ES2189516T3 - Bis(tetrahidro-indenil) metallocenes como catalizadores de polimerizacion de las olefinas. - Google Patents
Bis(tetrahidro-indenil) metallocenes como catalizadores de polimerizacion de las olefinas.Info
- Publication number
- ES2189516T3 ES2189516T3 ES99955972T ES99955972T ES2189516T3 ES 2189516 T3 ES2189516 T3 ES 2189516T3 ES 99955972 T ES99955972 T ES 99955972T ES 99955972 T ES99955972 T ES 99955972T ES 2189516 T3 ES2189516 T3 ES 2189516T3
- Authority
- ES
- Spain
- Prior art keywords
- substituents
- group
- atoms
- integer
- ranges
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 125000001424 substituent group Chemical group 0.000 abstract 8
- 125000004429 atom Chemical group 0.000 abstract 6
- 229910052757 nitrogen Inorganic materials 0.000 abstract 4
- 230000000737 periodic effect Effects 0.000 abstract 4
- 229910052698 phosphorus Inorganic materials 0.000 abstract 4
- 229910052710 silicon Inorganic materials 0.000 abstract 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- 229910052796 boron Inorganic materials 0.000 abstract 3
- 229910052731 fluorine Inorganic materials 0.000 abstract 3
- 229920006395 saturated elastomer Polymers 0.000 abstract 3
- 229910052717 sulfur Inorganic materials 0.000 abstract 3
- -1 tetrahydro-indenyl Chemical group 0.000 abstract 3
- 229910052732 germanium Inorganic materials 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 125000001462 1-pyrrolyl group Chemical group [*]N1C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000000593 indol-1-yl group Chemical group [H]C1=C([H])C([H])=C2N([*])C([H])=C([H])C2=C1[H] 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
- C07C13/465—Indenes; Completely or partially hydrogenated indenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98203905 | 1998-11-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2189516T3 true ES2189516T3 (es) | 2003-07-01 |
Family
ID=8234357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99955972T Expired - Lifetime ES2189516T3 (es) | 1998-11-18 | 1999-11-10 | Bis(tetrahidro-indenil) metallocenes como catalizadores de polimerizacion de las olefinas. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6541584B1 (enExample) |
| EP (1) | EP1047702B1 (enExample) |
| JP (1) | JP2002530286A (enExample) |
| KR (1) | KR20010034211A (enExample) |
| CN (1) | CN1291986A (enExample) |
| AR (1) | AR021311A1 (enExample) |
| AU (1) | AU1270500A (enExample) |
| BR (1) | BR9910192A (enExample) |
| CA (1) | CA2317588A1 (enExample) |
| DE (1) | DE69905011T2 (enExample) |
| ES (1) | ES2189516T3 (enExample) |
| HU (1) | HUP0101157A2 (enExample) |
| IL (1) | IL137036A0 (enExample) |
| WO (1) | WO2000029416A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1318436B1 (it) * | 2000-03-31 | 2003-08-25 | Enichem Spa | Ciclopentadieni sostituiti policiclici e metodo per la loropreparazione. |
| AU2001275462A1 (en) * | 2000-06-30 | 2002-01-14 | Dow Global Technology Inc. | Polycyclic, fused ring compounds, metal complexes and polymerization process |
| WO2003044877A2 (en) * | 2001-11-16 | 2003-05-30 | Cdt Oxford Limited | Light emitting device and compounds for use therein |
| EP1464657A1 (en) * | 2003-03-06 | 2004-10-06 | ATOFINA Research | Hydrogenated metallocene catalyst |
| US6958377B2 (en) * | 2003-10-15 | 2005-10-25 | Equistar Chemicals, Lp | Olefin polymerization process |
| EP1674523A1 (en) * | 2004-12-22 | 2006-06-28 | Total Petrochemicals Research Feluy | Caps and closures |
| EP1721913A1 (en) * | 2005-05-09 | 2006-11-15 | Total Petrochemicals Research Feluy | Microwave-promoted creation of catalytic species |
| JP5635234B2 (ja) | 2005-07-19 | 2014-12-03 | エクソンモービル・ケミカル・パテンツ・インク | ポリαオレフィン組成物およびこれを生成するためのプロセス |
| US7592395B2 (en) * | 2006-08-01 | 2009-09-22 | Exxonmobil Chemical Patents Inc. | Multimodal polyethylene for use in single piece beverage bottle caps and closures |
| EP2199078A1 (en) * | 2008-12-22 | 2010-06-23 | Total Petrochemicals Research Feluy | Polyethylene and poly(hydroxy carboxylic acid) multilayer films |
| CN102464748B (zh) * | 2010-11-16 | 2013-07-03 | 中国石油化工股份有限公司 | 一种丙烯共聚物大分子单体及其制备方法 |
| CA2849093C (en) * | 2011-10-10 | 2016-12-06 | Exxonmobil Chemical Patents Inc. | Poly alpha olefin compositions and process to produce poly alpha olefin compositions |
| CN104093730A (zh) * | 2011-12-19 | 2014-10-08 | 沙特基础工业公司 | 用于制备茂金属络合物的方法 |
| US9000200B2 (en) * | 2011-12-19 | 2015-04-07 | Saudi Basic Industries Corporation | Process for the preparation of metallocene complexes |
| CN103509060B (zh) * | 2012-06-27 | 2016-08-10 | 大林产业株式会社 | 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法 |
| US9932423B2 (en) | 2015-09-24 | 2018-04-03 | Exxonmobil Chemical Patents Inc. | Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such |
| WO2017118617A1 (en) | 2016-01-05 | 2017-07-13 | Sabic Global Technologies B.V. | Catalyst comprising a metallocene complex and a co-catalyst |
| US10669356B2 (en) | 2016-01-27 | 2020-06-02 | Lg Chem, Ltd. | Supported hybrid catalyst and method for preparing olefin polymer using the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3840772A1 (de) | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
| DE59107926D1 (de) * | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| DE59104869D1 (de) | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. |
| DE4121368A1 (de) | 1991-06-28 | 1993-01-07 | Hoechst Ag | Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen |
| NL9201970A (nl) | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| IT1276084B1 (it) * | 1995-11-07 | 1997-10-24 | Enichem Spa | Ciclopentadienil derivati pontati e procedimento per la loro preparazione |
| IT1290856B1 (it) * | 1996-12-19 | 1998-12-14 | Enichem Spa | Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine |
-
1999
- 1999-11-10 CA CA002317588A patent/CA2317588A1/en not_active Abandoned
- 1999-11-10 US US09/600,350 patent/US6541584B1/en not_active Expired - Fee Related
- 1999-11-10 WO PCT/EP1999/008647 patent/WO2000029416A1/en not_active Ceased
- 1999-11-10 IL IL13703699A patent/IL137036A0/xx unknown
- 1999-11-10 DE DE69905011T patent/DE69905011T2/de not_active Expired - Fee Related
- 1999-11-10 HU HU0101157A patent/HUP0101157A2/hu unknown
- 1999-11-10 AU AU12705/00A patent/AU1270500A/en not_active Abandoned
- 1999-11-10 EP EP99955972A patent/EP1047702B1/en not_active Expired - Lifetime
- 1999-11-10 KR KR1020007007865A patent/KR20010034211A/ko not_active Withdrawn
- 1999-11-10 CN CN99803373A patent/CN1291986A/zh active Pending
- 1999-11-10 BR BR9910192-0A patent/BR9910192A/pt not_active Application Discontinuation
- 1999-11-10 JP JP2000582403A patent/JP2002530286A/ja active Pending
- 1999-11-10 ES ES99955972T patent/ES2189516T3/es not_active Expired - Lifetime
- 1999-11-18 AR ARP990105861A patent/AR021311A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0101157A2 (hu) | 2001-07-30 |
| WO2000029416A1 (en) | 2000-05-25 |
| CN1291986A (zh) | 2001-04-18 |
| BR9910192A (pt) | 2001-05-22 |
| EP1047702A1 (en) | 2000-11-02 |
| IL137036A0 (en) | 2001-06-14 |
| KR20010034211A (ko) | 2001-04-25 |
| AU1270500A (en) | 2000-06-05 |
| AR021311A1 (es) | 2002-07-17 |
| JP2002530286A (ja) | 2002-09-17 |
| DE69905011D1 (de) | 2003-02-27 |
| EP1047702B1 (en) | 2003-01-22 |
| DE69905011T2 (de) | 2003-11-06 |
| CA2317588A1 (en) | 2000-05-25 |
| US6541584B1 (en) | 2003-04-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR930010061A (ko) | 고분자량 올레핀 중합체의 제조방법 | |
| KR950008543A (ko) | 에틸렌 중합체의 제조방법 및 이 방법으로 부터 수득한 생성물 | |
| KR940005641A (ko) | 리간드로서 아릴- 치환된 인데닐 유도체를 함유하는 메탈로센, 이의 제조방법 및 촉매로서의 이의 용도 | |
| ATE386043T1 (de) | Metallocene und von ihnen abgeleitete katalysatorzusammensetzungen | |
| DE69501720D1 (de) | Katalysatoren und verfahren zur polymerisierung von olefinen | |
| RU2007138560A (ru) | Металлоценовые соединения | |
| KR900011794A (ko) | 올레핀류의 중합용 촉매 | |
| ES2187161T3 (es) | Catalizador ciclopentadienil/fosfinimina con uno y solo un ligando activable. | |
| RU96108407A (ru) | Катализаторы и процессы полимеризации олефинов | |
| DE69703728D1 (de) | Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen | |
| AR021311A1 (es) | Bis(tetrahidro-indenil)metalocenos y catalizadores para la polimerizacion de olefinas que los contienen. | |
| AR021294A1 (es) | Compuestos de metaloceno con puente, procedimiento para su preparacion, y su uso en sistemas cataliticos para la polimerizacion de olefinas | |
| KR970001378A (ko) | 전이금속 화합물 | |
| KR950008546A (ko) | 에틸렌의 탄성 공중합체의 제조방법 및 그로부터 수득된 생성물 | |
| HUP9801341A2 (hu) | Polimerizációs katalizátorok és eljárás előállításukra | |
| KR960022548A (ko) | 메탈로센 화합물 및 촉매 성분으로의 이의 용도 | |
| ES2161283T3 (es) | Utilizacion de derivados de estaño como catalizadores latentes de policondensacion y premezcla que los contiene. | |
| NO20011147L (no) | Diiminooforbindelser | |
| AR021312A1 (es) | Metalocenos de puente de metileno, procedimiento para su preparacion y su uso como componentes cataliticos en la polimerizacion de olefinas. | |
| DE69916358T2 (de) | Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation | |
| KR970001387A (ko) | 사이클로올레핀 공중합체의 제조방법 | |
| ES2196905T3 (es) | Catalizador de metaloceno bimetalico para polimerizacion de polipropileno isotactico. | |
| RU98123829A (ru) | Металлоцены и катализаторы полимеризации олефинов | |
| TH46049A (th) | บีส (เททราไฮโดร-อินดีนิล) เมทัลโลซีน และแคททาลีสท์สำหรับทำโพลีเมอไรเซชัน ของ โอลิฟิน ที่มีสารนั้น | |
| TH33769A (th) | แคตะลิสท์และกรรมวิธีสำหรับการโพลีเมอไรเซชันของโอลิฟิน |