか、ま
たは添加して所望する香質乃至香気(シトラス、フルー
ティ、グリーン、フローラル、アルデヒド、スパイシ
ー、ウッディ、スイート、モッシー、ムスキー、アンバ
ー、アニマル、ハーバル、マリン、およびミントノート
など)を有する芳香・消臭組成物を調製することができ
る。Furthermore, in addition to the above-mentioned fragrances, (A) a top note component that can be used as a compounding material of the present invention,
Examples of (B) middle note component, (C) base note component synthetic fragrance, and (D) mixed note natural fragrance are shown in Tables 5 to 8 below. Synthetic flavors and natural flavors listed in Tables 5 to 8 are appropriately selected for each scent, and the fragrance is selected.
Substituted or added to the fragrance described in each group described in the desired fragrance or fragrance (citrus, fruity, green, floral, aldehyde, spicy, woody, sweet, mossy, musky, amber, animal, Fragrance and deodorant compositions having herbal, marine and mint notes can be prepared.
【0029】表−5(A)トップノート
アセトアルデヒド、アセトアルデヒドジエチルアセター
ル、アセトアルデヒドエチルヘキシルアセタール、アセ
トアルデヒドエチルシス−3−ヘキセニルアセタール、
アセトイン、3−アセチル−2,5−ジメチルフラン、
2−アセチルフラン、アセチルイソバレリル、2−アセ
チル−5−メチルフラン、2−アセチルピリジン、3−
アセチルピリジン、2−アセチルピロール、ヘプタナー
ルジメチルアセタール、アロオシメン、アロオシメノー
ル、アニソール、p−アリルアニソール、安息香酸アリ
ル、2−エチル酪酸アリル、イソチオシアン酸アリル、
イソ酪酸メチル、イソ吉草酸アリル、アリルメルカプタ
ン、アリルスルフィド、イソアミルメルカプタン、ギ酸
リナリル、ギ酸アミル、酪酸アミル、吉草酸アミル、酢
酸ブチル、ギ酸ブチル、イソ酪酸ブチル、イソ吉草酸ブ
チル、δ−3−カレン、2,6−ノナジエナール、ジア
セチル、ジアリルジスルフィド、ジアリルスルフィド、
ジブチルスルフィド、マロン酸ジエチル、ジメチルジス
ルフィド、2,6−ジメチル−5−ヘプテン−1−アー
ル、ジメチルビニルカルビノール、2,6−ジメチルヘ
プタン−2−オール<Dimetol:Dragoco>、ジペンテ
ン、3−ヒドロキシヘキサン酸エチル、アクリル酸エチ
ル、デカン酸エチル、クロトン酸エチル、ギ酸エチル、
フランカルボン酸エチル、トランス−2−ヘキセン酸エ
チル、トランス−3−ヘキセン酸エチル、2−ヘキシル
アセト酢酸エチル、3−ヒドロキシ酪酸エチル、5−エ
チル−3−ヒドロキシ−4−メチル2[5H]−フラノ
ン、エチルイソアミルケトン、乳酸エチル、2−メチル
吉草酸エチル、ピルビン酸エチル、チグリン酸エチル、
吉草酸エチル、ヘプタン酸エチル、フルフラール、フル
フラールアセトン、酢酸フルフリル、フルフリルアルコ
ール、フルフリルアクロレイン、2−フリリデンアセト
ン、ヘプタナールジメチルアセタール、2,3−ヘプタ
ンジオン、1−ヘプタノール、2−ヘプタノール、3−
ヘプタノール、2−ヘプタノン、3−ヘプタノン、4−
ヘプタノン、4−ヘプタナール、トランス−2−ヘプテ
ナール、3−ヘプテン−2−オン、2,4−ヘキサジエ
ナール、3−ヘキサンノン、シス−3−ヘキセナール、
ヘキサン酸シス−3−ヘキセニル、ヘキサン酸トランス
−2−ヘキセニル、乳酸シス−3−ヘキセニル、2−メ
チル酪酸シス3−ヘキセニル、プロピオン酸トランス−
2−ヘキセニル、プロピオン酸シス−3−ヘキセニル、
シス−4−ヘキセノール、トランス−2−ヘキセノー
ル、イソ酪酸ヘキシル、プロピオン酸ヘキシル、3−ヒ
ドロキシ−2−ブタノン、5−ヒドロキシ−4−オクタ
ノン、ヘキサナールジメチルアセタール、2,3−ヘキ
サンジオン、3,4−ヘキサンジオン、ギ酸イソアミ
ル、クロトン酸イソブチル、2−フランプロピオン酸イ
ソブチル、ヘキサン酸イソブチル、イソ酪酸イソブチ
ル、イソ吉草酸イソブチル、酢酸イソプロピル、酪酸イ
ソプロピル、ヘキサン酸イソプロピル、イソ酪酸イソプ
ロピル、イソ吉草酸イソプロピル、イソプロピルメルカ
プタン、酢酸イソプレギル、イソ吉草酸、メントフラ
ン、1−(p−メンテン−6−イル)−1−プロパノ
ン、酢酸メチル、3−メチル−2−ブテン−1−オー
ル、2−メチルブタナール、酢酸2−メチルブチル、メ
チルベンジルエーテル、シクロオクチルカルボン酸メチ
ル<Jasmacyclat:Henkel>、メチルシクロペンテノロ
ン、メチルシクロペンチリデンアセトン、5−メチルフ
ルフラール、2−フランカルボン酸メチル、メチルα−
フリルケトン、メチルヘプタノン、5−メチル−3−ヘ
プタノンオキシム、5−メチル−2,3−ヘキサンジオ
ン、ヘキサン酸メチル、トランス−2−ヘキセン酸メチ
ル、トランス−3−ヘキセン酸メチル、メチルヘキシル
エーテル、イソヘキサン酸メチル、メチルイソプロピル
ケトン、乳酸メチル、ノナン酸メチル、3−メチル−1
−ペンタノール、4−メチル−3−ペンテン−2−オ
ン、吉草酸メチル、ミルテナール、ミルテノール、2,
4−ノナジエナール、2,6−ノナジエノール、シス−
6−ノネノール、トランス−2−ノネノール、オシメン
エポキサイド、オシメノール、3−オクタノン、2,3
−ペンタンジオン、2−ペンタノン、トランス−2−ペ
ンテナール、α−フェランドレン、フェノキシアセトア
ルデヒド、2−(2−ピネン−10−イル−メチル)ピ
リジン、4−(2−ピネン−10−イル−メチル)ピリ
ジン、ピペリジン、アンゲリカ酸プレニル、安息香酸プ
レニル、プロピオフェノン、酢酸プロピル、酪酸プロピ
ル、ギ酸プロピル、2−フランアクリル酸プロピル、ヘ
キサン酸プロピル、イソ酪酸プロピル、イソ吉草酸プロ
ピル、プロピオン酸プロピル、ローズフラン、酢酸テト
ラヒドロフルフリル、3−チオフェンカルボキシアルデ
ヒド、チグリン酸、2,5,6−トリメチル−4−ヘプ
テナール、3,5,5−トリメチルヘキサナール、トリ
チオアセトン、吉草酸など。*以上表−5中、化合物名
の後の< >内は主な商品名とそのメーカー名を示す。 Table 5 (A) Top notes Acetaldehyde, acetaldehyde diethyl acetal, acetaldehyde ethylhexyl acetal, acetaldehyde ethyl cis-3-hexenyl acetal,
Acetoin, 3-acetyl-2,5-dimethylfuran,
2-acetylfuran, acetylisovaleryl, 2-acetyl-5-methylfuran, 2-acetylpyridine, 3-
Acetyl pyridine, 2-acetylpyrrole, heptanal dimethyl acetal, alloocimene, alloocimenol, anisole, p-allylanisole, allyl benzoate, allyl 2-ethylbutyrate, allyl isothiocyanate,
Methyl isobutyrate, allyl isovalerate, allyl mercaptan, allyl sulfide, isoamyl mercaptan, linalyl formate, amyl formate, amyl butyrate, amyl valerate, butyl acetate, butyl formate, butyl isobutyrate, butyl isovalerate, δ-3- Karen, 2,6-nonadienal, diacetyl, diallyl disulfide, diallyl sulfide,
Dibutyl sulfide, diethyl malonate, dimethyl disulfide, 2,6-dimethyl-5-hepten-1-al, dimethyl vinyl carbinol, 2,6-dimethyl heptan-2-ol <Dimetol: Dragoco>, dipentene, 3-hydroxy Ethyl hexanoate, ethyl acrylate, ethyl decanoate, ethyl crotonate, ethyl formate,
Ethyl furancarboxylate, ethyl trans-2-hexenoate, ethyl trans-3-hexenoate, ethyl 2-hexylacetoacetate, ethyl 3-hydroxybutyrate, 5-ethyl-3-hydroxy-4-methyl 2 [5H]- Furanone, ethyl isoamyl ketone, ethyl lactate, ethyl 2-methylvalerate, ethyl pyruvate, ethyl tiglate,
Ethyl valerate, ethyl heptanoate, furfural, furfural acetone, furfuryl acetate, furfuryl alcohol, furfuryl acrolein, 2-furylidene acetone, heptanal dimethyl acetal, 2,3-heptanedione, 1-heptanol, 2-heptanol, 3-
Heptanol, 2-heptanone, 3-heptanone, 4-
Heptanone, 4-heptanal, trans-2-heptenal, 3-hepten-2-one, 2,4-hexadienal, 3-hexanenon, cis-3-hexenal,
Hexanoic acid cis-3-hexenyl, hexanoic acid trans-2-hexenyl, lactate cis-3-hexenyl, 2-methylbutyric acid cis-3-hexenyl, propionate trans-
2-hexenyl, cis-3-hexenyl propionate,
Cis-4-hexenol, trans-2-hexenol, hexyl isobutyrate, hexyl propionate, 3-hydroxy-2-butanone, 5-hydroxy-4-octanone, hexanal dimethyl acetal, 2,3-hexanedione, 3,4 -Hexanedione, isoamyl formate, isobutyl crotonic acid, isobutyl 2-furanpropionate, isobutyl hexanoate, isobutyl isobutyrate, isobutyl isovalerate, isopropyl acetate, isopropyl butyrate, isopropyl hexanoate, isopropyl isobutyrate, isopropyl isovalerate, Isopropyl mercaptan, isopregyl acetate, isovaleric acid, mentofuran, 1- (p-menthen-6-yl) -1-propanone, methyl acetate, 3-methyl-2-buten-1-ol, 2-methylbutanal, Acetic acid 2-methylbutyl, methylbenzyl ether, methyl cyclooctylcarboxylate <Jasmacyclat: Henkel>, methylcyclopentenolone, methylcyclopentylideneacetone, 5-methylfurfural, methyl 2-furancarboxylate, methyl α-
Furyl ketone, methylheptanone, 5-methyl-3-heptanone oxime, 5-methyl-2,3-hexanedione, methyl hexanoate, methyl trans-2-hexenoate, methyl trans-3-hexenoate, methylhexyl ether , Methyl isohexanoate, methyl isopropyl ketone, methyl lactate, methyl nonanoate, 3-methyl-1
-Pentanol, 4-methyl-3-penten-2-one, methyl valerate, myrtenal, myrtenol, 2,
4-nonadienal, 2,6-nonadienol, cis-
6-nonenol, trans-2-nonenol, ocimene epoxide, ocimenol, 3-octanone, 2,3
-Pentanedione, 2-pentanone, trans-2-pentenal, α-ferrandrene, phenoxyacetaldehyde, 2- (2-pinen-10-yl-methyl) pyridine, 4- (2-pinen-10-yl-methyl) Pyridine, piperidine, prenyl angelica, prenyl benzoate, propiophenone, propyl acetate, propyl butyrate, propyl formate, propyl 2-furanacrylate, propyl hexanoate, propyl isobutyrate, propyl isovalerate, propyl propionate, rose Furan, tetrahydrofurfuryl acetate, 3-thiophene carboxaldehyde, tiglic acid, 2,5,6-trimethyl-4-heptenal, 3,5,5-trimethylhexanal, trithioacetone, valeric acid and the like. * In Table 5 above, the main product name and its manufacturer name are shown in <> after the compound name.
【0030】表−6(B)ミドルノート
アセトアルデヒドエチルイソオイゲニルアセタール、ア
セトアルデヒドエチルフェネチルアセタール、アセトア
ルデヒドフェネチル n−プロピルアセタール、アセト
ケタール、2’−アセトナフトン、シス−2−アセトニ
ル−4−メチルテトラヒドロピラン、アセトフェノンネ
オペンチルグリコールケタール、1−アセトキシ−2−
sec.−ブチル−1−ビニルシクロヘキサン、1−ア
セチル−3,3−ジメチル−1−シクロヘキセン、2−
アセチル−3,3−ジメチルノルボルナン、アセチルジ
メチルテトラヒドロベンズインダン、アセチルオイゲノ
ール、酢酸2−tert.−ブチルシクロヘキシル、ノ
ナナールジエチルアセタール、ヘキサナールP.G.ア
セタール、オクタン酸アリル、p−メチル−β−フェニ
ルグリシド酸エチル、2−n−ヘプチルシクロヘプタノ
ン、アリルシンナメート、シクロヘキシル酢酸アリル、
シクロヘキシルプロピオン酸アリル、ヘプタン酸アリ
ル、オクタン酸アリル、p−アリルフェノール、アリル
フェネチルエーテル、4,7−ジヒドロ−2−イソペン
チル−2−メチル−1,3−ジオキセピン、1−(2,
2,6−トリメチルシクロヘキシル)−4−ヘキサノー
ル、アミルカプロエート、オクタン酸アミル、アミルシ
クロペンタノン、2−アミルピリジン、α−アンゲリカ
ラクトン、アニシリデンアセトン、ギ酸α、3,3−ト
リメチルシクロヘキサンメチル、ベンズアルデヒドジメ
チルアセタール、ベンジルシアナイド、ギ酸ベンジル、
ヘキサン酸ベンジル、2−メチルブチル酪酸ベンジル、
吉草酸ベンジル、α−メチレンシトロネラール、酢酸ミ
ルセニル、プロピオン酸l−ボルニル、β−ブロモスチ
レン、ブチリル乳酸ブチル、o−sec.−ブチルシク
ロヘキサノン、o−tert.−ブチルシクロヘキサノ
ン、p−tert.−ブチルシクロヘキサノン、2−ブ
チル−1,4−ジオキサスピロ[4,4]ノナン、ヘキ
サン酸ブチル、ブチリデンアセトン、tert.−ブチ
ルヒドロキノンジメチルエーテル、乳酸n−ブチル、レ
ブリン酸ブチル、オクタン酸n−ブチル、ブチルスルフ
ィド、2−ブチル−4,4,6−トリメチル−1,3−
ジオキサン、γ−ブチロラクトン、2−メチル−6−ペ
ンチル−4−オキソシクロヘクス−2−エンカルボン酸
エチル、α,3,3−トリメチル−2−ノルボルナン−
2−メタノール、α−カンホレニックアルデヒド、カン
ファー、カルバクロール、カルベオール、酢酸カルビ
ル、プロピオン酸l−カルビル、チャビコール、シトラ
ールジメチルアセタール、シトラールP.G.アセター
ル、シトロネラールシクロモノグリコールアセタール、
シトロネラールE.G.アセタール、シトロネリルエチ
ルエーテル、ヘキサン酸シトロネリル、イソ酪酸シトロ
ネリル、イソ吉草酸シトロネリル、シトロネリルメチル
アセタール、シトロネリルオキシアセトアルデヒド、酢
酸シトリル、2,2−ジメチル−5−(1−メチル−1
−プロペニル)−テトラヒドロフラン、酢酸o−ter
t.−アミルシクロヘキシル、イソ酪酸p−クレジル、
4−イソプロピル−2−シクロヘキサノン、クミンアル
デヒド、クミンアルコール、酢酸クミニル、クミニルニ
トリル、p−イソプロピル−α−メチルヒドロシンナム
アルデヒド、シクロヘキシルオキシ酢酸アリル、酢酸1
−シクロヘキセ−1−エンイソプロピル、2−(1−シ
クロヘキセン−1−イル)シクロヘキサノン、クロトン
酸シクロヘキシル、酢酸シクロヘキシルエチル、シクロ
ヘキシルエチルアルコール、イソ吉草酸シクロヘキシ
ル、シクロヘキシルラクトン、4−シクロヘキシル−4
−メチル−2−ペンタノン、2,4−デカジエノール、
デカヒドロ−β−ナフトール、酢酸トランス−デカヒド
ロ−β−ナフチル、ギ酸デカヒドロ−β−ナフチル、イ
ソ酪酸トランス−デカヒドロ−β−ナフチル、デカナー
ルジエチルアセタール、デカナールジメチルアセター
ル、デカン酸、1−デカノール、トランス−2−デセン
−1−アール、シス−4−デセナール、トランス−4−
デセナール、2−デセン酸、酢酸9−デセニル、プロピ
オン酸9−デセニル、酢酸デセニル、デシルメチルエー
テル、デシルビニルエーテル、コハク酸ジエチル、ジヒ
ドロカルボン、ジヒドロシトロネロール、アジピン酸ジ
エチル、酢酸ジヒドロクミニル、ジヒドロオイゲノー
ル、ジヒドロジャスモン、ジヒドロミルセン、酢酸ジヒ
ドロテルピニル、ジヒドロ−α−ターピネオール、3,
4−ジメトキシベンズアルデヒド、1,2−ジメトキシ
ベンゼン、m−ジメトキシベンゼン、2,6−ジメトキ
シフェノール、2,4−ジメチル−4,4a、5,9b
−テトラヒドロインデノ[1,2d]−1,3−ジオキ
シン、酢酸2,4−ジメチルベンジル、p,α−ジメチ
ルベンジルアルコール、イソ酪酸1,3−ジメチル−3
−ブテニル、2,4−ジメチル−3−シクロヘキセン−
1−メタノール、γ、4−ジメチル−3−シクロヘキセ
ン−1−プロパノール、酢酸2,4−ジメチル−3−シ
クロヘキセニルメチル、3,3−ジメチルシクロヘキシ
ルメチルケトン、3,4−ジメチル−1,2−シクロペ
ンタンジオン、3,5−ジメチル−1,2−シクロペン
タンジオン、5,9−ジメチル−4,9−デカジエナー
ル、3,7−ジメチル−7−メトキシオクタン−2−オ
ール、3,7−ジメチル−2,6−ノナジエノニトリ
ル、6,8−ジメチル−2−ノナノール、2−(3,3
−ジメチルビシクロ[2.2.1]ヘプト−2−イリデ
ン)−エタノール、3,7−ジメチル−1−オクタナー
ル、3,6−ジメチルオクタン−3−オール、ジメチル
オクテノン、α,α−ジメチルフェネチルアルコール、
フタル酸ジメチル、コハク酸ジメチル、ジメチルトリス
ルフィド、酢酸6,10−ジメチル−5,9−ウンデカ
ジエン−2−イル、2−ヒドロキシ−6−イソプロピル
−3−メチル−2−シクロヘキサノン、2,4−ジオキ
サ−3−メチル−7,10−メタノスピロ[5.5]−
ウンデカン、ジプロピルジスルフィド、ジチオスピロフ
ラン、2,4−ドデカジエナール、ドデカンニトリル、
1−ドデカノール、3−ドデセナール、トランス−2−
ドデセナール、酢酸ドデシル、酢酸トリシクロデシル、
p−エチルフェノール、エチレングリコールモノブチル
エーテルアセテート、アセト酢酸エチルE.G.ケター
ル、アセト酢酸エチルP.G.1,2−ケタール、2−
ベンジルアセト酢酸エチル、2−tert.−ブチルシ
クロヘキシルカルボン酸エチル、シクロゲラン酸エチ
ル、デカジエン酸エチル、デカン酸エチル、2−デセン
酸エチル、デヒドロシクロゲラン酸エチル、3−エチル
−8(9),11−ジメチル−2,4−ジオキサスピロ
−[5.5]ウンデセ−8−エン、3−エチル−2,4
−ジオキサスピロ[5.5]−ウンデセ−8−エン、ド
デカン酸エチル、E.G.ジアセテート、E.G.モノ
ブチルエーテル、ゲラン酸エチル、4−エチルグアイア
コール、ヘプチンカルボン酸エチル、3−ヒドロキシ−
3−フェニルプロピオン酸エチル、エチルイソオイゲノ
ール、アセトアルデヒドエチルリナリルアセタール、酢
酸エチルリナリル、o−メトキシ安息香酸エチル、エチ
ル2−メトキシベンジルエーテル、オクタン酸エチル、
2−オクテン酸エチル、オクチンカルボン酸エチル、フ
ェニル酢酸エチル、3−フェニルプロピオン酸エチル、
3,5,5−トリメチルヘキサン酸エチル、ギ酸オイゲ
ニル、ホルムアルデヒドシクロドデシルエチルアセター
ル、ホルムアルデヒド(インダン−1−オール−2−ヒ
ドロキシメチル)アセタール、ホルミルエチルテトラメ
チルテトラリン、4(5)ホルミル−7,7,9(7,
7,9)−トリメチルビシクロ[4.3.0]−1−ノ
ネン、ゲラン酸、ゲラニルエチルエーテル、ジンゲロー
ル、n−ヘプタナールE.G.アセタール、ヘプタン
酸、2−n−ヘプチルシクロペンタノン、2−n−ヘプ
チルテトラヒドロフラン、吉草酸α−フルフリル、酢酸
1−エチニルシクロヘキシル、イソ酪酸2,4−ヘキサ
ジエニル、2,4−ヘキサジエン−1−オール、ヘキサ
ナールP.G.アセタール、ヘキサン酸、シス−3−ヘ
キセナールジエチルアセタール、トランス−2−ヘキセ
ナールジエチルアセタール、アンゲリカ酸シス−3−ヘ
キセニル、ヘキサン酸シス−3−ヘキセニル、チグリン
酸シス−3−ヘキセニル、吉草酸シス−3−ヘキセニ
ル、イソ酪酸シス−3−ヘキセニル、2−ヘキシルシク
ロペンタノン、ヘキサン酸ヘキシル、2−メチル酪酸ヘ
キシル、2−ヘキシル−5−メチル−1,3−ジオキソ
ラン、チグリン酸ヘキシル、ホモフラネオール、ホモマ
イラックアルデヒド、ヒドラトロピックアルコール、酢
酸ヒドラトロピル、ハイドロキノンジメチルエーテル、
ヒドロキシシトロネラールジエチルアセタール、5−
(ヒドロキシメチル)−2−フルフラール、3−ヒドロ
キシメチル−2−ノナノン、ヘプチンカルボン酸イソア
ミル、レブリン酸イソアミル、イソボルニルメチルエー
テル、アンゲリカ酸イソブチル、イソブチルベンジルカ
ルビノール、2−イソブチル−4−ヒドロキシ−4−メ
チルテトラヒドロピラン、p−イソブチル−α−メチル
ヒドロシンナミックアルデヒド、α−イソブチルフェネ
チルアルコール、フェニル酢酸イソブチル、プロピオン
酸イソブチル、2−イソブチルピリジン、3−イソブチ
ルピリジン、サリチル酸イソブチル、イソシクロゲラニ
オール、イソジヒドロラバンジュロール、酢酸イソジヒ
ドロラバンジュリル、イソノニルアルコール、5−イソ
プロペニル−メチル−2−ビニルテトラヒドロフラン、
4−イソプロピルベンズアルデヒド、安息香酸イソプロ
ピル、シス−p−イソプロピルシクロヘキシルメタノー
ル、デカン酸イソプロピル、p−イソプロピルハイドラ
トロピックアルデヒド、p−イソプロピルハイドロトロ
ピックアルデヒド、4−イソプロピル−1−メチル−2
−プロペニルベンゼン、フェニル酢酸イソプロピル、2
−エチリデン−6−イソプロポキシビシクロ[2.2.
1]ヘプタン、イソキノリン、イソサフロール、4,7
−ジヒドロ−2−(3−ペンタニル)−1,3−ジオキ
セピン、リモネンチオール、酪酸リナリル、ヘキサン酸
リナリル、イソ酪酸リナリル、イソ吉草酸リナリル、オ
クタン酸リナリル、プロピオン酸リナリル、メンタラク
トン、酢酸メンタニル、イソ吉草酸メンチル、プロピオ
ン酸メンチル、メルカプト酢酸、メシチルオキサイド、
p−メトキシアセトフェノン、o−メトキシベンズルデ
ヒド、p−メトキシベンズアルデヒド、o−メトキシシ
ンナムアルデヒド、メトキシシトロネラール、メトキシ
ジシクロペンタジエンカルボキサアルデヒド、p−メト
キシフェニルアセトン、4(4−メトキシフェニル)−
3−ブタン−2−オン、2−メトキシ−2−フェネチル
アルコール、1−(4−メトキシフェニル)−1−ペン
テン−3−オン、アンゲリカ酸メチル、α−メチルアニ
サールアセトン、p−メチルアニソール、2−メチルベ
ンズオキサゾール、2−メチル−2−ブテニルフェネチ
ルエーテル、1−メチルシクロドデシルメチルエーテ
ル、4−(4−メチル−3−シクロヘキセン−1−イリ
デン)−ペンタナール、メチルデカナール、デカン酸メ
チル、4−メチル−3−デセン−5−オール、デシンカ
ルボン酸メチル、7−メチル−3,5−ジヒドロ−2H
−ベンゾジオキセピン、ドデカン酸メチル、α−メチレ
ンシトロネラール、4−メチレン−3,5,6,6−テ
トラメチル−2−ヘプタノン、ゲラン酸メチル、4−メ
チルグアヤコール、6−メチル−3,5−ヘプタジエン
−2−オン、2−メチルヘプタン酸、p−メチルヒドラ
トロピックアルデヒド、β−メチルヒドロシンナミック
アルデヒド、ヒドロキシヘキサン酸メチル、p−メチル
イソプロピルベンゼン、o−メトキシ安息香酸メチル、
1−メチル−3−シクロヘキセンカルボン酸メチル、7
−メチル−3−メチレン−1,6−オクタジエン、1−
メチル−4−(4−メチル−3−ペンテニル)−3−シ
クロヘキセン−1−カルボキシアルデヒド、2−メチル
吉草酸2−メチルペンチル、2−メチル−3−(4−メ
チルフェニル)プロパナール、2−メチル−5−(メチ
ルチオ)フラン、3−(メチルチオ)プロピオン酸メチ
ル、ニコチン酸メチル、メチルチオ酢酸メチル、ニコチ
ン酸メチル、ノナン酸メチル、2−ノネン酸メチル、3
−ノネン酸メチル、メチルノニルアセトアルデヒドジメ
チルアセタール、2−メチルオクタナール、オクタン酸
メチル、オクチンカルボン酸メチル、4−メチルペンタ
ン酸、トランス−2−メチル−2−ペンテン酸、アンゲ
リカ酸3−メチルペンチル、p−メチルフェノキシアセ
トアルデヒド、p−メチルフェニルアセトアルデヒド、
3−メチル−4−フェニル−3−ブテン−2−オン、酢
酸β−メチル−β−フェネチル、メチルβ−フェネチル
アルコール、メチルフェネチルエーテル、5−メチル−
2−フェニル−2−ヘキサノール、3−メチル−1−フ
ェニル−3−プロパナ−ル、3−メチル−5−フェニル
ペンタノール、4−メチル−4−フェニル−2−ペンタ
ノン、4−メチル−2−フェニル−2−ペンテナール、
3−メチル−5−フェニルバレルアルデヒド、3−メチ
ル−5−プロピル−2−シクロヘキセン−1−オン、5
−メチル−5−プロピル−2−(1−メチルブチル)−
1,3−ジオキサン、2−メチル−4−プロピル−1,
3−オキサチアン、メチルプロピルジスルフィド、メチ
ルプロピルトリスルフィド、1−メチルピロール、p−
メチルキノリン、5−メチルキノキサリン、メチルテト
ラヒドロフラノン、9−ウンデセン酸メチル、メントラ
クトン、ミュゲットアルコール、酢酸ミラルディル、ア
ンゲリカ酸ブチル、ギ酸ネリル、プロピオン酸ネリル、
ノナナールジメチルアセタール、ノナンジオール−1,
3−ジアセテート、ノナン酸、1−ノナノール、2−ノ
ナノール、2−ノナノン、3−ノナノン、1−ノネン−
3−オ−ル、シス−6−ノネノール、ノニルアルコー
ル、sec.−ノニルアルコール、ノポール、酢酸オシ
メニル、2,4−オクタジエナール、オクタヒドロ−
4,7−メタノ−1H−インデンカルボキシアルデヒ
ド、オクタナールジエチルアセタール、オクタン酸、酢
酸3−オクチル、オクチルアルコール、sec.−オク
チルアルコール、酪酸オクチル、ギ酸オクチル、イソ酪
酸オクチル、イソ吉草酸オクチル、4−オキソイソホロ
ン、ギ酸オキシオクタリン、ノナン酸3,4,5,6,
6−ペンタメチル−2−ヘプタノール、フェニルアセト
アルデヒドE.G.アセタール、フェニルアセトアルデ
ヒドグリセンリアセタール、4−ペンテン酸,2−ペン
チル−2−シクロペンテン−1−オン、2−ペンチルピ
リジン、ペリラアルコール、酢酸ペリリル、フェノキシ
エチルアルコール、2−アンゲリカ酸2−フェネチル、
ギ酸2−フェネチル、2−メチル酪酸2−フェネチル、
5−フェニル−5−メチル−3−ヘキサノン、3−フェ
ニルプロピオンアルデヒド、3−フェニルプロピオンア
ルデヒドジメチルアセタール、プロピオン酸3−フェニ
ルプロピル、4−メチルトリシクロ[6.2.1.
02,7]ウンデカン−5−オン、5−プロペニルグエ
トール、安息香酸プロピル、3−プロピルビシクロ
[2.2.1]ヘプト−5−エン−2−カルボキシアル
デヒド、P.G.ジブチレート、P.G.ジプロピオネ
ート、ヘプタン酸プロピル、オクタン酸プロピル、α−
プロピルフェネチルアルコール、フェニル酢酸プロピ
ル、トランス−2、シス−4−デカジエン酸プロピル、
プソイドイオノン、キノリン、酪酸ロジニル、ギ酸ロジ
ニル、プロピオン酸ロジニル、サビネンヒドレート、サ
フラナール、サフロール、サリチルアルデヒド、3−ヒ
ドロキシ−4,5−ジメチル−2(5H)−フラノン、
イソ酪酸スチラリル、プロピオン酸スチラリル、スチロ
リルジアセテート、スチリルシアニド、ギ酸テルペニ
ル、α−テルペニルメチルエーテル、テトラヒドロシト
ラール、酪酸テトラヒドロフルフリル、酢酸テトラヒド
ロリナリル、テトラヒドロピロール、2,2,5,5−
テトラメチル−4−イソプロピル−1,3−ジオキサ
ン、3−ツヤノール、4−ツヤノール、β−ツヤプリシ
ン、チモール、テアスピラン、p−トリルアルデヒド、
トリアセチン、イソ酪酸トリシクロデセニル、トリシク
ロデセニルメチルエーテル、トリデカナール、2−トリ
デカノン、トランス−2−トリデカノール、トリデセン
−2−ニトリル、4−(2,2,6−トリメチル−2
(1)−シクロヘキセン)−2−メチルブタナール、
2,6,6−トリメチル−2−シクロヘキセン−1,4
−ジオン、2,3,5−トリメチル−2−シクロヘキセ
ン−4−イル−1−メチルケトン、3,3,5−トリメ
チルシクロヘキシルエチルエーテル、トリメチルデカジ
エナール、2,4,6−トリメチル−4,5−ジヒドロ
−1,3,5−ジチアン、9−エチリデン−3−オキサ
トリシクロ[6.2.1.02, 7]ウンデカン、酢
酸α,3,3−トリメチルシクロヘキサン−1−メチ
ル、2,2,5−トリメチル−5−ペンチルシクロペン
タノン、2,5,5−トリメチル−2−フェニル−1,
3−ジオキサン、α,α,p−トリメチルフェネチルア
ルコール、4,6,6(4,4,6)−トリメチルテト
ラヒドロピラン−2−オン、2,6,10−トリメチル
−5,9−ウンデカジエナール、トリメチルウンデカナ
ール、2,4−ウンデカジエナール、ウンデカナール、
2−ウンデカノール、2−ウンデカノン、1,3,5−
ウンデカトリエン、10−ウンデセン−1−オール、ウ
ンデシルアルコール、ウンデシレン酸、sec.−ウン
デシリックアルコール、バレンセン、γ−バレロラクト
ン、4,6,6−トリメチル(1R)−ビシクロ[3.
1.1]ヘプト−3−エン−2−オン、酢酸4−メチル
−4−フェニル−2−ペンチル、3−メチル−4−オク
タノリドなど。
*以上表−6中、化合物名の後の( )内は主な商品
名とそのメーカー名を示す。また、同じく表中でE.
G.は、Ethylene glycol、P.G.
は、Propylene Glycolを示す。 Table 6 (B) Middle note Acetaldehyde ethyl isoeugenyl acetal, acetaldehyde ethylphenethyl acetal, acetaldehyde phenethyl n-propyl acetal, acetoketal, 2'-acetonaphthone, cis-2-acetonyl-4-methyltetrahydropyran, acetophenone Neopentyl glycol ketal, 1-acetoxy-2-
sec. -Butyl-1-vinylcyclohexane, 1-acetyl-3,3-dimethyl-1-cyclohexene, 2-
Acetyl-3,3-dimethylnorbornane, acetyldimethyltetrahydrobenzindane, acetyleugenol, acetic acid 2-tert. -Butylcyclohexyl, nonanal diethyl acetal, hexanal P.I. G. Acetal, allyl octanoate, ethyl p-methyl-β-phenylglycidate, 2-n-heptylcycloheptanone, allyl cinnamate, allyl cyclohexyl acetate,
Allyl cyclohexylpropionate, allyl heptanoate, allyl octanoate, p-allylphenol, allylphenethyl ether, 4,7-dihydro-2-isopentyl-2-methyl-1,3-dioxepin, 1- (2,
2,6-Trimethylcyclohexyl) -4-hexanol, amyl caproate, amyl octanoate, amyl cyclopentanone, 2-amyl pyridine, α-angelica lactone, anisylidene acetone, formic acid α, 3,3-trimethylcyclohexanemethyl , Benzaldehyde dimethyl acetal, benzyl cyanide, benzyl formate,
Benzyl hexanoate, benzyl 2-methylbutylbutyrate,
Benzyl valerate, α-methylene citronellal, myrcenyl acetate, 1-bornyl propionate, β-bromostyrene, butyl butyryl lactate, o-sec. -Butylcyclohexanone, o-tert. -Butylcyclohexanone, p-tert. -Butylcyclohexanone, 2-butyl-1,4-dioxaspiro [4,4] nonane, butyl hexanoate, butylideneacetone, tert. -Butylhydroquinone dimethyl ether, n-butyl lactate, butyl levulinate, n-butyl octanoate, butyl sulfide, 2-butyl-4,4,6-trimethyl-1,3-
Dioxane, γ-butyrolactone, ethyl 2-methyl-6-pentyl-4-oxocyclohex-2-enecarboxylate, α, 3,3-trimethyl-2-norbornane-
2-methanol, α-camphorenic aldehyde, camphor, carvacrol, carveol, carbyl acetate, 1-carbyl propionate, cavicol, citral dimethyl acetal, citral P.I. G. Acetal, citronellal cyclomonoglycol acetal,
Citronellal E. G. Acetal, citronellyl ethyl ether, citronellyl hexanoate, citronellyl isobutyrate, citronellyl isovalerate, citronellyl methyl acetal, citronellyl oxyacetaldehyde, citryl acetate, 2,2-dimethyl-5- (1-methyl-1)
-Propenyl) -tetrahydrofuran, acetic acid o-ter
t. -Amylcyclohexyl, p-cresyl isobutyrate,
4-isopropyl-2-cyclohexanone, cumin aldehyde, cumin alcohol, cuminyl acetate, cuminyl nitrile, p-isopropyl-α-methylhydrocinnamaldehyde, cyclohexyloxyacetate allyl, acetic acid 1
-Cyclohex-1-eneisopropyl, 2- (1-cyclohexen-1-yl) cyclohexanone, cyclohexyl crotonic acid, cyclohexylethyl acetate, cyclohexylethyl alcohol, cyclohexyl isovalerate, cyclohexyllactone, 4-cyclohexyl-4
-Methyl-2-pentanone, 2,4-decadienol,
Decahydro-β-naphthol, trans-decahydro-β-naphthyl acetate, decahydro-β-naphthyl formate, trans-decahydro-β-naphthyl isobutyrate, decanal diethyl acetal, decanal dimethyl acetal, decanoic acid, 1-decanol, trans -2-decene-1-al, cis-4-decenal, trans-4-
Decenal, 2-decenoic acid, 9-decenyl acetate, 9-decenyl propionate, decenyl acetate, decyl methyl ether, decyl vinyl ether, diethyl succinate, dihydrocarbon, dihydrocitronellol, diethyl adipate, dihydrocuminyl acetate, dihydroeugenol, Dihydrojasmon, dihydromyrcene, dihydroterpinyl acetate, dihydro-α-terpineol, 3,
4-dimethoxybenzaldehyde, 1,2-dimethoxybenzene, m-dimethoxybenzene, 2,6-dimethoxyphenol, 2,4-dimethyl-4,4a, 5,9b
-Tetrahydroindeno [1,2d] -1,3-dioxin, 2,4-dimethylbenzyl acetate, p, α-dimethylbenzyl alcohol, 1,3-dimethyl-3 isobutyrate.
-Butenyl, 2,4-dimethyl-3-cyclohexene-
1-methanol, γ, 4-dimethyl-3-cyclohexene-1-propanol, 2,4-dimethyl-3-cyclohexenylmethyl acetate, 3,3-dimethylcyclohexyl methyl ketone, 3,4-dimethyl-1,2- Cyclopentanedione, 3,5-dimethyl-1,2-cyclopentanedione, 5,9-dimethyl-4,9-decadienal, 3,7-dimethyl-7-methoxyoctane-2-ol, 3,7-dimethyl -2,6-Nonadienonitrile, 6,8-dimethyl-2-nonanol, 2- (3,3
-Dimethylbicyclo [2.2.1] hept-2-ylidene) -ethanol, 3,7-dimethyl-1-octanal, 3,6-dimethyloctane-3-ol, dimethyloctenone, α, α-dimethylphenethyl alcohol,
Dimethyl phthalate, dimethyl succinate, dimethyl trisulfide, 6,10-dimethyl-5,9-undecadiene-2-yl acetate, 2-hydroxy-6-isopropyl-3-methyl-2-cyclohexanone, 2,4-dioxa -3-Methyl-7,10-methanospiro [5.5]-
Undecane, dipropyl disulfide, dithiospirofuran, 2,4-dodecadienal, dodecane nitrile,
1-dodecanol, 3-dodecenal, trans-2-
Dodecenal, dodecyl acetate, tricyclodecyl acetate,
p-ethylphenol, ethylene glycol monobutyl ether acetate, ethyl acetoacetate E.I. G. Ketal, ethyl acetoacetate P.I. G. 1,2-ketal, 2-
Ethyl benzylacetoacetate, 2-tert. -Ethyl butylcyclohexylcarboxylate, ethyl cyclogelanate, ethyl decadienoate, ethyl decanoate, ethyl 2-decenoate, ethyl dehydrocyclogeraneate, 3-ethyl-8 (9), 11-dimethyl-2,4-dioxaspiro- [5.5] Undece-8-ene, 3-ethyl-2,4
-Dioxaspiro [5.5] -undec-8-ene, ethyl dodecanoate, E.I. G. Diacetate, E. G. Monobutyl ether, ethyl gellanate, 4-ethylguaiacol, ethyl heptine carboxylate, 3-hydroxy-
Ethyl 3-phenylpropionate, ethyl isoeugenol, acetaldehyde ethyl linalyl acetal, ethyl linalyl acetate, ethyl o-methoxybenzoate, ethyl 2-methoxybenzyl ether, ethyl octanoate,
Ethyl 2-octenoate, ethyl octynecarboxylate, ethyl phenylacetate, ethyl 3-phenylpropionate,
Ethyl 3,5,5-trimethylhexanoate, eugenyl formate, formaldehyde cyclododecylethyl acetal, formaldehyde (indane-1-ol-2-hydroxymethyl) acetal, formylethyltetramethyltetralin, 4 (5) formyl-7,7 , 9 (7,
7,9) -Trimethylbicyclo [4.3.0] -1-nonene, gellan acid, geranyl ethyl ether, gingerol, n-heptanal E. G. Acetal, heptanoic acid, 2-n-heptylcyclopentanone, 2-n-heptyltetrahydrofuran, α-furfuryl valerate, 1-ethynylcyclohexyl acetate, 2,4-hexadienyl isobutyrate, 2,4-hexadiene-1-ol Hexanal P .; G. Acetal, hexanoic acid, cis-3-hexenal diethyl acetal, trans-2-hexenal diethyl acetal, cis-3-hexenyl angelic acid, cis-3-hexenyl hexanoate, cis-3-hexenyl tiglate, cis-3 valerate. -Hexenyl, cis-3-hexenyl isobutyrate, 2-hexylcyclopentanone, hexyl hexanoate, hexyl 2-methylbutyrate, 2-hexyl-5-methyl-1,3-dioxolane, hexyl tiglate, homofuraneol, Homomilac aldehyde, hydratropic alcohol, hydratropyl acetate, hydroquinone dimethyl ether,
Hydroxycitronellal diethyl acetal, 5-
(Hydroxymethyl) -2-furfural, 3-hydroxymethyl-2-nonanone, isoamyl heptine carboxylate, isoamyl levulinate, isobornyl methyl ether, isobutyl angelicaate, isobutylbenzylcarbinol, 2-isobutyl-4-hydroxy -4-methyltetrahydropyran, p-isobutyl-α-methylhydrocinnamic aldehyde, α-isobutylphenethyl alcohol, isobutyl phenylacetate, isobutyl propionate, 2-isobutylpyridine, 3-isobutylpyridine, isobutyl salicylate, isocyclogeraniol, Isodihydrolavandulol, isodihydrolavandryl acetate, isononyl alcohol, 5-isopropenyl-methyl-2-vinyltetrahydrofuran,
4-isopropylbenzaldehyde, isopropyl benzoate, cis-p-isopropylcyclohexylmethanol, isopropyl decanoate, p-isopropylhydrotropic aldehyde, p-isopropylhydrotropic aldehyde, 4-isopropyl-1-methyl-2
-Propenylbenzene, isopropyl phenylacetate, 2
-Ethylidene-6-isopropoxybicyclo [2.2.
1] Heptane, isoquinoline, isosaflor, 4,7
-Dihydro-2- (3-pentanyl) -1,3-dioxepin, limonenethiol, linalyl butyrate, linalyl hexanoate, linalyl isobutyrate, linalyl isovalerate, linalyl octanoate, linalyl propionate, mentalactone, menthanyl acetate, Menthyl isovalerate, menthyl propionate, mercaptoacetic acid, mesityl oxide,
p-methoxyacetophenone, o-methoxybenzaldehyde, p-methoxybenzaldehyde, o-methoxycinnamaldehyde, methoxycitronellal, methoxydicyclopentadienecarboxaldehyde, p-methoxyphenylacetone, 4 (4-methoxyphenyl)-
3-butan-2-one, 2-methoxy-2-phenethyl alcohol, 1- (4-methoxyphenyl) -1-penten-3-one, methyl angelica, α-methylanisalacetone, p-methylanisole, 2-methylbenzoxazole, 2-methyl-2-butenylphenethyl ether, 1-methylcyclododecylmethylether, 4- (4-methyl-3-cyclohexene-1-ylidene) -pentanal, methyldecanaal, methyl decanoate , 4-methyl-3-decen-5-ol, methyl decynecarboxylate, 7-methyl-3,5-dihydro-2H
-Benzodioxepin, methyl dodecanoate, α-methylene citronellal, 4-methylene-3,5,6,6-tetramethyl-2-heptanone, methyl gellanate, 4-methylguaiacol, 6-methyl-3 , 5-heptadien-2-one, 2-methylheptanoic acid, p-methylhydratropic aldehyde, β-methylhydrocinnamic aldehyde, methyl hydroxyhexanoate, p-methylisopropylbenzene, methyl o-methoxybenzoate,
Methyl 1-methyl-3-cyclohexenecarboxylate, 7
-Methyl-3-methylene-1,6-octadiene, 1-
Methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 2-methylpentyl 2-methylvalerate, 2-methyl-3- (4-methylphenyl) propanal, 2- Methyl-5- (methylthio) furan, methyl 3- (methylthio) propionate, methyl nicotinate, methyl methylthioacetate, methyl nicotinate, methyl nonanoate, methyl 2-nonenate, 3
-Methyl nonenate, methylnonylacetaldehyde dimethyl acetal, 2-methyloctanal, methyl octanoate, methyl octinecarboxylate, 4-methylpentanoic acid, trans-2-methyl-2-pentenoic acid, 3-methylpentyl angelic acid, p-methylphenoxyacetaldehyde, p-methylphenylacetaldehyde,
3-methyl-4-phenyl-3-buten-2-one, β-methyl-β-phenethyl acetate, methyl β-phenethyl alcohol, methylphenethyl ether, 5-methyl-
2-phenyl-2-hexanol, 3-methyl-1-phenyl-3-propanal, 3-methyl-5-phenylpentanol, 4-methyl-4-phenyl-2-pentanone, 4-methyl-2- Phenyl-2-pentenal,
3-methyl-5-phenylvaleraldehyde, 3-methyl-5-propyl-2-cyclohexen-1-one, 5
-Methyl-5-propyl-2- (1-methylbutyl)-
1,3-dioxane, 2-methyl-4-propyl-1,
3-oxathiane, methylpropyl disulfide, methylpropyl trisulfide, 1-methylpyrrole, p-
Methylquinoline, 5-methylquinoxaline, methyltetrahydrofuranone, methyl 9-undecenoate, menttolactone, muguet alcohol, miraldyl acetate, butyl angelicaate, neryl formate, neryl propionate,
Nonanal dimethyl acetal, nonanediol-1,
3-diacetate, nonanoic acid, 1-nonanol, 2-nonanol, 2-nonanone, 3-nonanone, 1-nonene-
3-ol, cis-6-nonenol, nonyl alcohol, sec. -Nonyl alcohol, nopol, ocimenyl acetate, 2,4-octadienal, octahydro-
4,7-methano-1H-indenecarboxaldehyde, octanal diethyl acetal, octanoic acid, 3-octyl acetate, octyl alcohol, sec. -Octyl alcohol, octyl butyrate, octyl formate, octyl isobutyrate, octyl isovalerate, 4-oxoisophorone, oxyoctaline formate, nonanoic acid 3,4,5,6,6
6-pentamethyl-2-heptanol, phenylacetaldehyde E. G. Acetal, phenylacetaldehyde glycene reacetal, 4-pentenoic acid, 2-pentyl-2-cyclopenten-1-one, 2-pentylpyridine, perilla alcohol, perillyl acetate, phenoxyethyl alcohol, 2-phenethyl 2-angelic acid,
2-phenethyl formate, 2-phenethyl 2-methylbutyrate,
5-phenyl-5-methyl-3-hexanone, 3-phenylpropionaldehyde, 3-phenylpropionaldehyde dimethyl acetal, 3-phenylpropyl propionate, 4-methyltricyclo [6.2.1.
0 2, 7] undecane-5-one, 5-propenyl guaethol, propyl benzoate, 3-propyl bicyclo [2.2.1] hept-5-ene-2-carboxaldehyde, P. G. Dibutyrate, P.I. G. Dipropionate, propyl heptanoate, propyl octanoate, α-
Propylphenethyl alcohol, phenyl phenylacetate, trans-2, propyl cis-4-decadienoate,
Pseudoionone, quinoline, rosinyl butyrate, rosinyl formate, rosinyl propionate, sabinene hydrate, safranal, safrole, salicylaldehyde, 3-hydroxy-4,5-dimethyl-2 (5H) -furanone,
Styralyl isobutyrate, styralyl propionate, styrolyl diacetate, styryl cyanide, terpenyl formate, α-terpenyl methyl ether, tetrahydrocitral, tetrahydrofurfuryl butyrate, tetrahydrolinalyl acetate, tetrahydropyrrole, 2,2,5,5-
Tetramethyl-4-isopropyl-1,3-dioxane, 3-tunanol, 4-tunanol, β-tsuyapurisin, thymol, theaspirane, p-tolylaldehyde,
Triacetin, tricyclodecenyl isobutyrate, tricyclodecenyl methyl ether, tridecanal, 2-tridecanone, trans-2-tridecanol, tridecene-2-nitrile, 4- (2,2,6-trimethyl-2)
(1) -cyclohexene) -2-methylbutanal,
2,6,6-trimethyl-2-cyclohexene-1,4
-Dione, 2,3,5-trimethyl-2-cyclohexen-4-yl-1-methylketone, 3,3,5-trimethylcyclohexylethyl ether, trimethyldecadienal, 2,4,6-trimethyl-4,5 - dihydro-1,3,5-dithiane, 9-ethylidene-3-oxatricyclo [6.2.1.0 2, 7] undecane, acetic alpha, 3,3-trimethylcyclohexane-1-methyl, 2, 2,5-trimethyl-5-pentylcyclopentanone, 2,5,5-trimethyl-2-phenyl-1,
3-dioxane, α, α, p-trimethylphenethyl alcohol, 4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one, 2,6,10-trimethyl-5,9-undecadie Nal, trimethylundecanal, 2,4-undecadienal, undecanal,
2-Undecanol, 2-Undecanone, 1,3,5-
Undecatriene, 10-undecen-1-ol, undecyl alcohol, undecylenic acid, sec. -Undecyl alcohol, valencene, γ-valerolactone, 4,6,6-trimethyl (1R) -bicyclo [3.
1.1] Hept-3-en-2-one, 4-methyl-4-phenyl-2-pentyl acetate, 3-methyl-4-octanolide and the like. * In Table 6 above, the main product name and its manufacturer name are shown in parentheses after the compound name. Similarly, in the table, E.
G. Are Ethylene Glycol, P. G.
Indicates Propylene Glycol.
【0031】表−7(C)ベースノート
アセチルカリオフィレン、アセチルバニリン、トリデカ
ナール、ヘキサナールジエチルアセタール、アリルα−
イオノン、α−アミルシンナミックアルデヒドジエチル
アセタール、α−アミルシンナミックアルデヒド−メチ
ルアンスラニレート(シッフベース)、α−アミルシン
ナミックアルデヒドジメチルアセタール、ギ酸アニシ
ル、プロピオン酸アニシル、4(5)−アセチル−7,
7,9(7,9,9)−トリメチルビシクロ[4,3,
0]ノン−1−エン(Atrinon:Henkel)、チグリン酸
ベンジル、ベンズアルデヒドグリセリルアセタール、ベ
ンズアルデヒドP.G.アセタール、ベンゾフェノン、
オクタン酸ベンジル、8,9−エポキシセドレン、ドデ
カン酸ベンジル、ベンジリデンアセトフェノン、ベンジ
ルイソチオシアネート、フェニル酢酸ベンジル、ビザボ
レン、2−tert.−ブチルシクロヘキサノール、ア
ントラニル酸ブチル、デカン酸ブチル、ドデカン酸ブチ
ル、p−tert.−ブチルヒドロシンナミックアルデ
ヒド、3−n−ブチリデンフタリド、2−n−ブチリデ
ン−3,5,5(3,3,5)−トリメチルシクロヘキ
サノン、p−tert.−ブチル−α−メチルヒドロシ
ンナミックアルデヒド、3−n−ブチルフタリド、2−
tert.−ブチルキノリン、6(p)−tert.−
ブチルキノリン、6−sec.−ブチルキノリン、8−
sec.−ブチルキノリン、サリチル酸ブチル、ステア
リン酸ブチル、10−ウンデセン酸ブチル、酢酸カリオ
フィレニル、β−カリオフィレンアルコール、カリオフ
ィレンアルデヒド、ギ酸カリオフィレニル、セド−8−
エン−10−オン<Cedranon>、プロピリデンフタリド
<Celeriax:IFF>、ケイヒ酸、アントラニル酸シンナ
ミル、安息香酸シンナミル、酪酸シンナミル、ギ酸シン
ナミル、イソ酪酸シンナミル、イソ吉草酸シンナミル、
プロピオン酸シンナミル、チグリン酸シンナミル、チグ
リン酸シトロネリル、オクタン酸p−クレジル、サリチ
ル酸p−クレジル、シクロヘキサデカノライド、シクロ
ヘキシルフェネチルエーテル、シクロメチレンシトロネ
ロール、2−シクロペンチルシクロペンタデカノン、シ
クロペンタデカノン、シクロテン、2,4−ジ−ter
t.−ブチルシクロヘキサノン<Cyclowood:TPC>、デ
カヒドロシクロドデカオキサゾール、δ−2−デセノラ
クトン、デシルアルコール、フタル酸ジエチル、ジベン
ジルエーテル、ジベンジルケトン、セバシン酸ジエチ
ル、酒石酸ジエチル、ジヒドロクマリン、ジヒドロイン
デニル−2,4−ジオキサン、1,4−ジメトキシ−2
−tert.−ブチルベンゼン、1,1−ジメチル−3
−フェニルプロパノール、2,2−ジメチル−3−フェ
ニルプロパノール、ジフェニル、ε−ドデカラクトン、
アニス酸エチル、シュウ酸エチルシトロネリル、ドデカ
ン酸エチル、2−メチル−6−ペンチル−4−オキソシ
クロヘキセー2−エンカルボン酸エチル<Calyxol:Ques
t>、メチルp−トリルグリシド酸エチル、ミリスチン
酸エチル、オレイン酸エチル、パルミチン酸エチル、デ
ヒドロシクロゲラン酸エチル(エチルサフラネート)、
ステアリン酸エチル、ファルネセン、ファルネシルアセ
トン、ヘキサン酸ゲラニル、ゲラニルオキシアセトアル
デヒド、フェニル酢酸ゲラニル、チグリン酸ゲラニル、
ヘリオトロピンジエチルアセタール、ヘリオトロピンジ
メチルアセタール、酢酸ヘリオトロピル、γ−ヘプタラ
クトン、ヘキサン酸ヘプチル、オクタン酸ヘプチル、δ
−ヘキサラクトン、3−オキサ−9−エチリデントリシ
クロ[6.2.1.02,7]−ウンデカン−4−オ
ン、オクタン酸ヘキシル、ヒノキチオール、、ヒドロシ
ンナミックアルコール、ヒドロシンナムアルデヒド、ヒ
ドロキシシトロネロール、4−(4−ヒドロキシ−3−
メトキシフェニル)−2−ブタノン、インドール−ヒド
ロキシシトロネラール(シッフベース)、オクタン酸イ
ソアミル、ケイヒ酸イソアミル、デカン酸イソアミル、
ドデカン酸イソアミル、ヘキサン酸イソアミル、ドデカ
ン酸イソアミル、フェニル酢酸イソアミル、ウンデシレ
ン酸イソアミル、ケイヒ酸イソブチル、酢酸イソブチル
フェネチル、2−イソブチルキノリン、イソオイゲニル
エチルエーテル、フェニル酢酸イソオイゲニル、イソヘ
キセニルシクロヘキセンカルボキシアルデヒド、イソフ
ィトール、ケイヒ酸イソプロピル、ミリスチン酸イソプ
ロピル、6−イソプロピルキノリン、安息香酸リナリ
ル、ケイヒ酸リナリル、フェニル酢酸l−メンチル、メ
チルセドリロン、α−メチル−trans−シンナミッ
クアルデヒド、6−メチルクマリン、メチルγ−デカラ
クトン、p−メチルジメチルベンジルカルビノール、3
−メチルインドール、3−メチル−4−(2,4,6−
トリメチル−3−シクロヘキセン−1−イル)−3−ブ
テン−2−オン<Methyl iritone:IFF>、ドデカン酸メ
チル、N−2′−メチルペンチリデンアントラニル酸メ
チル、ミリスチン酸メチル、オレイン酸メチル、N−メ
チル−N−フェニル−2−メチルブチルアミド、酢酸4
−メチル−4−フェニル−2−ペンチル、メチルプロピ
ルアセトアルデヒド−メチルアンスラニレート(シッフ
ベース)、テトラデカン酸メチル、2−メチル−4−
(2,2,6−トリメチル−1(2)−シクロヘキセニ
ル)−3−ブテン−1−アール、3−メチル−5−
(2,2,3−トリメチル−3−シクロペンテン−1−
イル)−3−ペンテン−2−オン、メチルバニリン、
1,1,3,3,5−ペンタメチル−4,6−ジニトロ
インダン<Moskene:Givaudan>、ムスコン、ムスクア
ンブレット、ムスクチベテン、ムスクケトン、酢酸ネロ
リジル、ヘプタン酸オクチル、オクタン酸オクチル、オ
レイン酸、13−オキサビシクロ[10.3.0]ペン
タデカン、3−オキサビシクロ[10.3.0]ペンタ
デセ−6−エン<Muscogene:Dragoco>、11−オキサ
ヘキサデカノリド、2−オキサスピロ[4.7]ドデカ
ン<Oxyvet:Henkel>、オキソセドラン、サリチル酸ペ
ンチル、イソ酪酸2−フェノキシエチル、プロピオン酸
2−フェノキシエチル、フェニルアセトアルデヒド2,
3−ブチレングリコールアセタール、フェニルアセトア
ルデヒドジイソブチルアセタール、フェニル酢酸、アン
トラニル酸2−フェネチル、安息香酸2−フェネチル、
オクタン酸2−フェネチル、ケイヒ酸2−フェネチル、
メタアクリル酸2−フェネチル、2−フェネチルメチル
エーテル、2−フェネチルメチルエチルカルビノール、
酢酸2−フェネチルメチルエチルカルビニル、ノナン酸
2−フェネチル、オクタン酸フェネチル、サリチル酸2
−フェネチル、吉草酸2−フェネチル、フェニルグリコ
ールジアセテート、イソ吉草酸3−フェニルプロピル、
サリチル酸フェニル、酢酸ピペロニル、ピペロニルアセ
トン、ケイヒ酸プロピル、ラズベリーアルデヒド、イソ
酪酸ロジニル、フェニル酢酸ロジニル、酢酸α(β)サ
ンタリル、スクラレン、スクラレオール、スカトール、
ステアリン酸、δ−テトラデカラクトン、テトラヒドロ
−p−メチルキノリン、5,6,7,8−テトラヒドロ
キノキサリン、δ−トリデカラクトン、2,6,10−
トリメチル−1−アセチル−2,5,9−シクロドデカ
トリエン、トリメチルシクロデカトリエンエポキシド、
2,5,5−トリメチル−2−オクタヒドロ−2−ナフ
トール、ジメチルベンズアルデヒド−メチルアンスラニ
レート(シッフベース)、バニリン酸、バニリンプロピ
レングリコールアセタール、バニリルアルコール、5−
プロペニルグエトール、1−(2,3,5,6,7,8
−ヘキサヒドロ−1,1−ジメチル−1H−ベンズイン
ダン−4−イル)−エタノンなど。以上表−7中、化合
物名の後の< >内は主な商品名とそのメーカー名を示
す。また、同じく表中でE.G.は、Ethylene
glycol、 P.G.は、Propylene
Glycolを示す。 Table 7 (C) Base note Acetyl caryophyllene, acetyl vanillin, tridecanal, hexanal diethyl acetal, allyl α-
Ionone, α-amyl cinnamic aldehyde diethyl acetal, α-amyl cinnamic aldehyde-methyl anthranilate (Schiff base), α-amyl cinnamic aldehyde dimethyl acetal, anisyl formate, anisyl propionate, 4 (5) -acetyl-7 ,
7,9 (7,9,9) -trimethylbicyclo [4,3,
0] non-1-ene (Atrinon: Henkel), benzyl tiglate, benzaldehyde glyceryl acetal, benzaldehyde P.I. G. Acetal, benzophenone,
Benzyl octanoate, 8,9-epoxy cedrene, benzyl dodecanoate, benzylidene acetophenone, benzyl isothiocyanate, benzyl phenylacetate, visabolene, 2-tert. -Butylcyclohexanol, butyl anthranilate, butyl decanoate, butyl dodecanoate, p-tert. -Butylhydrocinnamic aldehyde, 3-n-butylidenephthalide, 2-n-butylidene-3,5,5 (3,3,5) -trimethylcyclohexanone, p-tert. -Butyl-α-methylhydrocinnamic aldehyde, 3-n-butylphthalide, 2-
tert. -Butylquinoline, 6 (p) -tert. −
Butylquinoline, 6-sec. -Butylquinoline, 8-
sec. -Butylquinoline, butyl salicylate, butyl stearate, 10-butyl undecenoate, caryophyllenyl acetate, β-caryophyllene alcohol, caryophyllene aldehyde, caryophyllenyl formate, sed-8-
En-10-one <Cedranon>, propylidenephthalide <Celeriax: IFF>, cinnamic acid, cinnamyl anthranilate, cinnamyl butyrate, cinnamyl butyrate, cinnamyl formate, cinnamyl isobutyrate, cinnamyl isovalerate,
Cinnamyl propionate, cinnamyl tiglate, citronellyl tiglate, p-cresyl octanoate, p-cresyl salicylate, cyclohexadecanolide, cyclohexylphenethyl ether, cyclomethylene citronellol, 2-cyclopentylcyclopentadecanone, cyclopentadecanone, cycloten , 2,4-di-ter
t.-Butylcyclohexanone <Cyclowood: TPC>, decahydrocyclododecaxazole, δ-2-decenolactone, decyl alcohol, diethyl phthalate, dibenzyl ether, dibenzyl ketone, diethyl sebacate, diethyl tartrate, dihydrocoumarin, dihydroindene. Nyl-2,4-dioxane, 1,4-dimethoxy-2
-Tert. -Butylbenzene, 1,1-dimethyl-3
-Phenyl propanol, 2,2-dimethyl-3-phenyl propanol, diphenyl, ε-dodecalactone,
Ethyl anisate, ethyl citronellyl oxalate, ethyl dodecanoate, ethyl 2-methyl-6-pentyl-4-oxocyclohexe-2-enecarboxylate <Calyxol: Ques
t>, methyl p-tolylglycidate ethyl, ethyl myristate, ethyl oleate, ethyl palmitate, ethyl dehydrocyclogellanate (ethyl safranate),
Ethyl stearate, farnesene, farnesyl acetone, geranyl hexanoate, geranyloxyacetaldehyde, geranyl phenylacetate, geranyl tiglate,
Heliotropin diethyl acetal, heliotropin dimethyl acetal, heliotropyl acetate, γ-heptalactone, heptyl hexanoate, heptyl octanoate, δ
- hexalactone, 3-oxa-9-ethylidene tricyclo [6.2.1.0 2, 7] - undecane-4-one, hexyl octanoate, hinokitiol ,, hydro cinnamic alcohol, hydro cinnamaldehyde, hydroxy citronellol , 4- (4-hydroxy-3-
(Methoxyphenyl) -2-butanone, indole-hydroxycitronellal (Schiff base), isoamyl octanoate, isoamyl cinnamate, isoamyl decanoate,
Isoamyl dodecanoate, isoamyl hexanoate, isoamyl dodecanoate, isoamyl phenylacetate, isoamyl undecylenate, isobutyl cinnamate, isobutylphenethyl acetate, 2-isobutylquinoline, isoeugenyl ethyl ether, phenylacetate isoeugenyl, isohexenyl cyclohexene carboxaldehyde, iso Phytol, isopropyl cinnamate, isopropyl myristate, 6-isopropylquinoline, linalyl benzoate, linalyl cinnamate, l-menthyl phenylacetate, methylcedrilone, α-methyl-trans-cinnamic aldehyde, 6-methylcoumarin, methyl γ. -Decalactone, p-methyldimethylbenzylcarbinol, 3
-Methylindole, 3-methyl-4- (2,4,6-
Trimethyl-3-cyclohexen-1-yl) -3-buten-2-one <Methyl iritone: IFF>, methyl dodecanoate, methyl N-2′-methylpentylideneanthranilate, methyl myristate, methyl oleate, N -Methyl-N-phenyl-2-methylbutyramide, acetic acid 4
-Methyl-4-phenyl-2-pentyl, methylpropylacetaldehyde-methylanthranilate (Schiff base), methyl tetradecanoate, 2-methyl-4-
(2,2,6-Trimethyl-1 (2) -cyclohexenyl) -3-buten-1-al, 3-methyl-5-
(2,2,3-Trimethyl-3-cyclopentene-1-
Yl) -3-penten-2-one, methyl vanillin,
1,1,3,3,5-pentamethyl-4,6-dinitroindane <Moskene: Givaudan>, muscone, musk ambrette, musktibetane, musk ketone, nerolidyl acetate, octyl heptanoate, octyl octanoate, oleic acid, 13- Oxabicyclo [10.3.0] pentadecane, 3-oxabicyclo [10.3.0] pentadec-6-ene <Muscogene: Dragoco>, 11-oxahexadecanolide, 2-oxaspiro [4.7] dodecane <Oxyvet: Henkel>, oxocedrane, pentyl salicylate, 2-phenoxyethyl isobutyrate, 2-phenoxyethyl propionate, phenylacetaldehyde 2,
3-butylene glycol acetal, phenylacetaldehyde diisobutyl acetal, phenylacetic acid, 2-phenethyl anthranilate, 2-phenethyl benzoate,
2-phenethyl octanoate, 2-phenethyl cinnamate,
2-phenethyl methacrylic acid, 2-phenethyl methyl ether, 2-phenethyl methyl ethyl carbinol,
2-phenethylmethylethylcarbinyl acetate, 2-phenethyl nonanoate, phenethyl octanoate, salicylic acid 2
-Phenethyl, 2-phenethyl valerate, phenylglycol diacetate, 3-phenylpropyl isovalerate,
Phenyl salicylate, piperonyl acetate, piperonylacetone, propyl cinnamate, raspberry aldehyde, rosinyl isobutyrate, rosinyl phenylacetate, α (β) santalyl acetate, squalene, sclareol, skatole,
Stearic acid, δ-tetradecalactone, tetrahydro-p-methylquinoline, 5,6,7,8-tetrahydroquinoxaline, δ-tridecalactone, 2,6,10-
Trimethyl-1-acetyl-2,5,9-cyclododecatriene, trimethylcyclodecatriene epoxide,
2,5,5-Trimethyl-2-octahydro-2-naphthol, dimethylbenzaldehyde-methylanthranilate (Schiff base), vanillic acid, vanillin propylene glycol acetal, vanillyl alcohol, 5-
Propenylguetol, 1- (2,3,5,6,7,8
-Hexahydro-1,1-dimethyl-1H-benzindan-4-yl) -ethanone and the like. In Table 7 above, the main product names and manufacturer names are shown in <> after the compound names. Similarly, in the table, E. G. Is Ethylene
glycol, P.G. G. Is Propyrene
Indicates Glycol.
【0032】表−8(D)天然香料
アサフェチダ、アジョワン、アニシード(アニス)、ア
ビエス・ファー、シプレス、アミリス、アンゲリカ、オ
コティア、オールスパイス(ピメント)、オレガノ、オ
レンジフラワー(ネロリ)、ガージュンバルサム、カス
カリラ、カストリウム、カッシー、カッシャ、カラム
ス、ガーデニア、カーネーション、カブリューバー、キ
ク、キャロット、キンモクセイ、グアヤック、クスノ
キ、グーズベリー、クミン、グレープ、グレープフルー
ツ、コスタス、コパイバ、サクラ、ササフラス、シソ、
ジンコウ、ジンチョウゲ、スギ、スズラン、スチラック
ス、セイボリー、セロリー、タラゴン(エストラゴ
ン)、バイオレット、パイン、パセリ、ハニーサック
ル、パルマローザ、ヒソップ、ヒバ(ヒノキ)、ヒヤシ
ンス、ブチュ、ブルーム、マリーゴールド、メース、タ
ンジェリン、ミル(没薬)、ムスク、ラブダナム(シス
テ)、リナロエ、リラ、リリー、シプレス、バーベナ、
ビターアーモンド、ビターフェンネル、ブラックカーラ
ント、ホーウッド、メリッサ、ローズドメイ、ピメント
ベリー、ペパー、オリス、インセン、クベバ、セイボリ
ー、ウコン、アルニカ、ヘリクリサム、ミモザ、シャン
パカ、リンデンブロッサム、マグノリア、オスマンサス
など。上記表−8に記載される天然香料は、アブソリュ
ート、コンクリート、レジノイドなどの形状のものであ
ることもできる。 Table-8 (D) Natural fragrances Asaphetida, Ajowan, Aniseed (Anise), Abies Farr, Cypress, Amiris, Angelica, Ocotia, Allspice (Piment), Oregano, Orange flower (Neroli), Garjun balsam, Cascarilla, Castrium, Cassie, Cassia, Calamus, Gardenia, Carnation, Cabourver, Chrysanthemum, Carrot, Ginkgo, Guayac, Camphor, Gooseberry, Cumin, Grape, Grapefruit, Costas, Copaiba, Sakura, Sassafras, Perilla,
Ginkgo, Ginkgo, Japanese cedar, lily of the valley, Styrax, savory, celery, tarragon (estragon), violet, pine, parsley, honeysuckle, palmarosa, hyssop, hiba (hinoki), hyacinth, butchu, bloom, marigold, mace, tangerine, mill (Myrrh), musk, labdanum (system), linaloe, lira, lily, cypress, verbena,
Bitter almonds, bitter fennel, black currant, horwood, melissa, rose de may, pimento berry, pepper, orris, insen, cubeva, savory, turmeric, arnica, helichrysum, mimosa, champaca, linden blossom, magnolia, osmanthus. The natural flavors listed in Table 8 above may be in the form of absolute, concrete, resinoid, or the like.
【0033】上記のようにして製造された芳香・消臭組
成物の劣化を防止するため、必要により公知の天然ある
いは合成の酸化防止剤、光劣化防止剤を添加することが
できる。[周知・慣用技術集(香料)第1部 香料一般
2・4 香料の保存技術 141頁、平成11.1.29.発行]。In order to prevent deterioration of the fragrance / deodorant composition produced as described above, known natural or synthetic antioxidants and photodegradation inhibitors can be added, if necessary. [Collection of well-known and common techniques (fragrance) Part 1 Fragrance in general
2.4 Perfume preservation technology 141 pages, issued November 29, 1999].
【0034】また、必要により、溶剤(エタノール、エ
チレングリコール、プロピレングリコールなど)、公知
の天然・合成色素、公知の乳化剤、可溶化剤、保留剤・
保香剤、冷感剤・温感剤、エンハンサーなどを適宜に添
加することもできる[周知・慣用技術集(香料)第1部 香
料一般 2・3・8乳化・可溶化、2・6・11保留剤
・保香剤、2・6・12エンハンサー、2・6・13冷
感剤・温感剤 平成11.1.29発行]。If necessary, a solvent (ethanol, ethylene glycol, propylene glycol, etc.), a known natural / synthetic dye, a known emulsifier, a solubilizer, a holding agent, etc.
Perfumes, cooling agents, warming agents, enhancers, etc. can be added as appropriate [Collection of well-known and conventional techniques (fragrance) Part 1 11 Retention agent / fragrance agent, 2.6 / 12 enhancer, 2.61 / 13 cooling sensation / warming agent issued November 29, 1999].
【0035】また、本発明の芳香・消臭組成物、および
該芳香・消臭組成物の天然、および合成香料素材は、所
望により各種の精製・加工手段を採用して使用すること
もできる[周知・慣用技術集(香料)第1部 香料一般2
・3香料の精製・加工技術平成11.1.29発行]。Further, the fragrance / deodorant composition of the present invention and the natural and synthetic fragrance materials of the fragrance / deodorant composition can be used by adopting various refining / processing means if desired. Well-known and common technique collection (fragrance) Part 1 Fragrance general 2
・ 3 Refining and processing technology for fragrances issued November 29, 1999].
【0036】さらに、上記(A)、(B)および(C)
に記載の合成香料中に、幾何異性体あるいは光学異性体
が存在する場合は、これらを含むものであり、また、該
合成香料を含む天然香料も使用することができる。Further, the above (A), (B) and (C)
When the synthetic fragrance described in 1) has geometrical isomers or optical isomers, these are included, and a natural fragrance containing the synthetic fragrance can also be used.
【0037】かくして、上記のようにして製造された本
発明の芳香・消臭組成物は、各種の配合成分を含有する
人体用芳香・消臭剤に使用することができる。Thus, the fragrance / deodorant composition of the present invention produced as described above can be used as a fragrance / deodorant for human body containing various compounding ingredients.
【0038】デオドラントローション、デオドラントパ
ウダー、デオドラントスプレー、デオドラントスティッ
クなどの人体用芳香・消臭剤の配合成分としては、制汗
剤として例えばパラフェノールスルホン酸亜鉛、クエン
酸、アルミニウムクロロハイドレートなどのアルミニウ
ム塩、ジルコニウム塩など、抗菌剤として例えばトリク
ロサン、塩化ベンザルコニウム、塩化ベンゼトニウム、
塩酸クロルヘキシジン、グルコン酸クロルヘキシジン、
ハロカルバン、生薬抽出物など、消臭剤として例えば酸
化亜鉛、フラボノイド類、クロロフィルなどがそれぞれ
配合される。As a compounding ingredient of aroma and deodorant for the human body such as deodorant lotion, deodorant powder, deodorant spray, deodorant stick, etc., as an antiperspirant, for example, aluminum such as zinc paraphenolsulfonate, citric acid and aluminum chlorohydrate can be used. Antibacterial agents such as salts and zirconium salts, such as triclosan, benzalkonium chloride, benzethonium chloride,
Chlorhexidine hydrochloride, chlorhexidine gluconate,
For example, zinc oxide, flavonoids, chlorophyll, etc. are blended as deodorants such as halocarban and crude drug extracts.
【0039】本発明の芳香・消臭組成物を含有する人体
用芳香・消臭剤には上述したような成分のほかに、例え
ば粉末成分、液体油脂、固体油脂、ロウ、炭化水素、植
物抽出物、漢方成分、高級アルコール、低級アルコール
類、エステル類、長鎖脂肪酸、界面活性剤(非イオン界
面活性剤、アニオン界面活性剤、カチオン界面活性剤、
両性界面活性剤)、ステロール類、多価アルコール類、
保湿剤、水溶性高分子化合物、増粘剤、皮膜剤、防腐
剤、紫外線吸収剤、保留剤、冷感剤、温感剤、マスキン
グ剤、美白剤、金属イオン封鎖剤、糖分、アミノ酸類、
有機アミン類、合成樹脂エマルジョン、pH調製剤、皮
膚栄養剤、ビタミン類、酸化防止剤、酸化防止助剤、セ
ラミド類、NMF(天然保湿因子)、コラーゲン、尿
素、油分、粉体、機能性ビーズ、カプセル類、金属キレ
ート剤、無機塩、有機塩なども適宜配合できる。The fragrance / deodorant for human body containing the fragrance / deodorant composition of the present invention includes, in addition to the above-mentioned components, for example, powder components, liquid oil / fat, solid oil / fat, wax, hydrocarbon, plant extract. Substances, Chinese herbs, higher alcohols, lower alcohols, esters, long chain fatty acids, surfactants (nonionic surfactants, anionic surfactants, cationic surfactants,
Amphoteric surfactant), sterols, polyhydric alcohols,
Moisturizers, water-soluble polymer compounds, thickeners, film agents, preservatives, UV absorbers, holding agents, cooling agents, warming agents, masking agents, whitening agents, sequestering agents, sugars, amino acids,
Organic amines, synthetic resin emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, ceramides, NMF (natural moisturizing factor), collagen, urea, oil, powder, functional beads , Capsules, metal chelating agents, inorganic salts, organic salts and the like can be appropriately blended.
【0040】本発明の香気持続性を強化した人体用芳香
・消臭剤は、上述した成分を混合し、通常の方法によっ
て製造することができる。その剤型は、特に制限される
ものではなく、例えば液剤、エアゾール剤、軟膏剤、散
剤、固形粉末剤、ゲル状、ペースト状、スティック状な
どとすることができる。The fragrance / deodorant for human body of the present invention having enhanced aroma persistence can be produced by a conventional method by mixing the above-mentioned components. The dosage form is not particularly limited, and may be, for example, a liquid agent, an aerosol agent, an ointment agent, a powder agent, a solid powder agent, a gel, a paste, a stick or the like.
【0041】これらの人体用芳香・消臭剤に要求される
所定の香質乃至香気(例えば、シトラス、フルーティ、
グリーン、フローラル、アルデヒド、スパイシー、ウッ
ディ、スイート、モッシー、ムスキー、アンバー、アニ
マル、ハーバル、マリン、およびミントノートなど)に
調製された本発明の芳香・消臭組成物を、人体用芳香・
消臭剤に配合することにより、使用時には爽快な香りを
有し、また使用後もしばらく匂い続ける持続性と残香性
を有し、香料のマスキング機能により汗臭、腋臭、その
他の体臭などのマスキングに優れた効果を示し、これら
に使用されている基剤に対して安定で、基剤自体のマス
キングも可能であり、また使用した香料によるアロマテ
ラピー効果、ストレス緩和作用、また抗菌性も期待でき
るなど優れた効果を発揮することができる。Prescribed fragrances and odors required for these human fragrances and deodorants (eg, citrus, fruity,
Green, floral, aldehyde, spicy, woody, sweet, mossy, musky, amber, animal, herbal, marine, mint note, etc.)
When mixed with a deodorant, it has a refreshing scent when used, and it has a long-lasting and residual scent that continues to smell for a while even after use.The masking function of the fragrance masks sweat odor, armpit odor, and other body odors. It has an excellent effect on, is stable against the base used for these, the base itself can be masked, and the aromatherapy effect, stress relieving effect, and antibacterial effect of the fragrance used can be expected. It is possible to exert an excellent effect.
【0042】[0042]
【実施例】次に実施例を挙げて本発明を更に具体的に説
明する。
実施例 1-10;(A)トップノート成分(請求項5)と
天然香料からなる調合香料の処方例
実施例 11-40;(B)ミドルノート成分(請求項6)
と天然香料からなる調合香料の処方例
実施例 41-60;(C)ベースノート成分(請求項7)
と天然香料からなる調合香料の処方例
実施例 61-70 ;(D)天然香料からなる調合香料の処
方例(請求項8)
実施例 71-130;上記実施例1-70を組み合わせた調合香
料の処方例
実施例131-190;明細書記載の(A)トップノート成分
を主体とする合成及び天然香料から選ばれた素材からな
る調合香料の処方例
実施例191-310;明細書記載の(B)ミドルノート成分
を主体とする合成及び天然香料から選ばれた素材からな
る調合香料の処方例
実施例311-380;明細書記載の(C)ベースノート成分
を主体とする合成及び天然香料から選ばれた素材からな
る調合香料の処方例
実施例381-470;上記実施例131-380を組み合わせた調合
香料の処方例なお、以上の実施例中の香料化合物(品
名)の配合例の数値単位は重量部を示し、その合計量は
すべて100部を示す。また、所望によりこれらの実施
例に、任意の合成香料または天然香料(明細書記載のノ
ート別の合成香料、天然香料や、本明細書未記載の香
料)を適当量配合して、より優れた香調を有する消臭・
芳香組成物を提供することができる。以下に各種人体用
芳香・消臭剤の配合処方例を示す。EXAMPLES Next, the present invention will be described more specifically with reference to examples. Examples 1-10; (A) Top note component (Claim 5) and prescription example of blended fragrance consisting of natural fragrance Example 11-40; (B) Middle note component (Claim 6)
Formulation Example of Compounded Perfume Composed of Aroma and Natural Fragrance Example 41-60; (C) Base Note Component (Claim 7)
Formulation example of compounded fragrance consisting of and natural fragrance Example 61-70; (D) Formulation example of compounded fragrance consisting of natural fragrance (Claim 8) Example 71-130; Formulated fragrance combining the above Examples 1-70 Formulation Example Example 131-190; (A) Formulation of a perfume prepared from a material selected from synthetic and natural flavors containing (A) topnote components described in the specification Example Example 191-310; B) Formulation examples of blended fragrances composed of materials selected from synthetic and natural flavors mainly composed of middle note ingredients Example 311-380; (C) From synthetic and natural flavors mainly composed of base note ingredients Prescription example of compounded fragrance consisting of selected materials Example 381-470; Formulation example of compounded fragrance combining the above Examples 131-380 Numerical unit of compounding example of fragrance compound (product name) in the above Examples Indicates parts by weight, and the total amount indicates 100 parts. Further, if desired, an arbitrary amount of synthetic or natural fragrances (synthetic fragrances according to the notes described in the specification, natural fragrances, and fragrances not described in the specification) may be added in an appropriate amount to these Examples to obtain more excellent results. Deodorant with an aroma
An aroma composition can be provided. The following is an example of blending formulation of various human fragrances and deodorants.
【0043】 配合例−1:デオドラントローション(ロールオンタイプ) アルミニウムクロロハイドレート 10.0% 無水エチルアルコール 60.0 精製水 25.2 1,3−ブチレングリコール 3.0 塩化ベンザルコニウム 0.2 ポリオキシエチレン(40)硬化ヒマシ油 0.5 水溶性増粘剤 1.0 香料(処方例383の香料) 0.1 Formulation Example 1: Deodorant lotion (roll-on type) aluminum chlorohydrate 10.0% anhydrous ethyl alcohol 60.0 purified water 25.2 1,3-butylene glycol 3.0 benzalkonium chloride 0.2 poly Oxyethylene (40) hydrogenated castor oil 0.5 Water-soluble thickener 1.0 Fragrance (fragrance of Prescription Example 383) 0.1
【0044】 配合例−2:デオドラントローション(ナチュラルスプレータイプ) パラフェノールスルホン酸亜鉛 2.0% 無水エチルアルコール 74.0 ジメチルポリシロキサン 13.0 精製水 7.2 プロピレングリコール 3.0 トリクロサン 0.1 ポリオキシエチレン(40)硬化ヒマシ油 0.5 香料(処方例390の香料) 0.2 Formulation Example-2: Deodorant lotion (natural spray type) zinc paraphenolsulfonate 2.0% anhydrous ethyl alcohol 74.0 dimethylpolysiloxane 13.0 purified water 7.2 propylene glycol 3.0 triclosan 0.1 Polyoxyethylene (40) hydrogenated castor oil 0.5 Fragrance (fragrance of Formulation Example 390) 0.2
【0045】 配合例−3:デオドラントパウダー(プレストパウダー) アルミニウムクロロハイドレート 5.0% 酸化亜鉛 5.0 タルク 86.8 流動パラフィン 3.0 香料(処方例403の香料) 0.2 Formulation Example-3: Deodorant powder (pressed powder) Aluminum chlorohydrate 5.0% Zinc oxide 5.0 Talc 86.8 Liquid paraffin 3.0 Fragrance (fragrance of Formulation 403) 0.2
【0046】 配合例−4:デオドラントスプレー(化粧水型スプレー) パラフェノールスルホン酸亜鉛 2.0% 無水エチルアルコール 92.7 トリクロサン 0.1 1,3−ブチレングリコール 3.0 ミリスチン酸イソプロピル 2.0 香料(処方例416の香料) 0.2 以上50部にLPG50部を加えスプレー充填する。 Formulation-4: Deodorant spray (lotion spray) zinc paraphenolsulfonate 2.0% anhydrous ethyl alcohol 92.7 triclosan 0.1 1,3-butylene glycol 3.0 isopropyl myristate 2.0 Fragrance (fragrance of Formulation Example 416) 0.2 50 parts of LPG is added to 50 parts and spray-filled.
【0047】 配合例−5:デオドラントスプレー(パウダースプレー) アルミニウムクロロハイドレート(微粉末) 29.7% 無水ケイ酸(微粉末) 15.0 シリコン処理タルク 15.0 酸化亜鉛(微粉末) 5.0 トリクロサン 0.1 ミリスチン酸イソプロピル 21.9 ジメチルポリシロキサン 10.0 ソルビタン脂肪酸エステル 3.0 香料(処方例433の香料) 0.3 以上10部にLPG90部を加えスプレー充填する。 Formulation Example-5: Deodorant spray (powder spray) Aluminum chlorohydrate (fine powder) 29.7% Silicic anhydride (fine powder) 15.0 Silicon treated talc 15.0 Zinc oxide (fine powder) 5. 0 triclosan 0.1 isopropyl myristate 21.9 dimethylpolysiloxane 10.0 sorbitan fatty acid ester 3.0 Fragrance (fragrance of Prescription Example 433) 0.3 90 parts of LPG is added to 10 parts or more and spray-filled.
【0048】配合例−6:デオドラントステッィク(ワックス系) アルミニウムクロロハイドレート 23.0% タルク 15.0 固形パラフィンワックス 2.0 ステアリルアルコール 8.0 流動パラフィン 14.5 環状ジメチルポリシロキサン 36.5 ソルビタン脂肪酸エステル 1.0 香料(処方例445の香料) 0.2 Formulation Example-6: Deodorant Stick (Wax) Aluminum Chlorohydrate 23.0% Talc 15.0 Solid Paraffin Wax 2.0 Stearyl Alcohol 8.0 Liquid Paraffin 14.5 Cyclic Dimethyl Polysiloxane 36.5 Sorbitan Fatty acid ester 1.0 Fragrance (fragrance of Formulation Example 445) 0.2
【0049】 配合例−7:デオドラントステッィク(石けんアルコール系) ミルスチン酸イソプロピル 12.0% ステアリン酸ソーダ 10.0 セチルアルコール 3.0 プロピレングリコール 25.0 無水エチルアルコール 48.8 トリクロサン 0.1 精製水 1.0 香料(処方例467の香料) 0.1 Formulation Example-7: Deodorant Stick (soap alcohol type) Isopropyl myristate 12.0% Sodium stearate 10.0 Cetyl alcohol 3.0 Propylene glycol 25.0 Anhydrous ethyl alcohol 48.8 Triclosan 0.1 Purified water 1.0 Fragrance (fragrance of Prescription Example 467) 0.1
【0050】[0050]
【発明の効果】以上記載のごとく、香料素材を官能的に
トップノート成分、ミドルノート成分、ベースノート成
分およびミックスノート成分に分類し、これらの成分を
特定割合で配合したことにより、従来に比べ容易に芳香
・消臭組成物を調製することができる。 また、これを
消臭剤にその適当量を配合することにより、調和のとれ
た快い香りとともにマスキング効果を発揮できる人体用
芳香・消臭剤が得られる。As described above, the fragrance material is sensually classified into a top note component, a middle note component, a base note component and a mix note component. The fragrance / deodorant composition can be easily prepared. Also, by adding an appropriate amount of this to a deodorant, a human body fragrance / deodorant capable of exerting a masking effect together with a harmonious and pleasant scent can be obtained.
【0051】[0051]
【表1】 [Table 1]
【0052】[0052]
【表2】 [Table 2]
【0053】[0053]
【表3】 [Table 3]
【0054】[0054]
【表4】 [Table 4]
【0055】[0055]
【表5】 [Table 5]
【0056】[0056]
【表6】 [Table 6]
【0057】[0057]
【表7】 [Table 7]
【0058】[0058]
【表8】 [Table 8]
【0059】[0059]
【表9】 [Table 9]
【0060】[0060]
【表10】 [Table 10]
【0061】[0061]
【表11】 [Table 11]
【0062】[0062]
【表12】 [Table 12]
【0063】[0063]
【表13】 [Table 13]
【0064】[0064]
【表14】 [Table 14]
【0065】[0065]
【表15】 [Table 15]
【0066】[0066]
【表16】 [Table 16]
【0067】[0067]
【表17】 [Table 17]
【0068】[0068]
【表18】 [Table 18]
【0069】[0069]
【表19】 [Table 19]
【0070】[0070]
【表20】 [Table 20]
【0071】[0071]
【表21】 [Table 21]
【0072】[0072]
【表22】 [Table 22]
【0073】[0073]
【表23】 [Table 23]
【0074】[0074]
【表24】 [Table 24]
【0075】[0075]
【表25】 [Table 25]
【0076】[0076]
【表26】 [Table 26]
【0077】[0077]
【表27】 [Table 27]
【0078】[0078]
【表28】 [Table 28]
【0079】[0079]
【表29】 [Table 29]
【0080】[0080]
【表30】 [Table 30]
【0081】[0081]
【表31】 [Table 31]
【0082】[0082]
【表32】 [Table 32]
【0083】[0083]
【表33】 [Table 33]
【0084】[0084]
【表34】 [Table 34]
【0085】[0085]
【表35】 [Table 35]
【0086】[0086]
【表36】 [Table 36]
【0087】[0087]
【表37】 [Table 37]
【0088】[0088]
【表38】 [Table 38]
【0089】[0089]
【表39】 [Table 39]
【0090】[0090]
【表40】 [Table 40]
【0091】[0091]
【表41】 [Table 41]
【0092】[0092]
【表42】 [Table 42]
【0093】[0093]
【表43】 [Table 43]
【0094】[0094]
【表44】 [Table 44]
【0095】[0095]
【表45】 [Table 45]
【0096】[0096]
【表46】 [Table 46]
【0097】[0097]
【表47】 [Table 47]
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) A61L 9/00 A61L 9/00 Z 9/01 9/01 R V Fターム(参考) 4C080 AA04 BB03 CC01 HH03 MM13 MM14 MM15 MM16 MM17 MM18 MM31 4C083 AB212 AB222 AB372 AB432 AC012 AC022 AC072 AC102 AC122 AC242 AC352 AC432 AC442 AC692 AC792 AC812 AD152 AD172 BB41 CC17 DD08 DD11 DD17 DD27 EE18 4H059 BC23 DA09 DA30 EA31 EA40─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) A61L 9/00 A61L 9/00 Z 9/01 9/01 R V F term (reference) 4C080 AA04 BB03 CC01 HH03 MM13 MM14 MM15 MM16 MM17 MM18 MM31 4C083 AB212 AB222 AB372 AB432 AC012 AC022 AC072 AC102 AC122 AC242 AC352 AC432 AC442 AC692 AC792 AC812 AD152 AD172 BB41 CC17 DD08 DD11 DD17 DD27 EE18 4H059 BC23 DA09 DA30 EA31 EA40
Claims (11)
ミドルノート成分及び/又は(C)ベースノート成分及
び/又は(D)天然香料の群から選ばれる少なくとも1
種以上の香料を含有する芳香・消臭組成物。1. A top note component (A) and / or (B)
At least one selected from the group of middle note ingredients and / or (C) base note ingredients and / or (D) natural flavors
An aroma and deodorant composition containing one or more fragrances.
%、(B)ミドルノート成分が0〜100重量%、
(C)ベースノート成分が0〜100重量%、(D)天
然香料が0〜100重量%の割合で含有する請求項1記
載の芳香・消臭組成物。2. A top note component (A) is 0 to 100% by weight, a middle note component (B) is 0 to 100% by weight,
The fragrance / deodorant composition according to claim 1, wherein the base note component (C) is contained in an amount of 0 to 100% by weight and the natural flavor (D) is contained in an amount of 0 to 100% by weight.
%、(B)ミドルノート成分が10〜50重量%、
(C)ベースノート成分が10〜50重量%、(D)天
然香料が0.01〜100重量%の割合で含有する請求
項1〜2記載の芳香・消臭組成物。3. A topnote component (A) is 5 to 100% by weight, and a middle note component (B) is 10 to 50% by weight.
The aroma / deodorant composition according to claim 1 or 2, wherein the base note component (C) is contained in an amount of 10 to 50% by weight, and the natural flavor (D) is contained in an amount of 0.01 to 100% by weight.
揮散する香料、(B)ミドルノート成分が約2〜6時間
以内に揮散する香料、(C)ベースノート成分が約6時
間以上香りが持続する香料である請求項1〜3記載の芳
香・消臭組成物。4. A perfume (A) a top note component that volatilizes within about 2 hours, (B) a perfume that a middle note component volatilizes within about 2 to 6 hours, and (C) a base note component for about 6 hours or longer. The fragrance / deodorant composition according to claim 1, which is a fragrance having a persistent scent.
−ピネン、リモネン、p−サイメン、オシメン、ターピ
ノーレン、ジヒドロミルセノール、シス−3−ヘキセノ
ール、トランス−3−ヘキセノール、イソプレゴール、
l−メントール、1−オクテン−3−オール、1−ペン
テン−3−オール、ヘキサナール、ヘプタナール、オク
タナール、ノナナール、ベンズアルデヒド、2,6−ジ
メチル−5−ヘプテン−1−アール、2,6−ノナジエ
ナール、1,8−シネオール、 p−クレジルメチルエーテル、オクタナールジメチルア
セタール、リモネンオキサイド、ローズオキサイド、ギ
酸ヘキシル、酢酸エチル、オクタン酸アリル、2−エチ
ル酪酸アリル、ヘキサン酸アリル、ヘプタン酸エチル、
デカン酸メチル、ヘキサン酸メチル、オクタン酸メチ
ル、プロピオン酸イソアミル、酢酸イソアミル、酢酸プ
レニル、酢酸ミルテニル、酢酸1−オクテン−3−イ
ル、酪酸メチル、酪酸エチル、酪酸イソアミル、イソ酪
酸イソアミル、ヘキサン酸エチル、オクタン酸エチル、
2−エチルヘキサン酸エチル、イソ酪酸エチル、2−メ
チル酪酸メチル、2−メチル酪酸エチル、プロピオン酸
エチル、ギ酸シス−3−ヘキセニル、イソ吉草酸シス−
3−ヘキセニル、プロピオン酸シス−3−ヘキセニル、
アセト酢酸エチル、安息香酸メチル、フラネオール、メ
チルヘプテノン、8−メルカプトメントンから選ばれる
少なくとも1種以上の香料からなる請求項1〜4記載の
芳香・消臭組成物。5. (A) Top note component is α-pinene, β
-Pinene, limonene, p-cymene, ocimene, terpinolene, dihydromyrcenol, cis-3-hexenol, trans-3-hexenol, isopulegol,
1-menthol, 1-octen-3-ol, 1-penten-3-ol, hexanal, heptanal, octanal, nonanal, benzaldehyde, 2,6-dimethyl-5-hepten-1-al, 2,6-nonadienal, 1,8-cineole, p-cresyl methyl ether, octanal dimethyl acetal, limonene oxide, rose oxide, hexyl formate, ethyl acetate, allyl octanoate, allyl 2-ethylbutyrate, allyl hexanoate, ethyl heptanoate,
Methyl decanoate, methyl hexanoate, methyl octanoate, isoamyl propionate, isoamyl acetate, prenyl acetate, miltenyl acetate, 1-octen-3-yl acetate, methyl butyrate, ethyl butyrate, isoamyl butyrate, isoamyl isobutyrate, ethyl hexanoate. , Ethyl octoate,
Ethyl 2-ethylhexanoate, ethyl isobutyrate, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, ethyl propionate, cis-3-hexenyl formate, cis-isovalerate
3-hexenyl, cis-3-hexenyl propionate,
The fragrance / deodorant composition according to claims 1 to 4, comprising at least one or more fragrance selected from ethyl acetoacetate, methyl benzoate, furaneol, methylheptenone and 8-mercaptomentone.
ン、アセチルイソオイゲノール、ウンデカナール、ドデ
カナール、アリルアミルグリコレート、4−イソプロピ
ル−5,5−ジメチル−1,3−ジオキサン、酢酸ベン
ジル、ベンジルアルコール、プロピオン酸ベンジル、酢
酸o−tert.−ブチルシクロヘキシル、酢酸p−t
ert.−ブチルシクロヘキシル、カルボン、シトラー
ル、ゲラニルニトリル、シトロネラール、シトロネロー
ル、酢酸シトロネリル、シトロネリルニトリル、クレゾ
ール、酢酸p−クレジル、イソ酪酸p−クレジル、酢酸
トリシクロデセニル、プロピオン酸トリシクロデセニ
ル、1−デセナール、2−ペンチルシクロペンタノン、
ジヒドロリナロール、ジメチルベンジルカルビノール、
酢酸ジメチルベンジルカルビニル、ジメチルオクタナー
ル、酢酸3,7−ジメチルオクタニル、ジメチルフェネ
チルカルビノール、酢酸ジメチルフェネチルカルビニ
ル、ジフェニルオキサイド、4−トリシクロデシリデン
ブタナール、エストラゴール、p−エチル−α、α−ジ
メチルヒドロシンナムアルデヒド、レブリン酸エチル、
エチルリナロール、オイゲノール、α−フェンコン、酢
酸フェンキル、α−フェンキルアルコール、ゲラニオー
ル、酢酸ゲラニル、ギ酸ゲラニル、グアイアコール、酢
酸1−エチニルシクロヘキシル、アントラニル酸シス−
3−ヘキセニル、安息香酸シス−3−ヘキセニル、酪酸
シス−3−ヘキセニル、フェニルアセトアルデヒド、ハ
イドラトロパアルデヒドジメチルアセタール、ハイドラ
トロパアルデヒドエチレングリコールアセタール、ハイ
ドラトロピックアルデヒド、ヒドロキシシトロネラー
ル、ヒドロキシシトロネラールジメチルアセタール、イ
ンドール、アンゲリカ酸イソアミル、酢酸イソボルニ
ル、イソダマスコン、イソジャスモン、シクロオクチル
カルボン酸メチル、酢酸5−メチル−3−ブチルテトラ
ヒドロピラン−4−イル、シス−ジャスモン、4−メチ
レン−3,5,6,6−テトラメチル−2−ヘプタノ
ン、p−tert.−ブチル−α−メチルヒドロシンナ
ムアルデヒド、リナロール、リナロールオキサイド、マ
ルトール、メントン、酢酸l−メンチル、p−メチルア
セトフェノン、アニス酸メチル、ヘプチンカルボン酸メ
チル、フェニルグリシド酸メチル、サリチル酸メチル、
2−メチルウンデカナール、マイラックアルデヒド、ネ
ラール、ネロール、酢酸ネリル、酢酸ノニル、酢酸ノピ
ル、1−オクタノール、酢酸オクチル、酢酸3−ペンチ
ルテトラヒドロピラン−4−イル、フェニルアセトアル
デヒドジメチルアセタール、フェニルアセトアルデヒド
プロピレングリコールアセタール、酢酸フェネチル、β
−フェネチルアルコール、プロピオン酸2−フェネチ
ル、酢酸3−フェニルプロピル、3−フェニルプロピル
アルコール、イソ酪酸3−フェニルプロピル、酢酸ロジ
ニル、9−デセノール、酢酸スチラリル、スチラリルア
ルコール、ターピネン−4−オール、ターピネオール、
酢酸ターピニル、テトラヒドロアロオシメノール、テト
ラヒドロゲラニオール、テトラヒドロリナロール、テト
ラヒドロムゴール、テトラヒドロミルセノール、チオゲ
ラニオール、チモール、ジメチルテトラヒドロベンズア
ルデヒド、ウンデカナール、トランス−2−ウンデセナ
ール、2−メチル−3−(p−メトキシフェニル)−プ
ロパナール、アセトアルデヒド2−フェニル−2,4−
ペンタンジオールアセタールの群から選ばれる少なくと
も1種以上の香料からなる請求項1〜4記載の芳香・消
臭組成物。6. The middle note component (B) is acetyl cedrene, acetylisoeugenol, undecanal, dodecanal, allyl amyl glycolate, 4-isopropyl-5,5-dimethyl-1,3-dioxane, benzyl acetate, benzyl. Alcohol, benzyl propionate, acetic acid o-tert. -Butylcyclohexyl, acetic acid pt
ert. -Butylcyclohexyl, carvone, citral, geranyl nitrile, citronellal, citronellol, citronellyl acetate, citronellyl nitrile, cresol, p-cresyl acetate, p-cresyl isobutyrate, tricyclodecenyl acetate, tricyclodecenyl propionate, 1-decenal, 2-pentylcyclopentanone,
Dihydrolinalool, dimethylbenzylcarbinol,
Dimethylbenzylcarbinyl acetate, dimethyloctanal, 3,7-dimethyloctanyl acetate, dimethylphenethylcarbinol, dimethylphenethylcarbinyl acetate, diphenyl oxide, 4-tricyclodecylidenebutanal, estragal, p-ethyl-α , Α-dimethylhydrocinnamaldehyde, ethyl levulinate,
Ethyl linalool, eugenol, α-fencon, fenkill acetate, α-fenkill alcohol, geraniol, geranyl acetate, geranyl formate, guaiacol, 1-ethynylcyclohexyl acetate, cis-anthranilic acid
3-hexenyl, cis-3-hexenyl benzoate, cis-3-hexenyl butyrate, phenylacetaldehyde, hydratropaldehyde dimethyl acetal, hydratropaaldehyde ethylene glycol acetal, hydratropic aldehyde, hydroxycitronellal, hydroxycitronellal Dimethyl acetal, indole, isoamyl angelic acid, isobornyl acetate, isodamascon, isojasmon, methyl cyclooctylcarboxylate, 5-methyl-3-butyltetrahydropyran-4-yl acetate, cis-jasmon, 4-methylene-3,5,5. 6,6-Tetramethyl-2-heptanone, p-tert. -Butyl-α-methylhydrocinnamaldehyde, linalool, linalool oxide, maltol, menthone, l-menthyl acetate, p-methylacetophenone, methyl anisate, methyl heptinecarboxylate, methyl phenylglycidate, methyl salicylate,
2-methylundecanal, miracaldehyde, neral, nerol, neryl acetate, nonyl acetate, nopyr acetate, 1-octanol, octyl acetate, 3-pentyltetrahydropyran-4-yl acetate, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde propylene glycol Acetal, phenethyl acetate, β
-Phenethyl alcohol, 2-phenethyl propionate, 3-phenylpropyl acetate, 3-phenylpropyl alcohol, 3-phenylpropyl isobutyrate, rosinyl acetate, 9-decenol, styralyl acetate, styralyl alcohol, terpinen-4-ol, terpineol ,
Terpinyl acetate, tetrahydroaroosimenol, tetrahydrogeraniol, tetrahydrolinalool, tetrahydromugol, tetrahydromyrcenol, thiogeraniol, thymol, dimethyltetrahydrobenzaldehyde, undecanal, trans-2-undecenal, 2-methyl-3- (p- Methoxyphenyl) -propanal, acetaldehyde 2-phenyl-2,4-
The fragrance / deodorant composition according to any one of claims 1 to 4, comprising at least one fragrance selected from the group of pentanediol acetal.
ル、γ−ウンデカラクトン、γ−ノナラクトン、アンブ
ロックス、サリチル酸アミル、8,9−エポキシセドラ
ン、イソアミルフェネチルエーテル、アニスアルデヒ
ド、オーランチオール、ベンジルイソオイゲノール、サ
リチル酸ベンジル、6,7−ジヒドロ−1,1,2,
3,3−ペンタメチル−4−(5H)−インダノン、セ
ドリルメチルエーテル、セドレン、ギ酸セドリル、セド
ロール、シンナミックアルコール、酢酸シンナミル、ケ
イヒ酸シンナミル、クマリン、フェニル酢酸p−クレジ
ル、シクラメンアルデヒド、サリチル酸シクロヘキシ
ル、γ−デカラクトン、δ−デカラクトン、アントラニ
ル酸ジメチル、酪酸ジメチルベンジルカルビニル、δ−
ドデカラクトン、ケイヒ酸エチル、エチルマルトール、
メチルフェニルグリシド酸エチル、エチルバニリン、フ
ェニル酢酸オイゲニル、ファルネソール、酪酸ゲラニ
ル、イソ酪酸ゲラニル、イソ吉草酸ゲラニル、3a−エ
チルドデカヒドロ−6,6,9a−トリメチルナフト
[2.1b]フラン、ジヒドロジャスモン酸メチル、α
−メチル−3,4−メチレンジオキシヒドロシンナムア
ルデヒド、ヘリオトロピン、サリチル酸シス−3−ヘキ
セニル、α−ヘキシルシンナムアルデヒド、サリチル酸
ヘキシル、イソブチルキノリン、7−アセチル−1,
2,3,4,5,6,7,8−オクタヒドロ−1,1,
6,7−テトラメチルナフタレン、イソオイゲノール、
イソロンギホラノン、ジャスミンラクトン、γ−ジャス
モラクトン、テトラヒドロ−6−(3−ペンテニル)−
2H−ピラン−2−オン、4(3)−(4−ヒドロキシ
−4−メチルペンチル)−シクロヘキセン−1−カルボ
キシアルデヒド、1−(5,5−ジメチルシクロヘキセ
ン−1−イル)−4−ペンテン−1−オン、2,4−ジ
ヒドロキシ−3,6−ジメチル安息香酸メチル、β−ナ
フチルイソブチルエーテル、β−ナフチルメチルエーテ
ル、β−ナフチルエチルエーテル、ネロリドール、γ−
オクタラクトン、パチョリアルコール、フェニルアセト
アルデヒド2,4−ジヒドロキシ−4−メチルペンタン
アセタール、ピバリン酸2−フェネチル、p−ヒドロキ
シフェニルブタノン、ローズフェノン、1−(2,2,
6−トリメチルシクロヘキサン−1−イル)−ヘキサン
−3−オール、クエン酸トリエチル、バニリン、酢酸ベ
チベリル、ダマスコン類、ダマセノン類、イオノン類、
メチルイオノン類、合成サンダルウッド類、合成ムスク
類、イロン類の群から選ばれる少なくとも1種以上の香
料からなる請求項1〜4記載の芳香・消臭組成物。7. The base note component (C) is tetradecanal, γ-undecalactone, γ-nonalactone, unblocks, amyl salicylate, 8,9-epoxycedrane, isoamylphenethyl ether, anisaldehyde, auranthiol. , Benzylisoeugenol, benzyl salicylate, 6,7-dihydro-1,1,2,
3,3-pentamethyl-4- (5H) -indanone, cedryl methyl ether, cedrene, cedolyl formate, cedrol, cinnamic alcohol, cinnamyl acetate, cinnamyl cinnamate, coumarin, phenylacetic acid p-cresyl, cyclamenaldehyde, cyclohexyl salicylate. , Γ-decalactone, δ-decalactone, dimethyl anthranilate, dimethylbenzylcarbinyl butyrate, δ-
Dodecalactone, ethyl cinnamate, ethyl maltol,
Ethyl methylphenylglycidate, ethyl vanillin, eugenyl phenylacetate, farnesol, geranyl butyrate, geranyl isobutyrate, geranyl isovalerate, 3a-ethyldodecahydro-6,6,9a-trimethylnaphtho [2.1b] furan, dihydro Methyl jasmonate, α
-Methyl-3,4-methylenedioxyhydrocinnamaldehyde, heliotropin, cis-3-hexenyl salicylate, α-hexylcinnamaldehyde, hexyl salicylate, isobutylquinoline, 7-acetyl-1,
2,3,4,5,6,7,8-octahydro-1,1,
6,7-tetramethylnaphthalene, isoeugenol,
Isolongiforanone, jasmine lactone, γ-jasmolactone, tetrahydro-6- (3-pentenyl)-
2H-pyran-2-one, 4 (3)-(4-hydroxy-4-methylpentyl) -cyclohexene-1-carboxaldehyde, 1- (5,5-dimethylcyclohexen-1-yl) -4-pentene- 1-one, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, β-naphthyl isobutyl ether, β-naphthyl methyl ether, β-naphthyl ethyl ether, nerolidol, γ-
Octalactone, patchouli alcohol, phenylacetaldehyde 2,4-dihydroxy-4-methylpentaneacetal, 2-phenethyl pivalate, p-hydroxyphenylbutanone, rosephenone, 1- (2,2,
6-trimethylcyclohexan-1-yl) -hexan-3-ol, triethyl citrate, vanillin, vetiveryl acetate, damascones, damacenones, ionones,
The fragrance / deodorant composition according to any one of claims 1 to 4, comprising at least one fragrance selected from the group consisting of methylionones, synthetic sandalwoods, synthetic musks, and irons.
ウインターグリーン、オークモス、オポパナックス、オ
レンジ、カモミール、カルダモン、クミン、クローブ、
コリアンダー、サンダルウッド、ジャスミン、ジュニパ
ーベリー、ジンジャー、シンナモン、スペアミント、シ
ダー、ゼラニウム、タイム、トルーバルサム、ナツメッ
グ、ショウノウ、バジル、パチョリ、ハッカ(和種ハッ
カ)、バニラ、ベルガモット、ペルーバルサム、ベンゾ
イン、ホウショウ、ユーカリ、ヨモギ、ライム、ラベン
ダー、レモン、ローズ、ローズマリー、マンダリン、ロ
ーレルの群から選ばれる少なくとも1種以上を含有する
請求項1〜4記載の芳香・消臭組成物。8. (D) Natural fragrance is ylang-ylang, iris,
Winter green, oak moss, opopanax, orange, chamomile, cardamom, cumin, clove,
Coriander, sandalwood, jasmine, juniper berry, ginger, cinnamon, spearmint, cedar, geranium, thyme, troy balsam, nutmeg, camphor, basil, patchouli, peppermint, vanilla, bergamot, peruvian balsam, benzoin, spinach The aroma / deodorant composition according to claim 1, which comprises at least one selected from the group consisting of eucalyptus, mugwort, lime, lavender, lemon, rose, rosemary, mandarin and laurel.
0.001〜10重量%含有してなる人体用芳香・消臭
剤。9. A fragrance / deodorant for human body, containing 0.001 to 10% by weight of the fragrance / deodorant composition according to claim 1.
芳香・消臭剤、界面活性剤の少なくとも1種以上含有し
てなる請求項9記載の人体用芳香・消臭剤。10. A human body fragrance / deodorant is an antiperspirant, an antibacterial agent,
The fragrance / deodorant for human body according to claim 9, which comprises at least one kind of fragrance / deodorant and surfactant.
ション、デオドラントパウダー、デオドラントスプレ
ー、デオドラントスティックである請求項9記載の人体
用芳香・消臭剤。11. The human fragrance / deodorant according to claim 9, which is a deodorant lotion, a deodorant powder, a deodorant spray, or a deodorant stick.
Priority Applications (1)
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JP2001308879A JP2003113392A (en) | 2001-10-04 | 2001-10-04 | Perfuming/deodorizing composition and perfuming/ deodorizing agent for human body containing the perfuming/deodorizing composition |
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JP2001308879A JP2003113392A (en) | 2001-10-04 | 2001-10-04 | Perfuming/deodorizing composition and perfuming/ deodorizing agent for human body containing the perfuming/deodorizing composition |
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Publication Number | Publication Date |
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Family
ID=19128118
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JP2001308879A Pending JP2003113392A (en) | 2001-10-04 | 2001-10-04 | Perfuming/deodorizing composition and perfuming/ deodorizing agent for human body containing the perfuming/deodorizing composition |
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