CA2972375A1 - Malodor reduction compositions - Google Patents
Malodor reduction compositions Download PDFInfo
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- CA2972375A1 CA2972375A1 CA2972375A CA2972375A CA2972375A1 CA 2972375 A1 CA2972375 A1 CA 2972375A1 CA 2972375 A CA2972375 A CA 2972375A CA 2972375 A CA2972375 A CA 2972375A CA 2972375 A1 CA2972375 A1 CA 2972375A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
- C11B9/0019—Aliphatic compounds containing oxygen as the only heteroatom carbocylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/0034—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing six carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0042—Essential oils; Perfumes compounds containing condensed hydrocarbon rings
- C11B9/0046—Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings
- C11B9/0049—Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings the condensed rings sharing two common C atoms
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0042—Essential oils; Perfumes compounds containing condensed hydrocarbon rings
- C11B9/0046—Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings
- C11B9/0049—Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings the condensed rings sharing two common C atoms
- C11B9/0053—Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings the condensed rings sharing two common C atoms both rings being six-membered
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0061—Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0069—Heterocyclic compounds
- C11B9/0073—Heterocyclic compounds containing only O or S as heteroatoms
- C11B9/008—Heterocyclic compounds containing only O or S as heteroatoms the hetero rings containing six atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- G06—COMPUTING; CALCULATING OR COUNTING
- G06Q—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
- G06Q30/00—Commerce
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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Abstract
The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags.
Such malodor control technologies do not unduly interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.
Such malodor control technologies do not unduly interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.
Description
MALODOR REDUCTION COMPOSITIONS
FIELD OF THE INVENTION
The present invention relates to malodor reduction compositions and methods of making and using same.
BACKGROUND OF THE INVENTION
Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C2-C12 carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g.
fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g.
mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors.
Manufacturers often incorporate scented perfumes to help mask these difficult malodors.
Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus, what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules.
Thus, the malodor control technologies disclosed herein do not unduly interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.
SUMMARY OF THE INVENTION
The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags.
Such malodor control technologies do not unduly interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.
DETAILED DESCRIPTION OF THE INVENTION
As used herein "MORV" is the calculated malodor reduction value for a subject material.
A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.
As used herein "consumer product" means baby care, beauty care, fabric & home care, family care, feminine care, health careproducts or devices. Such products include but are not limited to plastic films garbage bags, storage bags, storage wraps, diapers, bibs, wipes, garments, textiles including sheets and towels, composters; products for and/or methods relating to treating hair (human, dog, and/or cat), including, bleaching, coloring, dyeing, conditioning, wet or dry shampooing, styling, scalp treatments; deodorants and antiperspirants;
personal cleansing;
cosmetics; skin care including application of creams, lotions, fine fragrances and other topically applied products for consumer use; and shaving products, products for and/or methods relating to treating fabrics, hard surfaces and any other surfaces in the area of fabric and home care, including:
air care including air filtration, car care, dishwashing, fabric conditioning (including softening), laundry detergency, laundry and rinse additive and/or care, hard surface cleaning and/or treatment, towel bowl cleaners and other cleaning and/or malodor treatments for consumer, agricultural, industrial or institutional use; products and/or methods relating to bath tissue, facial tissue, paper handkerchiefs, and/or paper towels; tampons, feminine napkins; products and/or methods relating to oral care including toothpastes, tooth gels, tooth rinses, denture adhesives, tooth whitening.
As used herein "energized system", refers to a system that operates by using an electrical and/or mechanical energy source such as a battery or electrical wall outlet to emit the malodor reduction composition. Examples of such devices include but are limited to liquid electric pluggable type air freshening devices.
As used herein, "malodor" refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.
As used herein, "neutralize" or "neutralization" refers to the ability of a compound or product to reduce or eliminate malodorous compounds. Odor neutralization may be partial, affecting only some of the malodorous compounds in each context, or affecting only part of a malodorous compound. A malodorous compound may be neutralized by chemical reaction resulting in a new chemical entity, by sequestration, by chelation, by association, or by any other interaction rendering the malodorous compound less malodorous or non-malodorous.
As used herein, "non-energized" refers to a system that emits a targeted active passively or without the need for an electrical energy source. Handheld aerosol sprayers and traditional trigger/pump sprayers are considered non-energized systems.
As used herein, "odor blocking" refers to the ability of a compound to dull the human sense of smell.
As used herein, "odor masking" refers to the ability of a compound with a non-offensive or pleasant smell that is dosed such that it limits the ability to sense a malodorous compound. Odor-masking may involve the selection of compounds which coordinate with an anticipated malodor to change the perception of the overall scent provided by the combination of odorous compounds.
As used herein, "compostable film" means a film that, when made into a bag, meets the testing specifications found in ASTM D6400.
As used herein, the terms "a" and "an" mean "at least one".
As used herein, the terms "include", "includes" and "including" are meant to be non-limiting.
Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
Malodor Reduction Materials Codes A = Vapor Pressure > 0.1 torr B = Vapor Pressure is between 0.01 torr and 0.1 torr C = ClogP < 3 D = ClogP >3 E = Probability of Ingredient Color Instability = 0%
F = Melamine formaldehyde PMC leakage less than or equal to 5%
Table 1 List of materials with at least one MORV from 1 to 5 Numbe IUPAC Name CAS Comment Number Code 1 2,2'-oxybis(ethan-l-ol) 111-46-6 3 butane-1,3-diol 107-88-0 BCE
4 hexane-1,6-diol 629-11-8 CE
5 2,2'-(ethane-1,2-diylbis(oxy))bis(ethan-1-ol) 112-27-6 CEF
6 2-methylpentane-2,4-diol 107-41-5 BCEF
8 2-oxopentanedioic acid 328-50-7 CE
9 hexane-1,2,6-triol 106-69-4 10 1-(1-ethoxyethoxy)propane 20680-11 (Z)-oct-5-en-1-ol 64275-73- ACE
12 (E)-oct-3-en-1-01 18185-81- ACE
13 (Z)-oct-5-enal 41547-22- AC
______________________________________________________ 2 14 triethoxymethane 122-51-0 ACE
asparagine 3130-87-8 16 2,5-dimethy1-1,4-dithiane-2,5-diol 55704-78- CF
17 2-methyloctan-2-ol 628-44-4 ADE
18 (E)-non-2-en-1-ol 22104-79- BCE
19 (E)-non-6-en-1-ol 40709-05- BCE
FIELD OF THE INVENTION
The present invention relates to malodor reduction compositions and methods of making and using same.
BACKGROUND OF THE INVENTION
Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C2-C12 carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g.
fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g.
mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors.
Manufacturers often incorporate scented perfumes to help mask these difficult malodors.
Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus, what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules.
Thus, the malodor control technologies disclosed herein do not unduly interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.
SUMMARY OF THE INVENTION
The present invention relates to malodor reduction compositions and methods of making and using same. The malodor reduction compositions are suitable for use in a variety of applications, including use in consumer products, for example, air freshening compositions, laundry detergents, fabric enhancers, surface cleaners, beauty care products, dish care products, diapers, feminine protection articles, and plastic films for garbage bags.
Such malodor control technologies do not unduly interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology.
DETAILED DESCRIPTION OF THE INVENTION
As used herein "MORV" is the calculated malodor reduction value for a subject material.
A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.
As used herein "consumer product" means baby care, beauty care, fabric & home care, family care, feminine care, health careproducts or devices. Such products include but are not limited to plastic films garbage bags, storage bags, storage wraps, diapers, bibs, wipes, garments, textiles including sheets and towels, composters; products for and/or methods relating to treating hair (human, dog, and/or cat), including, bleaching, coloring, dyeing, conditioning, wet or dry shampooing, styling, scalp treatments; deodorants and antiperspirants;
personal cleansing;
cosmetics; skin care including application of creams, lotions, fine fragrances and other topically applied products for consumer use; and shaving products, products for and/or methods relating to treating fabrics, hard surfaces and any other surfaces in the area of fabric and home care, including:
air care including air filtration, car care, dishwashing, fabric conditioning (including softening), laundry detergency, laundry and rinse additive and/or care, hard surface cleaning and/or treatment, towel bowl cleaners and other cleaning and/or malodor treatments for consumer, agricultural, industrial or institutional use; products and/or methods relating to bath tissue, facial tissue, paper handkerchiefs, and/or paper towels; tampons, feminine napkins; products and/or methods relating to oral care including toothpastes, tooth gels, tooth rinses, denture adhesives, tooth whitening.
As used herein "energized system", refers to a system that operates by using an electrical and/or mechanical energy source such as a battery or electrical wall outlet to emit the malodor reduction composition. Examples of such devices include but are limited to liquid electric pluggable type air freshening devices.
As used herein, "malodor" refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.
As used herein, "neutralize" or "neutralization" refers to the ability of a compound or product to reduce or eliminate malodorous compounds. Odor neutralization may be partial, affecting only some of the malodorous compounds in each context, or affecting only part of a malodorous compound. A malodorous compound may be neutralized by chemical reaction resulting in a new chemical entity, by sequestration, by chelation, by association, or by any other interaction rendering the malodorous compound less malodorous or non-malodorous.
As used herein, "non-energized" refers to a system that emits a targeted active passively or without the need for an electrical energy source. Handheld aerosol sprayers and traditional trigger/pump sprayers are considered non-energized systems.
As used herein, "odor blocking" refers to the ability of a compound to dull the human sense of smell.
As used herein, "odor masking" refers to the ability of a compound with a non-offensive or pleasant smell that is dosed such that it limits the ability to sense a malodorous compound. Odor-masking may involve the selection of compounds which coordinate with an anticipated malodor to change the perception of the overall scent provided by the combination of odorous compounds.
As used herein, "compostable film" means a film that, when made into a bag, meets the testing specifications found in ASTM D6400.
As used herein, the terms "a" and "an" mean "at least one".
As used herein, the terms "include", "includes" and "including" are meant to be non-limiting.
Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
Malodor Reduction Materials Codes A = Vapor Pressure > 0.1 torr B = Vapor Pressure is between 0.01 torr and 0.1 torr C = ClogP < 3 D = ClogP >3 E = Probability of Ingredient Color Instability = 0%
F = Melamine formaldehyde PMC leakage less than or equal to 5%
Table 1 List of materials with at least one MORV from 1 to 5 Numbe IUPAC Name CAS Comment Number Code 1 2,2'-oxybis(ethan-l-ol) 111-46-6 3 butane-1,3-diol 107-88-0 BCE
4 hexane-1,6-diol 629-11-8 CE
5 2,2'-(ethane-1,2-diylbis(oxy))bis(ethan-1-ol) 112-27-6 CEF
6 2-methylpentane-2,4-diol 107-41-5 BCEF
8 2-oxopentanedioic acid 328-50-7 CE
9 hexane-1,2,6-triol 106-69-4 10 1-(1-ethoxyethoxy)propane 20680-11 (Z)-oct-5-en-1-ol 64275-73- ACE
12 (E)-oct-3-en-1-01 18185-81- ACE
13 (Z)-oct-5-enal 41547-22- AC
______________________________________________________ 2 14 triethoxymethane 122-51-0 ACE
asparagine 3130-87-8 16 2,5-dimethy1-1,4-dithiane-2,5-diol 55704-78- CF
17 2-methyloctan-2-ol 628-44-4 ADE
18 (E)-non-2-en-1-ol 22104-79- BCE
19 (E)-non-6-en-1-ol 40709-05- BCE
2,4,6-trimethy1-1,3,5-trioxane 123-63-7 ACF
21 (E)-non-3-en-l-ol 10339-61- BCE
22 (Z)-non-3-en-1-ol 10340-23- BCE
23 (2E,6Z)-nona-2,6-dien-1-ol 28069-24 heptanedioic acid 111-16-0 CE
26 (E)-1,1-dimethoxyhex-2-ene 18318-27 3,5-dimethylcyclopentane-1,2-dione 13494-07- ACEF
28 methyl 2-hydroxy-4-methylpentanoate 40348-72- ACE
29 2,2',2"-nitrilotris(ethan- 1-ol) 102-71-6 CE
30 1-(1-methoxyethoxy)hexane 54340-90- ACE
31 3,4,4-trimethylcyclopentane-1,2-dione 33079-56-ACEF
32 2-(1-isopropoxyethoxy)propane 4285-59-0 ACEF
33 4-methyl-2-propy1-1,3-dioxolane 4352-99-2 ACE
34 3-Nonen-2-one 14309-57- AD
35 (E)-non-5-en-2-one 27039-84-AC
36 nonanoic acid 112-05-0 DE
37 2-(cyclohexyloxy)ethan- I -ol 1817-88-5 BCE
38 2,4,5-trimethylthiazole 13623-11- ACF
39 2-Nonenoic acid 3760-11-0 DE
40 octane-1,8-dithiol 1191-62-41 (E)-dec-2-en- 1-ol 22104-80-BDEF
43 (E)-dec-5-en-1-ol 56578-18-BDEF
44 2,3,6-trimethylphenol 2416-94-6 BC
45 L-Ascorbic acid 50-81-7 CE
47 (2E,4E)-deca-2,4-dienal 25152-84- BD
48 (2E,4Z)-deca-2,4-dienal 25152-83- BD
49 decane-1,10-diol 112-47-0 CEF
50 2-phenylpropan-2-ol 617-94-7 AC
52 nonan-3-ol 624-51-1 ADE
53 (Z)-dec-7-enal 21661-97- BD
54 (E)-prop-1-ene-1,2,3-tricarboxylic acid 4023-65-8 C
55 1,1-dimethoxyheptane 10032-05- A DEF
57 methyl octanoate 111-11-5 ADE
58 1-methoxydecane 7289-52-3 ADEF
59 undecane 1120-21-4 A DEF
60 methyl (Z)-oct-2-enoate 2396-85-2 ADE
61 decan-2-ol 1120-06-5 BDEF
62 3-(hydroxymethyl)phenol 620-24-6 C
64 non-1-en-3-ol 21964-44- ADE
21 (E)-non-3-en-l-ol 10339-61- BCE
22 (Z)-non-3-en-1-ol 10340-23- BCE
23 (2E,6Z)-nona-2,6-dien-1-ol 28069-24 heptanedioic acid 111-16-0 CE
26 (E)-1,1-dimethoxyhex-2-ene 18318-27 3,5-dimethylcyclopentane-1,2-dione 13494-07- ACEF
28 methyl 2-hydroxy-4-methylpentanoate 40348-72- ACE
29 2,2',2"-nitrilotris(ethan- 1-ol) 102-71-6 CE
30 1-(1-methoxyethoxy)hexane 54340-90- ACE
31 3,4,4-trimethylcyclopentane-1,2-dione 33079-56-ACEF
32 2-(1-isopropoxyethoxy)propane 4285-59-0 ACEF
33 4-methyl-2-propy1-1,3-dioxolane 4352-99-2 ACE
34 3-Nonen-2-one 14309-57- AD
35 (E)-non-5-en-2-one 27039-84-AC
36 nonanoic acid 112-05-0 DE
37 2-(cyclohexyloxy)ethan- I -ol 1817-88-5 BCE
38 2,4,5-trimethylthiazole 13623-11- ACF
39 2-Nonenoic acid 3760-11-0 DE
40 octane-1,8-dithiol 1191-62-41 (E)-dec-2-en- 1-ol 22104-80-BDEF
43 (E)-dec-5-en-1-ol 56578-18-BDEF
44 2,3,6-trimethylphenol 2416-94-6 BC
45 L-Ascorbic acid 50-81-7 CE
47 (2E,4E)-deca-2,4-dienal 25152-84- BD
48 (2E,4Z)-deca-2,4-dienal 25152-83- BD
49 decane-1,10-diol 112-47-0 CEF
50 2-phenylpropan-2-ol 617-94-7 AC
52 nonan-3-ol 624-51-1 ADE
53 (Z)-dec-7-enal 21661-97- BD
54 (E)-prop-1-ene-1,2,3-tricarboxylic acid 4023-65-8 C
55 1,1-dimethoxyheptane 10032-05- A DEF
57 methyl octanoate 111-11-5 ADE
58 1-methoxydecane 7289-52-3 ADEF
59 undecane 1120-21-4 A DEF
60 methyl (Z)-oct-2-enoate 2396-85-2 ADE
61 decan-2-ol 1120-06-5 BDEF
62 3-(hydroxymethyl)phenol 620-24-6 C
64 non-1-en-3-ol 21964-44- ADE
3 65 nonanenitrile 2243-27-8 BDE
66 (2-methoxyphenyl)methanol 612-16-8 BCE
67 dipentylsulfane 872-10-6 ADEF
68 methyl (E)-oct-3-enoate 35234-16- ACE
69 methyl (Z)-oct-4-enoate 21063-71- ACE
70 (Z)-hex-3-en-1-y1 2-hydroxypropanoate 61931-81-CE
71 1,1-diethoxypentane 3658-79-5 ACEF
72 decan-2-one 693-54-9 ADF
73 (3E,5E)-undeca-1,3,5-triene 19883-29- ADEF
74 1-oxaspiro[4.7]dodecane 62079-29- ADEF
75 2-(o-tolyl)ethan-1-01 19819-98- BCE
76 undecan-l-ol 112-42-5 DEF
77 (E)-dec-3-en-2-one 10519-33- AD
78 2-ethyl-4,5-dimethyloxazole 53833-30- ACE
79 3-ethy1-2-hydroxy-4-methylcyclopent-2-en-1-one 42348-12-CF
80 3-phenylpropan-l-ol 1335-12-2 BCE
81 4-methyl-2-propy1-1,3-dioxane 1745-87-5 ACE
82 (E)-oct-2-en-1-y1 acetate 2371-13-3 ADEF
83 (5Z)-2,6-dimethy1-3,5-Octadien-2-ol 18675-16- BDEF
84 (5E)-2,6-dimethy1-3,5-Octadien-2-ol 18675-17- BDEF
85 1-(1-ethoxyethoxy)hexane 54484-73- ADEF
87 2-(benzyloxy)ethan-1-01 622-08-2 CE
91 (2E,4Z)-hexa-2,4-dien-1-y1 isobutyrate 16491-24-ADEF
92 (E)-undec-2-en-1-ol 37617-03- DEF
93 1-(1-butoxyethoxy)butane 871-22-7 ADEF
94 decyl formate 5451-52-5 BDEF
95 (E)-undeca-1,3-dien-5-yne 166432- ADEF
96 (Z)-1-(1-ethoxyethoxy)hex-3-ene 28069-74- ACEF
97 (di methoxymethyl)benzene 1125-88-8 ACE
98 (2Z,4E)-undeca-2,4-dien-1-ol 59376-58- DEF
99 (E)-dec-4-enoic acid 57602-94-DEF
100 (E)-7-methyl-3-methyleneocta-4,6-dien-2-ol 22451-63-DF
66 (2-methoxyphenyl)methanol 612-16-8 BCE
67 dipentylsulfane 872-10-6 ADEF
68 methyl (E)-oct-3-enoate 35234-16- ACE
69 methyl (Z)-oct-4-enoate 21063-71- ACE
70 (Z)-hex-3-en-1-y1 2-hydroxypropanoate 61931-81-CE
71 1,1-diethoxypentane 3658-79-5 ACEF
72 decan-2-one 693-54-9 ADF
73 (3E,5E)-undeca-1,3,5-triene 19883-29- ADEF
74 1-oxaspiro[4.7]dodecane 62079-29- ADEF
75 2-(o-tolyl)ethan-1-01 19819-98- BCE
76 undecan-l-ol 112-42-5 DEF
77 (E)-dec-3-en-2-one 10519-33- AD
78 2-ethyl-4,5-dimethyloxazole 53833-30- ACE
79 3-ethy1-2-hydroxy-4-methylcyclopent-2-en-1-one 42348-12-CF
80 3-phenylpropan-l-ol 1335-12-2 BCE
81 4-methyl-2-propy1-1,3-dioxane 1745-87-5 ACE
82 (E)-oct-2-en-1-y1 acetate 2371-13-3 ADEF
83 (5Z)-2,6-dimethy1-3,5-Octadien-2-ol 18675-16- BDEF
84 (5E)-2,6-dimethy1-3,5-Octadien-2-ol 18675-17- BDEF
85 1-(1-ethoxyethoxy)hexane 54484-73- ADEF
87 2-(benzyloxy)ethan-1-01 622-08-2 CE
91 (2E,4Z)-hexa-2,4-dien-1-y1 isobutyrate 16491-24-ADEF
92 (E)-undec-2-en-1-ol 37617-03- DEF
93 1-(1-butoxyethoxy)butane 871-22-7 ADEF
94 decyl formate 5451-52-5 BDEF
95 (E)-undeca-1,3-dien-5-yne 166432- ADEF
96 (Z)-1-(1-ethoxyethoxy)hex-3-ene 28069-74- ACEF
97 (di methoxymethyl)benzene 1125-88-8 ACE
98 (2Z,4E)-undeca-2,4-dien-1-ol 59376-58- DEF
99 (E)-dec-4-enoic acid 57602-94-DEF
100 (E)-7-methyl-3-methyleneocta-4,6-dien-2-ol 22451-63-DF
4 101 (Z)-undec-2-enal 71277-05- BDF
102 (E)-undec-2-enal 53448-07- BDF
103 (2Z,4Z)-undeca-2,4-dienal 13162-46- BDF
104 (2E,4E)-undeca-2,4-dienal 30361-29- BDF
105 dec-9-enoic acid 14436-32- BDE
106 Cyclohexanecarboxylic acid, 1,3,4,5-tetrahydroxy-, 36413-60-CF
(1a,3R,4a,5R)-rel- 2 108 3-Cyclohexene-1-propanal 22858-74- AC
109 decan-3-ol 1565-81-7 BDEF
110 (E)-undec-8-enal 58296-81- BDF
111 cyclodecanol 1502-05-2 CE
112 nonanedioic acid 123-99-9 CE
113 cyclododecane 294-62-2 BDEF
114 decan-5-ol 5205-34-5 BDEF
115 1-benzy1-2-methyldisulfane 699-10-5 DE
116 dodecane 112-40-3 ADEF
118 methyl nonanoate 1731-84-6 ADEF
119 (1R,2S)-2-pentylcyclopropane-l-carboxylic acid 58650-45-CE
120 2,3,5-trimethylpyrazine 14667-55- AC
121 Bicyclo13.2.1loctan-8-o1, 1,5,8-trimethyl- 84681-91-BCF
122 1-(p-tolyl)ethan-1-01 536-50-5 BC
123 1-(2,2-dimethoxyethoxy)hexane 17597-95- ACEF
124 2-(diethoxymethyl)furan 13529-27- ACE
125 undecan-2-ol 1653-30-1 BDEF
126 (E)-3,7-dimethylocta-1,3,7-triene 502-99-8 AD
127 octanedinitrile 629-40-3 CE
128 7-methoxy-3,7-dimethyloctan-2-ol 41890-92- BCF
129 (E)-3,7-dimethylocta-2,6-dien-1-01 624-15-7 BD
130 1,3,346 methy1-2-thiabicyclo[2.2.21octane 5718-74-1 ADEF
131 4-(2-hydroxyethyl)phenol 501-94-0 CE
132 methyl (E)-non-3-enoate 13481-87- ADEF
133 2-(tert-butyl)cyclohexan-1-one 1728-46-7 ACEF
134 2-hepty1-1,3-dioxolane 4359-57-3 ADEF
135 (2E,4Z)-1,1-diethoxyhexa-2,4-diene 27310-22- ACEF
137 2-(furan-2-y1)-4-methyl-1,3-dioxolane 4359-54-138 decan-4-one 624-16-8 ADF
139 (E)-cyclododecene 1501-82-2 BDEF
140 (4-methoxyphenyl)methanol 105-13-5 CE
142 1,1-diethoxyhexane 3658-93-3 ADEF
143 dodec-1-ene 112-41-4 ADEF
144 2-methoxy-2-phenylethan-1-ol 2979-22-8 BCE
145 (E)-2-isopropy1-5-methylhex-2-en-1-ol 40853-53-BDEF
146 1,7,7-trimethyltricyclo[2.2.1.02,6Theptane 508-32-7 ADEF
147 2-ethyl-4,5-dimethylthiazole 873-64-3 ACEF
148 (E)-1,1-diethoxyhex-2-ene 67746-30- ACEF
149 re1-2-((2R,5S)-5-methyl-5-vinyltetrahydrofuran-2- 5989-33-3 BCF
yl)propan-2-ol 150 3-cyclohexylpropanoic acid 701-97-3 CE
151 1-bromo-4-vinylbenzene 2039-82-9 AD
152 (1S,6R)-3,7,7-trimethylbicyclo14.1.01hept-3-ene 19079-29-ADEF
153 (2S,4S)-4-methyl-2-penty1-1,3-dioxolane 26563-75-ACE
155 4-phenylbutan-1-ol 3360-41-6 CE
156 1-methyl-4-(prop-1-en-2-yl)benzene 1195-32-0 AD
157 (E)-non-2-en-1-y1 acetate 30418-89- BDEF
158 2-methylundecane 31807-55- ADEF
159 undecanoic acid 112-37-8 DEF
160 diethyl 2,3-dihydroxysuccinate 87-91-2 CEF
161 2-ethyloctanoic acid 25234-25- DEF
162 2-(p-tolyl)ethan-1-ol 699-02-5 BCE
163 6-methyl-3-(propan-2-ylidene)-7- 35178-55- BCF
oxabicyclo[4.1.0]heptan-2-one 3 164 (E)-dodec-2-en-1-ol 22104-81- DEF
165 (2E,6Z)-nona-2,6-dien-1-y1 acetate 68555-65- BDE
166 ethyl (Z)-octa-4,7-dienoate 69925-33- ADEF
167 1,2-dimethoxy-4-methylbenzene 494-99-5 AC
168 3-phenylpropyl formate 104-64-3 BCE
169 2-(p-tolyloxy)ethan-1-01 15149-10- CE
170 octan-2-y1 acetate 2051-50-5 ADEF
171 7-methyl-3-methyleneoct-6-enal 55050-40- AD
172 (2E,4E)-dodeca-2,4-dien-1-ol 18485-38- DEF
173 3-(hydroxymethyl)nonan-2-one 67801-33- CF
175 (1S,5S)-6,6-dimethy1-2- 18172-67- ADEF
methy1enebicyc1o[3.1.11heptane 3 176 1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene 555-08-8 ADEF
177 1-methoxy-4-(methoxymethyl)benzene 1515-81-7 ACE
178 (E)-dodec-2-enal 4826-62-4 BDF
179 (2E,4E)-dodeca-2,4-dienal 21662-16- DF
180 2,2,6,6-tetramethy1-4-methyleneheptane 141-70-8 ADEF
181 (E)-3-methylnon-2-enoic acid 35205-76- DEF
182 heptyl propionate 2216-81-1 ADEF
183 undec-10-enoic acid 112-38-9 DEF
184 (E)-2,6-dimethylocta-1,5,7-trien-3-ol 29414-56- BCF
185 (E)-5-(methylthio)-2-((methylthio)methyl)pent-2-enal 59902-01- CF
186 (E)-3-methylnon-3-enoic acid 35205-77- DEF
187 1-methyl-4-(prop-1-en-2-y1)-7- 1195-92-2 ACEF
oxabicyclo[4.1.0Theptane 188 (E)-dodec-3-enal 68083-57- BDF
189 4-(hydroxymethyl)-2-methoxyphenol 498-00-0 190 3,5-diethyl-1,2,4-trithiolane 54644-28- BDEF
191 3,7-di methyloctane-1,6-diol 53067-10- CF
192 1,1-dimethoxynonane 18824-63-ADEF
193 undecan-1-ol 30207-98- BDEF
194 (E)-dodec-4-enal 30390-51- BDF
195 dimethyl heptanedioate 1732-08-7 BC
196 4-allylphenol 501-92-8 BCE
197 (2E,6Z)-dodeca-2,6-dienal 21662-13- DF
198 1-(allyloxy)-2-methoxybenzene 4125-43-3 ACE
199 tridecane 629-50-5 BDEF
200 2,3,5,6-tetramethylpyrazine 1124-11-4 AC
201 3-(5-methylfuran-2-yl)butanal 203 diethyl 2-hydroxysuccinate 626-11-9 CEF
204 (E)-4-phenylbut-3-en-2-ol 17488-65- CE
205 2-pentylcyclopent-2-en-1-one 206 methyl decanoate 110-42-9 BDEF
207 3-methylenenonanoic acid 35205-78- DEF
208 ethyl 2,4-dioxohexanoate 13246-52- BC
209 2-isopropyl-4-methylphenol 4427-56-9 BDF
210 dodecan-2-ol 10203-28- DEF
211 2,6,6-trimethylbicyclo[3.1.11heptane-2-thiol 23832-18-ADEF
212 (Z)-styryl acetate 10521-96- BCE
213 (Z)-9,9-dimethoxynon-3-ene 68555-53- BDEF
214 methyl (2E,4Z)-deca-2,4-dienoate 4493-42-9 BDEF
215 methyl 2,4-dihydroxy-3-methylbenzoate 33662-58-216 2-heptylfuran 3777-71-7 ADEF
217 methyl (Z)-dec-2-enoate 2482-39-5 BDEF
218 3,7-dimethyloct-7-ene-1,6-diol 219 (E)-2-(pent-2-en- I -yl)cyclopentan-l-one 51608-18- AC
220 (1R,2S,3R,5S)-2,6,6-trimethylbicyclo[3.1.1[heptan-3- 25465-65- BCEF
ol 0 222 1-(furan-2-yl)hexan-1-one 14360-50- BC
223 benzo[d][1,3]dioxo1-5-ylmethanol 495-76-1 CE
224 undecane-2,3-dione 7493-59-6 BDF
225 5,5-dimethy1-2-penty1-1,3-dioxane 13273-89- ADEF
226 undecan-4-one 14476-37- BDF
227 2,7,7-trimethy1-3-oxatricyclo[4.1.1.02,4]octane 1686-14-228 octyl propionate 142-60-9 BDEF
229 2-(pentan-3-y1)-4,7-dihydro-1,3-dioxepine 53338-06- ACEF
230 (Z)-2,7-dimethyloct-5-en-4-one
102 (E)-undec-2-enal 53448-07- BDF
103 (2Z,4Z)-undeca-2,4-dienal 13162-46- BDF
104 (2E,4E)-undeca-2,4-dienal 30361-29- BDF
105 dec-9-enoic acid 14436-32- BDE
106 Cyclohexanecarboxylic acid, 1,3,4,5-tetrahydroxy-, 36413-60-CF
(1a,3R,4a,5R)-rel- 2 108 3-Cyclohexene-1-propanal 22858-74- AC
109 decan-3-ol 1565-81-7 BDEF
110 (E)-undec-8-enal 58296-81- BDF
111 cyclodecanol 1502-05-2 CE
112 nonanedioic acid 123-99-9 CE
113 cyclododecane 294-62-2 BDEF
114 decan-5-ol 5205-34-5 BDEF
115 1-benzy1-2-methyldisulfane 699-10-5 DE
116 dodecane 112-40-3 ADEF
118 methyl nonanoate 1731-84-6 ADEF
119 (1R,2S)-2-pentylcyclopropane-l-carboxylic acid 58650-45-CE
120 2,3,5-trimethylpyrazine 14667-55- AC
121 Bicyclo13.2.1loctan-8-o1, 1,5,8-trimethyl- 84681-91-BCF
122 1-(p-tolyl)ethan-1-01 536-50-5 BC
123 1-(2,2-dimethoxyethoxy)hexane 17597-95- ACEF
124 2-(diethoxymethyl)furan 13529-27- ACE
125 undecan-2-ol 1653-30-1 BDEF
126 (E)-3,7-dimethylocta-1,3,7-triene 502-99-8 AD
127 octanedinitrile 629-40-3 CE
128 7-methoxy-3,7-dimethyloctan-2-ol 41890-92- BCF
129 (E)-3,7-dimethylocta-2,6-dien-1-01 624-15-7 BD
130 1,3,346 methy1-2-thiabicyclo[2.2.21octane 5718-74-1 ADEF
131 4-(2-hydroxyethyl)phenol 501-94-0 CE
132 methyl (E)-non-3-enoate 13481-87- ADEF
133 2-(tert-butyl)cyclohexan-1-one 1728-46-7 ACEF
134 2-hepty1-1,3-dioxolane 4359-57-3 ADEF
135 (2E,4Z)-1,1-diethoxyhexa-2,4-diene 27310-22- ACEF
137 2-(furan-2-y1)-4-methyl-1,3-dioxolane 4359-54-138 decan-4-one 624-16-8 ADF
139 (E)-cyclododecene 1501-82-2 BDEF
140 (4-methoxyphenyl)methanol 105-13-5 CE
142 1,1-diethoxyhexane 3658-93-3 ADEF
143 dodec-1-ene 112-41-4 ADEF
144 2-methoxy-2-phenylethan-1-ol 2979-22-8 BCE
145 (E)-2-isopropy1-5-methylhex-2-en-1-ol 40853-53-BDEF
146 1,7,7-trimethyltricyclo[2.2.1.02,6Theptane 508-32-7 ADEF
147 2-ethyl-4,5-dimethylthiazole 873-64-3 ACEF
148 (E)-1,1-diethoxyhex-2-ene 67746-30- ACEF
149 re1-2-((2R,5S)-5-methyl-5-vinyltetrahydrofuran-2- 5989-33-3 BCF
yl)propan-2-ol 150 3-cyclohexylpropanoic acid 701-97-3 CE
151 1-bromo-4-vinylbenzene 2039-82-9 AD
152 (1S,6R)-3,7,7-trimethylbicyclo14.1.01hept-3-ene 19079-29-ADEF
153 (2S,4S)-4-methyl-2-penty1-1,3-dioxolane 26563-75-ACE
155 4-phenylbutan-1-ol 3360-41-6 CE
156 1-methyl-4-(prop-1-en-2-yl)benzene 1195-32-0 AD
157 (E)-non-2-en-1-y1 acetate 30418-89- BDEF
158 2-methylundecane 31807-55- ADEF
159 undecanoic acid 112-37-8 DEF
160 diethyl 2,3-dihydroxysuccinate 87-91-2 CEF
161 2-ethyloctanoic acid 25234-25- DEF
162 2-(p-tolyl)ethan-1-ol 699-02-5 BCE
163 6-methyl-3-(propan-2-ylidene)-7- 35178-55- BCF
oxabicyclo[4.1.0]heptan-2-one 3 164 (E)-dodec-2-en-1-ol 22104-81- DEF
165 (2E,6Z)-nona-2,6-dien-1-y1 acetate 68555-65- BDE
166 ethyl (Z)-octa-4,7-dienoate 69925-33- ADEF
167 1,2-dimethoxy-4-methylbenzene 494-99-5 AC
168 3-phenylpropyl formate 104-64-3 BCE
169 2-(p-tolyloxy)ethan-1-01 15149-10- CE
170 octan-2-y1 acetate 2051-50-5 ADEF
171 7-methyl-3-methyleneoct-6-enal 55050-40- AD
172 (2E,4E)-dodeca-2,4-dien-1-ol 18485-38- DEF
173 3-(hydroxymethyl)nonan-2-one 67801-33- CF
175 (1S,5S)-6,6-dimethy1-2- 18172-67- ADEF
methy1enebicyc1o[3.1.11heptane 3 176 1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene 555-08-8 ADEF
177 1-methoxy-4-(methoxymethyl)benzene 1515-81-7 ACE
178 (E)-dodec-2-enal 4826-62-4 BDF
179 (2E,4E)-dodeca-2,4-dienal 21662-16- DF
180 2,2,6,6-tetramethy1-4-methyleneheptane 141-70-8 ADEF
181 (E)-3-methylnon-2-enoic acid 35205-76- DEF
182 heptyl propionate 2216-81-1 ADEF
183 undec-10-enoic acid 112-38-9 DEF
184 (E)-2,6-dimethylocta-1,5,7-trien-3-ol 29414-56- BCF
185 (E)-5-(methylthio)-2-((methylthio)methyl)pent-2-enal 59902-01- CF
186 (E)-3-methylnon-3-enoic acid 35205-77- DEF
187 1-methyl-4-(prop-1-en-2-y1)-7- 1195-92-2 ACEF
oxabicyclo[4.1.0Theptane 188 (E)-dodec-3-enal 68083-57- BDF
189 4-(hydroxymethyl)-2-methoxyphenol 498-00-0 190 3,5-diethyl-1,2,4-trithiolane 54644-28- BDEF
191 3,7-di methyloctane-1,6-diol 53067-10- CF
192 1,1-dimethoxynonane 18824-63-ADEF
193 undecan-1-ol 30207-98- BDEF
194 (E)-dodec-4-enal 30390-51- BDF
195 dimethyl heptanedioate 1732-08-7 BC
196 4-allylphenol 501-92-8 BCE
197 (2E,6Z)-dodeca-2,6-dienal 21662-13- DF
198 1-(allyloxy)-2-methoxybenzene 4125-43-3 ACE
199 tridecane 629-50-5 BDEF
200 2,3,5,6-tetramethylpyrazine 1124-11-4 AC
201 3-(5-methylfuran-2-yl)butanal 203 diethyl 2-hydroxysuccinate 626-11-9 CEF
204 (E)-4-phenylbut-3-en-2-ol 17488-65- CE
205 2-pentylcyclopent-2-en-1-one 206 methyl decanoate 110-42-9 BDEF
207 3-methylenenonanoic acid 35205-78- DEF
208 ethyl 2,4-dioxohexanoate 13246-52- BC
209 2-isopropyl-4-methylphenol 4427-56-9 BDF
210 dodecan-2-ol 10203-28- DEF
211 2,6,6-trimethylbicyclo[3.1.11heptane-2-thiol 23832-18-ADEF
212 (Z)-styryl acetate 10521-96- BCE
213 (Z)-9,9-dimethoxynon-3-ene 68555-53- BDEF
214 methyl (2E,4Z)-deca-2,4-dienoate 4493-42-9 BDEF
215 methyl 2,4-dihydroxy-3-methylbenzoate 33662-58-216 2-heptylfuran 3777-71-7 ADEF
217 methyl (Z)-dec-2-enoate 2482-39-5 BDEF
218 3,7-dimethyloct-7-ene-1,6-diol 219 (E)-2-(pent-2-en- I -yl)cyclopentan-l-one 51608-18- AC
220 (1R,2S,3R,5S)-2,6,6-trimethylbicyclo[3.1.1[heptan-3- 25465-65- BCEF
ol 0 222 1-(furan-2-yl)hexan-1-one 14360-50- BC
223 benzo[d][1,3]dioxo1-5-ylmethanol 495-76-1 CE
224 undecane-2,3-dione 7493-59-6 BDF
225 5,5-dimethy1-2-penty1-1,3-dioxane 13273-89- ADEF
226 undecan-4-one 14476-37- BDF
227 2,7,7-trimethy1-3-oxatricyclo[4.1.1.02,4]octane 1686-14-228 octyl propionate 142-60-9 BDEF
229 2-(pentan-3-y1)-4,7-dihydro-1,3-dioxepine 53338-06- ACEF
230 (Z)-2,7-dimethyloct-5-en-4-one
5 231 (E)-3-methylnon-2-enenitrile 53153-66- BDEF
232 8-ethy1-1,5-dimethy1bicyc1o13.2.11octan-8-ol 84681-92-BDEF
233 heptyl (Z)-but-2-enoate 16930-99-BDEF
234 dodecan-2-one 6175-49-1 BDF
235 1-ally1-4-methyl benzene 3333-13-236 undec-l-en-3-one 42832-47- BDF
237 heptyl butyrate 5870-93-9 BDEF
238 2,6-dimethoxy-4-methylphenol 6638-05-7 240 propyl octanoate 624-13-5 BDEF
241 (1-ethoxyethoxy)benzene 5426-78-8 ACE
243 ( I S,2S,5S)-2-methyl-5-(prop-1-en-2-y1)cyclohexan- I - 38049-26- BCEF
ol 2 244 (Z)-7,7-diethoxyhept-3-ene 18492-65- ADEF
245 3-pentylpyridine 1802-20-6 ADE
246 5-phenylpentan-1-ol 10521-91- CE
247 rel-(1R,2S,5R)-5-methy1-2-(prop-1-en-2- 50373-36- BCEF
yl)cyclohexan- 1 -ol 9 248 3,5-diisopropy1-1,2,4-trithiolane 54934-99- DEF
249 2-pentylpyri dine 2294-76-0 ADE
250 (IS,2R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-one 547-60-4 ACEF
251 4-ethyloctanoic acid 16493-80- DEF
252 1-methoxy-2,3-dihydro- I H-indene 1006-27-5 ACE
253 (2R,5R)-5-isopropy1-2-methylcyclohexan-1-one 499-70-7 ADEF
254 (Z)-5-(hex-3-en-1-y1)-5-methyldihydrofuran-2(3H)- 70851-61- CEF
one 5 255 allyl octanoate 4230-97-1 BDEF
257 (E)-2-methy1-3-phenylprop-2-en-1-ol 1504-55-8 CE
258 (2S,5R)-2-isopropy1-5-methylcyclohexan-1-one 14073-97-ADEF
259 ethyl non-2-ynoate 10031-92- BDEF
260 (E)-dec-5-en-l-y1 acetate 38421-90-ADEF
261 (E)-2-(3-methylbut-1-en-l-y1)cyclopentan-l-one 2520-60-7 ACE
262 (E)-tridec-2-en-1-01 68480-25- DEF
264 (Z)-4-ethyloct-2-enoic acid 60308-75- DEF
265 dec-9-en-l-y1 acetate 50816-18- BDEF
266 (E)-dodec-2-enoic acid 32466-54-DEF
267 ((1S,2S,5S)-6,6-dimethy1bicyc1o[3.1.11heptan-2- 53369-17-BDEF
yl)methanol 8 268 (E)-hex-3-en-l-y1 2-methylbutanoate 10094-41- BDEF
269 octahydro-1H-4,7-methanoindene 6004-38-2 ADE
270 tridecanal 10486-19- BDF
271 2-methylundecan-1-ol 10522-26-DEF
232 8-ethy1-1,5-dimethy1bicyc1o13.2.11octan-8-ol 84681-92-BDEF
233 heptyl (Z)-but-2-enoate 16930-99-BDEF
234 dodecan-2-one 6175-49-1 BDF
235 1-ally1-4-methyl benzene 3333-13-236 undec-l-en-3-one 42832-47- BDF
237 heptyl butyrate 5870-93-9 BDEF
238 2,6-dimethoxy-4-methylphenol 6638-05-7 240 propyl octanoate 624-13-5 BDEF
241 (1-ethoxyethoxy)benzene 5426-78-8 ACE
243 ( I S,2S,5S)-2-methyl-5-(prop-1-en-2-y1)cyclohexan- I - 38049-26- BCEF
ol 2 244 (Z)-7,7-diethoxyhept-3-ene 18492-65- ADEF
245 3-pentylpyridine 1802-20-6 ADE
246 5-phenylpentan-1-ol 10521-91- CE
247 rel-(1R,2S,5R)-5-methy1-2-(prop-1-en-2- 50373-36- BCEF
yl)cyclohexan- 1 -ol 9 248 3,5-diisopropy1-1,2,4-trithiolane 54934-99- DEF
249 2-pentylpyri dine 2294-76-0 ADE
250 (IS,2R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-one 547-60-4 ACEF
251 4-ethyloctanoic acid 16493-80- DEF
252 1-methoxy-2,3-dihydro- I H-indene 1006-27-5 ACE
253 (2R,5R)-5-isopropy1-2-methylcyclohexan-1-one 499-70-7 ADEF
254 (Z)-5-(hex-3-en-1-y1)-5-methyldihydrofuran-2(3H)- 70851-61- CEF
one 5 255 allyl octanoate 4230-97-1 BDEF
257 (E)-2-methy1-3-phenylprop-2-en-1-ol 1504-55-8 CE
258 (2S,5R)-2-isopropy1-5-methylcyclohexan-1-one 14073-97-ADEF
259 ethyl non-2-ynoate 10031-92- BDEF
260 (E)-dec-5-en-l-y1 acetate 38421-90-ADEF
261 (E)-2-(3-methylbut-1-en-l-y1)cyclopentan-l-one 2520-60-7 ACE
262 (E)-tridec-2-en-1-01 68480-25- DEF
264 (Z)-4-ethyloct-2-enoic acid 60308-75- DEF
265 dec-9-en-l-y1 acetate 50816-18- BDEF
266 (E)-dodec-2-enoic acid 32466-54-DEF
267 ((1S,2S,5S)-6,6-dimethy1bicyc1o[3.1.11heptan-2- 53369-17-BDEF
yl)methanol 8 268 (E)-hex-3-en-l-y1 2-methylbutanoate 10094-41- BDEF
269 octahydro-1H-4,7-methanoindene 6004-38-2 ADE
270 tridecanal 10486-19- BDF
271 2-methylundecan-1-ol 10522-26-DEF
6 272 (2-isothiocyanatoethyl)benzene 2257-09-2 DE
273 3-ethyl-2,4-dioxaspiro[5.5]undec-8-ene 64165-57- BCEF
273 3-ethyl-2,4-dioxaspiro[5.5]undec-8-ene 64165-57- BCEF
7 274 octyl isobutyrate 109-15-9 BDEF
275 2-(3,4-dimethylphenyl)acetaldehyde 68844-97- BCF
276 2-(2,4-dimethylphenyl)acetaldehyde 68083-55- BCF
277 6,6-di methy1-2-methylenebicyclol3.1.11heptan-3-one 16812-40-ACEF
279 (2E,4E)-trideca-2,4-dienal 60998-24- DF
280 1,1-dimethoxy-3,5,5-trimethylhexane 72894-13- ADEF
281 1,3-dimethoxy-5-methylbenzene 4179-19-5 BC
282 (6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yOmethanol 515-00-4 BDEF
283 allyl 2-(2-methylbutoxy)acetate 67634-01- BCEF
284 3-(p-tolyl)propanal 5406-12-2 BC
285 3-ethyl-2,5-dimethylpyrazine 13360-65- ACE
286 8-methylnonyl acetate 69103-24-BDEF
275 2-(3,4-dimethylphenyl)acetaldehyde 68844-97- BCF
276 2-(2,4-dimethylphenyl)acetaldehyde 68083-55- BCF
277 6,6-di methy1-2-methylenebicyclol3.1.11heptan-3-one 16812-40-ACEF
279 (2E,4E)-trideca-2,4-dienal 60998-24- DF
280 1,1-dimethoxy-3,5,5-trimethylhexane 72894-13- ADEF
281 1,3-dimethoxy-5-methylbenzene 4179-19-5 BC
282 (6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yOmethanol 515-00-4 BDEF
283 allyl 2-(2-methylbutoxy)acetate 67634-01- BCEF
284 3-(p-tolyl)propanal 5406-12-2 BC
285 3-ethyl-2,5-dimethylpyrazine 13360-65- ACE
286 8-methylnonyl acetate 69103-24-BDEF
8 287 2-ethyl-3,5-dimethylpyrazine 13925-07- ACE
288 methyl cinnamate 1754-62-7 BCE
289 (4S,4aS,8aR)-4,8a-dimethyloctahydronaphthalen- 19700-21-DEF
4a(2H)-ol 1 290 isopropyl octanoate 5458-59-3 ADEF
291 (E)-2-(hex-2-en-1-yl)cyclopentan-292 2-(2-hydroxypropan-2-yI)-5-methylcyclohexan-1-01 42822-86- CF
293 11-methyldodecan-1-ol 27458-92-DEF
295 (2E,4Z,7Z)-trideca-2,4,7-trienal 13552-96- DF
296 cyclododecanol 1724-39-6 DEF
297 cyclohexyl(pentyl)sulfane 7133-42-8 BDEF
298 tetradecane 629-59-4 BDEF
299 2-(4-methylcyclohex-3-en-1-yl)prop-2-en-1-01 3269-90-7 CF
300 (R)-2-(4-methylcyclohex-3-en-l-yl)prop-2-en-1-01 38142-45-CF
288 methyl cinnamate 1754-62-7 BCE
289 (4S,4aS,8aR)-4,8a-dimethyloctahydronaphthalen- 19700-21-DEF
4a(2H)-ol 1 290 isopropyl octanoate 5458-59-3 ADEF
291 (E)-2-(hex-2-en-1-yl)cyclopentan-292 2-(2-hydroxypropan-2-yI)-5-methylcyclohexan-1-01 42822-86- CF
293 11-methyldodecan-1-ol 27458-92-DEF
295 (2E,4Z,7Z)-trideca-2,4,7-trienal 13552-96- DF
296 cyclododecanol 1724-39-6 DEF
297 cyclohexyl(pentyl)sulfane 7133-42-8 BDEF
298 tetradecane 629-59-4 BDEF
299 2-(4-methylcyclohex-3-en-1-yl)prop-2-en-1-01 3269-90-7 CF
300 (R)-2-(4-methylcyclohex-3-en-l-yl)prop-2-en-1-01 38142-45-CF
9 301 (E)-2-methy1-3-(pent-2-en-1-y1)cyclopent-2-en-1-one 11050-62- BCF
302 dimethyl octanedioate 1732-09-8 CF
304 methyl 3-phenylpropanoate 103-25-3 BCE
305 methyl undecanoate 1731-86-8 BDEF
306 4-isopropyl-2-methoxy- I -methylbenzene 6379-73-3 ADF
307 4,7,7-trimethy1-6-thiabicyclo[3.2.1]octane 68398-18-ADEF
308 (Z)-2-hexylidenecyclopentan-1-one 17373-89- BDF
309 2-isopropyl- 1-methoxy-4-methylbenzene 31574-44-ADF
311 (E)-hex-2-en-1-y1 3-methylbutanoate 68698-59-BDEF ' 312 (2E,6E)-3,7-dimethylnona-2,6-dienal 41448-29-BDF
313 cyclooctyl methyl carbonate 61699-38- DEF
314 benzyl 2-hydroxypropanoate 2051-96-9 C
315 methyl (E)-undec-9-enoate 5760-50-9 BDEF
316 N,N-diethylhexanamide 6282-97-9 BCEF
317 2,5-diethyl-4-methylthiazole 41981-71- ACEF
319 4,7,7-trimethy1-6-thiabicyclo[3.2.11oct-3-ene 6784-08-3 ADEF
320 dodecan-3-one 1534-27-6 BDF
321 2-(1-phenylethyl)-1,3-dioxolane 4362-22-5 BCEF
323 2,6-diisopropylphenol 2078-54-8 DEF
324 2-ethoxy-1,3,3-trimethylbicyclo[2.2.1]heptane 67800-86-ADEF
325 1-methoxy-l-methylcyclododecane 37514-30- BDEF
326 (E)-2-(hex-2-en-1-yl)cyclopentan-1-one 34687-46-BCF
327 1-(3,3-dimethylbicyclo[2.2.11heptan-2-yDethan-1-ol 66062-78- CEF
328 2-(4-methylenecyclohexyl)propanal 89116-22- ACF
329 6-penty1-2H-pyran-2-one 27593-23- CE
330 (S)-4-(prop-I-en-2-yl)cyclohex-1-ene-1-carbaldehyde 18031-40- BCF
331 2-hexy1-5,5-dimethyl- 1,3-dioxane 13273-90- BDEF
332 4- methy1-5-pentyldihydrofuran-2(3H)-one 33673-62-BCEF
333 (4aS,8aS)-4,4,8a-trimethyloctahydronaphthalen- 57963-77-DF
4a(2H)-ol 6 335 3a,4,7,7a-tetrahydro-1H-4,7-methanoindene 54335-17-ADE
336 4-methyl-2-phenyl-1,3-dioxolane 2568-25-4 BCE
337 phenyl butyrate 4346- I 8-3 BCE
338 (Z)-2,3-dimethylnon-2-enenitrile 53153-67- BDEF
339 tridecan-2-one 593-08-8 BDF
340 1,1-diethoxyoctane 54889-48- ADEF
341 octyl (E)-but-2-enoate 22874-79-BDEF
342 cyclohexyl (E)-but-2-enoate 31416-78- BDE
343 3-methyl- 1-phenylbutan-2- ol 705-58-8 ACE
344 1,3-di methylbicyclo[2.2.1]heptane-2-carbonitrile ' 104516-BCEF
345 methyl undec-10-enoate 111-81-9 BDEF
346 1-(4-isopropylphenyl)ethan-1-one 645-13-6 BCEF
347 undecyl acetate 1731-81-3 BDEF
348 dec-1-yn-1-y1 methyl carbonate 1322-34-5 DEF
349 (E)-3-(4-methoxyphenyl)acrylaldehyde 24680-50- C
350 (R)-6-penty1-5,6-dihydro-2H-pyran-2-one 51154-96-DE
2 .
351 3-phenylpropy 1 acetate 122-72-5 BCEF
352 benzo[d][1,3]di oxo1-5-ylmethyl formate 85262-96-C
353 methyl 2-hydroxy-4-methoxybenzoate 5446-02-6 C
354 cyclohexyl butyrate 1551-44-6 ADEF
355 tetradecan-l-ol I 1 2-72-1 DEF
356 octyl butyrate 110-39-4 BDEF
357 propyl nonanoate 6513-03-7 BDEF
358 (6,6-dimethylbicyclo[3.1.1]heptan-2-yl)methanethiol 6588-78-9 ADEF
359 (E)-6-(pent-2-en-l-yl)tetrahydro-2H-pyran-2-one 34686-71-CE
360 heptyl pen tan oate 5451-80-9 BDEF
361 butyl octanoate 589-75-3 BDEF
363 6-phenylhexan-1-ol 2430-16-2 DEF
364 1,7,7-trimethylbicyclo[2.2.1[ heptan-2-y1 formate 1200-67-365 (1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 7492-41-3 ADEF
formate 366 octahydro-1H-4,7-methanoinden-5-ol 13380-89- CEF
367 1-(dimethoxymethyl)-4-methoxybenzene 2186-92-7 ACEF
368 2-hexylpyridine 1129-69-7 ADEF
369 2-(4-isopropylcyclohexyl)ethan-1-01 3650-46-2 DEF
370 (E)-undec-2-en-l-y1 acetate 68480-27- DEF
371 (E)-3-ethyl-2-methylnon-2-enoic acid 71850-80-DEF
372 2-methyl-1-(p-tolyl)propan-2-ol 20834-59- BCEF
374 (E)-2-ethy1-2-(3-methylbut-2-en-l-y1)hex-3-en-1-01 85136-06-DEF
375 allyl 2,2,3-tri methylhexanoate 68132-80- BDEF
376 hexyl (E)-hex-2-enoate 33855-57-BDEF
377 (2,2-dichloro-l-methylcyclopropyl)benzene 3591-42-2 BDF
378 1,2-dimethoxy-4-vinylbenzene 6380-23-0 BCE
380 (E)-5-(prop-1-en-l-y1)benzo[d]
[1,3]dioxole 120-58-1 BCE
381 o-tolyl isobutyrate 36438-54- BCF
382 3-ethylhexahydrobenzofuran-2(3H)-one 54491-17- CEF
383 (Z)-hex-3-en-1-y1 hexanoate 31501-11- BDEF
384 undec-10-en-1-y1 acetate 112-19-6 BDEF
385 (E)-hex-2-en-1-y1 hexanoate 53398-86- BDEF
387 (E)-3-methyl-l-phenylpent-1-en-3-ol 62232-91- CEF
388 (2-hexy1-1,3-dioxolan-4-yl)methanol 1708-35-6 CEF
389 6-ethy1-3-methyloct-5-en-1-ol 26330-64- DEF
390 2-methyl-5,7-dihydrothieno[3,4-dlpyrimidine 36267-71- CE
393 octahydronaphthalen-2(1H)-one 4832-17-1 BCE
394 2-(4-isopropylphenyl)ethan-1-ol 10099-57- BCEF
395 1-methyl-4-(prop-1-en-2-y1)-7- 33204-74- BCEF
oxabicyclo[4.1.0Theptan-2-one 9 396 (Z)-hex-3-en-1-y1 (E)-hex-2-enoate 53398-87- DEF
397 (E)-5,9-dimethyldeca-4,9-dienal 68844-98- DF
398 5-methyl-3,4-dihydronaphthalen-1(2H)-one 6939-35-1 DE
399 4-(tert-butyl)cyclohexyl formate 68039-42- BDEF
400 8-methyl-3,4-dihydronaphthalen-1(2H)-one 51015-28- DE
401 2-hydroxyethyl 2-phenoxyacetate 1984-60-7 403 (E)-tetradec-2-enal 64461-99- DF
404 1-(tert-buty1)-4-methoxy-2-methylbenzene 31268-79- BDF
406 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethan-1- 128-50-7 DEF
ol 407 (E)-(3,3-dimethoxyprop-1-en-l-yl)benzene 4364-06-1 BCEF
408 (4,7,7-trimethy1bicyc1o[4.1.01hept-4-en-3-yOmethanol 15103-32- BDEF
410 (Z)-2-(3,3-dimethylbicyclo[2.2.1]heptan-2- 2226-05-3 CEF
ylidene)ethan-1-ol 411 2,3a'-dimethylhexahydro-2H-spiro[furan-3,2'- 38325-25-CEF
[1,3]dithiolo[4,5-blfuran] 6 412 1,3-dibromo-2-methoxy-4-methy1-5-nitrobenzene 62265-99- DF
413 (Z)-hex-3-en-1-y1 4-oxopentanoate 85554-70- CF
414 2-(tert-butyl)-1-methoxy-4-methylbenzene 43109-72- BDEF
416 1-(tert-buty1)-2-methoxy-4-methylbenzene 88-40-4 A DEF
417 4-isopropyl-1-methylcyclohexyl acetate 26252-11- ADEF
418 (3aR,7aR)-octahydro-5H-4,7-methanoinden-5-one 13380-94- BCEF
420 4-(3-hydroxybutyl)phenol 69617-84- CE
421 2,5,7,7-tetramethyloctanal 114119- BDF
422 2,5,5-trimethy1-2-phenyl-1,3-dioxane 5406-58-6 DEF
423 2-isobuty1-4,5-dimethylthiazole 53498-32- BDF
424 3,5-di methy1-2-propylpyrazine 32350-16- ACEF
426 2-phenylpent-4-enal 24401-36- BC
427 4-hydroxy-3,5-dimethoxybenzaldehyde 134-96-3 428 pentadecane 629-62-9 BDEF
429 allyl 2-aminobenzoate 7493-63-2 430 (E)-4-(3-hydroxyprop-1-en-l-y1)-2-methoxyphenol 458-35-5 431 3,6-dimethy1-5,6,7,7a-tetrahydrobenzofuran-2(4H)- 13341-72- CEF
one 5 433 2-methyl-4-phenylbutanal 40654-82- BC
434 (6,6-dimethylbicyclo[3.1.1Thept-2-en-2-yl)methyl 72928-52- BDEF
formate 0 435 2-octylthiophene 880-36-4 BDEF
436 methyl dodecanoate 111-82-0 BDEF
437 11-methyldodecanoic acid 25448-24- DEF
438 dimethyl nonanedioate 1732-10-1 CF
439 dodecanedioic acid 693-23-2 CEF
440 methyl 4-phenylbutanoate 2046-17-5 BCEF
441 (Z)-2-heptylidenecyclopentan-1-one 39189-74- DF
442 3-(4-methoxyphenyl)butan-2-one 7074-12-6 BCEF
443 2-ethyl-5-methoxybicyclo[2.2.1] heptane 122795- ADEF
444 tridecan-3-one 1534-26-5 BDF
445 (Z)-2-hexylidenecyclohexan-1-one 16429-07- DF
446 2-pentylcyclohex-2-en-1-one 25435-63- BDF
447 1,1,2,3,3-pentamethyloctahydro-1H-indene 33704-60- ADEF
450 methyl 2-(p-tolyloxy)acetate 38768-63- BCE
451 4,6,9-trimethy1-3,5,8,10-tetraoxadodecane 67715-79- BCEF
452 (E)-2-styry1-1,3-dioxolane 5660-60-6 BCE
453 3,5-di methoxybenzoic acid 1132-21-4 C
454 4-ethyl-2,6-dimethoxyphenol 14059-92- CEF
455 2-ethoxy-4-isopropyl-l-methylbenzene 4732-13-2 BDEF
456 ethyl undecanoate 627-90-7 BDEF
458 1,1-diethoxynonane 54815-13- BDEF
459 (E)-3-(3-methoxyphenyl)acrylic acid 6099-04-3 CE
460 2-((1,7,7-trimethylbicyc1o[2.2.1]heptan-2- 7070-15-7 CEF
yl)oxy)ethan-l-ol 461 4-(2,6,6-trimethylcyclohex-1-en- I -yl)butan-2-ol 3293-47-8 DF
463 pentadecan-l-ol 629-76-5 DEF
464 phenyl pentanoate 20115-23- BCEF
465 (E)-4-(2,6,6-trimethylcyclohex-1-en-l-y1)but-3-en-2- 22029-76- DF
ol 1 466 methyl (octahydropentalen-l-y1) carbonate 87731-19- CEF
467 cyclohexyl pentanoate 1551-43-5 BDEF
468 5-(dimethoxymethyl)benzoldll 1,3 ldioxole 59259-90- BCF
469 1,2-bis(allyloxy)benzene 4218-87-5 BDEF
470 1-(4-hydroxy-3,5-dimethoxyphenyl)ethan-1-one 2478-38-8 CEF
471 heptyl hexanoate 6976-72-3 BDEF
472 pentyl octanoate 638-25-5 BDEF
473 allyl 2-cyclohexylacetate 4728-82-9 BDEF
474 tetradecanoic acid 544-63-8 DEF
475 ally! 3,5,5-trimethylhexanoate 71500-37- BDEF
476 3,5-di methylbicyclo[2.2.11heptane-2-carbonitrile 104516-BCEF
477 (E)-dodec-2-en-1-y1 acetate 38363-23- DEF
478 dec-9-en-1-y1 propionate 68480-06- DEF
479 (2-pheny1-1,3-dioxolan-4-yOmethanol 1708-39-0 481 octyl 2-methylbutanoate 29811-50- BDEF
482 (E)-4-(2,6,6-trimethylcyclohex-2-en-l-yl)but-3-en-2- 25312-34- DF
ol 9 483 2-(tert-butyl)-1,4-dimethoxybenzene 21112-37- DF
484 1-allyI-2,2,7,7-tetramethylcycloheptan-l-o! 105463-DF
485 2-butyl-4,6-dimethy1-3,6-dihydro-2H-pyran 24237-01-ADEF
486 (S)-2,5,5-trimethy1-1,2,3,4,5,6,7,8- 670-24-6 DEF
octahydronaphthalen-2-o!
487 1-(naphthalen-1-yl)ethan-1-one 1333-52-4 DE
488 5-ethy1-2-methylnonan-1-ol 68083-56- DEF
489 1-phenylpropan-2-y1 acetate 2114-33-2 BCEF
490 8,8-dimethoxy-2,6-dimethyloctan-2-ol 141-92-4 CEF
491 3-(but-3-en-1-y1)-2,4,4-trimethylcyclohex-2-en-1-one 67401-27- DF
492 2-(4-isopropylcyclohexyl)propan-1-ol 67634-03-DEF
493 2,3-diethyl-5-methylpyrazine 18138-04- ACE
494 3,5-diethyl-2-methylpyrazine 18138-05- ACE
495 (E)-1-(butan-2-ylidene)-2-phenyl hydrazine 1129-62-496 pentadecanal 2765-11-9 DF
497 2-(4-methoxyphenoxy)propanoic acid 13794-15- CF
499 (Z)-2-ethylideneundecanal 6720-16-7 DF
500 1-(1-(hexyloxy)ethoxy)hexane 5405-58-3 BDEF
501 (E)-1-(2,6,6-trimethylcyclohex-3-en-l-yl)but-2-en-1- 71048-82- BDF
one 3 502 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-ol 13720-13-DF
503 (5s,8s)-8-isopropyl-1-oxaspiro[4.5]decan-2-one 4583-26-504 (5r,8r)-8-isopropyl-1-oxaspiro[4.5]decan-2-one 4625-90-5 DEF
505 2,5,5-trimethy1-2,3,4,4a,5,6,7,8-octahydronaphthalen- 643-53-8 DEF
2-ol 506 1,2-di(thiophen-2-yl)disulfane 6911-51-9 DEF
507 2'-methylspiro[bicyclo[2.2.1]heptane-2,5'- 87641-24-ACEF
[1,3]dioxane] 5 508 3,5-diethy1-2,6-dimethylcyclohex-2-en-1-one 65416-17- BDF
509 5-(1-mercaptopropan-2-y1)-2-methylcyclohexane-1- 4802-20-4 DEF
thiol 510 (Z)-4-(4-methylcyclohex-3-en-l-ylidene)pentanal 32540-03-DF
511 (2R,5S,6S)-2,6,10,10-tetramethy1-1- 57967-68- DF
oxaspiro[4.5]decan-6-ol 7 512 cyclododecyl formate 59052-82-DEF
513 methyl 2-(4-methoxyphenyl)acetate 23786-14-514 2-butyl-6-methyl-4-methylenetetrahydro-2H-pyran 24237-02- ADEF
515 heptane-1,1-diy1 diacetate 56438-09- CEF
516 6-methyl-3,4-dihydronaphthalen-1(2H)-one 51015-29- DE
517 ethyl benzo[d][1,3]dioxole-5-carboxylate 6951-08-2 CF
518 7-methyl-3,4-dihydronaphthalen-1(2H)-one 22009-37- DE
519 1-(dimethoxymethyl)-4-isopropylbenzene 67785-72- BDEF
520 hex adecane 544-76-3 DEF
521 (E)-2-(2,6-dimethylhepta-1,5-dien-l-y1)-1,3-dioxolane 66408-78- BDEF
522 5-ethyl-2-methylnonanal 68141-14- BDF
523 (3E,5E)-6,10-dimethylundeca-3,5,9-trien-2-one 141-10-6 DF
524 [1,1'-bi(cyclohexan)]-1'-en-2-one 1502-22-3 DF
525 3-butyl-2,5-dimethylpyrazine 40790-29- ACEF
526 2-butyl-3,5-dimethylpyrazine 50888-63- ACEF
528 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-one 13720-12- BDEF
529 2-isopropy1-2,3-dihydro-1H-inden-1-one 53446-63- DEF
530 (E)-4-(2,3,6-trimethylphenyl)but-3-en-2-one 57461-21- DEF
531 methyl tridecanoate 1731-88-0 DEF
532 2-(4-isopropylphenyl)propanal 533 6,10-dimethylundec-9-en-2-one 534 1,1,6-trimethy1-1,2,3,4-tetrahydronaphthalene 475-03-6 BDEF
535 (E)-6,10-dimethylundeca-5,9-dien-2-one 3796-70-1 BDF
536 dimethyl decanedioate 106-79-6 DF
537 1-(4-methoxy-2,2,6,6-tetramethylcyclohex-3-en-1- 16556-48-DEF
yl)ethan-l-one 2 538 benzo[d][1,3]dioxo1-5-ylmethyl acetate 326-61-4 CF
539 (methoxymethoxy)cyclododecane 42604-12- DEF
540 (E)-6,10-dimethylundeca-3,9-dien-2-one 13835-41- DF
541 1-(4-butylphenypethan-1-one 37920-542 tetradecan-3-one 629-23-2 DF
544 3-propylbicyclo[2.2.1]hept-5-ene-2-carbaldehyde 39067-39-BDF
545 2,5-dimethoxy-NI,N1-dimethylbenzene-1,4-diamine 72066-78- CF
546 (E)-2,6-dimethoxy-4-(prop-1-en-l-y1)phenol 20675-95- CF
547 1,2-bis(furan-2-ylmethyl)disulfane 4437-20-1 DF
548 dibenzo[b,d[furan 132-64-9 DEF
549 (2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 acetate 5655-61-8 BDEF
550 (E)-2-(oct-2-en-l-yl)cyclopentan-1-one 65737-52- DF
551 decahydronaphthalen-2-y1 formate 10519-12- BDEF
552 pentadecan-2-one 2345-28-0 DF
553 p-tolyl (E)-but-2-enoate 41873-74-CE
554 3-phenylpropyl propionate 122-74-7 DEF
555 phenethyl (E)-but-2-enoate 68141-556 (3,3-dimethoxy-2,2-dimethylpropyl)benzene 72727-59- DF
557 (2,2-diethoxyethyl)benzene 6314-97-558 (E)-6,10-dimethylundeca-5,10-dien-2-one 38237-36- DF
559 ethyl 4-phenylbutanoate 10031-93- DEF
561 (E)-4-isopropyl-1-methyl-2-(prop-1-en-l-yl)benzene 14374-92- BDF
562 3-hepty1-5-methyldihydrofuran-2(3H)-one 40923-64- DEF
563 3-methyldodecanenitrile 85351-07- DEF
564 decyl butyrate 5454-09-1 DEF
565 (E)-2,6-dimethylocta-1,5,7-trien-3-y1 acetate 61931-78-BDF
566 (Z)-5-(oct-2-en-l-yl)dihydrofuran-2(3H)-one 18679-18- DEF
567 3-isobuty1-2,5-dimethylpyrazine 32736-94- ACF
568 4,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,1'- 107715- DEF
cyclopentan1-3-one 18-4 569 (E)-1-(2,6,6-trimethylcyclohex-1-en-l-y1)pent-l-en-3- 93840-90- DEF
ol 5 570 2-methyl-4-phenylbutan-2-y1 acetate 103-07-1 DEF
571 allyl cinnamate 1866-31-5 CE
573 p-tolyl butyrate 14617-92- BCEF
574 benzyl pentanoate 10361-39- BDEF
575 butyl decanoate 30673-36- DEF
576 octan-3-y1 butyrate 20286-45- BDEF
578 cyclohexyl hexanoate 6243-10-3 BDEF
579 4-allyI-2-methoxyphenyl formate 10031-96- C
580 hexyl 4-hydroxy-3-methoxybenzoate 84029-93- BDEF
581 1-phenylethyl butyrate 3460-44-4 BDEF
582 (E)-tridec-2-en-1-y1 acetate 68480-26- DEF
583 heptyl heptanoate 624-09-9 DEF
584 2-hexy1-4,4,6-trimethy1-1,3-dioxane 5422-04-8 BDEF
585 4-ally1-2,6-dimethoxyphenol 6627-88-9 CF
587 2,6,8-trimethylnonan-4-one 123-18-2 ADEF
588 (2,8,8-trimethy1-1,2,3,4,5,6,7,8-octahydronaphthalen- 72928-44- DEF
2-yl)methanol 0 589 diethyl octanedioate 2050-23-9 CEF
590 5-isopropyl-2-methylphenyl acetate 6380-28-5 BDF
591 1-(tetrahydrofuran-2-yl)hexyl acetate 67634-08- DEF
592 1,3,3-trimethy1-2-oxabicyclo[2.2.21octan-6-y1 acetate 72257-53-BCF
593 ethyl 2-(cyclopent-2-en-l-yl)pent-4-enoate 84682-17- BDF
594 (E)-3-(4-methoxypheny1)-2-methylacrylaldehyde 65405-67- CF
595 2,3-dimethylquinoxaline 2379-55-7 BCE
597 butyl (E)-dec-2-enoate 7492-45-7 DEF
598 3-oxo-N-phenylbutanamide 102-01-2 CE
599 (5,6-dimethy1-1-(prop-1-en-2-y1)bicyc1o[2.2.1]hept-5- 110458-DEF
en-2-yl)methanol 85-0 600 1-(2,4-dimethylcyclohex-3-en-l-y1)-2,2- 69929-17-BDF
dimethylpropan-l-one 5 601 (E)-3-butylideneisobenzofuran-1(3H)-one 551-08-6 CEF
602 4-methyl- 1, 1 '-biphenyl 644-08-6 BDE
603 41S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2- 1079-01-2 BDEF
yl)methyl acetate 604 oct-1-en-3-y1 butyrate 16491-54-BDEF
605 5-(6-methylhept-5-en-2-yl)dihydrofuran-2(3H)-one 61099-53- DF
606 2-(4-(tert-butyl)-2-methylphenoxy)acetaldehyde 67845-53-DF
607 3-phenylpropyl isobutyrate 103-58-608 (1S,3aR,4S,8aS)-4,8,8-trimethy1-9- 475-20-7 BDEF
methylenedecahydro-1,4-methanoazulene 609 (E)-4-(4-hydroxy-3-methoxyphenyl)but-3-en-2-one 1080-12-2 CEF
610 tetradecahydrocyclododeca[b]furan 72013-84- BDEF
611 ethyl 2-hydroxy-4-methoxy-6-methylbenzoate 6110-36-7 DF
612 1-(2,4-diethylphenyl)ethan-1-one 52191-01- DF
613 3a,4,7b-trimethyloctahydro-2H-4,7a- 67919-67- BDF
ethanonaphtho[1,2-b]oxirene 9 614 (E)-4-(3-hydroxyprop-1-en-l-y1)-2,6- 537-33-7 CF
di methoxyphenol 615 3-butylisobenzofuran-1(3H)-one 6066-49-5 CEF
616 2,4,5-trimethy1-4-phenyl-1,3-dioxane 37922-18-DF
618 heptan-2-y1 hexanoate 6624-58-4 BDEF
619 11-methyldodecyl acetate 69103-23-DEF
620 2-phenylpropyl isobutyrate 65813-621 dibutyl succinate 141-03-7 DEF
622 14-methylpentadecan-1-ol 36311-34-DEF
623 2-(4-methylcyclohex-3-en-1-yl)al lyl acetate 15111-97-DF
624 heptadecane 629-78-7 DEF
625 (1S,3R,6R)-2',2',3,7,7- 121251-BDEF
pentamethylspiro[bicyc1o[4.1.01heptane-2,5'- 67-0 [1,3]dioxane]
626 adamantan-2-ol 700-57-2 CEF
627 (3aS,4S,8S,8aR)-2,2,4-trimethyldecahydro-4,8- 4586-22-5 DEF
methanoazulen-9-ol 628 (E)-3-(4-hydroxy-3,5-dimethoxyphenyl)acrylaldehyde 4206-58-0 CF
629 propane-1,2-diy1 dibutyrate 50980-84- CEF
630 (3E,5E)-3,6,10-trimethylundeca-3,5,9-trien-2-one 1117-41-5 DF
631 2-(4-(formyloxy)-4-isopropylcyclohex-1-en-l-y1)ethyl 72928-49- CF
formate 5 632 (E)-2,5,9-trimethyldeca-4,9-dienal 32803-39- DF
633 diphenylamine 122-39-4 DE
634 (E)-4-(benzo[d][1,3]dioxo1-5-yl)but-3-en-2-one 3160-37-0 CEF
635 (2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 1135-66-6 BDEF
2,4a-methanonaphthalene 637 4-(6,6-dimethy1bicyclo[3.1.1lhept-2-en-2-yl)butanal 38049-28- DF
638 2-methyl-5-(prop-1-en-2-y1)cyclohexyl acetate 20405-60-BDEF
639 (Z)-hex-3-en-1-y1 oct-2-ynoate 68698-58- DEF
640 (1R,5R)-2-methyl-5-(prop-1-en-2-y1)cyclohex-2-en-1- 7111-29-7 DF
yl acetate 641 (1R,2S,5R)-5-methy1-2-(prop-1-en-2-y1)cyclohexyl 57576-09-BDEF
acetate 7 642 dimethyl undecanedioate 4567-98-0 DF
643 6,6-dimethy1-2-methylenebicyclo[3.1.1]heptan-3-y1 1078-95-1 BDEF
acetate 644 2,8,8-trimethyloctahydro-2H-4a,2- 21280-29- DF
(epoxymethano)naphthalen-10-one 5 645 (E)-3,6,10-trimethylundeca-3,9-dien-2-one 68480-10- DF
646 4-methyl-8-methyleneadamantan-2-ol 122760- CEF
647 2-(3-phenylpropyl)tetrahydrofuran 3208-40-0 DEF
648 ethyl 5,5,7-trimethyl-1-oxaspiro[2.51octane-2- 60234-72-DF
carboxylate 2 650 dodecyl 2-hydroxypropanoate 6283-92-7 DEF
651 3-methyl-4-(2,2,6-trimethylcyclohexyl)butan-2-ol 60241-53-DEF
652 isopropyl undec-10-enoate 5459-98-3 DEF
653 (E)-1-(1-ethoxyethoxy)-3,7-dimethylocta-2,6-diene 38019-89-DEF
654 dodecyl propionate 6221-93-8 DEF
655 4,5,6,7,8,9,10,11,12,13- 38303-23- DEF
decahydrocyclododeca[d]oxazole 0 656 (E)-hex-2-en-l-y1 2-hydroxybenzoate 68133-77- DEF
657 hexadecan-2-one 18787-63- DF
658 2-hexy1-2-methylbenzo[d][1,3]dioxole 68298-48- DEF
659 1,1-diethoxyundecane 53405-97- DEF
662 (2R,3'R,3a'S,7'R,8a'S)-3',8',8'- 22037-88- BDEF
trimethyloctahydrospiro[oxirane-2,6'- 3 [3a,7]methanoazulene]
663 adamantan-2-one 700-58-3 BCEF
664 I -benzylpiperazine 2759-28-6 CEF
665 heptadecan-l-ol 1454-85-9 DEF
666 4-(4-methoxypheny1)-3-methylbutan-2-one 67828-19- CEF
668 (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1- 65113-95-DF
yl)pent-3-en-2-one 3 669 2-methyl-l-phenylpropan-2-y1 propionate 67785-77- DEF
670 2,4-di-tert-butylcyclohexan-1-one 13019-04- DEF
671 4,4,6-trimethy1-2-phenyl-1,3-dioxane 2568-06-1 DEF
672 methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate 42245-42-CF
673 cinnamyl butyrate 103-61-7 DEF
674 undecyl butyrate 5461-02-9 DEF
675 ethyl 2-ethyl-3,6,6-trimethylcyclohex-2-ene-1- 58535-04-DEF
carboxylate 9 676 propyl dodecanoate 3681-78-5 DEF
677 butyl cinnamate 538-65-8 DEF
678 allyl 4-cyclohexylbutanoate 7493-65-4 DEF
679 1-(5-isopropy1-2-methylcyclohex-2-en-l-y1)propan-1- 31375-17- BDF
one 4 681 (E)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en- I - 58102-02-DF
yl)but-3-enal 6 682 (E)-2-(hex-2-en-1-yl)cyclopentyl acetate 149982-DEF
683 (E)-2,6,10-trimethylundeca-5,9-dien- 1-01 24048-14- DEF
684 1-methy1-4-(4-methylpentyl)cyclohex-3-ene-1- 66327-54- DF
carbaldehyde 6 685 (R)-1-methy1-4-(1,2,2-trimethylcyclopentyl)benzene 16982-00- BDEF
686 2-(p-tolyloxy)tetrahydro-2H-pyran 13481-09- CEF
687 phenethyl pentanoate 7460-74-4 DEF
688 palmitic acid 57-10-3 DEF
689 (1S,3aR,4R,7R,8aR)-1,4,10,10-tetramethylhexahydro- 38337-32- BDEF
1H,4H-3a,8a-epoxy-4,7-methanoazulene 5 690 1,4,10,10-tetramethylhexahydro-1H,4H-3a,8a-epoxy- 67710-71- BDEF
4,7-methanoazulene 8 691 pentyl decanoate 5933-87-9 DEF
692 benzyl hexanoate 6938-45-0 DEF
693 5-hexyltetrahydrofuran-3-y1 acetate 10039-39-DEF
694 octyl heptanoate 5132-75-2 DEF
695 2-benzy1-4,5-dimethy1-1,3-dioxolane 5468-06-4 BCEF
696 heptyl octanoate 4265-97-8 DEF
697 cyclododecyl acetate 6221-92-7 DEF
698 pentyl 2-phenylacetate 5137-52-0 DEF
699 diethyl nonanedioate 624-17-9 DEF
700 2-benzy1-4-methyl-1,3-dioxane 701 (E)-3-(benzo[d][1,3]dioxo1-5-y1)-2- 6974-47-6 CF
methylacrylaldehyde 702 1-(2,6,6-trimethylcyclohex-2-en-l-yl)pentan-3-one 68480-17-DF
703 2-(tert-butyl)-4-methylcyclohexyl acetate 115724-BDEF
705 (3R,3aS,7S,8aS)-3,6,8,8-tetramethy1-2,3,4,7,8,8a- 469-61-4 BDEF
hexahydro-1 H-3a,7-methanoazulene 706 (2-(1-butoxyethoxy)ethyl)benzene 64577-9 1 - DEF
707 (5,7,7-trimethylbicyclo[4.1.0]hept-4-en-3-yOmethyl 15103-33-BDEF
acetate 0 708 (S,E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol 1119-38-6 DEF
709 3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-blfuran 21582-36- DEF
710 (Z)-2-(3,3-dimethylbicyclo [2.2.1] heptan-2- 2226-03-1 DEF
ylidene)ethyl acetate 711 dodecyl isobutyrate 6624-71-1 DEF
712 diisopropyl adipate 6938-94-9 BCEF
713 2-(cyclohexylmethyl)pyrazine 714 (E)-2,6,10-trimethylundeca-5,9-dienal 24048-13-DF
715 2,6-di-tert-butyl-4-(hydroxymethyl)phenol 882-33-7 DEF
716 (Z)-2-benzylidenehexanal 7492-44-6 DF
717 (8E,11E,14E)-heptadeca-1,8,11,14-tetraene 71046-96-DEF
718 2-methyl-1-phenylpropan-2-y1 isobutyrate 59354-71-DEF
719 p-tolyl 3-methylbut-2-enoate 24700-20- DEF
720 1',2',3,3',3a',4,4',6',7',7a'-decahydrospiro[pyran-2,5'- 26244-[4,7]methanoindene] 9 721 1,2-dicyclohexyldisulfane 2550-40-5 DEF
724 5,5,6,7,7-pentamethylhexahydroindeno[3a,4-b]oxiren- 33704-62- CEF
4(1aH)-one 0 725 (4E,6E)-7,11-dimethyldodeca-4,6,10-trien-3-one 26651-96-DF
726 2,5-di-tert-butylbenzene-1,4-diol 727 2-hexylnonanoic acid 37165-63- --DEF
728 octadecane 593-45-3 DEF
729 8-(sec-butyl)quinoline 67634-06--- DEF
731 2-methoxy-4-(4-methyl-1,3-dioxolan-2-yl)phenol 68527-74- -- CF
732 4-(3,4-dimethoxyphenyl)butan-2-one 6302-60-9 CEF
733 (Z)-2-(furan-2-ylmethylene)octanal 67801-17- DF
734 (E)-1-(4-methoxyphenyl)pent-l-en-3-one 104-27-8 -- CF
735 3-(4-isopropylpheny1)-2-methylpropan- 1-01 4756-19-8 -- DEF
736 decahydronaphthalen-2-y1 acetate 10519-11- BDEF
737 decyl 3-methylbutanoate 72928-48--- DEF
738 (E)-6-(2,2,3-tri methylcyclopent-3-en-1-yl)hex-5-en-3- 68480-05- DEF
ol 7 739 1-(benzo[ d][1,31dioxo1-5-yl)butan-2-one 23023-13- -- CF
740 6-(tert-butyl)quinoline 68141-13--- DEF
741 (1aS,4aS,7R,8aS)-4,4,8,8-tetramethyloctahydro-4a,7- 26619-69- BDEF
methanonaphtho[1,8a-b]oxirene 2 742 p-tolyl 3-methylbutanoate 55066-56--- BDEF
743 ethyl (1 S,2R,3R,4S)-3-isopropylbicyclo[2.2.11hept-5- 116126- --BDEF
ene-2-carboxylate 82-0 744 methyl 2-(4-(tert-butyl)phenyl)acetate 3549-23-3 -- DF
745 palmitonitrile 629-79-8 DEF
746 (Z)-hex-3-en-1-y1 non-2-ynoate 68480-29- DEF
747 di methyl dodecanedioate 1731-79-9 -- DF
748 1-(1,1,3-trimethy1-2,3,4,5,6,7-hexahydro-IH-inden-5- 87641-23- DF
yl)ethan-l-one 4 750 methyl 2-propionamidobenzoate 25628-84- -- CF
751 10-methy1-1,2,3,4,5,6,7,8,9,10-decahydro-5,9- 22690-27- --DF
methanobenzo[8[annulen-11-one 3 752 methyl 1,6-dimethy1-5-(prop-1-en-2- 68698-57- -- DF
y1)bicyclo[2.2.11hept-5-ene-2-carboxylate 7 753 4-methoxybenzyl butyrate 6963-56-0 -- CEF
754 6-nonyltetrahydro-2H-pyran-2-one 2721-22-4 DEF
755 3-(2-oxopropy1)-2-pentylcyclopentan-1-one 40942-73- -- CF
757 cinnamyl (E)-2-methylbut-2-enoate 61792-12- DEF
758 3-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1- 51414-25- CF
carbaldehyde 6 759 phenethyl furan-2-carboxylate 7149-32-8 DF
760 4,9,12,12-tetramethy1-5- 1209-61-6 BDEF
oxatricyclo[8.2Ø04,6]dodecane 762 2-i sobutylqui noline 1333-58-0 DEF
763 2-((1R,3S,4S)-4-methy1-3-(prop-1-en-2-y1)-4- 639-99-6 DEF
vinylcyclohexyl)propan-2-ol 764 4-(tert-butyl)cyclohexyl propionate 68797-70- BDEF
765 (octahydro-1H-4,7-methanoinden-2-yl)methyl formate 64644-32- DEF
766 dodecyl butyrate 3724-61-6 DEF
767 (E)-3-(4,7,7-trimethylbicyclo[4.1.0Theptan-3- 68804-02-DEF
ylidene)propanenitrile 4 768 1-phenylpropyl butyrate 10031-86- DEF
769 (E)-1-(4-methoxypheny1)-4-methylpent-l-en-3-one 103- I 3-9 CEF
770 (2R,4aR,8aS)-1,1,5,5-tetramethylhexahydro-2H-2,4a- 29461-13- DEF
methanonaphthalen-8(5H)-one 0 771 2-phenethylpyridine 2116-62-3 BDEF
772 4,6-dimethy1-2-phenyl-3,6-dihydro-2H-pyran 68039-41- BDEF
773 ( I R,9S,Z)-4,11,11-trimethy1-8- 118-65-0 BDEF
methylenebicyclo[7.2.01undec-4-ene 774 (Z)-3-phenylally1 pentanoate 10482-65- DEF
775 ethyl 2-methyl-3-(p-tolypoxirane-2-carboxylate 108492-CF
776 butyl dodecanoate 106-18-3 DEF
777 (E)-2,3-dimethy1-4-(2,6,6-trimethylcyclohex-2-en- 1- 68140-49- DF
yl)but-3-enal 8 778 3-phenylpropyl pentanoate 5451-88-7 DEF
779 3,6,6,7a-tetramethyloctahydro-2H-2a,7- 29597-36- BDEF
methanoazuleno[5,6-13]oxirene 2 780 cinnamyl 2-methylbutanoate 67883-77- DEF
781 (E)-4-methyl-2-styry1-1,3-dioxane 5420-98-4 CEF
782 benzo[d]1-1,3 klioxo1-5-ylmethyl isobutyrate 5461-08-5 CF
783 phenethyl hexanoate 6290-37-5 DEF
784 3,7-di methylocta-1,6-dien-3-y1 pentanoate 10471-96- DEF
785 diethyl decanedioate 110-40-7 DEF
786 hexyl 2-phenylacetate 5421-17-0 DEF
787 6-isopropyldecahydronaphthalen-2-ol 34131-99- DEF
788 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienal 502-67-0 DF
789 4-(3-oxobutyl)phenyl acetate 3572-06-3 CF
790 1,7,7-trimethylbicyclo12.2.1]heptan-2-y1 isobutyrate 50277-27-BDEF
792 ethyl 3-(4-methoxyphenyl)oxirane-2-carboxylate 16546-01- CF
793 2-methyl-34(1,7,7-trimethylbicyclo[2.2.1]heptan-2- 1281 I 9-DEF
yl)oxy)propan-l-ol 70-0 794 (E)- I -(((E)-non-2-en-l-yl)oxy)non-2-ene 68555-30- DEF
795 methyl 3-(bicyclo12.2.11hept-5-en-2-y1)-3- 72175-33-BCEF
methyloxirane-2-carboxylate 8 796 (E)-hex-2-en-1-y1 2-phenylacetate 797 (Z)-hex-3-en-1-y1 2-phen ylacetate 799 3-(4-(tert-butyl)pheny1)-2-methylpropan-1-ol 56107-04-DEF
800 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 4951-48-8 BDEF
propionate 801 2-methyl-4-methylene-6-phenyltetrahydro-2H-pyran 30310-41- BDEF
802 2-isopropyl-5-methylcyclohexyl 2-hydroxypropanoate 17162-29- DF
803 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl (S)-2- 61597-98-DF
hydroxypropanoate 6 804 4,7,7-trimethy1-4-(3-methylbut-2-en-1- 74499-59- DF
yl)bicyclo[4.1.0]heptan-3-one 5 805 4,4,8-trimethyltricyclo[6.3.1.02,51dodecan-1-y1 58096-46-DEF
formate 1 806 (Z)-2-methyl-1-(2,2,6-trimethylcyclohex-3-en-1- 68555-94-DF
yl)pent-l-en-3-one 2 807 3-((2-isopropy1-5-methylcyclohexyl)oxy)propane-1,2- 87061-04- CEF
diol 9 808 nonadecane 629-92-5 DEF
809 (Z)-2-benzylideneheptanal 1331-92-6 DF
810 4-(tert-butyl)cyclohexyl isobutyrate 5451-57-0 BDEF
811 (E)-1-(1-ethoxyethoxy)-2-methoxy-4-(prop-1-en-1- 84029-92-DF
yl)benzene 5 812 2-methyl-4-phenylbutan-2-y1 isobutyrate 10031-71- DEF
813 4,7,7-trimethy1-2-(3-methylbut-2-en-1- 74499-58- DF
yObicyclo14.1.01heptan-3-one 4 814 (E)-2-(( I S,3aR,4S,8aS)-4,8,8-trimethyldecahydro-I,4- 5989-05-9 DEF
methanoazulen-9-ylidene)ethan- I -ol 815 2,6,10,10-tetramethyl-l-oxaspirol-4.51decan-6-y1 72541-09-DF
acetate 4 816 6-i sopropyloctahydronaphthalen-2(1H)-one 34131-98- DEF
817 (2E,6E)-1-methoxy-3,7,11-trimethyldodeca-2,6,10- 15130-76-DEF
triene 4 818 cinnamyl 3-methyl butanoate 140-27-2 DEF
819 (octahydro-1H-4,7-methanoi nden-l-yl)methyl acetate 30772-69- DEF
820 7-ethoxy-4-methyl-2H-chromen-2-one 87-05-8 CF
821 isobutyl dodecanoate 37811-72-DEF
822 (S)-1-methy1-4-(6-methylhepta- I ,5-dien-2- 495-61-4 DEF
yl)cyclohex-1-ene 823 (E)-4-methy1-6-(2,2,3-trimethylcyclopent-3-en-1- 67801-19-DEF
yl)hex-4-en-3-ol 8 824 (E)-4-(2,6,6-trimethylcyclohex- 1 -en-l-yl)but-3-en-2- 22030-19-DF
yl acetate 9 825 4-(2,2,6-trimethylcyclohexyl)butan-2-y1 acetate 68555-59-DEF
826 3-phenylpropyl 3-methylbutanoate 5452-07-3 DEF
827 2-methyltetradecahydrocyclododecalblfuran 86505-83- DEF
828 3,8,8-trimethy1-6-methyleneoctahydro-IH-3a,7- 28231-03- DEF
methanoazulen-5-ol 0 829 phenyl 2-hydroxybenzoate 118-55-8 DF
830 (3R,3aR,6S,7S,8aS)-3,6,8,8-tetramethylhexahydro- 13794-73-DEF
1H-3a,7-methanoazulen-5(4H)-one 5 831 3,7-dimethylocta-1,6-dien-3-y1 3-methylbutanoate 1118-27-0 DF
832 (E)-4-methyl-6-(2,2,3-trimethylcyclopent-3-en-1- 67801-25-DEF
yl)hex-5-en-3-ol 6 833 8,8-dimethy1-1,2,3,4,5,6,7,8-octahydronaphthalene-2- 72928-51- DEF
carbonitri le 9 834 methyl 2-((1R,2R)-3-oxo-2-pentylcyclopentyl)acetate 2630-39-9 CF
835 I -(4,4-dimethy1-1,2,3,4-tetrahydronaphthalen-1- 74499-60-DF
yl)propan-l-one 8 836 8,12-di methyltridec-1 I -en-6-one 68141-18- DF
837 (E)-4-(2,6,6-trimethylcyclohex-2-en-l-yl)but-3-en-2- 52210-18- DF
yl acetate 1 838 propyl (E)-3-(4-methoxyphenypacrylate 68141-12- DEF
839 2-ethoxy-4-(4-methyl-1,3-dioxolan-2-yl)phenol 68527-76- CF
840 2-(4-methylcyclohex-3-en- I -yl)propan-2-y1 butyrate 2153-28-8 DEF
841 5,5,8a-trimethyldecahydronaphthalen-2-y1 acetate 24238-95-DEF
842 3-benzylheptan-4-one 7492-37-7 DF
843 ethyl pentadecanoate 41114-00-DEF
844 (2-(benzyloxy)ethyl)benzene 54894-37- DEF
846 2-isobutoxynaphthalene 2173-57-1 DEF
847 hexadecyl acetate 629-70-9 DEF
848 1,1,7-trimethyldecahydro-3a,7- 58096-47- DEF
methanocyclopent481annulen-3-y1 formate 2 849 1,7,7-trimethylbicyc1o[2.2.1[heptan-2-y1 butyrate 13109-70-BDEF
850 heptadecan-9-one 540-08-9 DE
851 1-ethoxy-4-(1-ethoxyviny1)-3,3,5,5- 36306-86-DEF
tetramethylcyclohex-l-ene 2 852 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-y1 68479-99-DF
acetate 2 853 4-(3-phenylpropyl)pyridine 2057-49-854 3-(3-phenylpropyl)pyridine 1802-34-855 allyl 6-cyclohexylhexanoate 7493-856 (2R,4a'R,8a'R)-3,6'-dimethy1-3',4',4a',5',8',8a'- 41723-98-DEF
hexahydro-l'H-spiro[oxirane-2,2'- 2 [1,4]methanonaphthalene]
857 ((2S,4aR)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro- 61826-53- DEF
2H-2,4a-methanonaphthalen-8-yl)methanol 7 858 (octahydro-1H-4,7-methanoindene-2,5- 28132-01-CEF
diyedimethanol 6 859 (1R,5S,9S,E)-4,11,11-trimethy1-8- 32214-88- DEF
methylenebicyclo[7.2.0jundec-3-en-5-ol 3 860 stearic acid 57-11-4 DEF
861 2-ethylbutyl 2-(cyclopent-1-en-l-y1)acetate 68092-41- DEF
862 1-(4-butoxy-2,2,6,6-tetramethylcyclohex-3-en-1- 16556-52-DF
yl)ethan-l-one 8 863 2,6-di-tert-butyl-4-(hydroxymethyl)phenol 88-26-6 DEF
864 (E)-2-methyl- -( I -methylbicyclo[2.2.11hept-5-en-2- 67739-11-DEF
yl)pent-l-en-3-ol 1 865 pentyl dodecanoate 5350-03-8 DEF
866 cinnamyl hexanoate 6994-20-3 DEF
867 (E)-1-(3,5,6-trimethylcyclohex-3-en-l-yl)pent-I-en-3- 67801-32- DF
one 5 868 (E)-1-(2,4,6-trimethylcyclohex-3-en-l-yl)pent-l-en-3- 67801-30- DF
one 3 869 ethyl 3-(3,3-dimethylbicyclo[2.2.1]heptan-2- 22833-73- DEF
yl)propanoate 4 870 3-phenylpropyl hexanoate 6281-40-9 DEF
871 2-((3S,3aS,5R,8S,8aS)-3,8-dimethyldecahydroazulen- 3526-75-8 DEF
5-yl)propan-2-ol 872 benzyl octanoate 10276-85-DEF
873 (2E,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal 4955-32-2 DE
874 2,3-dihydroxypropyl dodecanoate 142-18-7 DEF
875 (E)-hex-3-en-1-y1 cinnamate 68133-876 1-(2,5,5-trimethy1-1,3,4,5,6,7-hexahydro-2H-2,4a- 32388-56-DEE
ethanonaphthalen-8-yl)ethan-l-one 0 877 2,3-dihydroxypropyl 5-hydroxydecanoate 26446-31-CEF
878 2-methylbutyl cinnamate 4654-29-9 DEF
879 cyclohexyl 2-(cyclopent-2-en- I -yl)acetate 65405-69-DF
880 1,2-dimethy1-4-(1-phenylethyl)benzene 6196-95-8 DEF
881 (E)-2-methoxy-1-(pentyloxy)-4-(prop- I -en- I - 10484-36-DEF
yl)benzene 3 884 oxacyclohexadecane-2,13-d ione 38223-29- DEF
885 2-methyl-3-(2-methyl-5-(prop-1-en-2-y1)cyclopent-1- 54043-73- DEF
en-l-yl)propyl acetate 1 886 [1,1'-bi(cyclopentan)]-2-y1 (E)-but-2-enoate 68039-73-DEF
887 (3R,3aR,7S,8aS)-3,6,8,8-tetramethy1-1,2,3,7,8,8a- 30960-39-DF
hexahydro-4H-3a,7-methanoazulen-4-one 5 888 1-(2,3,8,8-tetramethy1-1,2,3,5,6,7,8,8a- 68155-66-DF
octahydronaphthalen-2-yl)ethan-1-one 8 889 naphthalen-l-yl butyrate 3121-70-8 DEF
890 diisobutyl adipate 141-04-8 DEF
891 7-isopropyl-5-methylbicyclo[2.2.2loct-5-ene-2- 68311-05-DEF
carbonitrile 7 894 (E)-chalcone 614-47-1 DEF
895 (E)-4-(1,3a,4,6,7,7a-hexahydro-5H-4,7- 126646-DEF
methanoinden-5-ylidene)butan-2-ol 14-8 896 (E)-3-((2,6,6-trimethylcyclohex-2-en-1- 26903-19-DF
ylidene)methyl)hex-5-en-2-one 5 897 (octahydro-1H-4,7-methanoinden-2-yl)methyl acetate 64644-34- DEF
898 o-tolyl 2-hydroxybenzoate 617-01-6 DF
899 (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid 463-40-1 DEF
901 methyl (E)-3-methyl-3-(2-(2,6,6-trimethylcyclohex-2- 67905-40- DF
en-l-yl)vinyl)oxirane-2-carboxylate 2 902 3-methyl-4-(2,2,6-trimethylcyclohexyl)butan-2-y1 60241-55-DEF
acetate 6 903 (3aR,5aS,9aS,9bR)-3a,6,6,9a- 564-20-5 DEF
tetramethyldecahydronaphtho[2,1-b]furan-2(1H)-one 904 (E)-3-methy1-4-(2,6,6-trimethylcyclohex-2-en-1- 68555-61-DF
yl)but-3-en-2-y1 acetate 3 905 (E)-5-methyl-1-(2,6,6-trimethylcyclohex-2-en-1- 70092-23-DF
yl)hex-1-en-3-one 8 906 decahydronaphthalen-2-y1 isobutyrate 67874-78-DEF
907 p-tolyl benzoate 614-34-6 DF
908 butyl tetradecanoate 110-36-1 DEF
909 4-(benzo[d][1,3]dioxo1-5-yl)butan-2-y1 acetate 68844-96-CF
910 hexyl dodecanoate 34316-64- DEF
911 heptyl cinnamate 10032-08- DEF
912 10,11-dihydro-5H-dibenzo[a,d]
Plannulen-5-one 1210-35-1 DEF
913 (4E,8E)-2,6,10-trimethy1-13- 14840-89- DEF
oxabicyclo[10.1.0]trideca-4,8-diene 2 914 (3aR,4aR,8aS,9aR)-3a,4,4a,5,8,8a,9,9a-octahydro-1H- 7158-25-0 DEF
4,9:5,8-dimethanocyclopenta[b]naphthalene 915 phenethyl octanoate 5457-70-5 DEF
916 octyl 2-phenylacetate 122-45-2 DEF
917 cyclohexyl 2-phenylacetate 42288-75- DF
918 p-tolyl octanoate 59558-23- DEF
919 ((2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 61826-52- DEF
2,4a-methanonaphthalen-8-yl)methyl formate 6 920 5,5,7,8,8-pentamethy1-5,6,7,8-tetrahydronaphthalene- 113221-DF
2-carbaldehyde 73-1 921 (S,Z)-3,7,11-trimethyldodeca-1,6,10-trien-3-y1 acetate 56001-43- DF
922 4-methyl-8-methyleneadamantan-2-y1 acetate 122760- DEF
923 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 3- 1142-85-4 DEF
methylbutanoate 924 1,1,3-trimethy1-3-pheny1-2,3-dihydro-1H-indene 3910-35-8 DF
925 henicosane 629-94-7 DEF
926 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-y1 68039-39- DEF
isobutyrate 4 927 (4R,4aS,6R,8aS)-4,4a-dimethy1-6-(prop-1-en-2- 20489-53- DEF
yl)octahydronaphthalen-2(1H)-one 6 928 (E)-3-methy1-4-(2,6,6-trimethylcyclohex-1-en-1- 76649-19- DF
yl)but-3-en-2-y1 acetate 9 929 heptyl undec-10-enoate 68141-27-DEF
931 1-(3,6,8,8-tetramethy1-2,3,4,7,8,8a-hexahydro-1H- 68039-35- DF
3a,7-methanoazulen-5-yl)ethan-l-one 0 932 2-(1,1,2,3,3-pentamethy1-2,3-dihydro-1H-inden-5- 1217-08-9 DEF
yl)propan-l-ol 933 isobutyl tetradecanoate 25263-97-DEF
934 5-(diethoxymethyl)-3a,4,5,6,7,7a-hexahydro-IH-4,7- 67633-92- DEF
methanoindene 5 935 propane-1,2,3-triy1 tripropionate 139-45-7 CEF
936 8-(tert-butyl)-4,6-dimethyl-2H-chromen-2-one 17874-34- DF
937 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646-DEF
methanoinden-5-y1)-3-methylbut-3-en-2-ol 07-9 938 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646-DEF
methanol nden-6-y1)-3-methylbut-3-en-2-ol 06-8 939 p-tolyl 2-hydroxybenzoate 607-88-5 DF
940 ethyl heptadecanoate 14010-23-DEF
941 2-((4-isopropylcyclohex-1-en-1- 56175-55- DF
yl)methyl)cyclopentan-l-one 4 943 cinnamyl benzoate 5320-75-2 DF
944 4-(5,5,6-trimethylbicyclo[2.2.1]heptan-2- 66068-84-DEF
yl)cyclohexan-l-ol 6 945 (7,7,8,8-tetramethyloctahydro-2,3b- 59056-70- DEF
methanocyclopenta[1,3]cyclopropa[1,2]benzen-4- 1 yl)methyl formate 946 1,3-diphenylpropan-2-one 102-04-5 DEF
947 2-isopropyl-5-methylcyclohexyl 3-methylbutanoate 16409-46-DEF
948 methyl (E)-2-(octylideneamino)benzoate 67801-44-DEF
949 1,1,3,3,5-pentamethy1-4,6-dinitro-2,3-dihydro-1H- 116-66-5 DF
indene 950 (2,2-diisobutoxyethyl)benzene 68345-22- DEF
951 2,2-dimethy1-3-(2-methyl-5-(prop-1-en-2- 84012-64-DEF
yl)cyclopent-l-en-l-y1)propyl propionate 6 952 methyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 301-00-8 DEF
953 diisopentyl 2-mercaptosuccinate 68084-03- DEF
954 3-((2R)-5,5,6-trimethylbicyclo [2.2.1] heptan-2- 3407-42-9 DEF
yl)cyclohexan-l-ol 956 isopentyl (E)-3-(4-methoxyphenyl)acrylate 71617-10-DF
957 diisopropyl decanedioate 7491-02-3 DEF
958 3-ethyl-5,5,8,8-tetramethy1-5,6,7,8- 58243-85-DF
tetrahydronaphthalene-2-carbaldehyde 9 959 (E)-2-((lS,3aR,4S,8aS)-4,8,8-tri methyldecahydro-1,4- 27530-63-DEF
methanoazulen-9-ylidene)ethyl acetate 8 960 (1S)-3-((Z)-benzylidene)-1,7,7- 36275-29- DEF
trimethylbicyclo[2.2.1]heptan-2-one 3 961 (Z)-3-benzylidene-1,7,7- 15087-24- DEF
trimethylbicyclo[2.2.1]heptan-2-one 8 962 isopentyl tetradecanoate 62488-24- DEF
964 3-(5,5-dimethy1-6-methylenebicycloi 2.2.1Theptan-2- 68141-24-DEF
yl)cyclohexan-l-ol 2 965 ((3R,3aS,7R,8aS)-3,8,8-trimethy1-2,3,4,7,8,8a- 1405-92-1 DEF
hexahydro-1H-3a,7-methanoazulen-6-yl)methyl acetate 966 ethyl stearate 111-61-5 DEF
967 bis(2,4-dihydroxyphenyl)methanone 131-55-5 CEF
968 6,10,14-trimethylpentadecan-2-one 13955-74- DEF
3 _________________________________________________________ 969 2-methoxyphenyl 2-phenylacetate 4112-89-4 DF
970 5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-l-y1)-5- 117933-DEF
methyl-1,3-dioxane 89-8 971 (5E,9E)-6,10,14-trimethylpentadeca-5,9,13-trien-2- 1117-52-8 DF
one 972 1-(3-ethy1-5,5,8,8-tetramethy1-5,6,7,8- 88-29-9 DF
tetrahydronaphthalen-2-yl)ethan-1-one 973 2-(4-ally1-2-methoxyphenoxy)tetrahydro-2H-pyran 72066-75- CF
974 butyl palm itate 111-06-8 DEF
976 hexyl tetradecanoate 42231-99- DEF
977 ethyl oleate 111-62-6 DEF
978 decyl decanoate 1654-86-0 DEF
979 m-tolyl 2-phenylacetate 122-27-0 DF
980 1-(3,3-diethoxy-2-methylpropy1)-4-isopropylbenzene 7149-24-8 DEF
981 tricosane 638-67-5 DEF
982 ethyl (9Z,12Z)-octadeca-9,12-dienoate 544-35-4 DEF
983 ethyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 1191-41-9 DEF
984 1,3,3-trimethylbicyclo[2.2.1]heptan-2-y1 benzoate 55066-54-DEF
985 dibutyl phthalate 84-69-5 DEF
986 isobutyl pal mitate 110-34-9 DEF
987 2-isopropoxy-1,2-diphenylethan-1-one 6652-28-4 DEF
988 2-ethyl-4,5-dimethylthiazole 87-29-6 DF
989 dibutyl decanedioate 109-43-3 DEF
990 (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-y1 2639-68-1 DF
isobutyrate 991 2-methoxy-4-(1,7,7-trimethylbicyclo[2.2.11heptan-2- 13746-56- DEF
yl)phenol 0 992 methyl (E)-2-((2-phenylethylidene)amino)benzoate 67785-76-DF
993 methyl (E)-2-((3,5,5- 67801-42- DEF
trimethylhexylidene)amino)benzoate 7 994 2-(2-(3,3,5-trimethylcyclohexyl)acetyl)cyclopentan-1- 84642-57- DEF
one 9 995 phenethyl cinnamate 103-53-7 DF
996 methyl (E)-2-(decylideneamino)benzoate 67874-67- DEF
997 3,3,5-trimethylcyclohexyl 2-hydroxybenzoate 118-56-9 DF
998 (2S,4R)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 51-6 999 (2S,4S)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 52-7 1000 cinnamyl 2-phenylacetate 7492-65-1 DF
1001 2-butoxy-1,2-diphenylethan-1-one 22499-11- DF
1002 (2,2-bis(isopentyloxy)ethyl)benzene 68555-28-DEF
1003 3,7-dimethylocta-1,6-dien-3-y1 2-phenylacetate 7143-69-3 DF
1004 ((ethane-1,1-diylbis(oxy))bis(ethane-2,1- 122-71-4 DEF
diy1))dibenzene 1005 (6E,10E)-3,7,11,15-tetramethylhexadeca-6,10,14- 70851-60-DEF
trien-3-ol 4 1006 (E)-3,7-dimethylocta-2,6-dien-l-y1 2-am inobenzoate 67874-69-DF
1007 3,7-dimethyloct-6-en-1-y1 2-aminobenzoate 68555-57- DF
1008 (6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14- 2211-30-5 DF
tetraen-3-ol 1009 2-isobutoxy-1,2-diphenylethan-1-one 22499-12-DEF
1010 4-ally!-1-(benzyloxy)-2-methoxybenzene 57371-42-DF
1011 (1R)-1,7,7-trimethy1-3-((Z)-4- 36861-47- DEF
methylbenzylidene)bicyclo[2.2.1]heptan-2-one 9 1012 1-(4-hydroxy-3-methoxyphenyl)decan-3-one 27113-22- DF
1013 methyl 3-(3,5-di-tert-butyl-4- 6386-38-5 DEF
hydroxyphenyl)propanoate 1014 3,7,11,15-tetramethylhexadec-1-yn-3-ol 29171-23-DEF
1015 2-hydroxypropyl stearate 142-75-6 DEF
1016 3-phenylpropyl cinnamate 122-68-9 DF
1017 7,11,15-trimethy1-3-methylenehexadec-1-ene 504-96-1 DEF
1018 decyl dodecanoate 36528-28- DEF
1019 (7R,11R,E)-3,7,11,15-tetramethylhexadec-2-en- 1 -ol 150-86-7 DEF
1020 (3R,5S,8R,9S,10S,13R,14S)-10,13-dimethyl- 1153-51-1 DEF
2,3,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-1H-cyclopentaralphenanthren-3-ol 1021 (S)-3,7-dimethyloct-7-en-1-y1 2-phenylacetate 10486-14-DF
1022 1-phenethoxy-2-(p-tolyloxy)ethan-1-ol 72987-59-DF
1023 ethyl (R,Z)-12-hydroxyoctadec-9-enoate 55066-53-DEF
1024 propane-1,2,3-triy1 tributyrate 60-01-5 CEF
1025 p-tolyl dodecanoate 10024-57- DEF
1026 butyl oleate 142-77-8 DEF
1027 (7-isopropyl-1,4a- 13393-93- DEF
dimethyltetradecahydrophenanthren-l-yl)methanol 6 1028 p-tolyl 3-oxo-3-phenylpropanoate 67801-43- DEF
1029 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 2- 14481-52- DF
aminobenzoate 8 1030 (5S,8R,9S,10S,13R, I 4S)-10,13-dimethyl- 18339-16- DEF
1,2,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-3H- 7 cyclopenta[a]phenanthren-3-one 1031 methyl 2-(((lE,2E)-3,7-dimethylocta-2,6-dien-1- 67801-47-DF
ylidene)amino)benzoate 2 1032 (7-i sopropy1-1,4a-dimethy1-1,2,3,4,4b,5,6,7,8,8a,9,10- 26266-77- DEF
dodecahydro-4a15-phenanthren-l-yl)methanol 3 1033 methyl (E)-2-((4- 14735-72- DF
methoxybenzylidene)amino)benzoate 9 1034 4-(6-methylhepta-1,5-dien-2-y1)-1-(4-methylpent-3- 532-87-6 DEF
en-l-yl)cyclohex- I -ene 1035 propane-1,2-diy1 dibenzoate 19224-26- DF
1036 methyl (E)-2-((3,7-dimethyloct-6-en-1- 67845-42- DF
ylidene)amino)benzoate 5 1037 4-ally1-2-methoxyphenyl benzoate 531-26-0 DF
1038 N-(4-hydroxy-3-methoxybenzyl)nonanamide 2444-46-4 DEF
1039 2,3-dihydroxypropyl stearate 123-94-4 DEF
1040 dodecyl 3,4,5-trihydroxybenzoate 1166-52-5 DEF
1041 (E)-2-methyl-5-(2-methyl-3- 67633-98- DEF
methylenebicyclo[2.2.11heptan-2-yppent-2-en-1-y1 1 butyrate 1042 2-phenyl-1H-benzo[dlimidazole-5-sulfonic acid 27503-81-ACF
1043 9-Octadecenoic acid (9Z)-, 2,3-dihydroxypropyl ester 111-03-5 DEF
1044 methyl (E)-2-((4-hydroxy-3- 72927-84- DF
methoxybenzylidene)amino)benzoate 5 1045 isopentyl stearate 627-88-3 DEF
1046 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 2- 26171-78-DEF
phenylacetate 8 1047 (S)-2-(4-methylcyclohex-3-en-l-yl)propan-2-y1 10024-56-DF
cinnamate 3 1048 2-methyl-5-(prop-1-en-2-y1)cyclohex-2-en-1-y1 2- 72152-81-DF
phenylacetate 9 1049 2-ethylhexyl (E)-3-(4-methoxyphenyl)acrylate 5466-77-3 DEF
1052 (E)-2-methoxy-4-(prop- I -en-l-yl)phenyl 2- 120-24-1 DF
phenylacetate 1053 dioctyl adipate 123-79-5 DEF
1054 methyl (1R,4aR,4bS,7R,8a5,10aR)-7-isopropy1-1,4a- 19941-28-DEF
dimethyltetradecahydrophenanthrene-l-carboxylate 7 1055 octadecyl heptanoate 66009-41-DEF
1056 methyl (1R,4aS,4b8,8aR,10aR)-7-isopropy1-1,4a- 33892-18-DEF
dimethy1-1,2,3,4,4a,4b,5,6,8a,9,10,10a- 1 dodecahydrophenanthrene-l-carboxylate 1057 methyl 7-isopropyl-1,4a-dimethyl- 67893-02- DEF
1 ,2,3,4,4a,4b,5,6,7,8,10,10a- 1 dodecahydrophenanthrene-l-carboxylate 1058 (7R,IIR,E)-3,7,11,15-tetramethylhexadec-2-en-1-y1 10236-16-DEF
acetate 5 1059 propane-1,2-diy1 dinonanoate 41395-83- DEF
1060 4-ally1-2-methoxyphenyl 2-phenylacetate 10402-33- DF
1061 methyl ( I R,4aR,4bR,10aR)-7-isopropy1-1,4a- 127-25-3 DEF
dimethy1-1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthrene-1-carboxylatedecahydrophenanthrene-l-carboxyl ate (1:1) 1062 bis(2-(2-butoxyethoxy)ethyl) adipate 141-17-3 DEF
1063 ((1R,4aR,4bR,10aR)-7-isopropy1-1,4a-di methyl- 54200-50-DEF
1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthren-1- 9 yl)methyl acetate 1064 octadecyl octanoate 18312-31- DEF
1065 tetradecyl dodecanoate 22412-97-DEF
1066 2-ethylhexyl palmitate 29806-73-DEF
1067 methyl (E)-2-((3-(4-methoxyphenyI)-2- 111753- DF
methylpropylidene)amino)benzoate 62-9 1068 1-(4-(tert-butyppheny1)-3-(4-methoxyphenyppropane- 70356-09- DEF
1,3-dione 1 1070 2-(3,4-dihydroxy-5-oxo-2,5-dihydrofuran-2-yI)-2- 137-66-6 DEF
hydroxyethyl palmitate 1071 dodecyl palmitate 42232-29- DEF
1073 methyl (E)-2-((3-(benzo[d] [1,3]dioxo1-5-y1)-2- 111753-DF
methylpropylidene)amino)benzoate 60-7 1074 (2R,3R,4S,5R)-6-oxohexane-1,2,3,4,5-pentayl 3891-59-6 CF
pentaacetate 1075 (((2-phenylethane-1,1- 65416-19-DF
diyObis(oxy))bis(methylene))dibenzene 5 1076 methyl (E)-2-(((4-(4-hydroxy-4- 67634-12- DF
methylpentyl)cyclohex-3-en-1- 2 yl)methylene)amino)benzoate 1077 bis(2-ethylhexyl) adipate 103-23-1 DEF
1078 methyl 2-(((E)-2-((E)- 68527-78-DEF
benzylidene)heptylidene)amino)benzoate 6 1079 1,1'-(2-phenylethane-1,1-diy1)bis(IH-indole) 67801-37- DF
1080 octadecyl tetradecanoate 3234-81-9 DEF
1081 didecyl phthalate 84-77-5 DEF
1082 2,5,7,8-tetramethy1-2-(4,8,12-trimethyltridecyl)chroman-6-ol 0 1083 2,5,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 148-03-8 DEF
6-ol 1084 2,7,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 54-28-4 DEF
6-ol 1085 2,8-dimethy1-2-(4,8,12-trimethyltridecyl)chroman-6- 119-13-1 DEF
ol 1087 (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta- 458-37-7 CEF
1,6-diene-3,5-dione 1088 2,6,10,15,19,23-hexamethyltetracosane 1 1 1 -01-3 DEF
1090 (6E,10E,14E,18E)-2,6,10,15,19,23- 111-02-4 DEF
hexamethyltetracosa-2,6,10,14,18,22-hexaene 1091 1,1'-(3,7-dimethyloct-6-ene-1,1-diy1)bis(IH-indole) 67801-16- DEF
1092 (2,2-bis((3,7-dimethyloct-6-en-1- 67634-04- DEF
yl)oxy)ethyl)benzene 2 1093 (2E,4E,6E,8E,10E,12E,14E,16E)-2,6,11,15- 1107-26-2 DF
tetramethy1-17-(2,6,6-trimethylcyclohex-1-en-1-y1)heptadeca-2,4,6,8,10,12,14,16-octaenal 1094 8,8-di(1H-indo1-3-y1)-2,6-dimethyloctan-2-ol 67860-00- DEF
1095 propane-1,2,3-triy1 tribenzoate 1096 11,11-bis((3,7-dimethyloct-6-en-1-yl)oxy)undec- 1- 67785-67-DEF
ene 5 1097 11,11-bis(((E)-3,7-dimethylocta-2,6-dien-1- 67785-74- DF
yl)oxy)undec-1-ene 4 1098 isopentyl 2-(((E)-2-((Z)- 72928-46- DEF
benzylidene)octylidene)amino)benzoate 2 1099 propane-1,2,3-triy1 trioctanoate 1100 octadecyl stearate 2778-96-3 DEF
1101 didodecyl phthalate 2432-90-8 DEF
1103 1((3,7-dimethy1-14(11-methyldodecypoxy)oct-6-en- 67923-82- DEF
1-yl)oxy)-11-methyldodecane 4 1104 (E)-(2-(bis((3,7-dimethylocta-1,6-dien-3- 67785-71- DEF
yl)oxy)methyl)hept-l-en-l-y1)benzene 1 1105 ((E)-2-(bis(((E)-3,7-dimethylocta-2,6-dien-1- 67785-69- DEF
ypoxy)methyphept-l-en-l-y1)benzene 7 1106 3,7-dimethylocta-1,6-dien-3-y1 2-(((E)-2-((E)- 72928-45- DEF
benzylidene)octylidene)amino)benzoate 1 1107 propane-1,2,3-triy1 tris(decanoate) 621-71-6 DEF
1108 2-hydroxypropane-1,3-diy1 distearate 1323-83-7 ADEF
1109 3,5-di methyladamantane-l-carboxylic acid 14670-94-DF
1 1 1 0 dimethyl cyclohexane-1,4-dicarboxylate 94-60-0 BCF
1111 (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1- 88335-93-carboxylic acid 7 1112 methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate 42245-42- CF
1113 (E)-1,1,4,4-tetramethoxybut-2-ene 6068-1114 dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5- 37031-29- CF
dicarboxylate 1 1115 1,2,3,4,5,6-hexamethylbenzene 87-85-4 BDEF
1116 dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate 4841-84-3 BCEF
Table 2 List of materials with at least one MORV greater than 5 to 10 Number IUPAC Name CAS Comment Number Code 25 Mannitol 87-78-5 CF
42 a-D-Glucopyranose 492-62-6 CF
174 2,4,6-trimethy1-1,3,5-trithiane 2765-04-0 BDEF
190 3,5-diethyl-1,2,4-trithiolane 54644-28- BDEF
248 3,5-diisopropy1-1,2,4-trithiolane 54934-99- DEF
613 3a,4,7b-trimethyloctahydro-2H-4,7a- 67919-67- BDF
ethanonaphtho[1,2-b]oxirene 9 689 (1S,3aR,4R,7R,8aR)-1,4,10,10- 38337-32- BDEF
tetramethylhexahydro-1H,4H-3a,8a-epoxy-4,7- 5 methanoazulene 690 1,4,10,10-tetramethylhexahydro-1H,4H-3a,8a-epoxy- 67710-71- BDEF
4,7-methanoazulene 8 695 2-benzy1-4,5-dimethy1-1,3-dioxolane 5468-06-4 BCEF
717 (8E,11E,14E)-heptadeca-1,8,11,14-tetraene 71046-96- DEF
751 10-methy1-1,2,3,4,5,6,7,8,9,10-decahydro-5,9- 22690-27- DF
methanobenzo[8]annulen-11-one 3 779 3,6,6,7a-tetramethyloctahydro-2H-2a,7- 29597-36- BDEF
methanoazuleno[5,6-b]oxirene 2 814 (E)-2-((lS,3aR,4S,8aS)-4,8,8-trimethyldecahydro- 5989-05-9 DEF
1,4-methanoazulen-9-ylidene)ethan-l-ol 828 3,8,8-trimethy1-6-methyleneoctahydro-IH-3a,7- 28231-03- DEF
methanoazulen-5-ol 0 830 (3R,3aR,6S,7S,8aS)-3,6,8,8-tetramethylhexahydro- 13794-73- DEF
1H-3a,7-methanoazulen-5(4H)-one 5 914 (3aR,4aR,8aS,9aR)-3a,4,4a,5,8,8a,9,9a-octahydro- 7158-25-0 DEF
1H-4,9:5,8-dimethanocyclopentaiblnaphthalene 919 ((2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 61826-52- DEF
2,4a-methanonaphthalen-8-yl)methyl formate 6 945 (7,7,8,8-tetramethyloctahydro-2,3b- 59056-70- DEF
methanocyclopentall,31cycloprop41,21benzen-4- 1 yl)methyl formate 959 (E)-2-((1S,3aR,4S,8aS)-4,8,8-trimethyldecahydro- 27530-63-DEF
1,4-methanoazulen-9-ylidene)ethyl acetate 8 965 ((3R,3aS,7R,8aS)-3,8,8-trimethy1-2,3,4,7,8,8a- 1405-92-1 DEF
hexahydro-1H-3a,7-methanoazulen-6-yl)methyl acetate 991 2-methoxy-4-(1,7,7-trimethy1bicyclo12.2.11heptan-2- 13746-56- DEF
yl)phenol 0 998 (2S,4R)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 51-6 999 (2S,4S)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 52-7 1020 (3R,5S,8R,9S,10S,13R,14S)-10,13-dimethyl- 1153-51-1 DEF
2,3,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-1H-cyclopentaralphenanthren-3-ol 1027 (7-isopropyl-1,4a- 13393-93- DEF
dimethyltetradecahydrophenanthren-l-yl)methanol 6 1030 (5S,8R,9S,10S,13R, I 4S)-10,13-di methyl- 18339-16- DEF
I,2,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-3H- 7 cyclopenta[a]phenanthren-3-one 1032 (7-i sopropy1-1,4a-dimethyl- 26266-77- DEF
1,2,3,4,4b,5,6,7,8,8a,9,10-dodecahydro-4a15- 3 phenanthren-l-yl)methanol 1050 3-amino-44(1-methoxy-1-oxo-3-phenylpropan-2- 22839-47- CF
yl)amino)-4-oxobutanoic acid 0 1054 methyl (1R,4aR,4bS,7R,8aS,10aR)-7-isopropyl- I ,4a- 19941-28- DEF
dimethyltetradecahydrophenanthrene-l-carboxylate 7 1056 methyl (1R,4aS,4bS,8aR,10aR)-7-isopropy1-1,4a- 33892-18-DEF
dimethy1-1,2,3,4,4a,4b,5,6,8a,9,10,10a- 1 dodecahydrophenanthrene-l-carboxylate 1057 methyl 7-isopropyl-1,4a-di methyl- 67893-02- DEF
1,2,3,4,4a,4b,5,6,7,8,10, I Oa- 1 dodecahydrophenanthrene-l-carboxyl ate 1061 methyl (1R,4aR,4bR,10aR)-7-isopropyl-1,4a- 127-25-3 DEF
dimethy1-1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthrene-1-carboxylatedecahydrophenanthrene-l-carboxylate (1:1) 1063 (( I R,4aR,4bR,10aR)-7-isopropy1-1,4a-dimethyl- 54200-50-DEF
1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthren-1- 9 yl)methyl acetate 1070 2-(3,4-dihydroxy-5-oxo-2,5-dihydrofuran-2-y1)-2- 137-66-6 DEF
hydroxyethyl palmitate 1071 dodecyl palmitate 42232-29- DEF
1072 (2R,3R,4S,5R,6R)-6-(acetoxymethyl)tetrahydro-2H- 604-68-2 CF
pyran-2,3,4,5-tetrayl tetraacetate 1075 (((2-phenylethane-1,1- 65416-19- DF
diyObis(oxy))bis(methylene))dibenzene 5 1076 methyl (E)-2-(((4-(4-hydroxy-4- 67634-12- DF
methylpentyl)cyclohex-3-en-1- 2 yl)methylene)amino)benzoate 1079 1,1'-(2-phenylethane-1,1-diy1)bi s(1H-indole) 67801-37- DF
1080 octadecyl tetradecanoate 3234-81-9 DEF
1082 2,5,7,8-tetramethy1-2-(4,8,12- 10191-41- DEF
trimethyltridecyl)chroman-6-ol 0 1083 2,5,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 148-03-8 DEF
6-ol 1084 2,7,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 54-28-4 DEF
6-ol 1085 2,8-dimethy1-2-(4,8,12-trimethyltridecyl)chroman-6- 119-13- I
DEF
ol 1086 bis(2-ethylhexyl) decanedioate 122-62-3 DEF
1087 (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta- 458-37-7 CEF
1,6-diene-3,5-dione 1088 2,6,10,15,19,23-hexamethyltetracosane 111-01-3 DEF
1089 (1R,2R,4aS,8aS)-1-((E)-6-((S)-2,2-dimethy1-6- 473-03-0 DEF
methylenecyclohexyl)-4-methylhex-3-en-l-y1)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol 1090 (6E,10E,14E,18E)-2,6,10,15,19,23- 111-02-4 DEF
hexamethyltetracosa-2,6,10,14,18,22-hexaene 1091 1,1'-(3,7-dimethyloct-6-ene-1,1-diy1)bis(1H-indole) 67801-16- DEF
1094 8,8-di(1H-indo1-3-y1)-2,6-dimethyloctan-2-ol 67860-00- DEF
1099 propane-1,2,3-triy1 trioctanoate 538-23-8 DEF
1101 didodecyl phthalate 2432-90-8 DEF
1103 1-((3,7-dimethy1-1-((11-methyldodecyl)oxy)oct-6-en- 67923-82- DEF
1-yl)oxy)-11-methyldodecane 4 1104 (E)-(2-(bis((3,7-dimethylocta-1,6-dien-3- 67785-71-DEF
yl)oxy)methyl)hept-l-en-l-y1)benzene 1 1105 ((E)-2-(bis(((E)-3,7-dimethylocta-2,6-dien-1- 67785-69- DEF
yl)oxy)methyl)hept-l-en-l-y1)benzene 7 1106 3,7-dimethylocta-1,6-dien-3-y1 2-(((E)-2-((E)- 72928-45- DEF
benzylidene)octylidene)amino)benzoate 1 Table 3 List of materials with at least one MORV from 0.5 to less than 1 Number IUPAC Name CAS Comment Number Code 2 1,1-dimethoxyethane 534-15-6 AC
4 hexane-1,6-diol 629-11-8 CE
7 (2E,4E)-hepta-2,4-dien-l-ol 33467-79- __ ACE
11 (Z)-oct-5-en-1-01 64275-73- ACE
18 (E)-non-2-en- 1-0122104-79-BCE
19 (E)-non-6-en-1-ol 40709-05- BCE
21 (E)-non-3-en- 1-0110339-61-BCE
22 (Z)-non-3-en-1-ol 10340-23- BCE
23 (2E,6Z)-nona-2,6-dien-1-01 28069-72- __ BCE
24 heptanedioic acid 111-16-0 CE
26 (E)-1,1-dimethoxyhex-2-ene 18318-83- __ ACEF
41 (E)-dec-2-en-1-ol 22104-80- BDEF
46 methyl 3-hydroxyhexanoate 21188-58- __ BCE
51 5-hydroxyoctan-4-one 496-77-5 __ AC
55 1,1-dimethoxyheptane 10032-05- __ ADEF
56 (E)-2-methyloct-2-enal 49576-57- __ AD
57 methyl octanoate 111-11-5 ADE
61 decan-2-ol 1120-06-5 BDEF
63 2-pentylfuran 3777-69-3 ADE
64 non-1-en-3-ol 21964-44- ADE
68 methyl (E)-oct-3-enoate 35234-16- ACE
70 (Z)-hex-3-en-1-y1 2-hydroxypropanoate 61931-81- CE
80 3-phenylpropan-l-ol 1335-12-2 __ BCE
86 Benzenemethanol, 4-methyl- 589-18-4 __ BC
88 7-methyloctanenitrile 51729-59- __ ADE
89 3,3-dimethy1-1,5-dioxaspiro15.51undecane 707-29-9 ACEF
90 4,4'-thi obi s(butan-2-one) 40790-04- CF
95 (E)-undeca-1,3-dien-5-yne 166432- __ ADEF
98 (2Z,4E)-undeca-2,4-dien-l-ol __ 59376-58- __ DEF
99 (E)-dec-4-enoic acid 57602-94- __ DEF
101 (Z)-undec-2-enal 71277-05- BDF
102 (E)-undec-2-enal 53448-07- BDF
107 4-isopropyl-2,2,5,5-tetramethy1-1,3-dioxane 61920-45-ACEF
108 3-Cyclohexene-l-propanal 22858-74- AC
111 cyclodecanol 1502-05-2 CE
113 cyclododecane 294-62-2 BDEF
115 1-benzy1-2-methyldisulfane 699-10-5 DE
117 (1S,3S,4R,5R)-1-isopropy1-4- 21653-20- BCEF
methylbicyclo[3.1.01hexan-3-ol 3 118 methyl nonanoate 1731-84-6 ADEF
119 (1R,2S)-2-pentylcyclopropane-1-carboxylic acid 58650-45-CE
121 Bicyclo[3.2. I ]octan-8-ol, 1,5,8-trimethyl- 84681-91-BCF
122 1-(p-tolyl)ethan-1-ol 536-50-5 BC
125 undecan-2-ol 1653-30-1 BDEF
129 (E)-3,7-dimethylocta-2,6-dien-1-01 624-15-7 BD
130 1,3,3-tri methy1-2-thiabicyclo[2.2.2] octane 5718-74-1 ADEF
132 methyl (E)-non-3-enoate 13481-87- ADEF
136 2,6-dimethylheptan-4-one 108-83-8 ACEF
139 (E)-cyclododecene 1501-82-2 BDEF
141 diethyl succinate 123-25-1 ACE
144 2-methoxy-2-phenylethan-1-01 2979-22-8 BCE
146 1,7,7-trimethyltricyclo[2.2.1.02,6]heptane 508-32-7 ADEF
147 2-ethyl-4,5-dimethylthiazole 873-64-3 ACEF
154 decahydronaphthalene 493-01-6 ADE
161 2-ethyloctanoic acid 25234-25-DEF
166 ethyl (Z)-octa-4,7-dienoate 69925-33- ADEF
171 7-methyl-3-methyleneoct-6-enal 55050-40- AD
173 3-(hydroxymethyl)nonan-2-one 67801-33- CF
178 (E)-dodec-2-enal 4826-62-4 BDF
179 (2E,4E)-dodeca-2,4-dienal 21662-16- DF
184 (E)-2,6-dimethylocta-1,5,7-trien-3-ol 29414-56- BCF
185 (E)-5-(methylthio)-2-((methylthio)methyl)pent-2- 59902-01-CF
enal I
189 4-(hydroxymethyl)-2-methoxyphenol 498-00-0 C
191 3,7-dimethyloctane-1,6-diol 53067-10- CF
192 1,1-dimethoxynonane 18824-63-ADEF
193 undecan-l-ol 30207-98- BDEF
200 2,3,5,6-tetramethylpyrazine 1124-11-4 AC
202 2,6-dimethoxybenzoic acid 1466-76-8 204 (E)-4-phenylbut-3-en-2-ol 17488-65- CE
205 2-pentylcyclopent-2-en-1-one 25564-22- BD
206 methyl decanoate 110-42-9 BDEF
207 3-methylenenonanoic acid 35205-78- DEF
209 2-i sopropy1-4-methylphenol 4427-56-9 BDF
211 2,6,6-trimethylbicyclo[3.1.1]heptane-2-thiol 23832-18-ADEF
213 (Z)-9,9-dimethoxynon-3-ene 68555-53- BDEF
215 methyl 2,4-dihydroxy-3-methylbenzoate 33662-58-218 3,7-dimethyloct-7-ene-1,6-diol 22460-95- CF
219 (E)-2-(pent-2-en-1-yl)cyclopentan-1-one 51608-18-AC
220 (1R,2S,3R,5S)-2,6,6-trimethylbicyclo[3.1.1Theptan- 25465-65- BCEF
3-ol 0 224 undecane-2,3-dione 7493-59-6 BDF
227 2,7,7-trimethy1-3-oxatricyclo[4.1.1.02,4]octane 1686-14-2 ACEF
232 8-ethy1-1,5-dimethy1bicyc1ol 3.2.1]octan-8-ol 84681-92-BDEF
239 isopentyl 3-methylbutanoate 659-70-1 ADEF
242 hexyl pentanoate 1117-59-5 BDEF
250 (1S,2R,5R)-2,6,6-trimethylbicyclo[3.1.11heptan-3- 547-60-4 ACEF
one 254 (Z)-5-(hex-3-en-l-y1)-5-methyldihydrofuran-2(3H)- 7085 1-61 - CEF
one 5 255 allyl octanoate 4230-97-1 BDEF
256 (Z)-pent-2-en-1-y1 hexanoate 74298-89- BDEF
257 (E)-2-methy1-3-phenylprop-2-en-1-01 1504-55-8 CE
260 (E)-dec-5-en-l-y1 acetate 38421-90- ADEF
263 methyl 2-hydroxy-5-methylbenzoate 22717-57- BC
266 (E)-dodec-2-enoic acid 32466-54-DEF
267 ((1S,2S,5S)-6,6-dimethy1bicyc1o[3.1.11heptan-2- __ 53369-17- __ BDEF
yl)methanol 8 268 (E)-hex-3-en-1-y1 2-methylbutanoate 10094-41- __ BDEF
270 tridecanal 10486-19- BDF
______________________________________________________ 8 271 2-methylundecan-1-ol 10522-26- __ DEF
273 3-ethyl-2,4-dioxaspiro[5.5]undec-8-ene __ 64165-57- __ BCEF
278 1,3-dihydro-2H-inden-2-one 615-13-4 BCE
279 (2E,4E)-trideca-2,4-dienal 60998-24- DF
281 1,3-di methoxy-5-methylbenzene 4179-19-5 BC
282 (6,6-dimethylbicyclo[3.1.11hept-2-en-2-yl)methanol 515-00-4 __ BDEF
284 3-(p-tolyl)propanal 5406-12-2 BC
289 (4S,4aS,8aR)-4,8a-dimethyloctahydronaphthalen- __ 19700-21- __ DEF
4a(2H)-ol 1 291 (E)-2-(hex-2-en-l-yl)cyclopentan-1-01 34686-67- __ CEF
294 1-(furan-2-ylmethyl)-1H-pyrrole 1438-94-4 BCE
297 cyclohexyl(pentyl)sulfane 7133-42-8 BDEF
298 tetradecane 629-59-4 BDEF
299 2-(4-methylcyclohex-3-en-1-yl)prop-2-en-1-01 3269-90-7 __ CF
300 (R)-2-(4-methylcyclohex-3-en-l-yl)prop-2-en-1-01 __ 38142-45- __ CF
301 (E)-2-methy1-3-(pent-2-en-l-y1)cyclopent-2-en-1-one 11050-62- BCF
303 7-methyl-3-methyleneoct-6-enenitrile 26410-85- __ B
DE
305 methyl undecanoate 1731-86-8 __ BDEF
306 4-isopropy1-2-methoxy-1-methylbenzene __ 6379-73-3 __ ADF
308 (Z)-2-hexylidenecyclopentan-1-one 17373-89- BDF
310 (E)-3-methy1-2-(pent-2-en-l-y1)cyclopent-2-en-1-one 6261-18-3 CF
313 cyclooctyl methyl carbonate 61699-38- DEF
315 methyl (E)-undec-9-enoate 5760-50-9 BDEF
318 (E)-2-phenylprop-1-en-l-y1 acetate 37973-51- __ BCEF
320 dodecan-3-one 1534-27-6 BDF
322 1-phenylpentan-1-one 1009-14-9 __ BD
323 2,6-dii sopropylphenol 2078-54-8 __ DEF
324 2-ethoxy-1,3,3-trimethylbicycloI2.2.1] heptane 67800-86- __ ADEF
325 1-methoxy-l-methylcyclododecane 37514-30- BDEF
326 (E)-2-(hex-2-en-l-yl)cyclopentan-1-one 34687-46- BCF
327 1-(3,3-dimethy1bicyc1o[2.2.11heptan-2-yeethan-1-01 66062-78- CEF
330 (S)-4-(prop-1-en-2-yl)cyclohex-1-ene-1- 18031-40- BCF
carbaldehyde 8 332 4-methyl-5-pentyldihydrofuran-2(3H)-one 33673-62-BCEF
333 (4aS,8aS)-4,4,8a-trimethyloctahydronaphthalen- 57963-77- DF
4a(2H)-ol 6 334 L-phenylalanine 150-30-1 335 3a,4,7,7a-tetrahydro-1H-4,7-methanoindene 54335-17-ADE
343 3-methyl-1-phenylbutan-2-ol 705-58-8 ACE
355 tetradecan-l-ol 112-72-1 DEF
358 (6,6-dimethylbicyclol 3.1.1 Theptan-2-yOmethanethiol 6588-78-9 ADEF
359 (E)-6-(pent-2-en-1-yl)tetrahydro-2H-pyran-2-one 34686-71- CE
362 diethyl adipate 141-28-6 BCEF
364 1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 formate 1200-67-5 ADEF
365 (1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 7492-41-3 ADEF
formate 366 octahydro-1H-4,7-methanoinden-5-ol 13380-89- CEF
367 1-(dimethoxymethyl)-4-methoxybenzene 2186-92-7 ACEF
369 2-(4-isopropylcyclohexyl)ethan-1-01 3650-46-2 DEF
370 (E)-undec-2-en-1-y1 acetate 68480-27- DEF
372 2-methyl-1-(p-tolyl)propan-2-ol 20834-59- BCEF
373 1-(3,3-dimethylbicyclo [2.2.1 lheptan-2-yl)ethan-1- 42370-07- BCEF
one 0 375 ally] 2,2,3-tri methyl hexanoate 68132-80- BDEF
378 1,2-dimethoxy-4-vinylbenzene 6380-23-0 BCE
379 2-(4-ethylphenyl)acetaldehyde 68083-54- BC
383 (Z)-hex-3-en-1-y1 hexanoate 31501-11- BDEF
385 (E)-hex-2-en-1-y1 hexanoate 53398-86- BDEF
386 dimethyl phthalate 131-11-3 389 6-ethy1-3-methyloct-5-en-1-ol 26330-64- DEF
390 2-methyl-5,7-dihydrothieno[3,4-d]pyrimidine 36267-71-CE
391 methyl (E)-3,7-dimethylocta-2,6-dienoate 1189-09-9 BDF
392 1-(3,4-dimethoxyphenypethan-1-one 1131-62-0 CE
393 octahydronaphthalen-2(1H)-one 4832-17-1 BCE
394 2-(4-isopropylphenyl)ethan-l-ol 10099-57- BCEF
395 1-methyl-4-(prop-1-en-2-y1)-7- 33204-74- BCEF
oxabicyclo [4.1.0] heptan-2-one 9 396 (Z)-hex-3-en-1-y1 (E)-hex-2-enoate 53398-87- DEF
402 7-methyloctyl propionate 65155-45- BDEF
404 1-(tert-buty1)-4-methoxy-2-methylbenzene 31268-79-BDF
405 4-(tert-butyl)cyclohexane-l-carbaldehyde 20691-52-DF
408 (4,7,7-trimethylbicyclo[4.1.0]hept-4-en-3- 15103-32-BDEF
yl)methanol 9 409 methyl 3,7-dimethyloct-6-enoate 2270-60-2 BDF
410 (Z)-2-(3,3-dimethylbicyclo[2.2.11heptan-2- 2226-05-3 CEF
ylidene)ethan-l-ol 413 (Z)-hex-3-en-1-y1 4-oxopentanoate 85554-70- CF
415 4-isopropylbenzyl formate 67634-21- BCEF
416 1-(tert-buty1)-2-methoxy-4-methylbenzene 88-40-4 ADEF
417 4-isopropyl- 1 -methylcyclohexyl acetate 26252-11-ADEF
418 (3aR,7aR)-octahydro-5H-4,7-methanoinden-5-one 13380-94-BCEF
419 furan-2-ylmethyl 3-methylbutanoate 13678-60- BCEF
420 4-(3-hydroxybutyl)phenol 69617-84- CE
424 3,5-dimethy1-2-propylpyrazine 32350-16- ACEF
425 7-isopropyl-4-methyloxepan-2-one 499-54-7 BCEF
427 4-hydroxy-3,5-dimethoxybenzaldehyde 134-96-3 428 pentadecane 629-62-9 BDEF
430 (E)-4-(3-hydroxyprop-1-en-l-y1)-2-methoxyphenol 458-35-5 432 (6R,7aR)-3,6-dimethy1-5,6,7,7a- 38049-04- CEF
tetrahydrobenzofuran-2(4H)-one 6 435 2-octylthiophene 880-36-4 BDEF
436 methyl dodecanoate 111-82-0 BDEF
437 11-methyldodecanoic acid 25448-24- DEF
441 (Z)-2-heptylidenecyclopentan-1-one 39189-74- DF
442 3-(4-methoxyphenyl)butan-2-one 7074-12-6 BCEF
443 2-ethyl-5-methoxybicyclo[2.2.1]heptane 122795- ADEF
444 tridecan-3-one 1534-26-5 BDF
445 (Z)-2-hexylidenecyclohexan-1-one ______________________________________________________ 5 448 ethyl 3-cyclohexylpropanoate 10094-36- A DEF
449 4-ethylphenyl acetate 3245-23-6 BCE
455 2-ethoxy-4-isopropyl-1-methylbenzene 4732-13-2 BDEF
457 (S)-2-(2,2,3-trimethylcyclopent-3-en-1-yl)ethyl 36789-59-BDF
acetate 0 460 2-((1,7,7-trimethylbicyclo[2.2.1[heptan-2- 7070-15-7 CEF
yl)oxy)ethan-l-ol 462 1-(5-isopropy1-2-methylphenyl)ethan-1-one 1202-08-0 BDEF
463 pentadecan-l-ol 629-76-5 DEF
469 1,2-bis(allyloxy)benzene 4218-87-5 BDEF
470 1-(4-hydroxy-3,5-dimethoxyphenyl)ethan-1-one 2478-38-8 CEF
473 allyl 2-cyclohexylacetate 4728-82-474 tetradecanoic acid 544-63-8 DEF
476 3,5-dimethylbicyclo[2.2.1]heptane-2-carbonitrile 104516-BCEF
477 (E)-dodec-2-en-1-y1 acetate 38363-23- DEF
478 dec-9-en-l-y1 propionate 68480-06-DEF
480 1-(4,7,7-trimethylbicyclo[4.1.0]hept-4-en-3-ypethan- 3608-11-5 BDF
1-one 481 octyl 2-methylbutanoate 29811-50-BDEF
482 (E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2- 25312-34- DF
ol 9 483 2-(tert-butyl)-1,4-dimethoxybenzene 21112-37- DF
484 1-allyI-2,2,7,7-tetramethylcycloheptan-1-01 105463- DF
485 2-butyl-4,6-dimethy1-3,6-dihydro-21-1-pyran 24237-01- ADEF
486 (S)-2,5,5-trimethy1-1,2,3,4,5,6,7,8- 670-24-6 DEF
octahydronaphthalen-2-ol 487 1-(naphthalen-l-yl)ethan-1-one 1333-52-4 DE
490 8,8-dimethoxy-2,6-dimethyloctan-2-ol 141-92-4 CEF
491 3-(but-3-en-l-y1)-2,4,4-trimethylcyclohex-2-en-1-one 67401-27- DF
493 2,3-diethyl-5-methylpyrazine 18138-04- ACE
494 3,5-diethyl-2-methylpyrazine 18138-05- ACE
498 (E)-3,7,9-trimethyldeca-1,6-dien-3-ol 56105-46-DEF
499 (Z)-2-ethylideneundecanal 6720-16-502 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-ol 13720-13-DF
503 (5 s,8s)-8-isopropy1-1-oxaspiro[4.5]decan-2-one 4583-26-0 DEF
504 (5r,8r)-8-isopropyl-1-oxaspiro[4.51decan-2-one 4625-90-5 DEF
505 2,5,5-trimethy1-2,3,4,4a,5,6,7,8-octahydronaphthalen- 643-53-8 DEF
2-ol 507 2'-methylspiro[bicyclo[2.2.1Theptane-2,5'- 87641-24-ACEF
[1,3]dioxane] 5 511 (2R,5S,6S)-2,6,10,10-tetramethy1-1- 57967-68-DF
oxaspiro[4.5]decan-6-ol 7 512 cyclododecyl formate 59052-82-DEF
514 2-butyl-6-methyl-4-methylenetetrahydro-2H-pyran 24237-02- A
DEF
515 heptane-1,1-diy1 diacetate 56438-09- CEF
519 1-(dimethoxymethyl)-4-isopropylbenzene 67785-72-BDEF
520 hexadecane 544-76-3 DEF
524 [1,1'-bi(cyclohexan)[ -1'-en-2-one 527 isobutyl 3-(furan-2-yl)propanoate 529 2-isopropyl-2,3-dihydro-1H-inden-1-one 53446-63-DEF
530 (E)-4-(2,3,6-trimethylphenyl)but-3-en-2-one 57461-21-DEF
532 2-(4-isopropylphenyl)propanal 535 (E)-6,10-dimethylundeca-5,9-dien-2-one 3796-70-1 BDF
537 1-(4-methoxy-2,2,6,6-tetramethylcyclohex-3-en-1- 16556-48-DEF
yl)ethan-1-one 2 539 (methoxymethoxy)cyclododecane 540 (E)-6,10-dimethylundeca-3,9-dien-2-one 13835-41-DF
541 1-(4-butylphenyl)ethan-1-one 542 tetradecan-3-one 629-23-2 DF
543 (E)-3,7-dimethylnona-1,6-dien-3-y1 acetate 61931-80-BDEF
544 3-propy1bicyclo[2.2.11hept-5-ene-2-carbaldehyde 39067-39-BDF
546 (E)-2,6-dimethoxy-4-(prop-1-en-l-ypphenol 20675-95-CF
547 1,2-bis(furan-2-ylmethyl)disulfane 549 (2S)-1,7,7-tri methylbicyclo[2.2.1]heptan-2-y1 acetate 5655-61-8 BDEF
551 decahydronaphthalen-2-y1 formate 552 pentadecan-2-one 2345-28-0 DF
556 (3,3-di methoxy-2,2-dimethylpropyl)benzene 72727-59- DF
562 3-hepty1-5-methyldihydrofuran-2(3H)-one 40923-64-DEF
565 (E)-2,6-dimethylocta-1,5,7-trien-3-y1 acetate 61931-78- BDF
569 (E)-1-(2,6,6-trimethylcyclohex-1-en-l-y1)pent-l-en- 93840-90- DEF
3-ol 5 571 ally' cinnamate 1866-31-5 CE
572 (1r,4r)-4-(tert-butyl)cyclohexyl acetate 1900-69-2 ADEF
573 p-tolyl butyrate 14617-92- BCEF
574 benzyl pentanoate 10361-39- BDEF
577 butyl 2-phenylacetate 122-43-0 BDEF
579 4-ally1-2-methoxyphenyl formate 10031-96-581 1-phenylethyl butyrate 3460-44-4 BDEF
582 (E)-tridec-2-en-l-y1 acetate 68480-26- DEF
585 4-ally1-2,6-dimethoxyphenol 6627-88-9 CF
586 benzyl 2-methylbutanoate 56423-40- BDEF
590 5-isopropyl-2-methylphenyl acetate 6380-28-5 BDF
595 2,3-dimethylquinoxaline 2379-55-7 BCE
596 (2E,6E)-3,7,9-trimethyldeca-2,6-dienal 58605-97-DF
599 (5,6-di methy1-1-(prop-1-en-2-yObicyclo12.2.1 lhept- 110458-DEF
5-en-2-yl)methanol 85-0 604 oct-1-en-3-y1 butyrate 16491-54-BDEF
606 2-(4-(tert-buty1)-2-methylphenoxy)acetaldehyde 67845-53-DF
607 3-phenylpropyl isobutyrate 103-58-2 DF
609 (E)-4-(4-hydroxy-3-methoxyphenyl)but-3-en-2-one 1080-12-2 CEF
611 ethyl 2-hydroxy-4-methoxy-6-methylbenzoate 6110-36-7 DF
612 1-(2,4-diethylphenyl)ethan-1-one 52191-01- DF
614 (E)-4-(3-hydroxyprop-1-en-l-y1)-2,6- 537-33-7 CF
dimethoxyphenol 615 3-butylisobenzofuran-1(3H)-one 6066-49-5 CEF
617 4-methyl-l-phenylpentan-2-one 5349-62-2 BCEF
622 14-methylpentadecan-1-ol 36311-34- DEF
623 2-(4-methylcyclohex-3-en-l-yl)al lyl acetate 15111-97- DF
628 (E)-3-(4-hydroxy-3,5- 4206-58-0 CF
di methoxyphenyl)acrylaldehyde 631 2-(4-(formyloxy)-4-isopropylcyclohex-1-en-1- 72928-49- CF
yl)ethyl formate 5 633 diphenylamine 122-39-4 DE
636 2-methoxy-3-(4-methylpentyl)pyrazi ne 68844-95- BCEF
638 2-methyl-5-(prop-1-en-2-y1)cyclohexyl acetate 20405-60-BDEF
643 6,6-dimethy1-2-methylenebicyclo13.1.11heptan-3-yl 1078-95-1 BDEF
acetate 649 benzyl 2,3-dimethylbut-2-enoate 7492-69-5 DF
651 3-methyl-4-(2,2,6-trimethylcyclohexyl)butan-2-ol 60241-53-DEF
652 isopropyl undec-10-enoate 5459-98-3 DEF
654 dodecyl propionate 6221-93-8 DEF
655 4,5,6,7,8,9,10,11,12,13- 38303-23- DEF
decahydrocyclododecard]oxazole 0 656 (E)-hex-2-en-1-y1 2-hydroxybenzoate 68133-77- DEF
657 hexadecan-2-one 18787-63- DF
660 ((octyloxy)methyl)benzene 54852-64- DEF
661 furan-2-ylmethyl benzoate 34171-46- DF
664 1-benzylpiperazine 2759-28-6 CEF
666 4-(4-methoxypheny1)-3-methylbutan-2-one 67828-19- CEF
669 2-methyl-l-phenylpropan-2-y1 propionate 67785-77- DEF
671 4,4,6-trimethy1-2-phenyl-1,3-dioxane 2568-06-1 DEF
674 undecyl butyrate 5461-02-9 DEF
676 propyl dodecanoate 3681-78-5 DEF
680 8-hydroxyquinoline-5-sulfonic acid 84-88-8 ACF
681 (E)-2-methy1-4-(2,6,6-trimethylcyclohex-2-en-1- 58102-02-DF
yl)but-3-enal 6 683 (E)-2,6,10-trimethylundeca-5,9-dien-1-01 24048-14- DEF
688 palmitic acid 57-10-3 DEF
692 benzyl hexanoate 6938-45-0 DEF
693 5-hexyltetrahydrofuran-3-y1 acetate 10039-39- DEF
702 1-(2,6,6-trimethylcyclohex-2-en-l-yl)pentan-3-one 68480-17- DF
703 2-(tert-butyl)-4-methylcyclohexyl acetate 115724-BDEF
707 (5,7,7-trimethylbicyclo[4.1.01hept-4-en-3-yl)methyl 15103-33-BDEF
acetate 0 709 3a,6,6,9a-tetramethyldodecahydronaphthol 2,1- 21582-36-DEF
b]furan 5 715 2,6-di-tert-butyl-4-(hydroxymethyl)phenol 882-33-7 DEF
723 1-phenylethane-1,2-diy1 diacetate 728 octadecane 593-45-3 DEF
734 (E)-1-(4-methoxyphenyl)pent-l-en-3-one 104-27-8 CF
735 3-(4-isopropylpheny1)-2-methylpropan-1-01 4756-19-8 DEF
737 decyl 3-methylbutanoate 72928-48-DEF
740 6-(tert-butyl)quinoline 68141-13-DEF
744 methyl 2-(4-(tert-butyl)phenyl)acetate 3549-23-3 DF
745 palmitonitrile 629-79-8 DEF
749 3,7-dimethyloctyl butyrate 67874-80- BDEF
752 methyl 1,6-di methy1-5-(prop-1-en-2- 68698-57-DF
yebicyclo[2.2.11hept-5-ene-2-carboxyl ate 7 754 6-nonyltetrahydro-2H-pyran-2-one 758 3-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1- 51414-25-CF
carbaldehyde 6 760 4,9,12,12-tetramethy1-5- 1209-61-6 BDEF
oxatricyclo[8.2Ø04,6]dodecane 761 ethyl 2-benzylbutanoate 2983-36-0 DEF
764 4-(tert-butyl)cyclohexyl propionate 68797-70- BDEF
766 dodecyl butyrate 3724-61-6 DEF
768 1-phenylpropyl butyrate 10031-86-DEF
771 2-phenethylpyridine 2116-62-3 BDEF
772 4,6-di methy1-2-pheny1-3,6-dihydro-2H-pyran 68039-41-BDEF
773 (1R,9S,Z)-4,11,11-trimethy1-8- 118-65-0 BDEF
methylenebicyclo17.2.01undec-4-ene 774 (Z)-3-phenylall yl pentanoate 10482-65- DEF
776 butyl dodecanoate 106-18-3 DEF
777 (E)-2,3-dimethy1-4-(2,6,6-trimethylcyclohex-2-en-1- 68140-49- DF
yl)but-3-enal 8 778 3-phenylpropyl pentanoate 5451-88-7 DEF
780 cinnamyl 2-methylbutanoate 67883-77- DEF
783 phenethyl hexanoate 6290-37-5 DEF
784 3,7-dimethylocta-1,6-dien-3-y1 pentanoate 10471-96-DEF
789 4-(3-oxobutyl)phenyl acetate 3572-06-3 CF
794 (E)-1-(((E)-non-2-en-l-yl)oxy)non-2-ene 68555-30-DEF
795 methyl 3-(bicyclo12.2.1]hept-5-en-2-y1)-3- 72175-33-BCEF
methyloxirane-2-carboxylate 8 796 (E)-hex-2-en-1-y1 2-phenylacetate 68133-78- DEF
797 (Z)-hex-3-en-1-y1 2-phenylacetate 42436-07- DEF
798 (E)-2-methyl-1-(2,6,6-trimethylcyclohex-2-en-1- 72117-72-DF
yl)pent-l-en-3-one 7 799 3-(4-(tert-butyl)pheny1)-2-methylpropan-1-ol 56107-04-DEF
800 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 4951-48-propionate 802 2-isopropyl-5-methylcyclohexyl 2- 17162-29- DF
hydroxypropanoate 7 803 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl (S)-2- 61597-98-DF
hydroxypropanoate 6 804 4,7,7-trimethy1-4-(3-methylbut-2-en-1- 74499-59-DF
yl)bicyclo [4.1.01heptan-3-one 5 806 (Z)-2-methyl-1-(2,2,6-trimethylcyclohex-3-en-1- 68555-94-DF
yl)pent-l-en-3-one 2 808 nonadecane 629-92-5 DEF
810 4-(tert-butyl)cyclohexyl isobutyrate 5451-57-815 2,6,10,10-tetramethyl-1-oxaspirol-4.51decan-6-y1 72541-09-DF
acetate 4 817 (2E,6E)-1-methoxy-3,7,11-trimethyldodeca-2,6,10- 15130-76-DEF
triene 4 818 cinnamyl 3-methylbutanoate 140-27-2 DEF
821 isobutyl dodecanoate 37811-72-DEF
823 (E)-4-methy1-6-(2,2,3-trimethylcyclopent-3-en-1- 67801-19-DEF
yl)hex-4-en-3-ol 8 824 (E)-4-(2,6,6-trimethylcyclohex-1-en-l-y1)but-3-en-2- 22030-19- DF
Y1 acetate 9 825 4-(2,2,6-trimethylcyclohexyl)butan-2-y1 acetate 68555-59-DEF
826 3-phenylpropyl 3-methyl butanoate 5452-07-3 DEF
829 phenyl 2-h ydroxybenzoate 118-55-8 DF
833 8,8-dimethy1-1,2,3,4,5,6,7,8-octahydronaphthalene-2- 72928-51- DEF
carbonitrile 9 835 1-(4,4-dimethy1-1,2,3,4-tetrahydronaphthalen-1- 74499-60-DF
yl)propan-l-one 8 836 8,12-dimethyltridec-11-en-6-one 68141-18- DF
837 (E)-4-(2,6,6-trimethylcyclohex-2-en-l-yl)but-3-en-2- 52210-18- DF
yl acetate 1 844 (2-(benzyloxy)ethyl)benzene 54894-37- DEF
850 heptadecan-9-one 540-08-9 DF
851 1-ethoxy-4-(1-ethoxyviny1)-3,3,5,5- 36306-86-DEF
tetramethylcyclohex-l-ene 2 852 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-y1 68479-99- DF
acetate 2 853 4-(3-phenylpropyl)pyridine 2057-49-0 DEF
854 3-(3-phenylpropyl)pyridine 1802-34-2 DEF
860 stearic acid 57-11-4 DEF
861 2-ethylbutyl 2-(cyclopent-1-en-1-y1)acetate 68092-41-DEF
864 (E)-2-methy1-1-(1-methylbicyc1o[2.2.11hept-5-en-2- 67739-11- DEF
yl)pent-l-en-3-ol 1 865 pentyl dodecanoate 5350-03-8 DEF
866 cinnamyl hexanoate 6994-20-3 DEF
867 (E)-1-(3,5,6-trimethylcyclohex-3-en-l-yl)pent- 1-en- 67801-32-DF
3-one 5 870 3-phenylpropyl hexanoate 6281-40-9 DEF
872 ben zyl octanoate 10276-85-DEF
874 2,3-dihydroxypropyl dodecanoate 142-18-7 DEF
875 (E)-hex-3-en-1-y1 cinnamate 68133-75- DEF
877 2,3-dihydroxypropyl 5-hydroxydecanoate 26446-31-CEF
881 (E)-2-methoxy-1-(pentyloxy)-4-(prop-1-en-1- 10484-36-DEF
yl)benzene 3 884 oxacyclohexadecane-2,13-dione 38223-29- DEF
886 [1,1'-bi(cyclopentan)1-2-y1 (E)-but-2-enoate 68039-73-DEF
891 7-isopropy1-5-methy1bicyc1o[2.2.21oct-5-ene-2- 6831 I -05-DEF
carbonitrile 7 894 (E)-chalcone 614-47-1 DEF
896 (E)-3-((2,6,6-trimethylcyclohex-2-en-1- 26903-19-DF
ylidene)methyl)hex-5-en-2-one 5 898 o-tolyl 2-hydroxybenzoate 617-01-6 DE
900 hexyl 4-hydroxy-3-methoxybenzoate 84375-71- DEF
901 methyl (E)-3-methy1-3-(2-(2,6,6-trimethylcyclohex- 67905-40-DF
2-en-l-yl)vinyl)oxirane-2-carboxylate 2 904 (E)-3-methy1-4-(2,6,6-trimethylcyclohex-2-en-1- 68555-61-DF
yl)but-3-en-2-y1 acetate 3 905 (E)-5-methy1-1-(2,6,6-trimethylcyclohex-2-en-1- 70092-23-DF
yl)hex-1-en-3-one 8 907 p-tolyl benzoate 614-34-6 DF
908 butyl tetradecanoate 110-36-1 DEF
910 hexyl dodecanoate 34316-64-DEF
911 heptyl cinnamate 10032-08- DEF
913 (4E,8E)-2,6,10-trimethy1-13- 14840-89- DEF
oxabicyclo[10.1.0]trideca-4,8-diene 2 915 phenethyl octanoate 5457-70-5 DEF
916 octyl 2-phenylacetate 122-45-2 DEF
917 cyclohexyl 2-phenylacetate 42288-75- DF
918 p-tol yl octanoate 59558-23- DEF
921 (S,Z)-3,7,11-trimethyldodeca-1,6,10-trien-3-y1 56001-43-DF
acetate 5 923 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 3- 1142-85-4 DEF
methylbutanoate 924 1,1,3-trimethy1-3-pheny1-2,3-dihydro-IH-indene 3910-35-8 DF
928 (E)-3-methyl-4-(2,6,6-trimethylcyclohex-1-en-1- 76649-19-DF
yl)but-3-en-2-y1 acetate 9 929 heptyl undec-10-enoate 68141-27- DEF
930 2-isopropyl-5-methylcyclohexyl (E)-2-methylbut-2- 67801-23-DEF
enoate 4 934 5-(diethoxymethyl)-3a,4,5,6,7,7a-hexahydro-IH-4,7- 67633-92- DEF
methanoindene 5 940 ethyl heptadecanoate 14010-23- DEF
943 cinnamyl benzoate 5320-75-2 DF
946 1,3-diphenylpropan-2-one 102-04-5 DEF
952 methyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 301-00-8 DEF
956 isopentyl (E)-3-(4-methoxyphenyl)acrylate 71617-10-DF
957 diisopropyl decanedioate 7491-02-3 DEF
963 phenethyl 2-aminobenzoate 133-18-6 DF
966 ethyl stearate 111-61-5 DEF
967 bis(2,4-dihydroxyphenyl)methanone 131-55-5 CEF
968 6,10,14-trimethylpentadecan-2-one 13955-74- DEF
971 (5E,9E)-6,10,14-trimethylpentadeca-5,9,13-trien-2- 1117-52-8 DF
one 974 butyl palmitate 111-06-8 DEF
976 hexyl tetradecanoate 42231-99- DU
977 ethyl oleate 111-62-6 DEF
978 decyl decanoate 1654-86-0 DEF
979 m-tolyl 2-phenyl acetate 122-27-0 DF
981 tricosane 638-67-5 DEF
982 ethyl (9Z,12Z)-octadeca-9,12-dienoate 544-35-4 DEF
983 ethyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 1191-41-9 DEF
987 2-isopropoxy-1,2-diphenylethan-1-one 6652-28-4 DEF
988 2-ethyl-4,5-dimethylthiazole 87-29-6 DF
994 2-(2-(3,3,5-trimethylcyclohexyeacetypcyclopentan- 84642-57- DEF
1-one 9 --995 phenethyl cinnamate 103-53-7 DF
997 3,3,5-trimethylcyclohexyl 2-hydrox ybenzoate 118-56-9 DF
1000 cinnamyl 2-phenylacetate 7492-65-1 DF
1003 3,7-dimethylocta-1,6-dien-3-y1 2-phenylacetate 7143-69-3 DF
1004 ((ethane-1,1-diyIbis(oxy))bis(ethane-2,1- 122-71-4 DEF
di yl))dibenzene 1006 (E)-3,7-dimethylocta-2,6-dien-l-y1 2-aminobenzoate 67874-69- DF
1014 3,7,11,15-tetramethylhexadec-1-yn-3-ol 29171-23- DEF
1016 3-phenylpropyl cinnamate 122-68-9 DF
1017 7,11,15-trimethy1-3-methylenehexadec-1-ene 504-96-1 DEF
1018 decyl dodecanoate 36528-28- DEF
1021 (S)-3,7-dimethyloct-7-en-l-y1 2-phenylacetate 10486-14-DF
1022 1-phenethoxy-2-(p-tol yloxy)ethan-l-ol 72987-59- DF
1026 butyl oleate 142-77-8 DEF
1029 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 2- 14481-52- DF
aminobenzoate 8 1031 methyl 2-(((1E,2E)-3,7-dimethylocta-2,6-dien-1- 67801-47-DF
ylidene)amino)benzoate 2 1036 methyl (E)-2-((3,7-dimethyloct-6-en-1- 67845-42- DF
ylidene)amino)benzoate 5 1046 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 2- 26171-78-DEF
phenylacetate 8 1049 2-ethylhexyl (E)-3-(4-methoxyphenyl)acrylate 5466-77-3 DEF
1053 di octyl adipate 123-79-5 DEF
1055 octadecyl heptanoate 66009-41-DEF
1058 (7R,11R,E)-3,7,11,15-tetramethylhexadec-2-en-l-y1 10236-16- DEF
acetate 5 1064 octadecyl octanoate 18312-31- DEF
1065 tetradecyl dodecanoate 22412-97-DEF
1066 2-ethylhexyl palmitate 29806-73-DEF
1067 methyl (E)-2-((3-(4-methoxypheny1)-2- 111753- DF
methylpropylidene)amino)benzoate 62-9 1072 (2R,3R,4S,5R,6R)-6-(acetoxymethyl)tetrahydro-2H- 604-68-2 CF
pyran-2,3,4,5-tetrayl tetraacetate 1075 (((2-phenylethane-1,1- 65416-19-DF
diy1)bis(oxy))bis(methylene))dibenzene 5 1079 1,1'-(2-phenylethane-1,1-diy1)bis(1H-indole) 67801-37-DF
1081 didecyl phthalate 84-77-5 DEF
1091 1,1'-(3,7-dimethyloct-6-ene-1,1-diyObis(IH-indole) 67801-16-DEF
1093 (2E,4E,6E,8E,10E,12E,14E,16E)-2,6,11,15- 1107-26-2 DF
tetramethy1-17-(2,6,6-trimethylcyclohex-1-en-1-y1)heptadeca-2,4,6,8,10,12,14,16-octaenal 1102 (E)-1,3,3a,4,5,6,7,8,9,10,1 1,13a- 40785-62-DEF
dodecahydrocyclododeca[c]furan 4 1103 1-((3,7-dimethy1-1-((11-methyldodecyl)oxy)oct-6-en- 67923-82- DEF
1-yl)oxy)-11-methyldodecane 4 1109 3,5-dimethyladamantane-1-carboxylic acid 14670-94-DF
1110 di methyl cyclohexane-1,4-dicarboxylate 94-60-0 BCF
1113 (E)-1,1,4,4-tetramethoxybut-2-ene 6068-62-8 ACEF
Table 4 List of materials with ALL MORVs from 1 to 5 Number IUPAC Name CAS Comment Number Code 406 2-(6,6-dimethylbicyclo[3.1.1lhept-2-en-2-ypethan- 128-50-7 DEF
1-ol 411 2,3a'-dimethylhexahydro-2H-spiro[furan-3,2'- 38325-25-CEF
[1,3]dithiolo[4,5-b]furan] 6 568 4,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,1'- 107715-DEF
cyclopentan1-3-one 18-4 588 (2,8,8-tri methyl-1,2,3,4,5,6,7,8- 72928-44-DEF
octahydronaphthalen-2-yl)methanol 0 608 (1S,3aR,4S,8aS)-4,8,8-trimethy1-9- 475-20-7 BDEF
methylenedecahydro-1,4-methanoazulene 627 (3aS,4S,8S,8aR)-2,2,4-trimethyldecahydro-4,8- 4586-22-5 DEF
methanoazulen-9-ol 635 (2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 1135-66-6 BDEF
2,4a-methanonaphthalene 644 2,8,8-trimethyloctahydro-2H-4a,2- 21280-29- DF
(epoxymethano)naphthalen-10-one 5 646 4-methy1-8-methyleneadamantan-2-ol 122760- CEF
662 (2R,3'R,3a'S,7'R,8a'S)-3',8',8'- 22037-88- BDEF
trimethyloctahydrospiro[oxirane-2,6'- 3 [3a,7]methanoazulene]
685 (R)-1-methy1-4-(1,2,2-trimethylcyclopentyl)benzene 16982-00- BDEF
705 (3R,3aS,7S,8aS)-3,6,8,8-tetramethy1-2,3,4,7,8,8a- 469-61-4 BDEF
hexahydro-1H-3a,7-methanoazulene 720 1',2',3,3',3a',4,4',6',7',7a'-decahydrospiro[pyran-2,5'- 26244-01- DEF
[4,7] methanoindene] 9 724 5,5,6,7,7-pentamethylhexahydroindeno[3a,4- 33704-62- CEF
b]oxiren-4(1aH)-one 0 732 4-(3,4-dimethoxyphenyl)butan-2-one 6302-60-9 CEF
738 (E)-6-(2,2,3-trimethylcyclopent-3-en-l-yl)hex-5-en- 68480-05- DEF
3-ol 7 741 (1aS,4aS,7R,8aS)-4,4,8,8-tetramethyloctahydro- 26619-69-BDEF
4a,7-methanonaphtho[1,8a-b ioxirene 2 748 1-(1,1,3-trimethy1-2,3,4,5,6,7-hexahydro-1H-inden- 87641-23- DF
5-yl)ethan-1-one 4 770 (2R,4aR,8aS)-1,1,5,5-tetramethylhexahydro-2H- 29461-13-DEF
2,4a-methanonaphthalen-8(5H)-one 0 790 1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 isobutyrate 50277-27- BDEF
793 2-methyl-34(1,7,7-trimethylbicyclo[2.2.1]heptan-2- 128119-DEF
yl)oxy)propan-l-ol 70-0 801 2-methyl-4-methylene-6-phenyltetrahydro-2H-pyran 30310-41- BDEF
805 4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-y1 58096-46-DEF
formate 1 813 4,7,7-trimethy1-2-(3-methylbut-2-en-1- 74499-58- DF
yl)bicyclo [4.1.01heptan-3-one 4 841 5,5,8a-trimethyldecahydronaphthalen-2-y1 acetate 24238-95-DEF
848 1,1,7-trimethyldecahydro-3a,7- 58096-47- DEF
methanocyclopenta[8]annulen-3-y1 formate 2 849 1,7,7-trimethylbicyclo[2.2.11heptan-2-y1 butyrate 13109-70-BDEF
856 (2R,4a'R,8a'R)-3,6'-dimethy1-3',4',4a',5',8',8a'- 41723-98-DEF
hexahydro-l'H-spirol oxirane-2,2'- 2 [1,4]methanonaphthalene]
857 ((2S,4aR)-1,1,5,5-tetramethy1-1,3,4,5,6,7- 61826-53- DEF
hexahydro-2H-2,4a-methanonaphthalen-8- 7 yl)methanol 858 (octahydro-1H-4,7-methanoindene-2,5- 281 32-01 - CEF
diy1)dimethanol 6 859 (1R,5S,9S,E)-4,11,11-trimethy1-8- 32214-88- DEF
methylenebicyclo[7.2.01undec-3-en-5-ol 3 871 2-((3S,3aS,5R,8S,8aS)-3,8- 3526-75-8 DEF
dimethyldecahydroazulen-5-yl)propan-2-ol 876 1-(2,5,5-trimethy1-1,3,4,5,6,7-hexahydro-2H-2,4a- 32388-56- DEF
ethanonaphthalen-8-yl)ethan-1-one 0 880 1,2-dimethy1-4-(1-phenylethyl)benzene 6196-95-8 DEF
887 (3R,3aR,7S,8aS)-3,6,8,8-tetramethy1-1,2,3,7,8,8a- 30960-39-DF
hexahydro-4H-3a,7-methanoazulen-4-one 5 888 1-(2,3,8,8-tetramethy1-1,2,3,5,6,7,8,8a- 68155-66- DF
octahydronaphthalen-2-yl)ethan-1-one 8 895 (E)-4-(1,3a,4,6,7,7a-hexahydro-5H-4,7- 126646- DEF
methanoinden-5-ylidene)butan-2-ol 14-8 903 (3aR,5aS,9aS,9bR)-3a,6,6,9a- 564-20-5 DEF
tetramethyldecahydronaphtho[2,1-1A furan-2(1H)-one 912 10,11-dihydro-5H-dibenzo[a,d1[7]annulen-5-one 1210-35-1 DEF
920 5,5,7,8,8-pentamethy1-5,6,7,8-tetrahydronaphthalene-2-carbaldehyde 73-1 922 4-methyl-8-methyleneadamantan-2-y1 acetate 122760- DEF
925 henicosane 629-94-7 DEF
926 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-y1 68039-39- DEF
isobutyrate 4 931 1-(3,6,8,8-tetramethy1-2,3,4,7,8,8a-hexahydro-IH- 68039-35- DF
3a,7-methanoazulen-5-yl)ethan-1-one 0 932 2-(1,1,2,3,3-pentamethy1-2,3-dihydro-1H-inden-5- 1217-08-9 DEF
yl)propan-l-ol 937 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646- DEF
methanoinden-5-y1)-3-methylbut-3-en-2-ol 07-9 938 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646- DEF
methanoinden-6-y1)-3-methylbut-3-en-2-ol 06-8 944 4-(5,5,6-trimethylbicyclo[2.2.1]heptan-2- 66068-84- DEF
yl)cyclohexan-l-ol 6 948 methyl (E)-2-(octylideneamino)benzoate 67801-44- DEF
954 34(2R)-5,5,6-trimethylbicyclo[2.2.1]heptan-2- 3407-42-9 DEF
yl)cyclohexan-l-ol 958 3-ethyl-5,5,8,8-tetramethy1-5,6,7,8- 58243-85- DF
tetrahydronaphthalene-2-carbaldehyde 9 960 (1S)-3-((Z)-benzylidene)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 3 961 (Z)-3-benzylidene-1,7,7- 15087-24- DEF
trimethylbicyclo[2.2.1Theptan-2-one 8 964 3-(5,5-dimethy1-6-methylenebicyclo[2.2.1 Iheptan-2- 68141-24- DEF
yl)cyclohexan-l-ol 2 969 2-methoxyphenyl 2-phenylacetate 4112-89-4 DF
972 1-(3-ethy1-5,5,8,8-tetramethy1-5,6,7,8- 88-29-9 DF
tetrahydronaphthalen-2-yl)ethan-l-one 973 2-(4-ally1-2-methoxyphenoxy)tetrahydro-2H-pyran 72066-75- CF
984 1,3,3-trimethylbicyclo[2.2.1] heptan-2-y1 benzoate 55066-54-DEF
992 methyl (E)-2((2-phenylethylidene)amino)benzoate 67785-76- DF
996 methyl (E)-2-(decylideneamino)benzoate 67874-67- DEF
1010 4-ally1-1-(benzyloxy)-2-methoxybenzene 57371-42- DF
1011 (1R)-1,7,7-trimethy1-3-((Z)-4- 36861-47- DEF
methylbenzylidene)bicyclo[2.2.1]heptan-2-one 9 1012 1-(4-hydroxy-3-methoxyphenyl)decan-3-one 27113-22-DF
1025 p-tolyl dodecanoate 10024-57-DEF
1028 p-tolyl 3-oxo-3-phenylpropanoate 67801-43- DEF
1033 methyl (E)-2-((4- 14735-72- DF
methoxybenzylidene)amino)benzoate 9 1034 4-(6-methylhepta-1,5-dien-2-y1)-1-(4-methylpent-3- 532-87-6 DEF
en-l-yl)cyclohex-1-ene 1037 4-ally1-2-methoxyphenyl benzoate 531-26-0 DF
1038 N-(4-hydroxy-3-methoxybenzyl)nonanamide 2444-46-4 DEF
1042 2-pheny1-1H-benzoldl imidazole-5-sulfonic acid 27503-81-ACF
1044 methyl (E)-2-((4-hydroxy-3- 72927-84- DF
methoxybenzylidene)amino)benzoate 5 1048 2-methyl-5-(prop-1-en-2-y1)cyclohex-2-en-1-y12- 72152-81-DF
phenylacetate 9 1052 (E)-2-methoxy-4-(prop-I-en-l-y1)phenyl 2- 120-24-1 DF
phenylacetate 1060 4-all y1-2-methoxyphenyl 2-phenylacetate 10402-33-DF
Table 5 List of materials with ALL MORVs from 0.5 to less than 1 Number IUPAC Name CAS Comment Number Code 310 (E)-3-methy1-2-(pent-2-en-1-y1)cyclopent-2-en-1- 6261-18-3 CF
one 480 1-(4,7,7-trimethy1bicyclo[4.1.0]hept-4-en-3- 3608-11-5 BDF
yl)ethan-l-one 798 (E)-2-methyl-1-(2,6,6-trimethylcyclohex-2-en-1- 72117-72-DF
yl)pent-l-en-3-one 7 The benefit agents and perfumes raw materials in this specification can be obtained from suppliers including: International Flavors and Fragrances of New York, NY USA; Givaudan of Vernier Switzerland; Firmenich of Geneva, Switzerland; Symrise of Holzminden, Germany;
Kao of Tokyo, Japan; Takasago of Tokyo, Japan; Merck's Sigma Aldrich division of Darmstadt, Germany and Florasynth of Tel-Aviv, Israel.
Compositions and Methods A composition comprising a malodor reduction material having an MORV of at least 0.5, from about 0.5 to about 10, from 0.5 to about 10, from about 1 to about 10, or from about 1 to about 5 is disclosed.
(Ingredients in Tables 1-3 having comment codes A&B-have at least 1 MORV > 0.5 and a vapor pressure > 0.01) In one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 6; 10; 11; 12; 13;
14; 17; 18; 19; 20; 21;
22; 23; 26; 27; 28; 30; 31; 32; 33; 34; 35; 37; 38; 40; 41; 43; 44; 47; 48;
50; 52; 53; 55; 57; 58; 59; 60; 61;
64; 65; 66; 67; 68; 69; 71; 72; 73; 74; 75; 77; 78; 80; 81; 82; 83; 84; 85;
91; 93; 94; 95; 96; 97; 101; 102;
103; 104; 105; 108; 109; 110; 113; 114; 116; 118; 120; 121; 122; 123; 124;
125; 126; 128; 129; 130; 132;
133; 134; 135; 137; 138; 139; 142; 143; 144; 145; 146; 147; 148; 149; 151;
152; 153; 156; 157; 158; 162;
163; 165; 166; 167; 168; 170; 171; 175; 176; 177; 178; 180; 182; 184; 187;
188; 190; 192; 193; 194; 195;
196; 198; 199; 200; 201; 205; 206; 208; 209; 211; 212; 213; 214; 216; 217;
219; 220; 222; 224; 225; 226;
227; 228; 229; 230; 231; 232; 233; 234; 235; 236; 237; 240; 241; 243; 244;
245; 247; 249; 250; 252; 253;
255; 258; 259; 260; 261; 265; 267; 268; 269; 270; 273; 274; 275; 276; 277;
280; 281; 282; 283; 284; 285;
286; 287; 288; 290; 297; 298; 301; 304; 305; 306; 307; 308; 309; 311; 312;
315; 316; 317; 319; 320; 321;
324; 325; 326; 328; 330; 331; 332; 335; 336; 337; 338; 339; 340; 341; 342;
343; 344; 345; 346; 347; 351;
354; 356; 357; 358; 360; 361; 364; 365; 367; 368; 372; 375; 376; 377; 378;
380; 381; 383; 384; 385; 393;
394; 395; 399; 404; 407; 408; 414; 416; 417; 418; 421; 423; 424; 426; 428;
433; 434; 435; 436; 440; 442;
443; 444; 446; 447; 450; 451; 452; 455; 456; 458; 464; 467; 468; 469; 471;
472; 473; 475; 476; 481; 485;
489; 493; 494; 495; 500; 501; 507; 508; 514; 519; 521; 522; 525; 526; 528;
532; 534; 535; 544; 549; 551;
557; 561; 565; 567; 573; 574; 576; 578; 580; 581; 584; 587; 590; 592; 593;
595; 600; 602; 603; 604; 608;
610; 613; 618; 625; 635; 638; 641; 643; 662; 663; 667; 679; 685; 689; 690;
695; 703; 705; 707; 712; 713;
736; 741; 742; 743; 760; 764; 771; 772; 773; 779; 790; 795; 800; 801; 810;
849; 1042; 1108; 1110; 1113;
1115; 1116 Table 2 materials 174; 190; 613; 689; 690; 695; 779, and Table 3 materials 2; 7; 11; 18;
19; 21; 22; 23; 26; 41; 46; 51; 55; 56; 57; 61; 63; 64; 68; 80; 86; 88; 89;
95; 101; 102; 107; 108; 113; 117;
118; 121; 122; 125; 129; 130; 132; 136; 139; 141; 144; 146; 147; 154; 166;
171; 178; 184; 192; 193; 200;
205; 206; 209; 211; 213; 219; 220; 224; 227; 232; 239; 242; 250; 255; 256;
260; 263; 267; 268; 270; 273;
278; 281; 282; 284; 294; 297; 298; 301; 303; 305; 306; 308; 315; 318; 320;
322; 324; 325; 326; 330; 332;
335; 343; 358; 362; 364; 365; 367; 372; 373; 375; 378; 379; 383; 385; 391;
393; 394; 395; 402; 404; 408;
409; 415; 416; 417; 418; 419; 424; 425; 428; 435; 436; 442; 443; 444; 448;
449; 455; 457; 462; 469; 473;
476; 480; 481; 485; 493; 494; 507; 514; 519; 527; 532; 535; 543; 544; 549;
551; 565; 572; 573; 574; 577;
581; 586; 590; 595; 604; 617; 636; 638; 643; 680; 703; 707; 749; 760; 764;
771; 772; 773; 795; 800; 810;
1110; 1113 and mixtures thereof;
(Ingredients in Tables 1-3 having comment code D-have at least 1 MORV > 0.5 and Clog P >3) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 17; 34; 36; 39; 40; 41; 43; 47;
48; 52; 53; 55; 57; 58;
59; 60; 61; 64; 65; 67; 72; 73; 74; 76; 77; 82; 83; 84; 85; 91; 92; 93; 94;
95; 98; 99; 100; 101; 102; 103;
104; 105; 109; 110; 113; 114; 115; 116; 118; 125; 126; 129; 130; 132; 134;
138; 139; 142; 143; 145; 146;
151; 152; 156; 157; 158; 159; 161; 164; 165; 166; 170; 171; 172; 175; 176;
178; 179; 180; 181; 182; 183;
186; 188; 190; 192; 193; 194; 197; 199; 205; 206; 207; 209; 210; 211; 213;
214; 216; 217; 224; 225; 226;
228; 230; 231; 232; 233; 234; 235; 236; 237; 240; 244; 245; 248; 249; 251;
253; 255; 258; 259; 260; 262;
264; 265; 266; 267; 268; 269; 270; 271; 272; 274; 279; 280; 282; 286; 289;
290; 293; 295; 296; 297; 298;
305; 306; 307; 308; 309; 311; 312; 313; 315; 319; 320; 323; 324; 325; 331;
333; 335; 338; 339; 340; 341;
342; 345; 347; 348; 350; 354; 355; 356; 357; 358; 360; 361; 363; 364; 365;
368; 369; 370; 371; 374; 375;
376; 377; 383; 384; 385; 389; 396; 397; 398; 399; 400; 403; 404; 406; 408;
412; 414; 416; 417; 421; 422;
423; 428; 434; 435; 436; 437; 441; 443; 444; 445; 446; 447; 455; 456; 458;
461; 463; 465; 467; 469; 471;
472; 473; 474; 475; 477; 478; 481; 482; 483; 484; 485; 486; 487; 488; 491;
492; 496; 499; 500; 501; 502;
503; 504; 505; 506; 508; 509; 510; 511; 512; 514; 516; 518; 519; 520; 521;
522; 523; 524; 528; 529; 530;
531; 532; 533; 534; 535; 536; 537; 539; 540; 541; 542; 544; 547; 548; 549;
550; 551; 552; 554; 555; 556;
557; 558; 559; 561; 562; 563; 564; 565; 566; 568; 569; 570; 574; 575; 576;
578; 580; 581; 582; 583; 584;
587; 588; 590; 591; 593; 597; 599; 600; 602; 603; 604; 605; 606; 607; 608;
610; 611; 612; 613; 616; 618;
619; 620; 621; 622; 623; 624; 625; 627; 630; 632; 633; 635; 637; 638; 639;
640; 641; 642; 643; 644; 645;
647; 648; 650; 651; 652; 653; 654; 655; 656; 657; 658; 659; 662; 665; 667;
668; 669; 670; 671; 673; 674;
675; 676; 677; 678; 679; 681; 682; 683; 684; 685; 687; 688; 689; 690; 691;
692; 693; 694; 696; 697; 698;
699; 702; 703; 705; 706; 707; 708; 709; 710; 711; 714; 715; 716; 717; 718;
719; 720; 721; 722; 725; 726;
727; 728; 729; 733; 735; 736; 737; 738; 740; 741; 742; 743; 744; 745; 746;
747; 748; 751; 752; 754; 756;
757; 759; 760; 762; 763; 764; 765; 766; 767; 768; 770; 771; 772; 773; 774;
776; 777; 778; 779; 780; 783;
784; 785; 786; 787; 788; 790; 791; 793; 794; 796; 797; 799; 800; 801; 802;
803; 804; 805; 806; 808; 809;
810; 811; 812; 813; 814; 815; 816; 817; 818; 819; 821; 822; 823; 824; 825;
826; 827; 828; 829; 830; 831;
832; 833; 835; 836; 837; 838; 840; 841; 842; 843; 844; 845; 846; 847; 848;
849; 850; 851; 852; 853; 854;
855; 856; 857; 859; 860; 861; 862; 863; 864; 865; 866; 867; 868; 869; 870;
871; 872; 873; 874; 875; 876;
878; 879; 880; 881; 882; 883; 884; 885; 886; 887; 888; 889; 890; 891; 892;
893; 894; 895; 896; 897; 898;
899; 901; 902; 903; 904; 905; 906; 907; 908; 910; 911; 912; 913; 914; 915;
916; 917; 918; 919; 920; 921;
922; 923; 924; 925; 926; 927; 928; 929; 931; 932; 933; 934; 936; 937; 938;
939; 940; 941; 942; 943; 944;
945; 946; 947; 948; 949; 950; 951; 952; 953; 954; 955; 956; 957; 958; 959;
960; 961; 962; 964; 965; 966;
968; 969; 970; 971; 972; 974; 975; 976; 977; 978; 979; 980; 981; 982; 983;
984; 985; 986; 987; 988; 989;
990; 991; 992; 993; 994; 995; 996; 997; 998; 999; 1000; 1001; 1002; 1003;
1004; 1005; 1006; 1007; 1008;
1009; 1010; 1011; 1012; 1013; 1014; 1015; 1016; 1017; 1018; 1019; 1020; 1021;
1022; 1023; 1025; 1026;
1027; 1028; 1029; 1030; 1031; 1032; 1033; 1034; 1035; 1036; 1037; 1038; 1039;
1040; 1041; 1043; 1044;
1045; 1046; 1047; 1048; 1049; 1051; 1052; 1053; 1054; 1055; 1056; 1057; 1058;
1059; 1060; 1061; 1062;
1063; 1064; 1065; 1066; 1067; 1068; 1069; 1070; 1071; 1073; 1075; 1076; 1077;
1078; 1079; 1080; 1081;
1082; 1083; 1084; 1085; 1088; 1090; 1091; 1092; 1093; 1094; 1095; 1096; 1097;
1098; 1099; 1100; 1101;
1103; 1104; 1105; 1106; 1107; 1108; 1109; 1115, Table 2 materials 174; 190;
248; 613; 689; 690; 717;
751; 779; 814; 828; 830; 914; 919; 945; 959; 965; 991; 998; 999; 1020; 1027;
1030; 1032; 1054; 1056;
1057; 1061; 1063; 1070; 1071; 1075; 1076; 1079; 1080; 1082; 1083; 1084; 1085;
1086; 1088; 1089; 1090;
1091; 1094; 1099; 1101; 1103; 1104; 1105; 1106, and Table 3 materials 41; 55;
56; 57; 61; 63; 64; 88;
95; 98; 99; 101; 102; 113; 115; 118; 125; 129; 130; 132; 139; 146; 154; 161;
166; 171; 178; 179; 192; 193;
205; 206; 207; 209; 211; 213; 224; 232; 239; 242; 255; 256; 260; 266; 267;
268; 270; 271; 279; 282; 289;
297; 298; 303; 305; 306; 308; 313; 315; 320; 322; 323; 324; 325; 333; 335;
355; 358; 364; 365; 369; 370;
375; 383; 385; 389; 391; 396; 402; 404; 405; 408; 409; 416; 417; 428; 435;
436; 437; 441; 443; 444; 445;
448; 455; 457; 462; 463; 469; 473; 474; 477; 478; 480; 481; 482; 483; 484;
485; 486; 487; 491; 498; 499;
502; 503; 504; 505; 511; 512; 514; 519; 520; 524; 529; 530; 532; 535; 537;
539; 540; 541; 542; 543; 544;
547; 549; 551; 552; 556; 562; 565; 569; 572; 574; 577; 581; 582; 586; 590;
596; 599; 604; 606; 607; 611;
612; 622; 623; 633; 638; 643; 649; 651; 652; 654; 655; 656; 657; 660; 661;
669; 671; 674; 676; 681; 683;
688; 692; 693; 702; 703; 707; 709; 715; 728; 735; 737; 740; 744; 745; 749;
752; 754; 760; 761; 764; 766;
768; 771; 772; 773; 774; 776; 777; 778; 780; 783; 784; 791; 794; 796; 797;
798; 799; 800; 802; 803; 804;
806; 808; 810; 815; 817; 818; 821; 823; 824; 825; 826; 829; 833; 835; 836;
837; 844; 845; 850; 851; 852;
853; 854; 860; 861; 864; 865; 866; 867; 870; 872; 874; 875; 881; 883; 884;
886; 891; 894; 896; 898; 900;
901; 904; 905; 907; 908; 910; 911; 913; 915; 916; 917; 918; 921; 923; 924;
928; 929; 930; 934; 940; 942;
943; 946; 952; 956; 957; 963; 966; 968; 971; 974; 976; 977; 978; 979; 981;
982; 983; 987; 988; 994; 995;
997; 1000; 1003; 1004; 1006; 1014; 1016; 1017; 1018; 1021; 1022; 1026; 1029;
1031; 1036; 1046; 1049;
1051; 1053; 1055; 1058; 1064; 1065; 1066; 1067; 1075; 1079; 1081; 1091; 1093;
1102; 1103; 1109 and mixtures thereof.
(Ingredients in Tables 1-3 having comment code D and A or B-have at least 1 MORV >
0.5, a Clog P >3 and a vapor pressure > 0.01 Torr) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 17; 34; 40; 41; 43; 47; 48; 52; 53; 55; 57; 58; 59; 60; 61; 64; 65; 67; 72;
73; 74; 77; 82; 83; 84; 85; 91; 93;
94; 95; 101; 102; 103; 104; 105; 109; 110; 113; 114; 116; 118; 125; 126; 129;
130; 132; 134; 138; 139;
142; 143; 145; 146; 151; 152; 156; 157; 158; 165; 166; 170; 171; 175; 176;
178; 180; 182; 188; 190; 192;
193; 194; 199; 205; 206; 209; 211; 213; 214; 216; 217; 224; 225; 226; 228;
230; 231; 232; 233; 234; 235;
236; 237; 240; 244; 245; 249; 253; 255; 258; 259; 260; 265; 267; 268; 269;
270; 274; 280; 282; 286; 290;
297; 298; 305; 306; 307; 308; 309; 311; 312; 315; 319; 320; 324; 325; 331;
335; 338; 339; 340; 341; 342;
345; 347; 354; 356; 357; 358; 360; 361; 364; 365; 368; 375; 376; 377; 383;
384; 385; 399; 404; 408; 414;
416; 417; 421; 423; 428; 434; 435; 436; 443; 444; 446; 447; 455; 456; 458;
467; 469; 471; 472; 473; 475;
481; 485; 500; 501; 508; 514; 519; 521; 522; 528; 532; 534; 535; 544; 549;
551; 557; 561; 565; 574; 576;
578; 580; 581; 584; 587; 590; 593; 600; 602; 603; 604; 608; 610; 613; 618;
625; 635; 638; 641; 643; 662;
667; 679; 685; 689; 690; 703; 705; 707; 736; 741; 742; 743; 760; 764; 771;
772; 773; 779; 790; 800; 801;
810; 849; 1108; 1115, Table 2 materials 174; 190; 613; 689; 690; 779, and Table 3 materials 41; 55;
56; 57; 61; 63; 64; 88; 95; 101; 102; 113; 118; 125; 129; 130; 132; 139; 146;
154; 166; 171; 178; 192; 193;
205; 206; 209; 211; 213; 224; 232; 239; 242; 255; 256; 260; 267; 268; 270;
282; 297; 298; 303; 305; 306;
308; 315; 320; 322; 324; 325; 335; 358; 364; 365; 375; 383; 385; 391; 402;
404; 408; 409; 416; 417; 428;
435; 436; 443; 444; 448; 455; 457; 462; 469; 473; 480; 481; 485; 514; 519;
532; 535; 543; 544; 549; 551;
565; 572; 574; 577; 581; 586; 590; 604; 638; 643; 703; 707; 749; 760; 764;
771; 772; 773; 800; 810 and mixtures thereof.
(Ingredients in Tables 1-3 having comment code C-have at least I MORV >0.5 and Clog P <3) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 1; 3; 4; 5; 6; 8; 9; 10; 11; 12; 13;
14; 15; 16; 18; 19; 20; 21;
22; 23; 24; 26; 27; 28; 29; 30; 31; 32; 33; 35; 37; 38; 44; 45; 49; 50; 54;
62; 66; 68; 69; 70; 71; 75; 78; 79;
80; 81; 87; 96; 97; 106; 108; 111; 112; 119; 120; 121; 122; 123; 124; 127;
128; 131; 133; 135; 137; 140;
144; 147; 148; 149; 150; 153; 155; 160; 162; 163; 167; 168; 169; 173; 177;
184; 185; 187; 189; 191; 195;
196; 198; 200; 201; 203; 204; 208; 212; 215; 218; 219; 220; 222; 223; 227;
229; 238; 241; 243; 246; 247;
250; 252; 254; 257; 261; 273; 275; 276; 277; 281; 283; 284; 285; 287; 288;
291; 292; 299; 300; 301; 302;
304; 314; 316; 317; 321; 326; 327; 328; 329; 330; 332; 336; 337; 343; 344;
346; 349; 351; 352; 353; 359;
366; 367; 372; 378; 380; 381; 382; 387; 388; 390; 393; 394; 395; 401; 407;
410; 411; 413; 418; 420; 424;
426; 427; 429; 430; 431; 433; 438; 439; 440; 442; 450; 451; 452; 453; 454;
459; 460; 464; 466; 468; 470;
476; 479; 489; 490; 493; 494; 495; 497; 507; 513; 515; 517; 525; 526; 538;
545; 546; 553; 560; 567; 571;
573; 579; 585; 589; 592; 594; 595; 598; 601; 609; 614; 615; 626; 628; 629;
631; 634; 646; 663; 664; 666;
672; 686; 695; 700; 701; 712; 713; 724; 730; 731; 732; 734; 739; 750; 753;
755; 758; 769; 775; 781; 782;
789; 792; 795; 807; 820; 834; 839; 858; 877; 909; 935; 967; 973; 1024; 1042;
1074; 1087; 1110; 1111;
1112; 1113; 1114; 1116, Table 2 materials 25; 42; 695; 1050; 1072; 1087, and Table 3 materials 2; 4;
7; 11; 18; 19; 21; 22; 23; 24; 26; 46; 51; 68; 70; 80; 86; 89; 90; 107; 108;
111; 117; 119; 121; 122; 136;
141; 144; 147; 173; 184; 185; 189; 191; 200; 202; 204; 215; 218; 219; 220;
227; 250; 254; 257; 263; 273;
278; 281; 284; 291; 294; 299; 300; 301; 310; 318; 326; 327; 330; 332; 334;
343; 359; 362; 366; 367; 372;
373; 378; 379; 386; 390; 392; 393; 394; 395; 410; 413; 415; 418; 419; 420;
424; 425; 427; 430; 432; 442;
449; 460; 470; 476; 490; 493; 494; 507; 515; 527; 546; 560; 571; 573; 579;
585; 595; 609; 614; 615; 617;
628; 631; 636; 664; 666; 680; 723; 730; 734; 758; 789; 795; 877; 967; 1072;
1110; 1113; and mixtures thereof.
(Ingredients in Tables 1-3 having comment code F- have at least one MORV >0.5 and are stable in microcapsules having a shell that comprises melamine formaldehyde and/or a polyacrylate) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 5; 6; 16; 20; 26; 27;
31; 32; 38; 40; 41; 43;
49; 55; 58; 59; 61; 67; 71; 72; 73; 74; 76; 79; 82; 83; 84; 85; 91; 92; 93;
94; 95; 96; 98; 99; 100; 101; 102;
103; 104; 106; 109; 110; 113; 114; 116; 118; 121; 123; 125; 128; 130; 132;
133; 134; 135; 138; 139; 142;
143; 145; 146; 147; 148; 149; 152; 157; 158; 159; 160; 161; 163; 164; 166;
170; 172; 173; 175; 176; 178;
179; 180; 181; 182; 183; 184; 185; 186; 187; 188; 190; 191; 192; 193; 194;
197; 199; 201; 203; 206; 207;
209; 210; 211; 213; 214; 216; 217; 218; 220; 224; 225; 226; 227; 228; 229;
230; 231; 232; 233; 234; 236;
237; 240; 243; 244; 247; 248; 250; 251; 253; 254; 255; 258; 259; 260; 262;
264; 265; 266; 267; 268; 270;
271; 273; 274; 275; 276; 277; 279; 280; 282; 283; 286; 289; 290; 291; 292;
293; 295; 296; 297; 298; 299;
300; 301; 302; 305; 306; 307; 308; 309; 311; 312; 313; 315; 316; 317; 319;
320; 321; 323; 324; 325; 326;
327; 328; 330; 331; 332; 333; 338; 339; 340; 341; 344; 345; 346; 347; 348;
351; 354; 355; 356; 357; 358;
360; 361; 363; 364; 365; 366; 367; 368; 369; 370; 371; 372; 374; 375; 376;
377; 381; 382; 383; 384; 385;
387; 388; 389; 394; 395; 396; 397; 399; 403; 404; 406; 407; 408; 410; 411;
412; 413; 414; 416; 417; 418;
421; 422; 423; 424; 428; 431; 434; 435; 436; 437; 438; 439; 440; 441; 442;
443; 444; 445; 446; 447; 451;
454; 455; 456; 458; 460; 461; 463; 464; 465; 466; 467; 468; 469; 470; 471;
472; 473; 474; 475; 476; 477;
478; 481; 482; 483; 484; 485; 486; 488; 489; 490; 491; 492; 496; 497; 499;
500; 501; 502; 503; 504; 505;
506; 507; 508; 509; 510; 511; 512; 514; 515; 517; 519; 520; 521; 522; 523;
524; 525; 526; 528; 529; 530;
531; 532; 533; 534; 535; 536; 537; 538; 539; 540; 541; 542; 544; 545; 546;
547; 548; 549; 550; 551; 552;
554; 555; 556; 557; 558; 559; 561; 562; 563; 564; 565; 566; 567; 568; 569;
570; 573; 574; 575; 576; 578;
580; 581; 582; 583; 584; 585; 587; 588; 589; 590; 591; 592; 593; 594; 597;
599; 600; 601; 603; 604; 605;
606; 607; 608; 609; 610; 611; 612; 613; 614; 615; 616; 618; 619; 620; 621;
622; 623; 624; 625; 626; 627;
628; 629; 630; 631; 632; 634; 635; 637; 638; 639; 640; 641; 642; 643; 644;
645; 646; 647; 648; 650; 651;
652; 653; 654; 655; 656; 657; 658; 659; 662; 663; 664; 665; 666; 667; 668;
669; 670; 671; 672; 673; 674;
675; 676; 677; 678; 679; 681; 682; 683; 684; 685; 686; 687; 688; 689; 690;
691; 692; 693; 694; 695; 696;
697; 698; 699; 700; 701; 702; 703; 705; 706; 707; 708; 709; 710; 711; 712;
713; 714; 715; 716; 717; 718;
719; 720; 721; 722; 724; 725; 726; 727; 728; 729; 730; 731; 732; 733; 734;
735; 736; 737; 738; 739; 740;
741; 742; 743; 744; 745; 746; 747; 748; 750; 751; 752; 753; 754; 755; 756;
757; 758; 759; 760; 762; 763;
764; 765; 766; 767; 768; 769; 770; 771; 772; 773; 774; 775; 776; 777; 778;
779; 780; 781; 782; 783; 784;
785; 786; 787; 788; 789; 790; 791; 792; 793; 794; 795; 796; 797; 799; 800;
801; 802; 803; 804; 805; 806;
807; 808; 809; 810; 811; 812; 813; 814; 815; 816; 817; 818; 819; 820; 821;
822; 823; 824; 825; 826; 827;
828; 829; 830; 831; 832; 833; 834; 835; 836; 837; 838; 839; 840; 841; 842;
843; 844; 845; 846; 847; 848;
849; 850; 851; 852; 853; 854; 855; 856; 857; 858; 859; 860; 861; 862; 863;
864; 865; 866; 867; 868; 869;
870; 871; 872; 873; 874; 875; 876; 877; 878; 879; 880; 881; 882; 883; 884;
885; 886; 887; 888; 889; 890;
891; 892; 893; 894; 895; 896; 897; 898; 899; 901; 902; 903; 904; 905; 906;
907; 908; 909; 910; 911; 912;
913; 914; 915; 916; 917; 918; 919; 920; 921; 922; 923; 924; 925; 926; 927;
928; 929; 931; 932; 933; 934;
935; 936; 937; 938; 939; 940; 941; 942; 943; 944; 945; 946; 947; 948; 949;
950; 951; 952; 953; 954; 955;
956; 957; 958; 959; 960; 961; 962; 964; 965; 966; 967; 968; 969; 970; 971;
972; 973; 974; 975; 976; 977;
978; 979; 980; 981; 982; 983; 984; 985; 986; 987; 988; 989; 990; 991; 992;
993; 994; 995; 996; 997; 998;
999; 1000; 1001; 1002; 1003; 1004; 1005; 1006; 1007; 1008; 1009; 1010; 1011;
1012; 1013; 1014; 1015;
1016; 1017; 1018; 1019; 1020; 1021; 1022; 1023; 1024; 1025; 1026; 1027; 1028;
1029; 1030; 1031; 1032;
1033; 1034; 1035; 1036; 1037; 1038; 1039; 1040; 1041; 1042; 1043; 1044; 1045;
1046; 1047; 1048; 1049;
1051; 1052; 1053; 1054; 1055; 1056; 1057; 1058; 1059; 1060; 1061; 1062; 1063;
1064; 1065; 1066; 1067;
1068; 1069; 1070; 1071; 1073; 1074; 1075; 1076; 1077; 1078; 1079; 1080; 1081;
1082; 1083; 1084; 1085;
1087; 1088; 1090; 1091; 1092; 1093; 1094; 1095; 1096; 1097; 1098; 1099; 1100;
1101; 1103; 1104; 1105;
1106; 1107; 1108; 1109; 1110; 1112; 1113; 1114; 1115; 1116, Table 2 materials 25; 42; 174; 190; 248;
613; 689; 690; 695; 717; 751; 779; 814; 828; 830; 914; 919; 945; 959; 965;
991; 998; 999; 1020; 1027;
1030; 1032; 1050; 1054; 1056; 1057; 1061; 1063; 1070; 1071; 1072; 1075; 1076;
1079; 1080; 1082; 1083;
1084; 1085; 1086; 1087; 1088; 1089; 1090; 1091; 1094; 1099; 1101; 1103; 1104;
1105; 1106, and Table 3 materials 26; 41; 55; 61; 89; 90; 95; 98; 99; 101; 102; 107; 113; 117; 118;
121; 125; 130; 132; 136; 139;
146; 147; 161; 166; 173; 178; 179; 184; 185; 191; 192; 193; 206; 207; 209;
211; 213; 218; 220; 224; 227;
232; 239; 242; 250; 254; 255; 256; 260; 266; 267; 268; 270; 271; 273; 279;
282; 289; 291; 297; 298; 299;
300; 301; 305; 306; 308; 310; 313; 315; 318; 320; 323; 324; 325; 326; 327;
330; 332; 333; 355; 358; 362;
364; 365; 366; 367; 369; 370; 372; 373; 375; 383; 385; 389; 391; 394; 395;
396; 402; 404; 405; 408; 409;
410; 413; 415; 416; 417; 418; 419; 424; 425; 428; 432; 435; 436; 437; 441;
442; 443; 444; 445; 448; 455;
457; 460; 462; 463; 469; 470; 473; 474; 476; 477; 478; 480; 481; 482; 483;
484; 485; 486; 490; 491; 498;
499; 502; 503; 504; 505; 507; 511; 512; 514; 515; 519; 520; 524; 527; 529;
530; 532; 535; 537; 539; 540;
541; 542; 543; 544; 546; 547; 549; 551; 552; 556; 562; 565; 569; 572; 573;
574; 577; 581; 582; 585; 586;
590; 596; 599; 604; 606; 607; 609; 611; 612; 614; 615; 617; 622; 623; 628;
631; 636; 638; 643; 649; 651;
652; 654; 655; 656; 657; 660; 661; 664; 666; 669; 671; 674; 676; 680; 681;
683; 688; 692; 693; 702; 703;
707; 709; 715; 723; 728; 730; 734; 735; 737; 740; 744; 745; 749; 752; 754;
758; 760; 761; 764; 766; 768;
771; 772; 773; 774; 776; 777; 778; 780; 783; 784; 789; 791; 794; 795; 796;
797; 798; 799; 800; 802; 803;
804; 806; 808; 810; 815; 817; 818; 821; 823; 824; 825; 826; 829; 833; 835;
836; 837; 844; 845; 850; 851;
852; 853; 854; 860; 861; 864; 865; 866; 867; 870; 872; 874; 875; 877; 881;
883; 884; 886; 891; 894; 896;
898; 900; 901; 904; 905; 907; 908; 910; 911; 913; 915; 916; 917; 918; 921;
923; 924; 928; 929; 930; 934;
940; 942; 943; 946; 952; 956; 957; 963; 966; 967; 968; 971; 974; 976; 977;
978; 979; 981; 982; 983; 987;
988; 994; 995; 997; 1000; 1003; 1004; 1006; 1014; 1016; 1017; 1018; 1021;
1022; 1026; 1029; 1031;
1036; 1046; 1049; 1051; 1053; 1055; 1058; 1064; 1065; 1066; 1067; 1072; 1075;
1079; 1081; 1091; 1093;
1102; 1103; 1109; 1110; 1113 and mixtures thereof.
A composition comprising a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane-l-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof is disclosed.
Preferably, said composition comprises, based on total composition weight, from 0.0001% to 100% of a malodor reduction material selected from the group consisting of 3,5-di methyladamantane-l-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof, and an adjunct material. Preferably, said composition is a consumer product.
A plastic film said plastic film comprising linear low density polyethylene (LLDPE), low density polyethylene (LDPE), high density polyethylene (HDPE), and/or compostable film and a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane-1-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-l-carboxylic acid;
(E)-1,1,4,4-tetramethoxybut-2-ene; dimethyl (4R,5R)-2,2-dimethy1-1,3-dioxolane-4,5-dicarboxylate;
1,2,3,4,5,6-hexamethylbenzene; dimethyl (I R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof is disclosed.
A method of controlling malodors comprising contacting a material comprising a malodor with a composition comprising a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane-l-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene; dimethyl (4R,5R)-2,2-dimethy1-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene; dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof is disclosed. Preferably, said composition comprises, based on total composition weight, from 0.0001% to 100% of a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane- I -carboxylic acid; (IR,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate;
1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof, and an adjunct material. Preferably, said composition is a consumer product.
The use of a composition comprising a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane- 1-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-l-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxyl ate;
1,2,3,4,5,6-hexamethylbenzene; dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof to reduce a malodor is disclosed In one aspect of said composition comprising a malodor reduction material, said composition comprises a malodor reduction material having a Universal MORV.
Preferably, said composition comprising a malodor reduction material having a Universal MORV comprises a malodor reduction material selected from the group consisting of Table 4 materials 608; 635; 662; 667; 685; 705; 741; 790; 801; 849; 1042; and Table 5 material 480 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV. In one aspect, said composition comprises, a malodor reduction material selected from the group consisting of Table 4 materials 406; 568; 588; 608;
627; 635; 644; 662;
667; 685; 705; 720; 738; 741; 748; 770; 790; 793; 801; 805; 813; 841; 848;
849; 856; 857; 859;
871; 876; 880; 887; 888; 892 and Table 5 materials 480; 798 and mixtures thereof are disclosed.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 608; 635; 662; 667; 685; 705; 741; 790; 801; 849 and Table 5 material 480 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 411; 646; 724; 732; 858; 973; 1042 and Table 5 material 310 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 406; 411; 568; 588; 608; 627; 635; 644; 646; 662; 667; 685;
705; 720; 724; 732;
738; 741; 748; 770; 790; 793; 801; 805; 813; 841; 848; 849; 856; 857; 858;
859; 871; 876; 880;
887; 888; 892; 895; 903; 912; 920; 922; 925; 926; 931; 932; 937; 938; 944;
948; 954; 955; 958;
960; 961; 964; 969; 972; 973; 975; 984; 992; 996; 1010; 1011; 1012; 1025;
1028; 1033; 1034;
1037; 1038; 1042; 1044; 1048; 1052; 1060; 1069 and Table 5 materials 310,480,798 and mixtures thereof.
A composition according to any preceding embodiment, said malodor reduction composition being a consumer product, said consumer product comprising a total of, based on total consumer product weight, from about 0.0001% to about 100% of one or more of said malodor reduction materials and an adjunct material is disclosed.
Said malodor reduction composition that is a consumer product is a laundry detergent that comprises a total of, based on total consumer product weight, from about 0.0001% to about 10%, in one aspect, from about 0.001% to about 5%, in one aspect, from about 0.01%
to about 3%, in one aspect, from about 0.1% to about 2% of one or more of said malodor reduction materials and, a material selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, a fabric softener active, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and mixtures thereof, in none aspect, said laundry detergent comprises an adjunct material selected from the group consisting of an organic acid, in one aspect, citric acid and/ or lactic acid, hydrogenated castor oil, ethoxylated polyethyleneimines, PEI 600 EO 20 and/or PEI 600, an enzyme, a cold water amylase, cold water protease and/ or xylogluconase.
Said malodor reduction composition that is a consumer product is an air care composition that comprises a total of, based on total consumer product weight, from about 0.001% to about 100%, preferably from 0.01 to 10%, of one or more of said malodor reduction materials and, optionally, one or more materials selected from the group consisting of surfactants, antimicrobial agents, wetting agents, buffering agents, cyclodextrins, propellants, and solvents.
Said malodor reduction composition that is a consumer product is a liquid fabric enhancer that comprises a total of, based on total composition weight, from about 0.05%
to about 10% of one or more of said malodor reduction materials and, a fabric softener active selected from the group consisting of a quaternary ammonium compound, a silicone polymer, a polysaccharide, a clay, an amine, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, said quaternary ammonium compound is selected from the group consisting of bis-(2-hydroxypropy1)-dimethylammonium methylsulphate fatty acid ester, 1,2-di(acyloxy)-3-trimethylammoniopropane chloride., N, N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate, 1, 2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tal lowdimethyl ammonium chloride dicanoladimethylammonium methylsulfate, 1-methyl-l-stearoylamidoethyl-2-stearoylimidazolinium methylsulfate, 1-tallowylamidoethy1-2-tallowylimidazoline, Dipal methyl Hydroxyethylammoinum Methosulfate and mixtures thereof, said fabric softening active having an Iodine Value of between 0-140, in one aspect, 5-100, in one aspect,10-80, in one aspect, 15-70, in one aspect 18-25.
Said malodor reduction composition that is a consumer product is a fabric enhancer solid particle or bead composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and at least about 25% polyethyleneglycol (PEG) 8000.
Said malodor reduction composition that is a consumer product is a soluble unit-dose composition contained within a polyvinyl alcohol (PVA) film.
Said malodor reduction composition that is a consumer product is a fabric softener dryer added sheet composition, said fabric softener dryer added sheet composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and impregnated onto a non-woven sheet.
Said malodor reduction composition that is a consumer product is a spray-dried laundry detergent powder, said composition comprising from about 0.05% to about 20% of one or more of said malodor reduction materials and at least 10% solids chosen from the following list or combinations thereof: sodium carbonate, sodium sulfate, carboxy methyl cellulose powder, a polymer comprising an acrylate monomer.
Said malodor reduction composition that is a consumer product is a plastic film said plastic film comprising LLDPE, LDPE, HDPE, and/or compostable film, in one aspect, said plastic film comprises about 0.5 mg to about 100 mg of said malodor reduction composition per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 30 mg per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 15 mg per 20 grams of said plastic film.
Said malodor reduction composition that is a consumer product is an absorbent article said absorbent article comprising a total of, based on total consumer product weight, from about 0.1% to about 75%, in one aspect, from about 1% to about 50%, from about 5% to about 40%, from about 12% to about 30% of one or more of said malodor reduction materials and, wherein the article comprises a topsheet, a backsheet, an absorbent core disposed between the topsheet and the backsheet, and an acquisition layer disposed between the topsheet and the absorbent core, wherein the malodor reduction composition is disposed on one of the backsheet, absorbent core, or acquisition layer, said absorbent article comprises a hot melt adhesive and the hot melt adhesive comprises the malodor reduction composition, the hot melt adhesive adheres the backsheet to the topsheet, the backsheet comprises a nonwoven layer and a film layer, and the hot melt adhesive adheres the backsheet nonwoven layer to the backsheet film layer.
Said malodor reduction composition that is a consumer product is a personal care deodorant composition, said deodorant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 0.01% to about 75% of an antimicrobial, said antimicrobials are selected from the group consisting of metals, zeolites, metal zeolites, quaternary ammonium (quat) compounds (e.g., cetyl pyridinium chloride, and benzylalkonium chloride), quat bound clays, metal bound clays, polyaspirin. salicylic acid, polyvinyl amines, coal tar, sulfur, whitfield's ointment, castellani's paint, aluminum chloride, gentian violet, octopirox (piroctone olamine), ciclopirox olamine, undecylenic acid and its metal salts, potassium permanganate, selenium sulfide, sodium thiosulfate, glycols, diols, oil of bitter orange, urea preparations, griseofulvin, 8-Hydroxyquinoline ciloquinol, thiobendazole, thiocarbamates, haloprogin, polyenes, hydroxypyridone, morpholine, benzylamine, allylamines (such as terbinafine), tea tree oil, clove leaf oil, coriander, palmarosa, berberine, thyme red, cinnamon oil, citronellic acid, hinokitol, ichthyol pale, Sensiva SC-50, Elestab HP-100, azelaic acid, lyticase, iodopropynyl butylcarbamate (IPBC), triclosan, triclocarban, isothiazalinones and azoles, and combinations thereof, more preferably, hexanediol, triclosan, octyl isothiazalinone metals selected from the group consisting of Zn, Cu, Al, Ti, Sn, Bi, and Ag, metal salts selected from the group consisting of zinc carbonate, copper sulfate, and zinc gluconate, metal pyrithione salts selected from the group consisting of zing pyrithione (ZPT) and copper pyrithione (CuPT), glycols selected from the group consisting of propylene glycol, dipropylene glycol and hexylene glycol and mixtures thereof, said personal care deodorant composition comprises, based on total deodorant weight, from about 10% to about 75% glycol.
Said malodor reduction composition that is a consumer product is a personal care body wash/shampoo composition, said body wash/shampoo comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials from about 3% to 30% of a surfactant, and, optionally, a micellar phase and/or lamellar phase.
Said malodor reduction composition that is a consumer product is a personal care antiperspirant composition, said antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 1% to about 25% of an aluminum salt antiperspirant active.
Said malodor reduction composition that is a consumer product is an anhydrous antiperspirant composition, said anhydrous antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and from about 1% to about 25% of an antiperspirant actives selected from the group consisting of astringent metallic salts, inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof, aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.
Said malodor reduction composition that is a consumer product is a dish cleaning composition, said dish cleaning composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials.
A method of controlling malodors comprising: contacting the material comprising a malodor with a composition selected from the group consisting of any of the compositions comprising a malodor reduction material disclosed herein and mixtures thereof, said contacting step comprises contacting said material containing a malodor with about 1 mg to about 50 mg, from about 3 mg to 30 mg, or from about 5 mg to about 20 mg of said composition per 20 grams of said material containing a malodor is disclosed.
A method of determining the material's ability to decrease or even eliminate the perception of one or more malodors comprising determining the MORV and/or Universal MORV
of said material, in one aspect, determining said MORV and/or Universal MORV by the MORV and Universal MORV method provided in Test Method I, is disclosed.
Adjunct Materials While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant compositions and may be desirably incorporated in certain aspects of the invention, for example to assist or enhance cleaning performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the fabric treatment operation for which it is to be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives.
As stated, the adjunct ingredients are not essential to Applicants' compositions. Thus, certain aspects of Applicants' compositions do not contain one or more of the following adjuncts materials: surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems structure elasticizing agents, carriers, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below.
Hueing Dye - The liquid laundry detergent composition may comprise a hueing dye. The hueing dyes employed in the present laundry care compositions may comprise polymeric or non-polymeric dyes, organic or inorganic pigments, or mixtures thereof. In one aspect, the hueing dye comprises a polymeric dye, comprising a chromophore constituent and a polymeric constituent. The chromophore constituent is characterized in that it absorbs light in the wavelength range of blue, red, violet, purple, or combinations thereof upon exposure to light. In one aspect, the chromophore constituent exhibits an absorbance spectrum maximum from about 520 nanometers to about 640 nanometers in water and/or methanol, and in another aspect, from about 560 nanometers to about 610 nanometers in water and/or methanol.
Although any suitable chromophore may be used, the dye chromophore is, in one aspect, selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and phthalocyanine dye chromophores. Mono and di-azo dye chromophores are may be preferred.
Surfactants - The compositions according to the present invention may comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi-polar nonionic surfactants and mixtures thereof.
The surfactant is typically present at a level of from about 0.1% to about 60%, from about 1% to about 50% or even from about 5% to about 40% by weight of the subject composition.
Chelating Agents - The compositions herein may contain a chelating agent.
Suitable chelating agents include copper, iron and/or manganese chelating agents and mixtures thereof.
When a chelating agent is used, the composition may comprise from about 0.1%
to about 15% or even from about 3.0% to about 10% chelating agent by weight of the subject composition.
Dye Transfer Inhibiting Agents - The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
When present in a subject composition, the dye transfer inhibiting agents may be present at levels from about 0.0001% to about 10%, from about 0.01% to about 5% or even from about 0.01% to about 3% by weight of the composition.
Dispersants - The compositions of the present invention can also contain dispersants.
Suitable water-soluble organic materials include the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.
Perfumes ¨ The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-t-butylpheny1)-2-methyl propanal, 3-(4-t-butylpheny1)-propanal, 3-(4-isopropylpheny1)-2-methylpropanal, 3-(3,4-methylenedioxypheny1)-2-methylpropanal, and 2,6-dimethy1-5-heptenal, a-damascone, [3-damascone, 8-damascone, 13-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethy1-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methy1-3-cyclohexeny1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and 13-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.
Perfume Delivery Technologies - The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies can also be used to increase the longevity of perfume release from the treated substrate.
Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 Al.
In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of:
perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:
Said perfume delivery technology may comprise microcapsules formed by at least partially surrounding a benefit agent with a wall material. The microcapsule wall material may comprise:
melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. Said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. Said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. Said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. Said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. The perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof.
The microcapsule may be a perfume microcapsule. One or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.
Said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use "reactive" polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically, the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery.
A material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. The alternative compounds can be used in combination with amine compounds. A single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA
Al and USP 6,413,920 BI.
Fabric Softening Actives The compositions of the present invention may comprise a fabric softening active ("FSA"). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quaternary ammonium compounds (quat), quaternary ammonium ester compounds, amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty acids, softening oils, polymer latexes and mixtures thereof.
Non-limiting examples of water insoluble fabric care benefit agents include dispersible polyethylene and polymer latexes.
The quaternary ammonium ester softening active The quaternary ammonium ester softening active may be present at a level of from 3.0%
to 25.0%, more preferably from 4.0% to 18%, even more preferably from 4.5% to 15% by weight of the composition. The level of quaternary ammonium ester softening active may depend of the desired concentration of total softening active in the composition (diluted or concentrated composition) and of the presence or not of other softening active. While higher FSA levels improve the softness benefits, the risk on instabilities is typically higher in fabric softener compositions with higher FSA levels.
Suitable quaternary ammonium ester softening actives include but are not limited to, materials selected from the group consisting of monoester quats, diester quats, triester quats and mixtures thereof. Preferably, the level of monoester quat is from 2.0% to 40.0%, the level of diester quat is from 40.0% to 98.0%, the level of triester quat is from 0.0%
to 25.0% by weight of total quaternary ammonium ester softening active.
Said quaternary ammonium ester softening active may comprise compounds of the following formula:
{R2(4_,,) - N+ - IX - Y ¨ RI]m} A-wherein:
m is I, 2 or 3 with proviso that the value of each m is identical;
each R1 is independently hydrocarbyl, or branched hydrocarbyl group, preferably R1 is linear, more preferably R1 is partially unsaturated linear alkyl chain;
each R2 is independently a C1-C3 alkyl or hydroxyalkyl group, preferably R2 is selected from methyl, ethyl, propyl, hydroxyethyl, 2-hydroxypropyl, 1-methyl-2-hydroxyethyl, poly(C2-3 alkoxy), polyethoxy, benzyl;
each X is independently -(CH2)n-, -CH2-CH(CH3)- or -CH-(CH3)-CH2- and each n is independently 1, 2, 3 or 4, preferably each n is 2;
each Y is independently -0-(0)C- or -C(0)-0-;
A- is independently selected from the group consisting of chloride, methyl sulfate, and ethyl sulfate, preferably A- is selected from the group consisting of chloride and methyl sulfate;
with the proviso that when Y is -0-(0)C-, the sum of carbons in each 121 is from 13 to 21, preferably from 13 to 19. Preferably, X is -CH2-CH(CH3)- or -CH-(CH3)-CH2- to improve the hydrolytic stability of the quaternary ammonium ester softening active, and hence further improve the stability of the fabric softener composition.
In preferred liquid fabric softener compositions the iodine value of the parent fatty acid from which the quaternary ammonium fabric softening active is formed is from 0 to 100, more preferably from 10 to 60, even more preferably from 15 to 45.
Examples of suitable quaternary ammonium ester softening actives are commercially available from KAO Chemicals under the trade name Tetranyl AT-1 and Tetranyl AT-7590, from Evonik under the tradename Rewoquat WE16 DPG, Rewoquat WE18, Rewoquat WE20, Rewoquat WE28, and Rewoquat 38 DPG, from Stepan under the tradename Stepantex GA90, Stepantex VR90, Stepantex VK90, Stepantex VA90, Stepantex DC90, Stepantex VL90A.
These types of agents and general methods of making them are disclosed in U.S.P.N. 4,137,180.
Silicone The compositions of the present invention may comprise a silicone. Suitable levels of silicone may comprise from about 0.1% to about 70%, alternatively from about 0.3% to about 40%, alternatively from about 0.5% to about 30%, alternatively from about 1%
to about 20% by weight of the composition. Useful silicones can be any silicone comprising compound. In one embodiment, the silicone polymer is selected from the group consisting of cyclic silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures thereof. The silicone is a polydialkylsilicone, alternatively a polydimethyl silicone (polydimethyl siloxane or "PDMS"), or a derivative thereof. The silicone is chosen from an aminofunctional silicone, amino-polyether silicone, alkyloxylated silicone, cationic silicone, ethoxylated silicone, propoxylated silicone, ethoxylated/propoxylated silicone, quaternary silicone, or combinations thereof.
TEST METHODS
Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and identified, by analytical methods that include GC-MS and/or NMR.
MORV and Universal MORV calculation 1.) Search Chemical Abstracts using the name and/or the CAS Registry number for the material of interest and use the structure provided. If there are multiple isomers for a given material, use the structure provided by Chemical Abstracts or use the isomer that is most prevalent in the material. Input structure of material into winMolconn (Hall Associates, version 1.1.2.1).
2.) Input values from 1.) above into the following four equations:
a) MORV = ¨8.5096 + 2.8597x(dxp9) + 1.1253x(knotpv) ¨
0.34484x(e1C202) ¨
0.00046231x(idw) + 3.3509x(idcbar) + 0.11158x(n2pag22) b) MORV = -5.2917 + 2.1741x(dxvp5) - 2.6595x(dxvp8) + 0.45297x(e I C2C2d) -0.6202x(c1C202) + 1.3542x(CdCH2) + 0.68105x(CaasC) + 1.7129x(idcbar) c) MORV = -0.0035 + 0.8028x(SHCsatu) + 2.1673x(xvp7) - 1.3507x(c 1 C1C3d) +
0.61496x(c1C102) + 0.00403x(idc) - 0.23286x(nd2).
d) MORV = -0.9926 - 0.03882x(Sd0) + 0.1869x(Ssp3OH) + 2.1847x(xp7) +
0.34344x(e1C302) - 0.45767x(c1C2C3) + 0.7684x(CKetone) Equation a) is for the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors) Equation b) is for the malodor trimethylamine (amine based malodors) Equation c) is for the malodor 3-mercapto-3-methylhexan-l-ol (thiol based malodors) Equation d) is for the malodor skatole (indole based malodors) 3.) For purpose of the present application, a material's MORV is the highest MORV value from equations 2.)a) through 2.)d).
4.) If all MORV values from equations 2.)a) through 2.)d) above are greater than 0.5, the subject material has a Universal MORV.
EXAMPLE 1: Malodor reduction composition comprising entirely non-perfume materials MRC A MRC B MRC C MRC MRC E
Ingredient CAS #
Percent Percent Percent Percent Percent (E)-1,1,4,4-tetramethoxybut-2-ene 6068-62-8 38.500 0.00 48.00 48.00 0.00 1,2,3,4,5,6-hexamethylbenzene 87-85-4 19.500 0.00 0.00 23.50 23.50 dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate 37031-29-1 4.000 10.00 5.00 5.00 6.00 3,5-Dimethyladamantane-1-carboxylic acid 14670-94-1 19.000 45.00 23.50 23.50 23.50 (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-l-carboxylic acid 88335-93-7 19.000 45.00 23.50 0.00 23.50 dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate 4841-84-3 0.000 0.00 0.00 0.00 23.50 Total 100.00 100.00 100.00 100.00 100.00 EXAMPLE 2: Malodor reduction composition comprising non-perfume and perfume materials functioning as malodor reduction materials such as those disclosed in patent application serial number 14/864,927, Frankenbach et al.
MRC MRC MRC MRC MRC
Ingredient CAS #
Percent Percent Percent Percent Percent (E)- I ,1,4,4-tetramethoxybut-2-ene 6068-62-8 38.500 0.00 48.00 48.00 20.00 1,2,3,4,5,6-hexamethylbenzene 87-85-4 19.500 0.00 0.00 23.50 14.00 dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate 37031-29-1 4.000 10.00 0 5.00 9.00 3,5-Dimethyladamantane-1-carboxylic acid 14670-94-1 9.00 45.00 23.50 3.00 23.50 (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene- l -carboxylic acid 88335-93-7 19.000 0.00 23.50 0.00 0.00 dimethyl (1R,2S)-cyclohex-4-ene-0.00 1,2-dicarboxylate 4841-84-3 0.000 0.00 0.00 0.00 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethy1-2H-2,4alpha-methanophthalen-8(5H)-one 23787-90-8 10.000 0. 000 0. 000 7.00 14.00 (E)-3,7-dimethylocta-2,6-dien-l-y1 palmitate 3681-73-0 0. 000 45.00 0. 000 0.
000 0. 000 3-(6,6-dimethylbicyclol3.1.1lhept-2-en-2-y1)-2,2-dimethylpropanal 33885-52-8 0. 000 0.000 5.00 0. 000 0. 000 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol 139504-68-0 0.000 0.000 0.000 13.50 10.00 (R,Z)-1-(2,6,6-trimethylcyclohex-2-en-l-yl)pent-l-en-3-one 127-42-4 0. 000 0. 000 0. 000 0.
000 9.50 Total 100.00 100.00 100.00 100.00 100.00 The term "air refresher" or "air freshener", as used herein, refer to any suitable composition that reduces odors in air, and/or reduces the impression of odors in the air by masking, layering or including malodor counteractant perfume raw materials into the composition.
Example 2.1-2.3: Energized Air Refresher An energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example Example Example 2.1 2.2 2.3 Perfume composition 40-60 50-60 30-50 Malodor reducing composition 10-20 15-30 10-25 Functional Perfume Component 30-50 10-30 25-60 Use of Functional Perfume Components at the recited levels may help modulate the evaporation profile of an entire perfume composition to provide perfume character consistency over the intended usage period.
Suitable FPCs may be highly volatile, low boiling, perfume ingredients. Non-limiting, suitable FPCs include iso-nonyl acetate, dihydro myrcenol (3 -methylene-7-methyloctan-7-ol), linalool (3-hydroxy-3,7-dimethy1-1,6 octadiene), geraniol (3,7 dimethy1-2,6-octadien-l-ol), d-limonene,1 -methyl-4-isopropeny1-1-cyclohexene, benzyl acetate, isopropyl mystristate, and combinations thereof.
Functional Perfume Component Examples 2.1-2.3 Example Al Example A2 Example A3 Benzyl alcohol 10-50 0-50 0-20 Iso nonyl acetate 1-20 1-10 1-10 Dipropylene glycol methyl ether 40-70 5-65 2-50 An energized air freshening device is filled with the composition above. The resulting air freshener is effective at reducing malodor.
Examples 3.1-3.3 - Non-Energized Air Freshener A non-energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example I.
Example Example Example 3.1 3.2 3.3 Perfume composition 20-30 20-50 10-30 Malodor reducing composition 10-20 10-20 20-50 Functional Perfume components 0-70 40-70 20-70 Functional Perfume components Example 1 Example 2 Example 3 3a,4,5,6,7,7a-hexahydro-1H-4,7- 15-25 20-25 0-20 methanoinden-l-yl propanoate Iso nonyl acetate 30-75 15-75 1-10 2-isobuty1-4-hydroxy-4-methyltetrahydropyran 20-30 5-65 2-50 A non-energized air freshener is filled with the example composition above.
The resulting air freshener is effective at reducing malodor.
Examples 4.1-4.2 - Fabric and Air Refresher Composition A fabric refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 4.3 Ingredient Example 4.1 Example 4.2 (ranges) Deionized Water Balance Balance Balance Ethanol 3.0 3.0 1-5.0%
Lupasol HF+ 0.0650 0.0650 0-0.1%
Diethylene Glycol 0.175 0.175 0-0.2%
Silwet L-7600 0.1 0.100 0-0.2 Maleic Acid and/or Citric Acid 0.05 0.05 0-0.2 Koralone B-119 0.015 0.015 0-0.1 Hydroxypropyl 13-cyclodextrin 0.630 0.630 0-2.0%
Sodium Hydroxide 0.003 0.003 0.001-0.01 Fragrance 0 0.4% 0-1.0%
Malodor Reduction Composition 0-0.1 %
(MRC A, B, C, D, E, F, G, H, J, 0.03% 0.04%
K) Total 100.000 100.000 100.000 Lupasol HF Polyethyleneimine (available from BASF) Silwet L-7600 Organosilicone (available from BASF) Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical) The resulting Fabric fresher composition is effective at reducing or preventing malodor when sprayed on fabrics, such as articles of clothing or upholstery.
Example 5.1-5.2 - Aerosol Air Freshener Composition An aerosol air freshener composition is prepared with malodor reduction composition, according to the compositions shown in Example I.
Ingredient Example 5.1 Example 5.2 Water Purified USP Balance 92.370 Ethyl Alcohol 5.000 5.000 Acid Polyacrylic 0.185 Sodium Citrate,Dihydrate 0.100 Acid Citric Solution 50% 0.100 Sodium Dicoctyl Sulfosuccinate 0-0.200 Silwet L-7600 0 - 0.2 0.200 Hydrogenated Castor Oil PEG 60 1.400 1.400 Fragrance 0- 1.5% 0 ¨ 1.5%
Malodor Reduction Composition (MRC A, B, C, D, E, F, G, H, J, or K) 1.0 0¨ 1.50%
Hydroxypropyl BetaCyclodextrine 0.380 0.380 Koralone B-119 0.050 0.050 Sodium Hydroxide 20% 0 - 0.3 Total 100 100 Silwet L-7600 Organosilicone (available from BASF) Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical) A resulting aerosol air freshener is effective at reducing malodor in the air when sprayed. In addition, the aerosol can be sprayed on fabrics to reduce or prevent malodor.
Examples 6.1-6.4 - Heavy Duty Liquid Composition A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 6.1 Example 6.2 Example 6.3 Example 6.4 WT%WT%
Ingredient WT% Active WT% Active Active Active AE1.8S 16.3 16.3 12 8 CI 1 ,8 linear alkyl benzene 2.8 2.8 8 sulfonic acid HSAS 13.6 13.6 0 22 C24 alcohol, E09 2.2 2.2 1 1.8 Citric Acid 0.9 0.9 2 1.7 Lactic Acid 5.8 C12-Cis Fatty Acid 2.3 1.3 0.8 3.0 Protease (55.3 mg/g) 1.7 1.7 1.7 1.7 Amylase (25.4mg/g) 0.7 0.7 0.7 0.7 Borax 3.6 3.6 3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2 Polyethyleneimine 600, E020 1.6 1.6 --- 1.6 Polyethyleneimine 600, 1.6 --- 2.0 1.6 E024, P016 ' DTPA 0.3 0.3 0.3 0.3 Tiron 0.8 0.8 0.8 0.8 Optical Brightener 171 0.3 0.3 0.3 0.3 NaOH 4.0 9.3 4.0 9.3 Na Cumene Sulfonate 1.1 1.1 1.1 1.1 Na Formate 0.2 0.2 0.2 0.2 Aesthetics Dye 0.03 - 1.0 0.03 - 1.0 0.03 - 1.0 0.03 -1.0 Perfume 0.5 - 3.0 0.5 - 3.0 0.5 - 3.0 0.5 - 3.0 Malodor Reduction Composition (MRC A, B, C, D, E, F, G, H, J, or K) 0.15-1.0 0.15-1.0 0.15-1.0 0.15-1.0 Water and Solvent Balance Balance Balance Balance pH 5.0 8.0 5.0 8.0 HSAS secondary alkyl sulfate, acid form DTPA diethylene triamine pentaacetic acid (DTPA) Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 7.1-7.3 - Heavy Duty Liquid Composition Other examples of HDL-Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 7.1 Example 7.2 Example 7.33 Ingredient WT% Active WT%
Active WT% Active AE1.8S 14% 8% 11%
Amine Oxide 2%
C11.8 linear alkyl benzene sulfonic --- ---
302 dimethyl octanedioate 1732-09-8 CF
304 methyl 3-phenylpropanoate 103-25-3 BCE
305 methyl undecanoate 1731-86-8 BDEF
306 4-isopropyl-2-methoxy- I -methylbenzene 6379-73-3 ADF
307 4,7,7-trimethy1-6-thiabicyclo[3.2.1]octane 68398-18-ADEF
308 (Z)-2-hexylidenecyclopentan-1-one 17373-89- BDF
309 2-isopropyl- 1-methoxy-4-methylbenzene 31574-44-ADF
311 (E)-hex-2-en-1-y1 3-methylbutanoate 68698-59-BDEF ' 312 (2E,6E)-3,7-dimethylnona-2,6-dienal 41448-29-BDF
313 cyclooctyl methyl carbonate 61699-38- DEF
314 benzyl 2-hydroxypropanoate 2051-96-9 C
315 methyl (E)-undec-9-enoate 5760-50-9 BDEF
316 N,N-diethylhexanamide 6282-97-9 BCEF
317 2,5-diethyl-4-methylthiazole 41981-71- ACEF
319 4,7,7-trimethy1-6-thiabicyclo[3.2.11oct-3-ene 6784-08-3 ADEF
320 dodecan-3-one 1534-27-6 BDF
321 2-(1-phenylethyl)-1,3-dioxolane 4362-22-5 BCEF
323 2,6-diisopropylphenol 2078-54-8 DEF
324 2-ethoxy-1,3,3-trimethylbicyclo[2.2.1]heptane 67800-86-ADEF
325 1-methoxy-l-methylcyclododecane 37514-30- BDEF
326 (E)-2-(hex-2-en-1-yl)cyclopentan-1-one 34687-46-BCF
327 1-(3,3-dimethylbicyclo[2.2.11heptan-2-yDethan-1-ol 66062-78- CEF
328 2-(4-methylenecyclohexyl)propanal 89116-22- ACF
329 6-penty1-2H-pyran-2-one 27593-23- CE
330 (S)-4-(prop-I-en-2-yl)cyclohex-1-ene-1-carbaldehyde 18031-40- BCF
331 2-hexy1-5,5-dimethyl- 1,3-dioxane 13273-90- BDEF
332 4- methy1-5-pentyldihydrofuran-2(3H)-one 33673-62-BCEF
333 (4aS,8aS)-4,4,8a-trimethyloctahydronaphthalen- 57963-77-DF
4a(2H)-ol 6 335 3a,4,7,7a-tetrahydro-1H-4,7-methanoindene 54335-17-ADE
336 4-methyl-2-phenyl-1,3-dioxolane 2568-25-4 BCE
337 phenyl butyrate 4346- I 8-3 BCE
338 (Z)-2,3-dimethylnon-2-enenitrile 53153-67- BDEF
339 tridecan-2-one 593-08-8 BDF
340 1,1-diethoxyoctane 54889-48- ADEF
341 octyl (E)-but-2-enoate 22874-79-BDEF
342 cyclohexyl (E)-but-2-enoate 31416-78- BDE
343 3-methyl- 1-phenylbutan-2- ol 705-58-8 ACE
344 1,3-di methylbicyclo[2.2.1]heptane-2-carbonitrile ' 104516-BCEF
345 methyl undec-10-enoate 111-81-9 BDEF
346 1-(4-isopropylphenyl)ethan-1-one 645-13-6 BCEF
347 undecyl acetate 1731-81-3 BDEF
348 dec-1-yn-1-y1 methyl carbonate 1322-34-5 DEF
349 (E)-3-(4-methoxyphenyl)acrylaldehyde 24680-50- C
350 (R)-6-penty1-5,6-dihydro-2H-pyran-2-one 51154-96-DE
2 .
351 3-phenylpropy 1 acetate 122-72-5 BCEF
352 benzo[d][1,3]di oxo1-5-ylmethyl formate 85262-96-C
353 methyl 2-hydroxy-4-methoxybenzoate 5446-02-6 C
354 cyclohexyl butyrate 1551-44-6 ADEF
355 tetradecan-l-ol I 1 2-72-1 DEF
356 octyl butyrate 110-39-4 BDEF
357 propyl nonanoate 6513-03-7 BDEF
358 (6,6-dimethylbicyclo[3.1.1]heptan-2-yl)methanethiol 6588-78-9 ADEF
359 (E)-6-(pent-2-en-l-yl)tetrahydro-2H-pyran-2-one 34686-71-CE
360 heptyl pen tan oate 5451-80-9 BDEF
361 butyl octanoate 589-75-3 BDEF
363 6-phenylhexan-1-ol 2430-16-2 DEF
364 1,7,7-trimethylbicyclo[2.2.1[ heptan-2-y1 formate 1200-67-365 (1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 7492-41-3 ADEF
formate 366 octahydro-1H-4,7-methanoinden-5-ol 13380-89- CEF
367 1-(dimethoxymethyl)-4-methoxybenzene 2186-92-7 ACEF
368 2-hexylpyridine 1129-69-7 ADEF
369 2-(4-isopropylcyclohexyl)ethan-1-01 3650-46-2 DEF
370 (E)-undec-2-en-l-y1 acetate 68480-27- DEF
371 (E)-3-ethyl-2-methylnon-2-enoic acid 71850-80-DEF
372 2-methyl-1-(p-tolyl)propan-2-ol 20834-59- BCEF
374 (E)-2-ethy1-2-(3-methylbut-2-en-l-y1)hex-3-en-1-01 85136-06-DEF
375 allyl 2,2,3-tri methylhexanoate 68132-80- BDEF
376 hexyl (E)-hex-2-enoate 33855-57-BDEF
377 (2,2-dichloro-l-methylcyclopropyl)benzene 3591-42-2 BDF
378 1,2-dimethoxy-4-vinylbenzene 6380-23-0 BCE
380 (E)-5-(prop-1-en-l-y1)benzo[d]
[1,3]dioxole 120-58-1 BCE
381 o-tolyl isobutyrate 36438-54- BCF
382 3-ethylhexahydrobenzofuran-2(3H)-one 54491-17- CEF
383 (Z)-hex-3-en-1-y1 hexanoate 31501-11- BDEF
384 undec-10-en-1-y1 acetate 112-19-6 BDEF
385 (E)-hex-2-en-1-y1 hexanoate 53398-86- BDEF
387 (E)-3-methyl-l-phenylpent-1-en-3-ol 62232-91- CEF
388 (2-hexy1-1,3-dioxolan-4-yl)methanol 1708-35-6 CEF
389 6-ethy1-3-methyloct-5-en-1-ol 26330-64- DEF
390 2-methyl-5,7-dihydrothieno[3,4-dlpyrimidine 36267-71- CE
393 octahydronaphthalen-2(1H)-one 4832-17-1 BCE
394 2-(4-isopropylphenyl)ethan-1-ol 10099-57- BCEF
395 1-methyl-4-(prop-1-en-2-y1)-7- 33204-74- BCEF
oxabicyclo[4.1.0Theptan-2-one 9 396 (Z)-hex-3-en-1-y1 (E)-hex-2-enoate 53398-87- DEF
397 (E)-5,9-dimethyldeca-4,9-dienal 68844-98- DF
398 5-methyl-3,4-dihydronaphthalen-1(2H)-one 6939-35-1 DE
399 4-(tert-butyl)cyclohexyl formate 68039-42- BDEF
400 8-methyl-3,4-dihydronaphthalen-1(2H)-one 51015-28- DE
401 2-hydroxyethyl 2-phenoxyacetate 1984-60-7 403 (E)-tetradec-2-enal 64461-99- DF
404 1-(tert-buty1)-4-methoxy-2-methylbenzene 31268-79- BDF
406 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethan-1- 128-50-7 DEF
ol 407 (E)-(3,3-dimethoxyprop-1-en-l-yl)benzene 4364-06-1 BCEF
408 (4,7,7-trimethy1bicyc1o[4.1.01hept-4-en-3-yOmethanol 15103-32- BDEF
410 (Z)-2-(3,3-dimethylbicyclo[2.2.1]heptan-2- 2226-05-3 CEF
ylidene)ethan-1-ol 411 2,3a'-dimethylhexahydro-2H-spiro[furan-3,2'- 38325-25-CEF
[1,3]dithiolo[4,5-blfuran] 6 412 1,3-dibromo-2-methoxy-4-methy1-5-nitrobenzene 62265-99- DF
413 (Z)-hex-3-en-1-y1 4-oxopentanoate 85554-70- CF
414 2-(tert-butyl)-1-methoxy-4-methylbenzene 43109-72- BDEF
416 1-(tert-buty1)-2-methoxy-4-methylbenzene 88-40-4 A DEF
417 4-isopropyl-1-methylcyclohexyl acetate 26252-11- ADEF
418 (3aR,7aR)-octahydro-5H-4,7-methanoinden-5-one 13380-94- BCEF
420 4-(3-hydroxybutyl)phenol 69617-84- CE
421 2,5,7,7-tetramethyloctanal 114119- BDF
422 2,5,5-trimethy1-2-phenyl-1,3-dioxane 5406-58-6 DEF
423 2-isobuty1-4,5-dimethylthiazole 53498-32- BDF
424 3,5-di methy1-2-propylpyrazine 32350-16- ACEF
426 2-phenylpent-4-enal 24401-36- BC
427 4-hydroxy-3,5-dimethoxybenzaldehyde 134-96-3 428 pentadecane 629-62-9 BDEF
429 allyl 2-aminobenzoate 7493-63-2 430 (E)-4-(3-hydroxyprop-1-en-l-y1)-2-methoxyphenol 458-35-5 431 3,6-dimethy1-5,6,7,7a-tetrahydrobenzofuran-2(4H)- 13341-72- CEF
one 5 433 2-methyl-4-phenylbutanal 40654-82- BC
434 (6,6-dimethylbicyclo[3.1.1Thept-2-en-2-yl)methyl 72928-52- BDEF
formate 0 435 2-octylthiophene 880-36-4 BDEF
436 methyl dodecanoate 111-82-0 BDEF
437 11-methyldodecanoic acid 25448-24- DEF
438 dimethyl nonanedioate 1732-10-1 CF
439 dodecanedioic acid 693-23-2 CEF
440 methyl 4-phenylbutanoate 2046-17-5 BCEF
441 (Z)-2-heptylidenecyclopentan-1-one 39189-74- DF
442 3-(4-methoxyphenyl)butan-2-one 7074-12-6 BCEF
443 2-ethyl-5-methoxybicyclo[2.2.1] heptane 122795- ADEF
444 tridecan-3-one 1534-26-5 BDF
445 (Z)-2-hexylidenecyclohexan-1-one 16429-07- DF
446 2-pentylcyclohex-2-en-1-one 25435-63- BDF
447 1,1,2,3,3-pentamethyloctahydro-1H-indene 33704-60- ADEF
450 methyl 2-(p-tolyloxy)acetate 38768-63- BCE
451 4,6,9-trimethy1-3,5,8,10-tetraoxadodecane 67715-79- BCEF
452 (E)-2-styry1-1,3-dioxolane 5660-60-6 BCE
453 3,5-di methoxybenzoic acid 1132-21-4 C
454 4-ethyl-2,6-dimethoxyphenol 14059-92- CEF
455 2-ethoxy-4-isopropyl-l-methylbenzene 4732-13-2 BDEF
456 ethyl undecanoate 627-90-7 BDEF
458 1,1-diethoxynonane 54815-13- BDEF
459 (E)-3-(3-methoxyphenyl)acrylic acid 6099-04-3 CE
460 2-((1,7,7-trimethylbicyc1o[2.2.1]heptan-2- 7070-15-7 CEF
yl)oxy)ethan-l-ol 461 4-(2,6,6-trimethylcyclohex-1-en- I -yl)butan-2-ol 3293-47-8 DF
463 pentadecan-l-ol 629-76-5 DEF
464 phenyl pentanoate 20115-23- BCEF
465 (E)-4-(2,6,6-trimethylcyclohex-1-en-l-y1)but-3-en-2- 22029-76- DF
ol 1 466 methyl (octahydropentalen-l-y1) carbonate 87731-19- CEF
467 cyclohexyl pentanoate 1551-43-5 BDEF
468 5-(dimethoxymethyl)benzoldll 1,3 ldioxole 59259-90- BCF
469 1,2-bis(allyloxy)benzene 4218-87-5 BDEF
470 1-(4-hydroxy-3,5-dimethoxyphenyl)ethan-1-one 2478-38-8 CEF
471 heptyl hexanoate 6976-72-3 BDEF
472 pentyl octanoate 638-25-5 BDEF
473 allyl 2-cyclohexylacetate 4728-82-9 BDEF
474 tetradecanoic acid 544-63-8 DEF
475 ally! 3,5,5-trimethylhexanoate 71500-37- BDEF
476 3,5-di methylbicyclo[2.2.11heptane-2-carbonitrile 104516-BCEF
477 (E)-dodec-2-en-1-y1 acetate 38363-23- DEF
478 dec-9-en-1-y1 propionate 68480-06- DEF
479 (2-pheny1-1,3-dioxolan-4-yOmethanol 1708-39-0 481 octyl 2-methylbutanoate 29811-50- BDEF
482 (E)-4-(2,6,6-trimethylcyclohex-2-en-l-yl)but-3-en-2- 25312-34- DF
ol 9 483 2-(tert-butyl)-1,4-dimethoxybenzene 21112-37- DF
484 1-allyI-2,2,7,7-tetramethylcycloheptan-l-o! 105463-DF
485 2-butyl-4,6-dimethy1-3,6-dihydro-2H-pyran 24237-01-ADEF
486 (S)-2,5,5-trimethy1-1,2,3,4,5,6,7,8- 670-24-6 DEF
octahydronaphthalen-2-o!
487 1-(naphthalen-1-yl)ethan-1-one 1333-52-4 DE
488 5-ethy1-2-methylnonan-1-ol 68083-56- DEF
489 1-phenylpropan-2-y1 acetate 2114-33-2 BCEF
490 8,8-dimethoxy-2,6-dimethyloctan-2-ol 141-92-4 CEF
491 3-(but-3-en-1-y1)-2,4,4-trimethylcyclohex-2-en-1-one 67401-27- DF
492 2-(4-isopropylcyclohexyl)propan-1-ol 67634-03-DEF
493 2,3-diethyl-5-methylpyrazine 18138-04- ACE
494 3,5-diethyl-2-methylpyrazine 18138-05- ACE
495 (E)-1-(butan-2-ylidene)-2-phenyl hydrazine 1129-62-496 pentadecanal 2765-11-9 DF
497 2-(4-methoxyphenoxy)propanoic acid 13794-15- CF
499 (Z)-2-ethylideneundecanal 6720-16-7 DF
500 1-(1-(hexyloxy)ethoxy)hexane 5405-58-3 BDEF
501 (E)-1-(2,6,6-trimethylcyclohex-3-en-l-yl)but-2-en-1- 71048-82- BDF
one 3 502 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-ol 13720-13-DF
503 (5s,8s)-8-isopropyl-1-oxaspiro[4.5]decan-2-one 4583-26-504 (5r,8r)-8-isopropyl-1-oxaspiro[4.5]decan-2-one 4625-90-5 DEF
505 2,5,5-trimethy1-2,3,4,4a,5,6,7,8-octahydronaphthalen- 643-53-8 DEF
2-ol 506 1,2-di(thiophen-2-yl)disulfane 6911-51-9 DEF
507 2'-methylspiro[bicyclo[2.2.1]heptane-2,5'- 87641-24-ACEF
[1,3]dioxane] 5 508 3,5-diethy1-2,6-dimethylcyclohex-2-en-1-one 65416-17- BDF
509 5-(1-mercaptopropan-2-y1)-2-methylcyclohexane-1- 4802-20-4 DEF
thiol 510 (Z)-4-(4-methylcyclohex-3-en-l-ylidene)pentanal 32540-03-DF
511 (2R,5S,6S)-2,6,10,10-tetramethy1-1- 57967-68- DF
oxaspiro[4.5]decan-6-ol 7 512 cyclododecyl formate 59052-82-DEF
513 methyl 2-(4-methoxyphenyl)acetate 23786-14-514 2-butyl-6-methyl-4-methylenetetrahydro-2H-pyran 24237-02- ADEF
515 heptane-1,1-diy1 diacetate 56438-09- CEF
516 6-methyl-3,4-dihydronaphthalen-1(2H)-one 51015-29- DE
517 ethyl benzo[d][1,3]dioxole-5-carboxylate 6951-08-2 CF
518 7-methyl-3,4-dihydronaphthalen-1(2H)-one 22009-37- DE
519 1-(dimethoxymethyl)-4-isopropylbenzene 67785-72- BDEF
520 hex adecane 544-76-3 DEF
521 (E)-2-(2,6-dimethylhepta-1,5-dien-l-y1)-1,3-dioxolane 66408-78- BDEF
522 5-ethyl-2-methylnonanal 68141-14- BDF
523 (3E,5E)-6,10-dimethylundeca-3,5,9-trien-2-one 141-10-6 DF
524 [1,1'-bi(cyclohexan)]-1'-en-2-one 1502-22-3 DF
525 3-butyl-2,5-dimethylpyrazine 40790-29- ACEF
526 2-butyl-3,5-dimethylpyrazine 50888-63- ACEF
528 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-one 13720-12- BDEF
529 2-isopropy1-2,3-dihydro-1H-inden-1-one 53446-63- DEF
530 (E)-4-(2,3,6-trimethylphenyl)but-3-en-2-one 57461-21- DEF
531 methyl tridecanoate 1731-88-0 DEF
532 2-(4-isopropylphenyl)propanal 533 6,10-dimethylundec-9-en-2-one 534 1,1,6-trimethy1-1,2,3,4-tetrahydronaphthalene 475-03-6 BDEF
535 (E)-6,10-dimethylundeca-5,9-dien-2-one 3796-70-1 BDF
536 dimethyl decanedioate 106-79-6 DF
537 1-(4-methoxy-2,2,6,6-tetramethylcyclohex-3-en-1- 16556-48-DEF
yl)ethan-l-one 2 538 benzo[d][1,3]dioxo1-5-ylmethyl acetate 326-61-4 CF
539 (methoxymethoxy)cyclododecane 42604-12- DEF
540 (E)-6,10-dimethylundeca-3,9-dien-2-one 13835-41- DF
541 1-(4-butylphenypethan-1-one 37920-542 tetradecan-3-one 629-23-2 DF
544 3-propylbicyclo[2.2.1]hept-5-ene-2-carbaldehyde 39067-39-BDF
545 2,5-dimethoxy-NI,N1-dimethylbenzene-1,4-diamine 72066-78- CF
546 (E)-2,6-dimethoxy-4-(prop-1-en-l-y1)phenol 20675-95- CF
547 1,2-bis(furan-2-ylmethyl)disulfane 4437-20-1 DF
548 dibenzo[b,d[furan 132-64-9 DEF
549 (2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 acetate 5655-61-8 BDEF
550 (E)-2-(oct-2-en-l-yl)cyclopentan-1-one 65737-52- DF
551 decahydronaphthalen-2-y1 formate 10519-12- BDEF
552 pentadecan-2-one 2345-28-0 DF
553 p-tolyl (E)-but-2-enoate 41873-74-CE
554 3-phenylpropyl propionate 122-74-7 DEF
555 phenethyl (E)-but-2-enoate 68141-556 (3,3-dimethoxy-2,2-dimethylpropyl)benzene 72727-59- DF
557 (2,2-diethoxyethyl)benzene 6314-97-558 (E)-6,10-dimethylundeca-5,10-dien-2-one 38237-36- DF
559 ethyl 4-phenylbutanoate 10031-93- DEF
561 (E)-4-isopropyl-1-methyl-2-(prop-1-en-l-yl)benzene 14374-92- BDF
562 3-hepty1-5-methyldihydrofuran-2(3H)-one 40923-64- DEF
563 3-methyldodecanenitrile 85351-07- DEF
564 decyl butyrate 5454-09-1 DEF
565 (E)-2,6-dimethylocta-1,5,7-trien-3-y1 acetate 61931-78-BDF
566 (Z)-5-(oct-2-en-l-yl)dihydrofuran-2(3H)-one 18679-18- DEF
567 3-isobuty1-2,5-dimethylpyrazine 32736-94- ACF
568 4,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,1'- 107715- DEF
cyclopentan1-3-one 18-4 569 (E)-1-(2,6,6-trimethylcyclohex-1-en-l-y1)pent-l-en-3- 93840-90- DEF
ol 5 570 2-methyl-4-phenylbutan-2-y1 acetate 103-07-1 DEF
571 allyl cinnamate 1866-31-5 CE
573 p-tolyl butyrate 14617-92- BCEF
574 benzyl pentanoate 10361-39- BDEF
575 butyl decanoate 30673-36- DEF
576 octan-3-y1 butyrate 20286-45- BDEF
578 cyclohexyl hexanoate 6243-10-3 BDEF
579 4-allyI-2-methoxyphenyl formate 10031-96- C
580 hexyl 4-hydroxy-3-methoxybenzoate 84029-93- BDEF
581 1-phenylethyl butyrate 3460-44-4 BDEF
582 (E)-tridec-2-en-1-y1 acetate 68480-26- DEF
583 heptyl heptanoate 624-09-9 DEF
584 2-hexy1-4,4,6-trimethy1-1,3-dioxane 5422-04-8 BDEF
585 4-ally1-2,6-dimethoxyphenol 6627-88-9 CF
587 2,6,8-trimethylnonan-4-one 123-18-2 ADEF
588 (2,8,8-trimethy1-1,2,3,4,5,6,7,8-octahydronaphthalen- 72928-44- DEF
2-yl)methanol 0 589 diethyl octanedioate 2050-23-9 CEF
590 5-isopropyl-2-methylphenyl acetate 6380-28-5 BDF
591 1-(tetrahydrofuran-2-yl)hexyl acetate 67634-08- DEF
592 1,3,3-trimethy1-2-oxabicyclo[2.2.21octan-6-y1 acetate 72257-53-BCF
593 ethyl 2-(cyclopent-2-en-l-yl)pent-4-enoate 84682-17- BDF
594 (E)-3-(4-methoxypheny1)-2-methylacrylaldehyde 65405-67- CF
595 2,3-dimethylquinoxaline 2379-55-7 BCE
597 butyl (E)-dec-2-enoate 7492-45-7 DEF
598 3-oxo-N-phenylbutanamide 102-01-2 CE
599 (5,6-dimethy1-1-(prop-1-en-2-y1)bicyc1o[2.2.1]hept-5- 110458-DEF
en-2-yl)methanol 85-0 600 1-(2,4-dimethylcyclohex-3-en-l-y1)-2,2- 69929-17-BDF
dimethylpropan-l-one 5 601 (E)-3-butylideneisobenzofuran-1(3H)-one 551-08-6 CEF
602 4-methyl- 1, 1 '-biphenyl 644-08-6 BDE
603 41S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2- 1079-01-2 BDEF
yl)methyl acetate 604 oct-1-en-3-y1 butyrate 16491-54-BDEF
605 5-(6-methylhept-5-en-2-yl)dihydrofuran-2(3H)-one 61099-53- DF
606 2-(4-(tert-butyl)-2-methylphenoxy)acetaldehyde 67845-53-DF
607 3-phenylpropyl isobutyrate 103-58-608 (1S,3aR,4S,8aS)-4,8,8-trimethy1-9- 475-20-7 BDEF
methylenedecahydro-1,4-methanoazulene 609 (E)-4-(4-hydroxy-3-methoxyphenyl)but-3-en-2-one 1080-12-2 CEF
610 tetradecahydrocyclododeca[b]furan 72013-84- BDEF
611 ethyl 2-hydroxy-4-methoxy-6-methylbenzoate 6110-36-7 DF
612 1-(2,4-diethylphenyl)ethan-1-one 52191-01- DF
613 3a,4,7b-trimethyloctahydro-2H-4,7a- 67919-67- BDF
ethanonaphtho[1,2-b]oxirene 9 614 (E)-4-(3-hydroxyprop-1-en-l-y1)-2,6- 537-33-7 CF
di methoxyphenol 615 3-butylisobenzofuran-1(3H)-one 6066-49-5 CEF
616 2,4,5-trimethy1-4-phenyl-1,3-dioxane 37922-18-DF
618 heptan-2-y1 hexanoate 6624-58-4 BDEF
619 11-methyldodecyl acetate 69103-23-DEF
620 2-phenylpropyl isobutyrate 65813-621 dibutyl succinate 141-03-7 DEF
622 14-methylpentadecan-1-ol 36311-34-DEF
623 2-(4-methylcyclohex-3-en-1-yl)al lyl acetate 15111-97-DF
624 heptadecane 629-78-7 DEF
625 (1S,3R,6R)-2',2',3,7,7- 121251-BDEF
pentamethylspiro[bicyc1o[4.1.01heptane-2,5'- 67-0 [1,3]dioxane]
626 adamantan-2-ol 700-57-2 CEF
627 (3aS,4S,8S,8aR)-2,2,4-trimethyldecahydro-4,8- 4586-22-5 DEF
methanoazulen-9-ol 628 (E)-3-(4-hydroxy-3,5-dimethoxyphenyl)acrylaldehyde 4206-58-0 CF
629 propane-1,2-diy1 dibutyrate 50980-84- CEF
630 (3E,5E)-3,6,10-trimethylundeca-3,5,9-trien-2-one 1117-41-5 DF
631 2-(4-(formyloxy)-4-isopropylcyclohex-1-en-l-y1)ethyl 72928-49- CF
formate 5 632 (E)-2,5,9-trimethyldeca-4,9-dienal 32803-39- DF
633 diphenylamine 122-39-4 DE
634 (E)-4-(benzo[d][1,3]dioxo1-5-yl)but-3-en-2-one 3160-37-0 CEF
635 (2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 1135-66-6 BDEF
2,4a-methanonaphthalene 637 4-(6,6-dimethy1bicyclo[3.1.1lhept-2-en-2-yl)butanal 38049-28- DF
638 2-methyl-5-(prop-1-en-2-y1)cyclohexyl acetate 20405-60-BDEF
639 (Z)-hex-3-en-1-y1 oct-2-ynoate 68698-58- DEF
640 (1R,5R)-2-methyl-5-(prop-1-en-2-y1)cyclohex-2-en-1- 7111-29-7 DF
yl acetate 641 (1R,2S,5R)-5-methy1-2-(prop-1-en-2-y1)cyclohexyl 57576-09-BDEF
acetate 7 642 dimethyl undecanedioate 4567-98-0 DF
643 6,6-dimethy1-2-methylenebicyclo[3.1.1]heptan-3-y1 1078-95-1 BDEF
acetate 644 2,8,8-trimethyloctahydro-2H-4a,2- 21280-29- DF
(epoxymethano)naphthalen-10-one 5 645 (E)-3,6,10-trimethylundeca-3,9-dien-2-one 68480-10- DF
646 4-methyl-8-methyleneadamantan-2-ol 122760- CEF
647 2-(3-phenylpropyl)tetrahydrofuran 3208-40-0 DEF
648 ethyl 5,5,7-trimethyl-1-oxaspiro[2.51octane-2- 60234-72-DF
carboxylate 2 650 dodecyl 2-hydroxypropanoate 6283-92-7 DEF
651 3-methyl-4-(2,2,6-trimethylcyclohexyl)butan-2-ol 60241-53-DEF
652 isopropyl undec-10-enoate 5459-98-3 DEF
653 (E)-1-(1-ethoxyethoxy)-3,7-dimethylocta-2,6-diene 38019-89-DEF
654 dodecyl propionate 6221-93-8 DEF
655 4,5,6,7,8,9,10,11,12,13- 38303-23- DEF
decahydrocyclododeca[d]oxazole 0 656 (E)-hex-2-en-l-y1 2-hydroxybenzoate 68133-77- DEF
657 hexadecan-2-one 18787-63- DF
658 2-hexy1-2-methylbenzo[d][1,3]dioxole 68298-48- DEF
659 1,1-diethoxyundecane 53405-97- DEF
662 (2R,3'R,3a'S,7'R,8a'S)-3',8',8'- 22037-88- BDEF
trimethyloctahydrospiro[oxirane-2,6'- 3 [3a,7]methanoazulene]
663 adamantan-2-one 700-58-3 BCEF
664 I -benzylpiperazine 2759-28-6 CEF
665 heptadecan-l-ol 1454-85-9 DEF
666 4-(4-methoxypheny1)-3-methylbutan-2-one 67828-19- CEF
668 (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1- 65113-95-DF
yl)pent-3-en-2-one 3 669 2-methyl-l-phenylpropan-2-y1 propionate 67785-77- DEF
670 2,4-di-tert-butylcyclohexan-1-one 13019-04- DEF
671 4,4,6-trimethy1-2-phenyl-1,3-dioxane 2568-06-1 DEF
672 methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate 42245-42-CF
673 cinnamyl butyrate 103-61-7 DEF
674 undecyl butyrate 5461-02-9 DEF
675 ethyl 2-ethyl-3,6,6-trimethylcyclohex-2-ene-1- 58535-04-DEF
carboxylate 9 676 propyl dodecanoate 3681-78-5 DEF
677 butyl cinnamate 538-65-8 DEF
678 allyl 4-cyclohexylbutanoate 7493-65-4 DEF
679 1-(5-isopropy1-2-methylcyclohex-2-en-l-y1)propan-1- 31375-17- BDF
one 4 681 (E)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en- I - 58102-02-DF
yl)but-3-enal 6 682 (E)-2-(hex-2-en-1-yl)cyclopentyl acetate 149982-DEF
683 (E)-2,6,10-trimethylundeca-5,9-dien- 1-01 24048-14- DEF
684 1-methy1-4-(4-methylpentyl)cyclohex-3-ene-1- 66327-54- DF
carbaldehyde 6 685 (R)-1-methy1-4-(1,2,2-trimethylcyclopentyl)benzene 16982-00- BDEF
686 2-(p-tolyloxy)tetrahydro-2H-pyran 13481-09- CEF
687 phenethyl pentanoate 7460-74-4 DEF
688 palmitic acid 57-10-3 DEF
689 (1S,3aR,4R,7R,8aR)-1,4,10,10-tetramethylhexahydro- 38337-32- BDEF
1H,4H-3a,8a-epoxy-4,7-methanoazulene 5 690 1,4,10,10-tetramethylhexahydro-1H,4H-3a,8a-epoxy- 67710-71- BDEF
4,7-methanoazulene 8 691 pentyl decanoate 5933-87-9 DEF
692 benzyl hexanoate 6938-45-0 DEF
693 5-hexyltetrahydrofuran-3-y1 acetate 10039-39-DEF
694 octyl heptanoate 5132-75-2 DEF
695 2-benzy1-4,5-dimethy1-1,3-dioxolane 5468-06-4 BCEF
696 heptyl octanoate 4265-97-8 DEF
697 cyclododecyl acetate 6221-92-7 DEF
698 pentyl 2-phenylacetate 5137-52-0 DEF
699 diethyl nonanedioate 624-17-9 DEF
700 2-benzy1-4-methyl-1,3-dioxane 701 (E)-3-(benzo[d][1,3]dioxo1-5-y1)-2- 6974-47-6 CF
methylacrylaldehyde 702 1-(2,6,6-trimethylcyclohex-2-en-l-yl)pentan-3-one 68480-17-DF
703 2-(tert-butyl)-4-methylcyclohexyl acetate 115724-BDEF
705 (3R,3aS,7S,8aS)-3,6,8,8-tetramethy1-2,3,4,7,8,8a- 469-61-4 BDEF
hexahydro-1 H-3a,7-methanoazulene 706 (2-(1-butoxyethoxy)ethyl)benzene 64577-9 1 - DEF
707 (5,7,7-trimethylbicyclo[4.1.0]hept-4-en-3-yOmethyl 15103-33-BDEF
acetate 0 708 (S,E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol 1119-38-6 DEF
709 3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-blfuran 21582-36- DEF
710 (Z)-2-(3,3-dimethylbicyclo [2.2.1] heptan-2- 2226-03-1 DEF
ylidene)ethyl acetate 711 dodecyl isobutyrate 6624-71-1 DEF
712 diisopropyl adipate 6938-94-9 BCEF
713 2-(cyclohexylmethyl)pyrazine 714 (E)-2,6,10-trimethylundeca-5,9-dienal 24048-13-DF
715 2,6-di-tert-butyl-4-(hydroxymethyl)phenol 882-33-7 DEF
716 (Z)-2-benzylidenehexanal 7492-44-6 DF
717 (8E,11E,14E)-heptadeca-1,8,11,14-tetraene 71046-96-DEF
718 2-methyl-1-phenylpropan-2-y1 isobutyrate 59354-71-DEF
719 p-tolyl 3-methylbut-2-enoate 24700-20- DEF
720 1',2',3,3',3a',4,4',6',7',7a'-decahydrospiro[pyran-2,5'- 26244-[4,7]methanoindene] 9 721 1,2-dicyclohexyldisulfane 2550-40-5 DEF
724 5,5,6,7,7-pentamethylhexahydroindeno[3a,4-b]oxiren- 33704-62- CEF
4(1aH)-one 0 725 (4E,6E)-7,11-dimethyldodeca-4,6,10-trien-3-one 26651-96-DF
726 2,5-di-tert-butylbenzene-1,4-diol 727 2-hexylnonanoic acid 37165-63- --DEF
728 octadecane 593-45-3 DEF
729 8-(sec-butyl)quinoline 67634-06--- DEF
731 2-methoxy-4-(4-methyl-1,3-dioxolan-2-yl)phenol 68527-74- -- CF
732 4-(3,4-dimethoxyphenyl)butan-2-one 6302-60-9 CEF
733 (Z)-2-(furan-2-ylmethylene)octanal 67801-17- DF
734 (E)-1-(4-methoxyphenyl)pent-l-en-3-one 104-27-8 -- CF
735 3-(4-isopropylpheny1)-2-methylpropan- 1-01 4756-19-8 -- DEF
736 decahydronaphthalen-2-y1 acetate 10519-11- BDEF
737 decyl 3-methylbutanoate 72928-48--- DEF
738 (E)-6-(2,2,3-tri methylcyclopent-3-en-1-yl)hex-5-en-3- 68480-05- DEF
ol 7 739 1-(benzo[ d][1,31dioxo1-5-yl)butan-2-one 23023-13- -- CF
740 6-(tert-butyl)quinoline 68141-13--- DEF
741 (1aS,4aS,7R,8aS)-4,4,8,8-tetramethyloctahydro-4a,7- 26619-69- BDEF
methanonaphtho[1,8a-b]oxirene 2 742 p-tolyl 3-methylbutanoate 55066-56--- BDEF
743 ethyl (1 S,2R,3R,4S)-3-isopropylbicyclo[2.2.11hept-5- 116126- --BDEF
ene-2-carboxylate 82-0 744 methyl 2-(4-(tert-butyl)phenyl)acetate 3549-23-3 -- DF
745 palmitonitrile 629-79-8 DEF
746 (Z)-hex-3-en-1-y1 non-2-ynoate 68480-29- DEF
747 di methyl dodecanedioate 1731-79-9 -- DF
748 1-(1,1,3-trimethy1-2,3,4,5,6,7-hexahydro-IH-inden-5- 87641-23- DF
yl)ethan-l-one 4 750 methyl 2-propionamidobenzoate 25628-84- -- CF
751 10-methy1-1,2,3,4,5,6,7,8,9,10-decahydro-5,9- 22690-27- --DF
methanobenzo[8[annulen-11-one 3 752 methyl 1,6-dimethy1-5-(prop-1-en-2- 68698-57- -- DF
y1)bicyclo[2.2.11hept-5-ene-2-carboxylate 7 753 4-methoxybenzyl butyrate 6963-56-0 -- CEF
754 6-nonyltetrahydro-2H-pyran-2-one 2721-22-4 DEF
755 3-(2-oxopropy1)-2-pentylcyclopentan-1-one 40942-73- -- CF
757 cinnamyl (E)-2-methylbut-2-enoate 61792-12- DEF
758 3-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1- 51414-25- CF
carbaldehyde 6 759 phenethyl furan-2-carboxylate 7149-32-8 DF
760 4,9,12,12-tetramethy1-5- 1209-61-6 BDEF
oxatricyclo[8.2Ø04,6]dodecane 762 2-i sobutylqui noline 1333-58-0 DEF
763 2-((1R,3S,4S)-4-methy1-3-(prop-1-en-2-y1)-4- 639-99-6 DEF
vinylcyclohexyl)propan-2-ol 764 4-(tert-butyl)cyclohexyl propionate 68797-70- BDEF
765 (octahydro-1H-4,7-methanoinden-2-yl)methyl formate 64644-32- DEF
766 dodecyl butyrate 3724-61-6 DEF
767 (E)-3-(4,7,7-trimethylbicyclo[4.1.0Theptan-3- 68804-02-DEF
ylidene)propanenitrile 4 768 1-phenylpropyl butyrate 10031-86- DEF
769 (E)-1-(4-methoxypheny1)-4-methylpent-l-en-3-one 103- I 3-9 CEF
770 (2R,4aR,8aS)-1,1,5,5-tetramethylhexahydro-2H-2,4a- 29461-13- DEF
methanonaphthalen-8(5H)-one 0 771 2-phenethylpyridine 2116-62-3 BDEF
772 4,6-dimethy1-2-phenyl-3,6-dihydro-2H-pyran 68039-41- BDEF
773 ( I R,9S,Z)-4,11,11-trimethy1-8- 118-65-0 BDEF
methylenebicyclo[7.2.01undec-4-ene 774 (Z)-3-phenylally1 pentanoate 10482-65- DEF
775 ethyl 2-methyl-3-(p-tolypoxirane-2-carboxylate 108492-CF
776 butyl dodecanoate 106-18-3 DEF
777 (E)-2,3-dimethy1-4-(2,6,6-trimethylcyclohex-2-en- 1- 68140-49- DF
yl)but-3-enal 8 778 3-phenylpropyl pentanoate 5451-88-7 DEF
779 3,6,6,7a-tetramethyloctahydro-2H-2a,7- 29597-36- BDEF
methanoazuleno[5,6-13]oxirene 2 780 cinnamyl 2-methylbutanoate 67883-77- DEF
781 (E)-4-methyl-2-styry1-1,3-dioxane 5420-98-4 CEF
782 benzo[d]1-1,3 klioxo1-5-ylmethyl isobutyrate 5461-08-5 CF
783 phenethyl hexanoate 6290-37-5 DEF
784 3,7-di methylocta-1,6-dien-3-y1 pentanoate 10471-96- DEF
785 diethyl decanedioate 110-40-7 DEF
786 hexyl 2-phenylacetate 5421-17-0 DEF
787 6-isopropyldecahydronaphthalen-2-ol 34131-99- DEF
788 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienal 502-67-0 DF
789 4-(3-oxobutyl)phenyl acetate 3572-06-3 CF
790 1,7,7-trimethylbicyclo12.2.1]heptan-2-y1 isobutyrate 50277-27-BDEF
792 ethyl 3-(4-methoxyphenyl)oxirane-2-carboxylate 16546-01- CF
793 2-methyl-34(1,7,7-trimethylbicyclo[2.2.1]heptan-2- 1281 I 9-DEF
yl)oxy)propan-l-ol 70-0 794 (E)- I -(((E)-non-2-en-l-yl)oxy)non-2-ene 68555-30- DEF
795 methyl 3-(bicyclo12.2.11hept-5-en-2-y1)-3- 72175-33-BCEF
methyloxirane-2-carboxylate 8 796 (E)-hex-2-en-1-y1 2-phenylacetate 797 (Z)-hex-3-en-1-y1 2-phen ylacetate 799 3-(4-(tert-butyl)pheny1)-2-methylpropan-1-ol 56107-04-DEF
800 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 4951-48-8 BDEF
propionate 801 2-methyl-4-methylene-6-phenyltetrahydro-2H-pyran 30310-41- BDEF
802 2-isopropyl-5-methylcyclohexyl 2-hydroxypropanoate 17162-29- DF
803 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl (S)-2- 61597-98-DF
hydroxypropanoate 6 804 4,7,7-trimethy1-4-(3-methylbut-2-en-1- 74499-59- DF
yl)bicyclo[4.1.0]heptan-3-one 5 805 4,4,8-trimethyltricyclo[6.3.1.02,51dodecan-1-y1 58096-46-DEF
formate 1 806 (Z)-2-methyl-1-(2,2,6-trimethylcyclohex-3-en-1- 68555-94-DF
yl)pent-l-en-3-one 2 807 3-((2-isopropy1-5-methylcyclohexyl)oxy)propane-1,2- 87061-04- CEF
diol 9 808 nonadecane 629-92-5 DEF
809 (Z)-2-benzylideneheptanal 1331-92-6 DF
810 4-(tert-butyl)cyclohexyl isobutyrate 5451-57-0 BDEF
811 (E)-1-(1-ethoxyethoxy)-2-methoxy-4-(prop-1-en-1- 84029-92-DF
yl)benzene 5 812 2-methyl-4-phenylbutan-2-y1 isobutyrate 10031-71- DEF
813 4,7,7-trimethy1-2-(3-methylbut-2-en-1- 74499-58- DF
yObicyclo14.1.01heptan-3-one 4 814 (E)-2-(( I S,3aR,4S,8aS)-4,8,8-trimethyldecahydro-I,4- 5989-05-9 DEF
methanoazulen-9-ylidene)ethan- I -ol 815 2,6,10,10-tetramethyl-l-oxaspirol-4.51decan-6-y1 72541-09-DF
acetate 4 816 6-i sopropyloctahydronaphthalen-2(1H)-one 34131-98- DEF
817 (2E,6E)-1-methoxy-3,7,11-trimethyldodeca-2,6,10- 15130-76-DEF
triene 4 818 cinnamyl 3-methyl butanoate 140-27-2 DEF
819 (octahydro-1H-4,7-methanoi nden-l-yl)methyl acetate 30772-69- DEF
820 7-ethoxy-4-methyl-2H-chromen-2-one 87-05-8 CF
821 isobutyl dodecanoate 37811-72-DEF
822 (S)-1-methy1-4-(6-methylhepta- I ,5-dien-2- 495-61-4 DEF
yl)cyclohex-1-ene 823 (E)-4-methy1-6-(2,2,3-trimethylcyclopent-3-en-1- 67801-19-DEF
yl)hex-4-en-3-ol 8 824 (E)-4-(2,6,6-trimethylcyclohex- 1 -en-l-yl)but-3-en-2- 22030-19-DF
yl acetate 9 825 4-(2,2,6-trimethylcyclohexyl)butan-2-y1 acetate 68555-59-DEF
826 3-phenylpropyl 3-methylbutanoate 5452-07-3 DEF
827 2-methyltetradecahydrocyclododecalblfuran 86505-83- DEF
828 3,8,8-trimethy1-6-methyleneoctahydro-IH-3a,7- 28231-03- DEF
methanoazulen-5-ol 0 829 phenyl 2-hydroxybenzoate 118-55-8 DF
830 (3R,3aR,6S,7S,8aS)-3,6,8,8-tetramethylhexahydro- 13794-73-DEF
1H-3a,7-methanoazulen-5(4H)-one 5 831 3,7-dimethylocta-1,6-dien-3-y1 3-methylbutanoate 1118-27-0 DF
832 (E)-4-methyl-6-(2,2,3-trimethylcyclopent-3-en-1- 67801-25-DEF
yl)hex-5-en-3-ol 6 833 8,8-dimethy1-1,2,3,4,5,6,7,8-octahydronaphthalene-2- 72928-51- DEF
carbonitri le 9 834 methyl 2-((1R,2R)-3-oxo-2-pentylcyclopentyl)acetate 2630-39-9 CF
835 I -(4,4-dimethy1-1,2,3,4-tetrahydronaphthalen-1- 74499-60-DF
yl)propan-l-one 8 836 8,12-di methyltridec-1 I -en-6-one 68141-18- DF
837 (E)-4-(2,6,6-trimethylcyclohex-2-en-l-yl)but-3-en-2- 52210-18- DF
yl acetate 1 838 propyl (E)-3-(4-methoxyphenypacrylate 68141-12- DEF
839 2-ethoxy-4-(4-methyl-1,3-dioxolan-2-yl)phenol 68527-76- CF
840 2-(4-methylcyclohex-3-en- I -yl)propan-2-y1 butyrate 2153-28-8 DEF
841 5,5,8a-trimethyldecahydronaphthalen-2-y1 acetate 24238-95-DEF
842 3-benzylheptan-4-one 7492-37-7 DF
843 ethyl pentadecanoate 41114-00-DEF
844 (2-(benzyloxy)ethyl)benzene 54894-37- DEF
846 2-isobutoxynaphthalene 2173-57-1 DEF
847 hexadecyl acetate 629-70-9 DEF
848 1,1,7-trimethyldecahydro-3a,7- 58096-47- DEF
methanocyclopent481annulen-3-y1 formate 2 849 1,7,7-trimethylbicyc1o[2.2.1[heptan-2-y1 butyrate 13109-70-BDEF
850 heptadecan-9-one 540-08-9 DE
851 1-ethoxy-4-(1-ethoxyviny1)-3,3,5,5- 36306-86-DEF
tetramethylcyclohex-l-ene 2 852 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-y1 68479-99-DF
acetate 2 853 4-(3-phenylpropyl)pyridine 2057-49-854 3-(3-phenylpropyl)pyridine 1802-34-855 allyl 6-cyclohexylhexanoate 7493-856 (2R,4a'R,8a'R)-3,6'-dimethy1-3',4',4a',5',8',8a'- 41723-98-DEF
hexahydro-l'H-spiro[oxirane-2,2'- 2 [1,4]methanonaphthalene]
857 ((2S,4aR)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro- 61826-53- DEF
2H-2,4a-methanonaphthalen-8-yl)methanol 7 858 (octahydro-1H-4,7-methanoindene-2,5- 28132-01-CEF
diyedimethanol 6 859 (1R,5S,9S,E)-4,11,11-trimethy1-8- 32214-88- DEF
methylenebicyclo[7.2.0jundec-3-en-5-ol 3 860 stearic acid 57-11-4 DEF
861 2-ethylbutyl 2-(cyclopent-1-en-l-y1)acetate 68092-41- DEF
862 1-(4-butoxy-2,2,6,6-tetramethylcyclohex-3-en-1- 16556-52-DF
yl)ethan-l-one 8 863 2,6-di-tert-butyl-4-(hydroxymethyl)phenol 88-26-6 DEF
864 (E)-2-methyl- -( I -methylbicyclo[2.2.11hept-5-en-2- 67739-11-DEF
yl)pent-l-en-3-ol 1 865 pentyl dodecanoate 5350-03-8 DEF
866 cinnamyl hexanoate 6994-20-3 DEF
867 (E)-1-(3,5,6-trimethylcyclohex-3-en-l-yl)pent-I-en-3- 67801-32- DF
one 5 868 (E)-1-(2,4,6-trimethylcyclohex-3-en-l-yl)pent-l-en-3- 67801-30- DF
one 3 869 ethyl 3-(3,3-dimethylbicyclo[2.2.1]heptan-2- 22833-73- DEF
yl)propanoate 4 870 3-phenylpropyl hexanoate 6281-40-9 DEF
871 2-((3S,3aS,5R,8S,8aS)-3,8-dimethyldecahydroazulen- 3526-75-8 DEF
5-yl)propan-2-ol 872 benzyl octanoate 10276-85-DEF
873 (2E,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal 4955-32-2 DE
874 2,3-dihydroxypropyl dodecanoate 142-18-7 DEF
875 (E)-hex-3-en-1-y1 cinnamate 68133-876 1-(2,5,5-trimethy1-1,3,4,5,6,7-hexahydro-2H-2,4a- 32388-56-DEE
ethanonaphthalen-8-yl)ethan-l-one 0 877 2,3-dihydroxypropyl 5-hydroxydecanoate 26446-31-CEF
878 2-methylbutyl cinnamate 4654-29-9 DEF
879 cyclohexyl 2-(cyclopent-2-en- I -yl)acetate 65405-69-DF
880 1,2-dimethy1-4-(1-phenylethyl)benzene 6196-95-8 DEF
881 (E)-2-methoxy-1-(pentyloxy)-4-(prop- I -en- I - 10484-36-DEF
yl)benzene 3 884 oxacyclohexadecane-2,13-d ione 38223-29- DEF
885 2-methyl-3-(2-methyl-5-(prop-1-en-2-y1)cyclopent-1- 54043-73- DEF
en-l-yl)propyl acetate 1 886 [1,1'-bi(cyclopentan)]-2-y1 (E)-but-2-enoate 68039-73-DEF
887 (3R,3aR,7S,8aS)-3,6,8,8-tetramethy1-1,2,3,7,8,8a- 30960-39-DF
hexahydro-4H-3a,7-methanoazulen-4-one 5 888 1-(2,3,8,8-tetramethy1-1,2,3,5,6,7,8,8a- 68155-66-DF
octahydronaphthalen-2-yl)ethan-1-one 8 889 naphthalen-l-yl butyrate 3121-70-8 DEF
890 diisobutyl adipate 141-04-8 DEF
891 7-isopropyl-5-methylbicyclo[2.2.2loct-5-ene-2- 68311-05-DEF
carbonitrile 7 894 (E)-chalcone 614-47-1 DEF
895 (E)-4-(1,3a,4,6,7,7a-hexahydro-5H-4,7- 126646-DEF
methanoinden-5-ylidene)butan-2-ol 14-8 896 (E)-3-((2,6,6-trimethylcyclohex-2-en-1- 26903-19-DF
ylidene)methyl)hex-5-en-2-one 5 897 (octahydro-1H-4,7-methanoinden-2-yl)methyl acetate 64644-34- DEF
898 o-tolyl 2-hydroxybenzoate 617-01-6 DF
899 (9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid 463-40-1 DEF
901 methyl (E)-3-methyl-3-(2-(2,6,6-trimethylcyclohex-2- 67905-40- DF
en-l-yl)vinyl)oxirane-2-carboxylate 2 902 3-methyl-4-(2,2,6-trimethylcyclohexyl)butan-2-y1 60241-55-DEF
acetate 6 903 (3aR,5aS,9aS,9bR)-3a,6,6,9a- 564-20-5 DEF
tetramethyldecahydronaphtho[2,1-b]furan-2(1H)-one 904 (E)-3-methy1-4-(2,6,6-trimethylcyclohex-2-en-1- 68555-61-DF
yl)but-3-en-2-y1 acetate 3 905 (E)-5-methyl-1-(2,6,6-trimethylcyclohex-2-en-1- 70092-23-DF
yl)hex-1-en-3-one 8 906 decahydronaphthalen-2-y1 isobutyrate 67874-78-DEF
907 p-tolyl benzoate 614-34-6 DF
908 butyl tetradecanoate 110-36-1 DEF
909 4-(benzo[d][1,3]dioxo1-5-yl)butan-2-y1 acetate 68844-96-CF
910 hexyl dodecanoate 34316-64- DEF
911 heptyl cinnamate 10032-08- DEF
912 10,11-dihydro-5H-dibenzo[a,d]
Plannulen-5-one 1210-35-1 DEF
913 (4E,8E)-2,6,10-trimethy1-13- 14840-89- DEF
oxabicyclo[10.1.0]trideca-4,8-diene 2 914 (3aR,4aR,8aS,9aR)-3a,4,4a,5,8,8a,9,9a-octahydro-1H- 7158-25-0 DEF
4,9:5,8-dimethanocyclopenta[b]naphthalene 915 phenethyl octanoate 5457-70-5 DEF
916 octyl 2-phenylacetate 122-45-2 DEF
917 cyclohexyl 2-phenylacetate 42288-75- DF
918 p-tolyl octanoate 59558-23- DEF
919 ((2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 61826-52- DEF
2,4a-methanonaphthalen-8-yl)methyl formate 6 920 5,5,7,8,8-pentamethy1-5,6,7,8-tetrahydronaphthalene- 113221-DF
2-carbaldehyde 73-1 921 (S,Z)-3,7,11-trimethyldodeca-1,6,10-trien-3-y1 acetate 56001-43- DF
922 4-methyl-8-methyleneadamantan-2-y1 acetate 122760- DEF
923 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 3- 1142-85-4 DEF
methylbutanoate 924 1,1,3-trimethy1-3-pheny1-2,3-dihydro-1H-indene 3910-35-8 DF
925 henicosane 629-94-7 DEF
926 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-y1 68039-39- DEF
isobutyrate 4 927 (4R,4aS,6R,8aS)-4,4a-dimethy1-6-(prop-1-en-2- 20489-53- DEF
yl)octahydronaphthalen-2(1H)-one 6 928 (E)-3-methy1-4-(2,6,6-trimethylcyclohex-1-en-1- 76649-19- DF
yl)but-3-en-2-y1 acetate 9 929 heptyl undec-10-enoate 68141-27-DEF
931 1-(3,6,8,8-tetramethy1-2,3,4,7,8,8a-hexahydro-1H- 68039-35- DF
3a,7-methanoazulen-5-yl)ethan-l-one 0 932 2-(1,1,2,3,3-pentamethy1-2,3-dihydro-1H-inden-5- 1217-08-9 DEF
yl)propan-l-ol 933 isobutyl tetradecanoate 25263-97-DEF
934 5-(diethoxymethyl)-3a,4,5,6,7,7a-hexahydro-IH-4,7- 67633-92- DEF
methanoindene 5 935 propane-1,2,3-triy1 tripropionate 139-45-7 CEF
936 8-(tert-butyl)-4,6-dimethyl-2H-chromen-2-one 17874-34- DF
937 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646-DEF
methanoinden-5-y1)-3-methylbut-3-en-2-ol 07-9 938 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646-DEF
methanol nden-6-y1)-3-methylbut-3-en-2-ol 06-8 939 p-tolyl 2-hydroxybenzoate 607-88-5 DF
940 ethyl heptadecanoate 14010-23-DEF
941 2-((4-isopropylcyclohex-1-en-1- 56175-55- DF
yl)methyl)cyclopentan-l-one 4 943 cinnamyl benzoate 5320-75-2 DF
944 4-(5,5,6-trimethylbicyclo[2.2.1]heptan-2- 66068-84-DEF
yl)cyclohexan-l-ol 6 945 (7,7,8,8-tetramethyloctahydro-2,3b- 59056-70- DEF
methanocyclopenta[1,3]cyclopropa[1,2]benzen-4- 1 yl)methyl formate 946 1,3-diphenylpropan-2-one 102-04-5 DEF
947 2-isopropyl-5-methylcyclohexyl 3-methylbutanoate 16409-46-DEF
948 methyl (E)-2-(octylideneamino)benzoate 67801-44-DEF
949 1,1,3,3,5-pentamethy1-4,6-dinitro-2,3-dihydro-1H- 116-66-5 DF
indene 950 (2,2-diisobutoxyethyl)benzene 68345-22- DEF
951 2,2-dimethy1-3-(2-methyl-5-(prop-1-en-2- 84012-64-DEF
yl)cyclopent-l-en-l-y1)propyl propionate 6 952 methyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 301-00-8 DEF
953 diisopentyl 2-mercaptosuccinate 68084-03- DEF
954 3-((2R)-5,5,6-trimethylbicyclo [2.2.1] heptan-2- 3407-42-9 DEF
yl)cyclohexan-l-ol 956 isopentyl (E)-3-(4-methoxyphenyl)acrylate 71617-10-DF
957 diisopropyl decanedioate 7491-02-3 DEF
958 3-ethyl-5,5,8,8-tetramethy1-5,6,7,8- 58243-85-DF
tetrahydronaphthalene-2-carbaldehyde 9 959 (E)-2-((lS,3aR,4S,8aS)-4,8,8-tri methyldecahydro-1,4- 27530-63-DEF
methanoazulen-9-ylidene)ethyl acetate 8 960 (1S)-3-((Z)-benzylidene)-1,7,7- 36275-29- DEF
trimethylbicyclo[2.2.1]heptan-2-one 3 961 (Z)-3-benzylidene-1,7,7- 15087-24- DEF
trimethylbicyclo[2.2.1]heptan-2-one 8 962 isopentyl tetradecanoate 62488-24- DEF
964 3-(5,5-dimethy1-6-methylenebicycloi 2.2.1Theptan-2- 68141-24-DEF
yl)cyclohexan-l-ol 2 965 ((3R,3aS,7R,8aS)-3,8,8-trimethy1-2,3,4,7,8,8a- 1405-92-1 DEF
hexahydro-1H-3a,7-methanoazulen-6-yl)methyl acetate 966 ethyl stearate 111-61-5 DEF
967 bis(2,4-dihydroxyphenyl)methanone 131-55-5 CEF
968 6,10,14-trimethylpentadecan-2-one 13955-74- DEF
3 _________________________________________________________ 969 2-methoxyphenyl 2-phenylacetate 4112-89-4 DF
970 5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-l-y1)-5- 117933-DEF
methyl-1,3-dioxane 89-8 971 (5E,9E)-6,10,14-trimethylpentadeca-5,9,13-trien-2- 1117-52-8 DF
one 972 1-(3-ethy1-5,5,8,8-tetramethy1-5,6,7,8- 88-29-9 DF
tetrahydronaphthalen-2-yl)ethan-1-one 973 2-(4-ally1-2-methoxyphenoxy)tetrahydro-2H-pyran 72066-75- CF
974 butyl palm itate 111-06-8 DEF
976 hexyl tetradecanoate 42231-99- DEF
977 ethyl oleate 111-62-6 DEF
978 decyl decanoate 1654-86-0 DEF
979 m-tolyl 2-phenylacetate 122-27-0 DF
980 1-(3,3-diethoxy-2-methylpropy1)-4-isopropylbenzene 7149-24-8 DEF
981 tricosane 638-67-5 DEF
982 ethyl (9Z,12Z)-octadeca-9,12-dienoate 544-35-4 DEF
983 ethyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 1191-41-9 DEF
984 1,3,3-trimethylbicyclo[2.2.1]heptan-2-y1 benzoate 55066-54-DEF
985 dibutyl phthalate 84-69-5 DEF
986 isobutyl pal mitate 110-34-9 DEF
987 2-isopropoxy-1,2-diphenylethan-1-one 6652-28-4 DEF
988 2-ethyl-4,5-dimethylthiazole 87-29-6 DF
989 dibutyl decanedioate 109-43-3 DEF
990 (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-y1 2639-68-1 DF
isobutyrate 991 2-methoxy-4-(1,7,7-trimethylbicyclo[2.2.11heptan-2- 13746-56- DEF
yl)phenol 0 992 methyl (E)-2-((2-phenylethylidene)amino)benzoate 67785-76-DF
993 methyl (E)-2-((3,5,5- 67801-42- DEF
trimethylhexylidene)amino)benzoate 7 994 2-(2-(3,3,5-trimethylcyclohexyl)acetyl)cyclopentan-1- 84642-57- DEF
one 9 995 phenethyl cinnamate 103-53-7 DF
996 methyl (E)-2-(decylideneamino)benzoate 67874-67- DEF
997 3,3,5-trimethylcyclohexyl 2-hydroxybenzoate 118-56-9 DF
998 (2S,4R)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 51-6 999 (2S,4S)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 52-7 1000 cinnamyl 2-phenylacetate 7492-65-1 DF
1001 2-butoxy-1,2-diphenylethan-1-one 22499-11- DF
1002 (2,2-bis(isopentyloxy)ethyl)benzene 68555-28-DEF
1003 3,7-dimethylocta-1,6-dien-3-y1 2-phenylacetate 7143-69-3 DF
1004 ((ethane-1,1-diylbis(oxy))bis(ethane-2,1- 122-71-4 DEF
diy1))dibenzene 1005 (6E,10E)-3,7,11,15-tetramethylhexadeca-6,10,14- 70851-60-DEF
trien-3-ol 4 1006 (E)-3,7-dimethylocta-2,6-dien-l-y1 2-am inobenzoate 67874-69-DF
1007 3,7-dimethyloct-6-en-1-y1 2-aminobenzoate 68555-57- DF
1008 (6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14- 2211-30-5 DF
tetraen-3-ol 1009 2-isobutoxy-1,2-diphenylethan-1-one 22499-12-DEF
1010 4-ally!-1-(benzyloxy)-2-methoxybenzene 57371-42-DF
1011 (1R)-1,7,7-trimethy1-3-((Z)-4- 36861-47- DEF
methylbenzylidene)bicyclo[2.2.1]heptan-2-one 9 1012 1-(4-hydroxy-3-methoxyphenyl)decan-3-one 27113-22- DF
1013 methyl 3-(3,5-di-tert-butyl-4- 6386-38-5 DEF
hydroxyphenyl)propanoate 1014 3,7,11,15-tetramethylhexadec-1-yn-3-ol 29171-23-DEF
1015 2-hydroxypropyl stearate 142-75-6 DEF
1016 3-phenylpropyl cinnamate 122-68-9 DF
1017 7,11,15-trimethy1-3-methylenehexadec-1-ene 504-96-1 DEF
1018 decyl dodecanoate 36528-28- DEF
1019 (7R,11R,E)-3,7,11,15-tetramethylhexadec-2-en- 1 -ol 150-86-7 DEF
1020 (3R,5S,8R,9S,10S,13R,14S)-10,13-dimethyl- 1153-51-1 DEF
2,3,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-1H-cyclopentaralphenanthren-3-ol 1021 (S)-3,7-dimethyloct-7-en-1-y1 2-phenylacetate 10486-14-DF
1022 1-phenethoxy-2-(p-tolyloxy)ethan-1-ol 72987-59-DF
1023 ethyl (R,Z)-12-hydroxyoctadec-9-enoate 55066-53-DEF
1024 propane-1,2,3-triy1 tributyrate 60-01-5 CEF
1025 p-tolyl dodecanoate 10024-57- DEF
1026 butyl oleate 142-77-8 DEF
1027 (7-isopropyl-1,4a- 13393-93- DEF
dimethyltetradecahydrophenanthren-l-yl)methanol 6 1028 p-tolyl 3-oxo-3-phenylpropanoate 67801-43- DEF
1029 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 2- 14481-52- DF
aminobenzoate 8 1030 (5S,8R,9S,10S,13R, I 4S)-10,13-dimethyl- 18339-16- DEF
1,2,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-3H- 7 cyclopenta[a]phenanthren-3-one 1031 methyl 2-(((lE,2E)-3,7-dimethylocta-2,6-dien-1- 67801-47-DF
ylidene)amino)benzoate 2 1032 (7-i sopropy1-1,4a-dimethy1-1,2,3,4,4b,5,6,7,8,8a,9,10- 26266-77- DEF
dodecahydro-4a15-phenanthren-l-yl)methanol 3 1033 methyl (E)-2-((4- 14735-72- DF
methoxybenzylidene)amino)benzoate 9 1034 4-(6-methylhepta-1,5-dien-2-y1)-1-(4-methylpent-3- 532-87-6 DEF
en-l-yl)cyclohex- I -ene 1035 propane-1,2-diy1 dibenzoate 19224-26- DF
1036 methyl (E)-2-((3,7-dimethyloct-6-en-1- 67845-42- DF
ylidene)amino)benzoate 5 1037 4-ally1-2-methoxyphenyl benzoate 531-26-0 DF
1038 N-(4-hydroxy-3-methoxybenzyl)nonanamide 2444-46-4 DEF
1039 2,3-dihydroxypropyl stearate 123-94-4 DEF
1040 dodecyl 3,4,5-trihydroxybenzoate 1166-52-5 DEF
1041 (E)-2-methyl-5-(2-methyl-3- 67633-98- DEF
methylenebicyclo[2.2.11heptan-2-yppent-2-en-1-y1 1 butyrate 1042 2-phenyl-1H-benzo[dlimidazole-5-sulfonic acid 27503-81-ACF
1043 9-Octadecenoic acid (9Z)-, 2,3-dihydroxypropyl ester 111-03-5 DEF
1044 methyl (E)-2-((4-hydroxy-3- 72927-84- DF
methoxybenzylidene)amino)benzoate 5 1045 isopentyl stearate 627-88-3 DEF
1046 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 2- 26171-78-DEF
phenylacetate 8 1047 (S)-2-(4-methylcyclohex-3-en-l-yl)propan-2-y1 10024-56-DF
cinnamate 3 1048 2-methyl-5-(prop-1-en-2-y1)cyclohex-2-en-1-y1 2- 72152-81-DF
phenylacetate 9 1049 2-ethylhexyl (E)-3-(4-methoxyphenyl)acrylate 5466-77-3 DEF
1052 (E)-2-methoxy-4-(prop- I -en-l-yl)phenyl 2- 120-24-1 DF
phenylacetate 1053 dioctyl adipate 123-79-5 DEF
1054 methyl (1R,4aR,4bS,7R,8a5,10aR)-7-isopropy1-1,4a- 19941-28-DEF
dimethyltetradecahydrophenanthrene-l-carboxylate 7 1055 octadecyl heptanoate 66009-41-DEF
1056 methyl (1R,4aS,4b8,8aR,10aR)-7-isopropy1-1,4a- 33892-18-DEF
dimethy1-1,2,3,4,4a,4b,5,6,8a,9,10,10a- 1 dodecahydrophenanthrene-l-carboxylate 1057 methyl 7-isopropyl-1,4a-dimethyl- 67893-02- DEF
1 ,2,3,4,4a,4b,5,6,7,8,10,10a- 1 dodecahydrophenanthrene-l-carboxylate 1058 (7R,IIR,E)-3,7,11,15-tetramethylhexadec-2-en-1-y1 10236-16-DEF
acetate 5 1059 propane-1,2-diy1 dinonanoate 41395-83- DEF
1060 4-ally1-2-methoxyphenyl 2-phenylacetate 10402-33- DF
1061 methyl ( I R,4aR,4bR,10aR)-7-isopropy1-1,4a- 127-25-3 DEF
dimethy1-1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthrene-1-carboxylatedecahydrophenanthrene-l-carboxyl ate (1:1) 1062 bis(2-(2-butoxyethoxy)ethyl) adipate 141-17-3 DEF
1063 ((1R,4aR,4bR,10aR)-7-isopropy1-1,4a-di methyl- 54200-50-DEF
1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthren-1- 9 yl)methyl acetate 1064 octadecyl octanoate 18312-31- DEF
1065 tetradecyl dodecanoate 22412-97-DEF
1066 2-ethylhexyl palmitate 29806-73-DEF
1067 methyl (E)-2-((3-(4-methoxyphenyI)-2- 111753- DF
methylpropylidene)amino)benzoate 62-9 1068 1-(4-(tert-butyppheny1)-3-(4-methoxyphenyppropane- 70356-09- DEF
1,3-dione 1 1070 2-(3,4-dihydroxy-5-oxo-2,5-dihydrofuran-2-yI)-2- 137-66-6 DEF
hydroxyethyl palmitate 1071 dodecyl palmitate 42232-29- DEF
1073 methyl (E)-2-((3-(benzo[d] [1,3]dioxo1-5-y1)-2- 111753-DF
methylpropylidene)amino)benzoate 60-7 1074 (2R,3R,4S,5R)-6-oxohexane-1,2,3,4,5-pentayl 3891-59-6 CF
pentaacetate 1075 (((2-phenylethane-1,1- 65416-19-DF
diyObis(oxy))bis(methylene))dibenzene 5 1076 methyl (E)-2-(((4-(4-hydroxy-4- 67634-12- DF
methylpentyl)cyclohex-3-en-1- 2 yl)methylene)amino)benzoate 1077 bis(2-ethylhexyl) adipate 103-23-1 DEF
1078 methyl 2-(((E)-2-((E)- 68527-78-DEF
benzylidene)heptylidene)amino)benzoate 6 1079 1,1'-(2-phenylethane-1,1-diy1)bis(IH-indole) 67801-37- DF
1080 octadecyl tetradecanoate 3234-81-9 DEF
1081 didecyl phthalate 84-77-5 DEF
1082 2,5,7,8-tetramethy1-2-(4,8,12-trimethyltridecyl)chroman-6-ol 0 1083 2,5,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 148-03-8 DEF
6-ol 1084 2,7,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 54-28-4 DEF
6-ol 1085 2,8-dimethy1-2-(4,8,12-trimethyltridecyl)chroman-6- 119-13-1 DEF
ol 1087 (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta- 458-37-7 CEF
1,6-diene-3,5-dione 1088 2,6,10,15,19,23-hexamethyltetracosane 1 1 1 -01-3 DEF
1090 (6E,10E,14E,18E)-2,6,10,15,19,23- 111-02-4 DEF
hexamethyltetracosa-2,6,10,14,18,22-hexaene 1091 1,1'-(3,7-dimethyloct-6-ene-1,1-diy1)bis(IH-indole) 67801-16- DEF
1092 (2,2-bis((3,7-dimethyloct-6-en-1- 67634-04- DEF
yl)oxy)ethyl)benzene 2 1093 (2E,4E,6E,8E,10E,12E,14E,16E)-2,6,11,15- 1107-26-2 DF
tetramethy1-17-(2,6,6-trimethylcyclohex-1-en-1-y1)heptadeca-2,4,6,8,10,12,14,16-octaenal 1094 8,8-di(1H-indo1-3-y1)-2,6-dimethyloctan-2-ol 67860-00- DEF
1095 propane-1,2,3-triy1 tribenzoate 1096 11,11-bis((3,7-dimethyloct-6-en-1-yl)oxy)undec- 1- 67785-67-DEF
ene 5 1097 11,11-bis(((E)-3,7-dimethylocta-2,6-dien-1- 67785-74- DF
yl)oxy)undec-1-ene 4 1098 isopentyl 2-(((E)-2-((Z)- 72928-46- DEF
benzylidene)octylidene)amino)benzoate 2 1099 propane-1,2,3-triy1 trioctanoate 1100 octadecyl stearate 2778-96-3 DEF
1101 didodecyl phthalate 2432-90-8 DEF
1103 1((3,7-dimethy1-14(11-methyldodecypoxy)oct-6-en- 67923-82- DEF
1-yl)oxy)-11-methyldodecane 4 1104 (E)-(2-(bis((3,7-dimethylocta-1,6-dien-3- 67785-71- DEF
yl)oxy)methyl)hept-l-en-l-y1)benzene 1 1105 ((E)-2-(bis(((E)-3,7-dimethylocta-2,6-dien-1- 67785-69- DEF
ypoxy)methyphept-l-en-l-y1)benzene 7 1106 3,7-dimethylocta-1,6-dien-3-y1 2-(((E)-2-((E)- 72928-45- DEF
benzylidene)octylidene)amino)benzoate 1 1107 propane-1,2,3-triy1 tris(decanoate) 621-71-6 DEF
1108 2-hydroxypropane-1,3-diy1 distearate 1323-83-7 ADEF
1109 3,5-di methyladamantane-l-carboxylic acid 14670-94-DF
1 1 1 0 dimethyl cyclohexane-1,4-dicarboxylate 94-60-0 BCF
1111 (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1- 88335-93-carboxylic acid 7 1112 methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate 42245-42- CF
1113 (E)-1,1,4,4-tetramethoxybut-2-ene 6068-1114 dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5- 37031-29- CF
dicarboxylate 1 1115 1,2,3,4,5,6-hexamethylbenzene 87-85-4 BDEF
1116 dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate 4841-84-3 BCEF
Table 2 List of materials with at least one MORV greater than 5 to 10 Number IUPAC Name CAS Comment Number Code 25 Mannitol 87-78-5 CF
42 a-D-Glucopyranose 492-62-6 CF
174 2,4,6-trimethy1-1,3,5-trithiane 2765-04-0 BDEF
190 3,5-diethyl-1,2,4-trithiolane 54644-28- BDEF
248 3,5-diisopropy1-1,2,4-trithiolane 54934-99- DEF
613 3a,4,7b-trimethyloctahydro-2H-4,7a- 67919-67- BDF
ethanonaphtho[1,2-b]oxirene 9 689 (1S,3aR,4R,7R,8aR)-1,4,10,10- 38337-32- BDEF
tetramethylhexahydro-1H,4H-3a,8a-epoxy-4,7- 5 methanoazulene 690 1,4,10,10-tetramethylhexahydro-1H,4H-3a,8a-epoxy- 67710-71- BDEF
4,7-methanoazulene 8 695 2-benzy1-4,5-dimethy1-1,3-dioxolane 5468-06-4 BCEF
717 (8E,11E,14E)-heptadeca-1,8,11,14-tetraene 71046-96- DEF
751 10-methy1-1,2,3,4,5,6,7,8,9,10-decahydro-5,9- 22690-27- DF
methanobenzo[8]annulen-11-one 3 779 3,6,6,7a-tetramethyloctahydro-2H-2a,7- 29597-36- BDEF
methanoazuleno[5,6-b]oxirene 2 814 (E)-2-((lS,3aR,4S,8aS)-4,8,8-trimethyldecahydro- 5989-05-9 DEF
1,4-methanoazulen-9-ylidene)ethan-l-ol 828 3,8,8-trimethy1-6-methyleneoctahydro-IH-3a,7- 28231-03- DEF
methanoazulen-5-ol 0 830 (3R,3aR,6S,7S,8aS)-3,6,8,8-tetramethylhexahydro- 13794-73- DEF
1H-3a,7-methanoazulen-5(4H)-one 5 914 (3aR,4aR,8aS,9aR)-3a,4,4a,5,8,8a,9,9a-octahydro- 7158-25-0 DEF
1H-4,9:5,8-dimethanocyclopentaiblnaphthalene 919 ((2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 61826-52- DEF
2,4a-methanonaphthalen-8-yl)methyl formate 6 945 (7,7,8,8-tetramethyloctahydro-2,3b- 59056-70- DEF
methanocyclopentall,31cycloprop41,21benzen-4- 1 yl)methyl formate 959 (E)-2-((1S,3aR,4S,8aS)-4,8,8-trimethyldecahydro- 27530-63-DEF
1,4-methanoazulen-9-ylidene)ethyl acetate 8 965 ((3R,3aS,7R,8aS)-3,8,8-trimethy1-2,3,4,7,8,8a- 1405-92-1 DEF
hexahydro-1H-3a,7-methanoazulen-6-yl)methyl acetate 991 2-methoxy-4-(1,7,7-trimethy1bicyclo12.2.11heptan-2- 13746-56- DEF
yl)phenol 0 998 (2S,4R)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 51-6 999 (2S,4S)-2,4-dimethy1-2-(5,5,8,8-tetramethy1-5,6,7,8- 131812-DF
tetrahydronaphthalen-2-y1)-1,3-dioxolane 52-7 1020 (3R,5S,8R,9S,10S,13R,14S)-10,13-dimethyl- 1153-51-1 DEF
2,3,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-1H-cyclopentaralphenanthren-3-ol 1027 (7-isopropyl-1,4a- 13393-93- DEF
dimethyltetradecahydrophenanthren-l-yl)methanol 6 1030 (5S,8R,9S,10S,13R, I 4S)-10,13-di methyl- 18339-16- DEF
I,2,4,5,6,7,8,9,10,11,12,13,14,15-tetradecahydro-3H- 7 cyclopenta[a]phenanthren-3-one 1032 (7-i sopropy1-1,4a-dimethyl- 26266-77- DEF
1,2,3,4,4b,5,6,7,8,8a,9,10-dodecahydro-4a15- 3 phenanthren-l-yl)methanol 1050 3-amino-44(1-methoxy-1-oxo-3-phenylpropan-2- 22839-47- CF
yl)amino)-4-oxobutanoic acid 0 1054 methyl (1R,4aR,4bS,7R,8aS,10aR)-7-isopropyl- I ,4a- 19941-28- DEF
dimethyltetradecahydrophenanthrene-l-carboxylate 7 1056 methyl (1R,4aS,4bS,8aR,10aR)-7-isopropy1-1,4a- 33892-18-DEF
dimethy1-1,2,3,4,4a,4b,5,6,8a,9,10,10a- 1 dodecahydrophenanthrene-l-carboxylate 1057 methyl 7-isopropyl-1,4a-di methyl- 67893-02- DEF
1,2,3,4,4a,4b,5,6,7,8,10, I Oa- 1 dodecahydrophenanthrene-l-carboxyl ate 1061 methyl (1R,4aR,4bR,10aR)-7-isopropyl-1,4a- 127-25-3 DEF
dimethy1-1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthrene-1-carboxylatedecahydrophenanthrene-l-carboxylate (1:1) 1063 (( I R,4aR,4bR,10aR)-7-isopropy1-1,4a-dimethyl- 54200-50-DEF
1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthren-1- 9 yl)methyl acetate 1070 2-(3,4-dihydroxy-5-oxo-2,5-dihydrofuran-2-y1)-2- 137-66-6 DEF
hydroxyethyl palmitate 1071 dodecyl palmitate 42232-29- DEF
1072 (2R,3R,4S,5R,6R)-6-(acetoxymethyl)tetrahydro-2H- 604-68-2 CF
pyran-2,3,4,5-tetrayl tetraacetate 1075 (((2-phenylethane-1,1- 65416-19- DF
diyObis(oxy))bis(methylene))dibenzene 5 1076 methyl (E)-2-(((4-(4-hydroxy-4- 67634-12- DF
methylpentyl)cyclohex-3-en-1- 2 yl)methylene)amino)benzoate 1079 1,1'-(2-phenylethane-1,1-diy1)bi s(1H-indole) 67801-37- DF
1080 octadecyl tetradecanoate 3234-81-9 DEF
1082 2,5,7,8-tetramethy1-2-(4,8,12- 10191-41- DEF
trimethyltridecyl)chroman-6-ol 0 1083 2,5,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 148-03-8 DEF
6-ol 1084 2,7,8-trimethy1-2-(4,8,12-trimethyltridecyl)chroman- 54-28-4 DEF
6-ol 1085 2,8-dimethy1-2-(4,8,12-trimethyltridecyl)chroman-6- 119-13- I
DEF
ol 1086 bis(2-ethylhexyl) decanedioate 122-62-3 DEF
1087 (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta- 458-37-7 CEF
1,6-diene-3,5-dione 1088 2,6,10,15,19,23-hexamethyltetracosane 111-01-3 DEF
1089 (1R,2R,4aS,8aS)-1-((E)-6-((S)-2,2-dimethy1-6- 473-03-0 DEF
methylenecyclohexyl)-4-methylhex-3-en-l-y1)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol 1090 (6E,10E,14E,18E)-2,6,10,15,19,23- 111-02-4 DEF
hexamethyltetracosa-2,6,10,14,18,22-hexaene 1091 1,1'-(3,7-dimethyloct-6-ene-1,1-diy1)bis(1H-indole) 67801-16- DEF
1094 8,8-di(1H-indo1-3-y1)-2,6-dimethyloctan-2-ol 67860-00- DEF
1099 propane-1,2,3-triy1 trioctanoate 538-23-8 DEF
1101 didodecyl phthalate 2432-90-8 DEF
1103 1-((3,7-dimethy1-1-((11-methyldodecyl)oxy)oct-6-en- 67923-82- DEF
1-yl)oxy)-11-methyldodecane 4 1104 (E)-(2-(bis((3,7-dimethylocta-1,6-dien-3- 67785-71-DEF
yl)oxy)methyl)hept-l-en-l-y1)benzene 1 1105 ((E)-2-(bis(((E)-3,7-dimethylocta-2,6-dien-1- 67785-69- DEF
yl)oxy)methyl)hept-l-en-l-y1)benzene 7 1106 3,7-dimethylocta-1,6-dien-3-y1 2-(((E)-2-((E)- 72928-45- DEF
benzylidene)octylidene)amino)benzoate 1 Table 3 List of materials with at least one MORV from 0.5 to less than 1 Number IUPAC Name CAS Comment Number Code 2 1,1-dimethoxyethane 534-15-6 AC
4 hexane-1,6-diol 629-11-8 CE
7 (2E,4E)-hepta-2,4-dien-l-ol 33467-79- __ ACE
11 (Z)-oct-5-en-1-01 64275-73- ACE
18 (E)-non-2-en- 1-0122104-79-BCE
19 (E)-non-6-en-1-ol 40709-05- BCE
21 (E)-non-3-en- 1-0110339-61-BCE
22 (Z)-non-3-en-1-ol 10340-23- BCE
23 (2E,6Z)-nona-2,6-dien-1-01 28069-72- __ BCE
24 heptanedioic acid 111-16-0 CE
26 (E)-1,1-dimethoxyhex-2-ene 18318-83- __ ACEF
41 (E)-dec-2-en-1-ol 22104-80- BDEF
46 methyl 3-hydroxyhexanoate 21188-58- __ BCE
51 5-hydroxyoctan-4-one 496-77-5 __ AC
55 1,1-dimethoxyheptane 10032-05- __ ADEF
56 (E)-2-methyloct-2-enal 49576-57- __ AD
57 methyl octanoate 111-11-5 ADE
61 decan-2-ol 1120-06-5 BDEF
63 2-pentylfuran 3777-69-3 ADE
64 non-1-en-3-ol 21964-44- ADE
68 methyl (E)-oct-3-enoate 35234-16- ACE
70 (Z)-hex-3-en-1-y1 2-hydroxypropanoate 61931-81- CE
80 3-phenylpropan-l-ol 1335-12-2 __ BCE
86 Benzenemethanol, 4-methyl- 589-18-4 __ BC
88 7-methyloctanenitrile 51729-59- __ ADE
89 3,3-dimethy1-1,5-dioxaspiro15.51undecane 707-29-9 ACEF
90 4,4'-thi obi s(butan-2-one) 40790-04- CF
95 (E)-undeca-1,3-dien-5-yne 166432- __ ADEF
98 (2Z,4E)-undeca-2,4-dien-l-ol __ 59376-58- __ DEF
99 (E)-dec-4-enoic acid 57602-94- __ DEF
101 (Z)-undec-2-enal 71277-05- BDF
102 (E)-undec-2-enal 53448-07- BDF
107 4-isopropyl-2,2,5,5-tetramethy1-1,3-dioxane 61920-45-ACEF
108 3-Cyclohexene-l-propanal 22858-74- AC
111 cyclodecanol 1502-05-2 CE
113 cyclododecane 294-62-2 BDEF
115 1-benzy1-2-methyldisulfane 699-10-5 DE
117 (1S,3S,4R,5R)-1-isopropy1-4- 21653-20- BCEF
methylbicyclo[3.1.01hexan-3-ol 3 118 methyl nonanoate 1731-84-6 ADEF
119 (1R,2S)-2-pentylcyclopropane-1-carboxylic acid 58650-45-CE
121 Bicyclo[3.2. I ]octan-8-ol, 1,5,8-trimethyl- 84681-91-BCF
122 1-(p-tolyl)ethan-1-ol 536-50-5 BC
125 undecan-2-ol 1653-30-1 BDEF
129 (E)-3,7-dimethylocta-2,6-dien-1-01 624-15-7 BD
130 1,3,3-tri methy1-2-thiabicyclo[2.2.2] octane 5718-74-1 ADEF
132 methyl (E)-non-3-enoate 13481-87- ADEF
136 2,6-dimethylheptan-4-one 108-83-8 ACEF
139 (E)-cyclododecene 1501-82-2 BDEF
141 diethyl succinate 123-25-1 ACE
144 2-methoxy-2-phenylethan-1-01 2979-22-8 BCE
146 1,7,7-trimethyltricyclo[2.2.1.02,6]heptane 508-32-7 ADEF
147 2-ethyl-4,5-dimethylthiazole 873-64-3 ACEF
154 decahydronaphthalene 493-01-6 ADE
161 2-ethyloctanoic acid 25234-25-DEF
166 ethyl (Z)-octa-4,7-dienoate 69925-33- ADEF
171 7-methyl-3-methyleneoct-6-enal 55050-40- AD
173 3-(hydroxymethyl)nonan-2-one 67801-33- CF
178 (E)-dodec-2-enal 4826-62-4 BDF
179 (2E,4E)-dodeca-2,4-dienal 21662-16- DF
184 (E)-2,6-dimethylocta-1,5,7-trien-3-ol 29414-56- BCF
185 (E)-5-(methylthio)-2-((methylthio)methyl)pent-2- 59902-01-CF
enal I
189 4-(hydroxymethyl)-2-methoxyphenol 498-00-0 C
191 3,7-dimethyloctane-1,6-diol 53067-10- CF
192 1,1-dimethoxynonane 18824-63-ADEF
193 undecan-l-ol 30207-98- BDEF
200 2,3,5,6-tetramethylpyrazine 1124-11-4 AC
202 2,6-dimethoxybenzoic acid 1466-76-8 204 (E)-4-phenylbut-3-en-2-ol 17488-65- CE
205 2-pentylcyclopent-2-en-1-one 25564-22- BD
206 methyl decanoate 110-42-9 BDEF
207 3-methylenenonanoic acid 35205-78- DEF
209 2-i sopropy1-4-methylphenol 4427-56-9 BDF
211 2,6,6-trimethylbicyclo[3.1.1]heptane-2-thiol 23832-18-ADEF
213 (Z)-9,9-dimethoxynon-3-ene 68555-53- BDEF
215 methyl 2,4-dihydroxy-3-methylbenzoate 33662-58-218 3,7-dimethyloct-7-ene-1,6-diol 22460-95- CF
219 (E)-2-(pent-2-en-1-yl)cyclopentan-1-one 51608-18-AC
220 (1R,2S,3R,5S)-2,6,6-trimethylbicyclo[3.1.1Theptan- 25465-65- BCEF
3-ol 0 224 undecane-2,3-dione 7493-59-6 BDF
227 2,7,7-trimethy1-3-oxatricyclo[4.1.1.02,4]octane 1686-14-2 ACEF
232 8-ethy1-1,5-dimethy1bicyc1ol 3.2.1]octan-8-ol 84681-92-BDEF
239 isopentyl 3-methylbutanoate 659-70-1 ADEF
242 hexyl pentanoate 1117-59-5 BDEF
250 (1S,2R,5R)-2,6,6-trimethylbicyclo[3.1.11heptan-3- 547-60-4 ACEF
one 254 (Z)-5-(hex-3-en-l-y1)-5-methyldihydrofuran-2(3H)- 7085 1-61 - CEF
one 5 255 allyl octanoate 4230-97-1 BDEF
256 (Z)-pent-2-en-1-y1 hexanoate 74298-89- BDEF
257 (E)-2-methy1-3-phenylprop-2-en-1-01 1504-55-8 CE
260 (E)-dec-5-en-l-y1 acetate 38421-90- ADEF
263 methyl 2-hydroxy-5-methylbenzoate 22717-57- BC
266 (E)-dodec-2-enoic acid 32466-54-DEF
267 ((1S,2S,5S)-6,6-dimethy1bicyc1o[3.1.11heptan-2- __ 53369-17- __ BDEF
yl)methanol 8 268 (E)-hex-3-en-1-y1 2-methylbutanoate 10094-41- __ BDEF
270 tridecanal 10486-19- BDF
______________________________________________________ 8 271 2-methylundecan-1-ol 10522-26- __ DEF
273 3-ethyl-2,4-dioxaspiro[5.5]undec-8-ene __ 64165-57- __ BCEF
278 1,3-dihydro-2H-inden-2-one 615-13-4 BCE
279 (2E,4E)-trideca-2,4-dienal 60998-24- DF
281 1,3-di methoxy-5-methylbenzene 4179-19-5 BC
282 (6,6-dimethylbicyclo[3.1.11hept-2-en-2-yl)methanol 515-00-4 __ BDEF
284 3-(p-tolyl)propanal 5406-12-2 BC
289 (4S,4aS,8aR)-4,8a-dimethyloctahydronaphthalen- __ 19700-21- __ DEF
4a(2H)-ol 1 291 (E)-2-(hex-2-en-l-yl)cyclopentan-1-01 34686-67- __ CEF
294 1-(furan-2-ylmethyl)-1H-pyrrole 1438-94-4 BCE
297 cyclohexyl(pentyl)sulfane 7133-42-8 BDEF
298 tetradecane 629-59-4 BDEF
299 2-(4-methylcyclohex-3-en-1-yl)prop-2-en-1-01 3269-90-7 __ CF
300 (R)-2-(4-methylcyclohex-3-en-l-yl)prop-2-en-1-01 __ 38142-45- __ CF
301 (E)-2-methy1-3-(pent-2-en-l-y1)cyclopent-2-en-1-one 11050-62- BCF
303 7-methyl-3-methyleneoct-6-enenitrile 26410-85- __ B
DE
305 methyl undecanoate 1731-86-8 __ BDEF
306 4-isopropy1-2-methoxy-1-methylbenzene __ 6379-73-3 __ ADF
308 (Z)-2-hexylidenecyclopentan-1-one 17373-89- BDF
310 (E)-3-methy1-2-(pent-2-en-l-y1)cyclopent-2-en-1-one 6261-18-3 CF
313 cyclooctyl methyl carbonate 61699-38- DEF
315 methyl (E)-undec-9-enoate 5760-50-9 BDEF
318 (E)-2-phenylprop-1-en-l-y1 acetate 37973-51- __ BCEF
320 dodecan-3-one 1534-27-6 BDF
322 1-phenylpentan-1-one 1009-14-9 __ BD
323 2,6-dii sopropylphenol 2078-54-8 __ DEF
324 2-ethoxy-1,3,3-trimethylbicycloI2.2.1] heptane 67800-86- __ ADEF
325 1-methoxy-l-methylcyclododecane 37514-30- BDEF
326 (E)-2-(hex-2-en-l-yl)cyclopentan-1-one 34687-46- BCF
327 1-(3,3-dimethy1bicyc1o[2.2.11heptan-2-yeethan-1-01 66062-78- CEF
330 (S)-4-(prop-1-en-2-yl)cyclohex-1-ene-1- 18031-40- BCF
carbaldehyde 8 332 4-methyl-5-pentyldihydrofuran-2(3H)-one 33673-62-BCEF
333 (4aS,8aS)-4,4,8a-trimethyloctahydronaphthalen- 57963-77- DF
4a(2H)-ol 6 334 L-phenylalanine 150-30-1 335 3a,4,7,7a-tetrahydro-1H-4,7-methanoindene 54335-17-ADE
343 3-methyl-1-phenylbutan-2-ol 705-58-8 ACE
355 tetradecan-l-ol 112-72-1 DEF
358 (6,6-dimethylbicyclol 3.1.1 Theptan-2-yOmethanethiol 6588-78-9 ADEF
359 (E)-6-(pent-2-en-1-yl)tetrahydro-2H-pyran-2-one 34686-71- CE
362 diethyl adipate 141-28-6 BCEF
364 1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 formate 1200-67-5 ADEF
365 (1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 7492-41-3 ADEF
formate 366 octahydro-1H-4,7-methanoinden-5-ol 13380-89- CEF
367 1-(dimethoxymethyl)-4-methoxybenzene 2186-92-7 ACEF
369 2-(4-isopropylcyclohexyl)ethan-1-01 3650-46-2 DEF
370 (E)-undec-2-en-1-y1 acetate 68480-27- DEF
372 2-methyl-1-(p-tolyl)propan-2-ol 20834-59- BCEF
373 1-(3,3-dimethylbicyclo [2.2.1 lheptan-2-yl)ethan-1- 42370-07- BCEF
one 0 375 ally] 2,2,3-tri methyl hexanoate 68132-80- BDEF
378 1,2-dimethoxy-4-vinylbenzene 6380-23-0 BCE
379 2-(4-ethylphenyl)acetaldehyde 68083-54- BC
383 (Z)-hex-3-en-1-y1 hexanoate 31501-11- BDEF
385 (E)-hex-2-en-1-y1 hexanoate 53398-86- BDEF
386 dimethyl phthalate 131-11-3 389 6-ethy1-3-methyloct-5-en-1-ol 26330-64- DEF
390 2-methyl-5,7-dihydrothieno[3,4-d]pyrimidine 36267-71-CE
391 methyl (E)-3,7-dimethylocta-2,6-dienoate 1189-09-9 BDF
392 1-(3,4-dimethoxyphenypethan-1-one 1131-62-0 CE
393 octahydronaphthalen-2(1H)-one 4832-17-1 BCE
394 2-(4-isopropylphenyl)ethan-l-ol 10099-57- BCEF
395 1-methyl-4-(prop-1-en-2-y1)-7- 33204-74- BCEF
oxabicyclo [4.1.0] heptan-2-one 9 396 (Z)-hex-3-en-1-y1 (E)-hex-2-enoate 53398-87- DEF
402 7-methyloctyl propionate 65155-45- BDEF
404 1-(tert-buty1)-4-methoxy-2-methylbenzene 31268-79-BDF
405 4-(tert-butyl)cyclohexane-l-carbaldehyde 20691-52-DF
408 (4,7,7-trimethylbicyclo[4.1.0]hept-4-en-3- 15103-32-BDEF
yl)methanol 9 409 methyl 3,7-dimethyloct-6-enoate 2270-60-2 BDF
410 (Z)-2-(3,3-dimethylbicyclo[2.2.11heptan-2- 2226-05-3 CEF
ylidene)ethan-l-ol 413 (Z)-hex-3-en-1-y1 4-oxopentanoate 85554-70- CF
415 4-isopropylbenzyl formate 67634-21- BCEF
416 1-(tert-buty1)-2-methoxy-4-methylbenzene 88-40-4 ADEF
417 4-isopropyl- 1 -methylcyclohexyl acetate 26252-11-ADEF
418 (3aR,7aR)-octahydro-5H-4,7-methanoinden-5-one 13380-94-BCEF
419 furan-2-ylmethyl 3-methylbutanoate 13678-60- BCEF
420 4-(3-hydroxybutyl)phenol 69617-84- CE
424 3,5-dimethy1-2-propylpyrazine 32350-16- ACEF
425 7-isopropyl-4-methyloxepan-2-one 499-54-7 BCEF
427 4-hydroxy-3,5-dimethoxybenzaldehyde 134-96-3 428 pentadecane 629-62-9 BDEF
430 (E)-4-(3-hydroxyprop-1-en-l-y1)-2-methoxyphenol 458-35-5 432 (6R,7aR)-3,6-dimethy1-5,6,7,7a- 38049-04- CEF
tetrahydrobenzofuran-2(4H)-one 6 435 2-octylthiophene 880-36-4 BDEF
436 methyl dodecanoate 111-82-0 BDEF
437 11-methyldodecanoic acid 25448-24- DEF
441 (Z)-2-heptylidenecyclopentan-1-one 39189-74- DF
442 3-(4-methoxyphenyl)butan-2-one 7074-12-6 BCEF
443 2-ethyl-5-methoxybicyclo[2.2.1]heptane 122795- ADEF
444 tridecan-3-one 1534-26-5 BDF
445 (Z)-2-hexylidenecyclohexan-1-one ______________________________________________________ 5 448 ethyl 3-cyclohexylpropanoate 10094-36- A DEF
449 4-ethylphenyl acetate 3245-23-6 BCE
455 2-ethoxy-4-isopropyl-1-methylbenzene 4732-13-2 BDEF
457 (S)-2-(2,2,3-trimethylcyclopent-3-en-1-yl)ethyl 36789-59-BDF
acetate 0 460 2-((1,7,7-trimethylbicyclo[2.2.1[heptan-2- 7070-15-7 CEF
yl)oxy)ethan-l-ol 462 1-(5-isopropy1-2-methylphenyl)ethan-1-one 1202-08-0 BDEF
463 pentadecan-l-ol 629-76-5 DEF
469 1,2-bis(allyloxy)benzene 4218-87-5 BDEF
470 1-(4-hydroxy-3,5-dimethoxyphenyl)ethan-1-one 2478-38-8 CEF
473 allyl 2-cyclohexylacetate 4728-82-474 tetradecanoic acid 544-63-8 DEF
476 3,5-dimethylbicyclo[2.2.1]heptane-2-carbonitrile 104516-BCEF
477 (E)-dodec-2-en-1-y1 acetate 38363-23- DEF
478 dec-9-en-l-y1 propionate 68480-06-DEF
480 1-(4,7,7-trimethylbicyclo[4.1.0]hept-4-en-3-ypethan- 3608-11-5 BDF
1-one 481 octyl 2-methylbutanoate 29811-50-BDEF
482 (E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2- 25312-34- DF
ol 9 483 2-(tert-butyl)-1,4-dimethoxybenzene 21112-37- DF
484 1-allyI-2,2,7,7-tetramethylcycloheptan-1-01 105463- DF
485 2-butyl-4,6-dimethy1-3,6-dihydro-21-1-pyran 24237-01- ADEF
486 (S)-2,5,5-trimethy1-1,2,3,4,5,6,7,8- 670-24-6 DEF
octahydronaphthalen-2-ol 487 1-(naphthalen-l-yl)ethan-1-one 1333-52-4 DE
490 8,8-dimethoxy-2,6-dimethyloctan-2-ol 141-92-4 CEF
491 3-(but-3-en-l-y1)-2,4,4-trimethylcyclohex-2-en-1-one 67401-27- DF
493 2,3-diethyl-5-methylpyrazine 18138-04- ACE
494 3,5-diethyl-2-methylpyrazine 18138-05- ACE
498 (E)-3,7,9-trimethyldeca-1,6-dien-3-ol 56105-46-DEF
499 (Z)-2-ethylideneundecanal 6720-16-502 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-ol 13720-13-DF
503 (5 s,8s)-8-isopropy1-1-oxaspiro[4.5]decan-2-one 4583-26-0 DEF
504 (5r,8r)-8-isopropyl-1-oxaspiro[4.51decan-2-one 4625-90-5 DEF
505 2,5,5-trimethy1-2,3,4,4a,5,6,7,8-octahydronaphthalen- 643-53-8 DEF
2-ol 507 2'-methylspiro[bicyclo[2.2.1Theptane-2,5'- 87641-24-ACEF
[1,3]dioxane] 5 511 (2R,5S,6S)-2,6,10,10-tetramethy1-1- 57967-68-DF
oxaspiro[4.5]decan-6-ol 7 512 cyclododecyl formate 59052-82-DEF
514 2-butyl-6-methyl-4-methylenetetrahydro-2H-pyran 24237-02- A
DEF
515 heptane-1,1-diy1 diacetate 56438-09- CEF
519 1-(dimethoxymethyl)-4-isopropylbenzene 67785-72-BDEF
520 hexadecane 544-76-3 DEF
524 [1,1'-bi(cyclohexan)[ -1'-en-2-one 527 isobutyl 3-(furan-2-yl)propanoate 529 2-isopropyl-2,3-dihydro-1H-inden-1-one 53446-63-DEF
530 (E)-4-(2,3,6-trimethylphenyl)but-3-en-2-one 57461-21-DEF
532 2-(4-isopropylphenyl)propanal 535 (E)-6,10-dimethylundeca-5,9-dien-2-one 3796-70-1 BDF
537 1-(4-methoxy-2,2,6,6-tetramethylcyclohex-3-en-1- 16556-48-DEF
yl)ethan-1-one 2 539 (methoxymethoxy)cyclododecane 540 (E)-6,10-dimethylundeca-3,9-dien-2-one 13835-41-DF
541 1-(4-butylphenyl)ethan-1-one 542 tetradecan-3-one 629-23-2 DF
543 (E)-3,7-dimethylnona-1,6-dien-3-y1 acetate 61931-80-BDEF
544 3-propy1bicyclo[2.2.11hept-5-ene-2-carbaldehyde 39067-39-BDF
546 (E)-2,6-dimethoxy-4-(prop-1-en-l-ypphenol 20675-95-CF
547 1,2-bis(furan-2-ylmethyl)disulfane 549 (2S)-1,7,7-tri methylbicyclo[2.2.1]heptan-2-y1 acetate 5655-61-8 BDEF
551 decahydronaphthalen-2-y1 formate 552 pentadecan-2-one 2345-28-0 DF
556 (3,3-di methoxy-2,2-dimethylpropyl)benzene 72727-59- DF
562 3-hepty1-5-methyldihydrofuran-2(3H)-one 40923-64-DEF
565 (E)-2,6-dimethylocta-1,5,7-trien-3-y1 acetate 61931-78- BDF
569 (E)-1-(2,6,6-trimethylcyclohex-1-en-l-y1)pent-l-en- 93840-90- DEF
3-ol 5 571 ally' cinnamate 1866-31-5 CE
572 (1r,4r)-4-(tert-butyl)cyclohexyl acetate 1900-69-2 ADEF
573 p-tolyl butyrate 14617-92- BCEF
574 benzyl pentanoate 10361-39- BDEF
577 butyl 2-phenylacetate 122-43-0 BDEF
579 4-ally1-2-methoxyphenyl formate 10031-96-581 1-phenylethyl butyrate 3460-44-4 BDEF
582 (E)-tridec-2-en-l-y1 acetate 68480-26- DEF
585 4-ally1-2,6-dimethoxyphenol 6627-88-9 CF
586 benzyl 2-methylbutanoate 56423-40- BDEF
590 5-isopropyl-2-methylphenyl acetate 6380-28-5 BDF
595 2,3-dimethylquinoxaline 2379-55-7 BCE
596 (2E,6E)-3,7,9-trimethyldeca-2,6-dienal 58605-97-DF
599 (5,6-di methy1-1-(prop-1-en-2-yObicyclo12.2.1 lhept- 110458-DEF
5-en-2-yl)methanol 85-0 604 oct-1-en-3-y1 butyrate 16491-54-BDEF
606 2-(4-(tert-buty1)-2-methylphenoxy)acetaldehyde 67845-53-DF
607 3-phenylpropyl isobutyrate 103-58-2 DF
609 (E)-4-(4-hydroxy-3-methoxyphenyl)but-3-en-2-one 1080-12-2 CEF
611 ethyl 2-hydroxy-4-methoxy-6-methylbenzoate 6110-36-7 DF
612 1-(2,4-diethylphenyl)ethan-1-one 52191-01- DF
614 (E)-4-(3-hydroxyprop-1-en-l-y1)-2,6- 537-33-7 CF
dimethoxyphenol 615 3-butylisobenzofuran-1(3H)-one 6066-49-5 CEF
617 4-methyl-l-phenylpentan-2-one 5349-62-2 BCEF
622 14-methylpentadecan-1-ol 36311-34- DEF
623 2-(4-methylcyclohex-3-en-l-yl)al lyl acetate 15111-97- DF
628 (E)-3-(4-hydroxy-3,5- 4206-58-0 CF
di methoxyphenyl)acrylaldehyde 631 2-(4-(formyloxy)-4-isopropylcyclohex-1-en-1- 72928-49- CF
yl)ethyl formate 5 633 diphenylamine 122-39-4 DE
636 2-methoxy-3-(4-methylpentyl)pyrazi ne 68844-95- BCEF
638 2-methyl-5-(prop-1-en-2-y1)cyclohexyl acetate 20405-60-BDEF
643 6,6-dimethy1-2-methylenebicyclo13.1.11heptan-3-yl 1078-95-1 BDEF
acetate 649 benzyl 2,3-dimethylbut-2-enoate 7492-69-5 DF
651 3-methyl-4-(2,2,6-trimethylcyclohexyl)butan-2-ol 60241-53-DEF
652 isopropyl undec-10-enoate 5459-98-3 DEF
654 dodecyl propionate 6221-93-8 DEF
655 4,5,6,7,8,9,10,11,12,13- 38303-23- DEF
decahydrocyclododecard]oxazole 0 656 (E)-hex-2-en-1-y1 2-hydroxybenzoate 68133-77- DEF
657 hexadecan-2-one 18787-63- DF
660 ((octyloxy)methyl)benzene 54852-64- DEF
661 furan-2-ylmethyl benzoate 34171-46- DF
664 1-benzylpiperazine 2759-28-6 CEF
666 4-(4-methoxypheny1)-3-methylbutan-2-one 67828-19- CEF
669 2-methyl-l-phenylpropan-2-y1 propionate 67785-77- DEF
671 4,4,6-trimethy1-2-phenyl-1,3-dioxane 2568-06-1 DEF
674 undecyl butyrate 5461-02-9 DEF
676 propyl dodecanoate 3681-78-5 DEF
680 8-hydroxyquinoline-5-sulfonic acid 84-88-8 ACF
681 (E)-2-methy1-4-(2,6,6-trimethylcyclohex-2-en-1- 58102-02-DF
yl)but-3-enal 6 683 (E)-2,6,10-trimethylundeca-5,9-dien-1-01 24048-14- DEF
688 palmitic acid 57-10-3 DEF
692 benzyl hexanoate 6938-45-0 DEF
693 5-hexyltetrahydrofuran-3-y1 acetate 10039-39- DEF
702 1-(2,6,6-trimethylcyclohex-2-en-l-yl)pentan-3-one 68480-17- DF
703 2-(tert-butyl)-4-methylcyclohexyl acetate 115724-BDEF
707 (5,7,7-trimethylbicyclo[4.1.01hept-4-en-3-yl)methyl 15103-33-BDEF
acetate 0 709 3a,6,6,9a-tetramethyldodecahydronaphthol 2,1- 21582-36-DEF
b]furan 5 715 2,6-di-tert-butyl-4-(hydroxymethyl)phenol 882-33-7 DEF
723 1-phenylethane-1,2-diy1 diacetate 728 octadecane 593-45-3 DEF
734 (E)-1-(4-methoxyphenyl)pent-l-en-3-one 104-27-8 CF
735 3-(4-isopropylpheny1)-2-methylpropan-1-01 4756-19-8 DEF
737 decyl 3-methylbutanoate 72928-48-DEF
740 6-(tert-butyl)quinoline 68141-13-DEF
744 methyl 2-(4-(tert-butyl)phenyl)acetate 3549-23-3 DF
745 palmitonitrile 629-79-8 DEF
749 3,7-dimethyloctyl butyrate 67874-80- BDEF
752 methyl 1,6-di methy1-5-(prop-1-en-2- 68698-57-DF
yebicyclo[2.2.11hept-5-ene-2-carboxyl ate 7 754 6-nonyltetrahydro-2H-pyran-2-one 758 3-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1- 51414-25-CF
carbaldehyde 6 760 4,9,12,12-tetramethy1-5- 1209-61-6 BDEF
oxatricyclo[8.2Ø04,6]dodecane 761 ethyl 2-benzylbutanoate 2983-36-0 DEF
764 4-(tert-butyl)cyclohexyl propionate 68797-70- BDEF
766 dodecyl butyrate 3724-61-6 DEF
768 1-phenylpropyl butyrate 10031-86-DEF
771 2-phenethylpyridine 2116-62-3 BDEF
772 4,6-di methy1-2-pheny1-3,6-dihydro-2H-pyran 68039-41-BDEF
773 (1R,9S,Z)-4,11,11-trimethy1-8- 118-65-0 BDEF
methylenebicyclo17.2.01undec-4-ene 774 (Z)-3-phenylall yl pentanoate 10482-65- DEF
776 butyl dodecanoate 106-18-3 DEF
777 (E)-2,3-dimethy1-4-(2,6,6-trimethylcyclohex-2-en-1- 68140-49- DF
yl)but-3-enal 8 778 3-phenylpropyl pentanoate 5451-88-7 DEF
780 cinnamyl 2-methylbutanoate 67883-77- DEF
783 phenethyl hexanoate 6290-37-5 DEF
784 3,7-dimethylocta-1,6-dien-3-y1 pentanoate 10471-96-DEF
789 4-(3-oxobutyl)phenyl acetate 3572-06-3 CF
794 (E)-1-(((E)-non-2-en-l-yl)oxy)non-2-ene 68555-30-DEF
795 methyl 3-(bicyclo12.2.1]hept-5-en-2-y1)-3- 72175-33-BCEF
methyloxirane-2-carboxylate 8 796 (E)-hex-2-en-1-y1 2-phenylacetate 68133-78- DEF
797 (Z)-hex-3-en-1-y1 2-phenylacetate 42436-07- DEF
798 (E)-2-methyl-1-(2,6,6-trimethylcyclohex-2-en-1- 72117-72-DF
yl)pent-l-en-3-one 7 799 3-(4-(tert-butyl)pheny1)-2-methylpropan-1-ol 56107-04-DEF
800 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 4951-48-propionate 802 2-isopropyl-5-methylcyclohexyl 2- 17162-29- DF
hydroxypropanoate 7 803 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl (S)-2- 61597-98-DF
hydroxypropanoate 6 804 4,7,7-trimethy1-4-(3-methylbut-2-en-1- 74499-59-DF
yl)bicyclo [4.1.01heptan-3-one 5 806 (Z)-2-methyl-1-(2,2,6-trimethylcyclohex-3-en-1- 68555-94-DF
yl)pent-l-en-3-one 2 808 nonadecane 629-92-5 DEF
810 4-(tert-butyl)cyclohexyl isobutyrate 5451-57-815 2,6,10,10-tetramethyl-1-oxaspirol-4.51decan-6-y1 72541-09-DF
acetate 4 817 (2E,6E)-1-methoxy-3,7,11-trimethyldodeca-2,6,10- 15130-76-DEF
triene 4 818 cinnamyl 3-methylbutanoate 140-27-2 DEF
821 isobutyl dodecanoate 37811-72-DEF
823 (E)-4-methy1-6-(2,2,3-trimethylcyclopent-3-en-1- 67801-19-DEF
yl)hex-4-en-3-ol 8 824 (E)-4-(2,6,6-trimethylcyclohex-1-en-l-y1)but-3-en-2- 22030-19- DF
Y1 acetate 9 825 4-(2,2,6-trimethylcyclohexyl)butan-2-y1 acetate 68555-59-DEF
826 3-phenylpropyl 3-methyl butanoate 5452-07-3 DEF
829 phenyl 2-h ydroxybenzoate 118-55-8 DF
833 8,8-dimethy1-1,2,3,4,5,6,7,8-octahydronaphthalene-2- 72928-51- DEF
carbonitrile 9 835 1-(4,4-dimethy1-1,2,3,4-tetrahydronaphthalen-1- 74499-60-DF
yl)propan-l-one 8 836 8,12-dimethyltridec-11-en-6-one 68141-18- DF
837 (E)-4-(2,6,6-trimethylcyclohex-2-en-l-yl)but-3-en-2- 52210-18- DF
yl acetate 1 844 (2-(benzyloxy)ethyl)benzene 54894-37- DEF
850 heptadecan-9-one 540-08-9 DF
851 1-ethoxy-4-(1-ethoxyviny1)-3,3,5,5- 36306-86-DEF
tetramethylcyclohex-l-ene 2 852 4-(2,2-dimethy1-6-methylenecyclohexyl)butan-2-y1 68479-99- DF
acetate 2 853 4-(3-phenylpropyl)pyridine 2057-49-0 DEF
854 3-(3-phenylpropyl)pyridine 1802-34-2 DEF
860 stearic acid 57-11-4 DEF
861 2-ethylbutyl 2-(cyclopent-1-en-1-y1)acetate 68092-41-DEF
864 (E)-2-methy1-1-(1-methylbicyc1o[2.2.11hept-5-en-2- 67739-11- DEF
yl)pent-l-en-3-ol 1 865 pentyl dodecanoate 5350-03-8 DEF
866 cinnamyl hexanoate 6994-20-3 DEF
867 (E)-1-(3,5,6-trimethylcyclohex-3-en-l-yl)pent- 1-en- 67801-32-DF
3-one 5 870 3-phenylpropyl hexanoate 6281-40-9 DEF
872 ben zyl octanoate 10276-85-DEF
874 2,3-dihydroxypropyl dodecanoate 142-18-7 DEF
875 (E)-hex-3-en-1-y1 cinnamate 68133-75- DEF
877 2,3-dihydroxypropyl 5-hydroxydecanoate 26446-31-CEF
881 (E)-2-methoxy-1-(pentyloxy)-4-(prop-1-en-1- 10484-36-DEF
yl)benzene 3 884 oxacyclohexadecane-2,13-dione 38223-29- DEF
886 [1,1'-bi(cyclopentan)1-2-y1 (E)-but-2-enoate 68039-73-DEF
891 7-isopropy1-5-methy1bicyc1o[2.2.21oct-5-ene-2- 6831 I -05-DEF
carbonitrile 7 894 (E)-chalcone 614-47-1 DEF
896 (E)-3-((2,6,6-trimethylcyclohex-2-en-1- 26903-19-DF
ylidene)methyl)hex-5-en-2-one 5 898 o-tolyl 2-hydroxybenzoate 617-01-6 DE
900 hexyl 4-hydroxy-3-methoxybenzoate 84375-71- DEF
901 methyl (E)-3-methy1-3-(2-(2,6,6-trimethylcyclohex- 67905-40-DF
2-en-l-yl)vinyl)oxirane-2-carboxylate 2 904 (E)-3-methy1-4-(2,6,6-trimethylcyclohex-2-en-1- 68555-61-DF
yl)but-3-en-2-y1 acetate 3 905 (E)-5-methy1-1-(2,6,6-trimethylcyclohex-2-en-1- 70092-23-DF
yl)hex-1-en-3-one 8 907 p-tolyl benzoate 614-34-6 DF
908 butyl tetradecanoate 110-36-1 DEF
910 hexyl dodecanoate 34316-64-DEF
911 heptyl cinnamate 10032-08- DEF
913 (4E,8E)-2,6,10-trimethy1-13- 14840-89- DEF
oxabicyclo[10.1.0]trideca-4,8-diene 2 915 phenethyl octanoate 5457-70-5 DEF
916 octyl 2-phenylacetate 122-45-2 DEF
917 cyclohexyl 2-phenylacetate 42288-75- DF
918 p-tol yl octanoate 59558-23- DEF
921 (S,Z)-3,7,11-trimethyldodeca-1,6,10-trien-3-y1 56001-43-DF
acetate 5 923 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 3- 1142-85-4 DEF
methylbutanoate 924 1,1,3-trimethy1-3-pheny1-2,3-dihydro-IH-indene 3910-35-8 DF
928 (E)-3-methyl-4-(2,6,6-trimethylcyclohex-1-en-1- 76649-19-DF
yl)but-3-en-2-y1 acetate 9 929 heptyl undec-10-enoate 68141-27- DEF
930 2-isopropyl-5-methylcyclohexyl (E)-2-methylbut-2- 67801-23-DEF
enoate 4 934 5-(diethoxymethyl)-3a,4,5,6,7,7a-hexahydro-IH-4,7- 67633-92- DEF
methanoindene 5 940 ethyl heptadecanoate 14010-23- DEF
943 cinnamyl benzoate 5320-75-2 DF
946 1,3-diphenylpropan-2-one 102-04-5 DEF
952 methyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 301-00-8 DEF
956 isopentyl (E)-3-(4-methoxyphenyl)acrylate 71617-10-DF
957 diisopropyl decanedioate 7491-02-3 DEF
963 phenethyl 2-aminobenzoate 133-18-6 DF
966 ethyl stearate 111-61-5 DEF
967 bis(2,4-dihydroxyphenyl)methanone 131-55-5 CEF
968 6,10,14-trimethylpentadecan-2-one 13955-74- DEF
971 (5E,9E)-6,10,14-trimethylpentadeca-5,9,13-trien-2- 1117-52-8 DF
one 974 butyl palmitate 111-06-8 DEF
976 hexyl tetradecanoate 42231-99- DU
977 ethyl oleate 111-62-6 DEF
978 decyl decanoate 1654-86-0 DEF
979 m-tolyl 2-phenyl acetate 122-27-0 DF
981 tricosane 638-67-5 DEF
982 ethyl (9Z,12Z)-octadeca-9,12-dienoate 544-35-4 DEF
983 ethyl (9Z,12Z,15Z)-octadeca-9,12,15-trienoate 1191-41-9 DEF
987 2-isopropoxy-1,2-diphenylethan-1-one 6652-28-4 DEF
988 2-ethyl-4,5-dimethylthiazole 87-29-6 DF
994 2-(2-(3,3,5-trimethylcyclohexyeacetypcyclopentan- 84642-57- DEF
1-one 9 --995 phenethyl cinnamate 103-53-7 DF
997 3,3,5-trimethylcyclohexyl 2-hydrox ybenzoate 118-56-9 DF
1000 cinnamyl 2-phenylacetate 7492-65-1 DF
1003 3,7-dimethylocta-1,6-dien-3-y1 2-phenylacetate 7143-69-3 DF
1004 ((ethane-1,1-diyIbis(oxy))bis(ethane-2,1- 122-71-4 DEF
di yl))dibenzene 1006 (E)-3,7-dimethylocta-2,6-dien-l-y1 2-aminobenzoate 67874-69- DF
1014 3,7,11,15-tetramethylhexadec-1-yn-3-ol 29171-23- DEF
1016 3-phenylpropyl cinnamate 122-68-9 DF
1017 7,11,15-trimethy1-3-methylenehexadec-1-ene 504-96-1 DEF
1018 decyl dodecanoate 36528-28- DEF
1021 (S)-3,7-dimethyloct-7-en-l-y1 2-phenylacetate 10486-14-DF
1022 1-phenethoxy-2-(p-tol yloxy)ethan-l-ol 72987-59- DF
1026 butyl oleate 142-77-8 DEF
1029 2-(4-methylcyclohex-3-en-1-yl)propan-2-y1 2- 14481-52- DF
aminobenzoate 8 1031 methyl 2-(((1E,2E)-3,7-dimethylocta-2,6-dien-1- 67801-47-DF
ylidene)amino)benzoate 2 1036 methyl (E)-2-((3,7-dimethyloct-6-en-1- 67845-42- DF
ylidene)amino)benzoate 5 1046 (1R,2S,5R)-2-isopropy1-5-methylcyclohexyl 2- 26171-78-DEF
phenylacetate 8 1049 2-ethylhexyl (E)-3-(4-methoxyphenyl)acrylate 5466-77-3 DEF
1053 di octyl adipate 123-79-5 DEF
1055 octadecyl heptanoate 66009-41-DEF
1058 (7R,11R,E)-3,7,11,15-tetramethylhexadec-2-en-l-y1 10236-16- DEF
acetate 5 1064 octadecyl octanoate 18312-31- DEF
1065 tetradecyl dodecanoate 22412-97-DEF
1066 2-ethylhexyl palmitate 29806-73-DEF
1067 methyl (E)-2-((3-(4-methoxypheny1)-2- 111753- DF
methylpropylidene)amino)benzoate 62-9 1072 (2R,3R,4S,5R,6R)-6-(acetoxymethyl)tetrahydro-2H- 604-68-2 CF
pyran-2,3,4,5-tetrayl tetraacetate 1075 (((2-phenylethane-1,1- 65416-19-DF
diy1)bis(oxy))bis(methylene))dibenzene 5 1079 1,1'-(2-phenylethane-1,1-diy1)bis(1H-indole) 67801-37-DF
1081 didecyl phthalate 84-77-5 DEF
1091 1,1'-(3,7-dimethyloct-6-ene-1,1-diyObis(IH-indole) 67801-16-DEF
1093 (2E,4E,6E,8E,10E,12E,14E,16E)-2,6,11,15- 1107-26-2 DF
tetramethy1-17-(2,6,6-trimethylcyclohex-1-en-1-y1)heptadeca-2,4,6,8,10,12,14,16-octaenal 1102 (E)-1,3,3a,4,5,6,7,8,9,10,1 1,13a- 40785-62-DEF
dodecahydrocyclododeca[c]furan 4 1103 1-((3,7-dimethy1-1-((11-methyldodecyl)oxy)oct-6-en- 67923-82- DEF
1-yl)oxy)-11-methyldodecane 4 1109 3,5-dimethyladamantane-1-carboxylic acid 14670-94-DF
1110 di methyl cyclohexane-1,4-dicarboxylate 94-60-0 BCF
1113 (E)-1,1,4,4-tetramethoxybut-2-ene 6068-62-8 ACEF
Table 4 List of materials with ALL MORVs from 1 to 5 Number IUPAC Name CAS Comment Number Code 406 2-(6,6-dimethylbicyclo[3.1.1lhept-2-en-2-ypethan- 128-50-7 DEF
1-ol 411 2,3a'-dimethylhexahydro-2H-spiro[furan-3,2'- 38325-25-CEF
[1,3]dithiolo[4,5-b]furan] 6 568 4,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,1'- 107715-DEF
cyclopentan1-3-one 18-4 588 (2,8,8-tri methyl-1,2,3,4,5,6,7,8- 72928-44-DEF
octahydronaphthalen-2-yl)methanol 0 608 (1S,3aR,4S,8aS)-4,8,8-trimethy1-9- 475-20-7 BDEF
methylenedecahydro-1,4-methanoazulene 627 (3aS,4S,8S,8aR)-2,2,4-trimethyldecahydro-4,8- 4586-22-5 DEF
methanoazulen-9-ol 635 (2S)-1,1,5,5-tetramethy1-1,3,4,5,6,7-hexahydro-2H- 1135-66-6 BDEF
2,4a-methanonaphthalene 644 2,8,8-trimethyloctahydro-2H-4a,2- 21280-29- DF
(epoxymethano)naphthalen-10-one 5 646 4-methy1-8-methyleneadamantan-2-ol 122760- CEF
662 (2R,3'R,3a'S,7'R,8a'S)-3',8',8'- 22037-88- BDEF
trimethyloctahydrospiro[oxirane-2,6'- 3 [3a,7]methanoazulene]
685 (R)-1-methy1-4-(1,2,2-trimethylcyclopentyl)benzene 16982-00- BDEF
705 (3R,3aS,7S,8aS)-3,6,8,8-tetramethy1-2,3,4,7,8,8a- 469-61-4 BDEF
hexahydro-1H-3a,7-methanoazulene 720 1',2',3,3',3a',4,4',6',7',7a'-decahydrospiro[pyran-2,5'- 26244-01- DEF
[4,7] methanoindene] 9 724 5,5,6,7,7-pentamethylhexahydroindeno[3a,4- 33704-62- CEF
b]oxiren-4(1aH)-one 0 732 4-(3,4-dimethoxyphenyl)butan-2-one 6302-60-9 CEF
738 (E)-6-(2,2,3-trimethylcyclopent-3-en-l-yl)hex-5-en- 68480-05- DEF
3-ol 7 741 (1aS,4aS,7R,8aS)-4,4,8,8-tetramethyloctahydro- 26619-69-BDEF
4a,7-methanonaphtho[1,8a-b ioxirene 2 748 1-(1,1,3-trimethy1-2,3,4,5,6,7-hexahydro-1H-inden- 87641-23- DF
5-yl)ethan-1-one 4 770 (2R,4aR,8aS)-1,1,5,5-tetramethylhexahydro-2H- 29461-13-DEF
2,4a-methanonaphthalen-8(5H)-one 0 790 1,7,7-trimethylbicyclo[2.2.1]heptan-2-y1 isobutyrate 50277-27- BDEF
793 2-methyl-34(1,7,7-trimethylbicyclo[2.2.1]heptan-2- 128119-DEF
yl)oxy)propan-l-ol 70-0 801 2-methyl-4-methylene-6-phenyltetrahydro-2H-pyran 30310-41- BDEF
805 4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-y1 58096-46-DEF
formate 1 813 4,7,7-trimethy1-2-(3-methylbut-2-en-1- 74499-58- DF
yl)bicyclo [4.1.01heptan-3-one 4 841 5,5,8a-trimethyldecahydronaphthalen-2-y1 acetate 24238-95-DEF
848 1,1,7-trimethyldecahydro-3a,7- 58096-47- DEF
methanocyclopenta[8]annulen-3-y1 formate 2 849 1,7,7-trimethylbicyclo[2.2.11heptan-2-y1 butyrate 13109-70-BDEF
856 (2R,4a'R,8a'R)-3,6'-dimethy1-3',4',4a',5',8',8a'- 41723-98-DEF
hexahydro-l'H-spirol oxirane-2,2'- 2 [1,4]methanonaphthalene]
857 ((2S,4aR)-1,1,5,5-tetramethy1-1,3,4,5,6,7- 61826-53- DEF
hexahydro-2H-2,4a-methanonaphthalen-8- 7 yl)methanol 858 (octahydro-1H-4,7-methanoindene-2,5- 281 32-01 - CEF
diy1)dimethanol 6 859 (1R,5S,9S,E)-4,11,11-trimethy1-8- 32214-88- DEF
methylenebicyclo[7.2.01undec-3-en-5-ol 3 871 2-((3S,3aS,5R,8S,8aS)-3,8- 3526-75-8 DEF
dimethyldecahydroazulen-5-yl)propan-2-ol 876 1-(2,5,5-trimethy1-1,3,4,5,6,7-hexahydro-2H-2,4a- 32388-56- DEF
ethanonaphthalen-8-yl)ethan-1-one 0 880 1,2-dimethy1-4-(1-phenylethyl)benzene 6196-95-8 DEF
887 (3R,3aR,7S,8aS)-3,6,8,8-tetramethy1-1,2,3,7,8,8a- 30960-39-DF
hexahydro-4H-3a,7-methanoazulen-4-one 5 888 1-(2,3,8,8-tetramethy1-1,2,3,5,6,7,8,8a- 68155-66- DF
octahydronaphthalen-2-yl)ethan-1-one 8 895 (E)-4-(1,3a,4,6,7,7a-hexahydro-5H-4,7- 126646- DEF
methanoinden-5-ylidene)butan-2-ol 14-8 903 (3aR,5aS,9aS,9bR)-3a,6,6,9a- 564-20-5 DEF
tetramethyldecahydronaphtho[2,1-1A furan-2(1H)-one 912 10,11-dihydro-5H-dibenzo[a,d1[7]annulen-5-one 1210-35-1 DEF
920 5,5,7,8,8-pentamethy1-5,6,7,8-tetrahydronaphthalene-2-carbaldehyde 73-1 922 4-methyl-8-methyleneadamantan-2-y1 acetate 122760- DEF
925 henicosane 629-94-7 DEF
926 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-y1 68039-39- DEF
isobutyrate 4 931 1-(3,6,8,8-tetramethy1-2,3,4,7,8,8a-hexahydro-IH- 68039-35- DF
3a,7-methanoazulen-5-yl)ethan-1-one 0 932 2-(1,1,2,3,3-pentamethy1-2,3-dihydro-1H-inden-5- 1217-08-9 DEF
yl)propan-l-ol 937 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646- DEF
methanoinden-5-y1)-3-methylbut-3-en-2-ol 07-9 938 (E)-4-(3a,4,5,6,7,7a-hexahydro-1H-4,7- 126646- DEF
methanoinden-6-y1)-3-methylbut-3-en-2-ol 06-8 944 4-(5,5,6-trimethylbicyclo[2.2.1]heptan-2- 66068-84- DEF
yl)cyclohexan-l-ol 6 948 methyl (E)-2-(octylideneamino)benzoate 67801-44- DEF
954 34(2R)-5,5,6-trimethylbicyclo[2.2.1]heptan-2- 3407-42-9 DEF
yl)cyclohexan-l-ol 958 3-ethyl-5,5,8,8-tetramethy1-5,6,7,8- 58243-85- DF
tetrahydronaphthalene-2-carbaldehyde 9 960 (1S)-3-((Z)-benzylidene)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 3 961 (Z)-3-benzylidene-1,7,7- 15087-24- DEF
trimethylbicyclo[2.2.1Theptan-2-one 8 964 3-(5,5-dimethy1-6-methylenebicyclo[2.2.1 Iheptan-2- 68141-24- DEF
yl)cyclohexan-l-ol 2 969 2-methoxyphenyl 2-phenylacetate 4112-89-4 DF
972 1-(3-ethy1-5,5,8,8-tetramethy1-5,6,7,8- 88-29-9 DF
tetrahydronaphthalen-2-yl)ethan-l-one 973 2-(4-ally1-2-methoxyphenoxy)tetrahydro-2H-pyran 72066-75- CF
984 1,3,3-trimethylbicyclo[2.2.1] heptan-2-y1 benzoate 55066-54-DEF
992 methyl (E)-2((2-phenylethylidene)amino)benzoate 67785-76- DF
996 methyl (E)-2-(decylideneamino)benzoate 67874-67- DEF
1010 4-ally1-1-(benzyloxy)-2-methoxybenzene 57371-42- DF
1011 (1R)-1,7,7-trimethy1-3-((Z)-4- 36861-47- DEF
methylbenzylidene)bicyclo[2.2.1]heptan-2-one 9 1012 1-(4-hydroxy-3-methoxyphenyl)decan-3-one 27113-22-DF
1025 p-tolyl dodecanoate 10024-57-DEF
1028 p-tolyl 3-oxo-3-phenylpropanoate 67801-43- DEF
1033 methyl (E)-2-((4- 14735-72- DF
methoxybenzylidene)amino)benzoate 9 1034 4-(6-methylhepta-1,5-dien-2-y1)-1-(4-methylpent-3- 532-87-6 DEF
en-l-yl)cyclohex-1-ene 1037 4-ally1-2-methoxyphenyl benzoate 531-26-0 DF
1038 N-(4-hydroxy-3-methoxybenzyl)nonanamide 2444-46-4 DEF
1042 2-pheny1-1H-benzoldl imidazole-5-sulfonic acid 27503-81-ACF
1044 methyl (E)-2-((4-hydroxy-3- 72927-84- DF
methoxybenzylidene)amino)benzoate 5 1048 2-methyl-5-(prop-1-en-2-y1)cyclohex-2-en-1-y12- 72152-81-DF
phenylacetate 9 1052 (E)-2-methoxy-4-(prop-I-en-l-y1)phenyl 2- 120-24-1 DF
phenylacetate 1060 4-all y1-2-methoxyphenyl 2-phenylacetate 10402-33-DF
Table 5 List of materials with ALL MORVs from 0.5 to less than 1 Number IUPAC Name CAS Comment Number Code 310 (E)-3-methy1-2-(pent-2-en-1-y1)cyclopent-2-en-1- 6261-18-3 CF
one 480 1-(4,7,7-trimethy1bicyclo[4.1.0]hept-4-en-3- 3608-11-5 BDF
yl)ethan-l-one 798 (E)-2-methyl-1-(2,6,6-trimethylcyclohex-2-en-1- 72117-72-DF
yl)pent-l-en-3-one 7 The benefit agents and perfumes raw materials in this specification can be obtained from suppliers including: International Flavors and Fragrances of New York, NY USA; Givaudan of Vernier Switzerland; Firmenich of Geneva, Switzerland; Symrise of Holzminden, Germany;
Kao of Tokyo, Japan; Takasago of Tokyo, Japan; Merck's Sigma Aldrich division of Darmstadt, Germany and Florasynth of Tel-Aviv, Israel.
Compositions and Methods A composition comprising a malodor reduction material having an MORV of at least 0.5, from about 0.5 to about 10, from 0.5 to about 10, from about 1 to about 10, or from about 1 to about 5 is disclosed.
(Ingredients in Tables 1-3 having comment codes A&B-have at least 1 MORV > 0.5 and a vapor pressure > 0.01) In one aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 3; 6; 10; 11; 12; 13;
14; 17; 18; 19; 20; 21;
22; 23; 26; 27; 28; 30; 31; 32; 33; 34; 35; 37; 38; 40; 41; 43; 44; 47; 48;
50; 52; 53; 55; 57; 58; 59; 60; 61;
64; 65; 66; 67; 68; 69; 71; 72; 73; 74; 75; 77; 78; 80; 81; 82; 83; 84; 85;
91; 93; 94; 95; 96; 97; 101; 102;
103; 104; 105; 108; 109; 110; 113; 114; 116; 118; 120; 121; 122; 123; 124;
125; 126; 128; 129; 130; 132;
133; 134; 135; 137; 138; 139; 142; 143; 144; 145; 146; 147; 148; 149; 151;
152; 153; 156; 157; 158; 162;
163; 165; 166; 167; 168; 170; 171; 175; 176; 177; 178; 180; 182; 184; 187;
188; 190; 192; 193; 194; 195;
196; 198; 199; 200; 201; 205; 206; 208; 209; 211; 212; 213; 214; 216; 217;
219; 220; 222; 224; 225; 226;
227; 228; 229; 230; 231; 232; 233; 234; 235; 236; 237; 240; 241; 243; 244;
245; 247; 249; 250; 252; 253;
255; 258; 259; 260; 261; 265; 267; 268; 269; 270; 273; 274; 275; 276; 277;
280; 281; 282; 283; 284; 285;
286; 287; 288; 290; 297; 298; 301; 304; 305; 306; 307; 308; 309; 311; 312;
315; 316; 317; 319; 320; 321;
324; 325; 326; 328; 330; 331; 332; 335; 336; 337; 338; 339; 340; 341; 342;
343; 344; 345; 346; 347; 351;
354; 356; 357; 358; 360; 361; 364; 365; 367; 368; 372; 375; 376; 377; 378;
380; 381; 383; 384; 385; 393;
394; 395; 399; 404; 407; 408; 414; 416; 417; 418; 421; 423; 424; 426; 428;
433; 434; 435; 436; 440; 442;
443; 444; 446; 447; 450; 451; 452; 455; 456; 458; 464; 467; 468; 469; 471;
472; 473; 475; 476; 481; 485;
489; 493; 494; 495; 500; 501; 507; 508; 514; 519; 521; 522; 525; 526; 528;
532; 534; 535; 544; 549; 551;
557; 561; 565; 567; 573; 574; 576; 578; 580; 581; 584; 587; 590; 592; 593;
595; 600; 602; 603; 604; 608;
610; 613; 618; 625; 635; 638; 641; 643; 662; 663; 667; 679; 685; 689; 690;
695; 703; 705; 707; 712; 713;
736; 741; 742; 743; 760; 764; 771; 772; 773; 779; 790; 795; 800; 801; 810;
849; 1042; 1108; 1110; 1113;
1115; 1116 Table 2 materials 174; 190; 613; 689; 690; 695; 779, and Table 3 materials 2; 7; 11; 18;
19; 21; 22; 23; 26; 41; 46; 51; 55; 56; 57; 61; 63; 64; 68; 80; 86; 88; 89;
95; 101; 102; 107; 108; 113; 117;
118; 121; 122; 125; 129; 130; 132; 136; 139; 141; 144; 146; 147; 154; 166;
171; 178; 184; 192; 193; 200;
205; 206; 209; 211; 213; 219; 220; 224; 227; 232; 239; 242; 250; 255; 256;
260; 263; 267; 268; 270; 273;
278; 281; 282; 284; 294; 297; 298; 301; 303; 305; 306; 308; 315; 318; 320;
322; 324; 325; 326; 330; 332;
335; 343; 358; 362; 364; 365; 367; 372; 373; 375; 378; 379; 383; 385; 391;
393; 394; 395; 402; 404; 408;
409; 415; 416; 417; 418; 419; 424; 425; 428; 435; 436; 442; 443; 444; 448;
449; 455; 457; 462; 469; 473;
476; 480; 481; 485; 493; 494; 507; 514; 519; 527; 532; 535; 543; 544; 549;
551; 565; 572; 573; 574; 577;
581; 586; 590; 595; 604; 617; 636; 638; 643; 680; 703; 707; 749; 760; 764;
771; 772; 773; 795; 800; 810;
1110; 1113 and mixtures thereof;
(Ingredients in Tables 1-3 having comment code D-have at least 1 MORV > 0.5 and Clog P >3) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 17; 34; 36; 39; 40; 41; 43; 47;
48; 52; 53; 55; 57; 58;
59; 60; 61; 64; 65; 67; 72; 73; 74; 76; 77; 82; 83; 84; 85; 91; 92; 93; 94;
95; 98; 99; 100; 101; 102; 103;
104; 105; 109; 110; 113; 114; 115; 116; 118; 125; 126; 129; 130; 132; 134;
138; 139; 142; 143; 145; 146;
151; 152; 156; 157; 158; 159; 161; 164; 165; 166; 170; 171; 172; 175; 176;
178; 179; 180; 181; 182; 183;
186; 188; 190; 192; 193; 194; 197; 199; 205; 206; 207; 209; 210; 211; 213;
214; 216; 217; 224; 225; 226;
228; 230; 231; 232; 233; 234; 235; 236; 237; 240; 244; 245; 248; 249; 251;
253; 255; 258; 259; 260; 262;
264; 265; 266; 267; 268; 269; 270; 271; 272; 274; 279; 280; 282; 286; 289;
290; 293; 295; 296; 297; 298;
305; 306; 307; 308; 309; 311; 312; 313; 315; 319; 320; 323; 324; 325; 331;
333; 335; 338; 339; 340; 341;
342; 345; 347; 348; 350; 354; 355; 356; 357; 358; 360; 361; 363; 364; 365;
368; 369; 370; 371; 374; 375;
376; 377; 383; 384; 385; 389; 396; 397; 398; 399; 400; 403; 404; 406; 408;
412; 414; 416; 417; 421; 422;
423; 428; 434; 435; 436; 437; 441; 443; 444; 445; 446; 447; 455; 456; 458;
461; 463; 465; 467; 469; 471;
472; 473; 474; 475; 477; 478; 481; 482; 483; 484; 485; 486; 487; 488; 491;
492; 496; 499; 500; 501; 502;
503; 504; 505; 506; 508; 509; 510; 511; 512; 514; 516; 518; 519; 520; 521;
522; 523; 524; 528; 529; 530;
531; 532; 533; 534; 535; 536; 537; 539; 540; 541; 542; 544; 547; 548; 549;
550; 551; 552; 554; 555; 556;
557; 558; 559; 561; 562; 563; 564; 565; 566; 568; 569; 570; 574; 575; 576;
578; 580; 581; 582; 583; 584;
587; 588; 590; 591; 593; 597; 599; 600; 602; 603; 604; 605; 606; 607; 608;
610; 611; 612; 613; 616; 618;
619; 620; 621; 622; 623; 624; 625; 627; 630; 632; 633; 635; 637; 638; 639;
640; 641; 642; 643; 644; 645;
647; 648; 650; 651; 652; 653; 654; 655; 656; 657; 658; 659; 662; 665; 667;
668; 669; 670; 671; 673; 674;
675; 676; 677; 678; 679; 681; 682; 683; 684; 685; 687; 688; 689; 690; 691;
692; 693; 694; 696; 697; 698;
699; 702; 703; 705; 706; 707; 708; 709; 710; 711; 714; 715; 716; 717; 718;
719; 720; 721; 722; 725; 726;
727; 728; 729; 733; 735; 736; 737; 738; 740; 741; 742; 743; 744; 745; 746;
747; 748; 751; 752; 754; 756;
757; 759; 760; 762; 763; 764; 765; 766; 767; 768; 770; 771; 772; 773; 774;
776; 777; 778; 779; 780; 783;
784; 785; 786; 787; 788; 790; 791; 793; 794; 796; 797; 799; 800; 801; 802;
803; 804; 805; 806; 808; 809;
810; 811; 812; 813; 814; 815; 816; 817; 818; 819; 821; 822; 823; 824; 825;
826; 827; 828; 829; 830; 831;
832; 833; 835; 836; 837; 838; 840; 841; 842; 843; 844; 845; 846; 847; 848;
849; 850; 851; 852; 853; 854;
855; 856; 857; 859; 860; 861; 862; 863; 864; 865; 866; 867; 868; 869; 870;
871; 872; 873; 874; 875; 876;
878; 879; 880; 881; 882; 883; 884; 885; 886; 887; 888; 889; 890; 891; 892;
893; 894; 895; 896; 897; 898;
899; 901; 902; 903; 904; 905; 906; 907; 908; 910; 911; 912; 913; 914; 915;
916; 917; 918; 919; 920; 921;
922; 923; 924; 925; 926; 927; 928; 929; 931; 932; 933; 934; 936; 937; 938;
939; 940; 941; 942; 943; 944;
945; 946; 947; 948; 949; 950; 951; 952; 953; 954; 955; 956; 957; 958; 959;
960; 961; 962; 964; 965; 966;
968; 969; 970; 971; 972; 974; 975; 976; 977; 978; 979; 980; 981; 982; 983;
984; 985; 986; 987; 988; 989;
990; 991; 992; 993; 994; 995; 996; 997; 998; 999; 1000; 1001; 1002; 1003;
1004; 1005; 1006; 1007; 1008;
1009; 1010; 1011; 1012; 1013; 1014; 1015; 1016; 1017; 1018; 1019; 1020; 1021;
1022; 1023; 1025; 1026;
1027; 1028; 1029; 1030; 1031; 1032; 1033; 1034; 1035; 1036; 1037; 1038; 1039;
1040; 1041; 1043; 1044;
1045; 1046; 1047; 1048; 1049; 1051; 1052; 1053; 1054; 1055; 1056; 1057; 1058;
1059; 1060; 1061; 1062;
1063; 1064; 1065; 1066; 1067; 1068; 1069; 1070; 1071; 1073; 1075; 1076; 1077;
1078; 1079; 1080; 1081;
1082; 1083; 1084; 1085; 1088; 1090; 1091; 1092; 1093; 1094; 1095; 1096; 1097;
1098; 1099; 1100; 1101;
1103; 1104; 1105; 1106; 1107; 1108; 1109; 1115, Table 2 materials 174; 190;
248; 613; 689; 690; 717;
751; 779; 814; 828; 830; 914; 919; 945; 959; 965; 991; 998; 999; 1020; 1027;
1030; 1032; 1054; 1056;
1057; 1061; 1063; 1070; 1071; 1075; 1076; 1079; 1080; 1082; 1083; 1084; 1085;
1086; 1088; 1089; 1090;
1091; 1094; 1099; 1101; 1103; 1104; 1105; 1106, and Table 3 materials 41; 55;
56; 57; 61; 63; 64; 88;
95; 98; 99; 101; 102; 113; 115; 118; 125; 129; 130; 132; 139; 146; 154; 161;
166; 171; 178; 179; 192; 193;
205; 206; 207; 209; 211; 213; 224; 232; 239; 242; 255; 256; 260; 266; 267;
268; 270; 271; 279; 282; 289;
297; 298; 303; 305; 306; 308; 313; 315; 320; 322; 323; 324; 325; 333; 335;
355; 358; 364; 365; 369; 370;
375; 383; 385; 389; 391; 396; 402; 404; 405; 408; 409; 416; 417; 428; 435;
436; 437; 441; 443; 444; 445;
448; 455; 457; 462; 463; 469; 473; 474; 477; 478; 480; 481; 482; 483; 484;
485; 486; 487; 491; 498; 499;
502; 503; 504; 505; 511; 512; 514; 519; 520; 524; 529; 530; 532; 535; 537;
539; 540; 541; 542; 543; 544;
547; 549; 551; 552; 556; 562; 565; 569; 572; 574; 577; 581; 582; 586; 590;
596; 599; 604; 606; 607; 611;
612; 622; 623; 633; 638; 643; 649; 651; 652; 654; 655; 656; 657; 660; 661;
669; 671; 674; 676; 681; 683;
688; 692; 693; 702; 703; 707; 709; 715; 728; 735; 737; 740; 744; 745; 749;
752; 754; 760; 761; 764; 766;
768; 771; 772; 773; 774; 776; 777; 778; 780; 783; 784; 791; 794; 796; 797;
798; 799; 800; 802; 803; 804;
806; 808; 810; 815; 817; 818; 821; 823; 824; 825; 826; 829; 833; 835; 836;
837; 844; 845; 850; 851; 852;
853; 854; 860; 861; 864; 865; 866; 867; 870; 872; 874; 875; 881; 883; 884;
886; 891; 894; 896; 898; 900;
901; 904; 905; 907; 908; 910; 911; 913; 915; 916; 917; 918; 921; 923; 924;
928; 929; 930; 934; 940; 942;
943; 946; 952; 956; 957; 963; 966; 968; 971; 974; 976; 977; 978; 979; 981;
982; 983; 987; 988; 994; 995;
997; 1000; 1003; 1004; 1006; 1014; 1016; 1017; 1018; 1021; 1022; 1026; 1029;
1031; 1036; 1046; 1049;
1051; 1053; 1055; 1058; 1064; 1065; 1066; 1067; 1075; 1079; 1081; 1091; 1093;
1102; 1103; 1109 and mixtures thereof.
(Ingredients in Tables 1-3 having comment code D and A or B-have at least 1 MORV >
0.5, a Clog P >3 and a vapor pressure > 0.01 Torr) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 17; 34; 40; 41; 43; 47; 48; 52; 53; 55; 57; 58; 59; 60; 61; 64; 65; 67; 72;
73; 74; 77; 82; 83; 84; 85; 91; 93;
94; 95; 101; 102; 103; 104; 105; 109; 110; 113; 114; 116; 118; 125; 126; 129;
130; 132; 134; 138; 139;
142; 143; 145; 146; 151; 152; 156; 157; 158; 165; 166; 170; 171; 175; 176;
178; 180; 182; 188; 190; 192;
193; 194; 199; 205; 206; 209; 211; 213; 214; 216; 217; 224; 225; 226; 228;
230; 231; 232; 233; 234; 235;
236; 237; 240; 244; 245; 249; 253; 255; 258; 259; 260; 265; 267; 268; 269;
270; 274; 280; 282; 286; 290;
297; 298; 305; 306; 307; 308; 309; 311; 312; 315; 319; 320; 324; 325; 331;
335; 338; 339; 340; 341; 342;
345; 347; 354; 356; 357; 358; 360; 361; 364; 365; 368; 375; 376; 377; 383;
384; 385; 399; 404; 408; 414;
416; 417; 421; 423; 428; 434; 435; 436; 443; 444; 446; 447; 455; 456; 458;
467; 469; 471; 472; 473; 475;
481; 485; 500; 501; 508; 514; 519; 521; 522; 528; 532; 534; 535; 544; 549;
551; 557; 561; 565; 574; 576;
578; 580; 581; 584; 587; 590; 593; 600; 602; 603; 604; 608; 610; 613; 618;
625; 635; 638; 641; 643; 662;
667; 679; 685; 689; 690; 703; 705; 707; 736; 741; 742; 743; 760; 764; 771;
772; 773; 779; 790; 800; 801;
810; 849; 1108; 1115, Table 2 materials 174; 190; 613; 689; 690; 779, and Table 3 materials 41; 55;
56; 57; 61; 63; 64; 88; 95; 101; 102; 113; 118; 125; 129; 130; 132; 139; 146;
154; 166; 171; 178; 192; 193;
205; 206; 209; 211; 213; 224; 232; 239; 242; 255; 256; 260; 267; 268; 270;
282; 297; 298; 303; 305; 306;
308; 315; 320; 322; 324; 325; 335; 358; 364; 365; 375; 383; 385; 391; 402;
404; 408; 409; 416; 417; 428;
435; 436; 443; 444; 448; 455; 457; 462; 469; 473; 480; 481; 485; 514; 519;
532; 535; 543; 544; 549; 551;
565; 572; 574; 577; 581; 586; 590; 604; 638; 643; 703; 707; 749; 760; 764;
771; 772; 773; 800; 810 and mixtures thereof.
(Ingredients in Tables 1-3 having comment code C-have at least I MORV >0.5 and Clog P <3) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 1; 3; 4; 5; 6; 8; 9; 10; 11; 12; 13;
14; 15; 16; 18; 19; 20; 21;
22; 23; 24; 26; 27; 28; 29; 30; 31; 32; 33; 35; 37; 38; 44; 45; 49; 50; 54;
62; 66; 68; 69; 70; 71; 75; 78; 79;
80; 81; 87; 96; 97; 106; 108; 111; 112; 119; 120; 121; 122; 123; 124; 127;
128; 131; 133; 135; 137; 140;
144; 147; 148; 149; 150; 153; 155; 160; 162; 163; 167; 168; 169; 173; 177;
184; 185; 187; 189; 191; 195;
196; 198; 200; 201; 203; 204; 208; 212; 215; 218; 219; 220; 222; 223; 227;
229; 238; 241; 243; 246; 247;
250; 252; 254; 257; 261; 273; 275; 276; 277; 281; 283; 284; 285; 287; 288;
291; 292; 299; 300; 301; 302;
304; 314; 316; 317; 321; 326; 327; 328; 329; 330; 332; 336; 337; 343; 344;
346; 349; 351; 352; 353; 359;
366; 367; 372; 378; 380; 381; 382; 387; 388; 390; 393; 394; 395; 401; 407;
410; 411; 413; 418; 420; 424;
426; 427; 429; 430; 431; 433; 438; 439; 440; 442; 450; 451; 452; 453; 454;
459; 460; 464; 466; 468; 470;
476; 479; 489; 490; 493; 494; 495; 497; 507; 513; 515; 517; 525; 526; 538;
545; 546; 553; 560; 567; 571;
573; 579; 585; 589; 592; 594; 595; 598; 601; 609; 614; 615; 626; 628; 629;
631; 634; 646; 663; 664; 666;
672; 686; 695; 700; 701; 712; 713; 724; 730; 731; 732; 734; 739; 750; 753;
755; 758; 769; 775; 781; 782;
789; 792; 795; 807; 820; 834; 839; 858; 877; 909; 935; 967; 973; 1024; 1042;
1074; 1087; 1110; 1111;
1112; 1113; 1114; 1116, Table 2 materials 25; 42; 695; 1050; 1072; 1087, and Table 3 materials 2; 4;
7; 11; 18; 19; 21; 22; 23; 24; 26; 46; 51; 68; 70; 80; 86; 89; 90; 107; 108;
111; 117; 119; 121; 122; 136;
141; 144; 147; 173; 184; 185; 189; 191; 200; 202; 204; 215; 218; 219; 220;
227; 250; 254; 257; 263; 273;
278; 281; 284; 291; 294; 299; 300; 301; 310; 318; 326; 327; 330; 332; 334;
343; 359; 362; 366; 367; 372;
373; 378; 379; 386; 390; 392; 393; 394; 395; 410; 413; 415; 418; 419; 420;
424; 425; 427; 430; 432; 442;
449; 460; 470; 476; 490; 493; 494; 507; 515; 527; 546; 560; 571; 573; 579;
585; 595; 609; 614; 615; 617;
628; 631; 636; 664; 666; 680; 723; 730; 734; 758; 789; 795; 877; 967; 1072;
1110; 1113; and mixtures thereof.
(Ingredients in Tables 1-3 having comment code F- have at least one MORV >0.5 and are stable in microcapsules having a shell that comprises melamine formaldehyde and/or a polyacrylate) In another aspect, said composition comprises a malodor reduction material selected from the group consisting of Table 1 materials 5; 6; 16; 20; 26; 27;
31; 32; 38; 40; 41; 43;
49; 55; 58; 59; 61; 67; 71; 72; 73; 74; 76; 79; 82; 83; 84; 85; 91; 92; 93;
94; 95; 96; 98; 99; 100; 101; 102;
103; 104; 106; 109; 110; 113; 114; 116; 118; 121; 123; 125; 128; 130; 132;
133; 134; 135; 138; 139; 142;
143; 145; 146; 147; 148; 149; 152; 157; 158; 159; 160; 161; 163; 164; 166;
170; 172; 173; 175; 176; 178;
179; 180; 181; 182; 183; 184; 185; 186; 187; 188; 190; 191; 192; 193; 194;
197; 199; 201; 203; 206; 207;
209; 210; 211; 213; 214; 216; 217; 218; 220; 224; 225; 226; 227; 228; 229;
230; 231; 232; 233; 234; 236;
237; 240; 243; 244; 247; 248; 250; 251; 253; 254; 255; 258; 259; 260; 262;
264; 265; 266; 267; 268; 270;
271; 273; 274; 275; 276; 277; 279; 280; 282; 283; 286; 289; 290; 291; 292;
293; 295; 296; 297; 298; 299;
300; 301; 302; 305; 306; 307; 308; 309; 311; 312; 313; 315; 316; 317; 319;
320; 321; 323; 324; 325; 326;
327; 328; 330; 331; 332; 333; 338; 339; 340; 341; 344; 345; 346; 347; 348;
351; 354; 355; 356; 357; 358;
360; 361; 363; 364; 365; 366; 367; 368; 369; 370; 371; 372; 374; 375; 376;
377; 381; 382; 383; 384; 385;
387; 388; 389; 394; 395; 396; 397; 399; 403; 404; 406; 407; 408; 410; 411;
412; 413; 414; 416; 417; 418;
421; 422; 423; 424; 428; 431; 434; 435; 436; 437; 438; 439; 440; 441; 442;
443; 444; 445; 446; 447; 451;
454; 455; 456; 458; 460; 461; 463; 464; 465; 466; 467; 468; 469; 470; 471;
472; 473; 474; 475; 476; 477;
478; 481; 482; 483; 484; 485; 486; 488; 489; 490; 491; 492; 496; 497; 499;
500; 501; 502; 503; 504; 505;
506; 507; 508; 509; 510; 511; 512; 514; 515; 517; 519; 520; 521; 522; 523;
524; 525; 526; 528; 529; 530;
531; 532; 533; 534; 535; 536; 537; 538; 539; 540; 541; 542; 544; 545; 546;
547; 548; 549; 550; 551; 552;
554; 555; 556; 557; 558; 559; 561; 562; 563; 564; 565; 566; 567; 568; 569;
570; 573; 574; 575; 576; 578;
580; 581; 582; 583; 584; 585; 587; 588; 589; 590; 591; 592; 593; 594; 597;
599; 600; 601; 603; 604; 605;
606; 607; 608; 609; 610; 611; 612; 613; 614; 615; 616; 618; 619; 620; 621;
622; 623; 624; 625; 626; 627;
628; 629; 630; 631; 632; 634; 635; 637; 638; 639; 640; 641; 642; 643; 644;
645; 646; 647; 648; 650; 651;
652; 653; 654; 655; 656; 657; 658; 659; 662; 663; 664; 665; 666; 667; 668;
669; 670; 671; 672; 673; 674;
675; 676; 677; 678; 679; 681; 682; 683; 684; 685; 686; 687; 688; 689; 690;
691; 692; 693; 694; 695; 696;
697; 698; 699; 700; 701; 702; 703; 705; 706; 707; 708; 709; 710; 711; 712;
713; 714; 715; 716; 717; 718;
719; 720; 721; 722; 724; 725; 726; 727; 728; 729; 730; 731; 732; 733; 734;
735; 736; 737; 738; 739; 740;
741; 742; 743; 744; 745; 746; 747; 748; 750; 751; 752; 753; 754; 755; 756;
757; 758; 759; 760; 762; 763;
764; 765; 766; 767; 768; 769; 770; 771; 772; 773; 774; 775; 776; 777; 778;
779; 780; 781; 782; 783; 784;
785; 786; 787; 788; 789; 790; 791; 792; 793; 794; 795; 796; 797; 799; 800;
801; 802; 803; 804; 805; 806;
807; 808; 809; 810; 811; 812; 813; 814; 815; 816; 817; 818; 819; 820; 821;
822; 823; 824; 825; 826; 827;
828; 829; 830; 831; 832; 833; 834; 835; 836; 837; 838; 839; 840; 841; 842;
843; 844; 845; 846; 847; 848;
849; 850; 851; 852; 853; 854; 855; 856; 857; 858; 859; 860; 861; 862; 863;
864; 865; 866; 867; 868; 869;
870; 871; 872; 873; 874; 875; 876; 877; 878; 879; 880; 881; 882; 883; 884;
885; 886; 887; 888; 889; 890;
891; 892; 893; 894; 895; 896; 897; 898; 899; 901; 902; 903; 904; 905; 906;
907; 908; 909; 910; 911; 912;
913; 914; 915; 916; 917; 918; 919; 920; 921; 922; 923; 924; 925; 926; 927;
928; 929; 931; 932; 933; 934;
935; 936; 937; 938; 939; 940; 941; 942; 943; 944; 945; 946; 947; 948; 949;
950; 951; 952; 953; 954; 955;
956; 957; 958; 959; 960; 961; 962; 964; 965; 966; 967; 968; 969; 970; 971;
972; 973; 974; 975; 976; 977;
978; 979; 980; 981; 982; 983; 984; 985; 986; 987; 988; 989; 990; 991; 992;
993; 994; 995; 996; 997; 998;
999; 1000; 1001; 1002; 1003; 1004; 1005; 1006; 1007; 1008; 1009; 1010; 1011;
1012; 1013; 1014; 1015;
1016; 1017; 1018; 1019; 1020; 1021; 1022; 1023; 1024; 1025; 1026; 1027; 1028;
1029; 1030; 1031; 1032;
1033; 1034; 1035; 1036; 1037; 1038; 1039; 1040; 1041; 1042; 1043; 1044; 1045;
1046; 1047; 1048; 1049;
1051; 1052; 1053; 1054; 1055; 1056; 1057; 1058; 1059; 1060; 1061; 1062; 1063;
1064; 1065; 1066; 1067;
1068; 1069; 1070; 1071; 1073; 1074; 1075; 1076; 1077; 1078; 1079; 1080; 1081;
1082; 1083; 1084; 1085;
1087; 1088; 1090; 1091; 1092; 1093; 1094; 1095; 1096; 1097; 1098; 1099; 1100;
1101; 1103; 1104; 1105;
1106; 1107; 1108; 1109; 1110; 1112; 1113; 1114; 1115; 1116, Table 2 materials 25; 42; 174; 190; 248;
613; 689; 690; 695; 717; 751; 779; 814; 828; 830; 914; 919; 945; 959; 965;
991; 998; 999; 1020; 1027;
1030; 1032; 1050; 1054; 1056; 1057; 1061; 1063; 1070; 1071; 1072; 1075; 1076;
1079; 1080; 1082; 1083;
1084; 1085; 1086; 1087; 1088; 1089; 1090; 1091; 1094; 1099; 1101; 1103; 1104;
1105; 1106, and Table 3 materials 26; 41; 55; 61; 89; 90; 95; 98; 99; 101; 102; 107; 113; 117; 118;
121; 125; 130; 132; 136; 139;
146; 147; 161; 166; 173; 178; 179; 184; 185; 191; 192; 193; 206; 207; 209;
211; 213; 218; 220; 224; 227;
232; 239; 242; 250; 254; 255; 256; 260; 266; 267; 268; 270; 271; 273; 279;
282; 289; 291; 297; 298; 299;
300; 301; 305; 306; 308; 310; 313; 315; 318; 320; 323; 324; 325; 326; 327;
330; 332; 333; 355; 358; 362;
364; 365; 366; 367; 369; 370; 372; 373; 375; 383; 385; 389; 391; 394; 395;
396; 402; 404; 405; 408; 409;
410; 413; 415; 416; 417; 418; 419; 424; 425; 428; 432; 435; 436; 437; 441;
442; 443; 444; 445; 448; 455;
457; 460; 462; 463; 469; 470; 473; 474; 476; 477; 478; 480; 481; 482; 483;
484; 485; 486; 490; 491; 498;
499; 502; 503; 504; 505; 507; 511; 512; 514; 515; 519; 520; 524; 527; 529;
530; 532; 535; 537; 539; 540;
541; 542; 543; 544; 546; 547; 549; 551; 552; 556; 562; 565; 569; 572; 573;
574; 577; 581; 582; 585; 586;
590; 596; 599; 604; 606; 607; 609; 611; 612; 614; 615; 617; 622; 623; 628;
631; 636; 638; 643; 649; 651;
652; 654; 655; 656; 657; 660; 661; 664; 666; 669; 671; 674; 676; 680; 681;
683; 688; 692; 693; 702; 703;
707; 709; 715; 723; 728; 730; 734; 735; 737; 740; 744; 745; 749; 752; 754;
758; 760; 761; 764; 766; 768;
771; 772; 773; 774; 776; 777; 778; 780; 783; 784; 789; 791; 794; 795; 796;
797; 798; 799; 800; 802; 803;
804; 806; 808; 810; 815; 817; 818; 821; 823; 824; 825; 826; 829; 833; 835;
836; 837; 844; 845; 850; 851;
852; 853; 854; 860; 861; 864; 865; 866; 867; 870; 872; 874; 875; 877; 881;
883; 884; 886; 891; 894; 896;
898; 900; 901; 904; 905; 907; 908; 910; 911; 913; 915; 916; 917; 918; 921;
923; 924; 928; 929; 930; 934;
940; 942; 943; 946; 952; 956; 957; 963; 966; 967; 968; 971; 974; 976; 977;
978; 979; 981; 982; 983; 987;
988; 994; 995; 997; 1000; 1003; 1004; 1006; 1014; 1016; 1017; 1018; 1021;
1022; 1026; 1029; 1031;
1036; 1046; 1049; 1051; 1053; 1055; 1058; 1064; 1065; 1066; 1067; 1072; 1075;
1079; 1081; 1091; 1093;
1102; 1103; 1109; 1110; 1113 and mixtures thereof.
A composition comprising a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane-l-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof is disclosed.
Preferably, said composition comprises, based on total composition weight, from 0.0001% to 100% of a malodor reduction material selected from the group consisting of 3,5-di methyladamantane-l-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof, and an adjunct material. Preferably, said composition is a consumer product.
A plastic film said plastic film comprising linear low density polyethylene (LLDPE), low density polyethylene (LDPE), high density polyethylene (HDPE), and/or compostable film and a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane-1-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-l-carboxylic acid;
(E)-1,1,4,4-tetramethoxybut-2-ene; dimethyl (4R,5R)-2,2-dimethy1-1,3-dioxolane-4,5-dicarboxylate;
1,2,3,4,5,6-hexamethylbenzene; dimethyl (I R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof is disclosed.
A method of controlling malodors comprising contacting a material comprising a malodor with a composition comprising a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane-l-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene; dimethyl (4R,5R)-2,2-dimethy1-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene; dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof is disclosed. Preferably, said composition comprises, based on total composition weight, from 0.0001% to 100% of a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane- I -carboxylic acid; (IR,6S)-6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate;
1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof, and an adjunct material. Preferably, said composition is a consumer product.
The use of a composition comprising a malodor reduction material selected from the group consisting of 3,5-dimethyladamantane- 1-carboxylic acid; (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-l-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxyl ate;
1,2,3,4,5,6-hexamethylbenzene; dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof to reduce a malodor is disclosed In one aspect of said composition comprising a malodor reduction material, said composition comprises a malodor reduction material having a Universal MORV.
Preferably, said composition comprising a malodor reduction material having a Universal MORV comprises a malodor reduction material selected from the group consisting of Table 4 materials 608; 635; 662; 667; 685; 705; 741; 790; 801; 849; 1042; and Table 5 material 480 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV. In one aspect, said composition comprises, a malodor reduction material selected from the group consisting of Table 4 materials 406; 568; 588; 608;
627; 635; 644; 662;
667; 685; 705; 720; 738; 741; 748; 770; 790; 793; 801; 805; 813; 841; 848;
849; 856; 857; 859;
871; 876; 880; 887; 888; 892 and Table 5 materials 480; 798 and mixtures thereof are disclosed.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 608; 635; 662; 667; 685; 705; 741; 790; 801; 849 and Table 5 material 480 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 411; 646; 724; 732; 858; 973; 1042 and Table 5 material 310 and mixtures thereof.
In one aspect, said composition comprising a malodor reduction material having a Universal MORV comprises, a malodor reduction material selected from the group consisting of Table 4 materials 406; 411; 568; 588; 608; 627; 635; 644; 646; 662; 667; 685;
705; 720; 724; 732;
738; 741; 748; 770; 790; 793; 801; 805; 813; 841; 848; 849; 856; 857; 858;
859; 871; 876; 880;
887; 888; 892; 895; 903; 912; 920; 922; 925; 926; 931; 932; 937; 938; 944;
948; 954; 955; 958;
960; 961; 964; 969; 972; 973; 975; 984; 992; 996; 1010; 1011; 1012; 1025;
1028; 1033; 1034;
1037; 1038; 1042; 1044; 1048; 1052; 1060; 1069 and Table 5 materials 310,480,798 and mixtures thereof.
A composition according to any preceding embodiment, said malodor reduction composition being a consumer product, said consumer product comprising a total of, based on total consumer product weight, from about 0.0001% to about 100% of one or more of said malodor reduction materials and an adjunct material is disclosed.
Said malodor reduction composition that is a consumer product is a laundry detergent that comprises a total of, based on total consumer product weight, from about 0.0001% to about 10%, in one aspect, from about 0.001% to about 5%, in one aspect, from about 0.01%
to about 3%, in one aspect, from about 0.1% to about 2% of one or more of said malodor reduction materials and, a material selected from the group consisting of surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, a fabric softener active, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and mixtures thereof, in none aspect, said laundry detergent comprises an adjunct material selected from the group consisting of an organic acid, in one aspect, citric acid and/ or lactic acid, hydrogenated castor oil, ethoxylated polyethyleneimines, PEI 600 EO 20 and/or PEI 600, an enzyme, a cold water amylase, cold water protease and/ or xylogluconase.
Said malodor reduction composition that is a consumer product is an air care composition that comprises a total of, based on total consumer product weight, from about 0.001% to about 100%, preferably from 0.01 to 10%, of one or more of said malodor reduction materials and, optionally, one or more materials selected from the group consisting of surfactants, antimicrobial agents, wetting agents, buffering agents, cyclodextrins, propellants, and solvents.
Said malodor reduction composition that is a consumer product is a liquid fabric enhancer that comprises a total of, based on total composition weight, from about 0.05%
to about 10% of one or more of said malodor reduction materials and, a fabric softener active selected from the group consisting of a quaternary ammonium compound, a silicone polymer, a polysaccharide, a clay, an amine, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, said quaternary ammonium compound is selected from the group consisting of bis-(2-hydroxypropy1)-dimethylammonium methylsulphate fatty acid ester, 1,2-di(acyloxy)-3-trimethylammoniopropane chloride., N, N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate, 1, 2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tal lowdimethyl ammonium chloride dicanoladimethylammonium methylsulfate, 1-methyl-l-stearoylamidoethyl-2-stearoylimidazolinium methylsulfate, 1-tallowylamidoethy1-2-tallowylimidazoline, Dipal methyl Hydroxyethylammoinum Methosulfate and mixtures thereof, said fabric softening active having an Iodine Value of between 0-140, in one aspect, 5-100, in one aspect,10-80, in one aspect, 15-70, in one aspect 18-25.
Said malodor reduction composition that is a consumer product is a fabric enhancer solid particle or bead composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and at least about 25% polyethyleneglycol (PEG) 8000.
Said malodor reduction composition that is a consumer product is a soluble unit-dose composition contained within a polyvinyl alcohol (PVA) film.
Said malodor reduction composition that is a consumer product is a fabric softener dryer added sheet composition, said fabric softener dryer added sheet composition comprising from 0.05% to about 10% of one or more of said malodor reduction materials and impregnated onto a non-woven sheet.
Said malodor reduction composition that is a consumer product is a spray-dried laundry detergent powder, said composition comprising from about 0.05% to about 20% of one or more of said malodor reduction materials and at least 10% solids chosen from the following list or combinations thereof: sodium carbonate, sodium sulfate, carboxy methyl cellulose powder, a polymer comprising an acrylate monomer.
Said malodor reduction composition that is a consumer product is a plastic film said plastic film comprising LLDPE, LDPE, HDPE, and/or compostable film, in one aspect, said plastic film comprises about 0.5 mg to about 100 mg of said malodor reduction composition per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 30 mg per 20 grams of said plastic film, in one aspect, said malodor reduction composition is present in the amount of about 5 mg to about 15 mg per 20 grams of said plastic film.
Said malodor reduction composition that is a consumer product is an absorbent article said absorbent article comprising a total of, based on total consumer product weight, from about 0.1% to about 75%, in one aspect, from about 1% to about 50%, from about 5% to about 40%, from about 12% to about 30% of one or more of said malodor reduction materials and, wherein the article comprises a topsheet, a backsheet, an absorbent core disposed between the topsheet and the backsheet, and an acquisition layer disposed between the topsheet and the absorbent core, wherein the malodor reduction composition is disposed on one of the backsheet, absorbent core, or acquisition layer, said absorbent article comprises a hot melt adhesive and the hot melt adhesive comprises the malodor reduction composition, the hot melt adhesive adheres the backsheet to the topsheet, the backsheet comprises a nonwoven layer and a film layer, and the hot melt adhesive adheres the backsheet nonwoven layer to the backsheet film layer.
Said malodor reduction composition that is a consumer product is a personal care deodorant composition, said deodorant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 0.01% to about 75% of an antimicrobial, said antimicrobials are selected from the group consisting of metals, zeolites, metal zeolites, quaternary ammonium (quat) compounds (e.g., cetyl pyridinium chloride, and benzylalkonium chloride), quat bound clays, metal bound clays, polyaspirin. salicylic acid, polyvinyl amines, coal tar, sulfur, whitfield's ointment, castellani's paint, aluminum chloride, gentian violet, octopirox (piroctone olamine), ciclopirox olamine, undecylenic acid and its metal salts, potassium permanganate, selenium sulfide, sodium thiosulfate, glycols, diols, oil of bitter orange, urea preparations, griseofulvin, 8-Hydroxyquinoline ciloquinol, thiobendazole, thiocarbamates, haloprogin, polyenes, hydroxypyridone, morpholine, benzylamine, allylamines (such as terbinafine), tea tree oil, clove leaf oil, coriander, palmarosa, berberine, thyme red, cinnamon oil, citronellic acid, hinokitol, ichthyol pale, Sensiva SC-50, Elestab HP-100, azelaic acid, lyticase, iodopropynyl butylcarbamate (IPBC), triclosan, triclocarban, isothiazalinones and azoles, and combinations thereof, more preferably, hexanediol, triclosan, octyl isothiazalinone metals selected from the group consisting of Zn, Cu, Al, Ti, Sn, Bi, and Ag, metal salts selected from the group consisting of zinc carbonate, copper sulfate, and zinc gluconate, metal pyrithione salts selected from the group consisting of zing pyrithione (ZPT) and copper pyrithione (CuPT), glycols selected from the group consisting of propylene glycol, dipropylene glycol and hexylene glycol and mixtures thereof, said personal care deodorant composition comprises, based on total deodorant weight, from about 10% to about 75% glycol.
Said malodor reduction composition that is a consumer product is a personal care body wash/shampoo composition, said body wash/shampoo comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials from about 3% to 30% of a surfactant, and, optionally, a micellar phase and/or lamellar phase.
Said malodor reduction composition that is a consumer product is a personal care antiperspirant composition, said antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 1% to about 25% of an aluminum salt antiperspirant active.
Said malodor reduction composition that is a consumer product is an anhydrous antiperspirant composition, said anhydrous antiperspirant composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and from about 1% to about 25% of an antiperspirant actives selected from the group consisting of astringent metallic salts, inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof, aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.
Said malodor reduction composition that is a consumer product is a dish cleaning composition, said dish cleaning composition comprising a total of, based on total consumer product weight, from about 0.1% to about 7% of one or more of said malodor reduction materials.
A method of controlling malodors comprising: contacting the material comprising a malodor with a composition selected from the group consisting of any of the compositions comprising a malodor reduction material disclosed herein and mixtures thereof, said contacting step comprises contacting said material containing a malodor with about 1 mg to about 50 mg, from about 3 mg to 30 mg, or from about 5 mg to about 20 mg of said composition per 20 grams of said material containing a malodor is disclosed.
A method of determining the material's ability to decrease or even eliminate the perception of one or more malodors comprising determining the MORV and/or Universal MORV
of said material, in one aspect, determining said MORV and/or Universal MORV by the MORV and Universal MORV method provided in Test Method I, is disclosed.
Adjunct Materials While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant compositions and may be desirably incorporated in certain aspects of the invention, for example to assist or enhance cleaning performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the fabric treatment operation for which it is to be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives.
As stated, the adjunct ingredients are not essential to Applicants' compositions. Thus, certain aspects of Applicants' compositions do not contain one or more of the following adjuncts materials: surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems structure elasticizing agents, carriers, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below.
Hueing Dye - The liquid laundry detergent composition may comprise a hueing dye. The hueing dyes employed in the present laundry care compositions may comprise polymeric or non-polymeric dyes, organic or inorganic pigments, or mixtures thereof. In one aspect, the hueing dye comprises a polymeric dye, comprising a chromophore constituent and a polymeric constituent. The chromophore constituent is characterized in that it absorbs light in the wavelength range of blue, red, violet, purple, or combinations thereof upon exposure to light. In one aspect, the chromophore constituent exhibits an absorbance spectrum maximum from about 520 nanometers to about 640 nanometers in water and/or methanol, and in another aspect, from about 560 nanometers to about 610 nanometers in water and/or methanol.
Although any suitable chromophore may be used, the dye chromophore is, in one aspect, selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and phthalocyanine dye chromophores. Mono and di-azo dye chromophores are may be preferred.
Surfactants - The compositions according to the present invention may comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi-polar nonionic surfactants and mixtures thereof.
The surfactant is typically present at a level of from about 0.1% to about 60%, from about 1% to about 50% or even from about 5% to about 40% by weight of the subject composition.
Chelating Agents - The compositions herein may contain a chelating agent.
Suitable chelating agents include copper, iron and/or manganese chelating agents and mixtures thereof.
When a chelating agent is used, the composition may comprise from about 0.1%
to about 15% or even from about 3.0% to about 10% chelating agent by weight of the subject composition.
Dye Transfer Inhibiting Agents - The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
When present in a subject composition, the dye transfer inhibiting agents may be present at levels from about 0.0001% to about 10%, from about 0.01% to about 5% or even from about 0.01% to about 3% by weight of the composition.
Dispersants - The compositions of the present invention can also contain dispersants.
Suitable water-soluble organic materials include the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.
Perfumes ¨ The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-t-butylpheny1)-2-methyl propanal, 3-(4-t-butylpheny1)-propanal, 3-(4-isopropylpheny1)-2-methylpropanal, 3-(3,4-methylenedioxypheny1)-2-methylpropanal, and 2,6-dimethy1-5-heptenal, a-damascone, [3-damascone, 8-damascone, 13-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethy1-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methy1-3-cyclohexeny1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and 13-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.
Perfume Delivery Technologies - The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies can also be used to increase the longevity of perfume release from the treated substrate.
Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 Al.
In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of:
perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:
Said perfume delivery technology may comprise microcapsules formed by at least partially surrounding a benefit agent with a wall material. The microcapsule wall material may comprise:
melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. Said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. Said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. Said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. Said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. The perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof.
The microcapsule may be a perfume microcapsule. One or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.
Said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use "reactive" polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically, the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery.
A material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. The alternative compounds can be used in combination with amine compounds. A single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA
Al and USP 6,413,920 BI.
Fabric Softening Actives The compositions of the present invention may comprise a fabric softening active ("FSA"). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quaternary ammonium compounds (quat), quaternary ammonium ester compounds, amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty acids, softening oils, polymer latexes and mixtures thereof.
Non-limiting examples of water insoluble fabric care benefit agents include dispersible polyethylene and polymer latexes.
The quaternary ammonium ester softening active The quaternary ammonium ester softening active may be present at a level of from 3.0%
to 25.0%, more preferably from 4.0% to 18%, even more preferably from 4.5% to 15% by weight of the composition. The level of quaternary ammonium ester softening active may depend of the desired concentration of total softening active in the composition (diluted or concentrated composition) and of the presence or not of other softening active. While higher FSA levels improve the softness benefits, the risk on instabilities is typically higher in fabric softener compositions with higher FSA levels.
Suitable quaternary ammonium ester softening actives include but are not limited to, materials selected from the group consisting of monoester quats, diester quats, triester quats and mixtures thereof. Preferably, the level of monoester quat is from 2.0% to 40.0%, the level of diester quat is from 40.0% to 98.0%, the level of triester quat is from 0.0%
to 25.0% by weight of total quaternary ammonium ester softening active.
Said quaternary ammonium ester softening active may comprise compounds of the following formula:
{R2(4_,,) - N+ - IX - Y ¨ RI]m} A-wherein:
m is I, 2 or 3 with proviso that the value of each m is identical;
each R1 is independently hydrocarbyl, or branched hydrocarbyl group, preferably R1 is linear, more preferably R1 is partially unsaturated linear alkyl chain;
each R2 is independently a C1-C3 alkyl or hydroxyalkyl group, preferably R2 is selected from methyl, ethyl, propyl, hydroxyethyl, 2-hydroxypropyl, 1-methyl-2-hydroxyethyl, poly(C2-3 alkoxy), polyethoxy, benzyl;
each X is independently -(CH2)n-, -CH2-CH(CH3)- or -CH-(CH3)-CH2- and each n is independently 1, 2, 3 or 4, preferably each n is 2;
each Y is independently -0-(0)C- or -C(0)-0-;
A- is independently selected from the group consisting of chloride, methyl sulfate, and ethyl sulfate, preferably A- is selected from the group consisting of chloride and methyl sulfate;
with the proviso that when Y is -0-(0)C-, the sum of carbons in each 121 is from 13 to 21, preferably from 13 to 19. Preferably, X is -CH2-CH(CH3)- or -CH-(CH3)-CH2- to improve the hydrolytic stability of the quaternary ammonium ester softening active, and hence further improve the stability of the fabric softener composition.
In preferred liquid fabric softener compositions the iodine value of the parent fatty acid from which the quaternary ammonium fabric softening active is formed is from 0 to 100, more preferably from 10 to 60, even more preferably from 15 to 45.
Examples of suitable quaternary ammonium ester softening actives are commercially available from KAO Chemicals under the trade name Tetranyl AT-1 and Tetranyl AT-7590, from Evonik under the tradename Rewoquat WE16 DPG, Rewoquat WE18, Rewoquat WE20, Rewoquat WE28, and Rewoquat 38 DPG, from Stepan under the tradename Stepantex GA90, Stepantex VR90, Stepantex VK90, Stepantex VA90, Stepantex DC90, Stepantex VL90A.
These types of agents and general methods of making them are disclosed in U.S.P.N. 4,137,180.
Silicone The compositions of the present invention may comprise a silicone. Suitable levels of silicone may comprise from about 0.1% to about 70%, alternatively from about 0.3% to about 40%, alternatively from about 0.5% to about 30%, alternatively from about 1%
to about 20% by weight of the composition. Useful silicones can be any silicone comprising compound. In one embodiment, the silicone polymer is selected from the group consisting of cyclic silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures thereof. The silicone is a polydialkylsilicone, alternatively a polydimethyl silicone (polydimethyl siloxane or "PDMS"), or a derivative thereof. The silicone is chosen from an aminofunctional silicone, amino-polyether silicone, alkyloxylated silicone, cationic silicone, ethoxylated silicone, propoxylated silicone, ethoxylated/propoxylated silicone, quaternary silicone, or combinations thereof.
TEST METHODS
Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and identified, by analytical methods that include GC-MS and/or NMR.
MORV and Universal MORV calculation 1.) Search Chemical Abstracts using the name and/or the CAS Registry number for the material of interest and use the structure provided. If there are multiple isomers for a given material, use the structure provided by Chemical Abstracts or use the isomer that is most prevalent in the material. Input structure of material into winMolconn (Hall Associates, version 1.1.2.1).
2.) Input values from 1.) above into the following four equations:
a) MORV = ¨8.5096 + 2.8597x(dxp9) + 1.1253x(knotpv) ¨
0.34484x(e1C202) ¨
0.00046231x(idw) + 3.3509x(idcbar) + 0.11158x(n2pag22) b) MORV = -5.2917 + 2.1741x(dxvp5) - 2.6595x(dxvp8) + 0.45297x(e I C2C2d) -0.6202x(c1C202) + 1.3542x(CdCH2) + 0.68105x(CaasC) + 1.7129x(idcbar) c) MORV = -0.0035 + 0.8028x(SHCsatu) + 2.1673x(xvp7) - 1.3507x(c 1 C1C3d) +
0.61496x(c1C102) + 0.00403x(idc) - 0.23286x(nd2).
d) MORV = -0.9926 - 0.03882x(Sd0) + 0.1869x(Ssp3OH) + 2.1847x(xp7) +
0.34344x(e1C302) - 0.45767x(c1C2C3) + 0.7684x(CKetone) Equation a) is for the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors) Equation b) is for the malodor trimethylamine (amine based malodors) Equation c) is for the malodor 3-mercapto-3-methylhexan-l-ol (thiol based malodors) Equation d) is for the malodor skatole (indole based malodors) 3.) For purpose of the present application, a material's MORV is the highest MORV value from equations 2.)a) through 2.)d).
4.) If all MORV values from equations 2.)a) through 2.)d) above are greater than 0.5, the subject material has a Universal MORV.
EXAMPLE 1: Malodor reduction composition comprising entirely non-perfume materials MRC A MRC B MRC C MRC MRC E
Ingredient CAS #
Percent Percent Percent Percent Percent (E)-1,1,4,4-tetramethoxybut-2-ene 6068-62-8 38.500 0.00 48.00 48.00 0.00 1,2,3,4,5,6-hexamethylbenzene 87-85-4 19.500 0.00 0.00 23.50 23.50 dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate 37031-29-1 4.000 10.00 5.00 5.00 6.00 3,5-Dimethyladamantane-1-carboxylic acid 14670-94-1 19.000 45.00 23.50 23.50 23.50 (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene-l-carboxylic acid 88335-93-7 19.000 45.00 23.50 0.00 23.50 dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate 4841-84-3 0.000 0.00 0.00 0.00 23.50 Total 100.00 100.00 100.00 100.00 100.00 EXAMPLE 2: Malodor reduction composition comprising non-perfume and perfume materials functioning as malodor reduction materials such as those disclosed in patent application serial number 14/864,927, Frankenbach et al.
MRC MRC MRC MRC MRC
Ingredient CAS #
Percent Percent Percent Percent Percent (E)- I ,1,4,4-tetramethoxybut-2-ene 6068-62-8 38.500 0.00 48.00 48.00 20.00 1,2,3,4,5,6-hexamethylbenzene 87-85-4 19.500 0.00 0.00 23.50 14.00 dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate 37031-29-1 4.000 10.00 0 5.00 9.00 3,5-Dimethyladamantane-1-carboxylic acid 14670-94-1 9.00 45.00 23.50 3.00 23.50 (1R,6S)-6-(methoxycarbonyl)cyclohex-3-ene- l -carboxylic acid 88335-93-7 19.000 0.00 23.50 0.00 0.00 dimethyl (1R,2S)-cyclohex-4-ene-0.00 1,2-dicarboxylate 4841-84-3 0.000 0.00 0.00 0.00 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethy1-2H-2,4alpha-methanophthalen-8(5H)-one 23787-90-8 10.000 0. 000 0. 000 7.00 14.00 (E)-3,7-dimethylocta-2,6-dien-l-y1 palmitate 3681-73-0 0. 000 45.00 0. 000 0.
000 0. 000 3-(6,6-dimethylbicyclol3.1.1lhept-2-en-2-y1)-2,2-dimethylpropanal 33885-52-8 0. 000 0.000 5.00 0. 000 0. 000 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol 139504-68-0 0.000 0.000 0.000 13.50 10.00 (R,Z)-1-(2,6,6-trimethylcyclohex-2-en-l-yl)pent-l-en-3-one 127-42-4 0. 000 0. 000 0. 000 0.
000 9.50 Total 100.00 100.00 100.00 100.00 100.00 The term "air refresher" or "air freshener", as used herein, refer to any suitable composition that reduces odors in air, and/or reduces the impression of odors in the air by masking, layering or including malodor counteractant perfume raw materials into the composition.
Example 2.1-2.3: Energized Air Refresher An energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example Example Example 2.1 2.2 2.3 Perfume composition 40-60 50-60 30-50 Malodor reducing composition 10-20 15-30 10-25 Functional Perfume Component 30-50 10-30 25-60 Use of Functional Perfume Components at the recited levels may help modulate the evaporation profile of an entire perfume composition to provide perfume character consistency over the intended usage period.
Suitable FPCs may be highly volatile, low boiling, perfume ingredients. Non-limiting, suitable FPCs include iso-nonyl acetate, dihydro myrcenol (3 -methylene-7-methyloctan-7-ol), linalool (3-hydroxy-3,7-dimethy1-1,6 octadiene), geraniol (3,7 dimethy1-2,6-octadien-l-ol), d-limonene,1 -methyl-4-isopropeny1-1-cyclohexene, benzyl acetate, isopropyl mystristate, and combinations thereof.
Functional Perfume Component Examples 2.1-2.3 Example Al Example A2 Example A3 Benzyl alcohol 10-50 0-50 0-20 Iso nonyl acetate 1-20 1-10 1-10 Dipropylene glycol methyl ether 40-70 5-65 2-50 An energized air freshening device is filled with the composition above. The resulting air freshener is effective at reducing malodor.
Examples 3.1-3.3 - Non-Energized Air Freshener A non-energized air refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example I.
Example Example Example 3.1 3.2 3.3 Perfume composition 20-30 20-50 10-30 Malodor reducing composition 10-20 10-20 20-50 Functional Perfume components 0-70 40-70 20-70 Functional Perfume components Example 1 Example 2 Example 3 3a,4,5,6,7,7a-hexahydro-1H-4,7- 15-25 20-25 0-20 methanoinden-l-yl propanoate Iso nonyl acetate 30-75 15-75 1-10 2-isobuty1-4-hydroxy-4-methyltetrahydropyran 20-30 5-65 2-50 A non-energized air freshener is filled with the example composition above.
The resulting air freshener is effective at reducing malodor.
Examples 4.1-4.2 - Fabric and Air Refresher Composition A fabric refresher composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 4.3 Ingredient Example 4.1 Example 4.2 (ranges) Deionized Water Balance Balance Balance Ethanol 3.0 3.0 1-5.0%
Lupasol HF+ 0.0650 0.0650 0-0.1%
Diethylene Glycol 0.175 0.175 0-0.2%
Silwet L-7600 0.1 0.100 0-0.2 Maleic Acid and/or Citric Acid 0.05 0.05 0-0.2 Koralone B-119 0.015 0.015 0-0.1 Hydroxypropyl 13-cyclodextrin 0.630 0.630 0-2.0%
Sodium Hydroxide 0.003 0.003 0.001-0.01 Fragrance 0 0.4% 0-1.0%
Malodor Reduction Composition 0-0.1 %
(MRC A, B, C, D, E, F, G, H, J, 0.03% 0.04%
K) Total 100.000 100.000 100.000 Lupasol HF Polyethyleneimine (available from BASF) Silwet L-7600 Organosilicone (available from BASF) Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical) The resulting Fabric fresher composition is effective at reducing or preventing malodor when sprayed on fabrics, such as articles of clothing or upholstery.
Example 5.1-5.2 - Aerosol Air Freshener Composition An aerosol air freshener composition is prepared with malodor reduction composition, according to the compositions shown in Example I.
Ingredient Example 5.1 Example 5.2 Water Purified USP Balance 92.370 Ethyl Alcohol 5.000 5.000 Acid Polyacrylic 0.185 Sodium Citrate,Dihydrate 0.100 Acid Citric Solution 50% 0.100 Sodium Dicoctyl Sulfosuccinate 0-0.200 Silwet L-7600 0 - 0.2 0.200 Hydrogenated Castor Oil PEG 60 1.400 1.400 Fragrance 0- 1.5% 0 ¨ 1.5%
Malodor Reduction Composition (MRC A, B, C, D, E, F, G, H, J, or K) 1.0 0¨ 1.50%
Hydroxypropyl BetaCyclodextrine 0.380 0.380 Koralone B-119 0.050 0.050 Sodium Hydroxide 20% 0 - 0.3 Total 100 100 Silwet L-7600 Organosilicone (available from BASF) Koralone B-119 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water (available from Dow Chemical) A resulting aerosol air freshener is effective at reducing malodor in the air when sprayed. In addition, the aerosol can be sprayed on fabrics to reduce or prevent malodor.
Examples 6.1-6.4 - Heavy Duty Liquid Composition A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 6.1 Example 6.2 Example 6.3 Example 6.4 WT%WT%
Ingredient WT% Active WT% Active Active Active AE1.8S 16.3 16.3 12 8 CI 1 ,8 linear alkyl benzene 2.8 2.8 8 sulfonic acid HSAS 13.6 13.6 0 22 C24 alcohol, E09 2.2 2.2 1 1.8 Citric Acid 0.9 0.9 2 1.7 Lactic Acid 5.8 C12-Cis Fatty Acid 2.3 1.3 0.8 3.0 Protease (55.3 mg/g) 1.7 1.7 1.7 1.7 Amylase (25.4mg/g) 0.7 0.7 0.7 0.7 Borax 3.6 3.6 3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2 Polyethyleneimine 600, E020 1.6 1.6 --- 1.6 Polyethyleneimine 600, 1.6 --- 2.0 1.6 E024, P016 ' DTPA 0.3 0.3 0.3 0.3 Tiron 0.8 0.8 0.8 0.8 Optical Brightener 171 0.3 0.3 0.3 0.3 NaOH 4.0 9.3 4.0 9.3 Na Cumene Sulfonate 1.1 1.1 1.1 1.1 Na Formate 0.2 0.2 0.2 0.2 Aesthetics Dye 0.03 - 1.0 0.03 - 1.0 0.03 - 1.0 0.03 -1.0 Perfume 0.5 - 3.0 0.5 - 3.0 0.5 - 3.0 0.5 - 3.0 Malodor Reduction Composition (MRC A, B, C, D, E, F, G, H, J, or K) 0.15-1.0 0.15-1.0 0.15-1.0 0.15-1.0 Water and Solvent Balance Balance Balance Balance pH 5.0 8.0 5.0 8.0 HSAS secondary alkyl sulfate, acid form DTPA diethylene triamine pentaacetic acid (DTPA) Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 7.1-7.3 - Heavy Duty Liquid Composition Other examples of HDL-Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 7.1 Example 7.2 Example 7.33 Ingredient WT% Active WT%
Active WT% Active AE1.8S 14% 8% 11%
Amine Oxide 2%
C11.8 linear alkyl benzene sulfonic --- ---
10%
acid HSAS 20% 15 HF LAS
C24 alcohol, E09 1% 2% 1.2%
Citric Acid 3% 1.5% 0.9%
C12-CI8 Fatty Acid 2% 1% 1.5%
Protease (55.3 mg/g) 0.013 0.8 0.013 Amylase (25.4mg/g) 0.02 0.7 0.02 Borax 2 - 8.0 2 - 8.0 2- 8.0 Calcium Formate 0.2 0.2 0.2 Carezyme 5.0L 0.01 -0.5 0.01 -0.5 Polyethyleneimine 600, E020 0.5 - 3.0 0.5 - 3.0 0.5 - 3.0 Polyethyleneimine 600, E024, P016 0.5 -3.0 0.5 -3.0 DTPA 0.1 - 1.0 0.1 - 1.0 0.1 - 1.0 Tiron 0.1 - 1.5 0.1 - 1.5 0.1 - 1.5 Optical Brightener 0.1 - 1.0 0.1 - 1.0 0.1 - 1.0 MEA- Hydrogenated Castor Oil 0.5 - 3.0 NaOH 0.1 -1.0 0.1-1.0 Na Cumene Sulfonate 1.1 Na Formate 0.2 0.2 Dye 0.1 0.1 Malodor Reduction Composition (MRC A, B, C, D, E, F, G, H, J, or K) 0.15-1.0 0.15-1.0 0.15-1.0 Perfume 0.9 0.5 - 3 Water and Solvent Balance Balance Balance HSAS secondary alkyl sulfate, acid form DTPA diethylene triatnine pentaacetic acid (DTPA) Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 8.1-8.6 - Soluble Uni-dose Heavy Duty Liquid Composition An example for a Soluble Uni-dose heavy duty liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
8.1 8.2 8.3 8.4 8.5 3 compartments pouched product 8.6 Form liquid liquid liquid liquid gel liq liq liq Compartment # 1 1 1 1 1 1 2 3 Dosage (g) 36.0 38.0 32.0 36.0 40.0 34.0 25 Alkylbenzene 14.5 13.8 16.0 14.5 13.5 14.5 20.0 sulfonic acid C12-14 alkyl 8.5 16.4 10.0 8.5 15.0 8.5 ethoxy 3 sulfate C12-13 alkyl 3- 13.0 ethoxylate C12_14 alkyl 7- 12.5 9.0 14.0 4.0 12.5 17.0 ethoxylate C12-18 Fatty acid 14.5 8.5 16.0 15.0 7.2 14.5 13.0 Citric acid 2.0 4.1 Enzymes 0-3 0-3 0-3 0-3 0-3 0-3 PAP granule 50.0 Ethoxysulfated 3.0 2.2 Hexamethylene Diamine Dimethyl Quat Ethoxylated 4.0 1.0 4.0 3.0 2.0 Polyethylenimine Hydroxyethane 1.0 1.0 1.6 0.6 0.6 diphosphonic acid Ethylene diamine 1.0 tetra(methylene phosphonic) acid Brightener 0.2 0.2 0.3 0.3 0.2 0.2 0.2 Polydimethyl 3.0 Siloxane Hueing dye 2 0.05 Perfume 1.5- 1.5- 1.5- 1.5- 1.5- 1.5-2.0 2.0 2.0 2.0 2.0 2.0 Malodor 0.3- - 0.3- 0.3- 0.3- 0.3- 0.3-Reduction 0.7 0.7 0.7 0.7 0.7 0.7 Composition (MRC A, B, C, D, E, F, G, H, J, or K) Water and minors To 100%
Buffers (sodium To pH 8.0 carbonate, monoethanolamine) Solvents (1,2 To 100%
propanediol, ethanol), Sulfate 1 PAP granule 2 Hueing dye The resulting Unidose pouch product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 9.1-9.5 - Fabric Enhancer Solid Particle or Bead Composition An example of a Fabric Enhancer bead composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 9.1 Example Example Example 9.4 Example 9.5 9.2 9.3 Ingredients Active Wt% Active Active Active Wt% Active Wt%
Wt% Wt%
PEG 8000 86.21 83.255 83.255 86.21 82.49 Free (Neat) 4.41 5.88 4.41 4.25 5.88 Perfume MRC 0.75-1.5 0.75-1.5 0.75-1.5 0.75-1.5 0.75-1.5 Perfume Micro 5.88 8.22 8.88 5.88 8.70 Capsule (PMC) Encapsulated 1.88 1.88 1.88 1.88 1.88 Perfume Malodor 1.47 --- 1.47 1.63 ---Reducing Composition Encapsulated --- 0.75 0.75 --- 0.9 Malodor Reducing Composition Aesthetics Dye 0.015 0.015 0.015 0.015 0.015 1. PMC is a friable PMC with a urea-formaldehyde shell from Appvion-Encapsys.
About 50% water by weight of the PMC (including encapsulated perfume) is assumed.
2. Encapsulated perfume (within PMC) assumes about 32% active The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.
Examples 10.1-10.4 - Dryer Added Fabric Softener Sheet Composition An example of a dryer added fabric softener sheet composition prepared with malodor reduction composition, according to the compositions shown in Example I.
Example 10.1 Example 10.2 Example 10.3 Example 10.4 Ingredient Wt% Active Wt% Active Wt% Active Wt% Active TPED' --- 3 --- ---Complex9 16.5 16.5 --- 8.0 Claym 3 4 --- 3 Free (Neat) Perfume 1.5 1.5 --- I .5 Free (Neat) malodor reducing 0.5 0.5 0.5 ---composition Encapsulated --- --- --- 1.56 Perfume/malodor reducing composition 11 Encapsulated Perfume' 2 --- 0.4 ---Encapsulated malodor --- --- --- 0.5 reducing composition Active Weight 2.4 2.4 1.9 2.4 (g/sheet) (1) DEQA1: Di(soft tallowoyloxyethyl)dimethylammonium methyl sulfate with 25%>
7018 FA, as described below, as solvent (2) DEQA2: Di(soft tallowoyloxyethyl)hydroxyethylmethylammoniun methyl sulfate with 18%
partially hydrogenated tallow fatty acid solvent (3) DTDMAMS: Di(hydrogenated tallowalkyl)dimethylammonium methyl sulfate (4) 7018FA: 70:30 Stearic Acid:Palmitic Acid (IV=0) Industrene 7018 sold by Witco (5) TS-20: Polyoxyethylene-20 Sorbitan Tristearate (Glycosperse TS-20, sold by Lonza (6) SMS: Sorbitan Mono Stearate (7) SDASA: 1 :2 ratio of stearyl dimethyl amine: triple pressed stearic acid (8) TPED: N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediamine (Quadrol, sold by BASF) (9) Complex: Beta-Cyclodextrin/Perfume Complex (10) Clay: Calcium Bentonite Clay (Bentonite L sold by Southern Clay Products Free (Neat) Perfume
acid HSAS 20% 15 HF LAS
C24 alcohol, E09 1% 2% 1.2%
Citric Acid 3% 1.5% 0.9%
C12-CI8 Fatty Acid 2% 1% 1.5%
Protease (55.3 mg/g) 0.013 0.8 0.013 Amylase (25.4mg/g) 0.02 0.7 0.02 Borax 2 - 8.0 2 - 8.0 2- 8.0 Calcium Formate 0.2 0.2 0.2 Carezyme 5.0L 0.01 -0.5 0.01 -0.5 Polyethyleneimine 600, E020 0.5 - 3.0 0.5 - 3.0 0.5 - 3.0 Polyethyleneimine 600, E024, P016 0.5 -3.0 0.5 -3.0 DTPA 0.1 - 1.0 0.1 - 1.0 0.1 - 1.0 Tiron 0.1 - 1.5 0.1 - 1.5 0.1 - 1.5 Optical Brightener 0.1 - 1.0 0.1 - 1.0 0.1 - 1.0 MEA- Hydrogenated Castor Oil 0.5 - 3.0 NaOH 0.1 -1.0 0.1-1.0 Na Cumene Sulfonate 1.1 Na Formate 0.2 0.2 Dye 0.1 0.1 Malodor Reduction Composition (MRC A, B, C, D, E, F, G, H, J, or K) 0.15-1.0 0.15-1.0 0.15-1.0 Perfume 0.9 0.5 - 3 Water and Solvent Balance Balance Balance HSAS secondary alkyl sulfate, acid form DTPA diethylene triatnine pentaacetic acid (DTPA) Tiron 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 8.1-8.6 - Soluble Uni-dose Heavy Duty Liquid Composition An example for a Soluble Uni-dose heavy duty liquid composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
8.1 8.2 8.3 8.4 8.5 3 compartments pouched product 8.6 Form liquid liquid liquid liquid gel liq liq liq Compartment # 1 1 1 1 1 1 2 3 Dosage (g) 36.0 38.0 32.0 36.0 40.0 34.0 25 Alkylbenzene 14.5 13.8 16.0 14.5 13.5 14.5 20.0 sulfonic acid C12-14 alkyl 8.5 16.4 10.0 8.5 15.0 8.5 ethoxy 3 sulfate C12-13 alkyl 3- 13.0 ethoxylate C12_14 alkyl 7- 12.5 9.0 14.0 4.0 12.5 17.0 ethoxylate C12-18 Fatty acid 14.5 8.5 16.0 15.0 7.2 14.5 13.0 Citric acid 2.0 4.1 Enzymes 0-3 0-3 0-3 0-3 0-3 0-3 PAP granule 50.0 Ethoxysulfated 3.0 2.2 Hexamethylene Diamine Dimethyl Quat Ethoxylated 4.0 1.0 4.0 3.0 2.0 Polyethylenimine Hydroxyethane 1.0 1.0 1.6 0.6 0.6 diphosphonic acid Ethylene diamine 1.0 tetra(methylene phosphonic) acid Brightener 0.2 0.2 0.3 0.3 0.2 0.2 0.2 Polydimethyl 3.0 Siloxane Hueing dye 2 0.05 Perfume 1.5- 1.5- 1.5- 1.5- 1.5- 1.5-2.0 2.0 2.0 2.0 2.0 2.0 Malodor 0.3- - 0.3- 0.3- 0.3- 0.3- 0.3-Reduction 0.7 0.7 0.7 0.7 0.7 0.7 Composition (MRC A, B, C, D, E, F, G, H, J, or K) Water and minors To 100%
Buffers (sodium To pH 8.0 carbonate, monoethanolamine) Solvents (1,2 To 100%
propanediol, ethanol), Sulfate 1 PAP granule 2 Hueing dye The resulting Unidose pouch product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 9.1-9.5 - Fabric Enhancer Solid Particle or Bead Composition An example of a Fabric Enhancer bead composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 9.1 Example Example Example 9.4 Example 9.5 9.2 9.3 Ingredients Active Wt% Active Active Active Wt% Active Wt%
Wt% Wt%
PEG 8000 86.21 83.255 83.255 86.21 82.49 Free (Neat) 4.41 5.88 4.41 4.25 5.88 Perfume MRC 0.75-1.5 0.75-1.5 0.75-1.5 0.75-1.5 0.75-1.5 Perfume Micro 5.88 8.22 8.88 5.88 8.70 Capsule (PMC) Encapsulated 1.88 1.88 1.88 1.88 1.88 Perfume Malodor 1.47 --- 1.47 1.63 ---Reducing Composition Encapsulated --- 0.75 0.75 --- 0.9 Malodor Reducing Composition Aesthetics Dye 0.015 0.015 0.015 0.015 0.015 1. PMC is a friable PMC with a urea-formaldehyde shell from Appvion-Encapsys.
About 50% water by weight of the PMC (including encapsulated perfume) is assumed.
2. Encapsulated perfume (within PMC) assumes about 32% active The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.
Examples 10.1-10.4 - Dryer Added Fabric Softener Sheet Composition An example of a dryer added fabric softener sheet composition prepared with malodor reduction composition, according to the compositions shown in Example I.
Example 10.1 Example 10.2 Example 10.3 Example 10.4 Ingredient Wt% Active Wt% Active Wt% Active Wt% Active TPED' --- 3 --- ---Complex9 16.5 16.5 --- 8.0 Claym 3 4 --- 3 Free (Neat) Perfume 1.5 1.5 --- I .5 Free (Neat) malodor reducing 0.5 0.5 0.5 ---composition Encapsulated --- --- --- 1.56 Perfume/malodor reducing composition 11 Encapsulated Perfume' 2 --- 0.4 ---Encapsulated malodor --- --- --- 0.5 reducing composition Active Weight 2.4 2.4 1.9 2.4 (g/sheet) (1) DEQA1: Di(soft tallowoyloxyethyl)dimethylammonium methyl sulfate with 25%>
7018 FA, as described below, as solvent (2) DEQA2: Di(soft tallowoyloxyethyl)hydroxyethylmethylammoniun methyl sulfate with 18%
partially hydrogenated tallow fatty acid solvent (3) DTDMAMS: Di(hydrogenated tallowalkyl)dimethylammonium methyl sulfate (4) 7018FA: 70:30 Stearic Acid:Palmitic Acid (IV=0) Industrene 7018 sold by Witco (5) TS-20: Polyoxyethylene-20 Sorbitan Tristearate (Glycosperse TS-20, sold by Lonza (6) SMS: Sorbitan Mono Stearate (7) SDASA: 1 :2 ratio of stearyl dimethyl amine: triple pressed stearic acid (8) TPED: N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediamine (Quadrol, sold by BASF) (9) Complex: Beta-Cyclodextrin/Perfume Complex (10) Clay: Calcium Bentonite Clay (Bentonite L sold by Southern Clay Products Free (Neat) Perfume
(11) PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/ or blocker) is assumed.
(12) Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active The compositions of Example 10 are mixed homogeneously and impregnated onto a non- woven polyester sheet having dimensions of about 6% in x 12" (about 17.1 cm x 30.5 cm) and weighing about 1 gram.
The resulting dryer added fabric softener sheet product when added to an automatic dryer is effective at reducing malodor on the clothing.
Examples 11.1-11.4 ¨ Liquid Fabric Enhancer Composition An example of a Liquid Fabric Enhancer composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 11.1 Example 11.2 Example 11.3 Example 11.4 Wt% Active Wt% Active Wt% Active Wt%
Ingredient Active ESA' 12 21 18 14 Low MW alcohol 1.95 3.0 3.0 2.28 Structurant2,3 1.25e 0.2t Free (Neat) Perfume 1.50 1.8 2.0 1.50 Free (Neat) malodor reducing 0.3 0.7 composition Encapsulated Perfume' - 0.6 - 0.6 Encapsulated malodor reducing - 0.6 0.6 composition 4 Perfume/ malodor reducing 1.85 1.85 3.7 composition encapsulated5 Calcium Chloride 0.10 0.12 0.1 0.45 DTPA6 0.005 0.005 0.005 0.005 Preservative (ppm)7 5 5 5 5 Antifoam8 0.015 0.15 0.11 0.011 Polyethylene imines9 0.15 0.05 0.1 Delivery enhancing 0.1 0.1 0.2 0.05 PDMS emulsionw - 0.5 1 2.0 Dispersant" - 0.5 0.2 Organosiloxane 5 Front-end Stability Aid12'13 0.0611 0.6312 0.3611 0.1412 Dye (parts per million ppm) 40 11 30 40 Ammonium Chloride 0.10 Hydrochloric Acid 0.010 0.01 0.10 0.010 1Deioni zed Water Balance Balance Balance Balance i (1) N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
(2) Cationic high amylose maize starch-available from National Starch under the trade name HYLON VII a (3) Cationic polymer available from BASF under the name Rheovis CDE.
(4) Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active (5) PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/ or malodor reducing composition) is assumed.
(6) Diethylene triamine pentaacetic acid (7) 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water available from Dow Chemical under the trade name Koralone B-119 (8) Silicone antifoam agent available from Dow Corning under the trade name DC2310.
(9) Polyethylene imines available from BASF under the trade name Lupasol 0.
(10) Polydimethylsiloxane emulsion from Dow Corning 0 under the trade name DC346.
(11) Non-ionic such as TWEEN 20 TM or cationic surfactant as Berol 648 and Ethoquad @ C 25 from Akzo Nobel.
(12) Organosiloxane polymer condensate made by reacting hexamethylenediisocyanate (HDI), and a, w silicone diol and 1,3-propanediamine, N'-(3-(dimethylamino)propyI)-N,N-dimethyl-Jeffcat Z130) or N-(3-dimethylaminopropy1)-N,Ndiisopropanolamine (Jeffcat ZR50) commercially available from Wacker Silicones, Munich, Germany.
The resulting dryer added fabric softener sheet product when added to an automatic dryer is effective at reducing malodor on the clothing.
Examples 11.1-11.4 ¨ Liquid Fabric Enhancer Composition An example of a Liquid Fabric Enhancer composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 11.1 Example 11.2 Example 11.3 Example 11.4 Wt% Active Wt% Active Wt% Active Wt%
Ingredient Active ESA' 12 21 18 14 Low MW alcohol 1.95 3.0 3.0 2.28 Structurant2,3 1.25e 0.2t Free (Neat) Perfume 1.50 1.8 2.0 1.50 Free (Neat) malodor reducing 0.3 0.7 composition Encapsulated Perfume' - 0.6 - 0.6 Encapsulated malodor reducing - 0.6 0.6 composition 4 Perfume/ malodor reducing 1.85 1.85 3.7 composition encapsulated5 Calcium Chloride 0.10 0.12 0.1 0.45 DTPA6 0.005 0.005 0.005 0.005 Preservative (ppm)7 5 5 5 5 Antifoam8 0.015 0.15 0.11 0.011 Polyethylene imines9 0.15 0.05 0.1 Delivery enhancing 0.1 0.1 0.2 0.05 PDMS emulsionw - 0.5 1 2.0 Dispersant" - 0.5 0.2 Organosiloxane 5 Front-end Stability Aid12'13 0.0611 0.6312 0.3611 0.1412 Dye (parts per million ppm) 40 11 30 40 Ammonium Chloride 0.10 Hydrochloric Acid 0.010 0.01 0.10 0.010 1Deioni zed Water Balance Balance Balance Balance i (1) N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
(2) Cationic high amylose maize starch-available from National Starch under the trade name HYLON VII a (3) Cationic polymer available from BASF under the name Rheovis CDE.
(4) Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active (5) PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/ or malodor reducing composition) is assumed.
(6) Diethylene triamine pentaacetic acid (7) 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water available from Dow Chemical under the trade name Koralone B-119 (8) Silicone antifoam agent available from Dow Corning under the trade name DC2310.
(9) Polyethylene imines available from BASF under the trade name Lupasol 0.
(10) Polydimethylsiloxane emulsion from Dow Corning 0 under the trade name DC346.
(11) Non-ionic such as TWEEN 20 TM or cationic surfactant as Berol 648 and Ethoquad @ C 25 from Akzo Nobel.
(12) Organosiloxane polymer condensate made by reacting hexamethylenediisocyanate (HDI), and a, w silicone diol and 1,3-propanediamine, N'-(3-(dimethylamino)propyI)-N,N-dimethyl-Jeffcat Z130) or N-(3-dimethylaminopropy1)-N,Ndiisopropanolamine (Jeffcat ZR50) commercially available from Wacker Silicones, Munich, Germany.
(13) Fineoxocol 0 180 from Nissan Chemical Co.
(14) Isofol @ 16 from Sasol.
**For example PGE
Examples 11.1 to 11.4 are made by combining the molten fabric softener active with the front-end stability agent to form a first mixture. This first mixture is combined with water and hydrochloric acid using a high shear mixing device to form a second mixture.
The adjunct ingredients are combined with the second mixture using low shear mixing to form the fabric enhancing formula.
Examples 11.1 through 11.4 are used by dosing 10 to 60 g of the formula into the rinse liquor for example via dispensing into a clothes washing machine. Clothes are dried on a line or in an automated clothes dryer. The fabrics treated with these formulas have improved feel and scent and are effective at reducing malodor on the clothing.
Example 12.1-12.2 ¨ Spray-Dried Laundry Detergent Powder composition and Process of Making it An example of a Spray-Dried Laundry Detergent Powder composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Compositions Slurry 12.1 Dried Slurry Dried Powder 12.2 Powder 12.1 12.2 w/w% w/w(7o wlw% wlw% _ Linear alkyl benzene sulfonate 10.6 15.8 21.3 35.7 Acrylate/ maleate copolymer 4.6 6.8 9.4 14.2 Ethylenediame disuccinic acid and /or 1.4 2.1 1.7 2.9 Hydroxyethane dimethylene phosphonic acid Sodium carbonate 19.4 26.5 18.8 29.9 Sodium sulfate 28.6 42.4 Carboxy methyl cellulose polymer 4.3 7.1 Miscellaneous, such as magnesium 1.4 2.2 2.5 4.2 sulfate, brightener and one or more stabilizers Free (Neat) Perfume (spray-on) 1.7 2.4 Free (Neat) malodor reduction 0.5 0.6 composition (spray-on) Water __________________________________ 34.0 2.0 42.0 3.0 Preparation of Spray-Dried Laundry Detergent Powders.
Aqueous slurry12.1 having the composition as described above is prepared having a moisture content of 34.0%. Any ingredient added above in liquid form is heated to 70 C., such that the aqueous slurry is never at a temperature below 70 C. At the end of preparation, the aqueous slurry is heated to 80 C. and pumped under pressure (5x106Nm-2), into a counter current spray-drying tower with an air inlet temperature of from 290 C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder, which is free-flowing. Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder 12.1 has a moisture content of 2.0 wt %, a bulk density of 310 g/1 and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder 12.1 is listed in the table above.
Perfume and malodor reduction composition are sprayed onto the composition following the spray dry procedure.
Aqueous slurry 12.2 having the composition as described above is prepared having a moisture content of 42.0%. Any ingredient added above in liquid form is heated to 70 C., such that the aqueous slurry is never at a temperature below 70 C. At the end of preparation, the aqueous slurry is heated to 85 C. and pumped under pressure (from 6.5x106Nm-2), into a counter current spray-drying tower with an air inlet temperature of from 275 C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder 12.2, which is free-flowing.
Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder has a moisture content of 3.0 wt %, a bulk density of 250 g/1 and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder is given in the table above. Perfume and malodor reduction composition are sprayed onto the composition after the spray dry process.
Example 13: Plastic film Example with Malodor Reducing Composition A plastic film is treated with a Malodor Reduction Composition disclosed in the present specification. Said treatment is accomplished by spraying said Malodor Reduction Composition on the film. Said Malodor Reduction Composition is applied to at a level of 0.01% to 5% based on weight of the film. The Malodor Reduction Composition is found on the surface and may also be absorbed into the plastic film.
Example 14: Diaper example with Malodor reducing composition A diaper article, is treated with a Malodor Reduction Composition disclosed in the present specification. The Malodor Reduction Composition is disposed on one or more areas such as:
= the garment-facing side;
= the body-facing side of the topsheet;
= the absorbent core;
= the body-facing side of the backsheet.
The Malodor Reduction Composition may also be disposed on the garment-facing side of the absorbent core and/or on other components such as the garment facing side of a nonwoven dusting layer or body-facing side of a secondary topsheet or acquisition layer. In some embodiments, a topsheet or an acquisition layer may comprise a tissue layer and/or a nonwoven layer, and the malodor reduction composition may be disposed on either the tissue layer or the nonwoven layer. As discussed below, the Malodor Reduction Composition may be in the absorbent article via incorporation into an adhesive. In some embodiments, the Malodor Reduction Composition may be incorporated into the absorbent article via a lotion that is applied to a substrate component of the article. In some embodiments, the malodor reduction composition may be incorporated into the absorbent article via an elastomeric film. In some embodiments, the malodor reduction composition may be in an article by having been incorporated into the making of an article component, including, but not limited to, a film, a nonwoven, AGM, elastics, and/or ink.
Example 16.1-16.5 Deodorant example with Malodor reducing composition.
An example of Deodorant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
Ingredient 16.1 16.2 16.3 16.4 16.5 Product Form Solid Solid Solid Solid Aerosol Deodorant Deodorant Deodorant Deodorant Deodorant Control or Body Spray dipropylene glycol 48 48 20 30 20 propylene glycol 19.3 19.3 22 - -tripopylene glycol - - 25 - -Glycerine 1 - - - 10 -Propylene Glycol 3 1.4 1.4 - - -Myristyl Ether ethanol QS
Water QS QS QS QS
sodium stearate 5.4 5.4 5.5 5.5 -tetra sodium EDTA 0.5 0.5 0.05 0.05 -sodium hydroxide - - 0.04 0.04 -triclosan - - 0.3 0.3 Neat Perfume 2.8 2.8 2 1.5 1.5 Malodor reducing - 0.7 1.0 0.5 0.35 composition Blue 1 0.0009 0.0009 - - -Propellant (1,1 - - - - 40 difluoroethane) QS - Indicates that this material is used to bring the total to 100%.
Examples 17.1-17.3: Body wash with Malodor reducing composition An example of Body Wash compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
17.1 17.2 17.3 Body Wash Body Wash Body Wash Sodium Laureth-3 Sulfate (as 28% 27.85% 27.85% 27.85%
active) Water Q.S. Q.S. Q.S.
Sodium Lauryl Sulfate (as 29% 10.34 10.34 10.34 active) Cocamidopropyl Betaine B (30% 4.01 4.01 4.01 active) 0.18 0.18 0.18 Citric Acid 0.3 0.3 0.3 Sodium Benzoate 0.12 0.12 0.12 Disodium EDTA
Methylchloroisothiazolinone/Methy 0.04 0.04 0.04 lisothiazolinone 2.35 1.7 1.6 Sodium Chloride 1.25 1 2 Neat Perfume 0.25 0.175 0.25 Malodor reducing composition QS - indicates that this material is used to bring the total to 100%.
Examples 18.1-18.6: Antiperspirant examples with Malodor reducing composition An example of Antiperspirant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
18.1 18.2 18.3 18.4 18.5 18.6 Invisible Invisible Invisible Soft Soft Soft Solid Solid Solid Solid Solid Solid Aluminum 24 24 24 26.5 26.5 26.5 Zirconium Trichlorohydrex Glycine Powder Cyclopentasiloxane Q.S Q.S. Q.S. Q.S. Q.S. Q.S.
_ _ _ 5 5 5 Dimethicone CO-1897 Stearyl 14 14 14 - - -Alcohol NF
Hydrogenated 3.85 3.85 3.85 - -Castor Oil MP80 Deodorized 0.2 0.2 0.2 - - -Behenyl Alcohol - - - 4.5 4.5 4.5 Tribehenin C 18 - 36 acid - - - 1.125 1.125 1.125 triglyceride Cl2-15 Alkyl 9.5 9.5 5 - - -Benzoate PPG-14 Butyl 6.5 6.5- 0.5 0.5 0.5 Ether Phenyl 3 - 3 - -Trimethicone 3 _ _ 3 3 3 White Petrolatum 1.0 1.0 1.0 - - -Mineral Oil Free (Neat) 1.0 0.75 2.0 0.75 1.0 1.25 Perfume Malodor reducing 0.25 - 0.35 0.175 0.25 0.1 composition Beta-Cyclodextrin - 3.0 - - - 3.0 complexed with Malodor reducing composition Talc Imperial 250 3.0 3.0 3.0 - - -USP
Polyacrylate - - 1.9 - -, Microcapsule loaded with Malodor reducing composition QS - Indicates that this material is used to bring the total to 100%.
Example 19.1-19.4: Dish cleansing composition examples with Malodor reducing composition An example of Dish cleaning compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
19.1 19.2 19.3 19.4 Alkyl C10-14 Ethoxy Sulphate 26.9 - 25.7 (AE0.6S) Alkyl CI o-14 Ethoxy Sulphate 18.7 26.9 (AE2S) Sodium alkyl benzene sulfonate 8.0 C12-14 dimethyl amine oxide 6.1 4.1 Cocamido propyl betaine 4.5 6.8 3.2 Branched Nonionic: 3-propyl 1.0 0.8 -heptanol E08 PEI600-E010-P07 block polymer 0.8 -Perfume 0.15-0.3 0.15-0.3 0.15-0.3 0.15-0.3 Malodor Reducing Composition 0.06-0.15 0.06-0.15 0.06-0.15 0.06-0.15 Ethanol 4.0 5.0 3.0 3.0 Polypropylene glycol MW2000 1.1 0.8 1.1 1.1 Sodium Chloride 1.3 0.8 1.3 0.5 Minors* and water to balance up to 100%
Examples 20.1-20.4 - Heavy Duty Liquid Composition A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 20.1 Example 20.2 Example 20.3 Example 20.4 Ingredient WT% Active WT% Active WT% Active WT% Active AE1.8S 16 16 12 8 C11.8 linear alkyl benzene sulfonic acid C24 alcohol, E09 2 2 1 2 Citric Acid 1 1 2 2 Lactic Acid 6 C12-C1 8 Fatty Acid 2 1 I 3 Protease (55.3 mg/g) 2 2 2 2 Amylase (25.4mg/g) 0.7 0.7 0.7 0.7 Borax 3.6 3.6 3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2 Polyethyleneimine 600, E020 1.6 1.6 1.6 Polyethyleneimine 600, 1.6 2.0 1.6 E024, P016 DTPA2 0.3 0.3 0.3 0.3 Tiron(D3 0.8 0.8 0.8 0.8 Optical Brightener 0.3 0.3 0.3 0.3 NaOH 4 9 4 9 Na Cumene Sulfonate 1 1 1 1 Na Formate 0.2 0.2 0.2 0.2 Aesthetics Dye 0.03 - 1 0.03 - 1 0.03 - 1 0.03 -Perfume 0.5 - 3 0.5 - 3 0.5 - 3 0.5 -Malodor Reducing Composition 0.1 - 1 0.1 - 1 0.1 - 1 0.1 - 1 Water and Solvent Balance Balance Balance Balance pH 5 8 5 8 The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 21.1-21.3 - Heavy Duty Liquid Composition Other examples of HDL-Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example I.
Example 21.1 Example 21.2 Example 21.3 Ingredient WT% Active WT%
Active WT% Active Amine Oxide 2 C11.8 linear alkyl benzene sulfonic ---10%
acid C24 alcohol, E09 I - 2 1 - 2 1 - 2 Citric Acid 0.5 - 3 0.5 - 3 0.5 - 3 C 12-C 18 Fatty Acid 1 - 2 1 - 2 1 - 2 Protease (55.3 mg/g) 0.013 -0.8 0.013 -0.8 0.013 -0.8 Amylase (25.4mg/g) 0.02 - 0.7 0.02 - 0.7 0.02 -0.7 Borax 2 - 8 2 - 8 2 - 8 Calcium Formate 0.2 0.2 0.2 Carezyme 5.0L 0.01 -0.5 0.01 -0.5 Polyethyleneimine 600, E020 0.5 - 3 0.5 - 3 0.5 - 3 Polyethyleneimine 600, E024, P016 0.5 -3 0.5 -3 DTPA2 0.1 - 1 0.1 - 1 0.1 - 1 Tiron 3 0.1 - 2 0.1 - 2 0.1 - 2 Optical Brightener 0.1 - 1 0.1 - 1 0.1 - 1 MEA - Hydrogenated Castor Oil 0.5 - 3 0.5 - 3 NaOH 0.1 - 1 0.1 - 1 0.1 - 1 Na Cumene Sulfonate 1.1 Na Formate 0.2 0.2 0.2 Dye 0.1 0.1 0.1 Malodor Reducing Composition 0.15-1.0 0.15-1.0 Encapsulated Malodor Reducing' 0.3 - 3 Perfume 0.5 - 2 0.5 - 2 Encapsulated Perfume' 1.5 - 3 Water and Solvent Balance Balance Balance I. HSAS is secondary alkyl sulfate, acid form 2. DTPA is diethylene triamine pentaacetic acid (DTPA) 3. Tiron is 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate 4. Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC
(including encapsulated perfume) is assumed.
The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 22.1-22.3 - Fabric Enhancer Solid Particle or Bead Composition An example of a Fabric Enhancer bead composition prepared with malodor reduction composition, according to the compositions shown in Example I.
Example 22.1 Example 22.2 Example 22.3 Ingredients Active Wt% Active Wt% Active Wt%
Free (Neat) Perfume 3.5-6 4-6 3-5 Malodor reducing composition 0.5-2 0.5-2 0.5-2 Encapsulated Perfume 1 0- 2 0- 2 2 -3 Encapsulated Malodor Reducing 0.5 -2 Composition Dipropylene Glycol 0 - 6 0 -5 0 - 4.5 Aesthetics Dye 0.015 0.015 0.015 1. Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC
(including encapsulated perfume) is assumed.
The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40 mm" is intended to mean "about 40 mm."
Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention.
Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
**For example PGE
Examples 11.1 to 11.4 are made by combining the molten fabric softener active with the front-end stability agent to form a first mixture. This first mixture is combined with water and hydrochloric acid using a high shear mixing device to form a second mixture.
The adjunct ingredients are combined with the second mixture using low shear mixing to form the fabric enhancing formula.
Examples 11.1 through 11.4 are used by dosing 10 to 60 g of the formula into the rinse liquor for example via dispensing into a clothes washing machine. Clothes are dried on a line or in an automated clothes dryer. The fabrics treated with these formulas have improved feel and scent and are effective at reducing malodor on the clothing.
Example 12.1-12.2 ¨ Spray-Dried Laundry Detergent Powder composition and Process of Making it An example of a Spray-Dried Laundry Detergent Powder composition prepared with malodor reduction composition, according to the compositions shown in Example 1.
Compositions Slurry 12.1 Dried Slurry Dried Powder 12.2 Powder 12.1 12.2 w/w% w/w(7o wlw% wlw% _ Linear alkyl benzene sulfonate 10.6 15.8 21.3 35.7 Acrylate/ maleate copolymer 4.6 6.8 9.4 14.2 Ethylenediame disuccinic acid and /or 1.4 2.1 1.7 2.9 Hydroxyethane dimethylene phosphonic acid Sodium carbonate 19.4 26.5 18.8 29.9 Sodium sulfate 28.6 42.4 Carboxy methyl cellulose polymer 4.3 7.1 Miscellaneous, such as magnesium 1.4 2.2 2.5 4.2 sulfate, brightener and one or more stabilizers Free (Neat) Perfume (spray-on) 1.7 2.4 Free (Neat) malodor reduction 0.5 0.6 composition (spray-on) Water __________________________________ 34.0 2.0 42.0 3.0 Preparation of Spray-Dried Laundry Detergent Powders.
Aqueous slurry12.1 having the composition as described above is prepared having a moisture content of 34.0%. Any ingredient added above in liquid form is heated to 70 C., such that the aqueous slurry is never at a temperature below 70 C. At the end of preparation, the aqueous slurry is heated to 80 C. and pumped under pressure (5x106Nm-2), into a counter current spray-drying tower with an air inlet temperature of from 290 C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder, which is free-flowing. Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder 12.1 has a moisture content of 2.0 wt %, a bulk density of 310 g/1 and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder 12.1 is listed in the table above.
Perfume and malodor reduction composition are sprayed onto the composition following the spray dry procedure.
Aqueous slurry 12.2 having the composition as described above is prepared having a moisture content of 42.0%. Any ingredient added above in liquid form is heated to 70 C., such that the aqueous slurry is never at a temperature below 70 C. At the end of preparation, the aqueous slurry is heated to 85 C. and pumped under pressure (from 6.5x106Nm-2), into a counter current spray-drying tower with an air inlet temperature of from 275 C. The aqueous slurry is atomized and the atomized slurry is dried to produce a solid mixture, which is then cooled and sieved to remove oversize material (>1.8 mm) to form a spray-dried powder 12.2, which is free-flowing.
Fine material (<0.15 mm) is elutriated with the exhaust the exhaust air in the spray-drying tower and collected in a post tower containment system. The spray-dried powder has a moisture content of 3.0 wt %, a bulk density of 250 g/1 and a particle size distribution such that greater than 90 wt % of the spray-dried powder has a particle size of from 150 to 710 micrometers. The composition of the spray-dried powder is given in the table above. Perfume and malodor reduction composition are sprayed onto the composition after the spray dry process.
Example 13: Plastic film Example with Malodor Reducing Composition A plastic film is treated with a Malodor Reduction Composition disclosed in the present specification. Said treatment is accomplished by spraying said Malodor Reduction Composition on the film. Said Malodor Reduction Composition is applied to at a level of 0.01% to 5% based on weight of the film. The Malodor Reduction Composition is found on the surface and may also be absorbed into the plastic film.
Example 14: Diaper example with Malodor reducing composition A diaper article, is treated with a Malodor Reduction Composition disclosed in the present specification. The Malodor Reduction Composition is disposed on one or more areas such as:
= the garment-facing side;
= the body-facing side of the topsheet;
= the absorbent core;
= the body-facing side of the backsheet.
The Malodor Reduction Composition may also be disposed on the garment-facing side of the absorbent core and/or on other components such as the garment facing side of a nonwoven dusting layer or body-facing side of a secondary topsheet or acquisition layer. In some embodiments, a topsheet or an acquisition layer may comprise a tissue layer and/or a nonwoven layer, and the malodor reduction composition may be disposed on either the tissue layer or the nonwoven layer. As discussed below, the Malodor Reduction Composition may be in the absorbent article via incorporation into an adhesive. In some embodiments, the Malodor Reduction Composition may be incorporated into the absorbent article via a lotion that is applied to a substrate component of the article. In some embodiments, the malodor reduction composition may be incorporated into the absorbent article via an elastomeric film. In some embodiments, the malodor reduction composition may be in an article by having been incorporated into the making of an article component, including, but not limited to, a film, a nonwoven, AGM, elastics, and/or ink.
Example 16.1-16.5 Deodorant example with Malodor reducing composition.
An example of Deodorant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
Ingredient 16.1 16.2 16.3 16.4 16.5 Product Form Solid Solid Solid Solid Aerosol Deodorant Deodorant Deodorant Deodorant Deodorant Control or Body Spray dipropylene glycol 48 48 20 30 20 propylene glycol 19.3 19.3 22 - -tripopylene glycol - - 25 - -Glycerine 1 - - - 10 -Propylene Glycol 3 1.4 1.4 - - -Myristyl Ether ethanol QS
Water QS QS QS QS
sodium stearate 5.4 5.4 5.5 5.5 -tetra sodium EDTA 0.5 0.5 0.05 0.05 -sodium hydroxide - - 0.04 0.04 -triclosan - - 0.3 0.3 Neat Perfume 2.8 2.8 2 1.5 1.5 Malodor reducing - 0.7 1.0 0.5 0.35 composition Blue 1 0.0009 0.0009 - - -Propellant (1,1 - - - - 40 difluoroethane) QS - Indicates that this material is used to bring the total to 100%.
Examples 17.1-17.3: Body wash with Malodor reducing composition An example of Body Wash compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
17.1 17.2 17.3 Body Wash Body Wash Body Wash Sodium Laureth-3 Sulfate (as 28% 27.85% 27.85% 27.85%
active) Water Q.S. Q.S. Q.S.
Sodium Lauryl Sulfate (as 29% 10.34 10.34 10.34 active) Cocamidopropyl Betaine B (30% 4.01 4.01 4.01 active) 0.18 0.18 0.18 Citric Acid 0.3 0.3 0.3 Sodium Benzoate 0.12 0.12 0.12 Disodium EDTA
Methylchloroisothiazolinone/Methy 0.04 0.04 0.04 lisothiazolinone 2.35 1.7 1.6 Sodium Chloride 1.25 1 2 Neat Perfume 0.25 0.175 0.25 Malodor reducing composition QS - indicates that this material is used to bring the total to 100%.
Examples 18.1-18.6: Antiperspirant examples with Malodor reducing composition An example of Antiperspirant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
18.1 18.2 18.3 18.4 18.5 18.6 Invisible Invisible Invisible Soft Soft Soft Solid Solid Solid Solid Solid Solid Aluminum 24 24 24 26.5 26.5 26.5 Zirconium Trichlorohydrex Glycine Powder Cyclopentasiloxane Q.S Q.S. Q.S. Q.S. Q.S. Q.S.
_ _ _ 5 5 5 Dimethicone CO-1897 Stearyl 14 14 14 - - -Alcohol NF
Hydrogenated 3.85 3.85 3.85 - -Castor Oil MP80 Deodorized 0.2 0.2 0.2 - - -Behenyl Alcohol - - - 4.5 4.5 4.5 Tribehenin C 18 - 36 acid - - - 1.125 1.125 1.125 triglyceride Cl2-15 Alkyl 9.5 9.5 5 - - -Benzoate PPG-14 Butyl 6.5 6.5- 0.5 0.5 0.5 Ether Phenyl 3 - 3 - -Trimethicone 3 _ _ 3 3 3 White Petrolatum 1.0 1.0 1.0 - - -Mineral Oil Free (Neat) 1.0 0.75 2.0 0.75 1.0 1.25 Perfume Malodor reducing 0.25 - 0.35 0.175 0.25 0.1 composition Beta-Cyclodextrin - 3.0 - - - 3.0 complexed with Malodor reducing composition Talc Imperial 250 3.0 3.0 3.0 - - -USP
Polyacrylate - - 1.9 - -, Microcapsule loaded with Malodor reducing composition QS - Indicates that this material is used to bring the total to 100%.
Example 19.1-19.4: Dish cleansing composition examples with Malodor reducing composition An example of Dish cleaning compositions prepared with malodor reduction composition, according to the compositions shown in Example 1.
19.1 19.2 19.3 19.4 Alkyl C10-14 Ethoxy Sulphate 26.9 - 25.7 (AE0.6S) Alkyl CI o-14 Ethoxy Sulphate 18.7 26.9 (AE2S) Sodium alkyl benzene sulfonate 8.0 C12-14 dimethyl amine oxide 6.1 4.1 Cocamido propyl betaine 4.5 6.8 3.2 Branched Nonionic: 3-propyl 1.0 0.8 -heptanol E08 PEI600-E010-P07 block polymer 0.8 -Perfume 0.15-0.3 0.15-0.3 0.15-0.3 0.15-0.3 Malodor Reducing Composition 0.06-0.15 0.06-0.15 0.06-0.15 0.06-0.15 Ethanol 4.0 5.0 3.0 3.0 Polypropylene glycol MW2000 1.1 0.8 1.1 1.1 Sodium Chloride 1.3 0.8 1.3 0.5 Minors* and water to balance up to 100%
Examples 20.1-20.4 - Heavy Duty Liquid Composition A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown in Example 1.
Example 20.1 Example 20.2 Example 20.3 Example 20.4 Ingredient WT% Active WT% Active WT% Active WT% Active AE1.8S 16 16 12 8 C11.8 linear alkyl benzene sulfonic acid C24 alcohol, E09 2 2 1 2 Citric Acid 1 1 2 2 Lactic Acid 6 C12-C1 8 Fatty Acid 2 1 I 3 Protease (55.3 mg/g) 2 2 2 2 Amylase (25.4mg/g) 0.7 0.7 0.7 0.7 Borax 3.6 3.6 3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2 Polyethyleneimine 600, E020 1.6 1.6 1.6 Polyethyleneimine 600, 1.6 2.0 1.6 E024, P016 DTPA2 0.3 0.3 0.3 0.3 Tiron(D3 0.8 0.8 0.8 0.8 Optical Brightener 0.3 0.3 0.3 0.3 NaOH 4 9 4 9 Na Cumene Sulfonate 1 1 1 1 Na Formate 0.2 0.2 0.2 0.2 Aesthetics Dye 0.03 - 1 0.03 - 1 0.03 - 1 0.03 -Perfume 0.5 - 3 0.5 - 3 0.5 - 3 0.5 -Malodor Reducing Composition 0.1 - 1 0.1 - 1 0.1 - 1 0.1 - 1 Water and Solvent Balance Balance Balance Balance pH 5 8 5 8 The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 21.1-21.3 - Heavy Duty Liquid Composition Other examples of HDL-Heavy Duty Liquid composition prepared with malodor reduction composition, according to the compositions shown in Example I.
Example 21.1 Example 21.2 Example 21.3 Ingredient WT% Active WT%
Active WT% Active Amine Oxide 2 C11.8 linear alkyl benzene sulfonic ---10%
acid C24 alcohol, E09 I - 2 1 - 2 1 - 2 Citric Acid 0.5 - 3 0.5 - 3 0.5 - 3 C 12-C 18 Fatty Acid 1 - 2 1 - 2 1 - 2 Protease (55.3 mg/g) 0.013 -0.8 0.013 -0.8 0.013 -0.8 Amylase (25.4mg/g) 0.02 - 0.7 0.02 - 0.7 0.02 -0.7 Borax 2 - 8 2 - 8 2 - 8 Calcium Formate 0.2 0.2 0.2 Carezyme 5.0L 0.01 -0.5 0.01 -0.5 Polyethyleneimine 600, E020 0.5 - 3 0.5 - 3 0.5 - 3 Polyethyleneimine 600, E024, P016 0.5 -3 0.5 -3 DTPA2 0.1 - 1 0.1 - 1 0.1 - 1 Tiron 3 0.1 - 2 0.1 - 2 0.1 - 2 Optical Brightener 0.1 - 1 0.1 - 1 0.1 - 1 MEA - Hydrogenated Castor Oil 0.5 - 3 0.5 - 3 NaOH 0.1 - 1 0.1 - 1 0.1 - 1 Na Cumene Sulfonate 1.1 Na Formate 0.2 0.2 0.2 Dye 0.1 0.1 0.1 Malodor Reducing Composition 0.15-1.0 0.15-1.0 Encapsulated Malodor Reducing' 0.3 - 3 Perfume 0.5 - 2 0.5 - 2 Encapsulated Perfume' 1.5 - 3 Water and Solvent Balance Balance Balance I. HSAS is secondary alkyl sulfate, acid form 2. DTPA is diethylene triamine pentaacetic acid (DTPA) 3. Tiron is 4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate 4. Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC
(including encapsulated perfume) is assumed.
The resulting heavy duty liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.
Examples 22.1-22.3 - Fabric Enhancer Solid Particle or Bead Composition An example of a Fabric Enhancer bead composition prepared with malodor reduction composition, according to the compositions shown in Example I.
Example 22.1 Example 22.2 Example 22.3 Ingredients Active Wt% Active Wt% Active Wt%
Free (Neat) Perfume 3.5-6 4-6 3-5 Malodor reducing composition 0.5-2 0.5-2 0.5-2 Encapsulated Perfume 1 0- 2 0- 2 2 -3 Encapsulated Malodor Reducing 0.5 -2 Composition Dipropylene Glycol 0 - 6 0 -5 0 - 4.5 Aesthetics Dye 0.015 0.015 0.015 1. Encapsulated perfume and encapsulated malodor reducing composition is a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC
(including encapsulated perfume) is assumed.
The resulting Fabric enhancing bead product when added to an automatic washing machine is effective at reducing malodor on the clothing.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40 mm" is intended to mean "about 40 mm."
Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention.
Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
Claims (6)
1. A composition comprising a malodor reduction material having an MORV of at least 0.5.
2. A composition comprising a malodor reduction material having a Universal MORV.
3. A composition according to Claim 1 comprising a malodor reduction material is selected from the group consisting of 3,5-dimethyladamantane-1-carboxylic acid; (1R,6S)-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid; (E)-1,1,4,4-tetramethoxybut-2-ene;
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof.
dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate; 1,2,3,4,5,6-hexamethylbenzene;
dimethyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate and mixtures thereof.
4. A composition comprising, based on total composition weight, from 0.0001% to 100% of a malodor reduction composition according to Claim 3 and mixtures thereof, and an adjunct material, said composition being a consumer product.
5. A plastic film said plastic film comprising LLDPE, LDPE, HDPE, and/or compostable film and a malodor reduction composition according to Claim 3 and mixtures thereof.
6. A method of controlling malodors comprising contacting a material comprising a malodor with a composition according to Claim 3 and mixtures thereof.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2972375A CA2972375A1 (en) | 2017-07-06 | 2017-07-06 | Malodor reduction compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2972375A CA2972375A1 (en) | 2017-07-06 | 2017-07-06 | Malodor reduction compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2972375A1 true CA2972375A1 (en) | 2017-09-12 |
Family
ID=60324251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2972375A Abandoned CA2972375A1 (en) | 2017-07-06 | 2017-07-06 | Malodor reduction compositions |
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CA (1) | CA2972375A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020057844A1 (en) | 2018-09-17 | 2020-03-26 | Unilever Plc | Composition |
WO2020057845A1 (en) | 2018-09-17 | 2020-03-26 | Unilever Plc | Composition |
WO2021250130A1 (en) * | 2020-06-10 | 2021-12-16 | Firmenich Sa | Prevention, reduction, or amelioration of old person smell |
WO2023213386A1 (en) * | 2022-05-04 | 2023-11-09 | Symrise Ag | A fragrance mixture (v) |
-
2017
- 2017-07-06 CA CA2972375A patent/CA2972375A1/en not_active Abandoned
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020057844A1 (en) | 2018-09-17 | 2020-03-26 | Unilever Plc | Composition |
WO2020057845A1 (en) | 2018-09-17 | 2020-03-26 | Unilever Plc | Composition |
WO2021250130A1 (en) * | 2020-06-10 | 2021-12-16 | Firmenich Sa | Prevention, reduction, or amelioration of old person smell |
WO2023213386A1 (en) * | 2022-05-04 | 2023-11-09 | Symrise Ag | A fragrance mixture (v) |
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