JP2002128561A - Far infrared radiation ceramic ware - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a ceramic ware containing graphite silica emitting a far infrared radiation, especially a piece of the ceramic ware and a container or the like which improve quality of fluid or mineral water to take on pulses which facilitate the absorption and digestion by a human body. SOLUTION: This filed invention is related to the ceramic ware containing graphite silica and its usage.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to ceramics that emit far-infrared rays, and more particularly to ceramics.

[0002]

2. Description of the Related Art Generally, far-infrared rays have a characteristic characteristic of having a wavelength that shows a gentle peak in a band of 4 to 14 μm, and this wavelength band is called a growing wave by experimental observation in some fields. In recent years, it has been attracting attention because it has begun to be used. Such breeding waves are also included in sunlight in large amounts, and are known to be indispensable growth factors for the growth of animals and plants. However, at present, earthenware, pottery, or pottery containing the component composition emitting far-infrared rays has not yet been developed.

[0003]

The present invention relates to porcelain containing graphite silica as a component composition for radiating far-infrared rays, and particularly to porcelains and a method for producing them. It is an object of the present invention to provide a porcelain, particularly a porcelain produced from silica stone powder and clay, and a method for producing the same and a firing method. Another object is ceramics containing graphite silica, which emits far-infrared rays, especially ceramics or pottery porcelains, which improve to high-quality liquid or mineral water that is easily absorbed and digested by the human body. It is to provide pottery pieces and containers.

[0004]

Means for Solving the Problems The present invention relates to ceramics, particularly ceramics, containing graphite silica as a component that emits far-infrared rays. The graphite silica (also known as silica black) produced in the southern part of Hokkaido used in the present invention is SiO ₂
Silica, alumina such as Al ₂ O ₃ , carbon, iron components such as iron oxide and iron dioxide, other calcium such as calcium oxide, magnesium oxide such as MgO, T
It has been confirmed that it is composed of titanium oxides such as iO ₂ , sodium oxides such as Na ₂ O, potassium oxides such as K ₂ O, and the like. And for its use, experimental observations have shown that silica black emits far infrared radiation. Then, the graphite ore of the natural ore is further crushed to 5 μm or less, and heated at 1400 ° C. for 10 hours in a graphite crucible made of graphite, whereby a large amount of single crystal of silicon carbide having high strength grows. That has been observed. Focusing on such characteristics of graphite silica, the inventor of the present invention has made effective use of these properties and has intensively studied the pottery and the method of manufacturing pottery of the present invention to complete the present invention. Furthermore, the graphite silica used in the present invention is not only favorable for the formation of silicon nitride crystals, but also because of its rich composition and components as described above, not only ceramics that emit far-infrared rays, but also unique It can be used as a raw material for ceramics having a high gloss. According to the experiment of the present inventor, the amount of graphite silica contained in the ceramics of the present invention is increased as the mixing ratio of the fine powder of graphite silica increases, but the radiation amount of far-infrared rays increases. It has been found that ceramics, especially fired products and molded products such as ceramics, are likely to collapse due to the reduced amount of use of such materials, and it is difficult to maintain the shape. More specifically,
The characteristics of graphite silica were empirically confirmed as follows. It has a porous structure suitable for the adsorption of organic substances. Contains ferrite. H ₂ O, O ₂ or O
_When a magnetic material such as ₃ passes, an electric potential is induced. When contacted with negative ions, H ₂ O ⁻ , O _2
^-, O 3 ^-, by ionized molecules are generated as to have the effect of decomposing the material into small molecules. In the part exposed to light as an iron catalyst, silica black contains iron, which increases oxidation activity and enhances the decomposability of organic substances, and also exhibits properties such as being effective in accelerating the dechlorination reaction Have been. Therefore, according to the experiments of the present invention based on such properties, clays 500 to 9
50 parts and 1 to 50 parts of graphite silica are preferred, and 3 to 40 parts of graphite silica are particularly suitable from the viewpoint of the strength of products such as ceramics.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The porcelain of the present invention, in particular porcelain, includes various kinds of corals, if necessary, in addition to graphite silica.
It is preferred to include chromite and feldspar. The amount of silica used is preferably 1 to 50% by weight, the amount of chromite is preferably 1 to 30 parts, and the amount of feldspar is preferably 1 to 3%.
0 parts is preferred. According to experimental confirmation, the amount of chromite and feldspar is 10 to 3 with respect to 100 parts of graphite silica.
0 parts is preferred. In the case of pottery, the main raw material is the same as in the case of manufacturing normal pottery, and in addition to coral powder to clay used for container-shaped pottery, graphite-silica powder of 50-700 mesh is added. preferable. The inventor of the present application has confirmed through many experiments that mixing powdery coral has unexpectedly excellent effects such as baking.

The porcelain of the present invention, especially porcelains, emits a smooth color tone such as golden color and light with the emission of far-infrared rays by graphite silica stone. Applying a glaze made of ash gives a unique color and luster. As the glaze in the present invention, in addition to the conventional glaze usually used, powder of coral reef, ash of various trees are preferable, and especially banyan tree, hoyuboku, sugarcane, sotetsu, Ryukyu pine, Yonematsu, mokumau, straw, or chaff Is particularly preferred. The amount of ash used is preferably from 1 to 20% by weight. The banyan is golden. Also, 100 to 700 parts of graphite silica powder, 200 to 500 chromite powder
Part, manganese, cobalt or iron oxide, etc., from 1 to 100 feldspars composed of a combination of two or more.
Glaze may be applied by mixing 1 to 305 parts of ash consisting of one or two or more of the above ashes, or these components may be applied separately. When applying the glaze of the present invention to the main firing, apply it after unglazing, or when directly applying the main firing after molding, apply the glaze at the stage where the molded product is dried after the molding. . According to the invention of this application, unglazing is 600-
It is preferable to carry out the treatment at a temperature of 900 ° C. for 5 to 6 hours. However, if the temperature is increased sharply, the molded product will have a bad influence on the fired material or the kiln, such as damage to the furnace wall. It is preferred to raise. After unglazing in such a procedure, it may be allowed to cool naturally. Furthermore, the baked product of the present invention is manufactured by applying a glaze as required two to three weeks after unglazing, and by a usual porcelain firing method.
It is particularly preferable to bake at 180 to 1450 ° C. for 1 to 3 days. The kiln is not particularly limited as long as it sinters and manufactures ceramics, and electric kilns, gas kilns, kerosene kilns, climbing kilns,
Cave kilns and the like are used, but climbing kilns are preferred because they can produce a large amount of various types of ceramics.

The shape of the raw material used for the porcelain of the present invention, in particular, the baked product such as porcelain, is not particularly limited, but is premised on the use of far-infrared rays and the desired purpose of the molded product. The desired shape can be selected according to the purpose of use, such as fine particles, powder, granules, blocks, plates, rings, spheres, rods, pyramids, or cones. Further, the fired product obtained according to the present invention can be used as containers such as cups, bottles, pots, etc., like ordinary pottery. For example, for the treatment of water, any of spherical, rod-like, or containers can be used. For health promotion, ring shape,
Powder, or container or chip-shaped ceramic pieces are particularly preferred. More specifically, as for the treatment of water, harmful microorganisms and various germs therein are removed or sterilized by putting pottery or porcelain pieces of various shapes obtained by the present invention into a water storage tank, and in addition, water pipes and the like. Has the effect of preventing calcium carbonate, such as calcium, from adhering thereto, has the effect of preventing washing and rust, such as that calcium does not adhere to boiler tubes, and has the effect of reducing fuel consumption. Also,
The improvement of beverages has the effect of gently modifying tap water and other drinking water, milk, alcoholic beverages, and the like. Furthermore, it can also be used as a snow melting material, an antifreezing material, a soil modifying agent, a medium modifying agent, a filter material, and the like.

[0008] Pottery chips or powders for health may be used as they are. For example, by making them into fine particles or powders, they can be integrated with fibers, non-woven fabrics, fabrics, films, sheets and the like. It can also be worn as clothing for clothing, especially as a supporter for joints and the like.
It can also be used as a pulp material together with the plaster. Furthermore, by using as a container, for example,
Since it converts molecules such as milk and other milk drinks into small molecules, it can be converted into food and drink that does not cause diarrhea.

The porcelain or porcelain of the present invention is prepared by kneading feldspars such as dolomite or the like with silica such as clay, silica or ground powder to obtain a 650 to 1500 ° C.
Can be fired in the range of

[0010] The water purification treatment is performed, for example, by placing pottery or porcelain pieces, such as rods or spheres, in a container containing water, or by pouring water into a pot formed of pottery, and then mellowing the water. In addition, the generation of algae, bacteria, and the like can be suppressed by far-infrared rays emitted from pottery. In addition, water clusters (molecular structures) can be prepared and converted into water or liquid that is easily absorbed by cells. For example, simply putting milk in a porcelain cup fired with the raw material of the invention of the present application makes it easy to digest, and even people who have diarrhea with milk can drink it with confidence.

The pottery or powdery or pottery of the present invention is particularly preferably used for promoting health. For example, the deep penetrating power of far-infrared rays (reaching inside the tissue) is strong, and it warms the body from the inside and improves blood circulation, thereby alleviating stiff shoulders and lower back pain. In addition, it acts on the nervous system, thereby relieving pain and stimulating the activity of autonomic nervous system, and the warming sensation by this promoting action relieves stress and is excellent in preventing various diseases. By making the shape of the pottery convex, an acupressure effect can be exerted in addition to the far-infrared effect.

[0012]

The present invention will be specifically described below with reference to examples. Example 1 900 g of clay and 100 g of graphite silica were sufficiently kneaded,
After forming the desired fired product, it is dried for 1 to 20 days. Then, unbaked at 800 ° C. for 5 to 9 hours. Immediately after unglazing or after standing for 1 to 7 days, the molded product is sprayed or coated with bengara (1 to 20% by weight) as a glaze. Next, after the glaze is applied, firing is performed, but 1250 ° C.
For 1 to 3 days to obtain the desired pottery. Thus, cups, plates, jugs, pots and the like were manufactured. In addition, glaze is chromite powder 1-50 weight%, feldspar 1-5
0% by weight and 1 to 30% by weight of ash are simultaneously immersed in the molded product, or each component of the glaze is adjusted in a separate container, and the molded product is immersed in it three times,
Or apply. In this way, by partially or entirely applying the glaze, a pottery having a color tone showing a partial or overall decorative effect of the glaze can be obtained.

Example 2 900 g of clay and 100 g of graphite silica are mixed together, kneaded, and formed into a desired shape. Thereafter, the formed product is dried in the sun for 1 to 30 days. 100 to 700 g% of graphite silica powder, chromite powder 20
A glaze prepared by mixing 0 to 500 g%, 1 to 100% of feldspar such as feldspar, and 1 to 100% of ash content of 50 years old banyan tree was applied by a brush. In addition, as a whole glaze, 100 to 400% by weight of chromite powder, 1 to 100% by weight of feldspars combining one or two or more of feldspar, manganese, cobalt, or iron oxide, and 1 to 100% by weight of ash. Then, the molded product is immersed or applied to each of the containers in each container to adjust the partial or entire color of the pottery. After the glaze was applied, it was subjected to main firing at 1250 ° C. for 1 to 3 days to produce desired pots, cups, jugs, dishes, and the like.

EXAMPLE 3 800 g clay, 100 mesh powdered graphite silica 100
g, chromite 100g, kneaded well, length 10cm
And baked in a gas kettle at 1250 ° C. for 12 hours to produce a rod-shaped or ball-shaped product.

Example 4 Clay 800 g, graphite silica 100 g, chromite 100
g was kneaded well, molded into each shape, and dried for 2 weeks. 100 mesh powdered graphite silica 1-5
0% by weight, feldspar, manganese, cobalt or iron oxide
0% by weight and 1 to 30% by weight of ash are used as glaze.
For glaze, stir these three components at the same time and place in a container. The glaze is applied by a method of dipping the pre-dried shape in a mixture of three components and then immersing the whole, or by making three component glazes individually and partially dipping the shape in each,
Alternatively, any method may be used in which the color is applied to give a one-point color. The firing temperature at this time is 1180 to 125
0 ° C. Thus, a rectangular parallelepiped, a ball, a cup, a stick, and the like were manufactured.

Example 5 850 g of clay, 100 g of graphite silica powder, chromite 2
After sufficiently kneading 00 g and feldspar (manganese, cobalt, iron oxide) 50 g, a cup was formed, and this was mixed in a gas kettle.
Bake at 750 ° C. for hours. Next, after applying 10 g of banyan ash to the inner and outer surfaces of the unglazed cup,
This was baked at 1250 ° C. in a gas kettle to obtain the desired ceramic cup. 500 cc of water is added to the cup obtained by this method.
Was added and left for several minutes, water and associated molecular components were eluted and adjusted by far-infrared rays emitted from the pottery, and high quality drinking water containing mineral components was obtained. Similarly, instead of water, alcohol such as milk, wine, whiskey, liquor, and awamori can be improved to a mellow flavored beverage in a short time of about 1 to 2 minutes by this ceramic.

Example 6 850 g of clay, 100 g of graphite silica, 25 g of silica, and 25 g of chromite were sufficiently kneaded, and then kneaded.
The rod is shaped into a rod having a length of 10 cm and a length of 10 cm, and is baked in a gas kettle at 1250 ° C. for 5 to 12 hours to obtain a desired rod-shaped pottery. The rod-shaped porcelain thus obtained is placed in a milk bottle containing milk and left for 3 to 5 minutes, whereby it can be reformed into low-molecular milk with a deep wave.

Example 7 850 g of clay, 100 g of graphite silica, 30 g of silica and 20 g of chromite were kneaded, and the inner diameter was 10 cm and the outer diameter was 16 c.
A ring shape having a thickness of 1.5 cm and a thickness of 1.5 cm is formed and baked in a gas kettle at 1250 ° C. for 5 to 12 hours to obtain a ring-shaped ceramic bracelet. When the obtained ring-shaped bracelet is inserted into a part of the body, for example, an arm, the far-infrared ray emitted by the ceramic bracelet warms up around the mounting part of the bracelet, and blood flow is improved, and accordingly the body The whole thing became warm.

Example 8 Spherical and rod-shaped ceramics obtained by baking with the same components as in Example 6 were poured into a glass of wine, allowed to stand for 1 to 3 minutes, and then drunk to obtain a flavorful wine. Improved.

Example 9 850 g of clay, 100 g of graphite silica powder, chromite 2
00g, 50g feldspar well kneaded into a ball, 600-
Unbaked at 800 ° C. Next, 10 g of banyan ash that produces a golden color is applied to the unglazed surface,
Bake at 1250 ° C for 10 hours. When this golden ball-shaped pottery was put into 1000 cc of water, many mineral components contained in the pottery and the contact permeation site were eluted by far-infrared rays and became round. Furthermore, when the obtained ball was put in a container filled with milk, about 10
By placing a minute, people who had diarrhea with milk had no diarrhea when drinking milk treated with this pottery.

Example 10 900 g clay, 100 g graphite silica, 100 coral powder
g is sufficiently kneaded, formed into a rod having a diameter of 2 cm and a length of about 10 cm, and baked at 600 to 800 ° C. The sugarcane ash is then applied to the required portion of the unglazed surface in a conventional manner and fired at 1250 ° C. The porcelain stick obtained by molding and baking in this way is, for example, vertically inserted or inserted into a container filled with coffee and left alone for 5 to 10 minutes to produce a mellow, flavorful and rich coffee with a vibrating wave. Can be changed. Ceramics obtained by firing a ring having a diameter of 15 cm and obtained in the same manner as in Example 10 were formed into a ring shape, and fitted on an arm like a bracelet. The body became warm due to far infrared rays from the ceramics.

[0022]

The porcelain of the present invention has a size of 4 to 14 μm.
It emits far-infrared rays of m, for example, gives resonance resonance motion to water molecules, arranges water clusters (molecular structure), and creates water with small molecules in a short time, so that water that is easily absorbed by cells can be made. . In addition, this wavelength has a deep penetration force (reach to the inside of the tissue), warms the body from the inside and improves blood circulation, thereby contributing to improvement of blood flow and promotion of blood circulation. There is an excellent effect of relaxing. In addition, it acts on the nervous system, relieves pain and promotes the activity of autonomic nervous system. The warmth sensation caused by the far-infrared rays relieves stress and has an excellent effect in preventing various diseases. In addition, mineral water contained in pottery can make drinking water like Iwashimizu.Furthermore, calcium contained in tap water is removed by far-infrared rays to reduce damage to water pipes and the like due to calcium components in water. You can also
Further, by preventing calcium from adhering to a boiler or the like, fuel efficiency can be increased.

[Brief description of the drawings]

Fig. 1 Spectral radiant energy of graphite silica

Fig. 2 Spectral emissivity of graphite silica

Claims (18)

[Claims] 1. A ceramic comprising graphite silica. 2. The ceramic according to claim 1, wherein the amount of graphite silica is 3 to 70% by weight. 3. The method according to claim 1, further comprising the step of containing silica stone.
Or the porcelain according to 2. 4. The ceramic according to claim 1, further comprising chromite. 5. The method according to claim 1, comprising feldspar.
4. The ceramic according to any one of 4. 6. The method according to claim 1, further comprising a coral.
The ceramics according to any one of Items 1 to 4. 7. The ceramic according to claim 1, wherein a glaze is applied. 8. The ceramic according to claim 1, wherein the glaze contains ash. 9. The porcelain according to claim 7, wherein the ash is banyan tree, sugar cane, soju, pine, Ryukyu pine, bamboo tree, or casuarina. 10. The ceramic according to claim 7, wherein the glaze comprises graphite silica. 11. The ceramic of claim 7, wherein the glaze comprises chromite. 12. The ceramic according to claim 7, wherein the glaze contains at least one of manganese, cobalt and iron oxide. 13. The pottery according to claim 1, wherein the pottery is pottery. 14. A sterilizing material comprising the porcelain according to any one of claims 1 to 12. 15. A calcium adhesion preventing material for a water pipe, a boiler pipe or the like, comprising the ceramics according to claim 1. Description: 16. A water quality improving material comprising the porcelain according to claim 1. Description: 17. A beverage-improving material comprising the porcelain according to claim 1. Description: 18. A health-promoting material comprising the porcelain according to claim 1. Description: