JP2002530286A - オレフィン重合触媒としてのビス(テトラヒドロ−インデニル)メタロセン - Google Patents

オレフィン重合触媒としてのビス(テトラヒドロ−インデニル)メタロセン

Info

Publication number
JP2002530286A
JP2002530286A JP2000582403A JP2000582403A JP2002530286A JP 2002530286 A JP2002530286 A JP 2002530286A JP 2000582403 A JP2000582403 A JP 2000582403A JP 2000582403 A JP2000582403 A JP 2000582403A JP 2002530286 A JP2002530286 A JP 2002530286A
Authority
JP
Japan
Prior art keywords
group
indenyl
metallocene
tetrahydro
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000582403A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002530286A5 (enExample
Inventor
レスコニ,ルイージ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Publication of JP2002530286A publication Critical patent/JP2002530286A/ja
Publication of JP2002530286A5 publication Critical patent/JP2002530286A5/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2000582403A 1998-11-18 1999-11-10 オレフィン重合触媒としてのビス(テトラヒドロ−インデニル)メタロセン Pending JP2002530286A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98203905 1998-11-18
EP98203905.9 1998-11-18
PCT/EP1999/008647 WO2000029416A1 (en) 1998-11-18 1999-11-10 Bis(tetrahydro-indenyl) metallocenes as olefin-polymerisation-catalyst

Publications (2)

Publication Number Publication Date
JP2002530286A true JP2002530286A (ja) 2002-09-17
JP2002530286A5 JP2002530286A5 (enExample) 2006-12-28

Family

ID=8234357

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000582403A Pending JP2002530286A (ja) 1998-11-18 1999-11-10 オレフィン重合触媒としてのビス(テトラヒドロ−インデニル)メタロセン

Country Status (14)

Country Link
US (1) US6541584B1 (enExample)
EP (1) EP1047702B1 (enExample)
JP (1) JP2002530286A (enExample)
KR (1) KR20010034211A (enExample)
CN (1) CN1291986A (enExample)
AR (1) AR021311A1 (enExample)
AU (1) AU1270500A (enExample)
BR (1) BR9910192A (enExample)
CA (1) CA2317588A1 (enExample)
DE (1) DE69905011T2 (enExample)
ES (1) ES2189516T3 (enExample)
HU (1) HUP0101157A2 (enExample)
IL (1) IL137036A0 (enExample)
WO (1) WO2000029416A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003529572A (ja) * 2000-03-31 2003-10-07 ポリメーリ エウローパ ソシエタ ペル アチオニ 置換多環式シクロペンタジエン及びその製造方法
JP2004505019A (ja) * 2000-06-30 2004-02-19 ダウ グローバル テクノロジーズ インコーポレーテッド 多環式、縮合環化合物、金属錯体及び重合方法

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003044877A2 (en) * 2001-11-16 2003-05-30 Cdt Oxford Limited Light emitting device and compounds for use therein
EP1464657A1 (en) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenated metallocene catalyst
US6958377B2 (en) * 2003-10-15 2005-10-25 Equistar Chemicals, Lp Olefin polymerization process
EP1674523A1 (en) * 2004-12-22 2006-06-28 Total Petrochemicals Research Feluy Caps and closures
EP1721913A1 (en) * 2005-05-09 2006-11-15 Total Petrochemicals Research Feluy Microwave-promoted creation of catalytic species
JP5635234B2 (ja) 2005-07-19 2014-12-03 エクソンモービル・ケミカル・パテンツ・インク ポリαオレフィン組成物およびこれを生成するためのプロセス
US7592395B2 (en) * 2006-08-01 2009-09-22 Exxonmobil Chemical Patents Inc. Multimodal polyethylene for use in single piece beverage bottle caps and closures
EP2199078A1 (en) * 2008-12-22 2010-06-23 Total Petrochemicals Research Feluy Polyethylene and poly(hydroxy carboxylic acid) multilayer films
CN102464748B (zh) * 2010-11-16 2013-07-03 中国石油化工股份有限公司 一种丙烯共聚物大分子单体及其制备方法
CA2849093C (en) * 2011-10-10 2016-12-06 Exxonmobil Chemical Patents Inc. Poly alpha olefin compositions and process to produce poly alpha olefin compositions
CN104093730A (zh) * 2011-12-19 2014-10-08 沙特基础工业公司 用于制备茂金属络合物的方法
US9000200B2 (en) * 2011-12-19 2015-04-07 Saudi Basic Industries Corporation Process for the preparation of metallocene complexes
CN103509060B (zh) * 2012-06-27 2016-08-10 大林产业株式会社 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法
US9932423B2 (en) 2015-09-24 2018-04-03 Exxonmobil Chemical Patents Inc. Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such
WO2017118617A1 (en) 2016-01-05 2017-07-13 Sabic Global Technologies B.V. Catalyst comprising a metallocene complex and a co-catalyst
US10669356B2 (en) 2016-01-27 2020-06-02 Lg Chem, Ltd. Supported hybrid catalyst and method for preparing olefin polymer using the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05331230A (ja) * 1991-06-28 1993-12-14 Hoechst Ag 高分子量ポリオレフィンの製造用触媒および製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3840772A1 (de) 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE59104869D1 (de) 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
NL9201970A (nl) 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1276084B1 (it) * 1995-11-07 1997-10-24 Enichem Spa Ciclopentadienil derivati pontati e procedimento per la loro preparazione
IT1290856B1 (it) * 1996-12-19 1998-12-14 Enichem Spa Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05331230A (ja) * 1991-06-28 1993-12-14 Hoechst Ag 高分子量ポリオレフィンの製造用触媒および製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JPN6009053276, "Synthesis of ansa−Titanocenes from 1,2−Bis(2−indenyl)ethane and Structural Comparisons in the Cataly", Organometallics, 1995, Vol.14, No.8, p.3732−40 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003529572A (ja) * 2000-03-31 2003-10-07 ポリメーリ エウローパ ソシエタ ペル アチオニ 置換多環式シクロペンタジエン及びその製造方法
JP2004505019A (ja) * 2000-06-30 2004-02-19 ダウ グローバル テクノロジーズ インコーポレーテッド 多環式、縮合環化合物、金属錯体及び重合方法

Also Published As

Publication number Publication date
HUP0101157A2 (hu) 2001-07-30
WO2000029416A1 (en) 2000-05-25
CN1291986A (zh) 2001-04-18
BR9910192A (pt) 2001-05-22
EP1047702A1 (en) 2000-11-02
IL137036A0 (en) 2001-06-14
KR20010034211A (ko) 2001-04-25
ES2189516T3 (es) 2003-07-01
AU1270500A (en) 2000-06-05
AR021311A1 (es) 2002-07-17
DE69905011D1 (de) 2003-02-27
EP1047702B1 (en) 2003-01-22
DE69905011T2 (de) 2003-11-06
CA2317588A1 (en) 2000-05-25
US6541584B1 (en) 2003-04-01

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