JP2002530286A - オレフィン重合触媒としてのビス(テトラヒドロ−インデニル)メタロセン - Google Patents
オレフィン重合触媒としてのビス(テトラヒドロ−インデニル)メタロセンInfo
- Publication number
- JP2002530286A JP2002530286A JP2000582403A JP2000582403A JP2002530286A JP 2002530286 A JP2002530286 A JP 2002530286A JP 2000582403 A JP2000582403 A JP 2000582403A JP 2000582403 A JP2000582403 A JP 2000582403A JP 2002530286 A JP2002530286 A JP 2002530286A
- Authority
- JP
- Japan
- Prior art keywords
- group
- indenyl
- metallocene
- tetrahydro
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
- C07C13/465—Indenes; Completely or partially hydrogenated indenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98203905 | 1998-11-18 | ||
| EP98203905.9 | 1998-11-18 | ||
| PCT/EP1999/008647 WO2000029416A1 (en) | 1998-11-18 | 1999-11-10 | Bis(tetrahydro-indenyl) metallocenes as olefin-polymerisation-catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002530286A true JP2002530286A (ja) | 2002-09-17 |
| JP2002530286A5 JP2002530286A5 (enExample) | 2006-12-28 |
Family
ID=8234357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000582403A Pending JP2002530286A (ja) | 1998-11-18 | 1999-11-10 | オレフィン重合触媒としてのビス(テトラヒドロ−インデニル)メタロセン |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6541584B1 (enExample) |
| EP (1) | EP1047702B1 (enExample) |
| JP (1) | JP2002530286A (enExample) |
| KR (1) | KR20010034211A (enExample) |
| CN (1) | CN1291986A (enExample) |
| AR (1) | AR021311A1 (enExample) |
| AU (1) | AU1270500A (enExample) |
| BR (1) | BR9910192A (enExample) |
| CA (1) | CA2317588A1 (enExample) |
| DE (1) | DE69905011T2 (enExample) |
| ES (1) | ES2189516T3 (enExample) |
| HU (1) | HUP0101157A2 (enExample) |
| IL (1) | IL137036A0 (enExample) |
| WO (1) | WO2000029416A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003529572A (ja) * | 2000-03-31 | 2003-10-07 | ポリメーリ エウローパ ソシエタ ペル アチオニ | 置換多環式シクロペンタジエン及びその製造方法 |
| JP2004505019A (ja) * | 2000-06-30 | 2004-02-19 | ダウ グローバル テクノロジーズ インコーポレーテッド | 多環式、縮合環化合物、金属錯体及び重合方法 |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2002339174A1 (en) * | 2001-11-16 | 2003-06-10 | Cdt Oxford Limited | Light emitting device and compounds for use therein |
| EP1464657A1 (en) * | 2003-03-06 | 2004-10-06 | ATOFINA Research | Hydrogenated metallocene catalyst |
| US6958377B2 (en) * | 2003-10-15 | 2005-10-25 | Equistar Chemicals, Lp | Olefin polymerization process |
| EP1674523A1 (en) * | 2004-12-22 | 2006-06-28 | Total Petrochemicals Research Feluy | Caps and closures |
| EP1721913A1 (en) * | 2005-05-09 | 2006-11-15 | Total Petrochemicals Research Feluy | Microwave-promoted creation of catalytic species |
| US8748361B2 (en) | 2005-07-19 | 2014-06-10 | Exxonmobil Chemical Patents Inc. | Polyalpha-olefin compositions and processes to produce the same |
| US7592395B2 (en) * | 2006-08-01 | 2009-09-22 | Exxonmobil Chemical Patents Inc. | Multimodal polyethylene for use in single piece beverage bottle caps and closures |
| EP2199078A1 (en) * | 2008-12-22 | 2010-06-23 | Total Petrochemicals Research Feluy | Polyethylene and poly(hydroxy carboxylic acid) multilayer films |
| CN102464748B (zh) * | 2010-11-16 | 2013-07-03 | 中国石油化工股份有限公司 | 一种丙烯共聚物大分子单体及其制备方法 |
| RU2014118599A (ru) | 2011-10-10 | 2015-11-20 | Эксонмобил Кемикэл Пейтентс Инк. | Композиции поли-альфа-олефинов и способы получения композиций поли-альфа-олефинов |
| US9234054B2 (en) * | 2011-12-19 | 2016-01-12 | Saudi Basic Industries Corporation | Process for the preparation of metallocene complexes |
| PT2800754T (pt) * | 2011-12-19 | 2017-08-18 | Saudi Basic Ind Corp (Sabic) | Processo para a preparação de complexos metalocenos |
| CN103509060B (zh) * | 2012-06-27 | 2016-08-10 | 大林产业株式会社 | 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法 |
| US9932423B2 (en) | 2015-09-24 | 2018-04-03 | Exxonmobil Chemical Patents Inc. | Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such |
| WO2017118617A1 (en) | 2016-01-05 | 2017-07-13 | Sabic Global Technologies B.V. | Catalyst comprising a metallocene complex and a co-catalyst |
| EP3312201B1 (en) | 2016-01-27 | 2019-12-25 | LG Chem, Ltd. | Supported hybrid catalyst and method for preparing olefin polymer using the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05331230A (ja) * | 1991-06-28 | 1993-12-14 | Hoechst Ag | 高分子量ポリオレフィンの製造用触媒および製造方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3840772A1 (de) | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
| EP0485823B1 (de) | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
| ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
| NL9201970A (nl) | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| IT1276084B1 (it) * | 1995-11-07 | 1997-10-24 | Enichem Spa | Ciclopentadienil derivati pontati e procedimento per la loro preparazione |
| IT1290856B1 (it) * | 1996-12-19 | 1998-12-14 | Enichem Spa | Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine |
-
1999
- 1999-11-10 DE DE69905011T patent/DE69905011T2/de not_active Expired - Fee Related
- 1999-11-10 HU HU0101157A patent/HUP0101157A2/hu unknown
- 1999-11-10 CN CN99803373A patent/CN1291986A/zh active Pending
- 1999-11-10 ES ES99955972T patent/ES2189516T3/es not_active Expired - Lifetime
- 1999-11-10 AU AU12705/00A patent/AU1270500A/en not_active Abandoned
- 1999-11-10 IL IL13703699A patent/IL137036A0/xx unknown
- 1999-11-10 EP EP99955972A patent/EP1047702B1/en not_active Expired - Lifetime
- 1999-11-10 BR BR9910192-0A patent/BR9910192A/pt not_active Application Discontinuation
- 1999-11-10 WO PCT/EP1999/008647 patent/WO2000029416A1/en not_active Ceased
- 1999-11-10 JP JP2000582403A patent/JP2002530286A/ja active Pending
- 1999-11-10 CA CA002317588A patent/CA2317588A1/en not_active Abandoned
- 1999-11-10 US US09/600,350 patent/US6541584B1/en not_active Expired - Fee Related
- 1999-11-10 KR KR1020007007865A patent/KR20010034211A/ko not_active Withdrawn
- 1999-11-18 AR ARP990105861A patent/AR021311A1/es unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05331230A (ja) * | 1991-06-28 | 1993-12-14 | Hoechst Ag | 高分子量ポリオレフィンの製造用触媒および製造方法 |
Non-Patent Citations (1)
| Title |
|---|
| JPN6009053276, "Synthesis of ansa−Titanocenes from 1,2−Bis(2−indenyl)ethane and Structural Comparisons in the Cataly", Organometallics, 1995, Vol.14, No.8, p.3732−40 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003529572A (ja) * | 2000-03-31 | 2003-10-07 | ポリメーリ エウローパ ソシエタ ペル アチオニ | 置換多環式シクロペンタジエン及びその製造方法 |
| JP2004505019A (ja) * | 2000-06-30 | 2004-02-19 | ダウ グローバル テクノロジーズ インコーポレーテッド | 多環式、縮合環化合物、金属錯体及び重合方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1270500A (en) | 2000-06-05 |
| HUP0101157A2 (hu) | 2001-07-30 |
| EP1047702A1 (en) | 2000-11-02 |
| KR20010034211A (ko) | 2001-04-25 |
| IL137036A0 (en) | 2001-06-14 |
| CN1291986A (zh) | 2001-04-18 |
| DE69905011D1 (de) | 2003-02-27 |
| WO2000029416A1 (en) | 2000-05-25 |
| US6541584B1 (en) | 2003-04-01 |
| ES2189516T3 (es) | 2003-07-01 |
| DE69905011T2 (de) | 2003-11-06 |
| BR9910192A (pt) | 2001-05-22 |
| CA2317588A1 (en) | 2000-05-25 |
| AR021311A1 (es) | 2002-07-17 |
| EP1047702B1 (en) | 2003-01-22 |
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Legal Events
| Date | Code | Title | Description |
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