JP2003049077A - Filler-containing flame-retardant resin composition and manufacturing method therefor - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a flame-retardant resin composition low in the deterioration of flame retardancy and flame resisting performance with the laps of time in a thin-walled molded body, and to provide a method for manufacturing the same. SOLUTION: The flame-retardant resin composition comprises 100 pts.wt. of a thermoplastic resin (A), 0.01-40 pts.wt. of a flame retardant (B), 0.1-200 pts.wt. of a filter (C) and 0-10 pts.wt. of a coloring agent (D). The composition contains lubricants (E) of <=5,000 ppm by weight in total. The method for manufacturing the same is also provided.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a flame-retardant resin composition which is excellent in flame retardancy in a thin-walled molded product and has little change in flame retardance performance over time, and a method for producing the same. In particular, the present invention relates to a colored flame-retardant resin composition having excellent flame retardancy in a thin-walled molded product and having little change in flame retardance performance over time, and a method for producing the same.

[0002]

2. Description of the Related Art A flame-retardant resin material containing a flame-retardant agent in a thermoplastic resin is inexpensive, lightweight, and easy to mold and process. Therefore, it is used as a structural member for various electric and electronic devices requiring flame retardancy. For example, it is widely used as a housing material for computer monitors, notebook computers, printers, word processors, copiers and the like. Further, recent flame-retardant resin materials used in electric / electronic devices are strongly required to be lightweight, and high degree of flame-retardant property is being demanded even in a thin molded body.

The above flame-retardant resin material is usually used by being colored in various colors with various dyes and pigments (colorants). Generally, the flame-retardant resin material has a lower flame-retardant performance as it becomes a thinner molded body. Further, the flame-retardant performance may be further deteriorated by coloring the flame-retardant resin material.

In recent years, in particular, flame-retardant resin materials using a non-bromine / non-chlorine flame retardant have been attracting attention due to increasing awareness of environmental protection. When a typical organophosphorus compound or organopolysiloxane is used as a flame retardant, these flame retardants tend to have inferior flame retardant effects as compared with the case where a conventionally used bromine / chlorine flame retardant is used. is there. Therefore, the flame-retardant performance is generally insufficient in response to a strong demand for thin-walled molded products.

Incidentally, the flame-retardant resin material usually contains various "lubricants". The term "lubricant" used in the present specification improves processing lubricity of a resin, dispersibility of a dye / pigment as a colorant of a resin, and further, releasability of a molded product from a mold. Compounds having an effect, which are generally referred to as “lubricant”, “processing aid”, “dispersant”, “release agent”, “spreading agent”, etc., are included, and aliphatic hydrocarbons, polyolefins A compound selected from the group of compounds such as a wax, a higher carboxylic acid, a higher carboxylic acid metal salt, a fatty acid amide, a fatty acid ester, and a higher alcohol.

The above-mentioned lubricant may be already contained in the resin as the raw material, or may be added in the processing such as compounding and coloring of the resin. For example,
A flame-retardant resin material is often molded into various molded products by injection molding, but in injection molding, a lubricant (release agent) is added to the flame-retardant resin material in order to improve the mold release property of the molded product from the molding die. A mold agent) may be added. Furthermore, in the process of coloring the flame-retardant resin material with a colorant (mainly dye / pigment), a lubricant (colorant dispersant) is used for the purpose of enhancing the dispersibility of the colorant in the resin, or the resin pellet surface In some cases, a lubricant (spreading agent) is used to improve the spread of the colorant on the surface and improve the uniformity of the color tone.

In the flame-retardant resin material used as a molding material as described above, particularly in the colored flame-retardant resin material, the above-mentioned lubricant component is generally contained. The lubricant component contained in the flame-retardant resin material is generally contained in the flame-retardant resin material as a total amount thereof in the order of several thousand to several tens of thousands ppm by weight. Since the lubricant component is a minor component, the effect of these lubricant components on the flame retardancy of the flame-retardant resin material has not been studied so far.

Further, investigations for improving the flame-retardant performance of a flame-retardant resin composition by blending talc have been made, for example, in JP-A Nos. 11-199768 and 2000-2265.
No. 02, etc., no attempt has been made to further improve the flame retardant performance by the combined effect of reducing the amount of lubricant used in the flame retardant resin composition.

[0009]

DISCLOSURE OF THE INVENTION An object of the present invention is to provide a flame-retardant resin composition which is excellent in flame retardancy in a thin-walled molded product and has little change over time in flame-retardant performance, particularly in a thin-walled molded product. It is an object of the present invention to provide a colored flame-retardant resin composition having excellent flammability and having little change in flame-retardant performance over time, and a method for producing the same.

[0010]

The present inventors have found that a flame-retardant resin composition used as a flame-retardant resin material, especially a flame-retardant resin composition using a non-bromine / non-chlorine flame retardant. As a result of earnestly studying the improvement of flame retardancy in a thin molded product, a lubricant component contained in a trace amount in the resin composition has a great influence on the flame retardancy of the resin composition, and a trace amount contained in the resin composition. It was found that the above lubricant components cause a decrease in flame retardant performance over time.

Furthermore, it was further found that certain fillers used in the resin composition affect the flame retardancy of the resin composition in a thin-walled molded product, and, surprisingly, the flame retardant resin By controlling the total amount of lubricant components contained in the composition to a certain amount or less, and by using some kind of filler together in the composition, the flame retardant performance in a thin molded article can be remarkably improved, and the flame retardancy is further improved. The inventors of the present invention have found that the deterioration of the sex over time can be suppressed, and have arrived at the present invention.

That is, the present invention relates to [1] 100 parts by weight of a thermoplastic resin (A), 0.01 to 40 parts by weight of a flame retardant (B), 0.1 to 200 parts by weight of a filler (C), and a coloring agent ( D)
A flame-retardant resin composition containing 0 to 10 parts by weight, wherein the total amount of the lubricant (E) is 5,000 ppm by weight or less,

[2] The lubricant (E) is an aliphatic hydrocarbon, a polyolefin wax, a higher carboxylic acid, a higher carboxylic acid metal salt, a higher fatty acid amide, a higher fatty acid ester,
And a flame-retardant resin composition according to the above [1], which is a compound selected from higher alcohols, [3]
The flame-retardant resin composition according to the above [1] or [2], wherein the thermoplastic resin (A) is an aromatic polycarbonate resin or a resin mainly containing an aromatic polycarbonate resin,

[4] In the above [1] or [2], the thermoplastic resin (A) is 70 to 95 parts by weight of an aromatic polycarbonate resin and 30 to 5 parts by weight of a rubber-modified styrene resin. [5] The flame-retardant resin composition described in [5], wherein the thermoplastic resin (A) is a polyphenylene ether resin or a resin mainly composed of a polyphenylene ether resin. [1] or [2] Flame retardant resin composition, [6] flame retardant (B) is represented by the following formula (1)

[0015]

[Chemical 5] The flame-retardant resin composition according to any one of [1] to [5] above, which is at least one kind of organophosphorus compound oligomer selected from the group of compounds represented by The fuel (B) has the following formula (2)

[0016]

[Chemical 6] The flame-retardant resin composition according to any one of [1] to [5], which is an organopolysiloxane represented by:

[8] The filler (C) is talc, glass,
The flame-retardant resin composition according to any one of the above [1] to [7], which is selected from carbon fiber and mica, [9] further fluoropolymer (F) 0.05.
~ 2 parts by weight of the flame-retardant resin composition according to any one of [1] to [8],

[10] 100 parts by weight of thermoplastic resin (A), 0.01 to 40 parts by weight of flame retardant (B), filler (C)
A method for producing a flame-retardant resin composition containing 0.1 to 200 parts by weight and a colorant (D) of 0 to 10 parts by weight by a melt-kneading apparatus, wherein the total amount of the lubricant (E) is 5,000 ppm by weight.
The method for producing a flame-retardant resin composition, characterized in that [11] the lubricant (E) is an aliphatic hydrocarbon, a polyolefin wax, a higher carboxylic acid, a higher carboxylic acid metal salt, a fatty acid amide, a fatty acid A method for producing a flame-retardant resin composition according to the above [10], which is a compound selected from an ester and a higher alcohol.

[12] The thermoplastic resin (A) is an aromatic polycarbonate resin or a resin mainly containing an aromatic polycarbonate resin, [10].
Or a method for producing a flame-retardant resin composition according to [11],
[13] The thermoplastic resin (A) comprises 70 to 95 parts by weight of an aromatic polycarbonate resin and a rubber-modified styrene resin 30.
To 5 parts by weight, the method for producing a flame-retardant resin composition according to the above [10] or [11], [1
4] The method for producing a flame-retardant resin composition according to the above [10] or [11], wherein the thermoplastic resin (A) is a polyphenylene ether resin or a resin mainly composed of a polyphenylene ether resin, [15] The flame retardant (B) is represented by the following formula (1)

[0020]

[Chemical 7] [1] which is at least one kind of organophosphorus compound oligomer selected from the group of compounds represented by
0] to [14], the method for producing a flame-retardant resin composition according to any one of [16], wherein the flame retardant (B) has the following formula (2):

[0021]

[Chemical 8] The method for producing a flame-retardant resin composition according to any one of [10] to [14], which is an organopolysiloxane represented by

[17] The flame-retardant resin composition according to any one of the above [10] to [16], wherein the filler (C) is selected from talc, glass, carbon fiber and mica. Manufacturing method, [18] The above [10], which further comprises 0.05 to 2 parts by weight of the fluoropolymer (F).
[17] The method for producing a flame-retardant resin composition according to any one of [17], [19] wherein the melt-kneading device is a twin-screw extruder.
0] to [18], a method for producing a flame-retardant resin / fat composition,

[20] A molded product obtained by molding the flame-retardant resin composition according to any one of [1] to [9] above.
[21] The above-mentioned [2] wherein the molded product has a thickness of 2 mm or less in an amount of 30% by weight or more of the entire molded product.
[0]].

The present invention will be described in detail below. The component (A) of the composition of the present invention is a thermoplastic resin, for example, polystyrene resin, polyphenylene ether resin, polyolefin resin, polyvinyl chloride resin, polyamide resin, polyester resin, polyphenylene sulfide resin. Polycarbonate-based resin, polymethacrylate-based resin, etc., or a mixture of two or more thereof may be used.

In the present invention, as the component (A), an aromatic polycarbonate resin or a resin mainly containing an aromatic polycarbonate, or a polyphenylene ether resin or a resin mainly containing a polyphenylene ether resin can be preferably used. The aromatic polycarbonate resin which can be preferably used as the component (A) of the present invention has a main chain composed of a repeating unit represented by the following formula.

[0026]

[Chemical 9] (In the formula, Ar is a divalent aromatic residue, for example, phenylene, naphthylene, biphenylene, pyridylene,
Examples include those represented by the following formula. )

[0027]

[Chemical 10] (In the formula, Ar ¹ and Ar ² are each an arylene group. For example, a group such as phenylene, naphthylene, biphenylene, and pyridylene is represented, and Y is an alkylene group or a substituted alkylene group represented by the following formula.)

[0028]

[Chemical 11]

(In the formula, R ¹ , R ² , R ³ and R ⁴ are each independently a hydrogen atom, a C 1-6 lower alkyl group, a C 5-10 cycloalkyl group, a C 6-30 aryl group. , A C7-31 aralkyl group, which may be optionally substituted with a halogen atom or a C1-10 alkoxy group, k is an integer of 3-11, and R ⁵ and R ⁶
Are independently selected for each X and independently of each other a hydrogen atom, or a lower alkyl group having 1 to 6 carbon atoms, or a lower alkyl group having 6 to 6 carbon atoms.
A 30 aryl group, which may be optionally substituted with a halogen atom or an alkoxy group having 1 to 10 carbon atoms;
Represents a carbon atom. ) Further, a divalent aromatic residue represented by the following formula may be contained as a copolymer component.

[0030]

[Chemical 12] (In formula, Ar < ¹ >, Ar < ² > is the same as said Chemical formula 10. Z is a mere bond or -O-, -CO-, -S-, -SO.
_{2 -, - CO 2 -,} - CON (R 1) - (R 1 is as defined above formula) is a divalent group such as. ) Examples of these divalent aromatic residues include those represented by the following formula.

[0031]

[Chemical 13]

[0032]

[Chemical 14]

(In the formula, R ⁷ and R ⁸ are each independently
Hydrogen, halogen, C1-10 alkyl group, C1
It is a C-10 alkoxy group, a C5-C10 cycloalkyl group, or a C6-C30 aryl group. m and n are 1
In to 4 integer, m is may be different in each of R ⁷ is the same in the case of 2-4, there is n is different in each of the same each R ⁸ in the case of 2-4 May be. Among these, one represented by the following formula is a preferable example.

[0034]

[Chemical 15]

Particularly preferred is a polycarbonate containing 85 mol% or more (based on all the monomer units in the polycarbonate) of a repeating unit having Ar represented by the above formula as Ar. The polycarbonate that can be used in the present invention may have a branched structure having a trivalent or higher valent aromatic residue as a branch point. The molecular structure of the polymer terminal is not particularly limited, but one or more terminal groups selected from a phenol group, an aryl carbonate group and an alkyl carbonate group can be bonded. The aryl carbonate end group is represented by the following formula.

[0036]

[Chemical 16] (In the formula, Ar ³ is a monovalent aromatic residue, and the aromatic ring may be substituted.) Specific examples of the aryl carbonate terminal group include those represented by the following formula. .

[0037]

[Chemical 17] The alkyl carbonate end group is represented by the following formula.

[0038]

[Chemical 18] (In the formula, R ⁹ represents a linear or branched alkyl group having 1 to 20 carbon atoms.) Specific examples of the alkyl carbonate terminal group include those represented by the following formula.

[0039]

[Chemical 19]

Of these, a phenol group, a phenyl carbonate group, a pt-butylphenyl carbonate group, a p-cumylphenyl carbonate and the like are preferably used. In the present application, the ratio of the phenol group terminal to the other terminal is not particularly limited, but from the viewpoint of obtaining excellent mechanical strength and heat resistance stability, the ratio of the phenol group terminal is 20% or more of the total number of terminal groups. 20 to 20 are preferable.
It is more preferably in the range of 80%. When the ratio of the phenol end groups exceeds 80% of the total number of end groups, the thermal stability at the time of melting tends to be slightly lowered.

The phenol group terminal amount is generally measured by using NMR (NMR method), using titanium (titanium method), UV or IR.
Can be determined by a method of measuring (UV method or IR method).

The weight average molecular weight (Mw) of the polycarbonate resin preferably used in the present invention is generally 5,000.
It is preferably in the range of 0 to 50,000, more preferably 10,000 to 40,000, still more preferably 15,000 to 30,000, and particularly preferably 18,000 to 25,000. is there. 5,000
If it is less than 5, impact resistance tends to be insufficient, and if it is 5
If it exceeds 10,000, the melt fluidity tends to be insufficient.

The weight average molecular weight (Mw) of the polycarbonate resin preferably used in the present invention is measured by gel permeation chromatography (GPC).
The measurement conditions are as follows. That is, using tetrahydrofuran as a solvent and polystyrene gel, the conversion molecular weight calibration curve according to the following equation is used to determine from the constitutional curve of standard monodisperse polystyrene. ^{_{M PC = 0.3591M PS 1.0388 (M}} PC is the weight average molecular weight of the polycarbonate, M _PS weight average molecular weight of polystyrene)

The aromatic polycarbonate resin preferably used in the present invention may be one produced by a known method. Specifically, for example, a known method of reacting an aromatic dihydroxy compound and a carbonate precursor, for example, reacting an aromatic dihydroxy compound and a carbonate precursor (for example, phosgene) in the presence of an aqueous sodium hydroxide solution and a methylene chloride solvent. Interfacial polymerization method (eg phosgene method), aromatic dihydroxy compound and carbonic acid diester (eg diphenyl carbonate)
A solid-state polymerization of a crystallized carbonate prepolymer obtained by a transesterification method (melting method), a phosgene method or a melting method of reacting, for example (JP-A-1-15803).
3 (corresponding to U.S. Pat. No. 4,948,871), Japanese Unexamined Patent Publication No. 1-271426, Japanese Unexamined Patent Publication No. 3-6862.
7 (corresponding to US Pat. No. 5,204,377) and the like are used.

The preferred polycarbonate resin is
A polycarbonate resin containing substantially no chlorine atom, which is produced from a dihydric phenol (aromatic dihydroxy compound) and a carbonic acid diester by a transesterification method can be used. In the present invention, two or more different polycarbonates having different structures and molecular weights may be combined and used as the component (A).

As the resin containing aromatic polycarbonate as the main component, which is preferably used as the component (A) of the present invention, there can be mentioned the resins comprising the aromatic polycarbonate resin and the rubber-modified styrene resin. Here, the rubber-modified styrenic resin means a rubbery polymer, and 1
A rubber-modified styrenic resin containing, as a component, one or more vinyl compounds.

As the rubbery polymer of the rubber-modified styrene resin, any one having a glass transition temperature of 0 ° C. or lower can be used. Specifically, polybutadiene, styrene / butadiene copolymer rubber, butadiene / butyl acrylate copolymer rubber, diene rubber such as acrylonitrile / butadiene copolymer rubber, acrylic rubber such as polybutyl acrylate, silicone / acrylic composite rubber , Polyisoprene, polychloroprene, ethylene-propylene rubber,
Block copolymers such as ethylene / propylene / diene terpolymer rubber, styrene / butadiene block copolymer rubber, styrene / isoprene block copolymer rubber, and hydrogenated products thereof can be used. Among these polymers, polybutadiene, styrene / butadiene copolymer rubber, acrylonitrile / butadiene copolymer rubber, polybutyl acrylate and the like are preferable.

The proportion of the rubbery polymer in the rubber-modified styrene resin is used in the range of 1 to 95% by weight, and it is determined according to the required mechanical strength, rigidity and molding processability. It is preferably 5 to 45% by weight, more preferably 10 to 40% by weight.

The vinyl compound used in the rubber-modified styrenic resin includes aromatic vinyl compounds such as styrene, α-methylstyrene and paramethylstyrene, alkyl (meth) acrylates such as methyl methacrylate, methyl acrylate, butyl acrylate and ethyl acrylate. ) Acrylates, (meth) acrylic acids such as acrylic acid and methacrylic acid, vinyl cyanide monomers such as acrylonitrile and methacrylonitrile, and α and β such as maleic anhydride
-Unsaturated carboxylic acid, N-phenylmaleimide, N-methylmaleimide, N-cyclohexylmaleimide and other maleimide-based monomers, and glycidyl group-containing monomers such as glycidylmethacrylate.

Of these, preferred are aromatic vinyl compounds, alkyl (meth) acrylates, vinyl cyanide monomers and maleimide type monomers, and more preferred are styrene, acrylonitrile, N-phenylmaleimide, Butyl acrylate. These vinyl compounds may be used alone or in combination of two or more. A combination of an aromatic vinyl compound and a vinyl compound other than aromatic is preferable. In this case, the aromatic vinyl compound and the non-aromatic vinyl compound are used in arbitrary proportions, but the preferable proportion of the non-aromatic vinyl compound is 5 to 8 with respect to the total amount of the vinyl compound alone.
It is in the range of 0% by weight. Examples of the rubber-modified styrene resin include ABS resin (acrylonitrile / butadiene / styrene resin), AAS resin (acrylonitrile / butyl acrylate / styrene resin), and HIPS (high impact polystyrene resin).

The method for producing the rubber-modified styrenic resin is not particularly limited, and bulk polymerization, solution polymerization, suspension polymerization,
A commonly known production method such as emulsion polymerization can be mentioned. Among them, the rubber-modified styrene resin produced by bulk polymerization or solution polymerization can obtain a rubber-modified styrene resin without using an emulsifier, and therefore, a fatty acid or a fatty acid metal salt derived from the emulsifier is rubber-modified. Since it is not substantially contained in the styrene resin, it can be particularly preferably used as a rubber-modified styrene resin used in combination with an aromatic polycarbonate resin.

Further, in the present invention, it is also effective to use the aromatic polycarbonate resin in combination with two or more different rubber-modified styrenic resins having different structures and molecular weights. For example, ABS as rubber-modified styrene resin
By using resin and MBS resin (methyl methacrylate, butadiene, styrene resin) in combination,
Excellent melt flowability and impact resistance can be simultaneously improved. A specific example of such an MBS is "METABLEN C- manufactured by Mitsubishi Rayon Co., Ltd. of Japan.
"223A" and "Metablene C-323A", "Kane Ace M-511" and "Kane Ace B-564" manufactured by Kanegafuchi Chemical Industry Co., Ltd., and "M" manufactured by Taiwan Plastics Co., Ltd. -5
1 ”and the like.

In the present invention, when the aromatic polycarbonate resin and the rubber-modified styrene resin are used in combination, the amount of the rubber-modified styrene resin is 100 parts by weight based on 100 parts by weight of the total amount of the aromatic polycarbonate resin and the rubber-modified styrene resin. , 50 to 5 parts by weight, more preferably 40 to 10 parts by weight, still more preferably 30 to 15 parts by weight. If the rubber-modified styrene-based resin exceeds 50 parts by weight, the heat resistance and the flame retardancy in a thin-walled molded product will be insufficient, while if it is less than 5 parts by weight, the melt fluidity tends to decrease.

Further, as the component (A) in the present invention, a polyphenylene ether resin or a resin mainly composed of a polyphenylene ether resin can be particularly preferably used. Here, the polyphenylene ether resin is a polyether having an aromatic ring in the main chain, such as poly (2,6-dimethyl-1,4-phenylene ether),
A copolymer of 2,6-dimethylphenol and 2,3,6-trimethylphenol is preferable, and poly (2,6-dimethyl-1,4-phenylene ether) can be preferably used.

The reduced viscosity η _sp / C (0.5 g / dl, chloroform solution, measured at 30 ° C.) of the above polyphenylene ether resin used in the present invention is 0.20 to 0.70.
It is preferably in the range of dl / g, and 0.30 to 0.
More preferably, it is in the range of 60 dl / g. As a means for satisfying the above requirement regarding the reduced viscosity η _sp / C of the polyphenylene ether resin, it can be carried out by adjusting the amount of catalyst in the production of the polyphenylene ether resin.

As the component (A) preferably used in the present invention, a resin mainly composed of a polyphenylene ether resin is a resin composed of the polyphenylene ether resin and a styrene resin, and the styrene resin is styrene. The polymer mainly composed of the components or the rubber-modified styrene resin is shown, but polystyrene and high-impact polystyrene can be preferably used.

The styrenic resin used in combination with the polyphenylene ether resin may be blended in any proportion, and the polyphenylene ether resin may be blended in any desired proportion in order to obtain high flame retardancy in a thin molded product. 30 to 99 parts by weight of styrene resin 70 to
A proportion of 1 part by weight is preferred.

The component (B) in the present invention is a flame retardant, and the flame retardant (B) according to the present invention means a flame retardant aid which accelerates the flame retardant action in combination with conventionally known flame retardants and flame retardants. That is. Examples of the component (B) used in the present invention include organic phosphorus compounds, organopolysiloxanes, halogen-containing compounds, metal oxides, metal hydroxides,
Examples thereof include triazine compounds, red phosphorus, zirconium compounds, polyphosphate compounds, sulfamic acid compounds, organic sulfonic acid alkali metal salts, and the like. Among the components (B) listed above, an organic phosphorus compound and an organopolysiloxane can be preferably used in the present invention.

Among the above-mentioned organophosphorus compounds, in the present invention, since the volatile components during molding can be reduced, the organophosphorus compound oligomer which is a compound having two or more phosphorus atoms in its structure can be preferably used. Among them, those selected from the group of compounds represented by the following formula (1) can be particularly preferably used.

[0060]

[Chemical 20]

The substituents R ^a , R ^b and R in the above formula (1) are
^c and R ^d each independently represent an aryl group having 6 to 12 carbon atoms, and one or more hydrogen atoms thereof may or may not be substituted. When one or more hydrogen atoms are substituted, the substituent is an alkyl group having 1 to 30 carbon atoms, an alkoxy group, an alkylthio group, a halogen, an aryl group, an aryloxy group, an arylthio group, a halogenated aryl group, etc. Or a group in which these substituents are combined (for example, an arylalkoxyalkyl group or the like) or a group in which these substituents are bonded by an oxygen atom, a sulfur atom, a nitrogen atom or the like (for example, an arylsulfonylaryl group). Etc.) may be used as a substituent.

Particularly preferred aryl groups as the substituents R ^a , R ^b , R ^c and R ^d are a phenyl group, a cresyl group, a xylyl group, a propylphenyl group and a butylphenyl group. Substituents R ^a , R ^b and R in the compound of the above formula (1)
^{When c} and R ^d are an alkyl group or a cycloalkyl group, the thermal stability is generally lowered and decomposition is likely to occur during melt kneading.

X in the above formula (1), which represents a group of compounds as an example of the organic phosphorus compound, is a diphenyloldimethylmethane residue as described above. As the oligomeric phosphoric acid ester, there are those in which X is a resorcinol residue or a hydroquinone residue, and in comparison with these, the compound represented by the above formula (1) (where X is a diphenyloldimethylmethane residue) is used. It is preferable to use, as the organic phosphorus compound, a compound selected from the group of compounds mentioned above, since the hydrolysis resistance and thermal stability of the organic phosphorus compound are improved.

The organophosphorus compound oligomer represented by the formula (1) is usually used as a mixture of a plurality of different organophosphorus compound oligomers having different values of n (n is a natural number). At this time, the weight average condensation degree (N) of a plurality of different organophosphorus compound oligomers
Is preferably 1 to less than 1.2. N is obtained by gel permeation chromatography or liquid chromatography to obtain the weight fraction (A _n ) of each component having different n, and is calculated by N = Σ (n · A _n ) / Σ (A _n ). It

Here, in _order to obtain A _n , a UV detector or an RI detector is usually used as a detector. However, in the calculation of N, a compound having a structure in which n in the above formula (1) is 0 is used in combination or included (that is, an organic phosphorus compound having only one phosphorus atom in one molecule is used or included). In the case), a compound in which n is 0 is excluded from the calculation of N. The weight average condensation degree N is
It is usually 1 or more and 5 or less, preferably 1 or more and 2 or less, and 1
It is more preferably 1.5 or more and 1.5 or less, and particularly preferably 1 or more and less than 1.2.

The smaller N is, the better the compatibility with the resin, the better the melt fluidity, and the higher the flame retardancy. In particular, the compound of N = 1 has a particularly excellent balance between flame retardancy and melt fluidity in the resin composition. When N of the compound of Chemical formula 20 as the organophosphorus compound is 5 or more, the viscosity of the compound becomes large, and the melt fluidity tends to be lowered particularly in the high shear rate region, and the flame retardancy is low. Tends to decline.

The acid value of the organic phosphorus compound used in the present invention is preferably 0.1 mgKOH / g or less, more preferably 0.08 mgKOH / g or less, and further preferably 0.05 mgKOH / g. g or less, and particularly preferably 0.01 mgKOH / g or less. By using an organic phosphorus compound having a low acid value, it is possible to obtain a flame-retardant resin composition having more excellent resistance to moist heat.

Further, the organic phosphorus compound represented by the above general formula (1) can be produced by the method described in US Pat. No. 2,520,090.
JP-B-62-25706, JP-A-63-2276
According to the method described in Japanese Unexamined Patent Publication No. 32, etc., phosphorus oxychloride is reacted with bisphenol A and monohydric phenol in the presence of a Lewis acid catalyst such as magnesium chloride or aluminum chloride to synthesize, and thereafter, a crude organophosphorus compound The product can be obtained by washing, purifying, and drying, but in the organophosphorus compound used in the present invention, mainly catalyst-derived magnesium and aluminum contained in the organophosphorus compound, alkali for washing and purifying, and alkali When using an aqueous solution containing a metal ion such as earth, the total amount of metal components such as sodium, potassium and calcium that may be introduced is preferably 30 ppm or less, more preferably 20 ppm or less, further preferably 10 ppm or less, Particularly preferably, it is 5 ppm or less, and the flame retardancy is superior to the moist heat resistance. Desirable in obtaining the resin composition.

Further, the chlorine concentration contained in the organic phosphorus compound is preferably 20 ppm or less, more preferably 1 ppm or less.
It is preferably 0 ppm or less, more preferably 5 ppm or less, and particularly preferably 1 ppm or less in order to obtain a flame-retardant resin composition having more excellent moist heat resistance. Further, as the component (B) which can be preferably used in the present invention, an organopolysiloxane can be mentioned. The organopolysiloxane preferably used as the component (B) in the present invention is known per se, and can be represented by, for example, the following formula: It is represented by (2).

[0070]

[Chemical 21] (In the formula, each R _X independently represents a hydrogen atom, an aromatic group, an aliphatic group, an alicyclic group, or a reactive functional group.
m and n are each independently an integer of 0 or 1 or more. )

Specific examples of R _X include aromatic groups
Examples thereof include aryl groups such as phenyl group, xylyl group and tolyl group, halogenated aryl groups such as chlorophenyl group, aralkyl groups such as phenylethyl group and benzyl group. Examples of the aliphatic group include an alkyl group such as a methyl group, an ethyl group and a propyl group, an alkenyl group such as a vinyl group, a propenyl group and a butynyl group, and a halogenated alkyl group such as a chlorobutyl group.

Examples of the alicyclic group include a cyclohexyl group and the like. As the reactive functional group, for example,
Hydroxyl groups, alkoxy groups and the like, further, epoxy group, amino group, carboxylic acid group, carboxylic acid ester group,
Examples thereof include an aliphatic group, an aromatic group, and an alicyclic group partially substituted with a reactive group such as a hydroxyl group and an alkoxy group. Of these, a methyl group, a phenyl group, a hydroxyl group, and an alkoxy group are preferably used in the present invention.

In the present invention, the ratio of hydrogen atom, aromatic group, aliphatic group, alicyclic group and reactive functional group in the organopolysiloxane is not particularly limited. Generally, the more aromatic groups there are, the more excellent the heat resistance is, and the better the compatibility with the resin tends to be. In addition, l, m, and n in the formula shown in formula (2)
The ratio of is also not particularly limited. It becomes liquid as l becomes larger, and becomes rubbery as n becomes larger. Preferably,
The molar ratio of 1: m: n is from 1: 0 to 8: 0-5. Further, the weight average molecular weight of the organopolysiloxane is generally 5,000 to 300,000 and is not particularly limited.

Further, in the present invention, as the component (B),
It is also possible to use an alkali metal salt of an aromatic sulfonic acid and / or an alkali metal salt of a perfluoroalkane sulfonic acid, and to further improve the flame retardancy by using these in combination with the organopolysiloxane. Is possible. The alkali metal salt of aromatic sulfonic acid is represented by the following formula, for example.

[0075]

[Chemical formula 22] (In the formula, R is a phenyl group or a naphthyl group, A is one or more selected from a halogen atom, an alkyl group, an aryl group, a vinyl group, an alkoxy group, an amino group, a methyl ester group and an ethyl ester group. The substituent, M represents an alkali metal, and when R is a phenyl group, m and n are integers (m + n ≦ 6) of 0 to 5 and 1 to 2, respectively, and when R is a naphthyl group, m and n.
Represents an integer of 0 to 7 and 1 to 2 (m + n ≦ 8). )

Examples of the alkali metal salt of aromatic sulfonic acid satisfying the above formula include p-toluenesulfonic acid and p-toluenesulfonic acid.
-Styrene sulfonic acid, 1-naphthalene sulfonic acid,
Dimethyl isophthalate-5-sulfonic acid, 2,6-naphthalenedisulfonic acid, benzenesulfonic acid, benzenedisulfonic acid, dimethyl 2,4,6-trichloro-5-sulfoisophthalate, 2,5-dichlorobenzenesulfonic acid, 2 , 4,5-Trichlorobenzenesulfonic acid, p-
Alkali metal salts such as iodobenzene sulfonic acid and 7-amino-1,3-naphthalene disulfonic acid are mentioned,
These can be used alone or in combination. The alkali metal salt of perfluoroalkanesulfonic acid is represented by the following formula, for example.

[0077]

[Chemical formula 23] (In the formula, M represents an alkali metal and n represents an integer of 1 to 8.)

Examples of the alkali metal salt of perfluoroalkanesulfonic acid satisfying the above formula include, for example, perfluoromethanesulfonic acid, perfluoroethanesulfonic acid,
Alkali metal salts such as perfluoropropanesulfonic acid, perfluorobutanesulfonic acid, perfluoromethylbutanesulfonic acid, perfluorohexanesulfonic acid, perfluoroheptanesulfonic acid, and perfluorooctanesulfonic acid are listed, and these may be used alone or It can be used in combination with more than that.

In the present invention, when the alkali metal salt of aromatic sulfonic acid and / or the alkali metal salt of perfluoroalkane sulfonic acid represented by the formulas (22) and (23) is used, the compounding amount is A) 100
0.01 to 2 parts by weight is preferable with respect to parts by weight. 0.0
If it is less than 1 part by weight, the effect of improving the flame retardancy is insufficient, and if it exceeds 2 parts by weight, the thermal stability is poor, which is not preferable. The range is more preferably 0.01 to 1 part by weight, still more preferably 0.02 to 0.4 part by weight.

The amount of the component (B) in the resin composition of the present invention depends on the kind of the component (B), the combination of the component (A) and the component (B), etc., but is 100 parts by weight of the component (A). On the other hand, it is 0.01 to 40 parts by weight, preferably 0.1 to 30 parts by weight, and more preferably 1 to 20 parts by weight. If the amount of component (B) is less than 0.01 parts by weight, the flame retardancy of the thin-walled molded product will be insufficient, while if it exceeds 40 parts by weight, the impact resistance of the resin composition will be insufficient.

The component (C) in the resin composition of the present invention is a filler. Usually, the filler is used to impart necessary functions to the thin-walled molded product such as rigidity, dimensional stability, and mechanical strength, but the present invention aims to improve the flame retardancy of the thin-walled molded product. Used as the main purpose.

The component (C) used in the present invention is, for example, talc, mica, clay, glass fiber, glass flake, milled glass, carbon fiber, aramid fiber, silica, glass beads, glass balloon, silica balloon, metal. Fiber, metal powder, wollastonite, potassium titanate, silicon carbide, calcium carbonate, magnesium carbonate, graphite, calcium sulfate, barium sulfate, charcoal powder, and the like are preferable, and talc, glass fiber, carbon fiber, glass are preferable. Flakes, milled glass,
Examples thereof include wollastonite, potassium titanate, calcium carbonate, barium sulfate, and mica. The reinforcing agent used in the present invention may be used alone, or may be used as a mixture with other types.

The component (C) of the present invention is preferably a plate-like filler, and examples thereof include glass flakes, metal flakes, mica, talc and kaolin. Among them, talc, mica, glass flakes and metal flakes are preferable, and talc, mica and glass flakes are particularly preferable.

The talc used in the present invention is hydrous magnesium silicate having a layered structure, and has a chemical formula of 4SiO.
Is represented by ₂ · 3MgO · 2H ₂ O, typically SiO ₂ about 63 wt%, MgO about 32%, H ₂ O to about 5 wt%, other Fe ₂
It contains O ₃ and Al ₂ O ₃ and has a specific gravity of about 2.7. In the present invention, the average particle size is 0.01 to 20 μm.
A powder of m is preferably used from the viewpoint of improving rigidity. The average particle size of talc here means a value measured by a laser diffraction method. If the average particle size of the talc used in the present invention is smaller than this range, the rigidity tends to decrease, and if it exceeds this range, the appearance of the molded product deteriorates.

The mica used in the present invention is a pulverized silicate mineral containing aluminum, potassium, magnesium, sodium, iron and the like. Muscovite mica,
There are phlogopite, biotite, artificial mica, etc., and any mica can be used as the mica of the present invention, but muscovite is preferable. In addition, as a method for producing mica, a dry crushing method of crushing mica rough with a dry crusher and a rough crushing of mica rough with a dry crusher, followed by main crushing with a wet crusher in a slurry state by adding water. Although there is a wet pulverization method in which dehydration and drying are performed thereafter, mica produced by the wet pulverization method capable of pulverizing mica thinly and finely is preferable in the present invention.

The average particle size of mica is 10 to 1 as measured by the Microtrack laser diffraction method.
Those having a diameter of 00 μm can be used. Preferably the average particle size is 2
It is from 0 to 50 μm. Average particle size of mica is 10μ
If it is less than m, the effect of improving the rigidity is small, and if it exceeds 100 μm, the weld strength is lowered.

As the thickness of the mica, one having a thickness of 0.01 to 1 μm actually measured by observation with an electron microscope can be preferably used. More preferably the thickness is 0.03 to 0.3
μm. If the thickness of the mica is less than 0.01 μm, the rigidity of the mica is small because the mica is likely to be broken during melt-kneading, and if it exceeds 1 μm, the effect of improving the rigidity is not sufficient. Further, the mica used in the present invention is
It may be surface-treated with a silane coupling agent or the like,
Further, it may be granulated with a binder to form granules.

As the mica used in the present invention,
It is also possible to use metal-coated mica coated with a metal such as gold, silver, nickel or aluminum. The glass flakes and metal flakes used in the present invention include:
When the average particle size is 10 to 1,000 μm, and the average particle size is (a) and the thickness is (c),
The (a) / (c) ratio is preferably 5 to 500,
6 to 450 are more preferable, and 7 to 400 are even more preferable.

The average particle size is less than 10 μm or (a) /
If the ratio (c) is less than 5, the rigidity tends to decrease,
Average particle size exceeds 1,000 μm, or (a)
If the / (c) ratio exceeds 500, the appearance of the molded product and the weld strength tend to deteriorate. The average particle diameter of the glass flakes and the metal flakes as used herein is calculated as the median diameter of the weight distribution of the particle diameter obtained by the standard sieving method. Among such glass flakes and metal flakes, glass flakes are particularly preferable.

These glass flakes and metal flakes can be subjected to a focusing treatment with various compounds such as epoxy type, urethane type and acrylic type, and those which are surface-treated with a silane coupling agent described later are preferably used. Can be done. Also, as glass flakes,
It is also possible to use metal-coated glass flakes coated with a metal such as gold, silver, nickel or aluminum.

The kaolin used in the present invention is hydrous aluminum silicate having a layered structure and has a chemical formula of Al ₂
It is represented by Si ₂ O ₅ (OH) ₄ . Normally, kaolin calculated naturally includes kaolinite, dickite, and nacrite, but any of them can be used in the present invention. In the present invention, powdery ones having an average particle diameter of 0.01 to 20 μm can be preferably used. The average particle diameter of kaolin as used herein means a value measured by a laser diffraction method. In the case of kaolin, if the average particle size is smaller than this range, the rigidity tends to decrease, and if it exceeds this range, the appearance of the molded product is deteriorated, which is not preferable.

The plate-like filler is preferably surface-treated with a silane coupling agent or the like. By this surface treatment, the decomposition of the thermoplastic resin (A) is suppressed, the adhesion to the resin can be further improved, and the mechanical strength and the weld strength can be further improved. The silane coupling agent here is the following formula

[0093]

[Chemical formula 24]

(Wherein Y is a group having reactivity or affinity such as amino group, epoxy group, carboxylic acid group, vinyl group, mercapto group, halogen atom, etc., R ¹ , R ² , R ³ and R ⁴ are respectively It represents a single bond or an alkylene group having 1 to 7 carbon atoms, and an amide bond, an ester bond, an ether bond or an imino bond may be present in the alkylene molecular chain, and X ¹ , X ² and X ³ are each alkoxy. Group, preferably an alkoxy group having 1 to 4 carbon atoms or a halogen atom)
A silane compound represented by

Specifically, vinyltrichlorosilane, vinyltriethoxysilane, vinyltrimethoxysilane,
γ-methacryloxypropyltrimethoxysilane, β-
(3,4-Epoxycyclohexyl) ethyltrimethoxysilane, γ-glycidoxypropyltrimethoxysilane, N-β (aminoethyl) γ-aminopropyltrimethoxysilane, γ-aminopropyltriethoxysilane, N-phenyl- Examples thereof include γ-aminopropyltrimethoxysilane, γ-mercaptopropyltrimethoxysilane and γ-chloropropyltrimethoxysilane.

The blending amount of the component (C) in the present invention is 0.1 to 20 with respect to 100 parts by weight of the thermoplastic resin (A).
The amount is 0 parts by weight, preferably 1 to 100 parts by weight, more preferably 3 to 50 parts by weight, and particularly preferably 5 to 10 parts by weight. If the amount is less than 0.1 part by weight, the effect of improving the flame retardancy in the thin-walled molded product is small, and if the amount exceeds 200 parts by weight, the mechanical strength of the resin composition is lowered, and the melt-kneading becomes difficult, resulting in practicality. Lack.

The flame-retardant resin composition of the present invention can improve the flame-retardant property in a thin molded product by blending the component (C), but the lubricant component (E )
When the content of the component (c) increases, it becomes difficult to sufficiently obtain the action and effect of the component (C) for improving the flame retardancy in a thin-walled molded product.
Therefore, in order to enhance the flame-retardant effect in the thin molded article which is the object of the present invention, it is necessary to consider the content of the component (E) in the composition to be 5,000 ppm or less together with the composition of the component (C). is necessary.

The component (D) in the resin composition of the present invention is a colorant. The colorant used in the present invention is a pigment or dye used for coloring a resin, for example, an inorganic pigment such as titanium white (titanium oxide), titanium yellow, red iron oxide, ultramarine blue, spinel green, or a condensed azo type pigment. Organic pigments, quinacridone organic pigments, isoindolinone organic pigments, perylene organic pigments, anthraquinone organic pigments, organic pigments such as phthalocyanine organic pigments, carbon black, perylene dyes, perinone dyes, anthraquinone dyes And dyes of heterocyclic dyes.

Among the colorants, titanium oxide is not limited by the production method and crystal structure, but titanium oxide produced by the chlorine method and having a rutile crystal structure is preferable. The average particle size of titanium oxide used is not particularly limited, but is 0.01 to 0.0.
It is preferably 5 μm, and particularly preferably 0.1 to 0.3 μm. Further, within the range that does not impair the object of the present invention,
It may be previously treated with a treating agent which is usually used as a surface treating agent for titanium oxide.

Examples of such treating agents include alumina and silica, which may be used alone or in combination. Further, as the surface treatment agent, an organic dispersant, a stabilizer and the like are contained, and the organic dispersant and the stabilizer may correspond to the component (E) of the present invention, but these are used within the scope of the present invention. It is possible to

In the flame-retardant resin composition of the present invention, the above-mentioned component (D) is usually used in combination with a plurality of coloring agents in order to achieve the desired color development. The total amount of the colorant (D) is 0 to 10 parts by weight, preferably 0.0001, relative to 100 parts by weight of the component (A).
To 8 parts by weight, more preferably 0.001 to 7 parts by weight, still more preferably 0.002 to 5 parts by weight. In the present invention, the component (D) may not be contained, but if it exceeds 10 parts by weight, the mechanical properties and flame retardancy of the resin composition are deteriorated.

The lubricant (E) in the present invention means an aliphatic hydrocarbon, a polyolefin wax, a higher carboxylic acid,
A compound selected from the group of compounds such as higher carboxylic acid metal salt, fatty acid amide, fatty acid ester, and higher alcohol is shown. Some of these lubricants (E) are already contained in the resin raw material, but as a processing aid when producing the resin composition or as a dispersant for the colorant when coloring the resin composition. There are also those added to the resin composition as a spreading agent, and as a release agent for improving the mold release of the molded body during molding.

Among the components (E), the aliphatic hydrocarbon is an aliphatic hydrocarbon compound having 5 to 100 carbon atoms,
Examples thereof include ligroin, paraffin oil, mineral oil and liquid paraffin.

The polyolefin wax is a wax having a weight average molecular weight of 500 as a basic structural unit.
A low molecular weight polyolefin that is ~ 10,000,
Examples thereof include paraffin wax, polyethylene wax, polypropylene wax, ethylene / vinyl acetate copolymer wax, and polyolefin ionomer wax.

The higher carboxylic acid has 5 to 5 carbon atoms.
A fatty acid having 50 saturated or unsaturated bonds, for example, stearic acid, valeric acid, caproic acid, capric acid, lauric acid, myristic acid, palmitic acid, arachidic acid, behenic acid, lignoceric acid, serotic acid, melicinic acid. , Tetratriacontanoic acid, glutaric acid, adipic acid, azelaic acid, naphthenic acid, rosin acid, oleic acid, linoleic acid, linolenic acid and the like.

The higher carboxylic acid metal salt is a metal salt of the higher carboxylic acid, and examples thereof include alkali metal stearate, calcium stearate, zinc stearate, magnesium stearate, lead stearate and the like. it can. The fatty acid amide has 12 to 150 carbon atoms having at least one acid amide bond in the molecule.
Examples thereof include stearic acid amide, oleic acid amide, erucic acid amide, ethylenebisstearic acid amide, methylenebisstearic acid amide, and ethylenebisoleic acid amide.

The fatty acid ester is a compound having at least one ester bond in the molecule and having 10 to 200 carbon atoms, and is, for example, an ester of a higher carboxylic acid such as butyl stearate and a monohydric alcohol, or ethylene glycol. Monostearate, glycerin monostearate, trimethylolpropane monostearate, pentaerythritol monostearate, pentaerythritol monolaurate, pentaerythritol distearate, glycerin dilaurate, glycerin tristearate, trimethylolpropane distearate, glycerin Distearate, glycerin tribehenate, pentaerythritol tristearate, trimethylolpropane tricaprate, trimethylolpropane dioleate, pentaerythritol Can be mentioned esters of higher carboxylic acids tetrastearate and the like with a polyhydric alcohol.

The higher alcohol is a compound having one or more hydroxyl groups in the molecule and having 5 to 50 carbon atoms, and examples thereof include stearyl alcohol.

In the present invention, the total amount of the lubricant (E) contained in the flame-retardant resin composition, that is, the total amount of the lubricant component contained in the flame-retardant resin composition of the present invention is 5,000 weight. ppm or less, preferably 0.01 to 3,000
Ppm by weight, more preferably 0.1 to 2,000
Ppm by weight, particularly preferably 1 to 1,000 ppm by weight
With this, a high degree of flame retardancy can be achieved even in the case of a thin molded product.

The content of the component (E) in the flame-retardant resin composition of the present invention is determined by the proton NMR method by separating or extracting the component (E) from the composition by a combination of a good solvent and a poor solvent. , Gas chromatography / mass spectrum method (GC / MS method), liquid chromatography / mass spectrum method (LC / MS method) and the like can be combined and quantified.

In the flame-retardant resin composition of the present invention, the fluoropolymer (F) is further added for the purpose of preventing dropping of combustion products.
Can be blended. In the present invention, a fluoropolymer having a fibril forming ability can be preferably used, and a fine powdery fluoropolymer, an aqueous dispersion of the fluoropolymer, a powdery mixture with a second resin such as AS or PMMA, and the like, Various forms of fluoropolymer can be used.

In the present invention, in particular, an aqueous dispersion of a fluoropolymer can be preferably used as the component (F), and the aqueous dispersion of the fluoropolymer means polytetrafluoroethylene, tetrafluoroethylene / propylene copolymer A tetrafluoroethylene polymer such as a coalesced polymer, a perfluoroalkane polymer other than polytetrafluoroethylene, preferably a tetrafluoroethylene polymer, and particularly preferably polytetrafluoroethylene is described in, for example, “Fluorine Resin Handbook” (Nikkan Kogyo Shimbun, 1990). Manufactured by suspension polymerization or emulsion polymerization as described in 1., and further used as a form of an aqueous dispersion.

That is, the dispersion liquid of the fluoropolymer fine particles obtained by suspension polymerization or emulsion polymerization is 40 to 7
1 shows a milky white aqueous dispersion stabilized with a surfactant after being concentrated to a concentration of 0 wt%. The concentration of the fluoropolymer in the aqueous dispersion of the fluoropolymer can be diluted with water as long as the concentration is such that the dispersion state is stable, but 5 to 70 wt% is preferable,
More preferably 20 to 65 wt%, particularly preferably 30
~ 60 wt%. The average primary particle diameter of the fluoropolymer in the aqueous dispersion is 0.01 to 0.6.
0 μm is preferable, and more preferably 0.10 to 0.40.
μm, and particularly preferably 0.18 to 0.30 μm.

Further, as the surfactant for stabilizing the aqueous dispersion of the fluoropolymer, nonionic surfactants such as ethoxylated alkylphenol and ethoxylated higher alcohol are preferably used, and the compounding amount thereof is usually 1 -15 wt%, preferably 2-10
wt%, and more preferably 3 to 7 wt%. further,
The aqueous dispersion of the fluoropolymer has a pH
Those whose values are usually adjusted to 9 to 10 are preferably used.

The fluoropolymer concentration is 60 wt.
%, The aqueous dispersion has a liquid specific gravity of about 1.5 and a viscosity (25 ° C.) in the range of 15 to 30 cp. As an aqueous dispersion of a fluoropolymer that can be preferably used in the present invention, “Teflon 30J” manufactured by Mitsui DuPont Fluorochemical Co., Ltd., “Polyflon D-1” and “Polyflon D-” manufactured by Daikin Industries, Ltd.
2 "," Polyflon D-2C "," Polyflon D-2C
E ”can be illustrated.

As the component (F), a fluoropolymer prepared as a powdery mixture with a second resin such as AS or PMMA can also be preferably used. Techniques relating to fluoropolymers made into a powdery mixture with these second resins are disclosed in JP-A-9-95583, JP-A-11-49912, JP-A-2000-143966, and JP-A-2000.
It is disclosed in Japanese Patent Publication No.-297189. Examples of fluoropolymers that can be preferably used in the present invention as a powdery mixture with these second resins include "Blendex 449" manufactured by GE Specialty Chemicals, and "Metabrene A-3000" manufactured by Mitsubishi Rayon Co., Ltd. You can

When the component (F) is used in the flame-retardant resin composition of the present invention, its content is preferably 0.05 to 2 parts by weight per 100 parts by weight of the component (A), 1 to
1.5 parts by weight is more preferable, and 0.1 is more preferable.
5 to 1.0 part by weight, particularly preferably 0.2 to 0.8 part by weight. When the amount of the fluoropolymer is less than 0.05 part by weight, the effect of preventing the dropping of the combustion product may be insufficient, while when it exceeds 2 parts by weight, melt flowability and impact resistance are insufficient. There is a tendency.

Furthermore, in the flame-retardant resin composition of the present invention,
A heat resistance stabilizer can be preferably used. The heat resistance stabilizer is used for the melt-kneading step of the thermoplastic resin, the melt retention inside the molding machine during molding, or the progress of heat aging mainly due to oxygen in the air when the molded body is exposed to a high temperature environment. Used to prevent.

As the heat resistance stabilizer preferably used in the present invention, a hindered phenol antioxidant, a phosphite heat stabilizer, and a sulfur heat stabilizer can be mentioned. The hindered phenolic antioxidant is an antioxidant composed of a compound having at least one hindered phenol structure in the molecule, and has a molecular weight of 50 in the present invention.
Those having a value of 0 or more can be particularly preferably used because they have a heat aging resistance and a small amount of bleed-out to a molded product.
The phosphite heat stabilizer is an antioxidant composed of a compound having one or more trivalent phosphite structure in the molecule. The sulfur-based heat stabilizer is an antioxidant composed of a compound having at least one sulfur atom in the molecule.

In the present invention, when the above heat-resistant stabilizer is used, the amount thereof used is in the range of 0.01 to 5 parts by weight as the total amount of the heat-resistant stabilizer with respect to 100 parts by weight of the component (A). Preferably, more preferably 0.05 to 4 parts by weight,
It is more preferably 0.1 to 3 parts by weight. When the heat resistance stabilizer is less than 0.01 part by weight, the heat aging resistance of the composition tends to be insufficient, while when it exceeds 5 parts by weight, the flame retardancy in a thin molded article tends to decrease. is there. Further, in the flame-retardant resin composition of the present invention, an ultraviolet absorber, an epoxy compound and the like can be added as necessary within the range not impairing the gist of the present invention.

Next, the method for producing the flame-retardant resin composition of the present invention will be described. The resin composition of the present invention comprises the above components (A) to (C), and if necessary, components (D) to (F),
And other ingredients in the composition ratio described in the present specification,
It can be obtained by melt-kneading using a melt-kneading device such as an extruder, but in the present invention, the total amount of the lubricant (E) contained in the flame-retardant resin composition is 5,000 ppm by weight or less. In consideration of the above, melt kneading is performed. For the blending and melt-kneading of the respective constituents at this time, a generally-used device, for example, a pre-mixing device such as a tumbler or a ribbon blender, a melt-kneading device such as a single-screw extruder or a twin-screw extruder, or a kneader is used. You can

The method for obtaining the flame-retardant resin composition of the present invention may be a method for obtaining the desired flame-retardant resin composition by simultaneously melt-kneading all the components,
A method in which a composition comprising a combination of the respective components is manufactured by melt kneading in advance, and then other components are added and melt kneading is performed, for example, a thermoplastic resin (A), a flame retardant (B) and a filler (C) are previously prepared. To obtain pellets of a colored flame-retardant resin composition by obtaining a pellet of an uncolored composition mainly composed of and by melt-kneading, and then adding the colorant (D) and melt-kneading. Methods can also be used.

In the production method of the present invention, the lubricant (E) can be compounded at any stage of melt-kneading as long as it is within the range described in the present invention. Further, the raw materials can be supplied to the melt-kneading device after mixing the respective components in advance, but it is also possible to supply the respective components independently to the melt-kneading device.

The melt-kneading is usually carried out at a cylinder set temperature of the extruder of 200 to 400 ° C., preferably 220 to 350.
℃, the extruder screw rotation speed 100 ~ 700rp
m, preferably in the range of 200 to 500 rpm, can be appropriately selected and carried out, but care should be taken not to give excessive heat to the resin during melt kneading. Further, it is also effective to provide an extruder with an opening and perform open devolatilization or reduced-pressure devolatilization as necessary. The residence time of the raw material resin in the extruder is usually appropriately selected within the range of 10 to 150 seconds.

Pellets of an uncolored flame-retardant resin composition mainly composed of a thermoplastic resin (A), a flame retardant (B) and a filler (C) are produced by melt-kneading, and then the pellets are colored. In the method for obtaining a colored flame-retardant resin composition by further mixing the agent (D) and melt-kneading with a single-screw or twin-screw extruder, the dispersibility of the colorant (D) and the uniform coloring are obtained. In order to improve the property, it is possible to use the component (E) as a colorant dispersant or a colorant spreader, but in the present invention, these colorant dispersants or colorant spreaders are used. It is necessary to consider that the total amount of the component (E) used is within the range of 5,000 ppm by weight or less based on the flame retardant resin composition.

In this case, when a twin-screw extruder is used as the melt-kneading device, the amount of the component (E) used can be reduced, or the component (D) can be well dispersed in the resin composition without using them. It is preferable because it is possible. In addition, the use of a twin-screw extruder is preferable because the coloring uniformity can be improved. When a single-screw extruder is used, it is preferable to use a single-screw extruder having a screw configuration with an enhanced kneading and dispersing function, for example, having 3 to 6 stages of Dalmaged screw parts.

The molding method for obtaining a molded article made of the flame-retardant resin composition of the present invention is not particularly limited, but for example,
Injection molding, gas assist molding, extrusion molding, compression molding and the like can be mentioned, among which injection molding is preferably used.

The flame-retardant resin composition of the present invention has excellent flame retardancy even in a thin-walled molded product, and further, its flame-retardant performance does not decrease with time. Therefore, the molded product preferably has a wall thickness of 2 mm.
The following part is 30% by weight or more of the entire molded product, more preferably the wall thickness is 2 mm or less, the molded product is 50% by weight or more of the entire molded product, and more preferably the wall thickness is 2 mm or less. 70% by weight of the whole molded product
It can be suitably used in the above-mentioned molded products.

Examples of molded articles using the flame-retardant resin composition of the present invention include personal computer monitors, notebook computers, copiers, printers and other OA equipment housings, OA equipment chassis, mobile phone housings, Etc.

[0130]

BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be specifically described below with reference to Examples and Comparative Examples. In Examples or Comparative Examples, the following components (A), (B),
A flame-retardant resin composition was produced using (C), and if necessary, components (D), (E), (F) and other components.

1. Component (A): Thermoplastic resin (PC1) A bisphenol A-based polycarbonate produced from bisphenol A and diphenyl carbonate by a melt transesterification method and containing no lubricant (E). Weight average molecular weight (Mw) = 24,500 Phenolic end group ratio (ratio of phenolic end groups to the total number of end groups) = 37 mol% Component (E) content = 0 weight ppm

(PC2) A bisphenol A polycarbonate obtained by the phosgene method, containing no lubricant (E). Weight average molecular weight (Mw) = 25,500 Phenolic end group ratio (ratio of phenolic end groups to the total number of end groups) = 5 mol% Component (E) content = 0 weight ppm

(ABS) The ABS graft copolymer obtained by polymerizing by emulsion polymerization and coagulating by sulfate salting out, followed by washing and drying was used as acrylonitrile unit 2
5 wt%, styrene unit 75 wt%, obtained by diluting and kneading with AS resin (styrene-acrylonitrile resin) having a weight average molecular weight (Mw) of 160,000, butadiene rubber content content is 20 wt%, rubber weight Emulsion polymerization type acrylonitrile butadiene styrene resin having an average particle size of 0.26 μm, and a lubricant (component (E): rosin acid) as an emulsifier residue is 2,000 wt pp.
Those that include m. Rosin acid content (component (E)) = 2,000
0 weight ppm

(MBS) Polymerized by emulsion polymerization method, solidified by sulfate salting out method, washed and dried to obtain a butadiene rubber content content of 80 wt%,
Styrene unit 50 wt% and methyl methacrylate unit 5
It is a powdery methylmethacrylate-butadiene-styrene (MBS) resin having a copolymerization component of 0 wt% of 20 wt% and a rubber weight average particle diameter of 0.21 μm, and a lubricant (component (E)) as an emulsifier residue. : Rosin acid) in an amount of 2,500 ppm by weight. Rosin acid content (component (E)) = 2,500 ppm by weight

(PPE) Oxidative coupling polymerization of 2,6-xylenol in the presence of dibutylamine according to the method described in US Pat. No. 4,788,277 (Japanese Patent Application No. 62-77570). Manufactured by η _sp
/C=0.45 (0.5 g / dl, chloroform solution, measured at 30 ° C.), poly (2,6-dimethyl-)
1,4-phenylene ether).

(HIPS) A high-impact polystyrene containing 12% by weight of a butadiene rubber component and 88% by weight of a styrene unit.

2. Component (B): flame retardant (organopolysiloxane), which is produced by a known method and has a molar ratio of 1: m: n 2 in Chemical Formula 21 of 2:
An organopolysiloxane having a molecular weight of 50,000, wherein the ratio is 8: 0, 98% or more of R _x is composed of a phenyl group and a methyl group, and the ratio thereof is 60:40.

(Sulfonic acid metal salt) Perfluorobutanesulfonic acid potassium salt (trade name F114) manufactured by Dainippon Ink and Chemicals, Inc.

(Phosphate 1) An organophosphorus compound oligomer represented by the above chemical formula 20, wherein substituents R ^a , R ^b ,
R ^c and R ^d are all phenyl groups, the weight average condensation degree (N) is 1.12, and the magnesium content is 5.2.
ppm, a chlorine content of 1 ppm or less, and an acid value of 0.01 mgKOH / g.

(Phosphate 2) manufactured by Daihachi Chemical Co., Ltd.
Resorcinol-di-phosphate (CR733S) weight average condensation degree (N) is 1.48, magnesium content is 6.2 ppm, chlorine content is 1 ppm or less, and acid value is 0.01 mg / KOH. some stuff.

3. Ingredient (C): Filler (talc) Talc manufactured by Nippon Talc Co., Ltd. (trade name: Microace P-
3) Average particle diameter = 0.4 μm, L / D = 8, bulk specific volume = 2.3
ml / g (GFL) Glass flakes manufactured by Nippon Sheet Glass Co., Ltd. (trade name REFG)
-101) Average particle size D = 40 μm, L / D = 8

4. Component (D): Colorant (white) Titanium oxide manufactured by DuPont (trade name Ti-
(Ture R103-08) (Black) Tokai Carbon Co., Ltd. carbon black (trade name: carbon black 7550F) (Yellow) Shepherd titanium yellow (trade name: Yellow 29)

5. Ingredient (E): lubricant (release agent) stearic acid monoglyceride type release agent (dispersant) ethylenebisstearyl amide (spreading agent) paraffin oil manufactured by Esso Oil Co., Ltd. (trade name Cristol J-352)

6. Ingredient (F): Fluoropolymer (PTFE) GE Specialty Chemicals Co. mixed powder of polytetrafluoroethylene and acrylonitrile-styrene copolymer (Blendex 449)
PTFE content = 50 wt%

7. Other components: Heat resistance stabilizer (I-1076: hindered phenolic antioxidant)
Ciba Specialty Chemicals (trade name IR
GANOX 1076) Octadecyl-3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate (P-168: phosphite heat stabilizer) manufactured by Ciba Specialty Chemicals (trade name IRGAFOS1
68) Tris (2,4-di-t-butylphenyl) phosphite

[0146]

EXAMPLES Examples 1 to 10 Components (A), (B), (C), (D), (E), (F)
The other components were melt-kneaded in the amounts shown in Table 1 (unit: parts by weight) using a twin-screw extruder to obtain a flame-retardant resin composition. However, the number of parts of the component (F) indicates the number of parts as a fluoropolymer. Twin screw extruder (ZSK
-25, L / D = 37, manufactured by Werner & Pfleiderer), cylinder set temperature 250 ° C., screw rotation speed 280 rpm, kneading resin discharge speed 10 to 20 kg /
Hr, residence time of raw material resin inside the extruder is 30 to 100
Melt kneading was performed under the condition of seconds.

When an organopolysiloxane was used as the flame retardant (B), all the components were premixed together and put into a twin-screw extruder for melt-kneading. When an organophosphorus compound oligomer is used as the flame retardant (B), components (A), (C), (D), (E), (F) and other components are pre-blended in advance by a weight feeder. The mixture was charged into an extruder, and the component (B) was preheated to 80 ° C. in advance, and was compounded by press-fitting through a injection nozzle from the middle of the extruder by a gear pump. Further, in any of the above cases, the pressure reduction devolatilization of 15 mmHg-G (gauge pressure) was performed in the latter part of the extruder. The obtained pellets were dried and molded with an injection molding machine (Autoshot 50D, manufactured by FANUC), and the following tests were carried out.

(1) Flame Retardancy Test The obtained pellets were dried, and strip-shaped compacts (thickness 2.0 mm, 1.5 mm and 1.2 mm) for combustion test were molded using an injection molding machine. . Each molded body is heated at 23 ° C, 50
After being kept in an environment of RH% for 2 days, UL94 standard 20M
M vertical burning test was performed and classified into V-0, V-1 or V-2. The symbol NC in the table is non-classifiable (non-classifi
cation). (Flame retardancy: V-0> V-1
>V-2> NC)

(2) Time-dependent change in flame retardancy The strip-shaped molded product having a thickness of 1.5 mm, which was obtained by the above-mentioned method, for combustion test was subjected to 5 hours in an environment of 23 ° C. and 50 RH%.
After holding for 30 days and 30 days, UL94 standard 20MM vertical burning test was performed and classified into V-0, V-1 or V-2.

(3) Dart impact test The obtained pellets were dried and injection molded to 100 mm.
A × 100 mm × 2 mm (t) flat plate was prepared. The gate for injection molding was a pin gate having a diameter of 2 mm. After holding the created flat plate for 2 days at 23 ° C. and 50 RH% environment, using a graphic impact tester manufactured by Toyo Seiki Co., Ltd., a falling weight load of 10 kg, a falling height of 100 cm, a falling weight diameter of 20 mmφ, and a sample at 23 ° C. Holder diameter 76m
The total absorbed energy was measured under the condition of mφ. (unit:
J)

(4) Appearance of molded product 100 mm × 100 mm × prepared for the dirt impact test
The surface appearance of a 2 mm (thickness) square shaped body was visually observed. The molded product was visually evaluated by passing (∘) when there were no molding defects such as peeling of the surface layer, silver, burns, sink marks, and stickiness on the surface, and rejecting (x) when there was. The results are shown in Table 1.

[0152]

[Table 1]

The total amount of the component (E) in the composition shown in Table 1 is a calculated value, and is a value obtained by calculation including the component (E) contained in the component (A) as the raw material resin. . Although Examples 1 to 10 are results of the composition of the present invention, it can be seen that the resin compositions are thin and have excellent flame retardancy. Also,
The flame retardant performance is maintained at a high level with respect to changes over time.

Comparative Examples 1 to 10 As in Examples 1 to 10, the components and amounts shown in Table 2 were used.
Melt-kneading was performed using a twin-screw extruder to obtain a flame-retardant resin composition. The obtained pellets were dried and evaluated in the same manner as in Examples 1-10. The results are shown in Table 2.

[0155]

[Table 2]

The total amount of the component (E) in the composition shown in Table 2 is a calculated value obtained in the same manner as in Table 1. Comparative Example 1 is an example lacking the component (C), but the flame retardancy of a 1.2 mm thick molded piece is poor. Comparative Examples 2 and 3 are examples in which the total amount of the component (E) exceeds the upper limit of the range of the present invention, but the flame retardancy is poor. Comparative Example 4 is an example lacking the component (C), but the 1.2 mm thick molded piece is inferior in flame retardancy. Comparative Examples 5 and 6 are examples in which the total amount of the component (E) exceeds the upper limit of the range of the present invention, but the flame retardancy is poor.

Comparative Example 7 is an example lacking the component (C),
Flame retardancy is poor with 1.2 mm thick molded pieces. Comparative Example 8 is an example in which the total amount of the component (E) exceeds the upper limit of the range of the present invention, but the flame retardancy is poor. Comparative Example 9 is an example lacking the component (C), but the flame retardancy of a 1.2 mm thick molded piece is poor. Comparative Example 1
0 is an example in which the total amount of the component (E) exceeds the upper limit of the range of the present invention, but the flame retardancy is poor. In addition, Comparative Examples 2, 5, 6,
In Nos. 8 and 10, a decrease in flame retardance was observed with time.

Examples 11 to 17 The amounts shown in Table 3 were melt-kneaded using a twin-screw extruder to obtain flame-retardant resin compositions. The melt-kneading device is a twin-screw extruder (Z
SK-25, L / D = 37, manufactured by Werner & Pfleiderer)
Cylinder set temperature 310 ° C, screw rotation speed 250 rpm, kneading resin discharge speed 10 to 20 k
g / Hr, residence time of raw material resin inside the extruder is 30 to 1
Melt kneading was performed under the condition of 50 seconds.

When an organopolysiloxane was used as the flame retardant (B), all the components were premixed together and put into a twin-screw extruder for melt-kneading. When an organophosphorus compound oligomer is used as the flame retardant (B), components (A), (C), (D), (E), (F) and other components are pre-blended in advance by a weight feeder. The mixture was charged into an extruder, and the component (B) was preheated to 80 ° C. in advance, and was compounded by press-fitting through a injection nozzle from the middle of the extruder by a gear pump. Further, in any of the above cases, the pressure reduction devolatilization of 15 mmHg-G (gauge pressure) was performed in the latter part of the extruder. The obtained pellets were dried and evaluated in the same manner as in Examples 1-10. The results are shown in Table 3.

[0160]

[Table 3]

The total amount of the component (E) in the composition shown in Table 3 is a calculated value obtained in the same manner as in Table 1. Examples 11 to
No. 17 is the result of the composition of the present invention, and it can be seen that it is a resin composition which is thin and has excellent flame retardancy. Further, the flame retardant performance is maintained at a high level with respect to aging.

Comparative Examples 11 to 17 Flame retardant resin compositions were obtained in the same manner as in Examples 11 to 17 by melt-kneading with the components and amounts shown in Table 4 using a twin-screw extruder. The pellets obtained are dried and the results are obtained in Examples 11 to 11.
The same evaluation as in 17 was performed. The results are shown in Table 4.

[0163]

[Table 4]

The total amount of the component (E) in the composition shown in Table 4 is a calculated value obtained in the same manner as in Table 1. Comparative Example 11 is an example lacking the component (C), but the flame retardancy of a 1.2 mm thick molded piece is poor. Comparative Examples 12 and 13 are examples in which the total amount of the component (E) exceeds the upper limit of the range of the present invention, but the flame retardancy is poor. Comparative Example 14 is an example lacking the component (C), but 1.2
Inferior flame retardancy for mm thick molded pieces. Comparative Example 15 is an example in which the total amount of the component (E) exceeds the upper limit of the range of the present invention, but the flame retardancy is poor.

Comparative Example 16 is an example lacking the component (C), but the flame retardancy of a 1.2 mm thick molded piece is poor. Comparative Example 17
Is an example in which the total amount of the component (E) exceeds the upper limit of the range of the present invention, but the flame retardancy is poor. Further, in Comparative Examples 12 and 15, a decrease in flame retardance was observed with time.

[0166]

EFFECTS OF THE INVENTION The flame-retardant resin composition of the present invention has excellent flame-retardant properties even in a thin-walled molded product, and has little deterioration in flame-retardant performance with time. Materials that require flammability, such as computer monitors, notebook computers, printers, word processors, copiers,
It is useful as a material for housings of mobile phones and the like, and is extremely useful particularly when a molded product having a thin portion is obtained.

─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) C08K 5/00 C08K 5/00 7/06 7/06 C08L 69/00 C08L 69/00 71/12 71 / 12 // (C08L 69/00 C08L 23:00 23:00 51:04 51:04 83:04 83:04 27:12 27:12) (C08L 71/12 23:00 83:04 27:12) F term (reference) 4F070 AA06 AA18 AA32 AA34 AA50 AA52 AB08 AB09 AC04 AC27 AC28 AC32 AC36 AC40 AC43 AC47 AC50 AC55 AC75 AC79 AC92 AD01 AE01 AE04 AE07 AE09 AE17 FA03 FA17 FB06 FC06 4F071 AA02 AA10X AA14 AA22X AA26 AA50 AA51 AA67 AA77 AB03 AB28 AB30 AC02 AC05 AC09 AC10 AC12 AC15 AD01 AE07 AE09 AE11 AE17 AF47 AF57 BC12 4J002 AE032 AE052 BB001 BB022 BB062 BB112 BB232 BC021 BD031 BD155 BG051 BN063 BN143 CP05 CP01 CP04 CP1 CP4 CP01 CP4 CP1 CG4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CP1 CH4 CG4 A027 DA056 DA067 DE046 DE118 DE187 DE237 DG047 DG057 DH056 DJ007 DJ017 DJ037 DJ047 DJ057 DL007 EA019 EC069 EF059 FD0179 FD 017 FD 017 FD 017 FB FD 157 FB FD 157 FB FD 157 FB FD 157 FB FD 157 FB FD 157 FB FD FB FD FB FD FB FD FB FB FD FB FD FB FD FB FB FB FB FB FB FB FB FB FB TD FB FB FB FB FB FB FB FB FB FB TD FB FB FB FB FB FB FB FA FB FB FB FB FA FB FB FB FB FB FB FB FA FB FB FB FB FB FB FB FB FB FB FB FB FB FB FB to FB FB FB to FA FB FB to FB FB to FA FB to FB

Claims (21)

[Claims] 1. A thermoplastic resin (A) 100 parts by weight, a flame retardant (B) 0.01 to 40 parts by weight, and a filler (C) 0.1 to 100 parts by weight.
A flame-retardant resin composition containing 200 parts by weight and 0 to 10 parts by weight of a colorant (D), wherein the total amount of the lubricant (E) is 5,000.
A flame-retardant resin composition having a weight ppm or less. 2. The lubricant (E) is a compound selected from aliphatic hydrocarbons, polyolefin waxes, higher carboxylic acids, higher carboxylic acid metal salts, higher fatty acid amides, higher fatty acid esters, and higher alcohols. The flame-retardant resin composition according to claim 1. 3. The flame-retardant resin composition according to claim 1 or 2, wherein the thermoplastic resin (A) is an aromatic polycarbonate resin or a resin containing an aromatic polycarbonate resin as a main component. 4. The flame-retardant according to claim 1, wherein the thermoplastic resin (A) is 70 to 95 parts by weight of an aromatic polycarbonate resin and 30 to 5 parts by weight of a rubber-modified styrene resin. Resin composition. 5. The flame-retardant resin composition according to claim 1, wherein the thermoplastic resin (A) is a polyphenylene ether resin or a resin mainly composed of a polyphenylene ether resin. 6. The flame retardant (B) is represented by the following formula (1): 2. At least one kind of organophosphorus compound oligomer selected from the group of compounds represented by:
The flame-retardant resin composition according to any one of 1 to 5. 7. The flame retardant (B) is represented by the following formula (2): The flame-retardant resin composition according to any one of claims 1 to 5, which is an organopolysiloxane represented by: 8. The flame-retardant resin composition according to claim 1, wherein the filler (C) is selected from talc, glass, carbon fiber and mica. 9. The fluoropolymer (F) 0.05
The flame-retardant resin composition according to any one of claims 1 to 8, containing 2 to 2 parts by weight. 10. A thermoplastic resin (A) 100 parts by weight, a flame retardant (B) 0.01 to 40 parts by weight, and a filler (C) 0.1.
To 200 parts by weight, and a flame-retardant resin composition containing 0 to 10 parts by weight of the colorant (D) by a melt-kneading device, and the total amount of the lubricant (E) is 5,000 ppm by weight or less. A method for producing a flame-retardant resin composition, comprising: 11. The lubricant (E) is a compound selected from aliphatic hydrocarbons, polyolefin waxes, higher carboxylic acids, higher carboxylic acid metal salts, fatty acid amides, fatty acid esters, and higher alcohols. A method for producing the flame-retardant resin composition according to claim 10. 12. The thermoplastic resin (A) is an aromatic polycarbonate resin or a resin containing an aromatic polycarbonate resin as a main component.
1. The method for producing the flame-retardant resin composition according to 1. 13. The thermoplastic resin (A) is 70 to 95 parts by weight of an aromatic polycarbonate resin and 30 to 5 parts by weight of a rubber-modified styrenic resin.
Or the method for producing the flame-retardant resin composition according to item 11. 14. The thermoplastic resin (A) is a polyphenylene ether resin or a resin mainly composed of a polyphenylene ether resin.
1. The method for producing the flame-retardant resin composition according to 1. 15. The flame retardant (B) is represented by the following formula (1): 2. At least one kind of organophosphorus compound oligomer selected from the group of compounds represented by:
The method for producing a flame-retardant resin composition according to any one of 0 to 14. 16. The flame retardant (B) is represented by the following formula (2): It is organopolysiloxane represented by these, The manufacturing method of the flame-retardant resin composition in any one of Claims 10-14 characterized by the above-mentioned. 17. The method for producing a flame-retardant resin composition according to claim 10, wherein the filler (C) is selected from talc, glass, carbon fiber and mica. 18. The fluoropolymer (F) 0.0
The method for producing a flame-retardant resin composition according to any one of claims 10 to 17, containing 5 to 2 parts by weight. 19. The method for producing a flame-retardant resin / fat composition according to claim 10, wherein the melt-kneading device is a twin-screw extruder. 20. A molded product obtained by molding the flame-retardant resin composition according to any one of claims 1 to 9. 21. The molded product according to claim 20, wherein the molded product has a thickness of 2 mm or less in an amount of 30% by weight or more of the entire molded product.