JP2002003886A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain an acetic acid-containing detergent composition which can mask an acetic acid odor without intensifying the fragrance of the composition to a great extent and has good durability of the masking effect in use and an excellent feeling of its use. SOLUTION: This acetic acid-containing detergent composition comprises a perfume of a citrus type such as of Yuzu (a sort of orange produced in Japan) oil, lemon oil, lime oil, grapefruit oil, mandarin oil, and orange oil or a perfume of a fruity type which is a perfume of apple, peach, pineapple, strawberry, banana or grape type.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a cleaning composition. More specifically, the present invention relates to a cleaning composition containing acetic acid and / or vinegar, wherein the odor of acetic acid is reduced by blending a specific fragrance.

[0002]

2. Description of the Related Art Stains in kitchen sinks consist of inorganic stains containing silicon or calcium as a main component and oily stains from cooking or tableware, and a tub in a bathroom, a floor or a wall of a bathroom,
The dirt adhering to the wash basin or the toilet in the toilet room is composed of oily substances, fatty acid metal salts, calcium phosphate and the like secreted from the human body. On the other hand, stains on window glass are caused by dust in the atmosphere and nitrogen oxides, sulfur oxides, hydrocarbons, silicon oxides, iron oxides, etc. which are exhaust gas components of cars, and sebum such as cotton dust, cigarette dust and hand stains. Consists of dirt.
These stain components become stains that are very difficult to remove over a long period of time. Conventionally, as a detergent for removing these stains, an acidic detergent using hydroxycarboxylic acid or hydrochloric acid as an acidic substance, or a neutral or alkaline solution containing a sequestering agent represented by ethylenediaminetetraacetate and the like. Are known.

On the other hand, the cleaning effect of vinegar has been known for a long time, and JP-A-54-105108 discloses a method of cleaning with a detergent composition containing acetic acid and / or vinegar. However, when acetic acid or vinegar is added, a unique odor of acetic acid has to be put into use, so that a slight odor of vinegar must be tolerated during use, and there is a problem that the feeling of use of the product is significantly reduced.

[0004] In view of the above, a method of enhancing the feeling of use by adding a fragrance and masking the acetic acid odor is considered.
When acetic acid or vinegar is added in the required amount to enhance the cleaning effect, the amount is overwhelmingly greater than the amount of fragrance, so in the conventional technology, a strong fragrance is used to completely mask the acetic acid odor. There is no other way to perfume in large quantities. However, in this method, the problem that the aroma of the detergent composition becomes too strong, and in a kitchen close to the dining table, not only that the smell is strong but also that the smell affects the taste, the smell is extremely strong. There was a problem that cleaning agents were not suitable.

[0005]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to mask acetic acid odor without excessively intensifying the scent of the composition, and to provide a good feeling of use even when used in a kitchen or the like. An object of the present invention is to provide an excellent cleaning composition.

[0006]

Means for Solving the Problems As a result of intensive studies, the present inventors have found that the above-mentioned object can be achieved by blending a specific flavor component into a detergent composition containing acetic acid and / or vinegar. Was found. That is, the cleaning composition of the present invention contains (A) 0.1 to 8% by weight of acetic acid, (B) 0.001 to 1% by weight of a fruit-based flavor, and (C) 0.1 to 10% by weight of a surfactant. Is achieved by

Hereinafter, the cleaning composition of the present invention will be described in detail. As the acetic acid as the component (A) of the present invention, synthetic acetic acid, or processed vinegar or brewed vinegar is used. If the amount of acetic acid is too large, masking with a fragrance becomes difficult, and if the amount is too small, the washing effect of acetic acid is reduced, so that 0.1 to 8% by weight of the total composition is preferable.

The fruit flavors (B) of the present invention include citrus aroma of yuzu, lemon, lime, grapefruit, mandarin, orange or apple, peach, pineapple, strawberry,
There is no particular limitation as long as it emits a banana or grape-based scent, and one or a combination of two or more selected from the group consisting of natural fragrances, synthetic fragrances, and the like depending on the application is used.

Examples of the natural flavors include lemon oil, lime oil, grapefruit oil, mandarin oil, thyme red oil, pine oil, citronella oil, eucalyptus oil, lemongrass oil, orange oil, bergamot oil, camomil oil and the like.

Examples of the synthetic fragrance include terpene hydrocarbons such as limonene, camphene, α-pinene, β-pinene, γ-terpinene, terpinolene, myrcene and ocimene; borneol, citronellol, dihydromyrcenol, 2,6- Dimethylheptane-2-ol, geraniol, cis-3-hexenol, linalool, terpineol, α-phenkyl alcohol, phenylethyl alcohol, menthol, benzyl alcohol, anis alcohol, cinamic alcohol, butyl alcohol, isobutyl alcohol, amyl alcohol, Alcohols such as isoamyl alcohol, 2-methylbutanol, hexanol, trans-2-hexenol, 2-ethylhexanol, octanol, nerol, dimethylphenylethylcarbinol, etc. C6 to C12 aliphatic aldehydes, citral, citronellal, dimethyltetrahydrobenzaldehyde, isohexenylcyclohexenecarboxaldehyde, amylcinnamicaldehyde, hexylcinnamicaldehyde, perilaldehyde, cuminaldehyde, cyclamenaldehyde, acetaldehyde, butyraldehyde, 2-methylbutyraldehyde, valeraldehyde, isovaleraldehyde,
Aldehydes such as hexanal, trans-2-hexenal, benzaldehyde, phenylacetaldehyde, lillyaldehyde, laryl, helional, vanillin, ethylvanillin, heliotropin, furfural, and the like;
Camphor, sedolyl methyl ketone, methyl-β-naphthyl ketone, methyl heptenone, methyl-n-amyl ketone, carvone, menthone, acetophenone, yonone,
Nootkatone, γ-methylyonone, α-damascon, β
Ketones such as damascon, δ-damascon, β-damasenone, isodamascon, allylyonone, cis jasmon, dihydrojasmon, paramethylacetophenone, isomentone, pulegone, raspberry ketone; allyl amyl glycolate, allyl heptanoate, allyl hexanoate, Isoamyl acetate, benzyl acetate, o-tert-butylcyclohexyl acetate, cedrill acetate, citronellyl acetate, ethyl butyrate, ethyl methyl phenyl glycidate, geranyl acetate, cis-3-hexenyl acetate, n-
Hexyl acetate, linalyl acetate, methyl dihydrojasmonate, methyl anthranilate, methyl-N-methyl anthranilate, methyl phenylcarbinyl acetate, tricyclodecenyl acetate, terpinyl acetate, dihydroterpinyl acetate, methyl Benzoate, methyl cinnamate, methyl salicylate, ethyl acetate, propyl acetate, butyl acetate, octyl acetate, amyl acetate, hexyl acetate, trans-2-hexenyl acetate, 2-methylbutyl acetate, phenylethyl acetate, styryl acetate, Prenyl acetate, p-tert-butylcyclohexyl acetate, neryl acetate, dimethylbenzylcarbinyl acetate, ethyl acetoacetate G, ethyl propionate,
Allyl cyclohexane propionate, citronellyl propionate, neryl propionate, geranyl propionate, benzyl propionate, styryl propionate, tricyclodecenyl propionate, hexyl butyrate, isoamyl butyrate, Methyl-2-methylbutyrate, ethyl-2-methylbutyrate, cis-3-hexenylbutyrate, dimethylbenzylcarbylbutyrate, citronellylbutyrate, nerylbutyrate, geranylbutyrate, 2-methylbutylbutyrate , Ethyl isobutyrate, phenoxyethyl isobutyrate, ethyl isovalerate, isobutyl isovalerate, isoamyl isovalerate, 2-methylbutyl isovalerate, ethyl lactate, ethyl laurate, isoamyl ho Esters, hexylformate, methylhexanoate, ethylhexanoate, hexyl salicylate, phenylethyl salicylate, ethyl benzoate; benzoic acid, butyric acid, isovaleric acid, gernic acid Acids such as cineole, anethole, maltol, ethyl maltol, estragole, β-naphthyl ethyl ether, β-naphthyl methyl ether; coumarin, γ-undecalactone, γ-decalactone, γ-nonalactone, γ- Octalactone, γ-
Lactones such as dodecalactone, δ-decalactone, δ-undecalactone, δ-dodecalactone, cis jasmine lactone; acetaldehyde diethyl acetal;
Hexanal diethyl acetal, hexanal ethyl hexyl acetal, trans-2-hexenal diethyl acetal, hydratropaldehyde dimethyl acetal, phenylacetaldehyde dimethyl acetal,
Acetals such as phenylacetaldehyde glycerin acetal, acetaldehyde-2-phenyl-2,4-pentanediol acetal, acetaldehyde ethyl linalyl acetal; galact solid, tonalid,
Polycyclic musks such as Celestrid; macrocyclic musks such as ethylene brassate and cyclopentadecanolide; phenols such as thymol and nitrogen-containing compounds;

Particularly preferred are C6-C12 aliphatic aldehydes, citral, citronellal, dimethyltetrahydrobenzaldehyde, isohexenylcyclohexenecarboxaldehyde, amylcinamic aldehyde, acetaldehyde, butyl aldehyde, 2-methylbutyraldehyde, valeraldehyde, isovaler Aldehyde, hexanal, trans-2-hexenal,
Benzaldehyde, cuminaldehyde, phenylacetaldehyde, lilyaldehyde, liral, helional, hexylcinnamic aldehyde, vanillin, ethyl vanillin, cyclamenaldehyde, heliotropin,
Aldehydes consisting of furfural; borneol, citronellol, dihydromyrcenol, 2,6-dimethylheptane-2-ol, geraniol, cis-3-hexenol, linalool, terpineol, fenkyl alcohol, phenylethyl alcohol, butyl alcohol, isobutyl Consists of alcohol, amyl alcohol, isoamyl alcohol, 2-methylbutanol, hexanol, trans-2-hexenol, 2-ethylhexanol, octanol, nerol, menthol, benzyl alcohol, phenylethyl alcohol, dimethylphenylethylcarbinol, and cinnamic alcohol Alcohols: camphor, sedolyl methyl ketone, methyl β-naphthyl ketone, methylheptenone, yonone, γ-methylyono , Α-damascon, β-damascon, δ-damascon, β-damasenone, isodamascon, allylyonone, cis jasmon, dihydrojasmon, paramethylacetophenone, carvone, mentone,
Ketones consisting of isomentone, pulegone, raspberry ketone; allyl amyl glycolate, allyl heptanoate, allyl hexanoate, isoamyl acetate,
Benzyl acetate, o-tert-butylcyclohexyl acetate, cedril acetate, citronellyl acetate, ethyl butyrate, ethylmethylphenylglycidate, geranyl acetate, cis-3-hexenyl acetate, n-hexyl acetate, linalyl acetate, methyldihydrojas Monate, methyl anthranilate, methyl-N-methyl anthranilate, methyl phenylcarbinyl acetate, tricyclodecenyl acetate, ethyl acetate, propyl acetate, butyl acetate, octyl acetate, amyl acetate, trans-2-hexenyl Acetate, 2-methylbutyl acetate, phenylethyl acetate, styryl acetate, prenyl acetate, tricyclodecenyl acetate, p-ter t-butylcyclohexyl acetate, neryl acetate, dimethylbenzylcarbinyl acetate, ethyl acetoacetate, ethyl propionate, allyl cyclohexane propionate, citronellyl propionate, neryl propionate, geranyl propionate, benzyl propionate , Styrylpropionate, tricyclodecenylpropionate, hexylbutyrate, isoamylbutyrate, methyl-2-methylbutyrate, ethyl-2-methylbutyrate, cis-3-hexenylbutyrate, dimethylbenzyl Carvinyl butyrate, citronellyl butyrate,
Neryl butyrate, geranyl butyrate, 2-methylbutyl butyrate, ethyl isobutyrate, phenoxyethyl isobutyrate, ethyl isovalerate, isobutyl isovalerate, isoamyl isovalerate, 2-methylbutyl isovalerate, ethyl Esters consisting of lactate, ethyl laurate, isoamyl formate, hexyl formate, methyl hexanoate, ethyl hexanoate, allyl hexanoate, hexyl salicylate, phenylethyl salicylate, ethyl benzoate, methyl cinnamate Acetaldehyde-2-
Acetals comprising phenyl-2,4-pentanediol acetal, acetaldehyde ethyl linalyl acetal, acetaldehyde diethyl acetal, hexanal diethyl acetal, hexanal ethylhexyl acetal, hydratropaldehyde dimethyl acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde glycerin acetal; 1, 4
-Cineole, estragole, β-naphthyl ethyl ether, β-naphthyl methyl ether, ethers composed of anethole, maltol, ethyl maltol; phenols composed of thymol; limonene, camphene, α
Terpene hydrocarbons composed of pinene, β-pinene, γ-terpinene, terpinolene; γ-undecalactone;
Lactones composed of γ-decalactone, γ-nonalactone, γ-octalactone, γ-dodecalactone, δ-decalactone, δ-undecalactone, δ-dodecalactone, and cis-jasmine lactone; consisting of galactsolid, tonalid, and celestrid Polycyclic musks; macrocyclic musks composed of ethylene brassate and cyclopentadecanolide; and essential oils composed of grapefruit oil, lemon oil, lime oil, mandarin oil, orange oil and thyme red oil.

If the proportion of the fruit flavor which is a component of the present invention is too small, the acetic acid odor cannot be favorably masked. If it is too large, it is uneconomical. Therefore, the content of the fruit flavor is preferably in the range of 0.001 to 1% by weight, and particularly preferably 100/1 to 1/1 based on the pure acetic acid content.

The fruit-based flavor composition of the present invention may contain, if necessary, ordinary components contained in the flavor, such as antioxidants.

The fragrance may contain a fragrance compound other than the above components as long as the fragrance of the whole composition is not too strong.
-Isomethylyonone, synthetic sandals, trichloromethylphenylcarbinyl acetate, eugenol, geranylnitrile, dihydrorose oxide, decenol,
p-tert-butylcyclohexyl acetate, furtate, musk ketone, musk tibeten and the like.

The surfactant of the component (C) is soluble in perfume,
Increasing the dispersibility and stability has the effect of increasing the persistence of acetic acid odor masking, and increasing the foaming of the present detergent also enhances the masking effect. Examples of the surfactant include anionic surfactants, various surfactants such as nonionic surfactants and amphoteric surfactants, and examples of the anionic surfactant include alkylbenzene sulfonate and α-olefin sulfone. Acid salts, alkane sulfonates, alkyl diphenyl ether disulfonates, alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, alkyl or alkenyl ether carboxylates, alkyl or alkenyl phosphate salts, and the like can be used. Among them, it is preferable to use a sulfonic acid type anionic surfactant such as an alkylbenzene sulfonate having an average carbon number of 8 to 18 carbon atoms, an α-olefin sulfonate, an alkane sulfonate and an alkyl diphenyl ether disulfonate. it can. In this case, as a counter ion forming a salt, a sodium ion or a potassium ion is preferable.

Examples of the nonionic surfactant include, for example,
Polyoxyalkylene alkyl or alkenyl ether having an average alkyl group of 8 to 22 carbon atoms, polyoxyethylene alkyl phenyl ether or alkenyl ether,
Sucrose fatty acid esters, alkyl glucosides, fatty acid glycerin monoesters, higher fatty acid alkanolamides or alkylene oxide adducts thereof can be used. Among them, the average carbon number of the alkyl group is 8 to 1
Preferred are polyoxyalkylene alkyl or alkenyl ethers having 6 and ethylene oxide addition mole number of 5 to 16.

Examples of the amphoteric surfactant include an alkylamine oxide, an amino acid surfactant, an N-acyl amino acid surfactant, a betaine amphoteric surfactant, and a sulfonic acid amphoteric surfactant. In addition, an alkylpyrrolidone such as octylpyrrolidone and dodecylpyrrolidone, other cationic surfactants, silicone surfactants and fluorine surfactants may be blended. If the amount of these surfactants is too small, the sustaining effect and the cleaning effect of acetic acid odor masking become low, and if the amount is too large, it is uneconomical, so that the amount is 0.1 to 10% by weight. It is preferable that the mixing ratio of the surfactant is in the range of 1/2 to 1/300.

In the cleaning composition of the present invention, the components other than the above-mentioned components include a sequestering agent, a solvent, a hydrotrope, a thickener, an abrasive, an anti-redeposition agent, an inorganic electrolyte, a bactericide, and an enzyme. , A dye, and the like.
Examples of sequestering agents include, for example, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, glycol etherdiaminetetraacetic acid, hydroxyethyliminodiacetic acid,
Aminopolyacetic acid such as triethylenetetraminehexaacetic acid, nitrilotriacetic acid, iminodiacetic acid and / or a salt thereof, polyacrylic acid, polyfumaric acid, polymaleic acid, poly-α-
A polymer electrolyte such as hydroxyacrylic acid, polyacetal carboxylic acid and / or a salt thereof, a hydroxycarboxylic acid such as glycolic acid, citric acid, lactic acid, tartaric acid, malic acid, and gluconic acid, and / or a salt thereof; an orthophosphate;
Phosphate, tripolyphosphate, metaphosphate, hexametaphosphate, phosphates such as phytate, ethane-
Phosphonic acids such as 1,1-diphosphonic acid, ethane-1,1,2-triphosphonic acid, ethane-1-hydroxy-1,1-diphosphonic acid, ethanehydroxy-1,1,2-triphosphonic acid and / or Salt, 2-phosphonobutane-
1,2-dicarboxylic acid, 1-phosphonobutane-2,3
4-tricarboxylic acid, phosphonocarboxylic acid such as α-methylphosphonosuccinic acid and / or a salt thereof, aspartic acid,
Amino acids such as glutamic acid and glycine or salts thereof can be used. Among these sequestering agents, hydroxycarboxylic acids and / or salts thereof are preferable. Particularly, citric acid or malic acid or a salt thereof is erroneously used by a user to use a chlorine-based compound mainly containing hypochlorite or the like. It is more preferable because it has an effect of suppressing the amount of chlorine gas generated when used or mixed with a bleach or a detergent. Alkali metal salts are preferred as salts of these sequestering agents. The content of these sequestering agents is 20% by weight or less, preferably 0.1 to 16% by weight.

Examples of the solvent include lower alcohols such as ethanol and isopropanol; polyhydric alcohols such as ethylene glycol, propylene glycol and glycerin;
Ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether , Tripropylene glycol monomethyl ether, propylene glycol monobutyl ether, propylene glycol tert-butyl ether, dipropylene glycol monobutyl ether, tripropylene glycol monobutyl ether, polyoxyethylene (P = 1 to 3) polyoxypropylene (P = 1 to 4) glycol monoethyl ether (P indicates the average number of moles added), polyoxyethylene (P = 1 to 2) polyoxypropylene (P = 1 to 4)
3) glycol monobutyl ether, propylene glycol dimethyl ether, dipropylene glycol dimethyl ether, polyoxyethylene (P = 2-3) polyoxypropylene (P = 2-3) glycol dimethyl ether, polyoxyethylene (p = 2-4) glycol phenyl Glycol ether solvents such as ether, phenyl carbitol, phenyl cellosolve, and benzyl carbitol, and 3-methyl-3-methoxybutanol, methylpyrrolidone, and the like can be used. Is preferred. The content of these solvents is 15% by weight or less, preferably 1 to 10% by weight.

The hydrotrope agent can be blended as a solubilizer for fragrances or solvents which are hardly soluble in water, or as a stabilizer or a foam regulator for making the solution uniform, and specific examples include p-toluenesulfonic acid, m-xylene sulfonic acid or a salt thereof.

As the thickener, high molecular weight polysaccharides such as xanthan gum, carrageenan, locust bean gum, alginate and cellulose derivatives, high molecular weight polyacrylates and polyvinyl alcohol can be used.

Examples of abrasives include silica or porous silica, aluminum oxide, titanium oxide, aluminosilicate, silicon carbide, quartz sand, sand, shells and other natural pulverized materials, mica powder, silica, diatomaceous earth, kaoronite, halloysite,
Montmorillonite, illite, vermiculite and the like can be used.

As the anti-redeposition agent, low molecular weight polyethylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylate, carboxymethyl cellulose and the like can be used.

Hereinafter, the present invention will be described in more detail by way of examples.

A detergent composition having the composition shown in Table 3 was prepared by using a yuzu fragrance having the composition shown in Table 1 and a lime fragrance having the composition shown in Table 2, and (1) a masking test for acetic acid odor, and (2) acetic acid. An odor masking persistence test was performed. As a comparison, a detergent composition without fragrance was also tested. Table 3 shows the results.

[0026]

【table 1】

[0027]

[Table 2]

(1) Masking test for acetic acid odor The acetic acid odor when the detergent composition used as a sample was put into a trigger pump and sprayed was evaluated in three steps according to the following criteria. ×: When the acetic acid smell smells considerably △: When the acetic acid smell smells a little ○: When the acetic acid smell hardly smells

(2) Persistence test of acetic acid odor masking The detergent composition as a sample was sealed and stored in a plastic container,
C. for one month, and the acetic acid odor when the subsequent cleaning composition was sprayed into a trigger pump was evaluated in the same manner as above.

[0030]

[Table 3]

The cleaning compositions of Examples 1 to 4 all had good acetic acid odor masking effect and good acetic acid odor masking durability. On the other hand, in Comparative Examples 1 and 2, there was a pungent odor of acetic acid.

A cleaning composition having the composition shown in Table 6 was prepared using the apple fragrance having the composition shown in Table 4 and the peach fragrance having the composition shown in Table 5, and the same test was conducted. Table 6 shows the results.

[0033]

[Table 4]

[0034]

[Table 5]

[0035]

[Table 6]

The detergent compositions of Examples 5 to 10 all had good acetic acid odor masking effect and good acetic acid odor masking durability. On the other hand, in Comparative Examples 3 and 4, there was a pungent odor of acetic acid.

Pineapple fragrance having the composition shown in Table 7 and Table 8
A similar test was performed using a strawberry-based flavor having the following composition. As a result, even when these flavors were used, the masking effect of acetic acid odor and the persistence of acetic acid odor masking were good.

[0038]

[Table 7]

[0039]

[Table 8]

[0040]

[Practical test 1] Table 1 using lemon-based flavors having the composition shown in Table 9
A cleaning composition having a composition of No. 0 was prepared, and a practical test was conducted on a sink, a bathroom, a toilet, and a window glass to which dirt in a general household is attached, in terms of detergency and masking of acetic acid odor. Table 10 shows the results.

(1) Practical test in a sink A stainless steel sink to which dirt is attached was tested. 10 ml of the cleaning composition of Example 11 shown in Table 10 was soaked in a urethane sponge, and the entire inside of the sink was rubbed and washed. The degree of removal of the stain after washing and the maskability of acetic acid odor during washing were evaluated according to the following criteria. Detergency evaluation criteria ：: Stain is completely removed. Δ: There is unevenness in dirt removal. X: Almost no dirt is removed. Evaluation criteria for masking property of acetic acid odor ×: When acetic acid odor is quite odorable Δ: When acetic acid odor is slightly odorized ○: When acetic acid odor is hardly smelled (2) Practical test in bathroom In plastic bath with dirt attached Tested. 10 ml of the cleaning composition of Example 12 shown in Table 10 was impregnated into a urethane sponge, and the entire inside of the bath was rubbed and washed.
The degree of removal of stains after washing and the masking property of acetic acid odor during washing were evaluated in the same manner as above. (3) Practical test in toilet The test was performed on a toilet bowl with dirt. 10 ml of the cleaning composition of Example 13 shown in Table 10 was sprinkled on the soil and rubbed and washed with nylon scrub. The degree of removal of stains after washing and the masking property of acetic acid odor during washing were evaluated in the same manner as above. (4) Practical test on window glass A test was performed on a window glass to which dirt had adhered. The cleaning composition of Example 14 shown in Table 10 was sprayed with a trigger pump so as to wet the entire window glass, and immediately wiped and cleaned with a dry cloth. The degree of removal of stains after washing and the masking property of acetic acid odor during washing were evaluated in the same manner as above.

[0042]

[Table 9]

[0043]

[Table 10]

Each of the cleaning compositions of Examples 11 to 14 had a good masking effect of acetic acid odor, and also had excellent cleaning properties.

[0045]

[Practical test 2] A cleaning composition having the composition shown in Table 11 was prepared using an apple fragrance having the composition shown in Table 4 and a peach fragrance having the composition shown in Table 5. Practical tests were conducted on sinks, bathrooms, toilets, and windowpanes to which odor was adhered. Table 11 shows the results.

(1) Practical test in a sink The cleaning composition of Example 15 shown in Table 11 was evaluated in the same manner as in Practical test 1. (2) Practical test in bathroom The cleaning composition of Example 16 shown in Table 11 was evaluated in the same manner as in Practical test 1. (3) Practical test in toilet Using the cleaning composition of Example 18 shown in Table 11, evaluation was made in the same manner as in Practical test 1. Furthermore, the cleaning composition of Example 17 was sprayed so that the entire toilet seat was wet with a trigger pump, wiped off and washed with a dry cloth, and evaluated with the same evaluation criteria. (4) Practical test on window glass The cleaning composition of Example 19 shown in Table 11 was evaluated in the same manner as the practical test 1.

[0047]

[Table 11]

Each of the cleaning compositions of Examples 15 to 19 had a good masking effect of acetic acid odor, and also had excellent cleaning properties.

The cleaning composition of the present invention can mask acetic acid odor without excessively increasing the fragrance of the composition,
In addition, it has good masking continuity during use and is excellent in use feeling.

Claims (3)

[Claims] (1) 0.1 to 8% by weight of (A) acetic acid, (B) 0.001 to 1% by weight of a fruit flavor, and (C) 0.1 to 1% by weight of a surfactant.
A detergent composition masked with acetic acid odor, characterized by containing 0% by weight. 2. The fruit flavor is a citrus flavor of yuzu, lemon, lime, grapefruit, mandarin, orange or apple, peach, pineapple, strawberry, banana, grape flavor. Item 7. The cleaning composition according to Item 1. 3. A fruit-based flavor comprising a C6-C12 aliphatic aldehyde, citral, citronellal, dimethyltetrahydrobenzaldehyde, isohexenylcyclohexenecarboxaldehyde, amylcinamic aldehyde, acetaldehyde, butyraldehyde, 2-methylbutyraldehyde, valeraldehyde. , Isovaleraldehyde, hexanal, trans-2-hexenal,
Benzaldehyde, cuminaldehyde, phenylacetaldehyde, lilyaldehyde, liral, helional, hexylcinnamic aldehyde, vanillin, ethyl vanillin, cyclamenaldehyde, heliotropin,
Aldehydes consisting of furfural; borneol, citronellol, dihydromyrcenol, 2,6-dimethylheptane-2-ol, geraniol, cis-3-hexenol, linalool, terpineol, fenkyl alcohol, phenylethyl alcohol, butyl alcohol, isobutyl Consists of alcohol, amyl alcohol, isoamyl alcohol, 2-methylbutanol, hexanol, trans-2-hexenol, 2-ethylhexanol, octanol, nerol, menthol, benzyl alcohol, phenylethyl alcohol, dimethylphenylethylcarbinol, and cinnamic alcohol Alcohols: camphor, sedolyl methyl ketone, methyl β-naphthyl ketone, methylheptenone, yonone, γ-methylyono , Α-damascon, β-damascon, δ-damascon, β-damasenone, isodamascon, allylyonone, cis jasmon, dihydrojasmon, paramethylacetophenone, carvone, mentone,
Ketones consisting of isomentone, pulegone, raspberry ketone; allyl amyl glycolate, allyl heptanoate, allyl hexanoate, isoamyl acetate,
Benzyl acetate, o-tert-butylcyclohexyl acetate, cedril acetate, citronellyl acetate, ethyl butyrate, ethylmethylphenylglycidate, geranyl acetate, cis-3-hexenyl acetate, n-hexyl acetate, linalyl acetate, methyldihydrojas Monate, methyl anthranilate, methyl-N-methyl anthranilate, methyl phenylcarbinyl acetate, tricyclodecenyl acetate, ethyl acetate, propyl acetate, butyl acetate, octyl acetate, amyl acetate, trans-2-hexenyl Acetate, 2-methylbutyl acetate, phenylethyl acetate, styryl acetate, prenyl acetate, tricyclodecenyl acetate, p-ter t-butylcyclohexyl acetate, neryl acetate, dimethylbenzylcarbinyl acetate, ethyl acetoacetate, ethyl propionate, allyl cyclohexanepropionate, citronellyl propionate, neryl propionate, geranyl propionate, benzyl propionate , Styrylpropionate, tricyclodecenylpropionate, hexyl butyrate, isoamyl butyrate, methyl-2-methylbutyrate, ethyl-2-methylbutyrate, cis-3-hexenylbutyrate, dimethylbenzyl Carvinyl butyrate, citronellyl butyrate,
Neryl butyrate, geranyl butyrate, 2-methylbutyl butyrate, ethyl isobutyrate, phenoxyethyl isobutyrate, ethyl isovalerate, isobutyl isovalerate, isoamyl isovalerate, 2-methylbutyl isovalerate, ethyl Esters consisting of lactate, ethyl laurate, isoamyl formate, hexyl formate, methyl hexanoate, ethyl hexanoate, allyl hexanoate, hexyl salicylate, phenylethyl salicylate, ethyl benzoate, methyl cinnamate Acetaldehyde-2-
Acetals comprising phenyl-2,4-pentanediol acetal, acetaldehyde ethyl linalyl acetal, acetaldehyde diethyl acetal, hexanal diethyl acetal, hexanal ethylhexyl acetal, hydratropaldehyde dimethyl acetal, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde glycerin acetal; 1, 4
-Cineole, estragole, β-naphthyl ethyl ether, β-naphthyl methyl ether, ethers composed of anethole, maltol, ethyl maltol; phenols composed of thymol; limonene, camphene, α
Terpene hydrocarbons consisting of pinene, β-pinene, γ-terpinene, terpinolene; γ-undecalactone;
Lactones composed of γ-decalactone, γ-nonalactone, γ-octalactone, γ-dodecalactone, δ-decalactone, δ-undecalactone, δ-dodecalactone, and cis-jasmin lactone; Polycyclic musks; Macrocyclic musks composed of ethylene brassate and cyclopentadecanolide; one or two selected from grapefruit oil, lemon oil, lime oil, mandarin oil, orange oil, and thyme red oil The cleaning composition according to claim 1 or 2, comprising the above components.