JP2019104838A - Acetic acid odor depressant and acetic acid cleaning agent composition containing the same - Google Patents

Abstract

To provide an acetic acid odor depressant capable of masking an acetic acid odor without excessively strengthening a flavor of a composition, and an acetic acid cleaning agent composition containing the same.SOLUTION: An acetic acid odor depressant of this invention is composed of one or more kinds of alkyl glycosides and is blended with an acetic acid cleaning agent composition containing acetic acid as an effective component.SELECTED DRAWING: None

Description

  The present invention relates to an acetic acid odor control agent which is mixed with an acetic acid detergent composition containing acetic acid as an active ingredient to suppress an acetic acid odor at the time of use, and an acetic acid detergent composition containing the same.

  The dirt in the kitchen sink consists of inorganic dirt mainly composed of silicon and calcium and oily dirt from cooking and dishes, and also the bathtub in the bathroom, the floor and wall of the bathroom, the toilet bowl in the washstand or the toilet room, etc. The soiling on the surface consists of oily substances secreted from the human body, fatty acid metal salts, calcium phosphate and the like. On the other hand, dirt on the walls and windows of buildings is dust in the air and nitrogen oxides, sulfur oxides, hydrocarbons, silicon oxides, iron oxides, etc., which are exhaust gas components of cars, cotton dust, tobacco dust, dust, etc. Consists of sebum dirt such as. These dirt components become dirt which is very difficult to remove after being left for a long time.

  Conventionally, as a cleaning agent for removing these stains, neutral or alkaline containing an acidic cleaning agent using hydroxycarboxylic acid, hydrochloric acid or the like as an acidic substance, or a metal ion blocking agent typified by ethylenediaminetetraacetic acid salt or the like Detergents are known.

  On the other hand, the cleaning effect of acetic acid and vinegar has been known for a long time. However, since acetic acid and vinegar have a unique acetic acid odor, when acetic acid and vinegar are mixed as a washing component, some acetic acid odor must be endured at the time of use, and there was a problem that the feeling of use of the product is significantly reduced. .

  Therefore, a method of enhancing the feeling of use of a detergent containing acetic acid by masking an acetic acid odor has been proposed, for example, in Patent Document 1, in a detergent composition containing acetic acid, yuzu, lemon, lime, There is disclosed a detergent composition comprising grapefruit, mandarin, orange citrus flavor or a fruit flavor which is apple, peach, pineapple, strawberry, banana, and a grape flavor.

JP, 2002-3886, A

  When acetic acid and vinegar are added in a necessary amount to enhance the cleaning effect, the amount is far greater than that of the flavor, and the method described in Patent Document 1 completely eliminates the odor of acetic acid by the method described in Patent Document 1. It is necessary to perfume a large amount of strong perfume. In that case, there is a problem that the odor of the detergent composition becomes extremely strong even if the acetic acid odor can be masked. In particular, in the kitchen close to the dining table, since the odor affects the taste, a detergent having a very strong odor has been unsuitable.

  In view of the above problems, the present invention aims to provide an acetic acid odor control agent capable of masking an acetic acid odor without excessively strengthening the aroma of the composition, and an acetic acid detergent composition containing the same. I assume.

  In order to achieve the above object, the present invention is an acetic acid deodorant agent which is compounded in an acetic acid detergent composition containing acetic acid as an active ingredient and which comprises one or more alkyl glycosides.

  Further, the present invention is characterized in that, in the acetic acid odor inhibitor having the above-mentioned constitution, the alkyl chain length of the alkyl glycoside is C4 to C10.

  Further, the present invention is characterized in that, in the above-described acetic acid odor inhibitor, the alkyl glycoside is one or two selected from decyl glycoside and octyl glycoside.

  Further, the present invention is characterized in that, in the acetic acid odor suppressant having the above-mentioned constitution, the compounding amount of the alkyl glycoside with respect to the acetic acid detergent composition is 0.2% by mass or more and 15% by mass or less.

  Further, the present invention is characterized in that, in the acetic acid odor suppressant having the above-mentioned constitution, a blending amount of the alkyl glycoside with respect to the acetic acid detergent composition is 1% by mass or more and 3% by mass or less.

  Further, the present invention comprises (A) 1% by mass or more and 5% by mass or less of acetic acid, (B) an acetic acid odor inhibitor of 0.2% by mass or more and 15% by mass or less of an alkyl glycoside, and (C) water. Acetic acid detergent composition characterized by

  Further, the present invention is characterized in that, in the acetic acid cleaner composition having the above-mentioned constitution, the alkyl chain length of the alkyl glycoside is C4 to C10.

  Further, the present invention is characterized in that, in the acetic acid detergent composition having the above-mentioned constitution, the alkyl glycoside is one or two selected from decyl glycoside and octyl glycoside.

  Further, the present invention is characterized in that, in the acetic acid detergent composition having the above-mentioned constitution, the blending amount of the alkyl glycoside is 1% by mass or more and 3% by mass or less.

  According to the first aspect of the present invention, by using one or more alkyl glycosides as an acetic acid odor inhibitor of the acetic acid detergent composition, it is possible to wash the acetic acid without excessively strengthening the aroma of the composition. The acetic acid odor can be masked when using the agent composition. Therefore, an acetic acid detergent composition having high washability with acetic acid and a feeling of use can be easily produced at low cost.

  Further, according to the second configuration of the present invention, in the acetic acid odor inhibitor of the first configuration, the acetic acid odor is more effectively suppressed by using an alkyl glycoside having an alkyl chain length of C4 to C10. be able to.

  Further, according to the third configuration of the present invention, in the acetic acid odor control agent of the second configuration, one or a member selected from decyl glycosides and octyl glycosides which are particularly high in the acetic acid odor suppressing effect and easy to obtain. By using two types, the control effect of an acetic acid odor can be remarkably improved, and an acetic acid detergent composition excellent in safety can be easily produced at low cost.

  Further, according to the fourth configuration of the present invention, in the acetic acid odor suppressant according to any one of the first to third configurations, the blending amount of the alkyl glycoside to the acetic acid detergent composition is 0.2% by mass or more. By setting it as mass% or less, the control effect of an acetic acid smell at the time of use of an acetic acid detergent composition can be expressed more effectively.

  Further, according to the fifth configuration of the present invention, in the acetic acid odor control agent of the fourth configuration, the blending amount of the alkyl glycoside to the acetic acid detergent composition is 1% by mass or more and 3% by mass or less. The blending amount of the alkyl glycoside can be a blending amount sufficient for improving the feeling of use by suppressing the acetic acid odor at the time of use of the acetic acid detergent composition.

  Further, according to the sixth configuration of the present invention, (A) 1% by mass or more and 5% by mass or less acetic acid, (B) an acetic acid odor inhibitor 0.2% by mass or more and 15% by mass or less alkyl glycoside, By containing water (C), the effect of removing acetic acid stain is high, and by suppressing the acetic acid odor at the time of use, an acetic acid detergent composition having excellent feeling in use and high safety can be obtained.

  Further, according to the seventh aspect of the present invention, in the acetic acid detergent composition of the sixth aspect, when an alkyl glycoside having an alkyl chain length of C4 to C10 is blended as an acetic acid odor inhibitor, The acetic acid detergent composition can be more effectively suppressed.

  Further, according to the eighth configuration of the present invention, in the acetic acid detergent composition of the seventh configuration, decyl glycoside, octyl glycoside, which is particularly high in acetic acid odor suppressing effect as an acetic acid odor inhibitor and easy to obtain By using 1 type or 2 types chosen from these, the control effect of an acetic acid smell can be improved notably, and it becomes an acetic acid detergent composition excellent also in safety.

  Further, according to the ninth configuration of the present invention, in the acetic acid cleaner composition according to any one of the sixth to eighth configurations, the blending amount of the alkyl glycoside with respect to the acetic acid cleaner composition is 1% by mass or more and 3% By setting it as% or less, the compounding quantity of alkyl glycoside can be made into a compounding quantity sufficient in order to improve a feeling of use by suppression of the acetic acid smell at the time of use of an acetic acid detergent composition.

  Hereinafter, the acetic acid deodorant and the acetic acid detergent composition of the present invention will be described in detail. The acetic acid detergent composition of the present invention contains (A) acetic acid, (B) alkyl glycoside, and (C) water.

  The component (A) acetic acid to be blended in the acetic acid detergent composition of the present invention includes synthetic acetic acid, or processed vinegar and brewed vinegar.

  Although the compounding quantity of the acetic acid in the acetic acid detergent composition of this invention is not specifically limited, When there are too few compounding quantities, sufficient cleaning effect may not be acquired. On the other hand, if the compounding amount is too large, it will be difficult to suppress the acetic acid odor by the acetic acid odor inhibitor. The blending amount of acetic acid is preferably in the range of 1% by mass to 5% by mass with respect to the whole of the acetic acid cleaner composition.

Component (B) alkyl glycoside is blended with the acetic acid detergent composition of the present invention as an acetic acid odor inhibitor. The alkyl glycoside is a nonionic surfactant derived from a natural material having a sugar skeleton as a hydrophilic group, in which a sugar and a higher alcohol are glycosidically bonded, and is represented by the following general formula (I).
R-O-Gx ... (I)
In formula (I), R represents a linear or branched alkyl group or alkenyl group. G shows the residue derived from a C5-C6 reducing sugar, and the average degree of condensation of x shows a number of 1-10, preferably 1-2.

  There have been many reports on methods for blending acetic acid to mask the odor of acetic acid. However, blending of an amount of perfume that can mask the odor of acetic acid reversely makes the flavor of the perfume too strong. Then, as a result of conducting earnest studies, the present inventors have found that it is possible to suppress the acetic acid odor of an acetic acid detergent composition by incorporating an alkyl glycoside in the composition. Conventionally, it has been known to blend an alkyl glycoside as a surfactant or a dispersing agent, but it is a finding discovered for the first time by the present inventors that the alkyl glycoside itself has an effect of suppressing an acetic acid odor.

  Specific examples of the alkyl glycoside represented by the general formula (I) include n-butyl-β-D-glycoside (butyl glycoside), n-heptyl-β-D-glycoside (heptyl glycoside), n-octyl- β-D-glycoside (octyl glycoside), n-octyl-β-D-maltoside, n-decyl-β-D-glycoside (decyl glycoside), n-decyl-β-D-maltoside, n-dodecyl-β- Examples include D-glycoside (lauryl glycoside), n-heptyl-β-D-thioglycoside, n-octyl-β-D-thioglycoside, n-nonyl-β-D-thiomaltoside and the like, but of course is not limited thereto .

  Among the above alkyl glycosides, alkyl glycosides in which the carbon number (alkyl chain length) of the alkyl group is C4 to C10 are preferable from the viewpoint of the solubility in the acetic acid detergent composition and the effect of suppressing the acetic acid odor. Examples of the alkyl glycoside having an alkyl chain length of C4 to C10 include butyl glycoside, heptyl glycoside, octyl glycoside and decyl glycoside. In particular, alkyl glycosides having an alkyl chain length of C8 to C10 are preferred because they are widely used as chemical products, are easily available, and have a remarkable acetic acid odor control effect. Examples of the alkyl glycoside having an alkyl chain length of C8 to C10 include octyl glycoside and decyl glycoside.

  If the content of the alkyl glycoside is too small, the acetic acid odor can not be sufficiently masked. On the other hand, when the content of the alkyl glycoside is too large, although the acetic acid odor is masked, the base odor of the alkyl glycoside itself becomes strong. In addition, the solubility of the alkyl glycoside in the acetic acid detergent composition may be reduced, or the viscosity of the acetic acid detergent composition may be increased to make the spray by the trigger spray difficult. It is preferable to mix | blend the compounding quantity of alkyl glycoside in 0.2 to 15 mass% with respect to the whole acetic acid detergent composition, and the range of 1 to 3 mass% is more preferable.

  In addition to acetic acid and an alkyl glycoside as an acetic acid deodorant, a sequestering agent is added to the acetic acid detergent composition. As the sequestering agent, for example, aminopolyacetic acid such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, glycol ether diamine tetraacetic acid, hydroxyethyliminodiacetic acid, triethylenetetramine hexaacetic acid, nitrilotriacetic acid, iminodiacetic acid and / or the like Polyelectrolytes such as polyacrylic acid, polyfumaric acid, polymaleic acid, poly-α-hydroxyacrylic acid, polyacetal carboxylic acid and / or salts thereof, glycolic acid, diglycolic acid, oxydisuccinic acid, carboxymethyl oxysuccinic acid , Citric acid, lactic acid, tartaric acid, malic acid, gluconic acid, carboxymethylsuccinic acid, carboxymethyl tartaric acid and other oxycarboxylic acids and / or salts thereof, orthophosphates, pyrophosphates, tripolyphosphates, metaphosphates, hexame Phosphate, phytate and other phosphates, ethane-1,1-diphosphonic acid, ethane-1,1,2-triphosphonic acid, ethane-1-hydroxy-1,1-diphosphonic acid, ethanehydroxy-1 And phosphonic acids such as 1,2-triphosphonic acid and / or salts thereof, 2-phosphonobutane-1,2-dicarboxylic acid, 1-phosphonobutane-2,3,4-tricarboxylic acid, α-methylphosphonosuccinic acid and the like Phosphonocarboxylic acids and / or salts thereof, amino acids such as aspartic acid, glutamic acid, glycine or the like or salts thereof can be used. Among these sequestering agents, oxycarboxylic acids are preferred, and in particular, citric acid, malic acid or salts thereof enhance detergency, and the user erroneously uses hypochlorite as a main component. It is more preferable because it has the effect of suppressing the amount of chlorine gas generated when it is used in combination with or mixed with a chlorine bleach or detergent. As salts of these sequestering agents, alkali metal salts, ammonium salts, morpholine salts, alkanolamine salts and the like are preferable, and alkali metal salts are particularly preferable. The content of these sequestering agents is 20% by mass or less, preferably 0.1 to 16% by mass.

  In preparing the acetic acid detergent composition, as components other than the above, various surfactants such as anionic surfactants, nonionic surfactants, amphoteric surfactants and cationic surfactants, perfumes, solvents, A hydrotrope agent, a thickener, an abrasive, an anti-redeposition agent, an inorganic electrolyte, a germicide, an enzyme, a pigment, and the like may be appropriately blended within the range that does not impair the effect of the present invention.

  As an anionic surfactant, for example, alkyl benzene sulfonate, α-olefin sulfonate, alkane sulfonate, alkyl diphenyl ether disulfonate, alkyl or alkenyl ether sulfate, alkyl or alkenyl sulfate, alkyl or alkenyl ether Carboxylic acid salts, alkyl or alkenyl phosphates and the like can be used. Among them, sulfonic acid type anionic surfactants such as alkyl benzene sulfonates having an alkyl chain length of C8 to C18, α-olefin sulfonates, alkane sulfonates and alkyl diphenyl ether disulfonates can be preferably used. In this case, the counter ion which forms a salt is an alkali metal, an alkaline earth metal, an alkanolamine, an ammonium ion or the like, but an alkali metal ion such as a sodium ion or a potassium ion is preferable.

  The nonionic surfactant includes, for example, polyoxyethylene alkyl or alkenyl ether having an alkyl chain length of C8 to C22, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, and polyoxy acids represented by adecaplulonic Ethylene polyoxypropylene block polymers, alkyl glycosides, sucrose fatty acid esters, fatty acid glycerin monoesters, higher fatty acid alkanolamides or alkylene oxide adducts thereof can be used.

  Amphoteric surfactants include alkylamine oxide, amino acid type surfactant, N-acyl amino acid type surfactant, imidazoline type amphoteric surfactant, betaine type amphoteric surfactant, sulfonic acid type amphoteric surfactant Particularly, as betaine type amphoteric surfactant, alkylbetaine, alkylamide betaine, alkylamide carbobetaine and the like, and as sulfonic acid type amphoteric surfactant, alkyl chain length of C8 to C20, preferably C10 to C16 alkyl sulfone Betaine, alkylhydroxysulfobetaine, alkylamidosulfobetaine, alkylamidohydroxysulfobetaine and the like are preferably used. In addition, the amphoteric surfactant has the merit that foamability can be provided.

  Examples of the cationic surfactant include alkyl trimethyl ammonium salts, alkyl dimethyl ammonium salts, alkyl ammonium salts, alkyl benzyl dimethyl ammonium salts and the like having an alkyl chain length of C8 to C22. The counter ions of these cationic surfactants are, for example, chloride ions and bromide ions.

  Other surfactants include alkyl pyrrolidones such as octyl pyrrolidone and dodecyl pyrrolidone, silicones such as dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, and dimethylsiloxane / methyl (polyoxyethylene polyoxypropylene) siloxane copolymer You may mix | blend surfactant and fluorine type surfactant etc.

  As the flavoring agents, hydrocarbons such as aliphatic hydrocarbons, terpene hydrocarbons and aromatic hydrocarbons, alcohols such as aliphatic alcohols, terpene alcohols and aromatic alcohols, ethers such as aliphatic ethers and aromatic ethers, Aliphatic oxides, oxides such as oxides of terpenes, aliphatic aldehydes, terpene aldehydes, hydrogenated aromatic aldehydes, etc., aldehydes such as thioaldehydes, aromatic aldehydes, aliphatic ketones, terpene ketones, hydrogenated aromatics Ketones, aliphatic cyclic ketones, non-benzene aromatic ketones, ketones such as aromatic ketones, acetals, ketals, phenols, phenol ethers, fatty acids, terpene carboxylic acids, hydrogenated aromatic carboxylic acids, aroma Family carboxylic acids, acid amides, aliphatic lactones, macrocycles Lactones, terpene-based lactones, hydrogenated aromatic lactones, lactones such as aromatic lactones, aliphatic esters, furan-based carboxylic acid esters, aliphatic cyclic carboxylic acid esters, cyclohexylcarboxylic acid-based esters, terpene-based carboxylic acid esters, Synthetic fragrances such as esters such as aromatic carboxylic acid esters, nitromusks, nitriles, amines, pyridines, quinolines, nitrogen-containing compounds such as pyrrole and indole, and one or more kinds of natural fragrances from animals and plants Can be mixed and used.

  Specific examples of these perfumes include aldehydes C6 to C12, anisaldehyde, acetal R, acetophenone, acetyl cedrene, adoxyl, allyl amyl glycolate, allyl cyclohexane propionate, alpha damascone, beta damascone, delta damascone , Ambroxlid, ambroxane, amyl cinnamic aldehyde, amyl cinnamic aldehyde dimethyl acetal, amyl valerianate, amyl salicylate, iso amyl acetate, iso amyl acetate, iso amyl salicylate, oulanium thiol, acetyl ugenol, bacdanol, benzyl acetate, benzyl alcohol, benzyl salicylate , Bengamil acetate, bornyl acetate, butyl butyrate, paratertiary butyl cyclohexano Para-tertiary butyl cyclohexyl acetate, ortho tertiary butyl cyclohexanol, benzaldehyde, benzyl formate, caryophyllene, kashmelan, carvone, sedro amber, cedolyl acetate, cedrol, celestrid, cinnamic alcohol, cinnamic aldehyde, cis Jasmone, citral, citral dimethylacetal, citrosal, citronellal, citronellol, citronellyl acetate, citronellyl formate, citronellyl nitrile, cyclaset, cyclamenaldehyde, cyclaprop, caron, coumarin, cinnamyl acetate, delta C6- C13 lactone, dimethyl benzyl carbinol, dihydro jasmon, dihydro linalool, dihydro Lucenol, Dimetol, Dimylcetol, Diphenyl oxide, Ethyl vanaline, Eugenol, Fluate, Fentyl alcohol, Phenyl ethyl phenyl acetate, Galaki solid, Gamma C 6-13 lactone, Geraniol, Geranyl acetate, Geranyl acetate, Geranyl nitrile, Hedion, Helional, Heliotropin , Cis-3-hexenol, cis-3-hexenyl acetate, cis-3-hexenyl salicylate, hexyl cinnamic aldehyde, hexyl salicylate, hyacinth dimethyl acetal, hydrotropic alcohol, hydroxycitronellal, indole, ionone, Isobornyl acetate, isocyclo citral, iso E super, isoyugenol, isononyl Acetate, isobutyl quinoline, jasmaal, jasmo lactone, jasmo filane, coabon, ligstrar, lilyal, lime oxide, limonene, linalool, linalool oxide, linalyl acetate, rilaryl, manvalate, mayyol, mensanyl acetate, mensonate, methyl ansanilate , Methyl ugenol, menthol, alpha methyl ionone, beta methyl ionone, gamma methyl ionone, methyl isoeugenol, methyl lavender ketone, methyl salicylate, muuge aldehyde, mugol, musk TM-II, musk 781, musk C14, Musk T, musk ketone, muskuchibetin, musk mosken, milacaldehyde, methylphenyl acetate, nerol, nerilysace Over DOO, Bruno peel acetate, Nopiruaruko - Le, neo Verga formate, Okemos No. 1, Oryribone, oxyphenylone, paracresyl methyl ether, pentalid, phenylethyl alcohol, phenylethyl acetate, alpha pinene, rubafuran, rose phenone, rose oxide, sandaroa, sundala, sundela, santa rex, styraryl acetate, styra reel Propionate, Terpineol, Terpinyl Acetate, Tetrahydrolinalool, Tetrahydrolinalyl Acetate, Tetrahydrogeraniol, Tetrahydrogeraniol Acetate, Tonalid, Traserolide, Tripural, Timole, Croiline, Verdox, Yala Yala, Anise oil, bay oil, boad rose oil, cananga oil, cardamom oil, cassia oil, cedarwood oil, orange oil, mandarin oil, tangerine oil, basil oil Nutmeg oil, citronella oil, clove oil, coriander oil, elemi oil, eucalyptus oil, fennel oil, galvanum oil, geranium oil, hiba oil, soy sauce, jasmine oil, lavandine oil, lavender oil, lemon oil, lemon grass oil, lime Oil, neroli oil, oak moth oil, ochochi oil, patchouli oil, peppermint oil, perilla oil, petit gren oil, pine oil, rose oil, rosemary oil, sperm oil, chaff oil, clary sage oil, sandalwood oil, spearmint oil, Spike lavender oil, star anise oil, thyme oil, tonka tincture, turpentine oil, crocodile bean tincture, vetiver oil, ylang ylang oil, grapefruit oil, zuzu oil, benzoin, peru balsam, toru balsam, tuberose oil, musk cinchus, castorium Tincture, chibitte tincture, a Bar grease tincture and the like.

  The solvent can be blended as a solubilizer when the alkyl glycoside or the flavor is difficult to dissolve in water. As the solvent, lower alcohols such as ethanol and isopropanol, polyhydric alcohols such as ethylene glycol, propylene glycol and glycerin, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether , Diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, propylene glycol monobutyl ether, propylene glycol tert-butyl ether, Lopylene glycol monobutyl ether, tripropylene glycol monobutyl ether, polyoxyethylene (P = 1 to 3) polyoxypropylene (P = 1 to 4) glycol monoethyl ether (P represents an average added mole number), polyoxyethylene P = 1 to 2) Polyoxypropylene (P = 1 to 3) glycol monobutyl ether, propylene glycol dimethyl ether, dipropylene glycol dimethyl ether, polyoxyethylene (P = 2 to 3) polyoxypropylene (P = 2 to 3) glycol Glycol ether solvents such as dimethyl ether, polyoxyethylene (P = 2 to 4) glycol phenyl ether, phenyl carbitol, phenyl cellosolve, benzyl carbitol and others 3-methyl-3-methoxy butanol , Can be used such as methyl pyrrolidone, glycol ether-based solvents are preferred, especially in view of cleaning effect for oily dirt. The blending amount of these solvents is 30% by weight or less, preferably 1 to 20% by weight.

  Moreover, diethyl phthalate, dipropylene glycol, benzyl benzoate, isopropyl myristate, hercoline etc. can be used as a solvent or retention agent of a fragrance.

  The hydrotrope agent can be blended as a solubilizing agent for a flavoring agent or solvent which is difficult to dissolve in water, a stabilizer for making the solution uniform, or a foam control agent. As a specific example of a hydrotrope agent, p-toluenesulfonic acid, m-xylene sulfonic acid or their salts etc. are mentioned.

  As the thickener, high molecular weight polysaccharides such as xanthan gum, carrageenan, locust bean gum, alginate, and cellulose derivatives, high molecular weight polyacrylates and polyvinyl alcohol can be used.

  As the abrasive, silica or porous silica, aluminum oxide, titanium oxide, aluminosilicate, silicon carbide, quartz sand, sand, natural crushed material such as shell, mica powder, silica stone, diatomaceous earth, kaoronite, halloysite, montmorillonite, illite, Vermi cue light etc. can be used.

  As the anti-redeposition agent, low molecular weight polyethylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylate, carboxymethyl cellulose and the like can be used.

  By applying or spraying the thus obtained acetic acid cleaner composition of the present invention around a bathroom or a kitchen, various stains such as inorganic stains, oily stains, sebum stains and the like can be effectively removed, and The feeling of use of the product can be enhanced by suppressing the acetic acid odor at the time of use. In addition, as apparent from the examples described later, when the foamer portion forming foam is attached to the trigger pump and sprayed in a foam shape, the effect of suppressing acetic acid odor compared to the case where the foamer portion is removed and sprayed in a mist shape Becomes higher.

  In addition, the acetic acid detergent composition of the present invention has a very simple composition in which (A) acetic acid and (B) alkyl glycoside are mixed in (C) water. Therefore, in addition to being easy to manufacture, the acetic acid smell at the time of use is not bothered and the feeling of use is extremely high.

  The present invention is not limited to the above-described embodiment, and various modifications can be made within the scope of the claims, and an embodiment obtained by appropriately combining the technical means respectively disclosed in different embodiments. The form is also included in the technical scope of the present invention. Hereinafter, the effects of the present invention will be more specifically described by way of examples, but the present invention is not limited to these examples.

[Confirmation test of acetic acid odor control effect]
The acetic acid detergent compositions of Inventions 1 to 19 and Comparative Examples 1 to 6 were prepared, and the effect of suppressing acetic acid odor was investigated.

In the test method, each sample was placed in a trigger pump attached with a foam-forming unit, and the intensity of acetic acid odor when sprayed once in a 200 mL beaker was scored according to the following criteria.
Almost odorless: 2 points somewhat odor: 1 point considerably smells: 0 point

Based on the average score of the scores of four subjects, the control effect of acetic acid odor was evaluated in the following three stages. The results are shown in Tables 1 to 3 together with the formulations of Inventions 1 to 19 and Comparative Examples 1 to 6.
Average score is 1.5 or more: ◎
Average score is 1 or more and 1.25 or less: ○
Average point is 0.75 or less: x

注１；各成分の数字は質量％
注２；ノニオシドＢ−１５（第一工業製薬社製）
注３； ＳＩＭＵＬＳＯＬ ＳＬ７Ｇ（ＳＥＰＰＩＣ社製、平均縮合度ｘ：１〜１．５）
注４；ノニオシドＯ−１３（第一工業製薬社製）
注５；Ｏｒａｍｉｘ ＮＳ１０（ＳＥＰＰＩＣ社製）
※１；トリガーポンプからフォーマー部を外してミスト状にスプレー。
※２；溶解性が不均一であったためエタノールを添加。
※３；酢酸臭は消失したが、グリコシド自体の臭いが強い。

Note 1; Figures for each component are% by mass
Note 2; Nonioside B-15 (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.)
Note 3; SIMULSOL SL7G (SEPPIC, average condensation degree x: 1 to 1.5)
Note 4; Nonioside O-13 (Daiichi Kogyo Seiyaku Co., Ltd.)
Note 5; Oramix NS10 (manufactured by SEPPIC)
※ 1; Remove the former from the trigger pump and spray in the form of mist.
※ 2: Add ethanol because the solubility was uneven.
※ 3; Acetic acid smell disappeared, but smell of glycoside itself is strong.

  As a result of the test, the acetic acid detergent composition of the present invention 1 to 19 containing 0.2% by mass to 15% by mass of alkyl glycoside as an acetic acid odor inhibitor, the compounding amount of acetic acid is 1.5% by mass to 5% It was confirmed that the acetic acid odor was significantly reduced in the acetic acid detergent composition which is%. In particular, in the inventions 3 to 6 and 9, 11 to 14, 16 and 17 in which 1% by mass to 3% by mass of decyl glycoside and / or octyl glycoside as an alkyl glycoside are blended, the blending amount of acetic acid is 1.5% by mass to The acetic acid odor could be effectively reduced in the 3% by mass acetic acid detergent composition.

  Also, from the comparison of Examples 9 and 10, when the former is attached to the trigger pump and sprayed in a foam shape (Example 9), the acetic acid is removed as compared to the case where the former is removed and sprayed in a mist (Example 10) It has been confirmed that the odor control effect is enhanced.

  On the other hand, Comparative Examples 1 and 2 in which the compounding amount of the alkyl glycoside is 0.1% by mass, Comparative Examples 3 and 4 in which the compounding amount of the acetic acid is 10% by mass, and Comparative Example 6 in which the alkyl glycoside is not compounded. In each case, there was a pungent odor of acetic acid, and no effect of reducing acetic acid odor was observed. In addition, in Comparative Example 5 in which 30% by mass of octyl glycoside was blended, although the acetic acid odor disappeared, the odor of the glycoside itself was strong and not practical.

[Production Example of Acetic Acid Detergent Composition]
1.5% by mass of acetic acid, 3% by mass of octyl glycoside (acetic acid deodorant), 2% by mass of amine oxide (amphoteric surfactant) having an alkyl chain length of C12, benzalkonium chloride (cationic surfactant) 0. Purified water was added to 1% by mass, 2% by mass of ethylenediaminetetraacetic acid disodium salt (sequestering agent), and 5% by mass of diethylene glycol monobutyl ether (solvent) to prepare an acetic acid detergent composition at 100% by mass.

  A practical test was conducted to check the washability and the strength of the acetic acid odor in a household basin to which hot water stains adhere, using the obtained acetic acid cleaner composition. The masking effect of acetic acid odor is good. And the washability was also excellent.

  According to the acetic acid deodorant of the present invention, it is possible to obtain an acetic acid detergent composition for bathroom and kitchen surroundings which is excellent in the effect of masking acetic acid odor and has high detergency.

Claims (9)

  An acetic acid odor inhibitor which is compounded in an acetic acid detergent composition containing acetic acid as an active ingredient and which comprises one or more alkyl glycosides.   The acetic acid odor inhibitor according to claim 1, wherein the alkyl chain length of the alkyl glycoside is C4 to C10.   The acetic acid odor inhibitor according to claim 2, wherein the alkyl glycoside is one or two selected from decyl glycoside and octyl glycoside.   The compounding quantity of the said alkyl glycoside with respect to the said acetic acid detergent composition is 0.2 mass% or more and 15 mass% or less, The acetic acid odor inhibitor in any one of the Claims 1 thru | or 3 characterized by the above-mentioned.   The acetic acid deodorant according to claim 4, wherein a blending amount of the alkyl glycoside to the acetic acid detergent composition is 1% by mass or more and 3% by mass or less.   (A) Acetic acid containing 1% by mass to 5% by mass of acetic acid, (B) Acetic acid odor inhibitor 0.2% by mass to 15% by mass of alkyl glycoside, and (C) water Cleaning composition.   The acetic acid detergent composition according to claim 6, wherein the alkyl chain length of the alkyl glycoside is C4 to C10.   The acetic acid detergent composition according to claim 7, wherein the alkyl glycoside is one or two selected from decyl glycoside and octyl glycoside.   The acetic acid detergent composition according to any one of claims 6 to 8, wherein a blending amount of the alkyl glycoside is 1% by mass or more and 3% by mass or less.