JPH05112798A - Acidic detergent composition - Google Patents
Acidic detergent compositionInfo
- Publication number
- JPH05112798A JPH05112798A JP3339275A JP33927591A JPH05112798A JP H05112798 A JPH05112798 A JP H05112798A JP 3339275 A JP3339275 A JP 3339275A JP 33927591 A JP33927591 A JP 33927591A JP H05112798 A JPH05112798 A JP H05112798A
- Authority
- JP
- Japan
- Prior art keywords
- acetic acid
- detergent composition
- acidic detergent
- acid
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、酢酸を洗浄活性成分と
して含有する酸性洗浄剤組成物に関し、更に詳しくは、
浴室やトイレなどの洗浄に好適に使用できる酸性洗浄剤
組成物に関するものである。FIELD OF THE INVENTION The present invention relates to an acidic detergent composition containing acetic acid as a cleaning active ingredient.
The present invention relates to an acidic detergent composition that can be suitably used for cleaning bathrooms, toilets and the like.
【０００２】[0002]
【従来の技術】従来、酸性洗浄剤は、汚れを除去する効
果がすぐれていることから広く使用され、その洗浄活性
成分として、塩酸、硫酸等の無機酸、あるいは、クエン
酸、リンゴ酸、シュウ酸、スルファミン酸などの有機酸
が用いられてきた。しかしながら、特に無機酸を含有す
る洗浄剤は、使用後に水洗いを十分に行なわないと、錆
の発生や器具の損傷を生じるという欠点があった。更に
近年では、塩素系漂白剤と誤って混合した場合に、塩素
ガスが発生し、死亡事故を引き起こすといった憂慮すべ
き問題も生じている。2. Description of the Related Art Conventionally, acidic detergents have been widely used because of their excellent effect of removing stains. As the active ingredients for washing, inorganic acids such as hydrochloric acid and sulfuric acid, or citric acid, malic acid and oxalic acid are used. Organic acids such as acids and sulfamic acids have been used. However, a cleaning agent containing an inorganic acid, in particular, has a drawback that rusting and damage to equipment occur unless it is sufficiently washed with water after use. Furthermore, in recent years, there has been a worrisome problem that chlorine gas is generated when a chlorine-based bleaching agent is mistakenly mixed, causing a fatal accident.
【０００３】一方、酢酸は、有機溶剤として、あるいは
繊維加工や染色に、または、酢酸セルロース、酢酸ビニ
ル等の高分子化合物や各種工業薬品、医薬品、合成酢等
の原料として汎用され、更に最近では、電子工業界にお
いて、シリコンウェハー等の洗浄剤への添加剤としても
重用されている。しかし、家庭用の洗浄剤としては、塩
酸、硫酸等に比べて安全性が高く、また、クエン酸、シ
ュウ酸等の有機酸より洗浄力にすぐれているものの、使
用時に酢酸特有の臭いがあることや、前述したように、
塩素系漂白剤と混合した時に塩素ガスの発生が免れ得な
いという問題点があった。On the other hand, acetic acid is widely used as an organic solvent, for fiber processing and dyeing, or as a raw material for polymer compounds such as cellulose acetate and vinyl acetate, various industrial chemicals, pharmaceuticals and synthetic vinegar, and more recently. In the electronic industry, it is also heavily used as an additive to cleaning agents such as silicon wafers. However, as a household cleaning agent, it is more safe than hydrochloric acid, sulfuric acid, etc., and has a detergency superior to that of organic acids such as citric acid and oxalic acid, but it has a peculiar odor when used. As mentioned above,
There was a problem that generation of chlorine gas was inevitable when mixed with a chlorine bleach.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、安全性の高
い酢酸を含有する酸性洗浄剤であって、しかも、塩素系
漂白剤と混合してもほとんど塩素ガスを発生することが
なく、なおかつ酢酸特有の臭いを抑えた酸性洗浄剤組成
物を提供することを目的とする。DISCLOSURE OF THE INVENTION The present invention is a highly safe acidic detergent containing acetic acid, which hardly produces chlorine gas even when mixed with a chlorine bleach, and An object is to provide an acidic detergent composition in which the odor peculiar to acetic acid is suppressed.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するた
め、本発明は、（ａ）酢酸、（ｂ）界面活性剤の１種ま
たは２種以上、（ｃ）酢酸に対して５０％以上の過酸化
水素、および（ｄ）高分子多糖類の１種または２種以
上、を含有する酸性洗浄剤組成物に係る。In order to achieve the above object, the present invention provides (a) acetic acid, (b) one or more kinds of surfactants, and (c) 50% or more of acetic acid. The present invention relates to an acidic detergent composition containing hydrogen peroxide, and (d) one or more polymeric polysaccharides.
【０００６】[0006]
【作用】本発明の酸性洗浄剤組成物に含有される（ａ）
酢酸の量は、通常、１．０〜１０重量％で、好ましくは
２．０〜６．０重量％である。１．０重量％以下では洗
浄力が不十分であり、１０重量％を越えると酢酸臭の除
臭がむずかしい。(Function) (a) contained in the acidic detergent composition of the present invention
The amount of acetic acid is usually 1.0 to 10% by weight, preferably 2.0 to 6.0% by weight. If it is 1.0% by weight or less, the detergency is insufficient, and if it exceeds 10% by weight, it is difficult to remove the acetic acid odor.
【０００７】本発明で用いられる（ｂ）界面活性剤とし
ては、アニオン系界面活性剤、非イオン系界面活性剤、
両性界面活性剤が一般的で、通常、０．０１〜１０重量
％、好ましくは、０．１〜５．０重量％配合される。ア
ニオン系界面活性剤としては、酸性から弱酸性領域で安
定なものが好ましく、例えば、アルキルジフェニルエー
テルスルホネート、アルキルベンゼンスルホネート、ア
ルカンスルホネート、アルキルフェノールポリオキシエ
チレンエーテルサルフェート、ポリオキシエチレンアル
キルエーテルサルフェート等があげられる。非イオン系
界面活性剤についても特に限定されないが、例えば、ポ
リオキシエチレンアルキルエーテル、ポリオキシエチレ
ンポリオキシプロピレンアルキルエーテル、ポリオキシ
エチレンノニルフェニルエーテル、ポリオキシエチレン
ポリオキシプロピレンブロックポリマー、高級脂肪酸ア
ルカノールアミド、またはそのエチレンオキサイド付加
物、アミンオキサイドなどを例示できる。また、両性界
面活性剤としては、カルボン酸型、硫酸エステル型、ス
ルホン酸型、リン酸エステル型などがあげられるが、特
に、カルボン酸型であるベタイン型両性界面活性剤が好
ましい。これらの界面活性剤は、同種、異種にかかわら
ず、１種もしくは２種以上が用いられる。The surfactant (b) used in the present invention includes anionic surfactants, nonionic surfactants,
An amphoteric surfactant is generally used, and is usually added in an amount of 0.01 to 10% by weight, preferably 0.1 to 5.0% by weight. As the anionic surfactant, those which are stable in the acidic to weakly acidic region are preferable, and examples thereof include alkyldiphenyl ether sulfonate, alkylbenzene sulfonate, alkane sulfonate, alkylphenol polyoxyethylene ether sulfate, polyoxyethylene alkyl ether sulfate and the like. The nonionic surfactant is not particularly limited, and examples thereof include polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene polyoxypropylene block polymer, and higher fatty acid alkanolamide. , Or its ethylene oxide adduct, amine oxide, and the like. Examples of the amphoteric surfactant include carboxylic acid type, sulfuric acid ester type, sulfonic acid type, phosphoric acid ester type, and the like, and the carboxylic acid type betaine type amphoteric surfactant is particularly preferable. These surfactants may be the same kind or different kinds, and one kind or two kinds or more are used.
【０００８】本発明は、塩素系漂白剤と混合した時でも
塩素ガスの発生を抑制するため、（ｃ）過酸化水素を配
合したことに特徴を有する。過酸化水素の含有量は、酢
酸の含有量に対して５０％以上が必要で、通常、０．５
〜１０重量％が適当である。過酸化水素が、塩素の発生
防止に効果的な理由については不明な点が多いが、過酸
化水素の酸化作用が、次亜塩素酸からの塩素発生メカニ
ズムをブロックするものと考えられる。The present invention is characterized in that it contains (c) hydrogen peroxide in order to suppress generation of chlorine gas even when mixed with a chlorine bleach. The content of hydrogen peroxide should be 50% or more with respect to the content of acetic acid.
-10 wt% is suitable. Although there are many unclear points about why hydrogen peroxide is effective in preventing the generation of chlorine, it is considered that the oxidizing action of hydrogen peroxide blocks the mechanism of chlorine generation from hypochlorous acid.
【０００９】本発明では更に、酢酸の臭いを抑えると共
に、増粘効果を付与するために（ｄ）高分子多糖類が必
須成分として配合される。高分子多糖類としては、カラ
ギーナン、キサンタンガム、カラヤガム、トラガントガ
ム、グアーガムがあげられ、適宜、１種または２種以上
が、０．５〜５．０重量％添加される。Further, in the present invention, (d) a high molecular polysaccharide is added as an essential component in order to suppress the odor of acetic acid and impart a thickening effect. Examples of the high molecular polysaccharide include carrageenan, xanthan gum, karaya gum, tragacanth gum, and guar gum, and one kind or two or more kinds are appropriately added in an amount of 0.5 to 5.0% by weight.
【００１０】更に、本発明の酸性洗浄剤組成物には、必
要に応じて、過酸化水素の安定剤、ハイドロトロープ
剤、香料、着色剤、また、洗浄力向上剤として、ホスホ
ン酸基含有化合物、ヒドロキシ多価カルボン酸またはそ
の塩等のキレート剤、有機酸、無機酸等を任意に加える
ことができる。過酸化水素の安定剤としては、アミノポ
リカルボン酸類、トリポリリン酸塩などや、α−トコフ
ェロール、ＢＨＴ、ＢＨＡなどの酸化防止剤があげられ
る。Furthermore, if necessary, the acidic detergent composition of the present invention contains a phosphonic acid group-containing compound as a stabilizer for hydrogen peroxide, a hydrotrope, a fragrance, a colorant, and a detergent for improving detergency. A chelating agent such as a hydroxy polycarboxylic acid or a salt thereof, an organic acid, an inorganic acid or the like can be optionally added. Examples of hydrogen peroxide stabilizers include aminopolycarboxylic acids, tripolyphosphates, and antioxidants such as α-tocopherol, BHT, and BHA.
【００１１】こうして得られた本発明の酸性洗浄剤を、
浴室、トイレ、台所等で使用すれば、酢酸の臭いを気に
することなく、酢酸のすぐれた洗浄力によって汚れを手
軽に、かつ確実に除去できるものである。また、塩素系
漂白剤と混合しても塩素ガスを発生しないので、本発明
の酸性洗浄剤は、安全性の面でも非常にすぐれていると
いえる。The acidic detergent of the present invention thus obtained is
If it is used in a bathroom, a toilet, a kitchen, etc., stains can be easily and surely removed without worrying about the smell of acetic acid by the excellent cleaning power of acetic acid. Further, since chlorine gas is not generated even when mixed with a chlorine-based bleaching agent, it can be said that the acidic cleaning agent of the present invention is also very excellent in safety.
【００１２】次に試験例及び実施例をあげて本発明をよ
り詳細に説明するが、本発明はその要旨を越えない限り
これらのみに限定されるものではない。Next, the present invention will be described in more detail with reference to test examples and examples, but the present invention is not limited to these as long as the gist thereof is not exceeded.
【００１３】[0013]
【試験例】下表に示す組成の酸性洗浄剤組成物を調製
し、家庭用品品質表示法に規定された塩素ガス発生試験
により塩素ガスの測定を行うと共に、酢酸臭の強さを官
能的に評価した。なお、評価基準は以下のとおりとし
た。 評価基準 ○ ； 酢酸臭をほとんど感じない。 △ ； 酢酸臭をやや感じる。 × ； 酢酸臭を強く感じる。[Test example] An acidic detergent composition having the composition shown in the table below was prepared, and chlorine gas was measured by the chlorine gas generation test specified in the Household Goods Quality Labeling Method. evaluated. The evaluation criteria are as follows. Evaluation Criteria O: Almost no acetic acid odor is felt. Δ: The smell of acetic acid is slightly felt. X: A strong smell of acetic acid is felt.
【００１４】[0014]
【表１】 [Table 1]
【００１５】試験の結果、酢酸ならびに界面活性剤に、
過酸化水素、および高分子多糖類を配合した本発明洗浄
剤組成物は、塩素系漂白剤と混合しても塩素ガスを発生
することがなく、また酢酸臭が気になることもなかっ
た。一方、過酸化水素が無添加、あるいは酢酸に対して
５０％量以下の組成物（対照洗浄剤２，３）では、塩素
ガスの発生を防止できず、更に、対照洗浄剤４，５のよ
うに、高分子多糖類が０．５重量％以下の組成物では、
酢酸臭を抑えることができず不適であった。As a result of the test, acetic acid and a surfactant were added,
The cleaning composition of the present invention containing hydrogen peroxide and a high molecular polysaccharide did not generate chlorine gas even when mixed with a chlorine-based bleaching agent, and did not cause acetic acid odor. On the other hand, the composition containing no hydrogen peroxide or containing 50% or less of acetic acid (control detergents 2 and 3) cannot prevent the generation of chlorine gas, and is more difficult than the control detergents 4 and 5. In a composition containing 0.5% by weight or less of high molecular polysaccharide,
It was unsuitable because it could not suppress the acetic acid odor.
【００１６】[0016]
【実施例】酢酸５．０重量％、アルキルベンゼンスルホ
ネート２．０重量％、ポリオキシエチレンアルキルエー
テル１．５重量％、過酸化水素４．０重量％、キサンタ
ンガム２．０重量％、アミノポリカルボン酸０．５重量
％及び着色剤微量を混合して酸性洗浄剤組成物を調製し
た。この酸性洗浄剤をトイレの黄バミに処理したとこ
ろ、汚れを完全に除去でき、酢酸臭は全く気にならなか
った。EXAMPLE 5.0% by weight acetic acid, 2.0% by weight alkylbenzene sulfonate, 1.5% by weight polyoxyethylene alkyl ether, 4.0% by weight hydrogen peroxide, 2.0% by weight xanthan gum, aminopolycarboxylic acid An acidic detergent composition was prepared by mixing 0.5% by weight and a trace amount of a colorant. When this acidic cleaning agent was applied to toilet yellow bami, stains could be completely removed and the acetic acid odor was not noticed at all.
【００１７】[0017]
【発明の効果】本発明は、塩素系漂白剤と混合してもほ
とんど塩素ガスを発生することがなく、かつ酢酸特有の
臭いを抑えた酸性洗浄剤組成物を提供する。INDUSTRIAL APPLICABILITY The present invention provides an acidic detergent composition which hardly generates chlorine gas even when mixed with a chlorine bleach and suppresses the odor peculiar to acetic acid.
Claims (2)
は２種以上、（ｃ）酢酸に対して５０％以上の過酸化水
素、および（ｄ）高分子多糖類の１種または２種以上、
を含有することを特徴とする酸性洗浄剤組成物。1. A type of (a) acetic acid, (b) one or more types of surfactants, (c) 50% or more hydrogen peroxide relative to acetic acid, and (d) one type of polymeric polysaccharide. Or two or more,
An acidic detergent composition comprising:
サンタンガム、カラヤガム、トラガントガム、グアーガ
ムである請求項１記載の酸性洗浄剤組成物。2. The acidic detergent composition according to claim 1, wherein the high-molecular polysaccharide (d) is carrageenan, xanthan gum, karaya gum, tragacanth gum, or guar gum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3339275A JPH05112798A (en) | 1991-10-22 | 1991-10-22 | Acidic detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3339275A JPH05112798A (en) | 1991-10-22 | 1991-10-22 | Acidic detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH05112798A true JPH05112798A (en) | 1993-05-07 |
Family
ID=18325913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3339275A Pending JPH05112798A (en) | 1991-10-22 | 1991-10-22 | Acidic detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH05112798A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0667392A2 (en) * | 1994-02-14 | 1995-08-16 | JEYES GROUP plc | Bleach compositions |
| JP2001354994A (en) * | 2000-06-12 | 2001-12-25 | Dainippon Jochugiku Co Ltd | Agent and process for reducing acetic acid odor of acetic acid-compounded detergent composition for bathroom and kitchen |
| JP2002003886A (en) * | 2000-04-19 | 2002-01-09 | Dainippon Jochugiku Co Ltd | Detergent composition |
| WO2007118835A1 (en) * | 2006-04-13 | 2007-10-25 | Akzo Nobel N.V. | Aqueous hydrogen peroxide-containing composition and its use for cleaning surfaces |
| JP2013053286A (en) * | 2011-09-01 | 2013-03-21 | Amtec Co Ltd | Chlorine gas reducing agent |
| JP2013053287A (en) * | 2011-09-01 | 2013-03-21 | Amtec Co Ltd | Chlorine gas reducing agent constituting composite with base material |
| JP2019104838A (en) * | 2017-12-13 | 2019-06-27 | 大日本除蟲菊株式会社 | Acetic acid odor depressant and acetic acid cleaning agent composition containing the same |
-
1991
- 1991-10-22 JP JP3339275A patent/JPH05112798A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0667392A2 (en) * | 1994-02-14 | 1995-08-16 | JEYES GROUP plc | Bleach compositions |
| EP0667392A3 (en) * | 1994-02-14 | 1995-11-15 | Jeyes Group Plc | Bleach compositions. |
| JP2002003886A (en) * | 2000-04-19 | 2002-01-09 | Dainippon Jochugiku Co Ltd | Detergent composition |
| JP2001354994A (en) * | 2000-06-12 | 2001-12-25 | Dainippon Jochugiku Co Ltd | Agent and process for reducing acetic acid odor of acetic acid-compounded detergent composition for bathroom and kitchen |
| JP4711488B2 (en) * | 2000-06-12 | 2011-06-29 | 大日本除蟲菊株式会社 | A method for reducing acetic acid odor in a detergent composition containing acetic acid for bathrooms and kitchens. |
| WO2007118835A1 (en) * | 2006-04-13 | 2007-10-25 | Akzo Nobel N.V. | Aqueous hydrogen peroxide-containing composition and its use for cleaning surfaces |
| JP2009533510A (en) * | 2006-04-13 | 2009-09-17 | アクゾ ノーベル ナムローゼ フェンノートシャップ | Aqueous hydrogen peroxide-containing composition and use thereof for cleaning surfaces |
| US7824503B2 (en) | 2006-04-13 | 2010-11-02 | Akzo Nobel N.V. | Aqueous hydrogen peroxide-containing composition and its use for cleaning surfaces |
| JP2013053286A (en) * | 2011-09-01 | 2013-03-21 | Amtec Co Ltd | Chlorine gas reducing agent |
| JP2013053287A (en) * | 2011-09-01 | 2013-03-21 | Amtec Co Ltd | Chlorine gas reducing agent constituting composite with base material |
| JP2019104838A (en) * | 2017-12-13 | 2019-06-27 | 大日本除蟲菊株式会社 | Acetic acid odor depressant and acetic acid cleaning agent composition containing the same |
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